The hydrothermal system of Nevado del Ruiz volcano,Colombia

Hot springs and steam vents on the slopes of Nevado del Ruiz volcano provide evidence regarding the nature of hydrothermal activity within the summit and flanks of the volcano. At elevations below 3000 m, alkali-chloride water is discharged from two groups of boiling springs and several isolated warm springs on the western slope of Nevado del Ruiz. Chemical and isotopic geothermometers suggest that the boiling springs are fed by an aquifer having a subsurface equilibration temperature of at least 175°C, and the sampled warm spring is fed by an aquifer having a subsurface equilibration temperature near 150°C. Similarities in conservative solute ratios (e.g., B/Cl) indicate that the alkali-chloride waters may be related to a single reservoir at depth. Isotopic ratios of hydrogen and oxygen indicate that recharge for the alkali-chloride aquifers comes mostly from higher elevations on the volcano. Steam vents and steam-heated bicarbonate-sulfate springs at higher elevations, along a linear structural trend with the alkali-chloride springs, may be derived partly from the alkali-chloride water at depth by boiling. Steam from the vents (84°C) yields a gas geothermometer temperature of 209°C. Acid-sulfate-chloride and acid-sulfate waters are discharged widely from warm springs above 3000 m on the northern and eastern slopes of Nevado del Ruiz. Similarities in B/Cl and SO₄/Cl ratios suggest that the acid waters are mixtures of water from an acid-sulfate-chloride reservoir with various proportions of shallow, dilute groundwater. The major source of sulfate, halogens, and acidity for the acid waters may be high-temperature magmatic gases. Available data on hot spring temperatures and compositions indicate that they have remained fairly stable since 1968. However, the eruption of November 13, 1985 apparently caused an increase in sulfate concentration in some of the acid springs that peaked about a year after the eruption. Long-term monitoring of hot spring compositions over many years will be required to better define the effects of volcanic activity on the Nevado del Ruiz hydrothermal system.     

Eruption and mass-wasting-induced processes during the late holocene destructive phase of Nevado del Ruiz volcano, Colombia

The November 13, 1985, eruption was characteristic of the Arenas eruptive stage of Nevado del Ruiz, the most recent of a series of twelve eruptive stages that have occurred in the past 11,000 years. Eruptive sequences, deposits and processes similar to that of 1985 have characterized the behavior of Nevado del Ruiz during three major prehistorical and historical eruptive stages: the approximately 3300-3100 yr. B.P. Hedionda, the 16th century Azufrado, and the mid-1800's Lagunillas eruptive stages, that partly destroyed the present Ruiz summit.According to the interpretation of the stratigraphic record of prehistorical eruptions and historical accounts, almost every recent magmatic event was small or short-lived. Nevertheless, rockslide-debris avalanches and catastrophic debris flows were triggered in all the eruptions owing to slope failures related to specific tectonic features of Ruiz volcano and/or to significant interactions between pyroclastic debris and the ice cap. Evidence for headward retreat of avalanche scarps during multiple eruptions reinforce the case that large slope failures can occur repeatedly at a large-volume volcano like Ruiz without reconstruction of the edifice. The latest Ruiz eruptions that involved rockslide-debris avalanches resemble in part the Shiveluch 1964 event for which evidence of lateral blast deposits are lacking, but differ in part from this type because non-eruptive and mass-wasting processes also triggered rockslide-debris avalanches.Many factors render the cluster of domes of the Ruiz summit unstable, including: (1) deeply dissected troughs opened toward the north-northeast (Azufrado), east (Lagunillas), and south (Recio) flanks; (2) strongly hydrothermally altered north and east flanks of the summit; (3) currently glaciated or recently deglaciated, high cliffs; (4) steep unstable margins of the ice cap on the north and east.Thus, in light of its past behavior, a small eruption or an earthquake might trigger catastrophic rockslide-debris avalanches. Furthermore, such avalanches as well as glacial outburst-floods and ice avalanches could induce debris flows by mobilizing weathered, water-saturated, and unconsolidated rocks or deposits.     

Analysis of swarms of high-frequency seismic events at Nevado del Ruiz volcano, Colombia (January 1986–August 1987): Development of a procedure

The determination of signal properties like frequency, amplitude, “signature” of the sequence of arrivals of P- and S-phases and the subsequent computation of hypocenter parameters, are the steps of a procedure in the analysis of swarms of high-frequency seismic events from Nevado del Ruiz volcano, which could be useful in other volcanic areas. The use of this procedure on Ruiz data led to the determination of various seismic source volumes, which together with hypocenters of non-swarmed events and the identification of geological features such as faults which cross the area, alignment of domes and volcanic edifices, and the record of low-frequency seismic events not centered in the area of the active vent, suggest the existence of a magma chamber of a rather complex geometry. This hypothesis would suggest that magma, emplaced in zones of weakness (faults) that affect the area, may act as the source of seismic activity. This demands a revision of the methodology used in the deformation measurements, and in the analysis of released energy and event occurrence too. The relations between hypocenters (sources), location and relative energy of the swarms, as well as the general volcanic activity (tremor, ash and gas emission, deformation) could turn out to be a possible means to assist in the identification of premonitory activity and thus be relevant to the process of monitoring and forecasting.     

Analysis of seismic patterns observed at Nevado del Ruiz volcano, Colombia during August – September 1985

The seismic activity of the Nevado del Ruiz volcano was monitored during August–September 1985 using a three-component portable seismograph station placed on the upper part of the volcano. The objective was to investigate the frequency content of the seismic signals and the possible sources of the volcanic tremor. The seismicity showed a wide spectrum of signals, especially at the beginning of September. Some relevant patterns from the collected records, which have been analyzed by spectrum analysis, are presented. For the purpose of analysis, the records have been divided into several categories such as long-period events, tremor, cyclic tremor episodes, and strong seismic activity on September 8, 1985.The origin of the seismic signals must be considered in relation to the dynamical and acoustical properties of fluids and the shape and dimensions of the volcano's conduits.The main results of the present experiment and analysis show that the sources of the seismic signals are within the volcanic edifice. The signal characteristics indicate that the sources lie in fluid-phase interactions rather than in brittle fracturing of solid components.     

Leakage of Active Crater lake brine through the north flank at Rincón de la Vieja volcano, northwest Costa Rica, and implications for crater collapse

The Active Crater at Rincón de la Vieja volcano, Costa Rica, reaches an elevation of 1750 m and contains a warm, hyper-acidic crater lake that probably formed soon after the eruption of the Rio Blanco tephra deposit approximately 3500 years before present. The Active Crater is buttressed by volcanic ridges and older craters on all sides except the north, which dips steeply toward the Caribbean coastal plains. Acidic, above-ambient-temperature streams are found along the Active Crater's north flank at elevations between 800 and 1000 m. A geochemical survey of thermal and non-thermal waters at Rincón de la Vieja was done in 1989 to determine whether hyper-acidic fluids are leaking from the Active Crater through the north flank, affecting the composition of north-flank streams.Results of the water-chemistry survey reveal that three distinct thermal waters are found on the flanks of Rincón de la Vieja volcano: acid chloride–sulfate (ACS), acid sulfate (AS), and neutral chloride (NC) waters. The most extreme ACS water was collected from the crater lake that fills the Active Crater. Chemical analyses of the lake water reveal a hyper-acidic (pH0) chloride–sulfate brine with elevated concentrations of calcium, magnesium, aluminum, iron, manganese, copper, zinc, fluorine, and boron. The composition of the brine reflects the combined effects of magmatic degassing from a shallow magma body beneath the Active Crater, dissolution of andesitic volcanic rock, and evaporative concentration of dissolved constituents at above-ambient temperatures. Similar cation and anion enrichments are found in the above-ambient-temperature streams draining the north flank of the Active Crater. The pH of north-flank thermal waters range from 3.6 to 4.1 and chloride:sulfate ratios (1.2–1.4) that are a factor of two greater than that of the lake brine (0.60). The waters have an ACS composition that is quite different from the AS and NC thermal waters that occur along the southern flank of Rincón de la Vieja.The distribution of thermal water types at Rincón de la Vieja strongly indicates that formation of the north-flank ACS waters is not due to mixing of shallow, steam-heated AS water with deep-seated NC water. More likely, hyper-acidic brines formed in the Active Crater area are migrating through permeable zones in the volcanic strata that make up the Active Crater's north flank. Dissolution and shallow subsurface alteration of north-flank volcanoclastic material by interaction with acidic lake brine, particularly in the more permeable tephra units, could weaken the already oversteepened north flank of the Active Crater. Sector collapse of the Active Crater, with or without a volcanic eruption, represents a potential threat to human lives, property, and ecosystems at Rincón de la Vieja volcano.     

Converting tropical rain forest to forest plantation in sabah,malaysia. Part I. Dynamics and net losses of nutrients in control catchment streams

Streamwatcr chemistry was monitored for five years in six streams in a paired catchment experiment in Mendolong, Sabah, Malaysia, including controls in rain forest and secondary vegetation after the [Borneo fire] of 1982–3 and comparing the effects of different ways of establishing forest plantations with Acacia mangium. Three catchments were covered with selectively logged lowland hill dipterocarp forest (W4-W6) and three (W1-W3) with secondary vegetation after forest fires. The control catchments, W3 and W6 reported in this paper, had no treatments applied. Reference monitoring at all streams was for 25 months and the total period of study reported here is 64 months. The soils in the catchments were mainly Orthic Acrisol in W3 and Gleyic Podsol in W6 and a mix of both soil types in the other catchments. Element baseflow concentrations were generally low and not significantly different from stormflow concentrations for all streams during the reference period. Concentrations were also generally consistently low for the two control streams during the whole period of measurement. Chemical inputs as wet deposition were low as a result of a high input from local convection. The rain forest on the Podsol had a tight nutrient circulation indicated by small net losses of macronutrients. The Podsol was found to have poorer conditions for soil mineralization and more surficial runoff, resulting in higher loads of S, C and N in the organic phases, with higher organic C/N ratio, in the discharge. Nitrogen was found to accumulate in both catchments. An almost double accumulation of N in W3 was attributed to a larger biomass accumulation continuing after the forest fire 3–8 years earlier. On the other hand, the Acrisol in W3 had much larger net losses of S, Si, K, Ca, Mg and Na. Most of differences could be attributed to differences in weathering between the soils and local mineralogical differences.     

The 1963–65 eruption of Irazú volcano,Costa Rica (the period of March 1963 to October 1964)

The 1963–65 eruption of Irazú, like all others of this volcano during the historic period, produced only ash and other fragmental ejecta without lava. The initial outbreak on March 13, 1963 started with a series of great explosions that hurled out much ash, blocks, and bombs, but the activity soon settled down to alternating periods of explosive cruptions and quiet emission of steam. Ash was deposited mostly along a zone that extended westward from the summit to and beyond the city of San Jose, 24 km away. The prolonged ashfall severely damaged dairy, vegetable, and coffee farms, and for a while made daily life in the affected cities extremely difficult. Accelerated runoff of rainwater from the ash-covered slopes of the volcano caused destructive floods, mudflows, and landslides. The climax of the cruption probably occurred during December 1963 and January 1964, when ash and incandescent scoria were erupted voluminously and the magma rose to within 100 meters of the lip of the vent. Precise levelling along the highway to the summit in May 1964 by the Geographic Institute revealed the upper part of the volcano upheaved as much as 11 cm above levels determined in 1949. A repetition of the levelling in September 1964 showed a subsidence to approximately the 1949 configuration, indicating a distinct reduction of pressure in the magma chamber. Substantial amounts of pulverized wallrock were present in the ash along with fragments of scoria and pumice. Progressive caving of the vent walls, which enlarged the diameter of the vent from 200 meters to 525 meters, kept dropping wallrock down onto the exploding magma, and at times stopped the eruption for a day or two by plugging the vent. The scoriaceous and pumiceous bombs were porphyritic two-pyroxene olivine basaltic andesite, and their composition remained remarkably constant throughout the eruption. The ash section was about 2 meters thick, 800 meters downwind from the vent in June 1964. In the section, deposits of the rainy season could be distinguished by their well developed stratification from those of the dry season. A zone containing three persistent pumice horizons represents the climactic period of December 1963 to January 1964. The cloudburst of December 10, 1963 is recorded by a highly rilled surface, and the strong winds of the dry season of 1964 are indicated by a rippled lag deposit.     

Evaluation of magmatic processes for the products of the Nevado del Ruiz Volcano, Colombia from geochemical and petrological data

Trace-element concentrations of the eruptive products from the Nevado del Ruiz volcano indicate that at least for the last 1 Ma, the major controlling factor in the evolution of the magma has been a simple fractional crystallization.The Zr/Hf ratios suggest that the source material is mantle-like in origin and whilst subduction-related contamination of the source material has taken place, there is no evidence that assimilation of continental crust has affected the series.No convincing geochemical evidence for magma mixing was found, and data on banded pumices of Pleistocene, Historic and the 1985 eruptions strongly support a crystal fractionation model to explain the compositional variation of their glasses. Therefore, if mixing has taken place it can only be a mixing of layers within a stratified or partially stratified magma chamber.Modeling of fractional crystallization using a stepwise program has been undertaken and least-squares approximations with small residuals are commensurate with analyzed samples. Crystal fractionation models with plagioclase dominating two-pyroxenes and iron oxides give good fits for all calculations. We conclude that simple crystal fractionation is the process most consistent with major- and trace-element variations in the Ruiz series. This closed-system model requires at least 77% crystal fractionation of a basaltic parent to generate the observed compositions of dacites.     

The chemical and hydrologic structure of Poa´s Volcano, Costa Rica

Comparison of the chemical characteristics of spring and river water draining the flanks of Poa´s Volcano, Costa Rica indicates that acid chloride sulfate springs of the northwestern flank of the volcano are derived by leakage and mixing of acid brines formed in the summit hydrothermal system with dilute flank groundwater. Acid chloride sulfate waters of the Rio Agrio drainage basin on the northwestern flank are the only waters on Poa´s that are affected by leakage of acid brines from the summit hydrothermal system. Acid sulfate waters found on the northwestern flank are produced by the interaction of surface and shallow groundwater with dry and wet acid deposition of SO₂ and H₂SO₄ aerosols, respectively. The acid deposition is caused by a plume of acid gases that is released by a shallow magma body located beneath the active crater of Poa´s.No evidence for a deep reservoir of neutral pH sodium chloride brine is found at Poa´s. The lack of discharge of sodium chloride waters at Poa´s is attributed to two factors: (1) the presence of a relatively volatile-rich magma body degassing at shallow depths (< 1 km) into a high level summit groundwater system; and (2) the hydrologic structure of the volcano in which high rates of recharge combine with rapid lateral flow of shallow groundwater to prevent deep-seated sodium chloride fluids from ascending to the surface. The shallow depth of the volatile-rich magma results in the degassing of large quantities of SO₂ and HCl. These gases are readily hydrolyzed and quickly mix with meteoric water to form a reservoir of acid chloride-sulfate brine in the summit hydrothermal system. High recharge rates and steep hydraulic gradients associated with elevated topographic features of the summit region promote lateral flow of acid brines generated in the summit hydrothermal system. However, the same high recharge rates and steep hydraulic gradients prevent lateral flow of deep-seated fluids, thereby masking the presence of any sodium chloride brines that may exist in deeper parts of the volcanic edifice.Structural, stratigraphic, and topographic features of Poa´s Volcano are critical in restricting flow of acid brines to the northwestern flank of the volcano. A permeable lava-lahar sequence that outcrops in the Rio Agrio drainage basin forms a hydraulic conduit between the crater lake and acid chloride sulfate springs. Spring water residence times are estimated from tritium data and indicate that flow of acid brines from the active crater to the Rio Agrio source springs is relatively rapid (3 to 17 years). Hydraulic conductivity values of the lava-lahar sequence calculated from residence time estimates range from 10⁻⁵ to 10⁻⁷ m/s. These values are consistent with hydraulic conductivity values determined by aquifer tests of fractured and porous lava/pyroclastic sequences at the base of the northwestern flank of the volcano.Fluxes of dissolved rock-forming elements in Rio Agrio indicate that approximately 4300 and 1650 m³ of rock are removed annually from the northwest flank aquifer and the active crater hydrothermal system, respectively. Over the lifetime of the hydrothermal system (100's to 1000's of years), significant increases in aquifer porosity and permeability should occur, in marked contrast to the reduction in permeability that often accompanies hydrothermal alteration in less acidic systems. Average fluxes of fluoride, chloride and sulfur calculated from discharge and compositional data collected in the Rio Agrio drainage basin over the period 1988–1990 are approximately 2, 38 and 30 metric tons/day. These fluxes should be representative of minimum volatile release rates at Poa´s in the last 10 to 20 years.     

Helium-isotope systematics at Nevado del Ruiz volcano, Colombia: implications for the volcanic hydrothermal system

We have collected 14 water and gas samples from 9 thermal springs and gas vents near Nevado del Ruiz volcano, Colombia. The ³He/⁴He and ⁴He/²⁰Ne ratios vary significantly from 0.98 R_atm (where R_atm is the atmospheric ³He/⁴He ratio of 1.4 × 10⁻⁶) to 6.30 R_atm, and from 0.37 to 7.0, respectively. The ³He/⁴He ratio (corrected for air contamination) decreases with increasing distance from the central crater of the volcano to the sampling site. The trend is very similar to that observed at Ontake volcano, Japan. A hydrodynamic porous-media dispersion model can explain the ³He/⁴He trend. The temporal variations in the ³He/⁴He ratio at four sites provide useful information on the apparent velocity of the magmatic fluid flow brought on by a volcanic eruption. The estimated value of several tens m day⁻¹ agrees well with the inferred velocity of flow in Oshima volcano, Japan and is comparable to the largest rate of groundwater movement in a deep sedimentary basin.     

Caldera formation at Volcán Colima, Mexico, by a large large holocene volcanic debris avalanche

About 4,300 years ago, 10 km³ of the upper cone of ancestral Volcán Colima collapsed to the southwest leaving a horseshoe-shaped caldera 4 km in diameter. The collapse produced a massive volcanic debris avalanche deposit covering over 1550 km² on the southern flanks of the volcano and extending at least 70 km from the former summit. The avalanche followed a steep topographic gradient unobstructed by barriers, resulting in an unusually high area/volume ratio for the Colima deposit. The apparent coefficient of friction (fall height/distance traveled) for the Colima avalanche is 0.06, a low value similar to those of other large-volume deposits. The debris avalanche deposit contains 40–75% angular volcanic clasts from the ancestral cone, a small proportion of vesicular blocks that may be juvenile, and in distal exposures, rare carbonate clasts plucked from the underlying surface by the moving avalanche. Clasts range in size to over 20 m in diameter and are brecciated to different degrees, pulverized, and surrounded by a rock-flour matrix. The upper surface of the deposit shows prominent hummocky topography with closed depressions and surface boulders. A thick, coarse-grained, compositionally zoned scoria-fall layer on the upper northeastern slope of the volcano may have erupted at the time of collapse. A fine-grained surge layer is present beneath the avalanche deposit at one locality, apparently representing an initial blast event. Most of the missing volume of the ancestral volcano has since been restored at an average rate of 0.002 km³/yr through repeated eruptions from the post-caldera cone. As a result, the southern slope of Volcán Colima may again be susceptible to collapse. Over 200,000 people are now living on primary or secondary deposits of the debris avalanche, and a repetition of this event would constitute a volcanic disaster of great magnitude.Ancestral Volcán Colima grew on the southern, trenchward flank of the earlier and larger volcano Nevado de Colima. Trenchward collapse was favored by the buttressing effect of Nevado, the rapid elevation drop to the south, and the intrusion of magma into the southern flank of the ancestral volcano. Other such trenchward-younging, paired volcanoes are known from Mexico, Guatemala, El Salvador, Chile, and Japan. The trenchward slopes of the younger cones are common sites for cone collapse to form avalanche deposits, as occurred at Colima and Popocatepetl in Mexico and at San Pedro Volcano in Chile.     

Challenges of modeling current very large lahars at Nevado del Huila Volcano,Colombia

Nevado del Huila, a glacier-covered volcano in the South of Colombia’s Cordillera Central, had not experienced any historical eruptions before 2007. In 2007 and 2008, the volcano erupted with phreatic and phreatomagmatic events which produced lahars with flow volumes of up to about 300 million m³ causing severe damage to infrastructure and loss of lives. The magnitude of these lahars and the prevailing potential for similar or even larger events, poses significant hazards to local people and makes appropriate modeling a real challenge. In this study, we analyze the recent lahars to better understand the main processes and then model possible scenarios for future events. We used lahar inundation depths, travel duration, and flow deposits to constrain the dimensions of the 2007 event and applied LAHARZ and FLO-2D for lahar modeling. Measured hydrographs, geophone seismic sensor data and calculated peak discharges served as input data for the reconstruction of flow hydrographs and for calibration of the models. For model validation, results were compared with field data collected along the Páez and Simbola Rivers. Based on the results of the 2007 lahar simulation, we modeled lahar scenarios with volumes between 300 million and 1 billion m³. The approach presented here represents a feasible solution for modeling high-magnitude flows like lahars and allows an assessment of potential future events and related consequences for population centers downstream of Nevado del Huila.     

The Bear Brook Watershed in Maine: Multi-decadal whole-watershed experimental acidification

The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH₄)₂SO₄] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture.     

Hydrological study of the potential effects of the melting of Nevado del Ruiz glacier on urban growth zones in Manizales,Colombia

ABSTRACT

This paper presents the results of a hydrological study aimed at characterizing flood-prone areas in the urban growth zone in the city of Manizales based on the potential effects of melting of the Nevado del Ruiz glacier, in Caldas, Colombia. These results constitute a basis for decision making regarding possible urban growth zones in Andean areas that face risks from volcanic eruptions producing lahars and floods caused by glacier melt. Conservative estimates of extreme flows in the Chinchiná River in the urban growth area of El Rosario can be obtained by considering the effects of rain triggered by airborne particulate material following a volcanic explosion combined with the effects of glacier melt. The effects of global warming on tropical glaciers contribute to their retreat, leading to their disappearance. Therefore, the worst scenario would take place if these events occurred in the short term as glacier volume decreases with time.

Editor Z.W. Kundzewicz; Associate editor not assigned     

Eruptive history of the Colima volcanic complex (Mexico)

The evolution of the Colima volcanic complex can be divided into successive periods characterized by different dynamic and magmatic processes: emission of andesitic to dacitic lava flows, acid-ash and pumice-flow deposits, fallback nuées ardentes leading to pyroclastic flows with heterogeneous magma, plinian air-fall deposits, scoriae cones of alkaline and calc-alkaline nature. Four caldera-forming events, resulting either from major ignimbrite outbursts or Mount St. Helens-type eruptions, separate the main stages of development of the complex from the building of an ancient shield volcano (25 × 30 km wide) up to two summit cones, Nevado and Fuego.The oldest caldera, C1 (7–8 km wide), related to the pouring out of dacitic ash flows, marks the transition between two periods of activity in the primitive edifice called Nevado I: the first one, which is at least 0.6 m.y. old, was mainly andesitic and effusive, whereas the second one was characterized by extrusion of domes and related pyroclastic products. A small summit caldera, C2 (3–3.5 km wide), ended the evolution of Nevado I.Two modern volcanoes then began to grow. The building of the Nevado II started about 200,000 y. ago. It settled into the C2 caldera and partially overflowed it. The other volcano, here called Paleofuego, was progressively built on the southern side of the former Nevado I. Some of its flows are 50,000 y. old, but the age of its first outbursts is not known. However, it is younger than Nevado II. These two modern volcanoes had similar evolutions. Each of them was affected by a huge Mount St. Helens-type (or Bezymianny-type) event, 10,000 y. ago for the Paleofuego, and hardly older for the Nevado II. The landslides were responsible for two horseshoe-shaped avalanche calderas, C3 (Nevado) and C4 (Paleofuego), each 4–5 km wide, opening towards the east and the south. In both cases, the activity following these events was highly explosive and produced thick air-fall deposits around the summit craters.The Nevado III, formed by thick andesitic flows, is located close to the southwestern rim of the C3 caldera. It was a small and short-lived cone. Volcan de Fuego, located at the center of the C4 caldera, is nearly 1500 m high. Its activity is characterized by an alternation of long stages of growth by flows and short destructive episodes related to violent outbursts producing pyroclastic flows with heterogeneous magma and plinian air falls.The evolution of the primitive volcano followed a similar pattern leading to formation of C1 and then C2. The analogy between the evolutions of the two modern volcanoes (Nevado II–III; Paleofuego-Fuego) is described. Their vicinity and their contemporaneous growth pose the problem of the existence of a single reservoir, or two independent magmatic chambers, after the evolution of a common structure represented by the primitive volcano.     

Remanent magnetization of andesitic and dacitic pumice from the 1985 eruption of Nevado del Ruiz (Colombia) reversed due to self-reversal

The natural remanent magnetization of andesitic pumice emitted during the 1985 eruption of the Nevado del Ruiz volcano (Colombia) has a direction opposite to the present geomagnetic field. The self-reversing mechanism can be re-activated in the laboratory during cycles of heating and subsequent cooling in air and zero magnetic field. Laboratory-produced thermoremanent magnetization is dominated by the same self-reversal process in fields up to several mT. Microchemical, optical and Curie temperature analyses indicate that the ferromagnetic minerals are members of the magnetite-ulvöspinel and hematite-ilmenite series with average compositions of Fe_2.73Ti_0.27O₄ and Fe_1.38Ti_0.62O₃, respectively. In analogy with the magnetic behaviour of synthetically grown antiferromagnetic-ferromagnetic FeMn-FeNi films, the self-reversal can probably be interpreted in terms of an exchange field acting between a Ti-poor canted antiferromagnetic and a Ti-rich ferrimagnetic phase in the hemoilmenite grains.     

TOMS measurement of the sulfur dioxide emitted during the 1985 Nevado del Ruiz eruptions

The eruptions of Nevado del Ruiz in 1985 were unusually rich in sulfur dioxide. These eruptions were observed with the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) which can quantitatively map volcanic sulfur dioxide plumes on a global scale. A small eruption, originally believed to be of phreatic origin, took place on September 11, 1985. However, substantial amounts of sulfur dioxide from this eruption were detected with TOMS on the following day. The total mass of SO₂, approximately 9 ± 3 × 10⁴ metric tons, was deposited in two clouds, one in the upper troposphere, the other possibly at 15 km near the stratosphere.The devastating November 13 eruptions were first observed with TOMS at 1150 EST on November 14. Large amounts of sulfur dioxide were found in an arc extending 1100 km from south of Ruiz northeastward to the Gulf of Venezuela and as an isolated cloud centered at 7°N on the Colombia-Venezuela border. On November 15 the plume extended over 2700 km from the Pacific Ocean off the Colombia coast to Barbados, while the isolated mass was located over the Brazil-Guyana border, approximately 1600 km due east of the volcano. Based on wind data from Panama, most of the sulfur dioxide was located at 10–16 km in the troposphere and a small amount was quite likely deposited in the stratosphere at an altitude above 24 km.The total mass of sulfur dioxide in the eruption clouds was approximately 6.6 ± 1.9 × 10⁵ metric tons on November 14. When combined with quiescent sulfur dioxide emissions during this period, the ratio of sulfur dioxide to erupted magma from Ruiz was an order of magnitude greater than in the 1982 eruption of El Chichon or the 1980 eruption of Mount St. Helens.     

Chronic and episodic acidification of streams along the Appalachian Trail corridor,eastern United States

Acidic atmospheric deposition has adversely affected aquatic ecosystems globally. As emissions and deposition of sulfur (S) and nitrogen (N) have declined in recent decades across North America and Europe, ecosystem recovery is evident in many surface waters. However, persistent chronic and episodic acidification remain important concerns in vulnerable regions. We evaluated acidification in 269 headwater streams during 2010–2012 along the Appalachian Trail (AT) that transits several ecoregions and is located downwind of high levels of S and N emission sources. Discharge was estimated by matching sampled streams to those of a nearby gaged stream and assuming equivalent daily mean flow percentiles. Charge balance acid-neutralizing capacity (ANC) values were adjusted to the 15th (Q15) and 85th flow percentiles (Q85) by applying the ANC/discharge slope among sample pairs collected at each stream. A site-based approach was applied to streams sampled twice or more and a second regression-based approach to streams sampled once to estimate episodic acidification magnitudes as the ANC difference from Q15 to Q85. Streams with ANC <0 μeq/L doubled from 16% to 32% as discharge increased from Q15 to Q85 according to the site-based approach. The proportion of streams with ANC <0 μeq/L at low flow and high flow decreased from north to south. Base cation dilution explained the greatest amount of episodic acidification among streams and variation in sulfate (SO₄²⁻) concentrations was a secondary explanatory variable. Episodic SO₄²⁻ patterns varied geographically with dilution dominant in northern streams underlain by soils developed in glacial sediment and increased concentrations dominant in southern streams with older, highly weathered soils. Episodic acidification increased as low-flow ANC increased, exceeding 90 μeq/L in 25% of streams. Episodic increases in ANC were the dominant pattern in streams with low-flow ANC values <30 μeq/L. Chronic and episodic acidification remain an ecological concern among AT streams. The approach developed here could be applied to estimate the magnitude and extent of chronic and episodic acidification in other regions recovering from decreasing levels of atmospheric S and N deposition.     

Volcanic hazard zonation of the Nevado de Toluca volcano,México

The Nevado de Toluca is a quiescent volcano located 20 km southwest of the City of Toluca and 70 km west of Mexico City. It has been quiescent since its last eruptive activity, dated at ∼ 3.3 ka BP. During the Pleistocene and Holocene, it experienced several eruptive phases, including five dome collapses with the emplacement of block-and-ash flows and four Plinian eruptions, including the 10.5 ka BP Plinian eruption that deposited more than 10 cm of sand-sized pumice in the area occupied today by Mexico City. A detailed geological map coupled with computer simulations (FLOW3D, TITAN2D, LAHARZ and HAZMAP softwares) were used to produce the volcanic hazard assessment. Based on the final hazard zonation the northern and eastern sectors of Nevado de Toluca would be affected by a greater number of phenomena in case of reappraisal activity. Block-and-ash flows will affect deep ravines up to a distance of 15 km and associated ash clouds could blanket the Toluca basin, whereas ash falls from Plinian events will have catastrophic effects for populated areas within a radius of 70 km, including the Mexico City Metropolitan area, inhabited by more than 20 million people. Independently of the activity of the volcano, lahars occur every year, affecting small villages settled down flow from main ravines.     

Causes of acidity in the River Lillån in the coastal zone of central northern Sweden

Factors controlling acidity were studied in the acidic River Lillån in the coastal zone of central northern Sweden. The stream drains the hilly wave-washed terrain and the sediment-covered coastal plain which are the dominating types of landscape in the region. A synoptic study of 38 small streams, representing both types of landscape was also made. Acidity in all streams is caused by organic acids in combination with catchment sources of sulfate. The most acidic streams occur in the hilly terrain because of a high terrestrial export of organic acids and low buffering capacity. Acidic episodes during snowmelt were associated with strongly decreased base cation concentrations, decreased SO²⁻₄ and slightly increased organic acids concentrations. Frequently occurring acid episodes caused by rainstorms and associated outwash of organic acids from forest soils are typical for events in late summer and autumn. It is suggested that, in all essential aspects, the acidity in surface waters in this part of Sweden is of natural origin.