L'évolution séculaire des températures de surface de la mer Méditerranée (1856–2000)

The mean sea surface temperature anomalies (SSTA) of the Mediterranean Sea during the past 150 years (1856–2000) are analysed. The first empirical orthogonal function (EOF) of the covariance matrix of the SSTA explains more than 45% of the variance, suggesting that the temporal variation of the Mediterranean Sea is largely in phase over the whole basin. The mean variability of Mediterranean SSTA from 1856 to 2000 superposes a main irregular oscillation (period of 60–70 years and mean amplitude of 0.4–0.5 °C) and a weak long-term positive trend (equivalent to an increase of +0.1 °C per century). The last warm phase, which is strongest in the western basin, is not warmer than the decade 1935–1945 or the ending part of the 1960s. The mean temporal evolution of the North Hemisphere is close to the variation of the Mediterranean Sea, except that the long-term increase is more intense in the North Hemisphere. To cite this article: V. Moron, C. R. Geoscience 335 (2003).     

Impacts « multi-échelle » d'un échange (Mg,Ca)–Pb et ses conséquences sur l'augmentation de la perméabilité d'une bentonite

The article addresses the structural effects of solutions of lead nitrate on a suspended or compacted bentonite. A permeability increase is observed on compacted clay. Investigating the composition of output solution, using X-Rays Diffusion at Small Angles and Scanning Electron Microscopy, this permeability increase is explained from structural variations at nanometric (reduction of particle size) and micrometric scales (microfissuration of aggregates). To cite this article: N. Jozja et al., C. R. Geoscience 335 (2003).     

Analyse isotopique de l'air piégé dans la glace pour quantifier les variations de température

Isotopic measurements in polar ice core have shown a succession of rapid warming periods during the last glacial period over Greenland. However, this method underestimates the surface temperature variations. A new method based on gas thermal diffusion in the firn manages to quantify surface temperature variations through associated isotopic fractionations. We developed a method to extract air from the ice and to perform isotopic measurements to reduce analytical uncertainties to 0.006 and 0.020$\text{‰}$ for δ¹⁵N and δ⁴⁰Ar. It led to a 16±1.5 °C surface temperature variation during a rapid warming ($\text{?70}\text{000}$ yr). To cite this article: A. Landais et al., C. R. Geoscience 336 (2004).     

Détection de carrières souterraines par sismique haute résolution à Annet-sur-Marne (France)Underground cavities detection by using high resolution seismics at Annet-sur-Marne (France)

Seismic methods were tested to detect underground cavities in the surroundings of Annet-sur-Marne (Seine-et-Marne, France). Cavities are located in three Ludian gypsum layers, between 30 and 80 m in depth. A high resolution seismic profile 450 m long was carried out so that the first third and the other part are respectively above non-exploited and exploited areas. Data processing highlights a series of reflections related to the marl–gypsum interfaces in the non-exploited area, while these reflections disappear in the exploited area. With the help of numerical simulations, this feature is interpreted as a disorganisation of wave fronts reflected on interfaces because of the presence of cavities. To cite this article: G. Grandjean et al., C. R. Geoscience 334 (2002) 441–447.     

High-pressure,low-temperature metamorphism in Alpujarride Units of southeastern Betics (Spain)Métamorphisme de haute pression et basse température dans les unités Alpujarrides du Sud-Est de la cordillère Bétique (Espagne)

We present the first occurrences of high-pressure, low-temperature ferro-magnesiocarpholite-bearing mineral assemblages associated to quartz segregations in the Alpujarride units of southeastern Betics (Sierra de Almagro, Sierra de los Pinos and Sierra Cabrera). Thermobarometric results show that the carpholite-bearing rocks underwent the same P–T conditions in the three outcrops, i.e. 8–10 kbar, 350–400 °C. Metamorphic and structural data allow us to conclude that these rocks belong to the same Alpujarride unit. In the Sierra de Almagro, tectonic units with carpholite-bearing rocks overlie low-pressure, low-temperature Alpujarride units, then forming a stack with an inverted tectono-metamorphic sequence, as observed in the central and western part of the Alpujarride complex. The preservation of carpholite-bearing assemblages in these rocks implies that no significant temperature increase occurred during the exhumation history. To cite this article: G. Booth-Rea et al., C. R. Geoscience 334 (2002) 857–865.     

Un nouveau point de départ pour l'histoire de l'Atlantique central

The first oceanic crust in the central Atlantic is usually thought to have a Middle Jurassic age. The new interpretation of the two key parameters, the African homologue of the East Coast Magnetic Anomaly and the situation of the Triassic salt basin of Morocco and Novia Scotia, shows that this age was underestimated by about 20 Ma. In our kinematic reconstruction, the first oceanic crust begins at the Late Sinemurian. This difference in age is crucial for the evolution of those margins and we discuss here its consequences. To cite this article: M. Sahabi et al., C. R. Geoscience 336 (2004).     

Rôle du fluor dans la formation des gisements d'émeraude de Mananjary (Est de Madagascar)

The Mananjary emerald deposits are hosted in phlogopite-rich rocks formed through metasomatic alteration of meta-ultrabasites (hornblendites) at about 500 °C and 2 kbar due to infiltration of fluoride-rich fluids. A thermodynamic model explains the role of fluoride-complexation in the transport of Be and points to co-precipitation of F-phlogopite as the cause of beryl deposition. To cite this article: B. Moine et al., C. R. Geoscience 336 (2004).     

Modelling diffusion in a heterogeneous rock matrix with a time-domain Lagrangian method and an inversion procedureModélisation de la diffusion dans une matrice rocheuse hétérogène par une méthode lagrangienne dans le domaine des temps et une procédure d'inversion

A Lagrangian method in time domain is proposed to solve transport by diffusion over large grids such as those extracted from autoradiographs of rock samples. The method is rapid and well suited to simulate out-diffusion experiments in a heterogeneous rock matrix. By coupling with a Gauss–Newton optimiser, it is possible to identify automatically the diffusion coefficients of porous areas in the matrix. This offers a more comprehensive view of a potential transport of contaminants, e.g., after a leak from an underground repository site. To cite this article: F. Delay et al., C. R. Geoscience 334 (2002) 967–973.     

Un « point chaud » sous le système du Rift syrien : données pétrologiques complémentaires sur les enclaves du volcanisme récent

Ultrabasic xenoliths (pyroxenites, lherzolites, harzburgites) in recent (Neogene–Quaternary) volcanoes have been studied in three localities within Syria: Jubates (North), Mhailbeh (Center), Tel Thannoun (South). P–T conditions of mineral equilibration have been estimated by pyroxene thermometry (temperature) and maximum CO₂ density in primary inclusions (minimum pressure). Pyroxenites equilibrate at significantly higher conditions (T about 1200 °C, P>15 kbar) than lherzolites and harzburgites (900<T<1100 °C, P between 10 and 15 kbar). All are within the spinel lherzolite field, whereas Cretaceous xenoliths originate within the garnet lherzolite field. To cite this article: A. Bilal, F. Sheleh, C. R. Geoscience 336 (2004).     

UPb emplacement and 40Ar/39Ar cooling ages of the eastern Mont-Louis granite massif (Eastern Pyrenees,France)

Zircon UPb dating by SIMS of the Mont-Louis granite yields an age of 305±5 Ma, intrepreted to reflect the igneous emplacement age of the massif. It is in agreement with the Hercynian syntectonic character of Pyrenees granite. ⁴⁰Ar/³⁹Ar on hornblende, biotite and K-feldspar permit, to estimate the massif cooling. A rapid temperature decrease (≈30 °C/Ma) is revealed from Westphalian to Late Stephanian, coeval with the emplacement of a laccolithe in the upper crust. Then, the cooling rate decreases to ≈1 °C/Ma. This would be consistent with a long time residence for the pluton from the Late Palaeozoic to the Early Cainozoic at 6–8 km depth. To cite this article: O. Maurel et al., C. R. Geoscience 336 (2004).     

How reliable are growth strata in interpreting short-term (10 s to 100 s ka) growth structures kinematics?

High-frequency stratigraphic cycles (10 s to 100 s ka) often show, at a specific location, an alternation of ‘dynamic’ (proximal-energetic), and ‘non-dynamic’ (distal-pelagic) processes with time. When sedimentation is syn-deformation, these processes tend respectively to fill-up tectonically-induced topography or to drape it. As a consequence, growth strata are alternatively thickened and isopach across the growth structure. High-resolution kinematic studies of growth structures (folds and faults), which assume that sedimentation always fills up topographies (‘fill-to-the-top’ model), may therefore mistake sedimentary cyclicity for tectonic cyclicity. We address this problem with one example of growth anticline in the Spanish Pyrenees, and we discuss the fill-to-the-top model. To cite this article: S. Castelltort et al., C. R. Geoscience 336 (2004).     

Argiles et zéolites dans l'altération d'un volcan bouclier en milieu tropical (Le Piton des Neiges,La Réunion)

The drilling of a gallery through the Roche-Écrite massif (Reunion Island) allowed to sample the old formations of the ‘Piton des Neiges’ volcano. The mineralogical study of the alteration products of the formations showed significant variations of the zeolites/clay minerals ratio depending on the location of the rocks in the volcano. The abundance of zeolites in the formation near the surface hydrographic network or the underground water drainage system seems to be due to the physicochemical processes favouring zeolites in more open systems in their competition with secondary clays. To cite this article: L. Bret et al., C. R. Geoscience 335 (2003).     

Oxydation expérimentale de Fe-tourmalines et corrélation avec une déprotonation des groupes hydroxyleAnnealing in oxidising conditions of Fe-tourmalines and correlated deprotonation of OH groups

Annealing at 400?T?600 °C (40?P?60 MPa and HM buffer-controlled f(O₂)) of tourmalines synthesised at the same T and P with NNO buffer induces an oxidation of Fe²⁺ into Fe³⁺ in some Y sites only (Mössbauer Spectroscopy data). Annealing in the same conditions of natural tourmalines is consistent with these results. FTIR spectroscopy shows that oxidation of Fe²⁺ into Fe³⁺ is charge-balanced by deprotonation of the external OH₍₃₎ groups. To cite this article: Y. Fuchs et al., C. R. Geoscience 334 (2002) 245–249.     

Effects of Young's modulus on fault displacement

Elastic crack models predict a linear relationship between displacement (u) and rupture (trace) length (L) during slip in a fault zone. Attempts to find universal-scaling laws for L/u, however, have generally failed. Here I propose that these attempts have failed because they do not take into account the changes in the mechanical properties, in particular Young's modulus (stiffness), of the fault zone as it evolves. I propose that Young's modulus affects fault displacement both spatially and temporally: spatially when the trace of a fault at a given time dissects host rocks of different stiffnesses, and temporally when the stiffness of the fault zone itself changes. During the evolution of an active fault zone, the effective Young's modulus of its damage zone and fault core normally decreases, and so does the L/u ratio of the fault. By contrast, during inactive periods sealing and healing of the damage zone and core may increase the stiffness, hence the L/u ratio in subsequent slips. This model predicts that not only will the scaling of L/u within a given fault population vary in space and time, but also that of individual faults. To cite this article: A. Gudmundsson, C. R. Geoscience 336 (2004).     

Le volcanisme cambrien du Maroc central : implications géodynamiques

In southeastern Central Morocco, the Bou-Acila volcanic complex is considered of Cambrian age. In spite of low-grade metamorphic effect, initial volcanic texture and mineralogy can be recognized and volcanic rocks are dominated by dolerites and porphyric dolerites. The initial mineralogy is composed of plagioclases, pyroxenes and dark minerals. A secondary mineral assemblage is composed of albite, epidote, chlorite and calcite. According to their immobile elements compositions, the southeastern central Morocco metavolcanites are of within-plate continental tholeiites. This volcanism and those recognized in many other areas in Morocco confirm a Cambrian extensive episode within the Gondwana supercontinent. To cite this article: H. Ouali et al., C. R. Geoscience 335 (2003).To cite this article: H. Ouali et al., C. R. Geoscience 335 (2003).     

Electrochemical properties of solids at the aqueous–solid interface and heterogeneity of surfacePropriétés électrochimiques des solides à l'interface solide–eau et hétérogénéité de surface

In aqueous medium, solid surfaces are in general electrically charged. The induced electrical and chemical properties govern numerous phenomena, such as colloidal stability or transport of pollutants. Numerous industrial processes make use of these properties. The understanding of the underlying mechanisms at molecular level is of high importance in order to predict and master the behaviour of dispersed matter in the environment and in industrial processes. The present paper shows the evolution of theories and experimental methods, their recent developments and applications. To cite this article: F. Thomas et al., C. R. Geoscience 334 (2002) 633–648.     

Erosion of particulate inorganic and organic matter in the Gulf of LionÉrosion de la matière particulaire inorganique et organique dans le golfe du Lion

Critical shear stress of erosion and erosion rate of particulate inorganic and organic matter were measured in a flume at three muddy stations. Critical shear stress ranged between 0.022 and $\text{0.038 }\text{N}\text{m}{}^{\mathrm{?2}}$. At the deepest site, annual erosion of particulate organic nitrogen and phosphorus could exceed net deposition fluxes, showing the importance of erosion processes. Erosion may modify total system mineralisation rates by introducing sedimentary particulate organic matter into the water column and thus this process must be taken into account in studies of biogeochemical cycles. To cite this article: E. Schaaff et al., C. R. Geoscience 334 (2002) 1071–1077.     

Dévitrification et altération supergène d'une rhyolite (bassin du Paraná, Brésil) : mécanismes et bilans géochimiques

The weathering of a rhyolitic lava flow of the Paraná Basin (Brazil) developed, on few centimeters only, simplified petrographic features. The initial meteoric fluid pass-way is marked by celadonite-to-nontronite transformation. The second step is the complete dissolution of plagioclases, and the last one is the massive precipitation of halloysite. The geochemical mass balances according to the alteration features demonstrate the progressive leaching of major and trace elements fractionated by plagioclases, glass and opaques, and the sorption of Cu>As>Sb in the halloysite matrix. To cite this article: M. Bernard et al., C. R. Geoscience 336 (2004).     

Radiogenic lead mobility in the Shea Creek unconformity-related uranium deposit (Saskatchewan,Canada): migration pathways and Pb loss quantification

The average Pb/U ratio of the Shea Creek unconformity-type uranium deposit has been estimated at 0.071±0.015. The calculation was performed on a volume enclosing the orebody to take into account the possible radiogenic lead migration within the ore zone. Despite this precaution, this ratio is significantly lower than the expected ratio (0.211) assuming a main U deposition around 1315 Ma, as suggested by previous UPb isotopic dating. Although part of the radiogenic lead can be trapped as galena within the orebody, about 60% of Pb have migrated more than 700 m away from the orebody, preferentially along the unconformity. To cite this article: P. Kister et al., C. R. Geoscience 336 (2004).     

Morphodynamique d'une dune sous-marine du détroit du pas de CalaisMorphodynamics of an undersea sandwave of the Dover Straits

This paper investigates the dynamics of sandwaves in relationship with tidal currents and weather conditions. The studied sandwaves are located in the Dover Straits and are covered by megaripples. These megaripples have migration speeds of $\text{1 }\text{m}\text{h}{}^{\mathrm{?1}}$ and slopes of 34°, suggesting the potential for avalanches to occur along the flanks of the sandwave. Tidal cycles without reversing currents were observed during stormy weather. Wind-induced currents lead to a unidirectional migration of megaripples and sandwaves. Well-defined areas without megaripples were observed and correlated with an increase in sandwave height. We propose interpretations for understanding sandwave saturation and migration. To cite this article: D. Idier et al., C. R. Geoscience 334 (2002) 1079–1085.