Origin of the Yueguang gold deposit in Xinhua,Hunan Province,South China: insights from fluid inclusion and hydrogen–oxygen stable isotope analysis

The Yueguang gold deposit is located in Fengjia, Xinhua County, Hunan Province, South China. It represents a recently discovered small-scale gold deposit situated in the southwestern region of the Jiangnan Orogenic Belt, west of the Baimashan granitic batholith. In order to discern the characteristics of the ore-forming fluids, the underlying mineralization processes, and establish a foundation for the origin of the Yueguang gold deposit fluid inclusion micro-thermometry, as well as quartz hydro...     

Hawaiian double volcanic chain triggered by an episodic involvement of recycled material: Constraints from temporal Sr–Nd–Hf–Pb isotopic trend of the Loa-type volcanoes

The two parallel loci of recent Hawaiian volcanoes, Kea and Loa, have been regarded as the best targets to interpret the chemical structure of an upwelling mantle plume derived from the lower mantle. Here we show that the Sr–Nd–Hf–Pb isotopic data of the shield-building lavas along the Loa locus form a systematic trend from the main shield stage of Koolau (> 2.9 Ma) to the active Loihi volcanoes. During the growth of the Koolau volcano, the dominant material in the melting region successively changed from the proposed KEA, DMK (depleted Makapuu), to EMK (enriched Makapuu) components. The proportion of EMK, dominated by a recycled mafic component, is typified by some Koolau Makapuu-stage and some Lanai lavas. Subsequently, the EMK component decreased and LOIHI component increased toward the Loihi lavas. The temporal coincidence between the episodically elevated magma production rate and the abrupt appearance of the typical Loa-type lavas that is restricted to the last 3 Myr should be linked to magma genesis. We suggest that the abrupt appearance of Loa-type magmatism should be attributed to the transient incorporation of the relatively dense recycled material and surrounding less degassed lower mantle material that accumulated near the core–mantle boundary into the upwelling plume. This episodic involvement could have been trigged by episodic thermal pulses and buoyancy increases in the plume. The continuous appearance of Kea-type lavas during the long history of Hawaiian-chain magmatism and the larger magma volume of Kea-type lavas relative to that of the Loa-type lavas in the last 3 Myr indicate that the Kea locus is closer to the thermal centre of the Hawaiian plume relative to that of the Loa locus.     

Fluid inclusion and H–O isotope study of the Jiguanshan porphyry Mo deposit,Xilamulun Metallogenic Belt: implications for characteristics and evolution of ore-forming fluids

We studied the fluid inclusions of the Jiguanshan Mo deposit in China, which is a large porphyry deposit located in the southern Xilamulun Metallogenic Belt. The irregular Mo ore body with various types of hydrothermal veinlets is hosted by Late Jurassic granite porphyry. Intense hydrothermal alterations in the deposit from the core to margin are silicification–potassium feldspar alteration,pyrite–quartz–sericite–fluorite alteration, and propylitic alteration. Based on the mineral assemblages and crosscutting relationships of ore veins, the ore-forming process were divided into three stages and two substages: quartz–pyrite veins(stage I) associated with potassic alteration;quartz–molybdenite–chalcopyrite–pyrite veins(substage Ⅱ-1) and quartz–molybdenite–fluorite veins(substage Ⅱ-2)associated with phyllic alteration; and fluorite–quartz–carbonate veins(stage Ⅲ) with carbonation. Five majorfluid inclusions(FIs) types were distinguished in the quartz associated with oxide and sulfide minerals, i.e. polyphase brine(Pb-type), opaque-bearing brine(Ob-type), solid halite(S-type), two-phase aqueous(A-type), and vapor(Vtype) inclusions. The FIs of stage I were composed of liquid-rich S-, A-, and V-type FIs with homogenization temperatures and salinities of 490 to 511 °C and 8.9 to 56.0 wt% NaCl equiv., respectively. The FIs of substage Ⅱ-1 are composed of Pb-, Ob-, S-, A-, and V-type FIs with homogenization temperatures and salinities of 352 to460 °C and 3.7 to 46.1 wt% NaCl equiv, respectively. The FIs of substage Ⅱ-2 are Ob-, S-, A-, and V-type FIs with homogenization temperatures and salinities of 234 to309 °C and 3.7 to 39.2 wt% NaCl equiv, respectively. The FIs of stage Ⅲ are A-type FIs with homogenization temperatures and salinities of 136 to 172 °C and 1.1 to 8.9 wt%NaCl equiv, respectively. Fluid boiling, which resulted in the precipitation of sulfides, occurred in stages I and Ⅱ. The initial ore-forming fluids of the Jiguanshan deposit had high temperature, high salinity, and belonged to an F-rich NaCl ± KCl–H_2O system. The fluids gradually evolved to low temperature, low salinity, and belonged to a NaCl–H_2O system. Studies of the hydrogen and oxygen isotope compositions of quartz(δ~(18)O_(H2O)=-7.3 to 6.3%,δD_(H2O)=-104.3 to-83.3%) show that the ore-formingfluids gradually evolved from magmatic water to meteoric water.     

Analyzing seismic imagery in the time–amplitude and time–frequency domains to determine fluid nature and migration pathways: A case study from the Queen Charlotte Basin,offshore British Columbia

Combining time–amplitude and time–frequency information from seismic reflection data sets of different resolutions allows the analysis of anomalous reflections from very-shallow to great subsurface depths. Thus, it can enhance the imaging of subsurface features which have a frequency-dependent reflectivity such as gas. Analysing seismic data of different resolution in the time–amplitude and time–frequency domains is a powerful method to determine hydrocarbon migration pathways from deep reservoirs to the seafloor. This interpretation method has been applied to the formerly-glaciated offshore Queen Charlotte Basin hosting several seafloor pockmarks and mounds associated with the leakage of underlying hydrocarbon reservoirs. Low-frequency shadows observed in the time–frequency domain provide evidence of different resolutions that several anomalous reflection amplitudes may be attributed to the occurrence of gas. The seismic imagery shows that gas uses a fault to migrate from deep reservoirs included in Upper Mesozoic strata towards secondary reservoirs located along the fault plane into Neogene layers. Once gas reaches a porous cut-and-fill succession, migration changes from structurally- to stratigraphically-controlled before gas leaks through unconsolidated Quaternary sediments forming the shallow subsurface to eventually seep at the seafloor where pockmarks and carbonate mounds are formed.     

Isotope geochemistry (Sr–Nd–Pb) and petrogenesis of leucite-bearing volcanic rocks from “Colli Albani” volcano, Roman Magmatic Province, Central Italy: inferences on volcano evolution and magma genesis

The “Colli Albani” composite volcano is made up of strongly silica-undersaturated leucite-bearing rocks. Magmas were erupted during three main periods, but a complex plumbing system dominated by regional tectonics channelled magmas into different reservoirs. The most alkali-rich magmas, restricted to the caldera-forming period (pre-caldera), are extremely enriched in incompatible trace elements and display more radiogenic Sr (⁸⁷Sr/⁸⁶Sr?=?0.71057–0.71067), with slightly less radiogenic Pb with respect to those of the post-caldera period. Post-caldera volcanic activity was concentrated in three different volcanic environments: external to the caldera, along the caldera edge and within the caldera. The post-caldera magmas produced melilite- to leucitite-bearing, plagioclase-free leucitites. In contrast to the pre-caldera lavas, they are characterised by lower incompatible trace element abundances and less radiogenic Sr (⁸⁷Sr/⁸⁶Sr?=?0.71006–0.71039). Magmas evolved through crystal fractionation plus minor crustal assimilation in a large magma chamber during the pre-caldera period. The multiple caldera collapses dissected and partially obliterated the early magma chamber. During the post-caldera stage, magmas were channelled through several pathways and multiple shallow-level magma reservoirs were established. A lithospheric mantle wedge previously depleted in the basaltic component and subsequently enriched by metasomatic slab-derived component is suggested as the mantle source of Colli Albani parental magmas. Two different parental magmas are recognised for the pre- and post-caldera stages. The differences may be related to the interplay between smaller degrees of melting for the pre-caldera magmas and more carbonate-rich recycled subducted lithologies in the post-caldera magmas.