新疆阿尔泰南缘康布铁堡组钾-钠质流纹岩锆石U-Pb年龄和地球化学

阿尔泰南缘分布着大量的晚古生代康布铁堡组火山岩系,是许多铁矿、铜矿以及铅锌矿的赋矿围岩。阿尔泰南缘麦兹和克朗火山-沉积盆地内的钾-钠质流纹岩的年龄分别为396.7±1.4Ma和394.0±6.0Ma,结合近期研究成果,进一步表明阿尔泰南缘火山岩主要形成于晚古生代早期,锆石U-Pb年龄峰期在400Ma左右。钾-钠质流纹岩具有高硅(SiO₂的含量范围为73%~82%)、高碱(总碱含量介于4%~7%)和过铝质(高A/CNK值>1)的特征,并见有白云母和黑云母的矿物组合,属于高硅高碱过铝质的钙碱性火山岩。此外,它们的Sr和Nd同位素分别为⁸⁷Sr/⁸⁶Sr=0.7074~0.7144,¹⁴³Nd/¹⁴⁴Nd=0.512072~0.512252,具有上地壳来源的特征,说明其岩石成因与初生地壳的部分熔融作用有着密切关系。结合区域地质背景分析,它们都产在与俯冲消减作用有关的陆缘岛弧的地质环境中。因此,我们推断本区钾-钠质流纹岩的原始岩浆为高硅高碱的花岗质岩浆,是由进入陆壳的高侵位玄武岩浆的底侵作用导致其上部地壳近固相线的低程度部分熔融的产物。     

A review of the geological characteristics and mineralization history of iron deposits in the Altay orogenic belt of the Xinjiang,Northwest China

In this review, we describe the geological characteristics and metallogenic–tectonic origin of Fe deposits in the Altay orogenic belt within the Xinjiang region of northwestern China. The Fe deposits are found mainly within three regions (ordered from northwest to southeast): the Ashele, Kelan, and Maizi basins. The principal host rocks for the Fe deposits of the Altay orogenic belt are the Early Devonian Kangbutiebao Formation, the Middle to Late Devonian Altay Formation, with minor occurrences of Lower Carboniferous and Early Paleozoic metamorphosed volcano-sedimentary rocks. The principal mineral-forming element groups of the deposits are Fe, Fe–Cu, Fe–Mn, Fe–P, Fe–Pb–Zn, Fe–Au, and Fe–V–Ti. The Fe deposits are associated with distinct formations, such as volcanic rocks, skarn deposits, pegmatites, granite-related hydrothermal vein mineralization, and mafic pluton-related V–Ti-magnetite deposits. The Fe deposits are most commonly associated with volcanic rocks in the upper Kangbutiebao Formation, in the volcano-sedimentary Kelan Basin, and in skarn deposits at several localities, including the lower Kangbutiebao Formation in the volcano-sedimentary Maizi Basin, and the Altay Formation at Jiaerbasidao–Kekebulake region. Homogenization temperatures of fluid inclusions in the prograde, retrograde and sulfide stages of the skarn type deposit are mainly medium- to high-temperature (cluster between 200 and 500 °C), medium-temperature (cluster between 200 and 340 °C) and low- to medium temperature (cluster between 160 and 300 °C), respectively. Ore fluids in the sedimentation period in the volcano-sedimentary type deposit are characterized by low- to medium temperature (with a peak around 190 °C), low to moderate salinity (3.23 to 22.71 wt.% NaCl equiv). Ore fluids in the pegmatite type deposit are characterized by low- to medium temperature (with a peak at 240 °C), low salinity (with a peak around 9 wt.% NaCl equiv). An analysis of the isotopic data for Fe deposits from the Altay orogenic belt indicates that the sulfur was derived from several sources, including volcanic rocks and granite, as well as bacterial reduction of sulfate from seawater. The present results indicate that different deposit types were derived from various sources. The REE geochemistry of rocks and ores from the Fe deposits in the Altay orogenic belt suggests that the ore-forming materials were derived from mafic volcanic rocks. Based on isotopic age data, the timing of the mineralization can be divided into four broad intervals: Early Devonian (410–384 Ma), Middle Devonian (377 Ma), Early Permian (287–274 Ma), and Early Triassic (c. 244 Ma). The ore-forming processes of the Fe deposits are closely related to volcanic activity and the emplacement of intermediate and felsic intrusions. We conclude that Fe deposits within the Altay orogenic belt developed in a range of tectonic settings, including continental arc, post-collisional extensional settings, and intracontinental settings.     

Metallogenesis of the Carajás Mineral Province, Southern Amazon Craton, Brazil: Varying styles of Archean through Paleoproterozoic to Neoproterozoic base- and precious-metal mineralisation

The Itacaiúnas Belt of the highly mineralised Carajás Mineral Province comprises ca. 2.75 Ga volcanic rocks overlain by sedimentary sequences of ca. 2.68 Ga age, that represent an intracratonic basin rather than a greenstone belt. Rocks are generally at low strain and low metamorphic grade, but are often highly deformed and at amphibolite facies grade adjacent to the Cinzento Strike Slip System. The Province has been long recognised for its giant enriched iron and manganese deposits, but over the past 20 years has been increasingly acknowledged as one of the most important Cu–Au and Au–PGE provinces globally, with deposits extending along an approximately 150 km long WNW-trending zone about 60 km wide centred on the Carajás Fault. The larger deposits (approx. 200–1000 Mt @ 0.95–1.4% Cu and 0.3–0.85 g/t Au) are classic Fe-oxide Cu–Au deposits that include Salobo, Igarapé Bahia–Alemão, Cristalino and Sossego. They are largely hosted in the lower volcanic sequences and basement gneisses as pipe- or ring-like mineralised, generally breccia bodies that are strongly Fe- and LREE-enriched, commonly with anomalous Co and U, and quartz- and sulfur-deficient. Iron oxides and Fe-rich carbonates and/or silicates are invariably present. Rhenium–Os dating of molybdenite at Salobo and SHRIMP Pb–Pb dating of hydrothermal monazite at Igarapé-Bahia indicate ages of ca. 2.57 Ga for mineralisation, indistinguishable from ages of poorly-exposed Archean alkalic and A-type intrusions in the Itacaiúnas Belt, strongly implicating a deep magmatic connection.A group of smaller, commonly supergene-enriched Cu–Au deposits (generally < 50 Mt @ < 2% Cu and < 1 g/t Au in hypogene ore), with enrichment in granitophile elements such as W, Sn and Bi, spatially overlap the Archean Fe-oxide Cu–Au deposits. These include the Breves, Águas Claras, Gameleira and Estrela deposits which are largely hosted by the upper sedimentary sequence as greisen-to ring-like or stockwork bodies. They generally lack abundant Fe-oxides, are quartz-bearing and contain more S-rich Cu–Fe sulfides than the Fe-oxide Cu–Au deposits, although Cento e Dezoito (118) appears to be a transitional type of deposit. Precise Pb–Pb in hydrothermal phosphate dating of the Breves and Cento e Dezoito deposits indicate ages of 1872 ± 7 Ma and 1868 ± 7 Ma, respectively, indistinguishable from Pb–Pb ages of zircons from adjacent A-type granites and associated dykes which range from 1874 ± 2 Ma to 1883 ± 2 Ma, with 1878 ± 8 Ma the age of intrusions at Breves. An unpublished Ar/Ar age for hydrothermal biotite at Estrela is indistinguishable, and a Sm–Nd isochron age for Gameleira is also similar, although somewhat younger. The geochronological data, combined with geological constraints and ore-element associations, strongly implicate a magmatic connection for these deposits.The highly anomalous, hydrothermal Serra Pelada Au–PGE deposit lies at the north-eastern edge of the Province within the same fault corridor as the Archean and Paleoproterozoic Cu–Au deposits, and like the Cu–Au deposits is LREE enriched. It appears to have formed from highly oxidising ore fluids that were neutralised by dolomites and reduced by carbonaceous shales in the upper sedimentary succession within the hinge of a reclined synform. The imprecise Pb–Pb in hydrothermal phosphate age of 1861 ± 45 Ma, combined with an Ar/Ar age of hydrothermal biotite of 1882 ± 3 Ma, are indistinguishable from a Pb–Pb in zircon age of 1883 ± 2 Ma for the adjacent Cigano A-type granite and indistinguishable from the age of the Paleoproterozoic Cu–Au deposits. Again a magmatic connection is indicated, particularly as there is no other credible heat or fluid source at that time.Finally, there is minor Au–(Cu) mineralisation associated with the Formiga Granite whose age is probably ca. 600 Ma, although there is little new zircon growth during crystallisation of the granite. This granite is probably related to the adjacent Neoproterozoic (900–600 Ma) Araguaia Fold Belt, formed as part of the Brasiliano Orogeny.Thus, there are two major and one minor period of Cu–Au mineralisation in the Carajás Mineral Province. The two major events display strong REE enrichment and strongly enhanced LREE. There is a trend from strongly Fe-rich, low-SiO₂ and low-S deposits to quartz-bearing and more S-rich systems with time. There cannot be significant connate or basinal fluid (commonly invoked in the genesis of Fe-oxide Cu–Au deposits) involved as all host rocks were metamorphosed well before mineralisation: some host rocks are at mid- to high-amphibolite facies. The two major periods of mineralisation correspond to two periods of alkalic to A-type magmatism at ca. 2.57 Ga and ca. 1.88 Ga, and a magmatic association is compelling.The giant to world-class late Archean Fe-oxide Cu–Au deposits show the least obvious association with deep-seated alkaline bodies as shown at Palabora, South Africa, and implied at Olympic Dam, South Australia. The smaller Paleoproterozoic Cu–Au–W–Sn–Bi deposits and Au–PGE deposit show a more obvious relationship to more fractionated A-type granites, and the Neoproterozoic Au–(Cu) deposit to crustally-derived magmas. The available data suggest that magmas and ore fluids were derived from long-lived metasomatised lithosphere and lower crust beneath the eastern margin of the Amazon Craton in a tectonic setting similar to that of other large Precambrian Fe-oxide Cu–Au deposits.     

U–Pb dating of single detrital zircon grains from Mesozoic sandstone in the Beipiao Basin in the eastern Yan-Liao Orogenic Belt, China: provenance and correlation of tectonic evolution

Single grain U–Pb ages of sediments from the Beipiao Basin, Northeast China were conducted to determine the evolution of basin provenance. Zircons from a sandstone in the Upper Triassic Laohugou Formation yield a wide range of ages and, according to their U–Pb ages, fall into four groups: 209.3±4.0–304.2±4.9, 1565.5±71–2154±50, 2400±35–2499±9, 2512±11–2557±74 Ma. These ages indicate that the zircons were principally derived from Late Archean, Proterozoic and Late Paleozoic plutonic rocks. Intrusions in the Mongolian Accretion Belt and the northern margin of the North China Block (NCB) were probably the main source of the sediments in the basin, but the easterly Liaodong Block also provided minor detrital material, with lower U–Pb ages, during the Late Triassic. Most of the U–Pb ages from zircons collected from a sandstone in the Lower Jurassic Beipiao Formation range from 194.3±2.9 to 233.8±4.2 Ma, reflecting the major sediment source during the Early Jurassic. Zircons derived from Late Indosinian plutonic rocks increased, which suggests that the detritus was supplied mainly from the interior of the Yan-Liao Orogenic Belt, especially from the Liaodong Block. Late Indosinian zircons (200–230 Ma) were eroded and deposited in the Lower Jurassic Beipiao Formation, and this implies that intensive tectonic activation and uplift of the Yan-Liao Orogenic Belt in the Mesozoic commenced in the Late Indosinian.     

Late Paleozoic–Early Triassic magmatism on the western margin of Gondwana: Collahuasi area, Northern Chile

The basement in the ‘Altiplano’ high plateau of the Andes of northern Chile mostly consists of late Paleozoic to Early Triassic felsic igneous rocks (Collahuasi Group) that were emplaced and extruded along the western margin of the Gondwana supercontinent. This igneous suite crops out in the Collahuasi area and forms the backbone of most of the high Andes from latitude 20° to 22°S. Rocks of the Collahuasi Group and correlative formations form an extensive belt of volcanic and subvolcanic rocks throughout the main Andes of Chile, the Frontal Cordillera of Argentina (Choiyoi Group or Choiyoi Granite-Rhyolite Province), and the Eastern Cordillera of Peru.Thirteen new SHRIMP U–Pb zircon ages from the Collahuasi area document a bimodal timing for magmatism, with a dominant peak at about 300 Ma and a less significant one at 244 Ma. Copper–Mo porphyry mineralization is related to the younger igneous event.Initial Hf isotopic ratios for the ~ 300 Ma zircons range from about − 2 to + 6 indicating that the magmas incorporated components with a significant crustal residence time. The 244 Ma magmas were derived from a less enriched source, with the initial Hf values ranging from + 2 to + 6, suggestive of a mixture with a more depleted component. Limited whole rock ¹⁴⁴Nd/¹⁴³Nd and ⁸⁷Sr/⁸⁶Sr isotopic ratios further support the likelihood that the Collahuasi Group magmatism incorporated significant older crustal components, or at least a mixture of crustal sources with more and less evolved isotopic signatures.     

U–Pb SHRIMP monazite ages of the giant Morro Velho and Cuiabá gold deposits, Rio das Velhas greenstone belt, Quadrilátero Ferrífero, Minas Gerais, Brazil

U–Pb SHRIMP results of 2672 ± 14 Ma obtained on hydrothermal monazite crystals, from ore samples of the giant Morro Velho and Cuiabá Archean orogenic deposits, represent the first reliable and precise age of gold mineralization associated with the Rio das Velhas greenstone belt evolution, in the Quadrilátero Ferrífero, Brazil. In the basal Nova Lima Group, of the Rio das Velhas greenstone belt, felsic volcanic and volcaniclastic rocks have been dated between 2792 ± 11 and 2751 ± 9 Ma, coeval with the intrusion of syn-tectonic tonalite and granodiorite plutons, and also with the metamorphic overprint of older tonalite–trondhjemite–granodiorite crust. Since cratonization and stable-shelf sedimentation followed intrusion of Neoarchean granites at 2612 + 3/− 2 Ma, it is clear that like other granite–greenstone terranes in the world, gold mineralization is constrained to the latest stages of greenstone evolution.     

Paleomagnetism of Middle Proterozoic mafic intrusions and Upper Proterozoic (Nankoweap) red beds from the Lower Grand Canyon Supergroup, Arizona

Paleomagnetic data from lavas and dikes of the Unkar igneous suite (16 sites) and sedimentary rocks of the Nankoweap Formation (7 sites), Grand Canyon Supergroup (GCSG), Arizona, provide two primary paleomagnetic poles for Laurentia for the latest Middle Proterozoic (ca. 1090 Ma) at 32°N, 185°E (dp=6.8°, DM=9.3°) and early Late Proterozoic (ca. 850–900 Ma) at 10°S, 163°E (dp=3.5°, DM=7.0°). A new ⁴⁰Ar/³⁹Ar age determination from an Unkar dike gives an interpreted intrusion age of about 1090 Ma, similar to previously reported geochronologic data for the Cardenas Basalts and associated intrusions. The paleomagnetic data show no evidence of any younger, middle Late Proterozoic tectonothermal event such as has been revealed in previous geochronologic studies of the Unkar igneous suite. The pole position for the Unkar Group Cardenas Basalts and related intrusions is in good agreement with other ca. 1100 Ma paleomagnetic poles from the Keweenawan midcontinent rift deposits and other SW Laurentia diabase intrusions. The close agreement in age and position of the Unkar intrusion (UI) pole with poles derived from rift related rocks from elsewhere in Laurentia indicates that mafic magmatism was essentially synchronous and widespread throughout Laurentia at ca. 1100 Ma, suggesting a large-scale continental magmatic event. The pole position for the Nankoweap Formation, which plots south of the Unkar mafic rocks, is consistent with a younger age of deposition, at about 900 to 850 Ma, than had previously been proposed. Consequently, the inferred 200 Ma difference in age between the Cardenas Basalts and overlying Nankoweap Formation provides evidence for a third major unconformity within the Grand Canyon sequence.     

Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb–Zn–Ag–Au orefield, Northeastern China

The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (²⁰⁶Pb/²⁰⁴Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (²⁰⁶Pb/²⁰⁴Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 17.12 to 17.41, ²⁰⁷Pb/²⁰⁴Pb = 15.47 to 15.54, ²⁰⁸Pb/²⁰⁴Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (²⁰⁶Pb/²⁰⁴Pb = 18.20 to 24.28 and 18.32 to 20.06, ²⁰⁷Pb/²⁰⁴Pb = 15.69 to 16.44 and 15.66 to 15.98, ²⁰⁸Pb/²⁰⁴Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.     

Post-collisional crustal extension setting and VHMS mineralization in the Jinshajiang orogenic belt, southwestern China

The Jinshajiang orogenic belt (JOB) of southwestern China, located along the eastern margin of the Himalayan–Tibetan orogen, includes a collage of continental blocks joined by Paleozoic ophiolitic sutures and Permian volcanic arcs. Three major tectonic stages are recognized based on the volcanic–sedimentary sequence and geochemistry of volcanic rocks in the belt. Westward subduction of the Paleozoic Jinshajiang oceanic plate at the end of Permian resulted in the formation of the Chubarong–Dongzhulin intra-oceanic arc and Jamda–Weixi volcanic arc on the eastern margin of the Changdu continental block. Collision between the volcanic arcs and the Yangtze continent block during Early–Middle Triassic caused the closing of the Jinshajiang oceanic basin and the eruption of high-Si and -Al potassic rhyolitic rocks along the Permian volcanic arc. Slab breakoff or mountain-root delamination under this orogenic belt led to post-collisional crustal extension at the end of the Triassic, forming a series of rift basins on this continental margin arc. Significant potential for VHMS deposits occurs in the submarine volcanic districts of the JOB. Mesozoic VHMS deposits occur in the post-collisional extension environment and cluster in the Late Triassic rift basins.     

阿尔泰铁木尔特铅锌矿床的碳质流体组合及其地质意义

铁木尔特铅锌矿是阿尔泰克兰盆地内最主要的VMS型矿床。矿床受控于阿巴宫-库尔提断裂,铅锌矿体分布于该断裂NE逆冲盘的下泥盆统康布铁堡组地层绿泥石英片岩、大理岩或层状矽卡岩中。矿体形态多呈透镜状、似层状,并整合产于变质岩系中,发育多含矿化层。金属矿物有方铅矿、闪锌矿、黄铜矿、黄铁矿和磁黄铁矿等。铁木尔特铅锌矿床晚期发育多金属硫化物石英脉,至少可识别出3个流体包裹体组合（FIA）。FIO为高盐度流体包裹体组合,主要为含子矿物的多相包裹体（L-V-S型）,部分为气液两相包裹体（L-V型）,局限于单个石英颗粒内,包裹体呈无序分布,或呈孤立的单个包裹体分布,包裹体的最终均一温度322—422．5℃。F11为次生的CO2-H2O流体包裹体组合,主要由单相（LCO2）和两相（LCO2-LH2O）的富CO2包裹体组成,呈线性分布,穿透石英颗粒边界,明显属于次生包裹体范畴。FI2为碳质（CO2-CH4）流体包裹体组合,广泛发育,包裹体主要由单相（LCO2、LCO2-CH4或LCO2-N2）、少量两相（LCO2-LH2O）富CO2包裹体组成,大小5μm-20μm,成群定向分布,穿透石英颗粒边界并切断FI1,是晚于FI1的次生包裹体组合,反映晚期较大的构造一流体活动。对FI2的详细研究表明,LCO2型包裹体的TmCO2=-63．3～-57．7℃,ThCO2=-27．5～＋29．7℃;LCO2-CH4型或LCO2-N2型包裹体的TmCO2=-80．5～-5．5℃,LhCO2=-56．0～-25．0℃;LCO2-LH2O型包裹体CO2相的ThCO2=-66．9--0．9℃,ThCO2=-13．3～＋2．3℃,包裹体的最终均一温度Th,total=243．1—361．1℃。铁木尔特次生碳质流体组合,萨热阔布金矿主成矿阶段、赛都-多拉纳含金剪切带中早期透镜状石英脉碳质流体组合,以及阿舍勒等矿床的次生碳质流体组合,都具有相似的流体性质,均为高密度的CO2-CH4-N2流体,其来源与石炭-二叠造山作用主期的区域动力热流变质作用有关。     

Sedimentary processes caused by felsic caldera-forming volcanism in the Late Miocene to Early Pliocene intra-arc Aizu basin, NE Japan arc

Six large Late Miocene to Quaternary calderas, > 10 km in diameter, cluster together with several medium to small calderas and stratovolcanoes in a 60 × 30 km area of the Aizu volcanic field, southern NE Japan arc. These caldera volcanoes were built on a WNW–ESE trending highland coincident with a local uplifted swell since Late Miocene. The flare-up of felsic volcanism occurred synchronously along the NE Japan arc. Pyroclastic flow sheets from the calderas spread over the surrounding intra-arc basins and are interstratified with various sediments. Geochronological data indicates that the large-caldera eruptions have occurred six times since 8 Ma, at intervals of 1 to 2 million years. Late Miocene to Early Pliocene extra-caldera successions in the basin consist of nine sedimentary facies associations: (1) primary pyroclastics, (2) lahars, (3) gravelly fluvial channels, (4) sandy fluvial channels, (5) floodplains, (6) tidal flats, (7) delta fronts, (8) pro-delta slopes, and (9) pro-delta turbidites. The distribution of facies associations show westward prograding of volcaniclastic aprons, made up of braid delta, braidplain, pyroclastic flow sheet, and incised braided river deposits. The extra-caldera successions record: 1) an increase in felsic volcanism with an associated high rate of volcaniclastic sediment supply at about 10 Ma, prior to catastrophic caldera-forming eruptions; and 2) progradation of volcaniclastic aprons toward the back-arc side in response to the succeeding caldera-forming eruptions and sea-level changes, until about 3 Ma.     

Extensional Late Paleozoic deformation on the western margin of Pangea, Patlanoaya area, Acatlán Complex, southern Mexico

New mapping in the northern part of the Paleozoic Acatlán Complex (Patlanoaya area) records several ductile shear zones and brittle faults with normal kinematics (previously thought to be thrusts). These movement zones separate a variety of units that pass structurally upwards from: (i) blueschist-eclogitic metamorphic rocks (Piaxtla Suite) and mylonitic megacrystic granites (Columpio del Diablo granite ≡ Ordovician granites elsewhere in the complex); (ii) a gently E-dipping, listric, normal shear zone with top to the east kinematic indicators that formed under upper greenschist to lower amphibolite conditions; (iii) the Middle–Late Ordovician Las Minas quartzite (upper greenschist facies psammites with minor interbedded pelites intruded by mafic dikes and a leucogranite dike from the Columpio del Diablo granite) unconformably overlain by the Otate meta-arenite (lower greenschist facies psammites and pelites): roughly temporal equivalents are the Middle–Late Ordovician Mal Paso and Ojo de Agua units (interbedded metasandstone and slate, and metapelite and mafic minor intrusions, respectively) — some of these units are intruded by the massive, 461 ± 2 Ma, Palo Liso megacrystic granite: decussate, contact metamorphic muscovite yielded a ⁴⁰Ar/³⁹Ar plateau age of 440 ± 4 Ma; (iv) a steeply-moderately, E-dipping normal fault; (v) latest Devonian–Middle Permian sedimentary rocks (Patlanoaya Group: here elevated from formation status). The upward decrease in metamorphic grade is paralleled by a decrease in the number of penetrative fabrics, which varies from (i) three in the Piaxtla Suite, through (ii) two in the Las Minas unit (E-trending sheath folds deformed by NE-trending, subhorizontal folds with top to the southeast asymmetry, both associated with a solution cleavage), (iii) one in the Otate, Mal Paso, and Ojo de Agua units (steeply SE-dipping, NE–SW plunging, open-close folds), to (iv) none in the Patlanoaya Group. ⁴⁰Ar/³⁹Ar analyses of muscovite from the earliest cleavage in the Las Minas unit yielded a plateau age of 347 ± 3 Ma and show low temperature ages of  260 Ma. Post-dating all of these structures and the Patlanoaya Group are NE-plunging, subvertical folds and kink bands. An E–W, vertical normal fault juxtaposes the low-grade rocks against the Anacahuite amphibolite that is cut by megacrystic granite sheets, both of which were deformed by two penetrative fabrics. Amphibole from this unit has yielded a ⁴⁰Ar/³⁹Ar plateau age of 299 ± 6 Ma, which records cooling through  490 °C and is probably related to a Permo-Carboniferous reheating event during exhumation. The extensional deformation is inferred to have started in the latest Devonian ( 360 Ma) during deposition of the basal Patlanoaya Group, lasting through the rapid exhumation of the Piaxtla Suite at  350–340 Ma synchronous with cleavage development in the Las Minas unit, deposition of the Patlanoaya Group with active fault-related exhumation suggested by Mississippian and Early Permian conglomerates ( 340 and 300 Ma, respectively), and continuing at least into the Middle Permian (≡ 260 Ma muscovite ages). The continuity of Mid-Continent Mississippian fauna from the USA to southern Mexico suggests that this extensional deformation occurred on the western margin of Pangea after closure of the Rheic Ocean.     

He–Ar and Nd–Sr isotopic compositions of late Pleistocene felsic plutonic back arc basin rocks from Ulleungdo volcanic island, South Korea: Implications for the genesis of young plutonic rocks in a back arc basin

We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. ⁴⁰Ar/³⁹Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K₂O + Na₂O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (⁸⁷Sr/⁸⁶Sr = 0.70454–0.71264, ¹⁴³Nd/¹⁴⁴Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (⁸⁷Sr/⁸⁶Sr = 0.70466–0.70892, ¹⁴³Nd/¹⁴⁴Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial ⁸⁷Sr/⁸⁶Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (³He/⁴He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.     

Large P–T gap between Ballantrae blueschist/garnet pyroxenite and surrounding ophiolite, southern Scotland, UK: Diapiric exhumation of a Caledonian serpentinite mélange

The Ballantrae ophiolite in southern Scotland includes a NEE–SWW-trending serpentinite mélange that contains blocks of mafic blueschist and high-pressure, granulite facies, metapyroxenite (Sm–Nd metamorphic age: 576 ± 32 and 505 ± 11 Ma). Tectonic blocks of mafic schist are less than 3 × 3 m in size, and have greenschist, blueschist or epidote amphibolite facies assemblages corresponding to the high-pressure intermediate-type metamorphic facies series.Adjacent rocks of the serpentinite mélange are hydrothermally-altered MORB-like ophiolitic basalt (prehnite–pumpellyite facies), dolerite (actinolite–oligoclase sub-facies) and gabbro (amphibolite facies), all with assemblages that are diagnostic of the low-pressure metamorphic facies series.The difference in metamorphic facies series and parageneses of minerals between the high-pressure mafic blocks and the adjacent, low-pressure ophiolitic meta-basic rocks suggests that the former were exhumed from > 25 km depth within a cold subducted slab, and were juxtaposed with the latter, the bottom of a MORB-like ophiolite in the hanging wall of a trench. An ENE–WSW-trending, 501 ± 12 Ma volcanic arc belt extends for 3 km south of the serpentinite mélange. We suggest that ridge subduction associated with a slab window created arc-related gabbro (483 ± 4 Ma) at Byne Hill and within-plate gabbro (487 ± 8 Ma) at Millenderdale. Final continental collision created the duplex structure of the Ballantrae complex that includes the HP blocks and serpentinite mélange. These relations define diapiric exhumation in the Caledonian orogen of SW Scotland.     

Age of the Corsica–Sardinia rotation and Liguro–Provençal Basin spreading: new paleomagnetic and Ar/Ar evidence

The age of spreading of the Liguro–Provençal Basin is still poorly constrained due to the lack of boreholes penetrating the whole sedimentary sequence above the oceanic crust and the lack of a clear magnetic anomaly pattern. In the past, a consensus developed over a fast (20.5–19 Ma) spreading event, relying on old paleomagnetic data from Oligo–Miocene Sardinian volcanics showing a drift-related 30° counterclockwise (CCW) rotation. Here we report new paleomagnetic data from a 10-m-thick lower–middle Miocene marine sedimentary sequence from southwestern Sardinia. Ar/Ar dating of two volcanoclastic levels in the lower part of the sequence yields ages of 18.94±0.13 and 19.20±0.12 Ma (lower–mid Burdigalian). Sedimentary strata below the upper volcanic level document a 23.3±4.6° CCW rotation with respect to Europe, while younger strata rapidly evolve to null rotation values. A recent magnetic overprint can be excluded by several lines of evidence, particularly by the significant difference between the in situ paleomagnetic and geocentric axial dipole (GAD) field directions. In both the rotated and unrotated part of the section, only normal polarity directions were obtained. As the global magnetic polarity time scale (MPTS) documents several geomagnetic reversals in the Burdigalian, a continuous sedimentary record would imply that (unrealistically) the whole documented rotation occurred in few thousands years only. We conclude that the section contains one (or more) hiatus(es), and that the minimum age of the unrotated sediments above the volcanic levels is unconstrained. Typical back-arc basin spreading rates translate to a duration ≥3 Ma for the opening of the Liguro–Provençal Basin. Thus, spreading and rotation of Corsica–Sardinia ended no earlier than 16 Ma (early Langhian). A 16–19 Ma, spreading is corroborated by other evidences, such as the age of the breakup unconformity in Sardinia, the age of igneous rocks dredged west of Corsica, the heat flow in the Liguro–Provençal Basin, and recent paleomagnetic data from Sardinian sediments and volcanics. Since Corsica was still rotating/drifting eastward at 16 Ma, it presumably induced significant shortening to the east, in the Apennine belt. Therefore, the lower Miocene extensional basins in the northern Tyrrhenian Sea and margins can be interpreted as synorogenic “intra-wedge” basins due to the thickening and collapse of the northern Apennine wedge.     

Crustal structure and evolution of the southern Vøring Basin and Vøring Transform Margin, NE Atlantic

The dominantly passive volcanic Vøring and Møre Margins, NE Atlantic, are separated by the 200 km long Vøring Transform Margin (VTM). The southern Vøring Basin and the VTM have been studied by use of four regional Ocean Bottom Seismograph (OBS) profiles, combined by gravity modelling. The models demonstrate a complex pattern of magmatism along the transform margin. The distribution of magmatism seems to be related to the existence and trend of a lower crustal 8+ km/s body, interpreted as eclogitized rocks, present in the southern Vøring Basin. Early Tertiary breakup related magmatic ‘leakage’ across the Continent–Ocean-Transition (COT) appears to be facilitated where this layer is absent. These results support earlier workers who have concluded that the Jan Mayen Fracture Zone originated from a Caledonian zone of weakness. We propose that partly eclogitized rocks were uplifted into the lower crust close to this zone during the Caledonian orogeny and that this body acted as a barrier to magma emplacement during the Late Cretaceous–Early Eocene phase of rifting/breakup. The eclogitized terrain also appears to have caused northeastward channeling of the Late Cretaceous–Early Tertiary intrusions within the Vøring Basin. An up to 10 km thick pre-Cretaceous sedimentary basin in the southern Vøring Basin may be genetically related to the NS-trending Late Paleozoic and Mesozoic rift basins in North-East Greenland.     

U–Pb SHRIMP zircon geochronology and T–t–d history of the Kampa Dome, southern Tibet

Structural, petrographic and geochronologic studies of the Kampa Dome provide insights into the tectonothermal evolution of orogenic crust exposed in the North Himalayan gneiss domes of southern Tibet. U–Pb ion microprobe dating of zircons from granite gneiss exposed at the deepest levels within the dome yields concordia ²⁰⁶Pb/²³⁸U age populations of 506 ± 3 Ma and 527 ± 6 Ma, with no evidence of new zircon growth during Himalayan orogenesis. However, the granite contains penetrative deformation fabrics that are also preserved in the overlying Paleozoic strata, implying that the Kampa granite is a Cambrian pluton that was strongly deformed and metamorphosed during Himalayan orogenesis. Zircons from deformed leucogranite sills that cross-cut Paleozoic metasedimentary rocks yield concordant Cambrian ages from oscillatory zoned cores and discordant ages ranging from ca. 491–32 Ma in metamict grains. Since these leucogranites clearly post-date the metasedimentary rocks they intrude, the zircons are interpreted as xenocrysts that are probably derived from the Kampa granite. The Kampa Dome formed via a series of progressive orogenic events including regional ~ N–S contraction and related crustal thickening (D₁), predominately top-to-N ductile shearing and crustal extension (D₂), top-to-N brittle–ductile faulting and related folding on the north limb of the dome, localized top-to-S faulting on the southern limb of the dome, and crustal doming (D₃), and continued N–S contraction, E–W extension and doming (D₄). Structural and geochronologic variability amongst adjacent North Himalayan gneiss domes may reflect changes in the magnitude of crustal exhumation along the North Himalayan antiform, possibly relating to differences in the mid-crustal geometry of the exhuming fault systems.     

Porphyry Cu–Au and associated polymetallic Fe–Cu–Au deposits in the Beiya Area, western Yunnan Province, south China

The Alkaline porphyries in the Beiya area are located east of the Jinshajiang suture, as part of a Cenozoic alkali-rich porphyry belt in western Yunnan. The main rock types include quartz-albite porphyry, quartz-K-feldspar porphyry and biotite–K-feldspar porphyry. These porphyries are characterised by high alkalinity [(K₂O + Na₂O)% > 10%], high silica (SiO₂% > 65%), high Sr (> 400 ppm) and ⁸⁷Sr/⁸⁶Sr (> 0.706)] ratio and were intruded at 65.5 Ma, between 25.5 to 32.5 Ma, and about 3.8 Ma, respectively. There are five main types of mineral deposits in the Beiya area: (1) porphyry Cu–Au deposits, (2) magmatic Fe–Au deposits, (3) sedimentary polymetallic deposits, (4) polymetallic skarn deposits, and (5) palaeoplacers associated with karsts. The porphyry Cu–Au and polymetallic skarn deposits are associated with quartz–albite porphyry bodies. The Fe–Au and polymetallic sedimentary deposits are part of an ore-forming system that produced considerable Au in the Beiya area, and are characterised by low concentrations of La, Ti, and Co, and high concentrations of Y, Yb, and Sc.The Cenozoic porphyries in western Yunnan display increased alkalinity away from the Triassic Jinshajiang suture. Distribution of both the porphyries and sedimentary deposits in the Beiya area are interpreted to be related to partial melting in a disjointed region between upper mantle lithosphere of the Yangtze Plate and Gondwana continent, and lie within a shear zone between buried Palaeo-Tethyan oceanic lithosphere and upper mantle lithosphere, caused by the subduction and collision of India and Asia.     

Detrital record of late-stage silicic volcanism in the Emeishan large igneous province

Silicic volcanic rocks generally constitute a minor, but key product to track the magmatic evolution in mafic rock dominated large igneous provinces (LIPs). However, for their generally late-stage nature of the silicic volcanic rocks they have a poor preservation potential due to extensive post-eruption erosion. We track the eroded volcanic rocks from the ∼260 Ma Emeishan LIP by analyzing the provenance of the LIP-derived sedimentary rocks. Sandstones from a cored succession of the Late Permian Longtan Formation in the northern Youjiang Basin are rich in volcanic rock fragments, and associated mudstones have low Al₂O₃/TiO₂ ratios. Detrital zircon grains from the Longtan Formation display typical unimodal U–Pb age spectra with a prominent peak at ca. 260 Ma. These detrital zircons show an overall geochemical affinity akin to those crystallized from within-plate/anorogenic magmas. Such petrological and geochemical characteristics are consistent with a dominant source from the Emeishan volcanic rocks. Through the sampled succession, zircon grains of ∼260 Ma from the lower Longtan Formation generally display lower U/Yb (most < 0.5) and Th/Nb (most < 10) ratios and higher εHf(t) values (mostly in the range of +3 to +8) than those from the upper part. A similar sequential variation has also been observed in the Shaiwa Formation, which is an offshore time-equivalent unit to the Longtan Formation. These consistent temporal variations through the sedimentary successions in the Youjiang Basin are interpreted to reflect erosional unroofing of the Emeishan LIP during the Late Permian. These results, integrated with previous studies on the rhyolites and trachytes in Emeishan LIP, reveal a fractional crystallization dominated petrogenetic process with diminishing crustal assimilation for the late-stage silicic volcanism.     

新疆阿尔泰凯勒克赛依铁矿地质特征、锆石LA MC ICP MS U Pb年龄及其意义

凯勒克赛依铁矿床是新疆阿尔泰唯一的小型镜铁矿床,赋存于一套变质火山-沉积岩系中,近矿围岩为白云母石英片岩,矿体呈层状,与地层产状一致,矿石具有块状、条带状、条纹状构造,矿石中金属矿物主要为镜铁矿(TFeO=87349%~88988%,TiO2=0~1042%,Al2O3=0036%~0256%),矿化具有沉积特征。近矿围岩镜铁矿白云母石英片岩锆石LA MC ICP MS U Pb谐和年龄为(3756 ± 06)Ma,限定成矿时代在376 Ma左右,即中泥盆世成矿,是阿尔泰为数不多的中泥盆世成矿作用的产物。同时也厘定含矿的变质火山-沉积岩系属中—晚泥盆世阿勒泰镇组,不是前人认为的早泥盆世康布铁堡组。