Arsenic and fluoride in a loess aquifer in the central area of Argentina

The objective of this study is to analyze the geochemical conditions associated with the presence of arsenic (As) and fluoride (F) in the phreatic aquifer of Coronel Moldes, in the central sector of the Argentine Chacopampean plain. The studied aquifer is composed of silty sand sediments of aeolian origin, typically loess-like sediments. The geochemical composition of water varies from sodium bicarbonate to sodium sulfate-chloride water. As contents range from low concentrations, below detection level, to 250 μg/l. High values of F (up to 12 mg/l) were recorded. A high As–F correlation was found (R ² = 0.84). The pH varied from 7.31 to 8.85 and the nitrates reached concentrations up to 200 mg/l, indicating an oxidant environment. The highest values of As and F agreed with sodium bicarbonate waters as well as with the highest values of pH recorded. There was a high correlation between As and F⁻ as well as between As and the Na/Ca ratio. The composition and texture of loess, low permeability and hydraulic gradients together with the geochemical features of sodium bicarbonate waters are proper conditions for the mobilization of As and F in groundwater in the central area of Argentina.     

Chronology of Late Pleistocene environmental changes in the lower Mahi basin,western India

Sediments exposed in the lower Mahi basin at the southern fringe of the Thar Desert, Rajasthan, India, provide evidence of three distinct depositional environments, namely marine, aeolian and fluvial. These have been used to reconstruct Late Pleistocene environmental and tectonic history of the region. Infrared stimulated luminescence (IRSL) chronology of the fluvial and aeolian litho‐units provides evidence of two major fluvial aggradation phases in the region corresponding to Oxygen Isotopic Stages 5 and 3. The basal marine clay is inferred to represent the last interglacial stage and its present elevation at +20 m a.s.l. is attributed to post‐depositional tectonism. Comparison of fluvial records from other regions indicates interhemispherically documented wetter phases during Oxygen Isotope Stages 5 and 3. Copyright © 2000 John Wiley & Sons, Ltd.     

Late Pleistocene loess‐palaeosol sequences in the Vojvodina region,north Serbia

Late Pleistocene loess‐palaeosol sequences are widespread in the Vojvodina region, with thicknesses reaching a maximum of about 20 m. Our investigations include more than 40 of these loess sections. Geochronology of the last glacial loess‐palaeosol sequences, based on luminescence dating and amino acid racemisation, provides correlations between Upper Pleistocene loess‐palaeosol sediments in Vojvodina and comparable deposits at other European localities. Sedimentary logs of magnetic susceptibility, grain‐size measurements and carbonate content, combined with malacological evidence, indicate two main relatively cold and arid phases during the last glacial period, related to intensive accumulation of loess units L1L1 and L1L2, as well as many brief episodes of dry and windy climatic conditions, suggesting a possible relationship with cold events recorded in the North Atlantic region. Generally, late Pleistocene climate in the region was dry and relatively warm, compared with glacial period sites in central Europe, and was characterised by sharp differences between glacial and interglacial modes. New data and interpretations presented in this study emphasise the significance of loess‐palaeosol sequences in Vojvodina for the reconstruction of the temporal and spatial evolution of late Pleistocene palaeoclimate in this part of Europe. Copyright © 2007 John Wiley & Sons, Ltd.     

Chronology of the Last Glacial Maximum in the Salzach palaeoglacier area (Eastern Alps)

A chronostratigraphy based on luminescence data was established at a key loess profile (Duttendorf) in the northern alpine foreland of Austria. The data help to constrain the timing and duration of the Last Glacial Maximum (LGM) in the area of one of the largest east Alpine piedmont glaciers, the Salzach palaeoglacier. Climate deterioration and maximum advance of this glacier were coeval with the beginning of the main loess accumulation phase in the glacier forefield at ～29–30 ka. A late LGM‐outwash gravel layer deposited on top of the loess profile marks the end of the LGM glacier activity at ～20 ka. The geomorphological setting around the loess profile provides evidence of a major glacier oscillation during the course of the LGM, a phenomenon qualitatively known from other alpine palaeoglaciers but never interpreted in terms of palaeoclimate. A LGM glacier oscillation similar to that of the Salzach palaeoglacier was reported recently from the south Alpine Tagliamento palaeoglacier, suggesting a common forcing. The onset of loess deposition at Duttendorf and the tentatively contemporal advance of the Salzach palaeoglacier reflect, as do other data, the drastic cooling in Europe as a result of Heinrich event 3. The first glacier maximum is not well constrained in the study area but a correlation with the better dated Tagliamento amphitheatre suggests a possible response to Heinrich 2. The second re‐advance occurred synchronously (within dating uncertainties) in both palaeoglaciers forefields (at ～21 ka) but the forcing mechanism remains unknown. Copyright © 2011 John Wiley & Sons, Ltd.     

Palaeoenvironmental evolution and sea‐level fluctuations along the southeastern Pampa grasslands coast of Argentina during the Holocene

Holocene pollen and diatom analyses and complementary data from δ¹⁸O and δ¹³C, malacology and sedimentology have provided a detailed record of vegetation history and palaeoenvironmental change at arroyo Las Brusquitas, on the southeastern coast of the pampas of Argentina especially in relation to past sea levels. Holocene palaeosalinity trends were estimated by Detrended Correspondence Analysis and by salinity indexes based on pollen and diatom data. As a consequence of sea‐level rise from the postglacial an extensive wave‐cut platform formed over which Holocene infilling sequences were deposited unconformably. In these sequences, variation in pollen and diatom assemblages occurred in agreement with changes in mollusc diversity and abundance, isotope values, and sediment deposits. Between ca. 6700 and 6190 ¹⁴C yr BP (6279–6998 cal. yr BP) saline conditions predominated in an environment highly influenced by tides and salt water during the Holocene sea‐level highstand. Between ca. 6200 and 3900 ¹⁴C yr BP (4235–4608 cal. yr BP) shallow brackish water bodies formed surrounded by saltmarsh vegetation that became more widespread from 5180 ¹⁴C yr BP (5830–6173 cal. yr BP) to 3900 ¹⁴C yr BP in relation to a sea‐level stabilisation period within the regression phase. Less saline conditions marked by frequent variations in salinity predominated between ca. 3900 and 2040 yr ¹⁴C BP (1830–2160 cal. yr BP). The intertidal saltmarsh environment changed into a brackish marsh dominated by freshwater conditions and sporadic tidal influence. Halophytic vegetation increased towards ca. 2000¹⁴C yr BP indicating that saline conditions may be due to either desiccation or an unusually high tide range with rare frequency. After ca. 2000 ¹⁴C yr BP the sedimentary sequences were buried by aeolian sand dunes. Changes in Holocene vegetation and environments in Las Brusquitas area are in agreement with data obtained from various southeastern coastal sites of the Pampa grasslands. Copyright © 2005 John Wiley & Sons, Ltd.     

Post-collisional lamprophyric event in Sierra Norte, Córdoba, Argentina: Mineralogical, geochemical and isotopic characteristics

Over 20 lamprophyre dykes, varying in width between a few centimeters and several meters, have been identified in central Sierra Norte – Eastern Pampean Ranges, Córdoba, Argentina. Their mineralogy and chemistry indicate that they are part of the calc-alkaline lamprophyres clan (CAL). They contain phenocrysts of magnesiohornblende ± augite set in a groundmass of magnesiohornblende, calcic-plagioclase, alkali feldspar, and opaque minerals, which designate them as spessartite-type lamprophyres. Alteration products include chlorite, calcite and iron oxides after mafic phenocrysts, though some are partially replaced by actinolite. Feldspars are replaced by carbonate and clay minerals.The dykes are relatively primitive, and show restricted major element variation (SiO₂ 51.1–55.3 wt.%, Al₂O₃ 12–16.6 wt.%, total alkalies 1.5–4.7 wt.%), high Mg# (55–77), high Cr contents (27–988 ppm) and moderate to high Ni contents (60–190 ppm). Lamprophyre LILE (e.g. Rb averages 110 ppm, Sr 211–387 ppm, Ba 203–452 ppm) are high relative to HFSE (e.g., Ta 0.2–1.6 ppm, Nb 4–11 ppm, Y 17–21 ppm), and are enriched in LREE (30–70 times chondrite). They are characterized by relatively high ²⁰⁸Pb/²⁰⁴Pb (38.8–39.9), ²⁰⁷Pb/²⁰⁴Pb (15.7), and ²⁰⁶Pb/²⁰⁴Pb (18.7–20.1), combined with low (epsilon)ε_Nd (−4.69 to −1.52) and a relative moderately high (⁸⁷Sr/⁸⁶Sr)_i of 0.7055–0.7074. The Rb–Sr whole rock isochron indicates an Early Ordovician age of 485 ± 25 Ma. The calculated T_DM (1.7 Ga) suggests that these rocks appear to have originated from a reservoir that was created during a mantle metasomatism event related to the Pampean orogeny.The Sierra Norte lamprophyres show affinities with a subduction-related magma in an active continental margin. Their geochemical and isotopic features suggest a multicomponent source, composed of enriched mantle material variably contaminated by crustal components. The lamprophyric suite emplacement occurred at the dawning stage of the Pampean orogeny, in a regional post-collisional extensional setting developed in the Sierra Norte-Ambargasta batholith (SNAB) in Early Ordovician times.     

Late Quaternary paleosols, stratigraphy and landscape evolution in the Northern Pampa, Argentina

The field properties, micromorphology, grain-size, geochemistry, and optically stimulated luminescence (OSL) ages of two late Quaternary sections have been used to reconstruct the sequence of pedosedimentary processes and to provide insights into landscape evolution in part of the Northern Pampa of Argentina. Paleosols developed in paludal sediments adjacent to the Paraná river at Baradero and in loess at Lozada can both be correlated and linked to other sites, thus enabling for the first time the tentative recognition and tracing of a diachronous soil stratigraphic unit that probably spans the equivalent of at least part of marine oxygen isotope stage (OIS) 5. The paleosol at Lozada was truncated and buried beneath fluvial sediments during the time span of OIS 4 and 3. Eolian gradually replaced paludal inputs at Baradero over this period, and there were also two clearly defined breaks in sedimentation and development of paleosols. The period corresponding to OIS 2 was marked by significant loess accumulation at both sites with accretion continuing into the mid-Holocene only at Lozada. The more developed nature of the surface soil at Baradero probably reflects a combination of a moister climate and a longer soil-forming interval.     

A 20‐ka climate record from Central Himalayan loess deposits

The southwest monsoon that dominated Central Himalaya has preserved loessic silt deposits preserved in patches that are proximal to periglacial areas. The occurrence of such silts suggests contemporary prevalence of cold and dry northwesterly winds. Field stratigraphy, geochemistry, mineral magnetism, infrared stimulated luminescence (IRSL) and radiocarbon dating has enabled reconstruction of an event chronology during the past 20 ka. Three events of loess accretion could be identified. The first two events of loess deposition occurred betweem 20 and 9 ka and were separated by a phase of moderate weathering. Pedogenesis at the end of this event gave rise to a well‐developed soil that was bracketed around 9 to > 4 ka. This was followed by the third phase of loess accretion that occurred around 4 to > 1 ka. Episodes of loess deposition and soil formation are interpreted in terms of changes in the strength of the Indian southwest monsoon. Copyright © 2005 John Wiley & Sons, Ltd.     

Weathering profiles in granites, Sierra Norte (Córdoba, Argentina)

Two weathering profiles evolved on peneplain-related granites in Sierra Norte, Córdoba province, were examined. Several weathering levels, of no more than 2 m thickness, were studied in these profiles. They had developed from similar parent rock, which had been exposed to hydrothermal processes of varying intensity. Fracturing is the most notable feature produced by weathering; iron oxides and silica subsequently filled these fractures, conferring a breccia-like character to the rock. The clay minerals are predominantly illitic, reflecting the mineral composition of the protolith. Smaller amounts of interstratified I/S RO type are also present, as well as scarce caolinite+chlorite that originated from the weathering of feldspar and biotite, respectively. The geochemical parameters define the weathering as incipient, in contrast to the geomorphological characteristics of Sierra Norte, which point to a long weathering history. This apparent incompatibility could be due to the probable erosion of the more weathered levels of the ancient peneplains, of which only a few relicts remain. Similar processes have been described at different sites in the Sierras Pampeanas. Reconstruction and dating of the paleosurfaces will make it possible to set time boundaries on the weathering processes studied and adjust the paleographic and paleoclimatic interpretations of this great South American region.     

Re‐interpretation of the Meikirch pollen record,Swiss Alpine Foreland,and implications for Middle Pleistocene chronostratigraphy

The Meikirch drilling site in the Swiss Midlands north of Bern is re‐interpreted using a combination of sedimentological logging, pollen analyses and luminescence dating. The sedimentary sequence comprises about 70 m of lacustrine deposits, overlain by about 39 m of coarse glacial outwash interpreted to represent at least two independent ice advances. Pollen analyses of the apparently complete limnic sequence reveal a basal late glacial period followed by three warm phases that are interrupted by two stadial periods (Meikirch complex). The warm periods were previously correlated with the Holsteinian and Eemian Interglacials. According to luminescence dating, and with consideration of evidence for Middle Pleistocene climate patterns at other central European sites, a correlation of the Meikirch complex with marine isotope stage (MIS) 7 is now proposed. If this correlation is correct, it implies the presence of three intervals with interglacial character during MIS 7. However, the late Middle Pleistocene vegetational features of the Meikirch complex show significant differences when compared with the pollen record from the Velay region, central France. Possible explanations for this discrepancy are distinct Middle Pleistocene patterns of atmospheric circulation over central Europe and a different distribution of vegetation refugia compared to the Eemian Interglacial and the Holocene. Copyright © 2005 John Wiley & Sons, Ltd.     

Geomorphological investigations and luminescence dating in the southern part of the Khangay and the Valley of the Gobi Lakes (Central Mongolia)

Geomorphological investigations in the catchment area of the Baydragiyn river along the southern slope of the Khangay and in the Valley of the Gobi Lakes in western Mongolia provide evidence for Late Quaternary glaciations and lake‐level changes. Thermoluminescence (TL) and infrared optically stimulated luminescence (IRSL) dating of aeolian and colluvial sediments from the central Khangay place the sediments that overlie fluvial and glaciofluvial terraces in the Holocene. An age of 21 ka is determined for a sand deposit overlying the terrace that is related to the last glacial ice‐margin. Lacustrine sediments from higher beach lines in the Valley of the Gobi Lakes provide evidence for a slightly more humid period around 1.5 ka, and a larger extent of the lakes in the Early Holocene at about 8.5 ka, as also reported from other parts of Central Asia. Remnants of lacustrine sediments buried by alluvial gravel, and indicating a huge palaeolake in the basin of the Orog Nuur, however, date to the early stage of the last glaciation around 70 ka. Copyright © 2001 John Wiley & Sons, Ltd.     

High Resolution Element Records in the Late Pleistocene Xifeng Loess Profile

Eighty-one samples were selected from the Late Pleistocene Xifeng loess profile and analyzed for their element abundances using instrumental neutron activation analysis,and for ^10Be using the AMS method.The results show that the variations of element abundance and ^10Be with dept are similar to those of δ^18O in DSDP ,and may be considered as an indicator of climatic and environmental changes.     

Chronology and the upper dating limit for loess samples from Luochuan section in the Chinese Loess Plateau using quartz OSL SAR protocol

Luminescence dating of loess older than 100 ka has long been a challenge. It has been recently reported that, using optically stimulated luminescence (OSL) of fine-grained quartz (4–11 μm) extracted from loess, the range of luminescence dating could be pushed to 0.6 Ma with OSL ages being in agreement with independent ages [Watanuki, T., Murray, A.S., Tsukamoto, S., 2005. Quartz and polymineral luminescence dating of Japanese loess over the last 0.6 Ma: comparison with an independent chronology. Earth and Planetary Science Letters 240, 774–789]. The aim of this study is to provide a luminescence chronology (20 samples) for the standard Luochuan loess section, and to further examine the upper limit of quartz OSL dating for Chinese loess. The growth curve does not saturate at 700 Gy, and should allow reliable equivalent dose (D_e) determination up to at least 400 Gy. However, when compared with independent chronological control, the D_e that could be treated as reliable is less than 230 Gy (corresponding to 70 ka in age for Chinese loess), and the D_e larger than 230 Gy should be underestimated. Ages for samples from the lower part of palaeosol S1 are severely underestimated, with the maximum age of 95 ka for a sample from the bottom of this palaeosol, much younger than the expected age of 128 ka. The maximum D_e obtained for sample L9/M, collected from loess layer L9 which is below the Matuyama–Brunhes (B/M) boundary whose age is 780 ka, is only 403 Gy which corresponds to an age of 107 ka. The cause of underestimation is not yet clear. The previous results by Watunuki et al. (2005) on the extension of OSL dating of loess to 0.6 Ma is not confirmed. When evaluating the validity of OSL ages in S1, another possibility is to question the already established chronological frame for Luochuan section, which is based on the hypothesis of continuous dust deposition. The assumption of an erosion hiatus between L2 and S1 could make the OSL ages look reasonable. However, if this is the case, then it is difficult to explain why the age of sample L9/M is only 107 ka which could be treated as a saturation age, while the OSL can provide a correct age for loess as old as 94.9 ka for sample LC22 collected from the bottom of S1. Much work is required to clarify these confusions.     

A Pleistocene (MIS 5e) mollusk assemblage from Ezeiza (Buenos Aires Province,Argentina)

A fossil assemblage collected around 3.5 m amsl from Ezeiza, Buenos Aires province, have AMS ¹⁴C ages of ca. 33,000 to ca. 40,000 yr BP, whereas in the literature is a report of a conventional ¹⁴C age of >43,000 yr BP. An OSL age from the overlying deposit corresponds to ca. 22,000 yr. The samples contain marine fossils: mollusks, balanids and corals (Astrangia). La Coronilla (Uruguay, attributed to MIS 5e) is the locality most related to Ezeiza faunistically, despite is not the nearest one. In consequence, the relationship should be addressed to a more similar age and environment than others. The fauna indicates a higher water temperature than today. In Ezeiza exclusively cold water taxa are absent, and we found seven warm taxa with their southern distribution limit displaced northwards today, plus other six at their southern distribution limit. Around 60% of all the species and more than 70% of the individuals are of warm-temperate waters. In sum, although prima facie the numerical ages would locate the deposit in MIS3, faunistic, temperature, and height evidences show that the Ezeiza mollusk assemblage belong to MIS5e. A stronger than presently Brazil warm current, reaching Southern latitudes, may explain the changes in geographical ranges.     

Geochronology of Middle and Upper Pleistocene Loess Sections in Hungary

The application of both thermoluminescence and infrared stimulated luminescence dating to the extensively studied “classical” Hungarian loess/paleosol sequences from Basaharc, Mende, and Paks provides a reliable chronological framework and climatostratigraphic reconstruction for the last interglacial/glacial cycle. Based on this combined luminescence dating study a new chronology is proposed for the “Young Loess” in Hungary. Luminescence dating suggests that the loess below the MF2 horizon formed during the penultimate glaciation. The MF1 horizon probably formed during an interstade within oxygen isotope stage 3. For the youngest loess, overlying MF1, a very high accumulation rate was determined. Large time gaps occur above MF2 and MF1, indicating that most of the record of the last glaciation is missing in the standard sections at Basaharc, Mende, and Paks. Either large discontinuities or a very low accumulation rate occurred in all three type sections during the soil-forming periods. High-resolution studies of climatic proxies using this combined luminescence dating approach provide a reliable chronological framework for loess and loess derivatives of the last glacial cycle in Hungary, although a precise and complete chronostratigraphic reconstruction cannot be achieved from the incomplete records found at these sites.     

Arsenic associations in sediments from the loess aquifer of La Pampa,Argentina

Groundwater from the Quaternary loess aquifer of La Pampa, central Argentina, has significant problems with high concentrations of As (up to 5300 μg L⁻¹) as well as other potentially toxic trace elements such as F, B, Mo, U, Se and V. Total As concentrations in 45 loess samples collected from the aquifer have a range of 3–18 mg kg⁻¹ with a mean of 8 mg kg⁻¹. These values are comparable to world-average sediment As concentrations. Five samples of rhyolitic ash from the area have As concentrations of 7–12 mg kg⁻¹. Chemical analysis included loess sediments and extracted porewaters from two specially cored boreholes. Results reveal a large range of porewater As concentrations, being generally higher in the horizons with highest sediment As concentrations. The displaced porewaters have As concentrations ranging up to 7500 μg L⁻¹ as well as exceptionally high concentrations of some other oxyanion species, including V up to 12 mg L⁻¹. The highest concentrations are found in a borehole located in a topographic depression, which is a zone of likely groundwater discharge and enhanced residence time. Comparison of sediment and porewater data does not reveal unequivocally the sources of the As, but selective extract data (acid-ammonium oxalate and hydroxylamine hydrochloride) suggest that much of the As (and V) is associated with Fe oxides. Primary oxides such as magnetite and ilmenite may be partial sources but given the weathered nature of many of the sediments, secondary oxide minerals are probably more important. Extract compositions also suggest that Mn oxide may be an As source. The groundwaters of the region are oxidising, with dissolved O₂, NO₃ and SO₄ normally present and As(V) usually the dominant dissolved As species. Under such conditions, the solubility of Fe and Mn oxides is low and As mobilisation is strongly controlled by sorption–desorption reactions. Desorption may be facilitated by the relatively high-pH conditions of the groundwaters in the region (7.0–8.8) and high concentrations of potential competitors (e.g. V, P, HCO₃). PHREEQC modelling suggests that the presence of V at the concentrations observed in the Pampean porewaters can suppress the sorption of As to hydrous Fe(III) oxide (HFO) by up to an order of magnitude. Bicarbonate had a comparatively small competitive effect. Oxalate extract concentrations have been used to provide an upper estimate of the amount of labile As in the sediments. A near-linear correlation between oxalate-extractable and porewater As in one of the cored boreholes investigated has been used to estimate an approximate K_d value for the sediments of 0.94 L kg⁻¹. This low value indicates that the sediments have an unusually low affinity for As.     

西藏阿里札达盆地上新世—早更新世河湖相地层年代学研究

通过对西藏阿里札达盆地河湖相地层实测剖面中的古地磁、ESR样品的测试分析,确定了札达盆地新近纪上新世—第四纪早更新世沉积地层的时间序列。测试结果表明:从剖面自下而上所做的古地磁测年数据为5.41～1.60Ma;而ESR测年数据为5.4～1.36Ma,两者大体吻合。根据古地磁、ESR测年结果,可将该套河湖相地层的时序划分为:上新世托林组(N21t)的形成时间为5.41～4.20Ma、上新世古格组(N22g)为4.20～2.57Ma、早更新世香孜组(Qp1-1x)为2.57～1.36Ma。为青藏高原新近纪上新世—第四纪早更新世地层时间序列标尺的建立,以及上新世、早更新世河湖相地层的划分与对比提供了重要依据。     

Fission‐track dating of a tephra layer related to Poti‐Malal and Seguro drifts in the Río Grande basin,Mendoza, Argentina

Two old drift units called Poti‐Malal and Seguro have been differentiated in the Río Grande basin based on relative‐age criteria, stratigraphical relationships, morphology and fission‐track dating. A tephra dated at 0.226 ± 0.025 Ma was deposited on the Poti‐Malal drift and underlies the Seguro outwash, which is inferred to equate with marine oxygen isotope stage 6. The stratigraphical position and age suggest that the tephra post‐dates the Poti‐Malal glaciation and that it is older than the Seguro drift. The Poti‐Malal glaciation must be at least as old as Early–Middle Pleistocene, and the Seguro glaciation is assigned to the penultimate glaciation. The tephra unit may have been deposited during marine oxygen isotope stage 7. Copyright © 2002 John Wiley & Sons, Ltd.     

Multiple and single aliquot luminescence dating techniques applied to quartz extracted from Middle and Upper Weichselian loess,Zemechy, Czech Republic

This paper reports the application of optically stimulated luminescence (OSL) dating to relatively coarse grains (100–200 μm) of quartz extracted from loess. Two approaches were tested – a multiple aliquot technique and a new single aliquot approach, which is especially suited to the dating of small quantities of such grains found in some loess. The results are compared with infra‐red stimulated luminescence and thermoluminescence (TL) measurements on the finer‐grained (4–11 μm) polymineral fraction and TL measurements on the relatively coarse grains of quartz. The advantages of the new single aliquot (OSL) approach are described and the iterating, computer‐controlled measurement procedure is given. The automated iterative single aliquot regeneration (AISAR) method corrects for changes in luminescence sensitivity during the measurement sequence by monitoring the response to a test dose. Some initial measurements are presented for the loess section at Zemechy, Czech Republic, and these show that the AISAR method gives more precise results than those using a multiple aliquot method. Copyright © 2000 John Wiley & Sons, Ltd.