热释光年代测定方法在鱼洞水库地区断层活动性研究中的应用

用作者研制的RS 81 1型热释光仪对云南昭通鱼洞水库地区两条断层的破碎带内发育的方解石脉进行了热释光年代测定和显微构造分析 .结果显示 :2条断层破碎带内发育 4期方解石脉 ,其中有 3期发生了变形 .F1 断层距今 5× 1 0 4 a以来 ,F2 断层距今 2 5× 1 0 4 a以来没有强烈活动的迹象 .断层泥中石英颗粒表面形态分析结果与热释光法相同 .     

EXPERIMENTAL STUDY ON DEFORMATION FABRICS OF QUARTZ AND CALCITE IN SHEAR ZONE

Frictional experiments of samples with quartz and calcite sandwich have been operated under certain confining pressures, strain rate and different temperatures. Samples deformed and undeformed have been studied by means of microscope, TEM, and U-Stage. On the basis of this, changes of deformation micro-structures and fabrics of quartz and calcite aggragates with temperatures under condition of simple shear have been analyzed     

方解石变形温度回零微观标志的实验研究和相关问题讨论

为了判断变形方解石温度回零程度，设计了一组岩石破裂实验，对含方解石灰岩样品进行不同温度下的固定围压实验，对原态固结破裂样品进行微观观测，提出不同回零状态的微观识别标志，从而为方解石变形年代测定值可靠性评价提供微观依据。最后对未达到回零温度的变形样品年代测定值的修正问题进行了探讨。     

DEFORMATION OF THE BRITTLE-PLASTIC TRANSITION ZONE AT THE POST-SEISMIC RELAXATION PERIOD: A CASE STUDY OF THE RED RIVER FAULT

The transition from microscopic brittle deformation to microscopic plastic deformation is called brittle-plastic transition, which is considered as a key layer for determining the limit of lower continental crust seismicity. The depth and deformation mechanism of the brittle-plastic transition zone is controlled mainly by temperature. Besides, the strain rate and fluid pore pressure also affect the transition during the different deformation stages at the seismic cycle. In this paper, microstructure observation of catalcastic samples collected from the Red River Fault was carried out using optical polarized microscopy and scanning electron microscopy. The morphology, microstructures of deformation characteristics, mineral composition, water-rock reaction, pressure solution, exsolution, crack healing in the samples were systematically observed. The mineral components quantitative analyses were examined using the EDS. Water-rock reaction and pressure solution were systematically observed under SEM. The fabric of the main minerals in the samples was measured using electron backscattered diffraction(EBSD). Based on these analyses, the deformation mode was setup for the brittle-plastic transition zone of the fault during the post-seismic relaxation period. Both brittle deformation and plastic deformation were developed in the cataclastic samples. EBSD data shows that the c axial fabrics of quartz present low-temperature plastic deformation characteristics. The feldspar deformed as cataclastic rock, and the micro-fracture in feldspar was healed by static recrystallized quartz and calcite veins. The calcite vein underwent plastic deformation, which represents the post-seismic relaxation deformation. Based on the analysis of deformation mechanism of cataclastic samples in brittle-plastic transition zone of the Red River Fault, and combined with previous studies, we concluded that the brittle fracture and fracture healing is the main deformation mode at brittle-plastic transition zone in the post-seismic relaxation. High stress and high strain rate at post-seismic relaxation lead to brittle fracture of high-strength minerals such as feldspar in rocks. Plastic deformation occurs in low-strength minerals such as quartz and mica. Under the fluid condition, micro-fractures were healed by quartz and calcite. The minerals such as quartz and calcite in the fracture transformed from static recrystallization to dynamic recrystallization with stress gradually accumulating. With fracture healing and stress accumulation, the fault strength gradually increases which could accumulate energy for the next earthquake.     

高温高压下石英方解石断层带的摩擦滑动性状

在不同的温度、压力条件下进行了含石英和方解石断层泥标本的摩擦实验。结果表明,石英断层带的摩擦强度对压力的响应直到400℃都很明显,对温度的响应在高温(高于400℃)时才明显;方解石断层带的摩擦强度对温度很敏感,对围压的响应只在低温(200℃)时才明显;随温度升高,石英和方解石断层带均由粘滑转变为稳滑,但前者的转换界限在400℃到500℃之间,而后者在200℃到300℃之间。显微观察表明,上述差异归因于其具体变形机制的差别。      

方解石脉ESR定年信号和测量条件的研究

方解石脉是与断裂构造相关并在基岩区断裂带中常见的物质。方解石脉的定年有时对研究基岩区断裂活动时代具有重要的意义。方解石脉ESR测年是目前采用的测年方法之一,但是对于方解石脉的ESR信号特征及其测量条件目前尚没有定论。文中研究样品采自云南洱海海东断裂带中。根据对样品的初步研究认为,方解石脉人工辐照时易产生不稳定的短寿命信号,在测量之前至少将其在室温条件下存放5d。天然方解石脉中一般具有多个ESR信号,其中g=2.0040和g=2.0023信号对吸收剂量具有良好的响应关系,可以用于测年。这两个信号的增长曲线表明至少在1500Gy剂量范围内呈线性增长。人工给定已知剂量方法表明,要获得可靠的古剂量,g=2.0040和g=2.0023的信号所选择的微波功率是不同的。对于g=2.0040信号,测量的微波功率应在0.8或2mW;而g=2.0023信号,微波功率应选择2或5mW     

根据变形岩石的显微构造特征探讨断层的活动性

本文是通过一条断层及其围岩物质的显微构造的对比研究来探讨断层活动性的尝试。配合热释光年代学方法的测定结果,表明该断层自更新世以来曾发生过多次新的活动,主断裂形成时的古应力大约为700巴左右     

Effects of light exposure on the TL dating of pottery

Bleaching experiments on Chinese pottery fine grains were conducted under sunlight and laboratory light conditions. It is found that the thermoluminescence (TL) at high temperatures can be bleached significantly, but no effects were observed on TL signals used for the pre-dose dating technique. It is concluded that the pre-dose dating technique can be applied to samples even after light exposures. Pottery samples of Tang Dynasty and New Stone Age were studied. Modifications to routine pre-dose dating technique are proposed with adding preheat procedures and using saturation exponential fitting for the sensitivity change data. The modified technique can extend the dating range to New Stone Age.     

海原断裂带刺儿沟剖面烘烤次生黄土的光释光测年及其地质意义

选择海原活动断裂带刺儿沟剖面2个烘烤次生黄土样品LEDL0588H和LEDL0365的细颗粒石英,采用改进后的单测片再生法(SAR)和简单多测片再生剂量法(SMAR)进行了一系列实验研究。2个样品细颗粒石英的光释光信号均以快速组分为主,其等效剂量(DE)的预热坪实验表明,在180～260℃的预热温度范围内均能获得基本一致的DE值。SAR法测量不同预热温度下的释光感量变化、剂量恢复实验和LN/TN比值的关系以及SMAR法测量中LN/TN比值与预热温度的关系的研究表明,文中所采用的流程能有效地校正测量过程中释光信号感量变化。2种方法均适用于采自不同层位的2个烘烤样品细颗粒石英的OSL测年,并获得了非常接近的OSL年龄。2个样品最后一次被烘烤的时间可能代表的是同一时期的人类活动     

Retention of cosmogenic 3He in calcite

Cosmogenic ³He can be used to date a wide range of mineral phases because it is produced from all target elements and can be readily measured above atmospheric contamination. Calcite is a particularly attractive target mineral due to its natural abundance, large crystal size (>1 mm), and low He closure temperature (<70 °C), which limit non-cosmogenic ³He components (Copeland et al., 2007). However, several recent studies have shown that some calcite may not be retentive to helium, even under surface temperatures (Cros et al., 2014; Copeland et al., 2007). This study thus explores ³He retention and production in natural calcite samples at four different sites. Samples from two high elevation sites appear retentive to ³He over 10 kyr timescales, whereas two additional sites clearly suffer from diffusive loss of ³He. Step-degassing experiments suggest that diffusion in calcite is controlled by multiple diffusion domains, with an apparent activation energy of 25–27 kcal mol⁻¹. Although minor ³He loss is expected from the smallest diffusion domains, the observed kinetics cannot explain the poor retention at all sites. We thus propose that opaque (non-transparent) calcite may be more retentive due to the presence of imperfections in the crystal lattice. We conclude that ³He dating of calcite shows promise in some settings. However, because retention depends on crystallographic variability it must be evaluated on a case-by-case basis until robust criteria for retention can be identified.     

天然麻粒岩高温流变实验研究

本实验在气体介质三轴高温流变仪上,采用怀安瓦窑口麻粒岩,在温度900～1200℃、围压300 MPa、应变速率10~(-4)～10~(-6)/s条件下,开展高温流变实验.实验样品麻粒岩由斜长石(52%)、单斜辉石和斜方辉石(40%)、石英(3%)、磁铁矿和钛铁矿(5%)组成,矿物平均粒度为:斜长石294μm、单斜辉石和斜方辉石282μm、石英97μm、磁铁矿和钛铁矿109μm.利用傅里叶变换红外光谱仪分析获得变形后样品的水含量约为0.17±0.05wt%.实验样品的强度随温度升高而降低,随应变速率降低而降低.基于力学数据,采用稳态流变方程,获得实验样品在900～1000℃时的应力指数为8.1～12.9,在1050～1150℃时的应力指数为4.8～5.8,平均值5.2.应力指数随着温度升高而降低.显微结构和成分分析表明,在900℃时麻粒岩出现矿物压扁与定向拉长特征,样品以位错滑移和微破裂变形为主;在950～1000℃时,麻粒岩样品中颗粒边界变得圆滑,表现出位错攀移特征,辉石和磁铁矿边缘出现微量熔体;在1050～1200℃时麻粒岩出现部分熔融,而且随着温度和实验时间(应变)增加,熔体含量增加,熔体结晶出微粒斜长石、辉石和橄榄石,部分辉石通过固体反应生成橄榄石.颗粒边界熔体和矿物反应促进了扩散作用,导致位错攀移和熔体引起的扩散蠕变共同控制了麻粒岩的高温流变.     

摩擦滑动对石英和方解石热释光性质的影响及其地震地质意义

通过高温高压实验及热释光测量建立了石英在100MPa和方解石在30MPa围压下剩余热释光强度随温度的变化曲线,以此为据,通过三轴摩擦实验前后样品的热释光测量,研究了相应围压、不同错动速率下摩擦滑动对石英和方解石剩余热释光强度的影响及其反映的温度变化。在此基础上,根据已有理论结果和实际资料,对利用热释光方法断代及推测断层活动方式的可能性等问题进行了讨论     

Interaction of cataclasis and pressure solution in a low-temperature carbonate shear zone

The mineralogical and elemental variations across the main shear zone of the Saltville thrust at Sharp Gap in Knoxville, Tennessee, U.S.A., were studied in a suite of deformed and undefromed carbonate rock samples using X-ray diffraction and electron microprobe methods. An examination of the samples for deformation effects at mesoscopic scale and under the optical microscope reveals familiar cataclastic deformation features including foliated cataclasites and microbreccias occurring in a well-defined, 1–2 m wide zone of intense deformation, plus evidence of hydrofracturing and extensive syndeformational pressure solution. There exists a clear correlation between the observed cataclastic deformation and mineral and elemental distribution which we interpret to result from a deformation-induced dolomite to calcite transformation in the shear zone. The transformation has resulted in removal of Mg from the shear zone, selective deposition of calcite as an intergranular cement in cataclasite/microbreccia units and a relative increase in the concentration of detrital quartz and feldspars.The compositional difference between the shear zone and wall rocks is explained in connection with cataclastic deformation features in terms of a model in which a dual pressure-solution/cataclastic flow mechanism leads to a gradual cementation-hardening of segments of the shear zone. Instabilities could occur via permeability reduction and increased pore pressure within these segments. Hydrofracturing of the hardened segments along with high strain rate reordering of the shear zone materials reset the ruptured zone back to the dual deformation mechanism regime. As a long-term effect, the compositional transformation of the shear zone is expected to prolong periods of creep and cause smaller coseismic stress drops since under the imposed conditions calcite is more ductile and soluble than dolomite.     

Luminescence dating of the last earthquake of the Sabzevar thrust fault, NE Iran

Iran is one of the world's most tectonically active regions, yet dating past earthquakes for neotectonic studies has been limited. One of the main reasons for this is that organic material suitable for radiocarbon dating of deformed sediments is rare. We investigate the use of infrared stimulated luminescence (IRSL) from coarse-grained feldspars to date colluvial deposits associated with the Sabzevar thrust fault in northeastern Iran. The single-aliquot regenerative (SAR) dose measurement procedure was used for this study. The current study investigates monitoring and correcting for sensitivity changes, recovering a known laboratory dose and equivalent dose estimation using three SAR IRSL methods. It is shown that SAR has recovered a given laboratory dose using a range of preheat temperatures but D_e determination of natural samples requires its own preheat plateaus for two of these SAR methods. The SAR IRSL method provided an age of 1.7±0.3 ka for colluvium, predating the last earthquake event on the Sabzevar fault. This result suggests that this fault is likely to be responsible for an earthquake that destroyed Sabzevar city in AD 1052.     

EXPERIMENTAL STUDY ON THE EFFECT OF WATER ON THE STRENGTH AND DEFORMATION MECHANISM OF CARRARA MARBLE AT HIGH TEMPERATURE

We performed deformation experiments using Carrara marble in dry and wet conditions under temperature of 400~700℃ and confining pressure 300MPa with two different strain rates. Water contents of deformed samples were measured using FTIR spectroscopy. The microstructure and deformation mechanisms of samples were observed under optical microscopy, scanning electron microscopy and energy spectroscopy analysis. The mechanical data show that samples display strain hardening at 400℃, and transition to steady creep at temperature from 500~700℃. The strength of marble reduced gradually with elevated temperatures or decreased strain rate. However, water effect to the strength of the marble is significantly weak. Microstructures observed show that the deformation is cataclastic flow in dry samples, fracture and pressure solution in wet samples at 400℃. Samples underwent brittle-plastic transition at 500℃. Dislocation glide is major deformation mechanism for dry samples at 600℃. Dislocation climb and dynamic recrystallization are major deformation mechanism for wet samples at 600℃ and for all wet samples and dry samples at 700℃. Lower strain rate and higher water content could promote the process of pressure solution and diffusion as well as dynamic recrystallization.     

Testing the use of feldspars for optical dating of hurricane overwash deposits

The geological record preserved in coastal salt marshes provides an opportunity to determine past hurricane activity during the Late Holocene in New England, USA. High precision dating is important to correlate overwash sand layers associated with hurricane strikes between different sites along the coastline. Three different optical dating methods have been tested and compared with independent age control; i) optically stimulated luminescence from quartz, ii) infrared stimulated luminescence from K-feldspar, and iii) a subtraction method.Quartz and K-feldspar dating results for three samples in a core from Round Hill Beach Marsh are in stratigraphic order and they are consistent within errors with radiocarbon ages and with each other. Subtraction dating results agreed with the quartz and K-feldspar ages for two of the three samples, but the subtraction age of the youngest sample gave an age underestimate. Replicate equivalent dose values from quartz showed a larger variation than those from feldspars, and this resulted in larger errors for the quartz and subtraction ages than those based on feldspars. K-feldspar yields the most precise optical ages, but is complicated by the need to correct for anomalous fading. Both quartz and K-feldspar are suitable for optical dating of hurricane overwash deposits in New England.     

Development of the SAR TT-OSL procedure for dating Middle Pleistocene dune and shallow marine deposits along the southern Cape coast of South Africa

Optically stimulated luminescence (OSL) dating is now commonly used to estimate the depositional age of Quaternary landforms along the southern Cape coast of South Africa. Due to the early onset of dose saturation in the quartz-rich sediments from this region, determining the age of deposits much older than the last three glacio-eustatic sea-level high stands has been a challenge. In this study, we explored the feasibility of using the thermally-transferred OSL (TT-OSL) dating method to obtain ages for aeolian and shallow marine deposits at three different localities that hold promise to further illuminate the long and complex Late Quaternary sea-level history of this region. The bleachability and behaviour of both the recuperated OSL (ReOSL) and the basic-transferred OSL (BT-OSL) signals were investigated, and used as independent chronometers to infer (a) the degree of bleaching of the sediments and (b) the stability of the ReOSL signal for dating of older samples. We examined the sensitivity of both signals to varying preheat temperatures and further developed the single-aliquot regenerative-dose procedure for TT-OSL dating of our samples. To verify our procedures, and to understand some of the underlying mechanisms responsible for the problems we observed, modern analogues and known-age Marine Isotope Sub-stage (MIS) 5e samples from the same localities were also measured. The Middle Pleistocene deposits investigated in this study produced statistically consistent ReOSL and BT-OSL ages compatible with sea-level high stands during Marine Isotope Stage 11. This result is of considerable significance, as it may yield new insights into maximum sea-level heights during this period, which is widely considered an appropriate analogue for future environmental conditions.     

Dating of lower terrace sediments from the Middle Rhine area, Germany

Modern and known-age Pleistocene fluvial sediments were investigated by optical dating of quartz to test the suitability of the approach for dating deposits from the deeply incised Middle Rhine Valley. Samples from modern flood sediments revealed skewed distributions indicating different residual levels of equivalent dose (D_e) within the different aliquots. Nevertheless, a substantial number of aliquots from the modern deposits reflect D_e values close to zero. For the Pleistocene samples, optical ages are in general consistent with age control given by the presence of the Laacher See Tephra and radiocarbon dating. However, some samples overestimate the known age by a few thousand years when using the arithmetic mean. This is apparently explained by including aliquots in the determination of mean D_e where the optical signal was incompletely bleached at deposition. The most difficult issue in this context is identifying a suitable approach that can distinguish between the variability of D_e due to partial bleaching and microdosimetry. However, even when considering these limitations it appears that optical dating will by a quite suitable method to date Pleistocene sediments from such a complex fluvial environment, especially when focusing on a precision scale beyond a few thousand years.     

Ultrasonic elastic characteristics of five kinds of metamorphic deformed coals under room temperature and pressure conditions

The calibration of the elastic characteristics of deformed coals is essential for seismic inversion of such units, because the prediction of coal deformation is essential for both mining safety and methane production. Therefore, many samples of broken and mylonitic deformed coal were tested with ultrasonic waves in the laboratory. These samples came from four mining areas: the Huainan, Pingdingshan, Hebi and Jiaozuo coal mines, which present five different metamorphic ranks shown as cylinders striking across circular limits of steel. Under normal pressures and temperatures, ultrasonic P- and S-wave tests show that the velocities, quality factors, and elastic moduli of the deformed coals were greatly reduced compared with undeformed coals. Also, some correlation was found between the P- and S-wave velocities in the deformed coals. However, there is no evidence of linear correlations between velocity and density, velocity and quality factor, or the quality factors of P- and S-waves. Compared with the elastic characteristics of undeformed coals, such as P- and S-wave velocity ratios or Poisson’s ratio, those of deformed coals generally decrease and the P-wave quality factors are less than those of S-waves. Moreover, the analysis of the relationship between pore structure and elastic modulus shows a better correlation between the P- and S-wave velocities and effective porosity, pore volume and specific surface area. Also, there are similar relationships between the pore structure and the Young’s and shear moduli. However, there are no such correlations with other moduli. Correlations between these elastic moduli, pore structure, coal rank and density were not found for the various samples of deformed coals, which is consistent with only structural destruction occurring in the deformed coals with other physical properties remaining unchanged. The experimental results show that it is possible to predict the deformation of coals with multi-component seismic elastic inversion.     

Paleostress fields from calcite twins in the Pyeongan Supergroup, South Korea

Abstract   Paleostress fields of the Late Paleozoic to Early Mesozoic Pyeongan Supergroup that is distributed along the northeastern part of the Ogcheon Belt in South Korea were investigated using the calcite strain gauge (CSG) technique. Combining the results of this study with those of other studies investigating the relationship between twin strain, twin density and width, which are used as indicators of deformation conditions in the natural low-temperature deformation of limestone, it was estimated that calcite twins in the study area were probably formed at temperatures lower than 170°C. From two samples, two different principal paleostress directions were inferred from calcite twins, while only one direction was inferred from two other samples. This result suggests that deformation occurred during two or more different tectonic events in the Pyeongan Supergroup during the Mesozoic era. The maximum shortening axis was oriented in two directions, northeast–southwest and northwest–southeast, respectively, which coincide well with the paleostress directions inferred from the stress inversion for many fault sets. Combining the results of the paleostress analysis from this and other studies, we hypothesize that the directions of the maximum shortening axis in the Pyeongan Supergroup changed from northeast–southwest during the pre-Daebo orogeny period (Late Triassic period) to northwest–southeast during the syn-Daebo orogeny period (Early Jurassic to Early Cretaceous period) in the Mesozoic era.