La Pacana caldera and the Atana Ignimbrite — a major ash-flow and resurgent caldera complex in the Andes of northern Chile

The recently discovered La Pacana caldera, 60 × 35 km, is the largest caldera yet described in South America. This resurgent caldera of Pliocene age developed in a continental platemargin environment in a major province of ignimbrite volcanism in the Central Andes of northern Chile at about 23° S latitude. Collapse of La Pacana caldera was initiated by the eruption of about 900 km³ of the rhyodacitic Atana Ignimbrite. The Atana Ignimbrite was erupted from a composite ring fracture system and formed at least four major ash-flow tuff units that are separated locally by thin air-fall and surge deposits; all four sheets were emplaced in rapid succession about 4.1 ± 0.4 Ma ago. Caldera collapse was followed closely by resurgent doming of the caldera floor, accompanied by early postcaldera eruptions of dacitic to rhyolitic lava domes along the ring fractures. The resurgent dome is an elongated, asymmetrical uplift, 48.5 × 12 km, which is broken by a complex system of normal faults locally forming a narrow discontinuous apical graben. Later, postcaldera eruptions produced large andesitic and dacitic stratocones along the caldera margins and dacitic domes on the resurgent dome beginning about 3.5 Ma ago and persisting into the Quaternary. Hydrothermally altered rocks occur in the eroded cores of precaldera and postcaldera stratovolcanoes and along fractures in the resurgent dome, but no ore deposits are known. A few warm springs located in salars within the caldera moat appear to be vestiges of the caldera geothermal system.     

Kaguyak dome field and its Holocene caldera,Alaska Peninsula

Kaguyak Caldera lies in a remote corner of Katmai National Park, 375 km SW of Anchorage, Alaska. The 2.5-by-3-km caldera collapsed ~ 5.8 ± 0.2 ka (¹⁴C age) during emplacement of a radial apron of poorly pumiceous crystal-rich dacitic pyroclastic flows (61–67% SiO₂). Proximal pumice-fall deposits are thin and sparsely preserved, but an oxidized coignimbrite ash is found as far as the Valley of Ten Thousand Smokes, 80 km southwest. Postcaldera events include filling the 150-m-deep caldera lake, emplacement of two intracaldera domes (61.5–64.5% SiO₂), and phreatic ejection of lakefloor sediments onto the caldera rim. CO₂ and H₂S bubble up through the lake, weakly but widely. Geochemical analyses (n = 148), including pre-and post-caldera lavas (53–74% SiO₂), define one of the lowest-K arc suites in Alaska. The precaldera edifice was not a stratocone but was, instead, nine contiguous but discrete clusters of lava domes, themselves stacks of rhyolite to basalt exogenous lobes and flows. Four extracaldera clusters are mid-to-late Pleistocene, but the other five are younger than 60 ka, were truncated by the collapse, and now make up the steep inner walls. The climactic ignimbrite was preceded by ~ 200 years by radial emplacement of a 100-m-thick sheet of block-rich glassy lava breccia (62–65.5% SiO₂). Filling the notches between the truncated dome clusters, the breccia now makes up three segments of the steep caldera wall, which beheads gullies incised into the breccia deposit prior to caldera formation. They were probably shed by a large lava dome extruding where the lake is today.     

Isotope geochemistry (Sr–Nd–Pb) and petrogenesis of leucite-bearing volcanic rocks from “Colli Albani” volcano, Roman Magmatic Province, Central Italy: inferences on volcano evolution and magma genesis

The “Colli Albani” composite volcano is made up of strongly silica-undersaturated leucite-bearing rocks. Magmas were erupted during three main periods, but a complex plumbing system dominated by regional tectonics channelled magmas into different reservoirs. The most alkali-rich magmas, restricted to the caldera-forming period (pre-caldera), are extremely enriched in incompatible trace elements and display more radiogenic Sr (⁸⁷Sr/⁸⁶Sr?=?0.71057–0.71067), with slightly less radiogenic Pb with respect to those of the post-caldera period. Post-caldera volcanic activity was concentrated in three different volcanic environments: external to the caldera, along the caldera edge and within the caldera. The post-caldera magmas produced melilite- to leucitite-bearing, plagioclase-free leucitites. In contrast to the pre-caldera lavas, they are characterised by lower incompatible trace element abundances and less radiogenic Sr (⁸⁷Sr/⁸⁶Sr?=?0.71006–0.71039). Magmas evolved through crystal fractionation plus minor crustal assimilation in a large magma chamber during the pre-caldera period. The multiple caldera collapses dissected and partially obliterated the early magma chamber. During the post-caldera stage, magmas were channelled through several pathways and multiple shallow-level magma reservoirs were established. A lithospheric mantle wedge previously depleted in the basaltic component and subsequently enriched by metasomatic slab-derived component is suggested as the mantle source of Colli Albani parental magmas. Two different parental magmas are recognised for the pre- and post-caldera stages. The differences may be related to the interplay between smaller degrees of melting for the pre-caldera magmas and more carbonate-rich recycled subducted lithologies in the post-caldera magmas.     

Zeolitization of intracaldera sediments and rhyolitic rocks in the 1.25 Ma lake of Valles caldera,New Mexico,USA

Quantitative X-ray diffraction analysis of about 80 rhyolite and associated lacustrine rocks has characterized previously unrecognized zeolitic alteration throughout the Valles caldera resurgent dome. The alteration assemblage consists primarily of smectite–clinoptilolite–mordenite–silica, which replaces groundmass and fills voids, especially in the tuffs and lacustrine rocks. Original rock textures are routinely preserved. Mineralization typically extends to depths of only a few tens of meters and resembles shallow “caldera-type zeolitization” as defined by Utada et al. [Utada, M., Shimizu, M., Ito, T., Inoue, A., 1999. Alteration of caldera-forming rocks related to the Sanzugawa volcanotectonic depression, northeast Honshu, Japan — with special reference to “caldera-type zeolitization.” Resource Geol. Spec. Issue No. 20, 129–140]. Geology and ⁴⁰Ar/³⁹Ar dates limit the period of extensive zeolite growth to roughly the first 30 kyr after the current caldera formed (ca. 1.25 to 1.22 Ma). Zeolitic alteration was promoted by saturation of shallow rocks with alkaline lake water (a mixture of meteoric waters and degassed hydrothermal fluids) and by high thermal gradients caused by cooling of the underlying magma body and earliest post-caldera rhyolite eruptions. Zeolitic alteration of this type is not found in the later volcanic and lacustrine rocks of the caldera moat (≤ 0.8 Ma) suggesting that later lake waters were cooler and less alkaline. The shallow zeolitic alteration does not have characteristics resembling classic, alkaline lake zeolite deposits (no analcime, erionite, or chabazite) nor does it contain zeolites common in high-temperature hydrothermal systems (laumontite or wairakite). Although aerially extensive, the early zeolitic alteration does not form laterally continuous beds and are consequently, not of economic significance.     

Ignimbrites of the Cerro Galan caldera, NW Argentina

The 35 × 20 km Cerro Galán resurgent caldera is the largest post-Miocene caldera so far identified in the Andes. The Cerro Galán complex developed on a late pre-Cambrian to late Palaeozoic basement of gneisses, amphibolites, mica schists and deformed phyllites and quartzites. The basement was uplifted in the early Miocene along large north-south reverse faults, producing a horst-and-graben topography. Volcanism began in the area prior to 15 Ma with the formation of several andesite to dacite composite volcanoes. The Cerro Galán complex developed along two prominent north-south regional faults about 20 km apart. Dacitic to rhyodacitic magma ascended along these faults and caused at least nine ignimbrite eruptions in the period 7-4 Ma (K-Ar determinations). These ignimbrites are named the Toconquis Ignimbrite Formation. They are characterised by the presence of basal plinian deposits, many individual flow units and proximal co-ignimbrite lag breccias. The ignimbrites also have moderate to high macroscopic pumice and lithic contents and moderate to low crystal contents. Compositionally banded pumice occurs near the top of some units. Many of the Toconquis eruptions occurred from vents along a north-south line on the western rim of the young caldera. However, two of the ignimbrites erupted from vents on the eastern margin. Lava extrusions occurred contemporaneously along these north-south lines. The total D.R.E. volume of Toconquis ignimbrite exceeds 500 km³.Following a 2-Ma dormant period a single major eruption of rhyodacitic magma formed the 1000-km³ Cerro Galán ignimbrite and the caldera. The ignimbrite (age 2.1 Ma on Rb-Sr determination) forms a 30–200-m-thick outflow sheet extending up to 100 km in all directions from the caldera rim. At least 1.4 km of welded intracaldera ignimbrite also accumulated. The ignimbrite is a pumice-poor, crystal-rich deposit which contains few lithic clasts. No basal plinian deposit has been identified and proximal lag breccias are absent. The composition of pumice clasts is a very uniform rhyodacite which has a higher SiO₂ content but a lower K₂O content than the Toconquis ignimbrites. Preliminary data indicate no evidence for compositional zonation in the magma chamber. The eruption is considered to have been caused by the catastrophic foundering of a cauldron block into the magma chamber.Post-caldera extrusions occurred shortly after eruption along both the northern extension of the eastern boundary fault and the western caldera margin. Resurgence also occurred, doming up the intracaldera ignimbrite and sedimentary fill to form the central mountain range. Resurgent doming was centred along the eastern fault and resulted in radial tilting of the ignimbrite and overlying lake sediments.     

Evolution of a Quaternary peralkaline volcano: Mayor Island, New Zealand

Mayor Island is a Holocene pantelleritic volcano showing a wide range of dispersive power and eruptive intensity despite a very limited range in magma composition of only 2% SiO₂. The primary controls on this range appear to have been the magmatic gas content on eruption and a varying involvement of basaltic magma, rather than major-element chemistry of the rhyolites. The ca. 130 ka subaerial history of the volcano contains portions of three geochemical cycles with abrupt changes in trace-element chemistry following episodes of caldera collapse. The uniform major-element chemistry of the magma may relate to a fine balance between rates of eruption and supply and the higher density of the more evolved (Ferich) magmas which could be tapped only after caldera-forming events had removed significant volumes of less evolved but lighter magma.     

Bimodal volcanism at the Katla subglacial caldera,Iceland: insight into the geochemistry and petrogenesis of rhyolitic magmas

The Katla subglacial caldera is one of the most active and hazardous volcanic centres in Iceland as revealed by its historical volcanic activity and recent seismic unrest and magma accumulation. A petrologic and geochemical study was carried out on a suite of mid-Pleistocene to Recent lavas and pyroclastic rocks originated from the caldera. The whole series is characterised by a bimodal composition, including Fe-Ti transitional alkali basalts and mildly alkalic rhyolites. Variations in trace-element composition amongst the basalts and rhyolites show that their chemical differentiation was mainly controlled by fractional crystallisation and possible assimilation. The petrology and chemistry of the few intermediate extrusive rocks show that they were derived from magma mingling or hybridisation. The absence of extrusive rocks of true intermediate magmatic composition and the occurrence of amphibole-bearing felsic xenoliths support the hypothesis of partial melting of the hydrated basalt crust as the main process leading to the generation of rhyolites. The ¹⁴³Nd/¹⁴⁴Nd and ⁸⁷Sr/⁸⁶Sr values of Katla volcanic rocks fit the general isotopic array defined by late Quaternary to Recent lavas from Iceland. A few rock specimens are distinguished by low ¹⁴³Nd/¹⁴⁴Nd values suggesting assimilation and mixing of much older crustal material. Despite their similar whole-rock chemical compositions, the postglacial rhyolitic extrusives differ from the felsic xenoliths by their glass composition and the absence of amphibole. This, together with the general chemical trend of volcanic glasses, indicates that the postglacial rhyolitic extrusives were probably derived by a process involving late reheating and partial melting of crustal material by intrusion of basaltic magmas.     

Reconstruction of a major caldera-forming eruption from pyroclastic deposit characteristics: Kos Plateau Tuff, eastern Aegean Sea

The 161 ka explosive eruption of the Kos Plateau Tuff (KPT) ejected a minimum of 60 km³ of rhyolitic magma, a minor amount of andesitic magma and incorporated more than 3 km³ of vent- and conduit-derived lithic debris. The source formed a caldera south of Kos, in the Aegean Sea, Greece. Textural and lithofacies characteristics of the KPT units are used to infer eruption dynamics and magma chamber processes, including the timing for the onset of catastrophic caldera collapse.The KPT consists of six units: (A) phreatoplinian fallout at the base; (B, C) stratified pyroclastic-density-current deposits; (D, E) volumetrically dominant, massive, non-welded ignimbrites; and (F) stratified pyroclastic-density-current deposits and ash fallout at the top. The ignimbrite units show increases in mass, grain size, abundance of vent- and conduit-derived lithic clasts, and runout of the pyroclastic density currents from source. Ignimbrite formation also corresponds to a change from phreatomagmatic to dry explosive activity. Textural and lithofacies characteristics of the KPT imply that the mass flux (i.e. eruption intensity) increased to the climax when major caldera collapse was initiated and the most voluminous, widespread, lithic-rich and coarsest ignimbrite was produced, followed by a waning period. During the eruption climax, deep basement lithic clasts were ejected, along with andesitic pumice and variably melted and vesiculated co-magmatic granitoid clasts from the magma chamber. Stratigraphic variations in pumice vesicularity and crystal content, provide evidence for variations in the distribution of crystal components and a subsidiary andesitic magma within the KPT magma chamber. The eruption climax culminated in tapping more coarsely crystal-rich magma. Increases in mass flux during the waxing phase is consistent with theoretical models for moderate-volume explosive eruptions that lead to caldera collapse.     

Mamaku Ignimbrite: a caldera-forming ignimbrite erupted from a compositionally zoned magma chamber in Taupo Volcanic Zone, New Zealand

Mamaku Ignimbrite was deposited during the formation of Rotorua Caldera, Taupo Volcanic Zone, New Zealand, 220–230 ka. Its outflow sheet forms a fan north, northwest and southwest of Rotorua, capping the Mamaku–Kaimai Plateau. Mamaku Ignimbrite can be divided into a partly phreatomagmatic basal sequence, and a main sequence which comprises lower, middle, and upper ignimbrite. The internal stratigraphy indicates that it was emplaced progressively from a pyroclastic density current of varying energy that became less particulate away from source. Gradational contacts between lower, middle, and upper ignimbrite are consistent with it being deposited during one eruptive event from the same source. Variations in lithic clast content and coexistence of different pumice types through the ignimbrite sequence indicate that caldera collapse occurred throughout the eruption, but particularly when middle Mamaku Ignimbrite was deposited and in the final stages of deposition of upper Mamaku Ignimbrite. Maximum lithic data and the location of lithic lag breccias in upper Mamaku Ignimbrite confirm Rotorua Caldera as the source. At least 120 m of geothermally altered intra-caldera Mamaku Ignimbrite occurs inside Rotorua Caldera. Pumice clasts in the Mamaku Ignimbrite are dacite to high-silica rhyolite and can be chemically divided into three types: high–silica rhyolite (type 1), rhyolite (type 2), and dacite (type 3). All are petrogenetically related and types 1 and 2 may be derived by up to 20% crystal fractionation from the type 3 dacite. All three types probably resided in a single, gradationally zoned magma chamber. Andesitic juvenile fragments are found only in upper Mamaku Ignimbrite and inferred to represent a discrete magma that was injected into the silicic chamber and is considered to have accumulated as a sill at the base of the magma chamber. The contrast in density between the andesitic and silicic magmas did not allow eruption of the andesitic fragments during the deposition of lower and middle Mamaku Ignimbrite. The advanced stage of caldera collapse, late in the main eruptive phase, created withdrawal dynamics that allowed andesitic magma to reach the surface as fragments within upper Mamaku Ignimbrite.     

Utility of trace elements in apatite for discrimination and correlation of Quaternary ignimbrites and co-ignimbrite ashes,Japan

Apatite is a common accessory mineral in intermediate and felsic igneous rocks. Because apatite has a wide range of trace-element compositions as well as strong resistance to diagenetic alteration, the trace-element composition of apatite has been used for tracing petrogenetic processes of plutonic bodies as well as the tephrochronology of Paleozoic tephras. However, it has been little used in Quaternary volcaniclastic deposits. Our studies of apatite trace-element compositions in representative Quaternary ignimbrites and their corresponding co-ignimbrite ashes in Japan demonstrated that such compositions are not affected by welding and can be successfully used for discrimination of, and correlation between, tephras and ignimbrites. We also could distinguish different tephra deposits and ignimbrites from the same caldera. Although most apatite trace-element compositions did not change throughout the succession of ejecta from a single eruption, the Fe contents in apatite varied across stratigraphic horizons. Consequently, we were able to correlate the Fe contents of apatite phenocrysts in specific ignimbrite horizons and their corresponding co-ignimbrite ashes and thus identify the phase of the eruption during which the major part of a co-ignimbrite ash was released.     

Caldera resurgence during magma replenishment and rejuvenation at Valles and Lake City calderas

A key question in volcanology is the driving mechanisms of resurgence at active, recently active, and ancient calderas. Valles caldera in New Mexico and Lake City caldera in Colorado are well-studied resurgent structures which provide three crucial clues for understanding the resurgence process. (1) Within the limits of ⁴⁰Ar/³⁹Ar dating techniques, resurgence and hydrothermal alteration at both calderas occurred very quickly after the caldera-forming eruptions (tens of thousands of years or less). (2) Immediately before and during resurgence, dacite magma was intruded and/or erupted into each system; this magma is chemically distinct from rhyolite magma which was resident in each system. (3) At least 1?km of structural uplift occurred along regional and subsidence faults which were closely associated with shallow intrusions or lava domes of dacite magma. These observations demonstrate that resurgence at these two volcanoes is temporally linked to caldera subsidence, with the upward migration of dacite magma as the driver of resurgence. Recharge of dacite magma occurs as a response to loss of lithostatic load during the caldera-forming eruption. Flow of dacite into the shallow magmatic system is facilitated by regional fault systems which provide pathways for magma ascent. Once the dacite enters the system, it is able to heat, remobilize, and mingle with residual crystal-rich rhyolite remaining in the shallow magma chamber. Dacite and remobilized rhyolite rise buoyantly to form laccoliths by lifting the chamber roof and producing surface resurgent uplift. The resurgent deformation caused by magma ascent fractures the chamber roof, increasing its structural permeability and allowing both rhyolite and dacite magmas to intrude and/or erupt together. This sequence of events also promotes the development of magmatic–hydrothermal systems and ore deposits. Injection of dacite magma into the shallow rhyolite magma chamber provides a source of heat and magmatic volatiles, while resurgent deformation and fracturing increase the permeability of the system. These changes allow magmatic volatiles to rise and meteoric fluids to percolate downward, favouring the development of hydrothermal convection cells which are driven by hot magma. The end result is a vigorous hydrothermal system which is driven by magma recharge.     

Petrology,geochemistry, and age of the Spurr volcanic complex,eastern Aleutian arc

The Spurr volcanic complex (SVC) is a calc-alkaline, medium-K, sequence of andesites erupted over the last 250000 years by the eastern-most currently active volcanic center in the Aleutian arc. The ancestral Mt. Spurr was built mostly of andesites of uniform composition (58%–60% SiO₂), although andesite production was episodically interrupted by the introduction of new batches of more mafic magma. Near the end of the Pleistocene the ancestral Mt. Spurr underwent avalanche caldera formation, resulting in the production of a volcanic debris avalanche with overlying ashflows. Immediately afterward, a large dome (the present Mt. Spurr) formed in the caldera. Both the ash flows and dome are made of acid andesite more silicic (60%–63% SiO₂) than any analyzed lavas from the ancestral Mt. Spurr, yet contain olivine and amphibole xenocrysts derived from more mafic magma. The mafic magma (53%–57% SiO₂) erupted during and after dome emplacement from a separate vent only 3 km away. Hybrid block-and-ash flows and lavas were also produced. The vents for the silicic and mafic lavas are in the center and in the breach of the 5-by-6-km horseshoe-shaped caldera, respectively, and are less than 4 km apart. Late Holocene eruptive activity is restricted to Crater Peak, and magmas continue to be relatively mafic. SVC lavas are plag ±ol+cpx±opx+mt bearing. All postcaldera units contain small amounts of high-Al₂O₃, high-alkali amphibole, and proto-Crater Peak and Crater Peak lavas contain abundant pyroxenite and anorthosite clots presumably derived from an immediately preexisting magma chamber. Ranges of mineral chemistries within individual samples are often nearly as large as ranges of mineral chemistries throughout the SVC suite, suggesting that magma mixing is common. Elevated Sr, Pb, and O isotope ratios and trace-element systematics incompatible with fractional crystallization suggest that a significant amount of continental crust from the upper plate has been assimilated by SVC magmas during their evolution.     

Variation of volatile concentration in a magma system of Satsuma-Iwojima volcano deduced from melt inclusion analyses

Chemical analyses of 30 melt inclusions from Satsuma-Iwojima volcano, Japan, were carried out to investigate volatile evolution in a magma chamber beneath the volcano from about 6300 yr BP to the present. Large variations in volatile concentrations of melts were observed. (1) Water concentration of rhyolitic melts decreases with time; 3–4.6 wt.% at the time of latest caldera-forming eruption of Takeshima pyroclastic flow deposit (ca. 6300 yr BP), 3 wt.% for small pyroclastic flow (ca. 1300 yr BP) of Iwodake, post-caldera rhyolitic dome, and 0.7–1.4 wt.% for submarine lava eruption (Showa-Iwojima) in 1934. (2) Rhyolitic melts of the Takeshima and Iwodake eruptions contained CO₂ of less than 40 ppm, while the Showa-Iwojima melt has higher CO₂ concentration of up to 140 ppm. (3) Water and CO₂ concentrations of basaltic to andesitic melt of Inamuradake, a post-caldera basaltic scoria cone, are 1.2–2.8 wt.% and ≤290 ppm, respectively.Volatile evolution in the magma chamber is interpreted as follows: (1) the rhyolitic magma at the time of the latest caldera-forming eruption (ca. 6300 yr BP) was gas-saturated due to pressure variation in the magma chamber because the large variation in water concentration of the melt was attributed to exsolution of volatile in the magma prior to the eruption. Iwodake eruption (ca. 1300 yr BP) was caused by a remnant of the caldera-forming rhyolitic magma, suggested from the similarity of major element composition between these magmas. (2) Volatile composition of the Showa-Iwojima rhyolitic melt agrees with that of magmatic gases presently discharging from a summit of Iwodake, indicating the low pressure degassing condition. (3) The degassing of the magma chamber by magma convection in a conduit of Iwodake during non-eruptive but active degassing period for longer than 800 years decreased water concentration of the rhyolitic magma. (4) Geological and petrological observations indicate that a stratified magma chamber, which consists of a lower basaltic layer and an upper rhyolitic layer, might have existed during the post-caldera stage. Addition of CO₂ from the underlying basaltic magma to the upper gas-undersaturated (degassed) rhyolitic magma increased CO₂ concentration of the rhyolitic magma.     

Asymmetric,multiple-block collapse at Rotorua Caldera,Taupo Volcanic Zone,New Zealand

Calderas worldwide have been classified according to their dominant collapse styles, although there is a good deal of speculation about the processes involved. Recent laboratory experiments have tried to constrain these processes by modelling magma withdrawal and observing the effects on overlying materials. However, many other factors also contribute to final caldera morphology. Rotorua Caldera formed during the eruption of the Mamaku Ignimbrite. Collapse structure and evolution of Rotorua Caldera is interpreted based its geophysical response, geology and geomorphology, and the stratigraphy of the Mamaku Ignimbrite. Rotorua Caldera is situated at the edge of the extensional Taupo Volcanic Zone, in which major faults strike NE-SW. A second, less dominant fault set strikes NW-SE. These two fault sets have a strong influence on the morphology of Rotorua Caldera. No one style of collapse can be applied to Rotorua Caldera; it was formed during a single eruption, but subsided as many blocks and shows features of trapdoor, piecemeal and downsag types of collapse. Here Rotorua Caldera is described, according to its composition, activity and geometry, as a rhyolitic, single event, asymmetric, multiple-block, single locus collapse structure. The Mamaku Ignimbrite is the only ignimbrite to have erupted from Rotorua Caldera. Extracaldera thickness of the Mamaku Ignimbrite is up to 145 m, whereas inside the caldera it may be greater than 1 km thick. The Mamaku Ignimbrite can be separated into a basal tephra sequence and main ignimbrite sequence. The main ignimbrite sequence contains no observable flow unit boundaries but can be split into lower, middle and upper parts (LMI, mMI, uMI respectively) based on crystal content, welding, jointing, devitrification and vapour phase alteration. Juvenile clasts within the ignimbrite comprise three consanguineous silicic pumice types and andesitic fragments. Only the most evolved pumice type occurs in the basal tephra sequence. All three pumice types occur together throughout the main ignimbrite sequence, whereas the andesitic fragments are only present in uMI. Lithic lag breccias in uMI indicate a late stage of caldera collapse. Concentration of lithic fragments increases towards the middle of the ignimbrite, and may also reflect increased subsidence rate during an earlier stage. Collapse of Rotorua Caldera is thought to have occurred throughout the eruption of the main ignimbrite sequence of the Mamaku Ignimbrite, allowing simultaneous eruption of all the different pumice types and causing the abrupt transition from deposition of the basal tephra sequence to the main ignimbrite sequence.     

Inverse differentiation pathway by multiple mafic magma refilling in the last magmatic activity of Nisyros Volcano, Greece

Based on detailed field, petrographic, chemical, and isotopic data, this paper shows that the youngest magmas of the active Nisyros volcano (South Aegean Arc, Greece) are an example of transition from rhyolitic to less evolved magmas by multiple refilling with mafic melts, triggering complex magma interaction processes. The final magmatic activity of Nisyros was characterized by sub-Plinian caldera-forming eruption (40?ka), emplacing the Upper Pumice (UP) rhyolitic deposits, followed by the extrusion of rhyodacitic post-caldera domes (about 31–10?ka). The latter are rich in magmatic enclaves with textural and compositional (basaltic–andesite to andesite) characteristics that reveal they are quenched portions of mafic magmas included in a cooler more evolved melt. Dome-lavas have different chemical, isotopic, and mineralogical characteristics from the enclaves. The latter have lower ⁸⁷Sr/⁸⁶Sr and higher ¹⁴³Nd/¹⁴⁴Nd values than dome-lavas. Silica contents and ⁸⁷Sr/⁸⁶Sr values decrease with time among dome-lavas and enclaves. Micro-scale mingling processes caused by enclave crumbling and by widespread mineral exchanges increase from the oldest to the youngest domes, together with enclave content. We demonstrate that the dome-lavas are multi-component magmas formed by progressive mingling/mixing processes between a rhyolitic component (post-UP) and the enclave-forming mafic magmas refilling the felsic reservoir (from 15?wt.% to 40?wt.% of mafic component with time). We recognize that only the more evolved enclave magmas contribute to this process, in which recycling of cumulate plagioclase crystals is also involved. The post-UP end-member derives by fractional crystallization from the magmas leftover after the previous UP eruptions. The enclave magma differentiation develops mainly by fractional crystallization associated with multiple mixing with mafic melts changing their composition with time. A time-related picture of the relationships between dome-lavas and relative enclaves is proposed, suggesting a delay between a mafic magma input and the relative dome outpouring. We also infer that the magma viscosity reduction by re-heating allows dome extrusion without explosive activity.     

Collapse mechanism of the Paleogene Sakurae cauldron, SW Japan

The Paleogene Sakurae cauldron of SW Japan is characterized by a nested structure with a polygonal outline (21×13 km²) including a circular collapsed part (5 km in diameter). Total thickness of the caldera infill amounts to 2,000 m. The lower member of the infill consists mainly of felsic crystal tuff and lesser intercalated andesitic lava flows, whereas the upper member is composed of high-grade ignimbrite capped with a large rhyolitic lava dome. These members represent the first and second stage eruptions, respectively. Faults bounding the cauldron rim comprise intersecting radial and concentric faults, producing the polygonal outline of this cauldron. The primary collapse of this cauldron thus occurred as a polygonal caldera basin where products of the first stage eruption accumulated. In contrast, the inner collapse part is defined by a ring fracture system. This sector subsided concurrently with accumulation of the high-grade ignimbrite of the second stage eruption. This inner circular collapse thus represents syn-eruptional subsidence concurrent with the climactic eruption. Magma drainage during the first stage probably induced outward-dipping ring fractures in the chamber roof. Opening of the ring fractures following subsidence of the central bell-jar block caused rapid evacuation of magma as voluminous pumice flows, even though magma pressure may have decreased to some degree.     

Glass-bearing plutonic fragments from ignimbrites of the Okataina caldera complex, Taupo Volcanic Zone, New Zealand: remnants of a partially molten intrusion associated with preceding eruptions

Glass-bearing plutonic fragments occur as rare accessory lithics within the ca. 64 ka Rotoiti and Earthquake Flat ignimbrites that were erupted from Okataina caldera complex, Taupo Volcanic Zone, New Zealand. Granitoid lithic fragments are only found in the Rotoiti ignimbrite and fall into two groups. Group 1 granitoids have textures consistent with a period of slow cooling followed by rapid quenching, and were excavated by the Rotoiti eruption from a single incompletely solidified magma body. Although isotopic ratios for the Group 1 granitoids are similar to the host ignimbrite, they are not cognate, having different chemistry, mineralogy, mineral chemistry and crystallisation history. It is more likely that they represent fragments of a separate incompletely solidified magma chamber that was intercepted by the erupting Rotoiti ignimbrite magma. Low LILE and high HFSE abundances favour a comagmatic link with the ca. 0.28 Ma Matahina ignimbrite and it is suggested they are derived from an isolated cupola of the Matahina magma chamber that remained at depth (between 3.5 and 5 kbar pressure) after eruption of the Matahina ignimbrite. Migration toward the surface probably accompanied development of the Rotoiti magma system in the upper crust. Most geochemical variation in Group 1 granitoids is related to the abundance of biotite, the concentration of which is controlled by differential shear. REE abundance is controlled by light REE-enriched accessory minerals preferentially included within biotite. Although Eu_n remains constant in the Group 1 granitoids, Eu/Eu^* varies systematically with (La/Yb)_n and is controlled by variations in Sm and Gd rather than in Eu. Group 2 granitoid fragments have a wide range of composition, comparable to many Okataina rhyolites, including those found as lithic fragments in the Rotoiti ignimbrite. Rare microdiorite fragments occur in both Rotoiti and Earthquake Flat ignimbrites and typically contain vesicular interstitial glass indicating that they were incompletely solidified prior to eruption. Those from the Rotoiti ignimbrite are comparable to the (>64 ka) Matahi basaltic tephra and probably represent part of the same magmatic event which generated the Matahi tephra.     

Genesis of dacitic magmatism at batur volcano, Bali, Indonesia: Implications for the origins of stratovolcano calderas

Batur is an active stratovolcano on the island of Bali, Indonesia, with a large, well-formed caldera whose formation is correlated with the eruption about 23,700 years ago of a thick ignimbrite sheet. Our study of the volcanic stratigraphy and geochemistry of Batur shows the formation of the caldera was signalled by a change in the composition of the erupting material from basaltic and andesitic to dacitic. The dacitic rocks are glassy, possess equilibrium phenocryst assemblages, and display compositional characteristics consistent with an origin by crystal-liquid fractionation from more mafic parent magmas in a shallow chamber, possibly at 1.5 km depth and 1000–1070°C.However, although separated by a gap of 6 wt.% SiO₂, the dacitic rocks are clearly related in their minor- and trace-element geochemistry to those basalts and basaltic andesites erupted after the caldera was formed rather than to the andesites erupted immediately before the dacites first appeared. We infer from this and published experimental modelling of the possible crystallization behaviour of basaltic magma chambers that a magmatic cycle involving caldera formation began independently of the previous activity of Batur by formation of a new, closed-system magma chamber beneath the volcano. Fractional crystallization, possibly at the walls of the chamber, led to the early production of derivative siliceous magmas and, consequently, to caldera formation, while most of the magma retained its original composition. The postcaldera Batur basalts represent the largely undifferentiated core liquids of this chamber.This model contrasts with the traditional evolutionary model for stratovolcano calderas but may be applicable to the origins of calderas similar to that of Batur, particularly those in volcanic island arcs.     

Formation of the mid-fifteenth century Kuwae caldera (Vanuatu) by an initial hydroclastic and subsequent ignimbritic eruption

In the mid-fifteenth century, one of the largest eruptions of the last 10 000 years occurred in the Central New Hebrides arc, forming the Kuwae caldera (12x6 km). This eruption followed a late maar phase in the pre-caldera edifice, responsible for a series of alternating hydromagmatic deposits and airfall lapilli layers. Tuffs related to caldera formation ( 120 m of deposits on a composite section from the caldera wall) were emitted during two main ignimbritic phases associated with two additional hydromagmatic episodes. The lower hydromagmatic tuffs from the precaldera maar phase are mainly basaltic andesite in composition, but clasts show compositions ranging from 48 to 60% SiO₂. The unwelded and welded ashflow deposits from the ignimbritic phases and the associated intermediate and upper hydromagmatic deposits also show a wide compositional range (60–73% SiO₂), but are dominantly dacitic. This broad compositional range is thought to be due to crystal fractionation. The striking evolution from one eruptive style (hydromagmatic) to the other (magmatic with emission of a large volume of ignimbrites) which occurred either over the tuff series as a whole, or at the beginning of each ignimbritic phase, is the most impressive characteristic of the caldera-forming event. This strongly suggests triggering of the main eruptive phases by magma-water interaction. A three-step model of caldera formation is presented: (1) moderate hydromagmatic (sequences HD 1–4) and magmatic (fallout deposits) activity from a central vent, probably over a period of months or years, affected an area slightly wider than the present caldera. At the end of this stage, intense seismic activity and extrusion of differentiated magma outside the caldera area occurred; (2) unhomogenized dacite was released during a hydromagmatic episode (HD 5). This was immediately followed by two major pyroclastic flows (PFD 1 and 2). The vents spread and intense magma-water interaction at the beginning of this stage decreased rapidly as magma discharge increased. Subsequent collapse of the caldera probably commenced in the southeastern sector of the caldera; (3) dacitic welded tuffs were emplaced during a second main phase (WFD 1–5). At the beginning of this phase, magma-water interaction continued, producing typical hydromagmatic deposits (HD 6). Caldera collapse extended to the northern part of the caldera. Previous C¹⁴ dates and records of explosive volcanism in ice from the south Pole show that the climactic phase of this event occurred in 1452 A.D.     

A resurgent cauldron in the early Paleozoic of Wales, U.K.

The paper presents a controversial interpretation of a mid-Ordovician volcano-sedimentary complex. It deals with the cyclic interdependence of intrusive, volcanic, and sedimentary processes, due to the development of a nearshore resurgent cauldron in the Caledonian fold belt of North Wales. Deformed volcanotectonic features include a resurgent dome and apical graben, surrounded by a moat and peripheral crescentic ring-fault, constituting a caldera 20 km in diameter. The resurgent Snowdon caldera developed through three cycles of ash-flow volcanism resulting from the continuous supply of magma into a shallow magma chamber emplaced beneath the floor of a marine basin. Each ash-flow cycle was preceded by the emergence, above sea level, of a geotumour that subsequently collapsed following eruption and evacuation of the magma chamber. Localized unconformities at the base of individual ash-flow cycles are compared with caldera margin and associated collapse features. Deeper-seated effects of caldera collapse are expressed as gaps in the Ordovician sequence due to normal faulting along the structural boundary of the caldera. Major ash-flow fissure vents were located at points of maximum unloading of the magma chamber by distention faults in its roof. Explosive mechanisms were triggered by rapid pressure release due to tectonic erosion.The presence of a resurgent cauldron implies that the Ordovician succession of North Wales is more complete than recorded in the literature, and that Caledonian structures were largely predetermined by Caradocian volcano-tectonics.