Characterization and evaluation of processes governing the groundwater quality in parts of the Sabarmati basin,Gujarat using hydrochemistry integrated with GIS

Intense agricultural and industrial activities in any area are likely to make groundwater vulnerable with respect to its quality. In one such area which is a part of Sabarmati river basin of Gujarat, factors influencing the groundwater hydrochemistry in pre‐ and post‐monsoon season were evaluated. Groundwater samples were collected from 5 km × 5 km grids on the basis of spectral signature of vegetation and soil, observed on satellite image. Integration of Conventional graphical plots, Piper plot, saturation index values (estimated using PHREEQC) and GIS was helpful not only to create the database for analysis of spatial variation in respective water quality parameters but also to decipher the hydrogeochemical process occurring in such a large area. USSL diagram and % sodium were used to characterise the suitability of groundwater for irrigation. It was observed that leaching of wastes disposed from anthropogenic activities and agrichemicals is the major factor influencing the groundwater quality, in addition to the natural processes such as weathering, dissolution and ion exchange. Sea water relics are also impacting the groundwater quality. Control of indiscriminate and unplanned exploitation of groundwater, application of fertilizers and disposal of industrial wastes in the affected areas can possibly ensure groundwater protection from further pollution and depletion. Copyright © 2011 John Wiley & Sons, Ltd.     

An analysis of the chemical and microbiological quality of ground water from boreholes and shallow wells in Zimbabwe

Groundwater from boreholes and shallow wells is a major source of drinking water in most rural areas of Zimbabwe. The quality of groundwater has been taken for granted and the status and the potential threats to groundwater quality have not been investigated on a large scale in Zimbabwe. A borehole and shallow well water quality survey was undertaken between January, 2009 and February, 2010 to determine the chemical and microbial aspects of drinking water in three catchment areas. Groundwater quality physico-chemical indicators used in this study were nitrates, chloride, water hardness, conductivity, alkalinity, total dissolved solids, iron, magnesium, manganese, potassium, calcium, fluoride, sulphates, sodium and pH. The microbiological indicators were total coliforms, faecal coliforms and heterotrophs. Principal component analysis (PCA) showed that most of the variation in ground water quality in all catchment areas is accounted for by Total Dissolved Solids (TDS), electrical conductivity (EC), sodium, bicarbonate and magnesium. The principal dissolved constituents in ground water are in the form of electrically charged ions. Nitrate is a significant problem as the World Health Organization recommended levels were exceeded in 36%, 37% and 22% of the boreholes in the Manyame, Mazowe and Gwayi catchment areas respectively. The nitrate levels were particularly high in commercial farming areas. Iron and manganese also exceeded the recommended levels. The probable source of high iron levels is the underlying geology of the area which is dominated by dolerites. Dolerites weather to give soils rich in iron and other mafic minerals. The high level of manganese is probably due to the lithology of the rock as well as mining activity in some areas. Water hardness is a problem in all catchment areas, particularly in the Gwayi catchment area where a value of 2550 mg/l was recorded in one borehole. The problems with hard water use are discussed. Chloride levels exceeded the recommended levels in a few areas under irrigation. Most of the chloride is probably from agricultural activity particularly the application of potassium chloride. Fluoride levels were particularly elevated in the Gwayi catchment area and this is because of the geology of the area. There was no evidence of microbial contamination in all the boreholes sampled as the total coliform, faecal coliforms, heterotrophs count was nil. However, severe microbial contamination was found in the wells especially those in clay areas.     

Groundwater recharge and discharge in a hyperarid alluvial plain (Akesu,Taklimakan Desert,China)

Groundwater recharge and discharge in the Akesu alluvial plain were estimated using a water balance method. The Akesu alluvial plain (4842 km²) is an oasis located in the hyperarid Tarim River basin of central Asia. The land along the Akesu River has a long history of agricultural development and the irrigation area is highly dependent on water withdrawals from the river. We present a water balance methodology to describe (a) surface water and groundwater interaction and (b) groundwater interaction between irrigated and non‐irrigated areas. Groundwater is recharged from the irrigation system and discharged in the non‐irrigated area. Uncultivated vegetation and wetlands are supplied from groundwater in the hyperarid environment. Results show that about 90% of groundwater recharge came from canal loss and field infiltration. The groundwater flow from irrigated to non‐irrigated areas was about 70% of non‐irrigated area recharge and acted as subsurface drainage for the irrigation area. This desalinated the irrigation area and supplied water to the non‐irrigated area. Salt moved to the non‐irrigation area following subsurface drainage. We conclude that the flooding of the Akesu River is a supplemental groundwater replenishment mechanism: the river desalinates the alluvial plain by recharging fresh water in summer and draining saline regeneration water in winter. Copyright © 2007 John Wiley & Sons, Ltd.     

Characteristics of Groundwater Recharge on the North China Plain

Groundwater recharge is an important component of the groundwater system. On the North China Plain (NCP), groundwater is the main water supply. Because of large‐scale overexploitation, the water table has declined, which has produced severe adverse effects on the environment and ecosystem. In this article, tracer experiment and watershed model were used to calculate and analyze NCP groundwater recharge. In the tracer experiment, average recharge was 108 mm/year and recharge coefficient 0.16. With its improved irrigation, vegetation coverage and evapotranspiration modules, the INFIL3.0 model was used for calculation of groundwater recharge. Regional modeling results showed an average recharge of 102 mm/year and recharge coefficient 0.14, for 2001–2009. These values are very similar to those from the field tracer experiment. Influences in the two methods were analyzed. The results can provide an important reference for NCP groundwater recharge.     

Groundwater Storage through Rain Water Harvesting (RWH)

Groundwater extraction is rampant in many developing countries and urban areas whereas the natural recharge is decreasing due to covering of Earth's surface for various developmental activities. This leads to declining levels of groundwater and deterioration in groundwater quality. Artificial recharge with rain water harvesting techniques offers an excellent scope to arrest this degradation. This paper presents a study that analyzes the influence of rain water harvesting (RWH) on groundwater storage and quality. Chennai City, India is selected as study area, as major RWH implementation has taken place during 2002–2003 due to Government legislation. Preliminary analysis of groundwater levels were done spatially and temporally. Groundwater table contours were drawn using the GIS software for pre‐ (1999–2000) and post‐RWH (2009–2010) periods. The groundwater levels follow a decreasing trend before implementation of RWH where as a positive increasing trend takes place after construction of RWH structures. “Groundwater Estimation Committee (GEC)” norms of Government of India were used to estimate the change in storage during pre‐ and post‐RWH periods, which are found to be 1.76 × 10⁶ and 32.77 × 10⁶ m³, respectively. The results show that the implementation of RWH has increased the groundwater storage considerably. Also, the influence of RWH on groundwater quality is found to be encouraging in some parts of the studied area.     

Evaluation of hydrologic data obtained from a local groundwater monitoring network in a metropolitan city,Korea

In the late 1980s, dramatic increases in water use caused over‐exploitation of groundwater resources and deterioration of water quality in Seoul metropolitan city. To monitor changes in quantity of groundwater resources and their quality, the metropolitan government established a local groundwater monitoring network in 1997 consisting of 119 monitoring wells. Groundwater resources in the urban area were affected by various human activities, including underground construction such as subways, pumping for public or private water use, leaky sewer systems and pavements. The variation patterns of the groundwater levels were mainly classified into four types, reflecting natural recharge due to rainfall events during the wet season, artificial recharge from leaky sewer or water supply systems, and heavy groundwater pumping for drainage or flood control purposes at underground construction sites. Significantly decreasing trends of groundwater levels in the suburbs of Seoul indicate groundwater use for various agricultural activities. Subway construction lowered the water level by an average of 25 m. Electrical conductivity values showed a wide range, from 100 to 1800 µS/cm (mean 470 µS/cm). Groundwater temperature generally showed a stable pattern, except for some sensitive increases at relatively shallow monitoring wells. Detailed analysis of the monitored groundwater data would provide some helpful implications for optimal and efficient management of groundwater resources in this metropolitan city. Copyright © 2005 John Wiley & Sons, Ltd.     

Importance of river water recharge to the San Joaquin Valley groundwater system

Groundwater is not a sustainable resource, unless abstraction is balanced by recharge. Identifying the sources of recharge in a groundwater basin is critical for sustainable groundwater management. We studied the importance of river water recharge to groundwater in the south‐eastern San Joaquin Valley (24,000 km², population 4 million). We combined dissolved noble gas concentrations, stable isotopes, tritium, and carbon‐14 analyses to analyse the sources, mechanisms, and timescales of groundwater recharge. Area‐representative groundwater sampling and numerical model input data enabled a stable isotope mass balance and quantitative estimates of river and local recharge. River recharge, identified by a lighter stable isotope signature, represents 47 ± 4% of modern groundwater in the San Joaquin Valley (recharged after 1950) but only 26 ± 4% of premodern groundwater (recharged before 1950). This implies that the importance of river water recharge in the San Joaquin valley has nearly doubled and is likely the result of a 40% increase in total recharge, caused by river water irrigation return flows and increased stream depletion and river recharge due to groundwater pumping. Compared with the large and long‐duration capacity for water storage in the subsurface, storage of water in rivers is limited in time and volume, as evidenced by cold river recharge temperatures resulting from fast infiltration and recharge. Groundwater banking of seasonal surface water flows and expansion of managed aquifer recharge practices therefore appear to be a natural and promising method for increasing the resilience of the San Joaquin Valley water supply system.     

Groundwater quality in the semi‐arid region of the Chahardouly basin,West Iran

Chahardouly basin is located in the western part of Iran and is characterized by semi‐arid climatic conditions and scarcity in water resources. The main aquifer systems are developed within alluvial deposits. The availability of groundwater is rather erratic owing to the occurrence of hard rock formation and a saline zone in some parts of the area. The aquifer systems of the area show signs of depletion, which have taken place in recent years due to a decline in water levels. Groundwater samples collected from shallow and deep wells were analysed to examine the quality characteristics of groundwater. The major ion chemistry of groundwater is dominated by Ca²⁺ and HCO₃^?, while higher values of total dissolved solids (TDS) in groundwater are associated with high concentrations of all major ions. An increase in salinity is recorded in the down‐gradient part of the basin. The occurrence of saline groundwater, as witnessed by the high electrical conductivity (EC), may be attributed to the long residence time of water and the dissolution of minerals, as well as evaporation of rainfall and irrigation return flow. Based on SAR values and sodium content (%Na), salinity appears to be responsible for the poor groundwater quality, rendering most of the samples not suitable for irrigation use. Copyright © 2007 John Wiley & Sons, Ltd.     

Groundwater composition and recharge origin in the shallow aquifer of the Djerid oases,southern Tunisia: implications of return flow

Abstract

Major ions and stable isotopes in groundwaters of the Plio-Quaternary shallow aquifer of the Djerid oases, southern Tunisia, were investigated to elucidate the origin of groundwater recharge and the mineralization processes. It has been demonstrated that the groundwater composition is mainly controlled by the water–rock interaction, the encroachment of brines from the Chotts and the return flow of irrigation waters. The isotopically depleted groundwater samples suggest that the recharge waters derive from an old palaeoclimatic origin. However, the enriched groundwater samples reflect the presence of evaporated recharge water. Furthermore, the large negative deuterium-excess values indicate the effect of secondary evaporation processes, probably related to the return flow of irrigation waters pumped from the underlying aquifer.

Editor D. Koutsoyiannis; Associate editor E. Custodio

Citation Tarki, M., Dassi, L. and Jedoui, Y., 2012. Groundwater composition and recharge origin in the shallow aquifer of the Djerid oases, southern Tunisia: implications of return flow. Hydrological Sciences Journal, 57 (4), 790–804.     

Sustainability of groundwater usage in northern China: dependence on palaeowaters and effects on water quality,quantity and ecosystem health

A synthesis of groundwater ages, recharge rates and information on processes affecting groundwater quality in northern China highlights the major challenges faced for sustainable management of the region's groundwater. Direct recharge rates range from hundreds of millimetres per year in the North China Plain, to tens of millimetres per year in the Loess Plateau to less than 4 mm/year in the arid northwest. Recharge rates and mechanisms to deep semiconfined and confined aquifers are poorly constrained; however, on the basis of available data, these are likely to be mostly negligible. Severe groundwater level declines (0.5–3 m/year) have occurred throughout northern China in the last three to four decades, particularly in deep aquifers. Radiocarbon dating, stable isotope and noble gas data show that the most intensively extracted deep groundwater is palaeowater, recharged under different climate and land cover conditions to the present. Reservoir construction has reduced surface runoff in mountain‐front areas that would naturally recharge regional Quaternary aquifers in many basins. In combination with intensive irrigation practices, this has resulted in the main recharge source shifting from surface runoff and mountain‐front recharge to irrigation returns. This has reduced infiltration of fresh recharge at basin margins and rapidly increased nitrate concentrations and overall mineralisation in phreatic groundwater over wide areas (in some cases to >400 mg/l and >10 g/l, respectively). In some basins, there is evidence that poor quality shallow water has leaked into deep layers (>200 m) via preferential flow, mixing with palaeowaters stored in semiconfined aquifers. High concentrations of naturally occurring fluoride and arsenic (locally >8.5 and >4 mg/l, respectively) have recently lead to the abandonment of numerous supply wells in northern China, creating further pressure on stressed water resources. Increasing water demand from direct and indirect consumption poses major challenges for water management in northern China, which must consider the full water cycle. Copyright © 2012 John Wiley & Sons, Ltd.     

Hydrogeochemical investigation of irrigation water in the vicinity of metallic ore deposits in Kiraz-İzmir,Turkey: Understanding the crucial nexus between “geology and food safety”

The increasing drought due to climate change poses a threat to issues such as safe and accessible drinking water, food safety, and protection from diseases. The provision of water supply is vital for agricultural and livestock activities, which are commonly practiced around natural ore deposits. Examining traditional “irrigation water quality” methods alone is insufficient; investigating potentially toxic metal content in the region's waters is vital, especially around metallic ore deposits. This study focused on the Kiraz district in Turkey, known for its agricultural activities, to assess the impact of geogenic water pollution on irrigation water quality and its implications for food safety and human health. Geology determines nutrient availability, water resources, and land suitability for agriculture. Conventional irrigation water quality parameters indicate groundwater suitability for irrigation in the study area, considering Na%, sodium adsorption ratio, residual sodium carbonate, permeability index, Kelly ratio, magnesium hazard, and potential salinity. However, when examining the potential toxic metal content in the region, it was determined that the values of Al ranged from 96 to 8676 ppb, Ni values ranged from 27 to 360 ppb, and Sb concentrations varied between 9 and 53 432 ppb. Utilizing geogenically contaminated water for irrigation and its indiscriminate use in livestock, dairy, and food industries can lead to foodborne illnesses (cancer, endocrine disruptors, tuberculosis, antimony spots, thyroid tumors, goiter, neurologic and cardiovascular diseases) that endanger human health. The use of low-quality water throughout the agricultural sector and food production chain increases food safety risks.     

Hydrogeochemical evaluation of high-fluoride groundwaters: a case study from Mehsana District,Gujarat, India

Abstract

Groundwater quality problems have emerged in many geographical areas due to natural environmental processes and human intervention in the geosystems. Hydrogeochemical appraisal of fluoride contaminated groundwater in Mehsana District, Gujarat State, India is carried out by means of groundwater quality investigations together with X-ray diffraction analysis of soil samples in the delineated high fluoride areas. Results show that fluoride has negative relationships with calcium, whereas relationships with sodium, alkalinity and sulphate are positive. Results obtained from aqueous speciation modelling using PHREEQC reveal that the groundwater is undersaturated with fluorite and oversaturated with calcite. The factor analysis indicates that sodium plus potassium bicarbonate groundwater have high factor loading for fluoride, whereas that for calcium chloride and magnesium chloride groundwater is low. The plausible geochemical reactions in the study area are precipitation of calcite and dissolution of dolomite, carbon dioxide and sulphate minerals with ion exchange.     

Distinguishing Mountain Front and Mountain Block Recharge in an Intermontane Basin of the Himalayan Region

Intermontane basin aquifers worldwide, particularly in the Himalayan region, are recharged largely by the adjoining mountains. Recharge in these basins can occur either by water infiltrating from streams near mountain fronts (MFs) as mountain front recharge (MFR) or by sub-surface mountain block infiltration as mountain block recharge (MBR). MFR and MBR recharge are challenging to distinguish and are least quantified, considering the lack of extensive understanding of the hydrological processes in the mountains. This study used oxygen and hydrogen isotopes (δ¹⁸O and δ²H), electrical conductivity (EC) data, hydraulic head, and groundwater level data to differentiate MFR and MBR. Groundwater level data provide information about the groundwater-surface water interactions and groundwater flow directions, whereas isotopes and EC data are used to distinguish and quantify different recharge sources. The present methodology is tested in an intermontane basin of the Himalayan region. The results suggest that karst springs (KS) and deep groundwater (DGW) recharge are dominated by snowmelt (47% ± 10% and 46% ± 9%) as MBR from adjacent mountains, insignificantly affected by evaporation. The hydraulic head data and isotopes indicate Quaternary shallow groundwater (SGW) aquifer system recharge as MFR of local meteoric water with significant evaporation. The results indicate several flow paths in the aquifer system, a local flow for KS, intermediate flow for SGW, and regional flow for DGW. The findings will significantly impact water resource management in the area and provide vital baseline knowledge for sustainable groundwater management in other Himalayan intermontane basins.     

Agricultural management impacts on groundwater: simulations of existing and alternative management options in Peninsular India

Understanding the principal causes and possible solutions for groundwater depletion in India is important for its water security, especially as it relates to agriculture. A study was conducted in an agricultural watershed in Andhra Pradesh, India to assess the impacts on groundwater of current and alternative agricultural management. Hydrological simulations were used as follows: (1) to evaluate the recharge benefits of water‐harvesting tillage through a modified Soil and Water Assessment Tool (SWAT) model and (2) to predict the groundwater response to changing extent and irrigation management of rice growing areas. The Green–Ampt infiltration routine was modified in SWAT was modified to represent water‐harvesting tillage using maximum depression storage parameter. Water‐harvesting tillage in rainfed croplands was shown to increase basin‐scale groundwater recharge by 3% and decrease run‐off by 43% compared with existing conventional tillage. The groundwater balance (recharge minus irrigation withdrawals), negative 11 mm/year under existing management changed to positive (18–45 mm/year) when rice growing areas or irrigation depths were reduced. Groundwater balance was sensitive to changes in rice cropland management, meaning even small changes in rice cropland management had large impacts on groundwater availability. The modified SWAT was capable of representing tillage management of varying maximum depression storage, and tillage for water‐harvesting was shown to be a potentially important strategy for producers to enhance infiltration and groundwater recharge, especially in semi‐arid regions where rainfall may be becoming increasingly variable. This enhanced SWAT could be used to evaluate the landscape‐scale impacts of alternative tillage management in other regions that are working to develop strategies for reducing groundwater depletion. Copyright © 2013 John Wiley & Sons, Ltd.     

Using multiple‐variable indicator kriging to assess groundwater quality for irrigation in the aquifers of the Choushui River alluvial fan

This work attempted to locate clean and safe groundwater for irrigation use in the Choushui River alluvial fan. Multiple‐variable indicator kriging (MVIK) was adopted to evaluate numerous hydrochemical parameters for a standard of water quality for irrigation in Taiwan. Many hydrochemical parameters in groundwater were distinguished into three main categories—salinity/sodium hazard, nitrogen hazard and heavy metal hazard. Safe and potential hazardous regions of groundwater for irrigation were delineated according to different probabilities estimated by MVIK. The probabilistic results of the classifications gave an opportunity to explore the spatial uncertainty of the hazards and helped government administrators establish a sound policy associated with the development and management of groundwater resources. Analysis of the results indicate that the central distal‐fan and mid‐fan aquifers are the best places to extract clean and safe groundwater for irrigation, and the deep aquifer (exceeding 200 m depth) has wider regions with clean and safe groundwater for irrigation than shallow aquifers. The northern and southern aquifers, with multiple hazards, limit groundwater use for irrigation. Although the proximal‐fan aquifer is a zone of groundwater recharge, the high nitrogen content seriously affects the environment and is not suitable for irrigation use. Copyright © 2008 John Wiley & Sons, Ltd.     

The Impact of Geology of Recharge Areas on Groundwater Quality: A Case Study of Zhob River Basin,Pakistan

Groundwater is a major source of water supply for domestic and irrigation uses in semiarid, remote but rapidly developing Kilasaifullah district part of Zhob River Basin, located at Pakistan–Afghanistan Border. Zhob River is among few major rivers of perennial nature in Balochistan, which flows from WSW to ENE and falls in Gomal River, a tributary of Indus River. Keeping in view the important geopolitical position and rapid development of the region, this study is primarily focused on groundwater chemistry for contamination sources as well as agriculture development. Water samples from open and tube wells are analyzed and calculated for electrical conductivity (EC), total dissolved solids (TDS), turbidity, pH, K⁺, Na⁺, Ca²⁺, Mg²⁺, HCO, Cl^?, NO, SO, PO, sodium percent (Na%), sodium adsorption ratio (SAR), Kelly's index (KI), and heavy metals (Fe, Cu, Cr, Zn, Pb, and Mn). On the basis of the chemical constituents two zones within the study area are identified and possible causes of the contaminants are pointed out. Two recharge areas were responsible for the different chemical results in groundwater, e.g., zone A was recharged from NNW saline geological formations (Nisai, Khojak, Multana, Bostan formations, and Muslim Bagh ophiolites), which are concentrated with high sodium and chloride. On the other hand Zone B was sourced from SSW from carbonate rich rocks (Alozai, Loralai, Parh formations, and Muslim Bagh ophiolites). The groundwater is classified as C2–S1, C3–S1, C3–S2, C4–S2 on the basis of EC and SAR values which indicate that most of the water of both zones can be used for irrigation safely except the samples plotted in C3–S2 and C4–S2 categories which could be dangerous for soil and crops. Groundwater samples are plotted in good to permissible limits with some samples excellent to good and few samples belong to doubtful category based on sodium percent. Groundwater of zone A is unsuitable for irrigation use due to higher values of KI (more than one) but water of zone B are good for irrigation based on KI. In general, water of both zones is suitable for irrigation but care should be taken during the selection of crops which are sensitive to alkalinity or sodium hazards particularly in zone A.     

A review of aridity and groundwater

Surface hydrological studies are seen as inadequate in hyperarid and arid areas to provide reliable estimates of recharge. In most such areas surface discharges are not present so that assessments of groundwater resources are dependent upon ground interpretation and denied the flow control found in assessments elsewhere. Groundwater models show that gradients are sustained by long-term dewatering and very small amounts of modern indirect recharge. Recharge indications are well within the error of a hydrological balance. Discharges appear equally small. The development of groundwater in arid areas frequently faces problems of salination due to recycling of irrigation water and rising groundwater heads. Abstraction is often inadequately managed so that uncontrolled mining of groundwater occurs. The advantage that groundwater has, however, is that it offers staged development and staged appraisal.     

水化学分析方法在地下水异常核实中的应用

地震前兆识别中的异常核实工作是提高地震分析预报能力的重要环节。"四图一法"是地下水异常核实中有效的水化学分析方法,其中Piper图和Schoeller图用于判定地下水化学类型和补给关系,Gibbs图用于判定地下水化学成分来源,Giggenbach三角图用于判定地下水的水岩平衡状态和是否有深部活动信息,以及混合比例法用于计算地下水的混合程度。同时,介绍了水化学分析方法在异常核实应用中的水样采集、测试方法和基本原理。使用水化学分析方法,有助于判定异常的构造或非构造活动影响因素,提高异常判定的科学水平。     

Application of geochemical tracers for the investigations of groundwater resources in semi-arid region (Central-East Tunisia)

Groundwater resources in Mahdia-Ksour Essef region, located in the central-eastern part of Tunisia, suffer from intensive exploitation and degradation of water quality. The assessment of groundwater vulnerability, the well-understanding of geochemical processes and the investigation of groundwater quality variations are of particular importance for water resources management in this semi-arid region. The results of this multi-disciplinary investigation show that groundwaters of Mahdia-Ksour Essef region are flowing from El Jem and Boumerdes regions in the South, towards the Mediterranean Sea and the sebkha of Moknine in the North. The groundwaters are classified as either Na-Cl or Ca-SO₄. Stable oxygen and hydrogen isotope compositions (δ¹⁸O and δ²H) confirm a recharge by rapid water infiltration, evaporate surface water and water-rock interaction processes in the salinity increase. The rock-water interaction processes of the mineralization of groundwaters include the cation-exchange reactions and the dissolution of carbonates and evaporate. The high values of the water quality index (WQI) and of the total dissolved solids (TDS) (3.7–11 g/L) of these groundwaters indicate their unsuitability for drinking purpose. Moreover, the combination of the WQI, TDS and nitrate results prove the vulnerability of the studied groundwater to the anthropogenic pollution linked to agriculture and domestic activities and to the salt water contamination.     

Recharge seasonality based on stable isotopes: Nongrowing season bias altered by irrigation in Nebraska

The sustainability of groundwater resources for agricultural and domestic use is dependent on both the groundwater recharge rate and the groundwater quality. The main purpose of this study was to improve the understanding of the timing, or seasonality, of groundwater recharge through the use of stable isotopes. Based on 768 groundwater samples collected from aquifers underlying natural resources districts in Nebraska, the isotopic composition of groundwater (δ²H and δ¹⁸O) was compared with that of precipitation by (a) mapping the isotopic composition of groundwater samples and (b) mapping a seasonality index for groundwater. Results suggest that for the majority of the state, groundwater recharge has a nongrowing season signature (October–April). However, the isotopic composition of groundwater suggests that in some intensively irrigated areas, human intervention in the water cycle has shifted the recharge signature towards the growing season. In other areas, a different human intervention (diversion of Platte River water for irrigation) has likely produced an apparent but possibly misleading nongrowing season recharge signal because the Platte River water differs isotopically from local precipitation. These results highlight the need for local information even when interpreting isotopic data over larger regions. Understanding the seasonality of recharge can provide insight into the optimal times to apply fertilizer, specifically in highly conductive soils with high leaching potential. In areas with high groundwater nitrate concentrations, this information is valuable for protecting the groundwater from further degradation. Although previous studies have framed nongrowing season recharge within the context of future climate change, this study also illustrates the importance of understanding how historical human intervention in the water cycle has affected groundwater recharge seasonality and subsequent implications for groundwater recharge and quality.