Isotope geochemistry and origin of calc-alkaline lavas from a caledonian continental margin volcanic arc

Analyses for major and trace elements, including REE, and Sr, Nd and Pb isotopes are reported from a suite of Siluro-Devonian lavas from Fife, Scotland. The rocks form part of a major calc-alkaline igneous province developed on the Scottish continental margin above a WNW-dipping subduction zone. Within the small area (ca. 15 km²) considered, rock types range from primitive basalts and andesites (high Mg, Ni and Cr) to lavas more typical of modern calc-alkaline suites with less than 30 ppm Ni and Cr. There is a marked silica gap between these rocks (< 62%) and the rare rhyolites (> 74%), yet the latter can be generated by fractional crystallization from the more mafic lavas. In contrast, variation in incompatible element concentrations and ratios in the mafic lavas can not be generated by fractional crystallization processes. Increasing SiO₂ is accompanied by increasing Rb, K, Pb, U and Ba relative to Sr and high field strength elements, increasing LREE enrichment and increasing _Sr calculated at 410 Ma, and by decreasing HREE, Eu/Eu*, Sm/Nd and _Nd (410). _Nd and _Sr are roughly anticorrelated and have more radiogenic compositions than the mantle array, in common with data reported elsewhere from this part of the arc. The correlation extrapolates up to cross the mantle array within the composition field of the contemporary MORB source, and extrapolates down towards the probable compositional range of Lower Palaeozoic greywackes, which may form the uppermost 8 km of the crust, or may be supplied to the source by subduction. One sample, however, lies within the mantle array, and closely resembles lavas from northwestern parts of the arc, where a mantle source with mild time-integrated Rb/Sr and LREE enrichment has been inferred. The lavas have relatively high initial ²⁰⁷Pb/²⁰⁴Pb for their ²⁰⁶Pb/²⁰⁴Pb, a feature which has been interpreted elsewhere as the result of incorporation of a sediment component into arc magmas. The systematic changes with increasing SiO₂ in isotopic and chemical parameters can be explained by mixing of a greywacke-derived component with depleted mantle. The various possible mixing mechanisms are discussed, and it is considered most likely that mixing occurred in the mantle source through greywacke subduction. The bulk of the Rb, K, Ba and Pb in the lavas is probably recycled from the crust, whereas less than some 40% of the Sr and Nd is recycled. The calc-alkaline chemical trends are solely a function of mixing with the sediment component.     

Pyroxenite melting at subduction zone: Implications for the origin of mafic arc magmas

<正>1. Introduction The oceanic arc basalts and continental arc andesites are typical products of subduction zone magmatism(Straub et al., 2011; Zheng et al., 2020). However, there has been controversy over the lithology of their magma sources. As this issue is closely related to both physicochemical and geodynamic mechanisms of subduction zone magmatism, it has become one of the key issues in the study of convergent plate margins(Zheng et al., 2022).     

Evidence for changing plate motions in southwest Japan and reconstructions of the Philippine Sea plate

Abstract We propose that a change in convergence between the Pacific and Eurasian plates and the demise of the Kula-Pacific spreading centre at ca 43 Ma resulted in an ∼40° counterclockwise rotation in shortening direction within the Eocene Shimanto accretionary prism of southwest Japan. Evidence for this interpretation comes from: (1) structural studies of the accreted, deep-sea rocks of the Eocene Shimanto Belt from four widely separated localities; and (2) new plate reconstructions that incorporate the geological history of east Asia as well as the recently recognized reorganization of the Kula and Pacific plates at the time of anomaly 24. These reconstructions suggest that the Philippine Sea plate formed as the Kula-Pacific spreading centre reoriented at the time of anomaly 24 and that the Kula plate was being subducted beneath southwest Japan until ca 43 Ma. Our reconstructions and structural studies suggest that after ca 43 Ma, plate convergence in southwest Japan was oblique to the trend of the continental margin. Oblique convergence was apparently recorded at this time because arc volcanism had decreased and the accretionary prism was not detached from the arc massif. Moreover, the transition from cataclasis and faulting to pressure solution within the accreted sediments may have resulted in a stronger basal décollément, resulting in higher shear stresses along this boundary. We therefore propose that where the arc region and the décollément are of similar strengths, structures within accretionary prisms may record changing plate motions, including oblique convergence.     

Determination of Euler parameters of Philippine Sea plate and the inferences

Euler vectors of 12 plates, including Philippine Sea plate (PH), relative to a randomly fixed Pacific plate(PA) were determined by inverting the 1122 data from NUVEL-1 global plate motion model, earthquake slip vectors along Philippine Sea plate boundary, and GPS observed velocities. Euler vectors of Philippine Sea plate relative to adjacent plates are also gained. Our results are well consistent with observed data and can satisfy the geological and geophysical constraints along the Caroline(CR)-PH and PA-CR boundaries. Deformation of Philippine Sea plate is also discussed by using the plate motion Euler parameters.     

Contrasting pyroclast density spectra from subaerial and submarine silicic eruptions in the Kermadec arc: implications for eruption processes and dredge sampling

Pyroclastic deposits from four caldera volcanoes in the Kermadec arc have been sampled from subaerial sections (Raoul and Macauley) and by dredging from the submerged volcano flanks (Macauley, Healy, and the newly discovered Raoul SW). Suites of 16–32?mm sized clasts have been analyzed for density and shape, and larger clasts have been analyzed for major element compositions. Density spectra for subaerial dry-type eruptions on Raoul Island have narrow unimodal distributions peaking at vesicularities of 80–85%, whereas ingress of external water (wet-type eruption) or extended timescales for degassing generate broader distributions, including denser clasts. Submarine-erupted pyroclasts show two different patterns. Healy and Raoul SW dredge samples and Macauley Island subaerial-emplaced samples are dominated by modes at ~80–85%, implying that submarine explosive volcanism at high eruption rates can generate clasts with similar vesicularities to their subaerial counterparts. A minor proportion of Healy and Raoul SW clasts also show a pink oxidation color, suggesting that hot clasts met air despite 0.5 to >1?km of intervening water. In contrast, Macauley dredged samples have a bimodal density spectrum dominated by clasts formed in a submarine-eruptive style that is not highly explosive. Macauley dredged pyroclasts are also the mixed products of multiple eruptions, as shown by pumice major-element chemistry, and the sea-floor deposits reflect complex volcanic and sedimentation histories. The Kermadec calderas are composite features, and wide dispersal of pumice does not require large single eruptions. When coupled with chemical constraints and textural observations, density spectra are useful for interpreting both eruptive style and the diversity of samples collected from the submarine environment.     

大巴山弧形断裂（镇巴-高川段）的磁性特征及构造意义

秦巴山区的大巴山断裂（镇巴-高川段）及周边地区实施了高精度磁力勘探,经过向上解析延拓、垂向不同阶导数及欧拉反褶积等新方法处理及其分析,结果表明研究区磁场特征具有明显的规律性：横向上分别显示出沉积区、挤压构造变形区及侵入岩区的磁性特征,这是研究区多样化构造特征的具体反映;纵向上,浅部磁场呈现方向性磁场,深部呈现稳定基底的特征,这种磁性差异分界面构成了北大巴山地区逆冲推覆构造的滑脱面.而大巴山主断裂在不同区段表现出不同磁性结构的多样化特征,也反映了不同挤压应力作用下变质程度的差异.     

Volatiles in submarine volcanic rocks from the spreading axis of the East Scotia Sea back-arc basin

The volatile content of glassy pillow rims from East Scotia Sea back-arc basin (BAB) lavas are unlike those of mid-ocean ridge (MOR) pillow-rim glasses, although non-volatile compositions of the two rock groups overlap. The East Scotia Sea samples have three to ten times greater water contents and nearly twice the average CO₂ and Cl contents of MOR samples; F contents are similar. S contents are only one-third those from MOR samples. H₂O and CO₂ contents of glassy pillow rims from Mariana island arc andesites are similar to those in the BAB lavas studied. Nevertheless, volatiles in the East Scotia Sea BAB magmas are probably not directly derived from the subducted slab, because there is no seismic evidence that the slab extends within 200 km of the spreading axis of the East Scotia Sea. Available data do not preclude the possibility that the magmas were contaminated by seawater prior to eruption or that the mantle under the East Scotia Sea spreading center is volatile-rich. The volatiles may have been added to the mantle during an earlier period of subduction, perhaps during the initial formation of the East Scotia Sea basin.     

Recent tectonic stress field and major earthquakes of the Bohai Sea basin

Introduction The present Bohai Sea is a half-closed shallow one in the continent, located at the northeast to North China, with an area about 7.3104 km2. Geologically, it is situated in the northern North China basin and of a short development history. Previous studies (WANG, LI, 1983; Institute of Oceanology, Chinese Academy of Sciences, 1985; HUANG, et al, 1993) show that the Fu-jian-Lingnan uplift in the East China Sea continental shelf sank gradually into the oceanic bottom, mak…     

菲律宾群岛深部速度结构成像与双向俯冲板片构造特征

菲律宾群岛受到欧亚板块、菲律宾海板块和印度-澳大利亚板块的碰撞作用,地质环境复杂,构造因素多样.尽管近几年来已经有了少数关于该区域层析成像的研究,但这些研究的区域主要集中在马尼拉海沟、吕宋岛及中菲律宾地区,而关于群岛周围其他海沟和南菲律宾地区的讨论相对较少.到目前为止,还没有同时获得过关于菲律宾群岛深部纵、横波速度结构的研究,本次研究通过反演155779条P波震相和59642条S波震相,同时获得了菲律宾群岛从地表至150 km深度的纵、横波速度结构.地震层析成像结果表明该地区的壳幔速度结构具有较强的不均一性,地壳内部存在着广泛的低速异常,而表征俯冲板块的高速异常则沿着群岛周边的海沟展布.南海块体在马尼拉海沟中段的俯冲角度和俯冲活动性比南段小;菲律宾海板块在东吕宋海槽南段微弱的俯冲作用很有可能同本哈姆海台的碰撞有关.菲律宾群岛大部分M_W＞6.0的强震沿着各个板块的边界发生,体现出菲律宾海板块同欧亚板块之间的强耦合作用,群岛西侧的南海块体在马尼拉海沟16°N-20°N之间呈现出的弱耦合状态可能跟北吕宋地区的拉张应力环境有关,南海块体在16°N以南的地区同上覆块体之间的耦合作用较强;群岛东侧的菲律宾海板块在14°N以北的地区没有强震发生,它与菲律宾群岛之间的耦合程度从北向南逐渐增强,在12°N以南的地区要强于12°N以北的地区;此外苏禄海盆和菲律宾构造带之间也存在着强耦合关系.

     

Evolutionary events of Cainozoic Ostracoda of western Philippine Sea and paleoceanographical implications

The Oligocene ostracod fauna of IISDP Site 292 of the western Philippine Sea was marked by high density, diversity and origination, probably reflecting a favorable period for deep-sea Ostraroda; while the sharp decrease in dtmsity and diversity as well as the repeatedly occurring vxtinctions in thc. Neogene may indicate the deterioration in bottom-water environmcnts at that tlme. Five rriajor faunal changes have been recognized in terms of density, diversity and evolutionary artivity (origination and extinction), occurring in the earliest Oligocene (PI8), mid-Oligocene (P21), earliest Miocene (N4), early Middle Miocene (N8) and late Pliocene (N21). respectively. These changes in ostracod faunas are suggested to represent short-term events related to global paleoceanographical changes and to record the Cainozoic cooling history of the West Pacific Ocean and Philippine Sea deep-water. Project supported by the National Natural Science Foundation of China (Grant No. 49676287).     

Paleomagnetic result of the Lower-Cretaceous from Luanping basin,Hebei Province and its tectonic implications*

A paleomagnetic study of about 95 samples from 16 sites sampled in the Early Cretaceous in Luanping basin in Hebei Province was reported. Stepwise thermal demagnetization was used to isolate magnetic components. Most samples have a characteristic direction with a high temperature component above 500°C. The tectonic-corrected data areD = 347.8°,I = 50.4°, α₉₅ = 7.l°, and the corresponding pole position is at 76.1°N, 346.3°E,with dp =6.4°,dm = 3.8°, paleolatitude λ = 31.1°N. This result indicates a counterclockwise post-Cretaceous rotation of 30.7° ±9.8° with respect to the stable Ordos basin in the west of North China Block, and a non-significant northward motion. This rotation could be related to local fault action or structural detachment, or regional NNW-NWWward motion and collision of Kula-Pacific plate with eastern China since the Early Cretaceous.     

Paleomagnetic result of the Lower-Cretaceous from Luanping basin,Hebei Province and its tectonic implications*

A paleomagnetic study of about 95 samples from 16 sites sampled in the Early Cretaceous in Luanping basin in Hebei Province was reported. Stepwise thermal demagnetization was used to isolate magnetic components. Most samples have a characteristic direction with a high temperature component above 500°C. The tectonic-corrected data areD = 347.8°,I = 50.4°, α₉₅ = 7.l°, and the corresponding pole position is at 76.1°N, 346.3°E,with dp =6.4°,dm = 3.8°, paleolatitude λ = 31.1°N. This result indicates a counterclockwise post-Cretaceous rotation of 30.7° ±9.8° with respect to the stable Ordos basin in the west of North China Block, and a non-significant northward motion. This rotation could be related to local fault action or structural detachment, or regional NNW-NWWward motion and collision of Kula-Pacific plate with eastern China since the Early Cretaceous.

     

Geomorphic characteristics of the Minjiang drainage basin (eastern Tibetan Plateau) and its tectonic implications: New insights from a digital elevation model study

Abstract   The Minshan Mountain and adjacent region are the major continental escarpments along the eastern Tibetan Plateau. The Minjiang drainage basin is located within the plateau margin adjacent to the Sichuan Basin. Based on the analysis of the digital elevation model (DEM) acquired by the Shuttle Radar Topography Mission (SRTM), we know that the Minjiang drainage basin has distinct geomorphic characteristics. The regular increasing of local topographic relief from north to south is a result of the Quaternary sediment deposition within the plateau and the holistic uplift of the eastern margin of the Tibetan Plateau versus the Sichuan Basin. Results from DEM-determined Minjiang drainage sub-basins and channel profiles show that the tributaries on the opposite sides are asymmetric. Lower perimeter and area of drainage sub-basins, total channel length and bifurcation ratio within eastern flank along the Minjiang mainstream are the result of the Quaternary differential uplift of the Minshan Mountain region. Shorter stream lengths and lower bifurcation ratio might be the indications of the undergrowth and newborn features of these eastern streams, which are also representative for the eastern uplift of the Minshan Mountain.     

Geology and geochemistry of lavas at Nekoma volcano: Implications for origin of Quaternary low-K andesite in the north-eastern Honshu arc, Japan

Abstract Nekoma volcano forms part of the arc axis volcanic array of the North-eastern Honshu arc, Japan, which is commonly characterized by medium-K lava suites. However, Nekoma is exceptional because many of its lavas are low-K. This anomaly has been a matter of debate. Nekoma was active from 1.1 to 0.35 Ma. The volcano consists of thick andesite flows and domes associated with block and ash flow deposits produced during lava dome formation. A horseshoe-shaped collapse caldera was formed at the summit and small lava domes extruded into the caldera. Stratigraphy, published K–Ar ages, and tephrochronology define three stages of volcanic activity, about 1.1 Ma (Stage 1), 0.8–0.6 Ma (Stage 2) and 0.45–0.35 Ma (Stage 3; post caldera stage). Low-K andesites occur in all stages. Extremely low-K andesite was also associated in Stage 2 and medium-K andesite was dominant in Stage 3. In general, lavas changed from low-K to medium-K after caldera formation. Geochemical study of the Nekoma lavas shows that both low-K and medium-K lavas are isotopically similar and were derived from a common source. Adatara and Azuma volcanoes, which lie close to Nekoma, also have both low-K and medium-K andesites. However, Sr isotope ratios or temporal-spatial variations in K-level lava classification vary between the three centers. Comparisons of K suites and Sr isotope ratios with frontal arc volcanoes in North-east–Honshu suggest source heterogeneity existed in both medium- and low-K suites. The K contents of lavas and their Sr isotopes are not simply related. This requires re-examination of models for chemical variation of andesites in arcs.     

Morphology,sedimentary characteristics,and origin of the Dongsha submarine canyon in the northeastern continental slope of the South China Sea

The Dongsha submarine canyon is a large canyon belonging to a group of canyons on the northeastern South China Sea margin. Investigation of the Dongsha canyon is important for understanding the origin of this canyon group as well as the transport mechanism of sediments on the margin, and the evolution of the Taixinan foreland basin and the associated Taiwan orogenic belt. In this study, the morphology, sedimentary characteristics, and origin of the Dongsha canyon were investigated by integrating high-resolution multi-channel seismic reflection profiles and high-precision multibeam bathymetric data. This is a slope-confined canyon that originates in the upper slope east of the Dongsha Islands, extends downslope in the SEE direction, and finally merges with the South Taiwan Shoal canyon at a water depth of 3000 m. The total length and average width of the canyon are around 190 and 10 km, respectively. Eleven seismic sequence boundaries within the canyon fills were identified and interpreted as incision surfaces of the canyon. In the canyon fills, four types of seismic facies were defined: parallel onlap fill, chaotic fill, mounded divergent facies, and migrated wavy facies. The parallel onlap fill facies is interpreted as alternating coarser turbidites or other gravity-flow deposits and fine hemipelagic sediments filling the canyon valley. The chaotic fill facies is presumed to be debrites and/or basal lag deposits filling the thalwegs. The mounded divergent and migrated wavy seismic facies can be explained as canyon levees consisting mainly of overspilled fine turbidites and sediment waves on the levees or on the canyon-mouth submarine fans. Age correlation between the sequence boundaries and the ODP Site 1144 data suggests that the Dongsha canyon was initiated at approximately 0.9 Ma in the middle Pleistocene. Mapping of the canyon indicates that the canyon originated at the upstream portion of the middle reach of the modern canyon, and has been continuously expanding both upstream and downstream by retrogressive erosion, incision, and deposition of turbidity currents and other gravity transport processes. The ages of the sequence boundaries representing major canyon incision events are in good agreement with those of global sea-level lowstands, indicating that sea-level changes may have played an important role in the canyon's development. The Dongsha canyon developed in a region with an active tectonic background characterized by the Taiwan uplifting and the development of the Taixinan foreland basin. However, no evidence suggests that the canyon formation is directly associated with local or regional faulting and magmatic activities. Turbidity currents and other gravity transport processes(including submarine slides and slumps) may have had an important influence on the formation and evolution of the canyon.     

Petrological variation of large-volume felsic magmas from Hakkoda-Towada caldera cluster: Implications for the origin of high-K felsic magmas in the Northeast Japan Arc

Abstract The Hakkoda‐Towada caldera cluster (HTCC) is a typical Late Cenozoic caldera cluster located in the northern part of the Northeast Japan Arc. The HTCC consists of five caldera volcanoes, active between 3.5 Ma and present time. The felsic magmas can be classified into high‐K (HK‐) type and medium‐ to low‐K (MLK‐) type based on their whole‐rock chemistry. The HK‐type magmas are characterized by higher K₂O and Rb contents and higher ⁸⁷Sr/⁸⁶Sr ratios than MLK‐type magmas. Both magmas cannot be derived from fractional crystallization of any basaltic magma in the HTCC. Assimilation‐fractional crystallization model calculations show that crustal assimilation is necessary for producing the felsic magmas, and HK‐type magmas are produced by higher degree of crustal assimilation with fractional crystallization than MLK‐type magmas. Although MLK‐type magmas were erupted throughout HTCC activity, HK‐type magmas were erupted only during the initial stage. The temporal variations of magma types suggest the large contribution of crustal components in the initial stage. A major volcanic hiatus of 3 my before the HTCC activity suggests a relatively cold crust in the initial stage. The cold crust probably promoted crustal assimilation and fractional crystallization, and caused the initial generation of HK‐type magmas. Subsequently, the repeated supply of mantle‐derived magmas raised temperature in the crust and formed relatively stable magma pathways. Such a later system produced MLK‐type magmas with lesser crustal components. The MLK‐type magmas are common and HK‐type magmas are exceptional during the Pliocene–Quaternary volcanism in the Northeast Japan Arc. This fact suggests that exceptional conditions are necessary for the production of HK‐type magmas. A relatively cold crust caused by a long volcanic hiatus (several million years) is considered as one of the probable conditions. Intensive crustal assimilation and fractional crystallization promoted by the cold crust may be necessary for the generation of highly evolved HK‐type felsic magmas.     

Geochemistry of basalts from the Dumisseau Formation, southern Haiti: implications for the origin of the Caribbean Sea crust

Basalt and diabase from the Cretaceous Dumisseau Formation, southern Haiti have Mg-numbers of 43–63, TiO₂ contents of 1.6–3.9% and La abundances of 3.6–15.3 ppm.La/Ta ratios average 10, and indicate that the basalts are oceanic in character, distinct from the arc associations forming the northern part of Haiti. Oldest lavas have low TiO₂ (1.6%) and are LREE-depleted, similar to N-MORBs, whereas overlying lavas have higher TiO₂ (2–3.9%) and are LREE-enriched, similar to E-MORBs or hotspot basalts.⁸⁷Sr⁸⁶Sr ratios vary from 0.70280 to 0.70316,¹⁴³Nd¹⁴⁴Nd from 0.512929 to 0.513121, and²⁰⁶Pb²⁰⁴Pb from 19.00 to 19.27. LREE-depleted lavas have high¹⁴³Nd¹⁴⁴Nd (0.51309–0.51310) typical of MORBs, whereas¹⁴³Nd¹⁴⁴Nd in the LREE-enriched lavas varies widely (0.512929–0.513121).Chemical features of the Dumisseau basalts are equivalent to those of Caribbean seafloor basalts recovered on DSDP Leg 15, and support the contention that the Dumisseau is an uplifted section of Caribbean Sea crust. Oldest lavas are analogous to MORB-like basalts cored at Leg 15 Sites 146, 150, 152 and 153, and the overlying lavas are analogous to incompatible-element-enriched basalts cored at Site 151 on the Beata Ridge. Isotopic compositions of the Dumisseau basalts overlap with those of the eastern Pacific Galapagos and Easter Island hotspots. However, the presence of N-MORB basalts in the lower part of the Dumisseau and at the majority of Leg 15 Sites indicates that the anomalously thick Caribbean crust probably did not originate as a hotspot-related basaltic plateau, but may have been generated by on-ridge or near-ridge hotspot magmatism.     

黑龙江省饶河枕状玄武岩古地磁学研究及其构造意义

蛇绿岩中枕状玄武岩的古地磁学研究可为古海洋的恢复与演化提供定量化依据.黑龙江省饶河地区中侏罗世枕状玄武岩的岩石学、岩石磁学研究表明,该岩石具备水下喷出特点,发育辉长结构,载磁矿物为磁铁矿.17个采点181块样品的热退磁实验表明,中侏罗世枕状玄武岩记录了高温分量和中温分量,前者为熔岩喷发记录的原生剩磁方向,平均方向D/I=59.4°/46.3°,α95=6.8°,对应的极位置为40.3°N,224.6°E,A95=7°;后者可能为晚侏罗世—早白垩世岩浆热事件的叠加,平均方向D/I=55.4°/60.6°,α95=3.9°,对应的极位置为50.8°N,210.6°E,A95=5.2°.综合考虑区域地质背景,将这一结果与邻区同时代的古地磁数据对比,推测在中侏罗世之前,在饶河杂岩与佳木斯地体之间存在一定规模的海域,与现今日本海相似;早白垩世时期,该海域封闭,饶河杂岩与华北、西伯利亚板块在动力学上已成为整体.