赛里木地块北缘古元古界变质杂岩地质特征及构造意义

六十年代前,前人对新疆赛里木地块北缘地区构造单元划分侧重对地层、矿产等方面的考察及研究,地质构造涉及较少:六十年代后,随着对本区地质构造研究不断深入,大都以槽台学观点划分,并有较大区别.本次工作在研究前人成果基础上,运用板块学观点,以构造事件时空演化为主线,在区内初步划分出变质核部杂岩.该变质核部杂岩位于伊犁-伊赛克湖微板块的赛里木地块中,由古元古界温泉岩群及博河片麻岩套组成,受挤压作用推覆于长城系特克斯岩群上,其推覆方向由北向南,古生界汗吉尕组、托斯库尔他乌组及阿克沙克组、科古琴山组以盖层叠覆于古元古界上.温泉岩群原岩为亚杂砂岩、杂砂岩,该套地层Sm-Nd模式年龄为2 081～1 884 Ma;博河片麻岩套原岩为一套中酸性侵入岩(花岗岩、英云闪长岩、花岗闪长岩、奥长花岗岩),Sm-Nd模式年龄为2 10～1 086 Ma.长城系特克斯岩群与古元古界温泉岩群为逆冲推覆韧性断层接触,为一套浅海相碎屑岩、碳酸盐岩.     

辽东地区古元古代变基性岩床的成因和构造意义

辽东地区胶-辽-吉造山带发育大量的变基性岩墙/床,这些岩墙/床对研究造山带古元古代构造演化过程具有重要意义.本文通过对辽东地区辽河群中的变基性岩床进行岩石学、岩石地球化学和锆石LA-ICP-MS U-Pb年代学研究,探讨其成因和形成的构造背景,有助于深入认识胶-辽-吉造山带古元古代地质演化过程.辽东地区变基性岩床顺层侵入于辽河群大石桥组大理岩中,发生角闪岩相变质作用,岩石类型以斜长角闪岩和石榴斜长角闪岩为主,主要矿物为角闪石和斜长石,其他矿物有石榴子石、石英、黑云母、磁铁矿和黄铁矿等.变基性岩床样品的锆石具特征的环带结构和较低的Th/U值(0.01～0.34),指示锆石为变质成因,4个样品的锆石LA-ICP-MS U-Pb定年结果(1854±11 Ma、1846±12 Ma、1847±9 Ma和1848±7 Ma)表明基性岩床发生变质作用的时间为～1.85 Ga,与华北克拉通最终碰撞拼合的时间一致.根据基性岩床与胶-辽-吉造山带其他地区～2.1 Ga的基性岩具有相似的野外产状、岩石学和地球化学特征,推断其侵位时代可能为～2.1 Ga.基性岩床样品的SiO2含量为47.07％～52.18％,K2O+Na2O含量为1.78％～4.70％,MgO含量为3.92％～8.59％,属于拉斑玄武岩系列.大部分样品的稀土总量较低(47.3×10-6～109.5×10-6),富集轻稀土元素和大离子亲石元素(如Rb、Ba、La),亏损高场强元素(如Nb、Ta),Zr、Hf没有明显的亏损且未发生分馏作用.所有样品的Al2O3、CaO和Fe2O3T含量在主量元素相关性图解上分布规律且与MgO含量呈较好的相关性,Nb/La值(0.52～0.73)随SiO2和MgO含量的变化较小,表明岩浆在侵位过程中受地壳混染的程度较低,似"岛弧"型地球化学特征是富集岩石圈地幔源区遭受古俯冲组分改造的结果.结合已有的辽河群变质火山-沉积岩、辽吉花岗岩和基性岩的研究成果,胶-辽-吉造山带在～2.1 Ga处于陆内裂谷环境.     

扬子西南缘盐边群时代及构造环境: 来自碎屑沉积岩的约束

出露于扬子地块西南缘的盐边群为一套火山-沉积岩系,其深入研究对探讨扬子西缘新元古代构造环境具有重要意义.本文对盐边群中碎屑沉积岩进行了较系统的岩石学、碎屑物质组成和地球化学研究,并从小坪组和乍古组中各选取了1件变质砂岩样品进行锆石U-Pb年龄和Hf同位素分析.变质砂岩主要由棱角状-次棱角状火山岩岩屑、石英和长石矿物碎屑组成.碎屑沉积岩Al2O3/SiO2值为0.12～0.4,K2O/Na2O值范围为0.14 ～9.45(其中板岩K2O/Na2O值多大于1.0,而变质砂岩中多数样品的K2O/Na2O值小于1.0).所有样品具有轻-中等程度的轻重稀土元素分异((La/Yb)N=1.6 ～9.37),多数样品具有明显的负Eu异常.εNd(t)值范围为-1.77～ +5.01.变质砂岩碎屑锆石U-Pb年龄峰值为900～ 910Ma,同时存在少量太古代-古元古代碎屑锆石.小坪组和乍古组变质砂岩中年轻碎屑锆石206pb/238U年龄加权平均值分别为888±8Ma和884±14Ma.碎屑物质组成、地球化学和锆石U-Pb年龄结果共同表明,盐边群碎屑沉积为近源沉积,物源区主要为岛孤中酸性火山岩和花岗岩.结合关刀山岩体(857Ma)和荒田组玄武岩(880～830Ma)研究结果,进一步限定盐边群的时代为880～830Ma,形成于弧后盆地环境,其沉积物源区为华夏地块向扬子地块俯冲过程中,扬子西南缘形成的火山岛孤.     

兴安地块南段晚泥盆世包格德岩体时代的厘定及地质意义

中亚造山带东端兴安地块南段的包格德岩体由石英二长岩、二长花岗岩和花岗斑岩3种岩性组成,岩体锆石LA-ICP-MS U-Pb定年结果分别为368±+1 Ma、364±1 Ma、355±1 Ma,为晚泥盆-早石炭世岩浆活动的产物;岩体的(Na2O+K2O)含量为7.62％～8.82％,K2O/Na2O值为0.93～4.21...     

北天山西部温泉岩群中石榴角闪岩的岩石学和变质作用P-T轨迹研究

北天山西部温泉岩群中新发现的石榴角闪岩对于研究中亚造山带的形成与演化具有重要意义。详细的岩相学和相平衡模拟的结果表明,石榴角闪岩的变质演化过程可以划分为三个阶段:(1)升温升压进变质阶段,以石榴子石中包裹绿帘石为特征,矿物组合为石榴子石+角闪石+斜长石+石英+钛铁矿+绿帘石,峰期变质条件为700℃/9. 6kbar,可能发生的变质反应为角闪石+绿帘石+石英→石榴子石+斜长石+水;(2)近等温降压退变质阶段,以石榴子石周围发育由"斜长石+石英+角闪石"组成的"白眼圈"结构为特征,可能发生的变质反应为石榴子石+石英+水→角闪石+斜长石;(3)降温降压退变质阶段,以石榴子石发育绿泥石化为特征。结合前人研究成果,推测石榴角闪岩形成于晚奥陶世古亚洲洋俯冲消减的环境中。     

柴北缘赛坝沟金矿床中英云闪长岩的锆石U-Pb年龄、地球化学特征及地质意义

对赛坝沟英云闪长岩进行了 LA-ICP-MS锆石U-Pb年龄测试及岩石地球化学分析.结果表明,英云闪长岩的形成年龄为(470.4±5.2)Ma,属中奥陶世.英云闪长岩SiO2含量为62.46％～64.19％,平均为63.20％,Al2O3含量为14.39％～15.01％,平均为14.71％,全碱含量(K2O+Na2O)...     

东准噶尔北缘老山口矿区花岗质岩体 地球化学特征

东准噶尔北缘老山口铁铜金矿区花岗质岩体主要有石英闪长岩、黑云母闪长岩、二长花岗岩、正长斑岩和闪长(玢)岩.对黑云母闪长岩和正长斑岩进行了岩石地球化学研究,结果表明:黑云母闪长岩SiO2含量介于54.43％～55.10％,Al2O3和CaO含量分别为16.92％～17.64％和5.35％ ～ 5.94％,Mg#值为(51.95 ～55.96),富碱(K2O+ Na2O =9.0％ ～9.43％)和高钾(K2O/Na2O=1.32～1.74);与之相比,正长斑岩的SiO2 (59.96％ ～63.60％)、Al2O3(18.15％ ～ 19.13％)和Mg#(30.16 ～ 48.20)、全碱(K2O+Na2O=11.81％～13.17％)含量偏高,CaO含量(1.13％ ～2.47％)和K2O/Na2O比值(1.1 ～1.53)偏低.它们属钾玄质系列岩石.所有岩石富集LREE和Rb、K、Pb、Sr和Zr,相对亏损Nb、Ta和Ti,是晚古生代准噶尔古大洋俯冲的产物.黑云母闪长岩是俯冲板片熔体和富含钾的地幔楔熔体深侵位的产物,正长斑岩为黑云母闪长岩原始岩浆经角闪石和辉石的分离结晶后又经钾长石堆晶和角闪石残余岩浆浅侵位的产物.     

阿拉善地块北缘雅干花岗岩体地球化学、地质年代学及其对区域构造演化制约

位于阿拉善北部中蒙边境地区的雅干花岗岩体以二长花岗岩为主,岩体的锆石离子探针U-Pb年龄为283.2±2.2Ma (n=14,MSWD=0.016).该花岗岩体具有相对较低的SiO2含量(66.96％～70.71％),和较高的A12O3(15.05％～16.05％)和(Na2O+ K2O)含量(7.24％～9.19％),且岩体钠含量稍高(Na2O/K2O＞1).雅干花岗岩体总体上表现为高钾钙碱性及偏铝质-过铝质的特征.岩体稀土元素总合量为101.9×10-6～133.1 ×1O-6,在稀土元素配分模式图中,岩体表现为轻-重稀土元素中等程度-强烈分异,同时具有明显的负Eu异常(δEu =0.59 ～0.77);在微量元素原始地幔标准化蛛网图中,岩体表现为亏损Nb、Ta、P、Ti,富集Ba、Rb、Cs、Th、K等大离子亲石元素;岩体同位素特征则表现为具有高的(87 Sr/86 Sr)i值(0.707654 ～0.710235)以及负εNd(t)值.根据雅干花岗岩体的形成时代、地球化学特征以及相关的沉积建造特征,可推断该岩体形成于后碰撞环境,表明古亚洲洋在阿拉善地块北缘北部地区的分支于早二叠世(283.2 ±2.2Ma)之前已经闭合.     

西藏八宿吉利地区新发现寒武纪变质花岗岩锆石U-Pb年龄、地球化学特征及其地质意义

八宿吉利地区寒武纪变质花岗岩位于曲扎湖-提卡一带,主要由变质二长花岗岩和变质花岗闪长岩组成。这一新发现对于认识和恢复原特提斯构造历史演化具有重要意义。锆石CL图像显示变质花岗岩锆石为岩浆成因。锆石LA-ICP-MS测年得出片理化变质二长花岗岩年龄为503.7±4.7Ma、变质花岗闪长岩年龄为494.7±3.4Ma,表明该岩体形成时代属于寒武纪。通过岩石地球化学分析,变质二长花岗岩SiO2含量介于69.87%~79.89%之间;变质花岗闪长岩SiO2含量介于66.63%~70.15%之间。前者Al2O3含量变化于12.36%~14.82%,Na2O含量为2.54%~7.16%,K2O含量为0.15%~5.95%,K2O/Na2O=0.02~2.34;后者Al2O3含量变化于14.66%~15.41%,Na2O含量为3.60%~5.63%,K2O含量为0.77%~2.78%,K2O/Na2O=0.14~0.77,属于钙碱性-碱性过铝质花岗岩。在侵入岩构造环境Rb-(Y+Nb)判别图解、Rb-(Yb+Ta)判别图解中,样品均落入“火山弧花岗岩”区域中,表明其形成于大陆边缘火山弧环境。结合锆石测年结果及区域地质背景分析,认为吉利地区变质花岗岩形成于冈瓦纳大陆裂离卡穷微陆块阶段,同时表明原特提斯洋形成最早时限可追溯至寒武纪。     

阿拉善地区前寒武纪斜长角闪岩组成矿物特征及变质温压条件

本文对阿拉善地区四个岩群、岩组和片麻岩中斜长角闪岩的主要组成矿物角闪石和斜长石的化学成分进行了测定并划分了矿物种，对角闪石和斜长石矿物对采用多种计算方法进行了变质温度压力条件的计算。根据Ti-Al^Ⅳ关系图解和(Na2O K2O)-TiO2关系图解，限定其变质相等级。在此基础上结合形成环境进行了变质作用类型的划分。不同岩群、岩组和片麻杂岩中斜长角闪岩所含角闪石和斜长角闪岩一样，显示高TiO2和高K2O的特点。角闪石中FeO MgO含量基本一致，而FeO和MgO含量呈负相关。所有斜长角闪岩中的角闪石都属于钙质角闪石系列。由于MgO和FeO含量和镁铁比值的差异，按Leak B E的分类可分出七个矿物种类。斜长角闪岩中的斜长石主要为中长石，An在42％～66％之间，Ab在34％～58％之间，分布范围较集中。在少数岩石中，除中长石外还见有少量拉长石残余。叠布斯格岩群斜长角闪岩的压力范围为0．5～0．6Gpa时，温度为795～782℃，其变质相为高角闪岩相-角闪麻粒岩亚相，属中高温-高温区域变质作用。巴彦乌拉山岩组斜长角闪岩的变质压力在0．5Gpa时，温度为739℃。从岩相学和矿物组合分析，变质相已达高角闪岩相，相当于中高温区域变质作用。阿拉善岩群德尔和通特岩组的斜长角闪岩已达高角闪岩相，以中低压(0．45Gpa)，温度743℃为其变质温压条件，结合该岩群存在递增变质带的特点，属中高温(偏低)区域动力热流变质作用。波罗斯坦庙片麻杂岩中的斜长角闪岩在压力为0．45～0．8Gpa时，其温度为774～754℃，变质相达高角闪岩相，变质类型属中高温区域变质作用。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.