Mapping of H2S fluxes from the ground using copper passive samplers: An application study at the Zolforata di Pomezia degassing area (Alban Hills,Central Italy)

A new method for measuring H₂S mass flux from the ground, based on the digital analysis of the interference colours produced by the sulphidation of copper passive samplers (CPS), is proposed and discussed in this article. CPS sulphidation has a wide range of linear responses to H₂S doses and can be used together the accumulation chamber method to estimate gas fluxes from natural degassing areas. These are often characterized by the presence of vent centred degassing areas (VCDAs), which are recognizable from the absence or rarefaction of vegetation due to high acid gas concentrations in the soil pores and in the air at ground level. A reference emission curve, accounting for the advective and diffusive components of the flux, can be modelled and used to estimate the total H₂S mass released from each VCDA. The application of this method can be supported by remote sensing analysis that helps identify VCDAs in the field in perivolcanic H₂S degassing areas.As an illustrative application, H₂S gas fluxes from the ground were measured in spring 2007 at the Zolforata di Pomezia degassing area (ZPDA, Alban Hills, Central Italy) using an accumulation chamber internally equipped with CPS. H₂S peak fluxes were measured over the vents after remote sensing assisted identification of the VCDAs. Further measurements were carried out in two ponds and one artificial channel bordering the study area. The total atmospheric flux released at the ZPDA, estimated to be about 1207.6 kg day^? 1, was calculated as the summation of the fluxes from all the H₂S sources, the background flux being negligible.     

Tide-induced airflow in a two-layered coastal land with atmospheric pressure fluctuations

Tide-induced airflow is commonly seen in coastal lands and affects ground stability especially with a less permeable pavement on the ground surface. A tide-induced airflow model in a two-layered unsaturated zone consisting of a highly permeable layer underneath a less permeable layer was established by Li and Jiao [Li HL, JJ Jiao. One-dimensional airflow in unsaturated zone induced by periodic water table fluctuation. Water Resour Res 2005;41:W04007. doi:10.1029/2004WR003916] to describe the one-dimensional airflow with constant atmospheric pressure at the ground surface. In this study, we expand the Li and Jiao model by considering the realistic atmospheric pressure fluctuations and the initial condition. A new transient solution to the airflow model is developed for an initial boundary value problem (IBVP). The transient solution can be used not only to calculate the subsurface air pressure at a future time with a known initial condition, but also to evaluate the asymptotic air pressure variations when time becomes long. The amplitude ratio and phase lag of the subsurface air pressure relative to the tide-induced hydraulic head variations inside the unconfined aquifer below the unsaturated zone are investigated. The results reveal that effect on the subsurface pressure due to changes of atmospheric pressure amplitude depends on the configurations of air resistance in the less permeable layer and the air-filled porosity difference in the two layers. The introduction of atmospheric pressure fluctuations into the airflow model leads to insignificant influence on water table level. A field application of the new solution at Hong Kong International Airport in Hong Kong, China is demonstrated. It indicates that the new transient solution can be conveniently used to evaluate the subsurface air pressure with discrete atmospheric pressure data at the ground surface.     

Degassing of stratified magma by compositional convection

A new model is proposed for passive degassing from sub-volcanic magma chambers. The water content in stably stratified shallow magma chamber will be equated to its solubility at the upper boundary by convection. Water from a lower layer high in water content can enrich the contact zone of the upper layer and lead to further convective overturn of this boundary layer. A complete set of equations describing convection with bubble formation and dissolution is reduced to a simplified form by assuming a small bubble content. The development and pattern of flow driven by vesiculation is modeled numerically in a 2D magma chamber for relatively low Raleigh numbers (5×10⁵). Bubbles rising from the magma will collect near the roof in a layer of 8–10 vol% and then escape upward to fumaroles. The Stokes flux of bubbles escaping from an andesitic magma with viscosity 10⁴ P and a top surface of about 500×500 m corresponds with observed total magmatic water fluxes of 35 kg/s. Pressure within the chamber is buffered by elastic (and local visco-elastic) deformations in the solid rocks bounding the chamber to the range between ambient and close to lithostatic values. In a chamber closed to fresh magma inputs, the decrease in volume due to such gentle volatile escape lowers the reference pressure. Bubbles flux from the lower layer induced by variation of the saturation level around stratification boundary may be efficient mechanism for the water transport between layers.     

On the tensorial nature of advective porosity

Field tracer tests indicate that advective porosity, the quantity relating advective velocity to Darcy flux, may exhibit directional dependence. Hydraulic anisotropy explains some but not all of the reported directional results. The present paper shows mathematically that directional variations in advective porosity may arise simply from incomplete mixing of an inert tracer between directional flow channels within a sampling (or support) volume ω of soil or rock that may be hydraulically isotropic or anisotropic. In the traditional fully homogenized case, our theory yields trivially a scalar advective porosity equal to the interconnected porosity ϕ, thus explaining neither the observed directional effects nor the widely reported experimental finding that advective porosity is generally smaller than ϕ. We consider incomplete mixing under conditions in which the characteristic time t_D of longitudinal diffusion along channels across ω is much shorter than the characteristic time t_H required for homogenization through transverse diffusion between channels. This may happen where flow takes place preferentially through relatively conductive channels and/or fractures of variable orientation separated by material that forms a partial barrier to diffusive transport. Our solution is valid for arbitrary channel Peclet numbers on a correspondingly wide range of time scales t_D ⩽ t ≪ t_H. It shows that the tracer center of mass is advected at a macroscopic velocity which is generally not collinear with the macroscopic Darcy flux and exceeds it in magnitude. These two vectors are related through a second-rank symmetric advective dispersivity tensor Φ. If the permeability k of ω is a symmetric positive-definite tensor, so is Φ. However, the principal directions and values of these two tensors are generally not the same; whereas those of k are a fixed property of the medium and the length-scale of ω, those of Φ depend additionally on the direction and magnitude of the applied hydraulic gradient. When the latter is large, diffusion has negligible effect on Φ and one may consider tracer mass to be distributed between channels in proportion to the magnitude of their Darcy flux. This is made intuitive through a simple example of an idealized fracture network. Our analytical formalism reveals the properties of Φ but is too schematic to allow predicting the latter accurately on the basis of realistic details about the void structure of ω and tracer mass distribution within it. Yet knowing the tensorial properties of Φ is sufficient to allow determining it indirectly on the basis of ω-scale hydraulic and tracer data, including concentrations that represent homogenized samples extracted from (or sensed externally across) an ω-scale plume.     

A reassessment of current volcanic emissions from the Central American arc with specific examples from Nicaragua

The Central American volcanic arc supplies a significant proportion of the persistent annual global sulphur dioxide emissions from volcanoes. In November/December 2003, we completed a survey of the arc section from Mombacho to San Cristóbal in Nicaragua recording individual mean fluxes of 800, 530 and 220 Mg day^− 1 in the plumes from San Cristóbal, Telica and Masaya, respectively. An assessment of fluxes published since 1997 along the entire Central America arc yields a mean total arc flux of SO₂ of 4360 Mg day^− 1 or 8–16% of the annual estimated global volcanic SO₂ flux to the troposphere. New field data shows that Masaya volcano continues to show stable HCl/SO₂ and HF/SO₂ ratios, suggesting a sustained flux of these components of ∼ 220 and 30 Mg day^− 1, respectively (1997 to 2004). Masaya's plume composition also appears to have been stable, between 2001 and 2003, with respect to all the particulate species measured, with significant fluxes of SO₄²⁻ (4 Mg day^− 1), Na⁺ (0.9–1.3 Mg day^− 1) and K⁺ (0.7 Mg day^− 1). Extrapolating the Masaya plume species ratios to the entire Central American arc gives mean HCl and HF fluxes of 1300 and 170 Mg day^− 1 and a particulate sulphate flux of 40 Mg day^− 1 for 1997 to 2004, although without further understanding of the degassing processes and sources at depth of these different volatiles, these arc-scale estimates should be treated with caution. Combining our arc scale mean SO₂ flux with published measurements of volcanic gas compositions with respect to CO₂ and H₂O allows us to estimate mean CO₂ fluxes of 4400–9600 Mg day^− 1 and H₂O fluxes of 70,000–78,000 Mg day^− 1 for the arc. Preliminary comparisons of these estimates of outgassing rates with published volatile input fluxes into the Central American subduction zone, suggest that Cl is more efficiently recycled through the subduction zone than CO₂. The results for H₂O are inconclusive.     

Shake table tests of a new steel–asphalt composite layer system for the seismic base isolation of housing units

Base isolation is an effective way to reduce earthquake energy transfer from ground to structure, but existing seismic isolation systems are not very suitable for rural buildings for some reasons. A new steel–asphalt composite layer for the seismic base isolation of housing units is present in this paper. Its dynamic characteristics and isolation effect are studied by shake table tests of two full-scale specimens. Different earthquake waves with different peak ground accelerations (PGA, from 0.1 g to 0.4 g) are input. Test results show that the isolation layer could efficiently reduce the input acceleration. Moreover, as the PGA increase, the isolation layer shows good function of the displacement limit.     

Flow path oscillations in transient ground-water simulations of large peatland systems

Transient numerical simulations of the Glacial Lake Agassiz Peatland near the Red Lakes in Northern Minnesota were constructed to evaluate observed reversals in vertical ground-water flow. Seasonal weather changes were introduced to a ground-water flow model by varying evapotranspiration and recharge over time. Vertical hydraulic reversals, driven by changes in recharge and evapotranspiration were produced in the simulated peat layer. These simulations indicate that the high specific storage associated with the peat is an important control on hydraulic reversals. Seasonally driven vertical flow is on the order of centimeters in the deep peat, suggesting that seasonal vertical advective fluxes are not significant and that ground-water flow into the deep peat likely occurs on decadal or longer time scales. Particles tracked within the ground-water flow model oscillate over time, suggesting that seasonal flow reversals will enhance vertical mixing in the peat column. The amplitude of flow path oscillations increased with increasing peat storativity, with amplitudes of about 5 cm occurring when peat specific storativity was set to about 0.05 m⁻¹.     

Changes in water table level influence solute transport in uniform porous media

Changes in the water table level result in variable water saturation and variable hydrological fluxes at the interface between the unsaturated and saturated zone. This may influence the transport and fate of contaminants in the subsurface. The objective of this study was to examine the impact of a decreasing and an increasing water table on solute transport. We conducted tracer experiments at downward flow conditions in laboratory columns filled with two different uniform porous media under static and transient flow conditions either increasing or decreasing the water table. Tracer breakthrough curves were simulated using a mobile–immobile transport model. The resulting transport parameters were compared to identify dominant transport processes. Changes in the water table level affected dispersivities and mobile water fractions depending on the direction of water table movement and the grain size of the porous media. In fine glass beads, the water flow velocity was similar to the decline rate of the water table, and the mobile water fraction was decreased compared with steady‐state saturated conditions. However, immobile water was negligible. In coarse glass beads, water flow was faster because of fingered flow in the unsaturated part, and the mobile water fraction was smaller than in the fine material. Here, a rising water table led to an even smaller mobile water fraction and increased solute spreading because of diffusive interaction with immobile water. We conclude that changes of the water table need to be considered to correctly simulate transport in the subsurface at the transition of the unsaturated–saturated zone. Copyright © 2014 John Wiley & Sons, Ltd.     

Quantification of seep-related methane gas emissions at Tommeliten,North Sea

Tommeliten is a prominent methane seep area in the Central North Sea. Previous surveys revealed shallow gas-bearing sediments and methane gas ebullition into the water column. In this study, the in situ methane flux at Tommeliten is re-assessed and the potential methane transport to the atmosphere is discussed, with regards to the hydrographic setting and gas bubble modeling. We have compiled previous data, acquired new video and acoustic evidence of gas bubble release, and have measured the methane concentration, and its C-isotopic composition in the water column. Parametric subbottom sonar data reveal the three-dimensional extent of shallow gas and morphologic features relevant for gas migration. Five methane ebullition areas are identified and the main seepage area appears to be 21 times larger than previously estimated. Our video, hydroacoustic, subbottom, and chemical data suggest that ～1.5×10⁶ mol CH₄/yr (～26 tons CH₄/yr) of methane gas is being released from the seepage area of Tommeliten. Methane concentration profiles in the vicinity of the gas seeps show values of up to 268 nM (～100 times background) close to the seafloor. A decrease in δ¹³C-CH₄ values at 40 m water depth indicates an unknown additional biogenic methane source within the well oxygenated thermocline between 30 and 40 m water depth. Numerical modeling of the methane bubbles due to their migration and dissolution was performed to estimate the bubble-derived vertical methane transport, the fate of this methane in the water column, and finally the flux to the atmosphere. Modeling indicates that less than ～4% of the gas initially released at the seafloor is transported via bubbles into the mixed layer and, ultimately, to the atmosphere. However, because of the strong seasonality of mixing in the North Sea, this flux is expected to increase as mixing increases, and almost all of the methane released at the seafloor could be transferred into the atmosphere in the stormy fall and winter time.     

Influence of Fluctuating Groundwater Table on Volatile Organic Chemical Emission Flux at a Dissolved Chlorinated-Solvent Plume Site

Groundwater elevation fluctuation has been recognized as one mechanism causing temporal indoor air volatile organic chemical (VOC) impacts in vapor intrusion risk assessment guidance. For dissolved VOC sources, groundwater table fluctuation shortens/lengthens the transport pathway, and delivers dissolved contaminants to soils that are alternating between water saturated and variably saturated conditions, thereby enhancing volatilization potential. To date, this mechanism has not been assessed with field data, but enhanced VOC emission flux has been observed in lab-scale and modeling studies. This work evaluates the impact of groundwater elevation changes on VOC emission flux from a dissolved VOC plume into a house, supplemented with modeling results for cyclic groundwater elevation changes. Indoor air concentrations, air exchange rates, and depth to groundwater (DTW) were collected at the study house during an 86-d constant building underpressurization test. These data were used to calculate changes in trichloroethylene (TCE) emission flux to indoor air, during a period when DTW varied daily and seasonally from about 3.1 to 3.4 m below the building foundation (BF). Overall, TCE flux to indoor air varied by about 50% of the average, without any clear correlation to changes in DTW or its change rate. To complement the field study, TCE surface emission fluxes were simulated using a one-dimensional model (HYDRUS 1D) for conditions similar to the field site. Simulation results showed time-averaged surface TCE fluxes for cyclic water-table elevations were greater than for stationary water-table conditions at an equivalent time-averaged water-table position. The magnitudes of temporal TCE emission flux changes were generally less than 50% of the time-averaged flux, consistent with the field site observations. Simulation results also suggested that TCE emission flux changes due to groundwater fluctuation are likely to be significant at sites with shallow groundwater (e.g., < 0.5 m BF) and permeable soil types (e.g., sand).     

Non-passive transport of volatile organic compounds in the unsaturated zone

A detailed model was formulated to describe the non-passive transport of water-soluble chemicals in the unsaturated zone and used to illustrate one-dimensional infiltration and redistribution of alcohol–water mixtures. The model includes the dependence of density, viscosity, surface tension, molecular diffusion coefficient in the liquid-phase, and gas–liquid partition coefficient on the aqueous mixture composition. It also takes into account the decrease in the gas–liquid partition coefficient at high capillary pressures, in accordance with Kelvin’s equation for multi-component mixtures. Simulation of butanol–water mixtures infiltration in sand was in agreement with the experimental data and simulations reported in the literature. Simulation of methanol infiltration and redistribution in two different soils showed that methanol concentration significantly affects volumetric liquid content and concentration profiles, as well as the normalized volatilization and evaporation fluxes. Dispersion in the liquid-phase was the predominant mechanism in the transport of methanol when dispersivity at saturation was set to 7.8 cm. Liquid flow was mainly due to capillary pressure gradients induced by changes in volumetric liquid content. However, for dispersivity at saturation set to 0.2 cm, changes in surface tension due to variation in composition induced important liquid flow and convection in the liquid-phase was the most active transport mechanism. When the Kelvin effect was ignored within the soil, the gas-phase diffusion was significantly lower, leading to lower evaporation flux of water and higher volumetric liquid contents near the soil surface.     

Atmospheric polychlorinated biphenyl (pcb) inputs to a coastal city near the marmara sea

Recent studies have shown that polychlorinated biphenyl (PCB) levels are high in coastal sites. Various types of deposition events, including dry deposition, air–water exchange and wet deposition, were analyzed as part of the study to illustrate the pollution level. The atmospheric levels and deposition mechanisms of 82 PCBs were investigated in Mudanya, a coastal city in Turkey. A total of 175 samples and 112 blanks were collected. Air–water exchange and particle phase dry deposition fluxes were 120 ± 90 ng/m²-d and 125 ± 160 ng/m²-d, respectively. The wet-dry deposition sampler (WDDS) consisted of two reservoirs, wet and dry. Collected with the WDDS, the dry deposition flux was 21 ± 20 ng/m²-d, and the wet deposition fluxes (during the rainy period) were 145 ± 130 ng/m²-d and 195 ± 270 ng/m²-d for the dissolved and particulate phases, respectively. Mass transfer coefficients (MTCs), dry deposition velocities and washout ratios were calculated and compared with the literature values.     

Dynamics of North American sector ionospheric and thermospheric response during the November 2004 superstorm

We present a study of ionospheric and thermospheric response during a November 9–10, 2004 major geomagnetic storm event (DsT ～?300 nT). We utilize the North American sector longitude chain of incoherent scatter radars at Arecibo, Millstone Hill, and Sondrestrom, operating as part of a coordinated international mesosphere/lower thermosphere coupling study experiment. Total electron content (TEC) determinations from global positioning system (GPS) ground receivers, ground magnetometer traces from the Canadian CANOPUS array, Defense Meteorological Satellite Platform (DMSP) topside data, and global convection patterns from the SuperDARN radar network are analyzed to place the detailed radar data in proper mesoscale context. The plasmaspheric boundary layer (PBL) expanded greatly in the dusk sector during ring current intensification to span more than 25° of magnetic latitude, reaching as far south as 30° invariant latitude. Strong sub-auroral polarization stream velocities of more than 1 km/s were accompanied by large upwards thermal O+ fluxes to the overlying magnetosphere. The large PBL expansion subsequently exposed both Millstone Hill and Sondrestrom to the auroral convection pattern, which developed a complex multicell and reverse convection response under strongly northward IMF conditions during a period of global interplanetary electric field penetration. Large traveling atmospheric and ionospheric disturbances caused significant neutral wind and ion velocity surges in the mid-latitude and tropical ionosphere and thermosphere, with substorm activity launching equatorward neutral wind enhancements and subsequent mid-latitude dynamo responses at Millstone Hill. However, ionosphere and thermosphere observations at Arecibo point to significant disturbance propagation modification in the post-dusk sector PBL region.     

Currents and sediment transport in the Mississippi Canyon and effects of Hurricane Georges

The temporal variability in currents, temperature, and particulate matter concentration were measured in the Mississippi Canyon axis where the thalweg was 300 m deep from May–July and August–November 1998 using current meters, thermographs, a light-scattering sensor, and sediment traps. Canyon sediments were sampled by coring and observed using an ROV video camera. Currents in the upper Mississippi Canyon generally oscillated up/down canyon with diurnal periodicity and were bottom-intensified. Mean current speed at 3.5 mab was approximately 8 cm s^?1 during both deployments, reaching maximum speeds of over 50 cm s^?1 under normal conditions. Based on current velocities, critical bed shear stress for resuspension of canyon-floor sediments was exceeded about 30% of the time during both deployments. In late September, Hurricane Georges passed 150 km NE of the study site, significantly intensifying current velocities, bed shear stress, resuspension, trap fluxes and temperature fluctuations. As the hurricane passed, maximum current speed reached 68 cm^?s and temperature decreased ～7 °C in less than two hours. Critical bed shear stress for sediment resuspension was exceeded approximately 50% of the time during the five days of hurricane influence. Further evidence for sediment resuspension was the five-fold (and perhaps 70–130 fold) increase in trap fluxes and compositional similarities between canyon surface sediment and material collected by traps.     

The effect of biomanipulation on phosphorus exchange between sediment and water in shallow,tropical Huizhou West Lake,China

Three shallow basins in Huizhou West Lake, China, were compared with respect to phosphorus (P) cycling between sediment and water, binding forms of P in sediment, and macrophyte biomass. The basins had similar sediments and similar depths, but two of the basins were restored by carp fish removal and macrophyte transplantation. These two basins have had clear water, low Chl.a and high macrophyte coverage for seven and ten years, whilst the unrestored control basin had turbid water and higher Chl.a. Judged by diffusive ammonium efflux, sediments in restored basins had higher mineralization rates than the unrestored basin, but the release of total dissolved P were more similar. However, sediments of restored basins released primarily dissolved organic P, while the sediment from the unrestored basin only released dissolved inorganic P. One third of the P release in the unrestored basin occurred from resuspended sediment, while this pathway contributed less than 3% in restored basins where resuspension rates were 10 times lower and the surface sediments affinity for phosphate higher. Besides from the presence of carps in the unrestored basin, the main differences were a large pool of P (700–850 mg P m⁻²) in macrophyte biomass and a smaller pool (∼150 mg m⁻²) as loosely adsorbed P in the sediment of restored basins than in the unrestored (0 in macrophytes and 350 mg P m⁻² as loosely adsorbed). Also, a tendency of higher concentrations of oxidized iron was observed in the surface sediment from restored basins. The study underlines the potential of trophic structure changes to alter internal nutrient cycling in shallow lakes.     

On the effects of preferential or barrier flow features on solute plumes in permeable porous media

Despite that discrete flow features (DFFs, e.g. fractures and faults) are common features in the subsurface, few studies have explored the influence of DFFs on solute plumes in otherwise permeable rocks (e.g. sandstone, limestone), compared to low-permeability rock settings (e.g. granite and basalt). DFFs can provide preferential flow pathways (i.e. ‘preferential flow features’; PFFs), or can act to impede flow (i.e. ‘barrier flow features’; BFFs). This research uses a simple analytical expression and numerical modelling to explore how a single DFF influences the steady-state distributions of solute plumes in permeable aquifers. The analysis quantifies the displacement and widening (or narrowing) of a steady-state solute plume as it crosses a DFF in idealised, 1 × 1 m moderately permeable rock aquifers. Previous research is extended by accounting for DFFs as 2D flow features, and including BFF situations. A range of matrix-DFF permeability ratios (0.01 to 100) and DFF apertures (0.25 mm to 2 cm), typical of sedimentary aquifers containing medium-to-large fractures, are considered. The results indicate that for the conceptual models considered here, PFFs typically have a more significant influence on plume distributions than BFFs, and the impact of DFFs on solute plumes generally increases with increasing aperture. For example, displacement of peak solute concentration caused by DFFs exceeds 20 cm in some PFF cases, compared to a maximum of 0.64 cm in BFF cases. PFFs widen plumes up to 9.7 times, compared to a maximum plume widening of 2.0 times in BFF cases. Plumes crossing a PFF are less symmetrical, and peak solute concentrations beneath PFFs are up to two orders of magnitude lower than plumes in BFF cases. This study extends current knowledge of the attenuating influence of DFFs in otherwise permeable rocks on solute plume characteristics, through evaluation of 2D flow effects in DFFs for a variety of DFF apertures, and by considering BFF situations.     

Phosphorus retention and release by sediments in the eutrophic Mai Po Marshes,Hong Kong

This study examined the phosphorus retention and release characteristics of sediments in the eutrophic Mai Po Marshes in Hong Kong. Results of chemical fractionation show that the sum of inorganic P pools exceeded 50% of the total sediment P content, with the redox-sensitive iron-bound P (Fe(OOH) ≈ P) being the dominant P fraction. Given the considerable average Fe(OOH) ≈ P concentration of 912 μg g⁻¹, Mai Po sediments demonstrated a great potential to release bioavailable P under low sediment redox potentials. This was further supported by the high mean anaerobic P flux of 31.8 mg m⁻² d⁻¹ recorded in Mai Po sediment cores, indicating the role of bottom sediments as a net P source. Although sediments in Mai Po had appreciable Langmuir adsorption maxima (1642–3582 mg kg⁻¹), the high zero equilibrium P concentrations (0.02–0.51 mg L⁻¹) obtained suggest that sediment sorption processes would contribute to sustaining the eutrophic conditions in overlying water column even with a further reduction in external P load. Concerted efforts should be made to reduce internal loading of P, especially under reducing conditions, to complement the implementation of zero discharge policy for Deep Bay for effective eutrophication abatement and long-term water quality improvement in the Mai Po Marshes.     

Measuring forest floor and canopy interception in a savannah ecosystem

Interception is one of the most underestimated processes of the hydrological cycle. However, it amounts to a substantial part of the terrestrial evaporation and forms a direct feedback of moisture to the atmosphere which is important to sustain continental rainfall. Most investigations on interception focus on canopy interception only, whereas the interception by the surface and forest floor may be of same order of magnitude. Moreover there is a regional bias. Most research has been carried out in Europe and America and little is known about interception in Africa. This paper presents a study on forest floor and canopy interception in a savannah ecosystem. The study deals with both interception storage capacity of different vegetation types and the related moisture fluxes. The interception storage capacity of Msasa leaf litter and of Thatching grass is 1.8 mm and 1.5 mm respectively. This water storage capacity is dependent on storm intensity, with high intensity storms resulting in smaller storage capacity than less intensive storms. Canopy interception for the study period averaged 25% of the total rainfall, which is comparable with other studies. More importantly, the study revealed that combining canopy and forest floor interception yields a total interception flux amounting to 37% of the rainfall, or close to 50% of the total evaporation. This is a significant amount which implies that interception of both canopy and forest floor should be included in hydrological modelling and that interception is relevant for water management.     

Nutrient inputs from submarine groundwater discharge on the Santiago reef flat,Bolinao, Northwestern Philippines

Submarine groundwater discharge (SGD) on the reef flat of Bolinao, Pangasinan (Philippines) was mapped using electrical resistivity, ²²²Rn, and nutrient concentration measurements. Nitrate levels as high as 126 μM, or 1–2 orders of magnitude higher than ambient concentrations, were measured in some areas of the reef flat. Nutrient fluxes were higher during the wet season (May–October) than the dry season (November–April). Dissolved inorganic nitrogen (DIN = NO₃ + NO₂ + NH₄) and soluble reactive phosphorus (SRP) fluxes during the wet season were 4.4 and 0.2 mmoles m⁻² d⁻¹, respectively. With the increase population size and anthropogenic activities in Bolinao, an enhancement of SGD-derived nitrogen levels is likely. This could lead to eutrophic conditions in the otherwise oligotrophic waters surrounding the Santiago reef flat.     

Unusual sudden ionospheric disturbance from solar flare of 4 November 2003

An interpretation of the nature of the sudden ionospheric disturbance in terms of response to X-ray flux enhancement in the band 1–20 Å has been made by many authors. Last decades investigations revealed presence of important qualitative distinctions in spatially temporal pattern of geomagnetic response to solar flares featuring harder radiation spectra (with quanta energies above 100 keV). These distinctions can not be adequately described by classical theory implying ionization growing on E and D ionosperic layers and intensification of Sq-current system. In this respect, solar flare on 4 November 2003 characterizing by existence of two separate (time lag ~45 min) spectral maximums in X-rays range (average quantum energy <100 keV) and in γ-rays range (average quantum energy >100 keV), represents convenient proving ground for study of specifics the geomagnetic response to bursts marked by different hardness. In current article, we show that this flare has a number of unusual features including specific variation of accompanying current system and magnetospheric manifestation that is observed in trapped radiation fluxes and magnetic field on geosynchronous orbit. Possible physical mechanism leading to intensification of magnetospheric–ionospheric current system is discussed.