Effects of ground water exchange on the hydrology and ecology of surface water

Ground water exchange affects the ecology of surface water by sustaining stream base flow and moderating water-level fluctuations of ground water-fed lakes. It also provides stable-temperature habitats and supplies nutrients and inorganic ions. Ground water input of nutrients can even determine the trophic status of lakes and the distribution of macrophytes. In streams the mixing of ground water and surface water in shallow channel and bankside sediments creates a unique environment called the hyporheic zone, an important component of the lotic ecosystem. Localized areas of high ground water discharge in streams provide thermal refugia for fish. Ground water also provides moisture to riparian vegetation, which in turn supplies organic matter to streams and enhances bank resistance to erosion. As hydrologists and ecologists interact to understand the impact of ground water on aquatic ecology, a new research field called "ecohydrology" is emerging.     

Surface water input from snowmelt and rain throughfall in western juniper: potential impacts of climate change and shifts in semi‐arid vegetation

In the western USA, shifts from snow to rain precipitation regimes and increases in western juniper cover in shrub‐dominated landscapes can alter surface water input via changes in snowmelt and throughfall. To better understand how shifts in both precipitation and semi‐arid vegetation cover alter above‐ground hydrological processes, we assessed how rain interception differs between snow and rain surface water input; how western juniper alters snowpack dynamics; and how these above‐ground processes differ across western juniper, mountain big sagebrush and low sagebrush plant communities. We collected continuous surface water input with four large lysimeters, interspace and below‐canopy snow depth data and conducted periodic snow surveys for two consecutive water years (2013 and 2014). The ratio of interspace to below‐canopy surface water input was greater for snow relative to rain events, averaging 79.4% and 54.8%, respectively. The greater surface water input ratio for snow is in part due to increased deposition of redistributed snow under the canopy. We simulated above‐ground energy and water fluxes in western juniper, low sagebrush and mountain big sagebrush for two 8‐year periods under current and projected mid‐21st century warmer temperatures with the Simultaneous Heat and Water (SHAW) model. Juniper compared with low and mountain sagebrush reduced surface water input by an average of 138 mm or 24% of the total site water budget. Conversely, warming temperatures reduced surface water input by only an average of 14 mm across the three vegetation types. The future (warmer) simulations resulted in earlier snow disappearance and surface water input by 51 and 45 days, respectively, across juniper, low sagebrush and mountain sagebrush. Information from this study can help land managers in the sagebrush steppe understand how both shifts in climate and semi‐arid vegetation will alter fundamental hydrological processes. Copyright © 2016 John Wiley & Sons, Ltd.     

Oxygen and hydrogen in the primitive atmosphere

From time to time there appears in the literature the assertion that photolysis of water vapor could have maintained an appreciable concentration of oxygen in the primitive (prebiological) atmosphere. The implausibility of this assertion is argued in this paper.By itself, photolysis does not provide a source of oxygen because it is usually followed by recombination of the products of photolysis. Only the escape to space (at a much smaller rate) of the hydrogen produced by photolysis of water results in a net source of oxygen. The oxidation state of the primitive atmosphere depended on the relative magnitudes of this net source of oxygen and a volcanic source of hydrogen and other reduced gases. Today the volcanic source of reduced gases is approximately equal to the oxygen source provided by photolysis followed by escape. The oxygen source depends on the mixing ratio of water vapor in the stratosphere, which ultimately determines the rate of escape of hydrogen produced from water vapor. Its magnitude may not have been very different in the past. The volcanic source of hydrogen, on the other hand, is likely to have been much larger when the earth was tectonically young. Hydrogen was therefore released to the primitive atmosphere more rapidly than oxygen, probably. Photochemical reactions with the excess hydrogen maintained oxygen mixing ratios at negligibly small levels. The hydrogen mixing ratio was determined by a balance between the volcanic source (reduced by recombination with oxygen) and escape to space.In time, either because of decline of the volcanic source of hydrogen or because of addition of a biological source of oxygen, the input of oxygen to the atmosphere rose above the input of hydrogen. The oxidation state of the atmosphere changed rapidly. Volcanic hydrogen was now consumed by photochemical reactions with excess oxygen, while the oxygen mixing ratio was determined by a balance between the source (reduced by recombination with volcanic hydrogen) and consumption in reactions with reduced material at the surface.     

Seasonal formation and movement of the thermocline in lakes

Summary The work described deals with the formation and movement of the thermocline on a lake during the summer season. The formation requires an input of mechanical energy from the wind stress as well as an input of heat from solar radiation or from the air. The depth of the thermocline is shown to be nearly proportional to the ratio of the energy input to the heat input and the thermocline sinks or ascends as one input is greater or less than the other. Formulae are found for the variation of the energyE with the cumulative effect of the wind speed, the temperature difference between the water and air if positive, and the depth of the thermocline. A similar formula is obtained forQ the heat input against the total number of hours of sunshine and the positive water-air temperature difference. From these two formulae it is possible to derive a formula for the thermocline depth entirely in terms of meteorological data and surface temperatures of the water for the season.     

Innovative Sampling Techniques for Ground Water Monitoring at Hazardous Waste Sites

The authors have recently used several innovative sampling techniques for ground water monitoring at hazardous waste sites. Two of these techniques were used for the first time on the Biscayne Aquifer Super-fund Project in Miami, Florida. This is the largest sampling program conducted so far under the U.S. Environmental Protection Agency (EPA) Superfund Program.
One sampling technique involved the use of the new ISCO Model 2600 submersible portable well sampling pump. A compressed air source forces water from the well into the pump casing and then delivers it to the surface (through a pulsating action). This pump was used in wells that could not be sampled with surface lift devices.
Another sampling technique involved the use of a Teflon manifold sampling device. The manifold is inserted into the top of the sampling bottle and a peristaltic pump creates a vacuum to draw the water sample from the well into the bottle. The major advantage of using this sampling technique for ground water monitoring at hazardous waste sites is the direct delivery of the water sample into the collection container. In this manner, the potential for contamination is reduced because, prior to delivery to the sample container, the sample contacts only the Teflon, which is well-known for its inert properties.
Quality assurance results from the Superfund project indicate that these sampling techniques are successful in reducing cross-contamination between monitoring wells. Analysis of field blanks using organic-free water in contact with these sampling devices did not show any concentration at or above the method detection limit for each priority pollutant.     

Contrasting effects of cross-ecosystem subsidies and predation on benthic invertebrates in two Pacific coastal streams

Cross-ecosystem subsidies, such as terrestrial invertebrates and leaf litter falling into water as resources for aquatic communities, can vary across environmental gradients. We examined whether the effect of terrestrial subsidy inputs on benthic invertebrates was mediated by resident coastal cutthroat trout (Oncorhynchus clarki) in two representative streams. We experimentally manipulated the input rates (reduced, ambient) of terrestrial subsidies (terrestrial invertebrates and leaf litter) as well as the presence or absence of cutthroat trout in the two streams. The hypothesis that the reduction of terrestrial subsidies to the stream influences benthic invertebrate assemblages was supported by experimental results. The treatments of terrestrial subsidy reduction and cutthroat trout presence had a significant negative effect on benthic invertebrate community biomass and shredder biomass in East Creek with high natural terrestrial subsidy input and small amount of large wood in channel. In contrast, results from Spring Creek with low subsidy input and large amount of large wood in channel showed that only the terrestrial subsidy reduction significantly reduced the biomass of shredders. The effects of the terrestrial subsidy input and trout predation on benthic invertebrate communities varied between the two streams. Our results indicate that a subsidy effect on benthic communities can vary between nearby streams differing in canopy and habitats. This study, with the major finding of highly context-dependent effects of spatial subsidies, suggests that the interplay of resource subsidies and predators on invertebrate community assemblages can be site-specific and context-dependent on habitat features.     

The free jet as a means to improve water quality: Destratification and oxygen enrichment

Rivers, lakes, and coastal waters are chaotic systems — physical, chemical, and biological parameters influence their development. Each parameter itself is influenced by the system. Human interaction has led to fast eutrophication. Oxygen input and artificial mixing have been considered as tools to overcome the biggest problems of fish kills, algal blooms, and bad odour. The favoured technology for destratification and oxygen input so far is the bubble curtain. This technology has been applied successfully in several cases. But often, this technology could not be implemented because of high investment and operating costs.

Alternatively, the free jet is discussed as an efficient and low investment and operating cost technology. The free jet may transport oxygen-rich water from the surface down into the hypolimnion, thereby destratifying a water system. A free jet entrains on its way down even more oxygen rich and warm epilimnic water. This water will finally — if some mixing with the cold hypolimnic water occurs — be transferred to the metalimnion. The density differences will make this water travel long distances.

The energy input may be very low and the objective must not be to totally overturn a system. A jet started in early spring may help a lake to have a deep enough epilimnion, relatively large in volume in respect to the hypolimnion, and the normal wind will recirculate the water transferring enough oxygen to the deeper part, thus expanding the fish habitat and enabling benthic fauna. Literature also shows that the occurrence of massive algal blooms may be reduced.

The oxygen efficiency can be multifold compared to standard technologies.     

Continuous flushing of contaminants from ballast water tanks

The transport of non-indigenous species (NIS) with ship ballast water is a major environmental problem. The International Maritime Organisation (IMO) have recommended that ballast tanks are flushed through with sea water to remove NIS contaminants. The flushing efficiency is studied using mathematical models and a scaled experimental model of a ballast tank. The density contrast between the ballast water and water used for flushing is important when the Froude number Fr(w)=U(w)/sqr rt|g(')|H < 1 (defined in terms of average horizontal flow U(w), reduced buoyancy g', and H the vertical dimension in the tank). When denser water is used to flush a ballast tank, from below, it efficiently displaces lighter ballast water; but flushing through with light water creates a buoyant gravity current which effectively short circuits part of the tank. When Fr(w)>1, the density contrast between the ballast water and water used for flushing is not important and flushing is controlled by a bulk Péclet number, Pe(w). For Pe(w)<1 perfect mixing occurs, while for Pe(w)>1 displacement flushing occurs. Laboratory experiments of flushing were performed using a model two-dimensional ballast tank employing dye attenuation to measure the whole concentration field and these experiments confirm the essential features of the mathematical models. The results of this study are discussed in the context of current IMO flushing protocols.     

Do mixing models with different input requirement yield similar streamflow source contributions? Case study: A tropical montane catchment

Hydrogeochemical based mixing models have been successfully used to investigate the composition and source identification of streamflow. The applicability of these models is limited due to the high costs associated with data collection and the hydrogeochemical analysis of water samples. Fortunately, a variety of mixing models exist, requiting different amount of data as input, and in data scarce regions it is likely that preference will be given to models with the lowest requirement of input data. An unanswered question is if models with high or low input requirement are equally accurate. To this end, the performance of two mixing models with different input requirement, the mixing model analysis (MMA) and the end-member mixing analysis (EMMA), were verified on a tropical montane headwater catchment (21.7 km²) in the Ecuadorian Andes. Nineteen hydrogeochemical tracers were measured on water samples collected weekly during 3 years in streamflow and eight potential water sources or end-members (precipitation, lake water, soil water from different horizons and springs). Results based on 6 conservative tracers, revealed that EMMA (using all tracers) and MMA (using pair-combinations out of the 6 conservative ones), identified the same end-members: rainfall, soil water and spring water., as well as, similar contribution fractions to streamflow from rainfall 21.9% and 21.4%, soil water 52.7% and 52.3%, and spring water 26.1% and 28.7%, respectively. Our findings show that a hydrogeochemical mixing model requiring a few tracers can provide similar outcomes than models demanding more tracers as input data. This underlines the value of a preliminary detailed hydrogeochemical characterization as basis to derive the most cost-efficient monitoring strategy.     

Developing environmental indices using fuzzy numbers ordered weighted averaging (FN-OWA) operators

Environmental indices (EI) constitute a common communication tool that is often used to describe the overall status of environmental systems (air, water and soil). EI development entails the use of mathematical operators to aggregate various non-commensurate input parameters in a logical manner. The ordered weighted averaging (OWA) operator is a general mean type operator that provides flexibility in the aggregation process such that the aggregated value is bounded between minimum and maximum values of the input parameters. This flexibility of the OWA operator is realized through the concept of orness, which is a surrogate for decision maker’s attitude. The type of input parameters also affects the choice of aggregation operators. If the input parameters are linguistic or fuzzy, the aggregation through OWA operators is not possible, and the use of fuzzy arithmetic is warranted. The concept of fuzzy number OWA (FN-OWA) operators is explored to handle situations in which one or more input parameter has fuzzy (or linguistic) values. The proposed approach is demonstrated using data provided in an earlier study by Swamee and Tyagi (ASCE J Environ Eng 126(5):451–455, 2000) for establishing water quality indices. Multiple hypothetical scenarios are also generated to highlight the utility and sensitivity of the proposed approach.     

Do a bit more with convolution

Convolution is a form of superposition that efficiently deals with input varying arbitrarily in time or space. It works whenever superposition is applicable, that is, for linear systems. Even though convolution is well-known since the 19th century, this valuable method is still missing in most textbooks on ground water hydrology. This limits widespread application in this field. Perhaps most papers are too complex mathematically as they tend to focus on the derivation of analytical expressions rather than solving practical problems. However, convolution is straightforward with standard mathematical software or even a spreadsheet, as is demonstrated in the paper. The necessary system responses are not limited to analytic solutions; they may also be obtained by running an already existing ground water model for a single stress period until equilibrium is reached. With these responses, high-resolution time series of head or discharge may then be computed by convolution for arbitrary points and arbitrarily varying input, without further use of the model. There are probably thousands of applications in the field of ground water hydrology that may benefit from convolution. Therefore, its inclusion in ground water textbooks and courses is strongly needed.     

Analysis of Water Saturation, NAPL Content, Degradation Half-Life, and Lower Boundary Conditions on VOC Transport Modeling: Implications for Closure of Soil Venting Systems

Simulations using a one-dimensional, analytical, vadose zone, solute-transport screening code (VFLUX) were conducted to assess the effect of water saturation, NAPL saturation, degradation half-life, and boundary conditions at the vadose zone/ground water interface on model output. At high initial soil concentrations, model output was significantly affected by input parameters and lower boundary conditions yet still resulted in consistent decision-making to initiate or continue venting application. At lower soil concentrations, however, typical of what is observed after prolonged venting application, differences in model input and selection of lower boundary conditions resulted in inconsistent decision-making. Specifically, under conditions of low water saturation, use of a first-type, time-dependent lower boundary condition indicated that the primary direction of mass flux was from ground water to the vadose zone, suggesting little benefit from continued venting application. Use of a finite, zero-gradient lower boundary condition, though, indicated continued mass flux from the vadose zone to ground water, suggesting a continued need for venting application. In this situation, sensitivity analysis of input parameters, selection of boundary conditions, and consideration of overall objectives in vadose zone modeling become critical in regulatory decision-making.     

Water balance of tropical rainforest canopies in north Queensland,Australia

The water balance of four different rainforest types in the Wet Tropics region of north Queensland is inferred from measurements of canopy hydrological components undertaken for periods between 391 to 657 days. These measurements of rainfall, cloud interception, stem-flow, throughfall, canopy interception and transpiration have revealed considerable differences in the canopy water balance of different locations as a result of forest structural differences, altitude, exposure and climate. Cloud interception is a significant extra input of water to forests at high altitude sites (>1000 m) and varies between 7 and 29% of the total water input. At coastal and lower montane rainforests annual total evaporation is consistently around 50% of the total water input, but in upper montane cloud forest this drops dramatically to only 13% of the water input. At all sites actual evaporation is greater than potential evaporation for most of the year and on an annual basis exceeds potential by between 2 and 53%. The source of this additional energy is uncertain, but is likely to come from advection. Annual interception at all the rainforest sites was greater than annual transpiration, with transpiration dominating in the dry season and interception dominating in the wet season. All of the rainforests have a large annual net water balance to sustain runoff and recharge. Towards the end of the dry season runoff and recharge can cease in coastal lowland and lower mountain forests and they may have to draw on soil moisture and/or ground water at this time. In contrast, upper montane cloud forests have a positive net water balance throughout the year and are therefore an important source of dry season river flows. Furthermore, their exceptionally large annual runoff (∼6500 mm year⁻¹) is a major source of downstream water. Copyright © 2007 John Wiley & Sons, Ltd.     

Simulatoren meteorologischer Eingangsgrößen für mathematische Modelle der Wassergütewirtschaft

Operational stochastic models with different time discretisation levels have been developed for generation of meteorological input processes for hydrologic models. These stochastic models can also supply the input simulation for water quality management models. In this paper they are outlined with special regard to the threshold model for intermittend processes of short time intervals (less than about ten days) with is based on a “pressed” power transformation to normality and a method of quantiles or alternatively a modified method of moments for estimating the correlation coefficients.     

Alteration of an Apollo 12 sample by adsorption of water vapor

The adsorption of water vapor caused radical changes in the surface characteristics of an Apollo 12 lunar fines sample. In the initial state, the sample had a relatively low specific surface area and no inherent porosity as deduced from the adsorption isotherms of nitrogen and argon. However, the sample interacted strongly with water vapor, particularly at high relative pressures, and irreversibly retained, in vacuum, a quantity of water much larger than can be explained by a simple chemisorption process. The interaction with water vapor more than doubled the specific surface area and created a pore system. The suggested explanation is that water penetrates the severely radiation damaged, amorphous surface layers of the particles and creates pores by leaching out channels or forcing apart adherent particles. Lunar fines from the Apollo 11, 12 and 14 missions have markedly different reactivities toward water vapor, an observation which remains unexplained at the present time.     

Topographic analysis for the prairie pothole region of Western Canada

The unique topography of the pothole region of the North American prairies creates challenges for properly determining basin contributing area. Numerous depressions or potholes within the landscape impound runoff. However, potholes can ‘fill‐spill’ resulting in surface water connections between the potholes. Surface water connectivity between potholes ultimately influences basin contributing area. Currently, automated methods, such as landscape analysis tools, treat depressions in the landscape as artifacts and simply fill the depressions to delineate a drainage basin. Using this method to calculate contributing area assumes that all surface storage has been satisfied (threshold) and the drainage basin will contribute 100% of its area for all runoff events. However, most runoff events in the prairie pothole region are pre‐threshold events that contribute only a portion of surface runoff to the outlet. These pre‐threshold events have surface storage that varies because of antecedent water levels and have a variable or dynamic potential to store further runoff in the basin. Government agencies have developed methodologies for determining pre‐threshold contributing areas, but these methodologies do not incorporate current technologies and, as a result, have limitations. We propose an automated method for determining contributing area that incorporates the fill‐spill of prairie potholes. The algorithm, which uses the D‐8 drainage direction method, automates a methodology for identifying and quantifying runoff contributing area. Any algorithm that determines pre‐threshold contributing area, must allow the DEM to be filled in an incremental manner. This will simulate increasing pond levels, and the resulting decrease in available storage in the basin, in response to runoff events. The SPILL algorithm is an iterative solution that increases the magnitude of input runoff events and records the decreasing change in available surface storage and the increase in contributing area until the storage threshold is reached and the contributing area reaches 100%. Through application of the algorithm on prairie pothole region basins, we test proposed conceptual curves that describe a hypothesized non‐linear relationship between decreasing potential storage in the landscape and contributing area. Results indicate that the proposed conceptual curves represent the relationship between potential surface storage and contributing area in the test basins very well. Copyright © 2012 John Wiley & Sons, Ltd.     

Inverse Modeling Approach to Allogenic Karst System Characterization

Allogenic karst systems function in a particular way that is influenced by the type of water infiltrating through river water losses, by karstification processes, and by water quality. Management of this system requires a good knowledge of its structure and functioning, for which a new methodology based on an inverse modeling approach appears to be well suited. This approach requires both spring and river inflow discharge measurements and a continuous record of chemical parameters in the river and at the spring. The inverse model calculates unit hydrographs and the impulse responses of fluxes from rainfall hydraulic head at the spring or rainfall flux data, the purpose of which is hydrograph separation. Hydrograph reconstruction is done using rainfall and river inflow data as model input and enables definition at each time step of the ratio of each component. Using chemical data, representing event and pre-event water, as input, it is possible to determine the origin of spring water (either fast flow through the epikarstic zone or slow flow through the saturated zone). This study made it possible to improve a conceptual model of allogenic karst system functioning. The methodology is used to study the Bas-Agly and the Cent Font karst systems, two allogenic karst systems in Southern France.     

Input variable selection for water resources systems using a modified minimum redundancy maximum relevance (mMRMR) algorithm

Input variable selection (IVS) is a necessary step in modeling water resources systems. Neglecting this step may lead to unnecessary model complexity and reduced model accuracy. In this paper, we apply the minimum redundancy maximum relevance (MRMR) algorithm to identifying the most relevant set of inputs in modeling a water resources system. We further introduce two modified versions of the MRMR algorithm (α-MRMR and β-MRMR), where α and β are correction factors that are found to increase and decrease as a power-law function, respectively, with the progress of the input selection algorithms and the increase of the number of selected input variables. We apply the proposed algorithms to 22 reservoirs in California to predict daily releases based on a set from a 121 potential input variables. Results indicate that the two proposed algorithms are good measures of model inputs as reflected in enhanced model performance. The α-MRMR and β-MRMR values exhibit strong negative correlation to model performance as depicted in lower root-mean-square-error (RMSE) values.     

望虞河引长江水入太湖水体的总磷、总氮分析

太湖流域实施的调水引流,提高了流域水资源和水环境承载能力,发挥了水利工程在改善水环境方面的综合效益,支撑了流域经济社会的可持续发展.本文在分析近年来望虞河引江水量与入湖水量及入湖水体流经太湖湖湾水体水质变化情势的基础上,分析比较了2007年以来的调水引流期间,望虞河入太湖水体总磷、总氮浓度值与太湖贡湖湾、梅梁湾、湖西及江苏省其它主要入太湖河道的总磷、总氮浓度值,并通过监测结果分析了入太湖水体总磷、可溶性总磷的衰减趋势,从而得出,长江是优质水源,调引长江水为增加太湖水环境容量、改善太湖及区域水环境状况起到了积极作用.