光释光测年法——综述及进展

光释光(OSL)测年是对沉积物最后一次曝光(或热)事件年代的测定,其测试对象主要为石英和长石。自20世纪80年代该方法提出以来,在国内外得到了广泛的应用。但国内不少地学工作者对该技术的原理与测年方式了解十分有限,为了使应用者能更好、更全面地了解和使用这一方法,对OSL测年法及其近年来的国内外主要研究进展进行了回顾,重点对OSL测年法的基本原理、样品采集及实验室前处理过程、等效剂量(De)值的测定方式、环境剂量率的计算,以及影响测年结果可靠性的重要因素等进行了全面介绍、分析和探讨。同时,对近年来国内外关于De值测定方法与技术上的进展及已经获得较可信年龄的相关方法等进行了总结分析,并对OSL可能测年的范围和影响结果可靠性的一些潜在因素,以及对获得100ka~1Ma间的年龄新的释光信号研究方法等进行了介绍和探讨。     

OSL and 14C chronologies of a Holocene sedimentary record (Garding‐2 core) from the German North Sea coast

The history of sea‐level change and sediment accumulation since the last deglaciation along the German North Sea coast is still controversial because of a limitation in the quantity and quality of chronological data. In the current study, the chronology of a 16‐ka coastal sedimentary record from the Garding‐2 core, retrieved from the Eiderstedt Peninsula in Schleswig‐Holstein, northern Germany, was established using OSL and AMS ¹⁴C dating techniques. The robust chronology using 14 radiocarbon and 25 OSL dates from the Garding‐2 core is the first long‐term record that covers the Holocene as well as the last deglaciation period in one succession in the German North Sea area. It provides a new insight into understanding the Holocene transgression and coastal accumulation histories. The combined evidence from the sedimentology and chronology investigations indicates that an estuarine environment dominated in Eiderstedt Peninsula from 16 to 13 ka, followed by a depositional hiatus between 13 and 8.3 ka, attributed to erosion caused by the Holocene transgression; the onset of the Holocene transgression at the core site occurred at around 8.3 ka. The sea level continued to rise with a decelerated rate until around 3 ka. Since 3 ka, the shoreline has begun to prograde. Foreshore (tidal flat) sediments have been deposited at the drilling site with a very high sedimentation rate of about 10 m ka^?1. At around 2 ka, a sandy beach deposit accumulated in the sedimentary succession, indicating that the coastline shifted landward, which may represent a small‐scale transgression in the late Holocene. At around 1.5 ka, terrestrial clastic sediment started to accumulate, indicating a retreat of the relative sea level in this area, which may be related to local diking activities undertaken since the 11th century.     

OSL Age Determination of Archaeological Stone Structures Using Trapped Aeolian Sediments: A Case Study from the Negev Highlands,Israel

Optically stimulated luminescence (OSL) dating is widely applied to sediments in paleoenvironmental sciences. However, there are only limited examples determining the age of archaeological stone structures by OSL using dust deposits. The age of dust deposits associated with ancient buildings may be used to date the onset of settlement (sediment below structures), settlement activity (occupation layer), or the time after a settlement had been abandoned or destroyed (sediment between collapsed roofs and walls). In this study, OSL dating is applied to establish numerical dates for settlement structures situated in the Negev Highlands, Israel. Two archaeological sites are investigated to identify their occupation history, by dating nine samples of aeolian dust trapped within the remains of ancient buildings. The OSL dating technique is applied using coarse grain quartz and a standard single‐aliquot regenerative‐dose (SAR) protocol. It was possible to date the onset of sedimentation in a later phase of the human occupation or shortly after the sites were abandoned, to 3.7 ± 0.3 ka (Intermediate Bronze Age) at the central site and to 2.7 ± 0.2 ka (Iron Age) at the ephemeral site. These results are supported by archaeological evidence gained from pottery finds and the architecture of the ancient buildings.     

Dating recent floodplain sediments in the Hawkesbury‐Nepean River system,eastern Australia using single‐grain quartz OSL

Two fluvial sediment cores taken from a floodplain of the Hawkesbury‐Nepean River system in the Sydney region, eastern Australia are dated using Optically Stimulated Luminescence (OSL) to provide a reliable chronology essential for the management and planning of water resources. Nine charcoal ¹⁴C (AMS) dates constrain these OSL ages. Quartz extracted from seven OSL samples from each of the cores was measured using both single‐grain and multi‐grain OSL techniques. Three of the single‐grain natural dose distributions appear to be well bleached, but the others appear to be incompletely bleached to various degrees. Three minimum‐age models (MAM, MAM_UL and IEU) are applied to the single‐grain dose distributions. We conclude that these models give consistent age estimates. For one of the cores it appears to be necessary to use a minimum‐age model to obtain accurate ages, but in the other core incomplete bleaching is probably less important than postdepositional mixing and mixing during sampling. As a result, the burial age is probably best estimated using the weighted average of the individual single‐grain dose estimates. The application of multi‐grain OSL techniques to these samples results in an average apparent age overestimation of ～200 years, which is significant for these samples, but negligible for sediments older than a few thousand years. The intention is that the chronology obtained in this study will be used in conjunction with a proxy flood record, derived from floodplain sediments, to gain an understanding of the long‐term variability in periods of high and low rainfall in eastern Australia.     

A scanning system for measuring the age-related luminescence of split sediment cores

This article describes the development and performance of an integrated optical sensor system that has been designed for rapid analysis of split sediment cores. The primary aim of the system is to obtain information based on optically stimulated luminescence (OSL) techniques; these provide a record of the accrued radiation dose of material since deposition. Particularly after suitable normalization, the luminescence signal recorded along the length of the core will provide information on the relative age of the sediment. Two wavelengths of stimulation are used (infra-red and green) and these probe the feldspar, and combined feldspar and quartz components of the sediment respectively; the ratio of the two signals can thus provide some indication of relative changes in the silicate mineralogy. A secondary use of the system is for optical reflectance measurements. With the addition of a monochromator, optical reflectance spectroscopy can be applied to obtain additional information on down-core mineralogical changes. In this article we describe technical aspects of the sensor system, discuss measurement techniques and consider the relevance of data obtained. Two examples of sediment cores are presented, which demonstrate the applicability of the instrument.     

A new palaeoenvironmental model for the evolution of the Byzovaya Palaeolithic site,northern Russia

Recently, the sediment stratigraphy and geochronology of the well‐known Palaeolithic site Byzovaya in northern Russia were investigated. New technological analyses of the artefacts suggest a Middle Palaeolithic Mousterian culture, and occupation by Neanderthals, not Modern humans as previously thought. We present here a new and detailed documentation of the stratigraphy, including the geological context of the artefacts and faunal remains. From sedimentological criteria we confidently interpret the find‐bearing strata as debris‐flow deposits, covered by aeolian sediments. The chronology is based on radiocarbon and luminescence (OSL) dates from the find‐bearing and overlying strata. The results are utilized to reconstruct the geological history at the excavation area. The stratigraphy varies considerably across the excavation area. The most intact and undisturbed part of the sequence was found inside the most recent Excavation II. In this part the artefacts and bones appear to have been permanently sealed and protected by aeolian sand. The older Excavation I shows a more complicated stratigraphy, as the finds may have been temporarily exposed during the early Holocene owing to ravine incision and slumping activity. The individual radiocarbon dates that were collected from different parts of the site and from various stratigraphic positions are re‐investigated in this study. By using Bayesian statistics the conclusion is that the site was occupied during a restricted period around 30.6–34.7 ka. A series of partly unpublished OSL dates of coversand from different sites demonstrates a regional aeolian signal during the Lateglacial in northern Russia, 15–14 ka.     

沙漠边缘厚层黄土上部光释光测年的初步研究*

对处于中国西北黄土高原沙漠边缘曹岘厚层黄土剖面上部进行了光释光年代初步研究。实验结果表明,45~63μm石英颗粒的光释光信号以快组分为主,适合应用单片再生剂量法(SAR)测年。在自然和再生剂量预热温度为260℃持续10秒,检测剂量预热温度为160℃持续0秒的条件下,石英单片再生剂量法获得的光释光年龄随样品深度而增加。但是,剖面底部S₁古土壤和L₂顶部黄土样品的光释光年龄仅为69.1±5.5ka和72.0±4.6ka,表现出30 ％ ~50 ％ 的年龄低估。利用多片再生剂量法(MAR)得到的年龄与SAR方法所得年龄无显著差异,即出现了类似的年龄低估现象。在20.1~18.8ka时段内,该剖面的沉积速率超过500cm/ka。末次冰盛期的寒冷气候,与沙漠的距离以及近邻黄河的地貌特点共同造成了如此高的沉积速率。     

山地灾害沉积物的测年综述

山地灾害事件发生的年代是理解其发育机制并作出预测的基础.在长时间尺度上,常用的测牟方法有光释光、14C、宇宙成因核素和火山灰测年等,其中的关键是能否在剖面中寻找到合适的测年物质.短时间尺度的测年方法以树轮为主,辅以地衣测年.在山地灾害中,不仅灾害沉积本身,其相关沉积物对事件年代也具有指示意义.在实际应用中,根据测年材料...     

Radiocarbon-dating of transitions between marine and lacustrine sediments and their relation to the development of lakes

In three different areas in western Norway, large errors are obtained in the radiocarbon dates from lacustrine sediments close to marine/lacustrine sediment boundaries. Differences occur between radiocar-bon and pollenanalytic dates and between dates at isolation/ingression contacts for lakes of the same altitude above the present sea level. Younger radiocarbon dates are also obtained below older ones in undisturbed sediments. When divergent dates occur, the radiocarbon dates always seem to be the youngest. Large differences are also found between NaOH soluble and insoluble fractions of the same sediment samples. Insoluble fractions generally yield younger dates than the soluble. Differences are not found, however, for dates younger than about 8,000 B.P. The dating errors are connected to periods with more oligotrophic conditions with isoetides. Their roots penetrate older sediments. Due to contamination of the organic part of the sediment from partly decomposed roots, some radiocarbon dates will be too young. The isoetide vegetation and the dating errors disappear when the lakes become dystrophic.     

Luminescence dating of Late Quaternary sediments from East Greenland

Luminescence dating based on K-feldspars and using both TL and OSL methods have been performed on 94 sediment samples from East Greenland. The ages go back more than 380 ka, but are mainly from the last interglaciation and the subsequent period and include both shallow-marine/coastal-fluvial and ice proximal meltwater sediments. Independent age control indicates that the dates in the first group generally fall within ± 15% of the expected age, although a few samples show larger deviations. The ice proximal sediments, on the other hand, show a much larger spread and exaggerated ages, probably owing to incomplete bleaching. OSL may give better results than TL in these sediments.     

Chronologies of sedimentary changes in the south Bohai Sea,China: constraints from luminescence and radiocarbon dating

The alternation of terrestrial and marine deposits is an indicator of past environmental and sea‐level changes. The age of deposition is usually dated by means of radiocarbon. However, radiocarbon dates of molluscan shells from coastal areas may be complicated by various sources of carbon, and problematic for deposits of 40–50 ka or older. Herein, we apply the Optically Stimulated Luminescence (OSL) dating method to date samples from terrestrial and marine/coastal sediments extracted from three cores in the south Bohai Sea, China. Multiple‐ and single‐aliquot regenerative‐dose procedures using OSL signals from fine‐silt (4–11 μm), coarse‐silt (38–63 μm) and fine‐sand (63–90 or 90–125 μm) quartz were employed to determine the equivalent dose (D _e). The results showed that: (i) OSL ages from quartz of different grain sizes and different protocols are consistent with each other; (ii) for Holocene samples, most of the radiocarbon dates agree well with OSL ages; (iii) for pre‐Holocene samples, radiocarbon dates cluster at 40–50 ¹⁴ C ka BP, whereas OSL ages are in stratigraphic order from 11 ka to 176 ka. Because of the self‐consistency of the quartz OSL ages, the stratigraphic agreement in the three cores, and the clustering of the radiocarbon dates, we suggest that the quartz OSL ages are more reliable with respect to dating the samples from the south Bohai Sea. Finally, the four marine strata identified in the south Bohai Sea are likely to have formed during the Holocene, Marine Isotopic Stage (MIS) 3–5, MIS 6 and probably MIS 7, respectively.     

Intriguing climatic shifts in a 90 kyr old lake record from northern Russia

A 22 m long sediment core from Lake Yamozero on the Timan Ridge in northern Russia has provided evidence of intriguing climatic shifts during the last glacial cycle. An overall shallowing of the lake is reflected in the lower part of the cores, where pollen indicates a transition from glacial steppe vegetation to interstadial shrub-tundra. These beds are capped by a well-defined layer of compact clay deposited in relatively deep water, where pollen shows surrounding spruce forests and warmer-than-present summer temperatures. The most conservative interpretation is that this unit represents the last interglacial period. However, a series of Optical Stimulated Luminescence (OSL) dates suggests that it corresponds with the Early Weichselian Odderade interstadial (MIS 5a). This would imply that the Odderade interstadial was just as warm as a normal interglacial in this continental part of northern Europe. If correct, then pollen analysis, as a correlation tool, is less straightforward and the definition of an interglacial is more complex than previously thought. We discuss the validity and possible systematic errors of the OSL dates on which this age model is based, but conclude they really indicate a MIS 5a age for the warm period. Above the clay is an unconformity, most likely reflecting a period of subaerial exposure implying dry conditions. Deposition of silt under fluctuating cold climates in the Middle Weichselian continued until a second gap in the record at c . 40 kyr BP. The lake basin started to fill up again around 18 kyr BP.     

Late Pleistocene fluvial dynamics in the Hochrhein Valley and in the Upper Rhine Graben: chronological frame

During the Pleistocene, the Rhine glacier system acted as a major south–north erosion and transport medium from the Swiss Alps into the Upper Rhine Graben, which has been the main sediment sink forming low angle debris fans. Only some aggradation resulted in the formation of terraces. Optically stimulated luminescence (OSL) and radiocarbon dating have been applied to set up a more reliable chronological frame of Late Pleistocene and Holocene fluvial activity in the western Hochrhein Valley and in the southern part of the Upper Rhine Graben. The stratigraphically oldest deposits exposed, a braided-river facies, yielded OSL age estimates ranging from 59.6 ± 6.2 to 33.1 ± 3.0 ka. The data set does not enable to distinguish between a linear age increase triggered by a continuous autocyclical aggradation or two (or more) age clusters, for example around 35 ka and around 55 ka, triggered by climate change, including stadial and interstadial periods (sensu Dansgaard–Oeschger cycles). The braided river facies is discontinuously (hiatus) covered by coarse-grained gravel-rich sediments deposited most likely during a single event or short-time period of major melt water discharge postdating the Last Glacial Maximum. OSL age estimates of fluvial and aeolian sediments from the above coarse-grained sediment layer are between 16.4 ± 0.8 and 10.6 ± 0.5 ka, and make a correlation with the Late Glacial period very likely. The youngest fluvial aggradation period correlates to the beginning of the Little Ice Age, as confirmed by OSL and radiocarbon ages.     

OSL dating of the Middle Palaeolithic Hotel California site,Sierra de Atapuerca,north‐central Spain

In this study we present optically stimulated luminescence (OSL) dating results obtained at one of the most important open‐air Middle Palaeolithic sites in the Sierra de Atapuerca foothills – Hotel California. We also assess the possibility of obtaining extended‐range OSL chronologies for a nearby Middle Pleistocene fluvial deposit using several novel methods, namely OSL dating of individual quartz ‘supergrains’, multi‐grain aliquot thermally transferred OSL (TT‐OSL) dating and the first application of a single‐grain TT‐OSL dating procedure. Four single‐grain OSL ages constrain the Middle Palaeolithic occupation of Hotel California to between 71±6 and 48±3 ka. The Hotel California single‐grain equivalent dose (D_e) distributions are highly overdispersed and contain several dose populations, which are probably attributable to post‐depositional sediment mixing, partial bleaching and intrinsic scatter. The reliability of multi‐grain aliquot OSL dating is compromised by the complex underlying D_e dispersion affecting these samples, as well as by biasing multi‐grain averaging effects. Extended‐range OSL and TT‐OSL chronologies for the nearby Pico River terrace are consistent with each other and with broad independent age control. These experimental approaches yield a weighted average age of 348±16 ka for terrace T_A9 of the Arlanzón River sequence. Our results highlight the benefits of comparing ages obtained using several OSL methodologies to improve the robustness of luminescence chronologies. They also demonstrate the potential that single‐grain OSL techniques offer for establishing improved age constraints on the many other Middle Palaeolithic sites found at Atapuerca and elsewhere across north‐central Spain.     

OSL and TL dating of buried podsols and overlying sands in Ostrobothnia,western Finland

In Ostrobothnia, western Finland, buried fossil soils have been recognised in a number of places in the sandy sediments that occur between glaciofluvial deposits and overlying till. Samples from the soil horizons as well as below and above them were taken for optically stimulated luminescence (OSL) dating. The same sites were also sampled for thermoluminescence (TL) dating. Altogether five TL dates and seventeen OSL dates were obtained. The OSL dates can be grouped into two age classes, (i) 120-163 ka and (ii) 76-106 ka, whereas all TL dates are of the order 135-155 ka. A comparison between the results obtained from the two dating methods shows that OSL dates are generally younger than the TL dates for the same sample. The discrepancy may arise partly from problems of setting a correct residual level in TL dating. If this is the case then the TL dates may indicate an upper limit for the true age. The results support the geological interpretation that the fossil soils were formed during the last interglacial, that the soil-forming processes possibly also continued during the first Early Weichselian stadial and interstadial (Brørup sensu lato), and that in general the till-covered glaciofluvial sequences, interpreted as eskers in Ostrobothnia, were deposited during the Saalian or Early Weichselian deglaciation.     

Late Pleistocene carbonate aeolianites on Mallorca, Western Mediterranean: a luminescence chronology

Coastal outcrops of Upper Pleistocene deposits in north-eastern Mallorca (Balearic Islands, Spain) have been examined and a chronological framework established using Optically Stimulated Luminescence (OSL) dating. The outcrops record a complex interaction between aeolian, colluvial and alluvial fan deposition that result in a variable stratigraphical architecture. Dating and facies analysis make it possible to identify four aeolian activity episodes during MIS 5c/b, 4 and 3, and also add to the understanding of the environmental history of north-eastern Mallorca over the last 100 ka. The new data suggest enhanced aeolian transport and dune formation during cold climatic intervals when sea level was low, sediment supply (exposed marine carbonate sediment) was high, winter windiness was high, and vegetation on coastal plains at a minimum.     

The detrital record of orogenesis: A review of approaches and techniques used in the Himalayan sedimentary basins

The sediment archive, of material eroded from an active tectonic region and stored in adjacent basins, can provide a valuable record of hinterland tectonism especially when information in the source region itself is obscured by later metamorphism or removed by tectonism or erosion. Using the sediment record to document tectonism is a well established approach, but more recently there has been a burgeoning of the number of isotopic techniques which can be applied to detrital material, in particular single-grain analyses. Thus the scope for application of detrital studies to a number of different tectonic problems has widened considerably. In this review, the example of sediments eroded from the Himalayan orogen and preserved in the suture zone basin, foreland basin, remnant ocean basins and deep sea fans is used to illustrate the approach. Techniques as diverse as petrography, heavy mineral, XRF and Sr–Nd studies; single grain dating by Ar–Ar, U–Pb and fission track methodologies; and single grain Sm–Nd and Pb isotopic analyses, are described. The paper documents how the sediment record can be used to determine the thermal and tectonic evolution of the orogen, constrain mechanisms of continental deformation, exhumation rates and palaeodrainage.     

标准生长曲线法在华南沿海老红砂石英光释光测年中的适用性*

如何快速准确地建立老红砂剖面年代学标尺或区域年代学框架,是在实践中有待解决的问题。而标准生长曲线法(SGC)在减少样品测试时间、提高测年仪器的测试效率方面具有独特的优势,因此在内陆黄土及沙漠沉积年代测定中得到了广泛应用。在福建和海南海岸带老红砂分布区采集了4个剖面的测年样品共计20个,应用单片再生剂量法(SAR)及SGC法进行定年研究。结果表明: (1)福建和海南海岸带老红砂样品释光(OSL)信号均以快组分为主,在信号积分通道前0.64 s 快组分的信号占据总体信号的80%以上,适合使用SAR及SGC方法测年;其快、中组分光电离截面分别为: 福建老红砂2.62×10^-17 cm²和3.24×10^-18 cm²,海南老红砂2.66×10^-17 cm²和3.51×10^-18 cm²; 2个区域样品的IRSL(红外激发释光信号)/OSL信号比值表明,较老样品的红外释光信号明显高于较年轻的样品,这可能是受到长石包裹体的影响,但其比值均小于10%,符合SAR与SGC测试要求。 (2)SGC法在华南海岸地区老红砂OSL年代学研究中具有较好的适用性,不同样品之间的剂量生长曲线存在着相似的增长模式,可以建立标准生长曲线; 但福建与海南老红砂样品之间的标准生长曲线具有较大的差异,因此在较大区域范围内运用标准生曲线法应当谨慎小心。     

THE EVOLUTION OF SMALL LAKE BASINS IN THE GOBI DESERT IN MONGOLIA

In order to investigate pluvial lakes in the Gobi two places were selected for field studies: Khongoryn Els in South­ and Mongol Els in West­Mongolia. In the eastern and central parts of Khongoryn Els two small endorheic basins,Bayan Tukhem and Khongoryn Gol depressions were studied. Pluvial lake deposits and beach ridges both supposedly mid­Holocene in age give evidence of a 9m and a 15m deep freshwater lake,respectively. Today both depressions are nearly dried out and exposed to wind deflation. A different situation was found at Uujin Sair river valley which cuts through the dune field at its lowest and narrowest(3km)part. Here,a 22.5m thick fossil accumulation of at least 20 layers of fine sand(dune sand)alternating with silt(fluvial playa sediment)was exposed and OSL dated. 12 dates ranging between 14ka and 17ka reveal the accumulation as Late Glacial which correlates well with the aridity at that time reported for Central Asia by several authors. Interpreting the dates it seems obvious that the whole sediment was quickly deposited in a period of about 16ka,and shortly after dissected by the Uujin Sair during a similar short time due to increasing humidity of the climate. Another situation was found at the eastern rim of Mongol Els. Two rivers,Shurgiyn Gol and Zavran Gol are impinging here on the high dunes which have damed both rivers in the past. A younger,shallow lake existed during mid­Holocene(14C­dated to some 5.5ka)and a large,17m deep lake(14C－dated to some 39ka)probably during stage 4.Expected OSL dates will hopefully support this hypothesis. Anyhow,the palaeogeography of the dune field was different from today; it moved eastward daming the large river Shurgiyn Gol.     

Integrated chronological control on an archaeologically significant Pleistocene river terrace sequence: the Thames-Medway,eastern Essex,England

Late Middle Pleistocene Thames-Medway deposits in eastern Essex comprise both large expanses of Palaeolithic artefact-bearing river sands/gravels and deep channels infilled with thick sequences of fossiliferous fine-grained estuarine sediments that yield valuable palaeoenvironmental information. Until recently, chronological control on these deposits was limited to terrace stratigraphy and limited amino-acid racemisation (AAR) determinations. Recent developments in both this and optically stimulated luminescence (OSL) dating make them potentially powerful tools for improving the chronological control on such sequences. This paper reports new AAR analyses and initial OSL dating from the deposits in this region. These results will help with ongoing investigation of patterns of early human settlement.Using AAR, the attribution by previous workers of the interglacial channel deposits to both MIS 11 (Tillingham Clay) and MIS 9 (Rochford and Shoeburyness Clays) is reinforced. Where there are direct stratigraphic relationships between AAR and OSL as with the Cudmore Grove and Rochford Clays and associated gravels, they agree well. Where OSL dating is the only technique available, it seems to replicate well, but must be treated with caution since there are relatively few aliquots. It is suggested on the basis of this initial OSL dating that the gravel deposits date from MIS 8 (Rochford and Cudmore Grove Gravels) and potentially also MIS 6 (Dammer Wick and Barling Gravels). However, the archaeological evidence from the Barling Gravel and the suggested correlations between this sequence and upstream Thames terraces conflict with this latter age estimate and suggest that it may need more investigation.