A borehole investigation of zircon radiation damage annealing

This contribution reports Raman radiation damage measurements of zircons from the Kontinentale Tiefbohrung, on the western border of the Bohemian Massif. The mean wavenumbers (ω₃) and widths (Γ₃) of the ν₃(SiO₄) Raman band are constant down to 3 km, decrease (ω₃) resp. increase (Γ₃) between 3 and 5 km, and are again constant between 5 and 7 km. Uniform high Γ₃ values associated with ω₃ values close to those of undamaged zircon between 5 and 7 km are interpreted as due to residual damage predating the exhumation of the Bohemian Massif. A superimposed post‐exhumation signal indicates full damage retention down to 3 km depth, partial annealing between 3 and 5 km, and zero retention at greater depth. An attempt to calculate radiation damage ages gives results of a meaningful order of magnitude but also exposes difficulties associated with dating basement samples with complex damage accumulation and annealing histories.     

Very high-pressure (>4 GPa) eclogite associated with the Moldanubian Zone garnet peridotite (Nové Dvory, Czech Republic)

Equilibrium pressure–temperature (P–T) conditions were estimated for kyanite‐bearing eclogite from Nové Dvory, Czech Republic, by using garnet–clinopyroxene thermometry and garnet–clinopyroxene–kyanite–coesite (or quartz) barometry. The estimated P–T conditions are 1050–1150 °C, 4.5–4.9 GPa, which are mostly the same as previously estimated values for garnet peridotite from Nové Dvory (～1100–1250 °C, 5–6 GPa). Such very high‐P conditions, which correspond to about 150‐km depth, have been obtained for some garnet peridotites in the Gföhl Unit of the Bohemian Massif, but pressure conditions of eclogites associated with the garnet peridotites have not been so well constrained. This is the first substantial finding of eclogite that gives such very high‐P conditions in the Gföhl Unit of the Bohemian Massif. The Gföhl Unit mainly consists of felsic granulite or migmatitic gneiss, but these rock types do not display high‐P (>2.5 GPa) evidence. It is unclear whether both the peridotite body and surrounding felsic rocks in the Gföhl Unit were buried to very deep levels, but at least some garnet peridotites and associated eclogites in the Gföhl Unit have ascended from about 150‐km depth.     

Lithosphere thermal structure at the eastern margin of the Bohemian Massif: a case petrological and geophysical study of the Nied?wied? amphibolite massif (SW Poland)

The crustal section beneath amphibolite Nied?wied? Massif (Fore-Sudetic Block in NE Bohemian Massif), modelled on the basis of geological and seismic data, is dominated by gneisses with subordinate granites (upper and middle crust) and melagabbros (lower crust). The geotherm was calculated based on the chemical analyses of the heat-producing elements in the rocks forming the crust and the measurements of their density and heat conductivity. The results were verified by heat flow calculations based on temperature measurements from 1,600?m deep well in the Nied?wied? Massif and by temperature–depth estimates in mantle xenoliths coming from the nearby ca. 4.5?My basanite plug in Lutynia. The paleoclimate-corrected heat flow in the Nied?wied? Massif is 69.5?mW?m^?2, and the mantle heat flow is 28?mW?m^?2. The mantle beneath the Massif was located marginally relative to the areas of intense Cenozoic thermal rejuvenation connected with alkaline volcanism. This results in geotherm which is representative for lithosphere parts located at the margins of zones of continental alkaline volcanism and at its waning stages. The lithosphere–asthenosphere boundary (LAB) beneath Nied?wied? is located between 90 and 100?km depth and supposedly the rheological change at LAB is not related to the appearance of melt.     

Azimuthal variation of Pg velocity in the Moldanubian, Czech Republic: observations based on a multi-azimuthal common-shot experiment

We study the azimuthal velocity variation of Pg waves in the Moldanubian, which is a crystalline segment within the Bohemian Massif in the Czech Republic. We use the data from a multi-azimuthal common-shot experiment performed as part of the ALP 2002 refraction experiment, complemented by profile refraction data from the CELEBRATION 2000 experiment. We analyze the travel times of waves recorded by 72 portable seismic stations deployed along two circles with radii of 35 and 45 km around a shot. The observed travel times display an azimuthal variation indicating anisotropy of 2%. The minimum and maximum velocity values are 5.83 and 5.95 km/s, respectively. The direction of the maximum velocity is N50°E. These values characterize horizontal anisotropy of the uppermost crust down to 3 km. The strength and orientation of uppermost crustal anisotropy in the Moldanubian is consistent with the overall upper crustal anisotropy in the entire Bohemian Massif. The high-velocity direction is roughly perpendicular to the present-day maximum compressive stress in the Bohemian Massif and Central Europe and coincides with the orientation of structures formed by the main Variscan tectonic events in the area. This indicates that the anisotropy is caused predominantly by alignment of textural elements and minerals in the rocks, which developed in early geological stages rather than by a preferred orientation of cracks or microcracks due to present-day stress. If the crack-induced anisotropy is present in the medium, then its strength should not exceed 1% and the cracks should be water saturated.     

Quantitative Expression of Heat Flow versus Tectonic Deformation in the China Continent： The Effects of Plastic-Flow Network and Stable Block

1 Introduction It has been understood in the study of terrestrial heat flow that the distribution of heat flow in the interior of continent is influenced by a large number of factors, involving heat sources (e.g. mantle heat flow, heat production of radioactive elements in the crust, magmatic activity, and heat production of tectonic deformation), heat transfercondition (e.g. thermal conductivity and thickness of media), groundwater circulation, etc. On the background of these factors it is pa…     

Meso‐Cenozoic thermal structure of the lithosphere in the Bohai Bay Basin,eastern North China Craton

Thermal structure of the lithosphere studies the partition of crustal and mantle heat flow of the continental area and is of significant importance to understand various energy‐related geodynamic processes. The study addresses the spatial distribution of the Meso‐Cenozoic mantle heat flow and Moho temperatures in the region of the Bohai Bay Basin based on the thermal history of the sedimentary basin, radioactive heat production rate and thickness of crustal layering. The results show that the ratio of the mantle and surface heat flow (q_m/q_s) experienced two peaks in the late period of the Early Cretaceous (q_m/q_s ~ 68%) and the Middle to Late Palaeogene (q_m/q_s ~ 75%), respectively. Based on the q_m/q_s ratio, the lithosphere of the Bohai Bay Basin transformed its thermal structure during the Meso‐Cenozoic, from the ‘cold mantle but hot crust’ stage in the Triassic–Jurassic to the ‘hot mantle but cold crust’ stage in the Cretaceous and Cenozoic. The Moho temperatures (T_m) during the Meso‐Cenozoic were also calculated by using the equation of one‐dimensional heat conduction, and the result shows that there exist three T_m peaks occurring in the late period of the Early Cretaceous (930–1080 °C), the Middle‐Late Palaeogene (820–890 °C) and the Early Neogene (770–810 °C). The q_m/q_s ratio began to exceed 50%, and the Moho temperature started to go over 700 °C from the Cretaceous to the present day, which revealed that the activity of the upper mantle in the eastern North China Craton (NCC) increased significantly accompanied by the strong crustal movement in the Cretaceous. The thermal structure revealed the Cretaceous to be a revolutionary period during the evolution of the Bohai Bay Basin, and this paper may provide some thermal evidence for the studies of the geodynamic evolution during the destruction of the NCC. Copyright © 2015 John Wiley & Sons, Ltd.     

Clasts of Variscan high-grade rocks within Upper Viséan conglomerates – constraints on exhumation history from petrology and U-Pb chronology

In this paper, U‐Pb zircon, monazite and rutile data for crystalline rocks deposited as clasts in the Upper Viséan conglomerates at the eastern margin of the Bohemian Massif are reported. U‐Pb data of spherical zircon from three different granulite clasts yielded a mean age of 339.0 ± 0.7 Ma (±2σ), while oval and spherical grains of another granulite pebble define a slightly younger date of 337.1 ± 1.1 Ma. These ages are interpreted as dating granulite facies metamorphism. Thermochronology and the derived pressure–temperature (P–T) path of the granulite pebbles reflect two‐stage exhumation of the granulites. Near‐to‐isothermal decompression from at least 44 km to mid‐crustal depths of around 22 km was followed by a near‐isobaric cooling stage based on reaction textures and geothermobarometry. Minimum average exhumation rate corresponds to 2.8–4.3 mm year^?1. The extensive medium‐pressure/high‐temperature overprint on granulite assemblages is dated by U‐Pb in monazite at c. 333 Ma. This thermal event probably has a close link to generation and emplacement of voluminous Moldanubian granites, including the cordierite granite present in clasts. This granite was emplaced at mid‐crustal levels at 331 ± 3 Ma (U‐Pb monazite), whereas the U‐Pb zircon ages record only a previous magmatic event at c. 378 Ma. Eclogites and garnet peridotites normally associated with high‐pressure granulites are absent in the clasts but exotic subvolcanic and volcanic members of the ultrapotassic igneous rock series (durbachites) of the Bohemian Massif have been found in the clasts. It is therefore assumed that the clasts deposited in the Upper Viséan conglomerates sampled a structurally higher tectonic unit than the one that corresponds to the present denudation level of the Moldanubicum of the Bohemian Massif. The strong medium‐temperature overprint on granulites dated at c. 333 Ma is attributed to the relatively small size of the entirely eroded bodies compared with the presently exposed granulites.     

Variations in the transient prograde geothermal gradient from chloritoid-staurolite equilibria: a case study from the Barrovian and Buchan-type domains in the Bohemian Massif

Thermodynamic modelling of metamorphic rocks increases the possibilities of deciphering prograde paths that provide important insights into early orogenic evolution. It is shown that the chloritoid–staurolite transition is not only an indicator of temperature on prograde P–T paths, but also a useful indicator of pressure. The approach is applied to the Moravo‐Silesian eastern external belt of the Bohemian Massif, where metamorphic zones range from biotite to staurolite‐sillimanite. In the staurolite zone, inclusions of chloritoid occur in garnet cores, while staurolite is included at garnet rims and is widespread in the matrix. Chloritoid X_Fe = 0.91 indicates transition to staurolite at 5 kbar and 550 °C and consequently, an early transient prograde geothermal gradient of 29 °C km^?1. The overall elevated thermal evolution is then reflected in the prograde transition of staurolite to sillimanite and in the achievement of peak temperature of 660 °C at a relatively low pressure of 6.5 kbar. To the south and to the west of the studied area, high‐grade metamorphic zones record a prograde path evolution from staurolite to kyanite and development of sillimanite on decompression. Transition of chloritoid to staurolite was reported in two places, with chloritoid X_Fe = 0.75–0.80, occurring at 8–10 kbar and 560–580 °C, and indicating a transient prograde geothermal gradient of 16–18 °C km^?1. These data show variable barric evolutions along strike and across the Moravo‐Silesian domain. Elevated prograde geothermal gradient coincides with areas of Devonian sedimentation and volcanism, and syn‐ to late Carboniferous intrusions. Therefore, we interpret it as a result of heat inherited from Devonian rifting, further fuelled by syntectonic Carboniferous intrusions.     

Strain coupling between upper mantle and lower crust: natural example from the Běstvina granulite body, Bohemian Massif

Strain patterns within mantle rocks and surrounding coarse‐grained felsic granulites from the Kutná Hora Crystalline Complex in the Variscan Bohemian Massif have been studied in order to assess their strain coupling. The studied rock association occurs within low‐strain domains surrounded by fine‐grained granulite and migmatite. The Doubrava peridotite contains closely spaced and steeply dipping layers of garnet clinopyroxenite, which are parallel to the NE–SW‐striking, high‐temperature foliation in nearby granulites, while the Úhrov peridotite lacks such layering. The Spa?ice eclogite is not associated with peridotite and shows upright folds of alternating coarse‐ and fine‐grained varieties bearing NE–SW‐striking axial planes. Electron back‐scattered diffraction measurements revealed full strain coupling between clinopyroxenites and coarse‐grained granulites in the S₁ fabric that is superposed on the S₀ fabric preserved in peridotites. The B‐type olivine lattice preferred orientation (LPO) characterizes the S₀ fabric in peridotites and its reworking is strongly controlled by the presence of macroscopic clinopyroxenite layering. The S₁ in clinopyroxenites and coarse‐grained granulites is associated with the LS‐type clinopyroxene LPO and prism <c> slip in quartz respectively. While the S₁ fabric in these rock types is accompanied invariably by a sub‐vertical stretching lineation, the S₁ fabric developed in reworked Úhrov peridotite is associated with strongly planar axial (010) type of olivine LPO. The peridotites with the S₀ fabric are interpreted to be relicts of a fore‐arc mantle wedge hydrated to a various extent above the Saxothuringian subduction zone. The prograde metamorphism recorded in peridotites and eclogites occurred presumably during mantle wedge flow and was reaching UHP conditions. Strain coupling in the S₁ fabric between clinopyroxenites and granulites at Doubrava and upright folding of eclogites at Spa?ice document a link between tectonic and magmatic processes during orogenic thickening, coeval with intrusions of the arc‐related calcalkaline suites of the Central Bohemian Plutonic Complex (c. 360–345 Ma). Juxtaposition of peridotites and granulites could be explained by a rheological heterogeneity connected to the development of clinopyroxenite layering in the upper mantle and a previously published model of a lithospheric‐scale transpressional arc system. It invokes vertical shearing along NE–SW trending, sub‐vertical foliations in the upper mantle that could have led to an emplacement of mantle bodies into the granulitized, orogenic root in the sub‐arc region. Clearly, such a transpressional arc system could represent an important pathway for an emplacement of deep‐seated rocks in the orogenic lower crust.     

Permo-Carboniferous volcanism in late Variscan continental basins of the Bohemian Massif (Czech Republic): geochemical characteristic

Extensive Permo-Carboniferous volcanism has been documented from the Bohemian Massif. The late Carboniferous volcanic episode started at the Duckmantian–Bolsovian boundary and continued intermittently until Westphalian D to Stephanian B producing mainly felsic and more rarely mafic volcanics in the Central Bohemian and the Sudetic basins. During the early Permian volcanic episode, after the intra-Stephanian hiatus, additional large volumes of felsic and mafic volcanics were extruded in the Sudetic basins. The volcanics of both episodes range from entirely subalkaline (calc-alkaline to tholeiitic) of convergent plate margin-like type to transitional and alkaline of within-plate character. A possible common magma could not be identified among the Carboniferous and Permian primitive magmas, but a common geochemical signature (enrichment in Th, U, REE and depletion in Nb, Sr, P, Ti) in the volcanic series of both episodes was recognized. On the other hand, volcanics of both episodes differ in intensities of Nb, Sr and P depletion and also, in part, in their isotope signatures. High ⁸⁷Sr/⁸⁶Sr (0.707–0.710) and low ε_Nd (−6.0 to −6.1) are characteristic of the Carboniferous mafic volcanics, whereas low ⁸⁷Sr/⁸⁶Sr (0.705–0.708) and higher ε_Nd ranging from −2.7 to −3.4 are typical of the Permian volcanics. Felsic volcanics of both episodes vary substantially in ⁸⁷Sr/⁸⁶Sr (0.705–0.762) and ε_Nd (−0.9 to −5.1). Different depths of magma source or heterogeneity of the Carboniferous and Permian mantle can be inferred from variation in some characteristic elements of the geochemical signature for volcanics in some basins. The Sr–Nd isotopic data with negative ε_Nd values confirm a significant crustal component in the volcanic rocks that may have been inherited from the upper mantle source and/or from assimilation of older crust during magmatic underplating and ascending of primary basic magma. Two different types of primary magma development and formation of a bimodal volcanic series have been recognized: (i) creation of a unique magma by assimilation fractional crystallization processes within shallow-level reservoirs (type Intra-Sudetic Basin) and (ii) generation and mixing of independent mafic and felsic magmas, the latter by partial melting of upper crustal material in a high-level chamber (type Krkonoše Piedmont Basin). A similar origin for the Permo-Carboniferous volcanics of the Bohemian Massif is obvious, however, their geochemical peculiarities in individual basins indicate evolution in separate crustal magma chambers.     

Orthit in den Gesteinen der Sonnblickgruppe (Hohe Tauern)

Summary Some types of Allanite (Orthite) are here described. They are found as assessory minerals in the rocks of the Hohe Tauern (penninic zone of the Eastern Alps) and in the hercynian foreland (Bohemian Massif). We distinguish Allanite I, II and III.The Allanite I (Hohe Tauern) is not isotropisized, but currently idiomorphic, with a xenomorphic rim of Clinozoisite. Where Allanite I is bordering Quartz or Potassium feldspar there is generally no rim of Clinozoisite. In the tectonites one observes granulated Allanite I and transformation of Allanite I to finegranied aggregates of Clinozoisite.Allanite II (Hohe Tauern) is found in intensely radioactive rocks. It is currently isotropisized, xenomorphic and surrounded by xenomorphic rims of Pistacite.Allanite III (Bohemian Massif) may be the oldest one and it is mostly isotropisized.The problems of the genesis and the age of crystallisation of Allanite during the history of our polymetamorphic rocks are shortly touched.

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Mit 11 Textabbildungen

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Herrn Prof. Dr.H. Leitmeier zum 80. Geburtstag gewidmet.     

Finite-element folds of similar geometry

Model folds of similar geometry have been produced by using the finite-element method and the constitutive relations of a layer of wet quartzite embedded in a marble matrix with an initially sinusoidal configuration and a 10° limb dip. The power law for steady-state flow of Yule Marble (Heard and Raleigh, 1972) is used for the matrix and our new law for Canyon Creek quartzite deformed in the presence of water is used for the layer. The equiv- alent viscosity of the wet quartzite is highly temperature-sensitive, giving rise to a strong temperature dependence of the quartzite: marble viscosity ratio which, at a strain rate of 10⁻¹⁴/sec, drops from 543 at 200° to 0.13 at 800°C. At 375°C (η_q/η_m = 10), concentric folds develop at all strains to 80% natural shortening and stress, finite strain and viscosity distributions are somewhat similar to those found previously. Raising the temperature to 550° C (η_q/η_m = 1), at any stage of prior amplification, causes the folds to flatten with increasing strain, accompanied by attenuation of limbs and thickening of hinges, leading to folds with similar geometries and isoclinal folds at extreme strains. The effects are more pronounced at higher temperatures and at 700° C (η_q/η_m = 0.3) limb attenuation is so severe as to give rise to unrealistic geometries. At temperatures below about 600° C (η_q/η_m = 2), similar folds do not form. It thus appears as if a viscosity contrast near unity is required to produce similar folds in rocks, under the conditions simulated and different temperature dependencies of viscosities of materials in layered sequences is one important means of reducing viscosity contrasts.     

Geochronology and geochemistry of eclogites from the Mariánské Lázně Complex,Czech Republic: Implications for Variscan orogenesis

The Mariánské Lázn complex (MLC) is located in the Bohemian Massif along the north-western margin of the Teplá-Barrandian microplate and consists of metagabbro, amphibolite and eclogite, with subordinate amounts of serpentinite, felsic gneiss and calcsilicate rocks. The MLC is interpreted as a metaophiolite complex that marks the suture zone between the Saxothuringian rocks to the north-west and the Teplá-Barrandian microplate to the south-east. Sm-Nd geochronology of garnet-omphacite pairs from two eclogite samples yields ages of 377±7, and 367±4 Ma. Samples of eclogite and amphibolite do not define a whole rock Sm-Nd isochron, even though there is a large range in Sm/Nd ratio, implying that the suite of samples may not be cogenetic. Eclogites do not have correlated _Nd values and initial ⁸⁷Sr/⁸⁶Sr ratios. Five of the eight eclogite samples have high _Nd values (+10.2 to +7.1) consistent with derivation from a MORB-like source, but variable ⁸⁷Sr/⁸⁶Sr ratios (0.7033 to 0.7059) which probably reflect hydrothermal seawater alteration. Three other eclogite samples have lower _Nd values (+ 5.4 to –0.8) and widely variable ⁸⁷Sr/⁸⁶Sr ratios (0.7033 to 0.7096). Such low _Nd values are inconsistent with derivation from a MORB, source and may reflect a subduction or oceanic island basalt component in their source. The MLC is an important petrotectonic element in the Bohemian Massif, providing evidence for Cambro-Ordovician formation of oceanic crust and interaction with seawater, Late Devonian (Frasnian-Famennian) high- and medium-pressure metamorphism related to closure of a Saxothuringian ocean basin, Early Carboniferous (Viséan) thrusting of the Teplá terrane over Saxothuringian rocks and Late Viséan extension.     

Heat flow in the Altai-Sayan Area: new data

Eleven new estimates of heat flow (q) from the southern Altai-Sayan Folded Area (ASFA) have provided update to the heat flow map of Gorny Altai. Measured heat flow in the area varies from 33 to 90 mW/m², with abnormal values of >70 mW/m^q at four sites. The anomalies may have a deep source only at the Aryskan site in the East Sayan (q = 77 mW/m²) while high heat flows of 75–90 mW/m² obtained for the Mesozoic Belokurikha and Kalguty plutons appear rather to result from high radiogenic heat production in granite, which adds a 25–30 W/m² radiogenic component to a deep component of 50–60 mW/m². The latter value is consistent with heat flow estimates derived from helium isotope ratios (54 mW/m² in both plutons). Heat flow variations at other sites are in the range from 33 to 60 mW/m². The new data support the earlier inferences of a generally low heat flow over most of ASFA (average of 45–50 mW/m²) and of a “cold” Cenozoic orogeny in the area (except for southeastern ASFA), possibly driven by shear stresses associated with India indentation into Eurasia.     

Crustal structure at the easternmost termination of the Variscan belt based on CELEBRATION 2000 and ALP 2002 data

The eastern margin of the Variscan belt in Europe comprises plate boundaries between continental blocks and terranes formed during different tectonic events. The crustal structure of that complicated area was studied using the data of the international refraction experiments CELEBRATION 2000 and ALP 2002. The seismic data were acquired along SW–NE oriented refraction and wide-angle reflection profiles CEL10 and ALP04 starting in the Eastern Alps, passing through the Moravo-Silesian zone of the Bohemian Massif and the Fore-Sudetic Monocline, and terminating in the TESZ in Poland. The data were interpreted by seismic tomographic inversion and by 2-D trial-and-error forward modelling of the P waves. Velocity models determine different types of the crust–mantle transition, reflecting variable crustal thickness and delimiting contacts of tectonic units in depth. In the Alpine area, few km thick LVZ with the Vp of 5.1 km s^− 1 dipping to the SW and outcropping at the surface represents the Molasse and Helvetic Flysch sediments overthrust by the Northern Calcareous Alps with higher velocities. In the Bohemian Massif, lower velocities in the range of 5.0–5.6 km s^− 1 down to a depth of 5 km might represent the SE termination of the Elbe Fault Zone. The Fore-Sudetic Monocline and the TESZ are covered by sediments with the velocities in the range of 3.6–5.5 km s^− 1 to the maximum depth of 15 km beneath the Mid-Polish Trough. The Moho in the Eastern Alps is dipping to the SW reaching the depth of 43–45 km. The lower crust at the eastern margin of the Bohemian Massif is characterized by elevated velocities and high Vp gradient, which seems to be a characteristic feature of the Moravo-Silesian. Slightly different properties in the Moravian and Silesian units might be attributed to varying distances of the profile from the Moldanubian Thrust front as well as a different type of contact of the Brunia with the Moldanubian and its northern root sector. The Moho beneath the Fore-Sudetic Monocline is the most pronounced and is interpreted as the first-order discontinuity at a depth of 30 km.     

Heat flow and heat generation in the Churchill Province of the Canadian Shield, and their palaeotectonic significance

Six new heat flow determinations are presented for Proterozoic mobile belts of the Churchill Province of the Canadian Shield, an area that was affected by several stages of the Hudsonian orogenic sequence (1.9-1.6 Ga ago). With other, previously published, values the mean of eight determinations considered reliable and representative and corrected for the effects of Pleistocene glaciation is 44 ± 7 mW m⁻². Heat generation measurements have also been made; values range from 0.1–1.04 μW m⁻³.A linear relation between heat flow and heat production is apparent. The heat flow axis intercept is 37 mW m⁻², and the scale depth is 11 km, compared with 28 mW m⁻² and 13.6 km for the Archaean Superior Province. Approximately 20% of the Churchill heat flow appears to be derived from radioactive decay in the upper crust, compared with 30% for the Superior Province and shields as a whole. The observations imply that the heat flow-heat production relation for the Churchill Province should be written as Q = Q_c + Q_e + A₀b where Q_c is equivalent to the reduced heat flow for the Archaean terrain, b is similar for the two, and Q_e is an additional component of heat flow in the Proterozoic mobile belts of the Churchill Province.A speculative tectonic model is presented. It is suggested that rifting along two axes of an original craton, which had lateral variations in near surface radiogenic element concentration, followed by erosion of the radiogenic layer and subsequent reconvergence of the cratonic segments, led to widespread redistribution of radioactive elements into the reactivated inter-rift crustal block. One result would be that crustal temperatures are higher in that part of the Churchill Province than in the Superior.     

The origin of magnesite deposits from the Polish Foresudetic Block ophiolites: preliminary δ13C and δ18O investigations

Twenty-three magnesite samples from vein deposits, found in ultramafic rocks related to ophiolites in the north-east Bohemian Massif, have been examined for carbon and oxygen isotope ratios. In these rocks two stages of antigorite serpentinization took place prior to magnesite precipitation. δ¹⁸O_SMOW in magnesites ranges from 24.5 to 27.9%o (corrected for acid fractionation factor) which leads us to conclude a meteoric origin of the ore-forming solution. This inference is further supported by δ¹³C values (?18.7 to ?4.4%o) which point to a biogenic origin of carbon in the magnesites.     

Meso–Cenozoic thermal regime in the Bohai Bay Basin,eastern North China Craton

This article discusses the Meso–Cenozoic thermal history, thermal lithospheric thinning, and thermal structure of the lithosphere of the Bohai Bay Basin, North China. The present-day thermal regime of the basin features an average heat flow of 64.5 ± 8.1 mW m^–2, a lithospheric thickness of 76–102 km, and a ‘hot mantle but cold crust’-type lithospheric thermal structure. The Meso–Cenozoic thermal history experienced two heat flow peaks in the late Early Cretaceous and in the middle to late Palaeogene, with heat flow values of 82–86 mW m^?2 and 81–88 mW m^?2, respectively. Corresponding to these peaks, the thermal lithosphere experienced two thinning stages during the Cretaceous and Palaeogene, reaching a minimum thickness of 43–61 km. The lithospheric thermal structure transformed from the ‘hot crust but cold mantle’ type in the Triassic–Jurassic to the ‘cold crust but hot mantle’ type in the Cretaceous–Cenozoic, according to the ratio of mantle to surface heat flow (q_m/q_s). The research on the thermal history and lithospheric thermal structure of sedimentary basins can effectively reveal the thermal regime at depth in the sedimentary basins and provide significance for the study of the basin dynamics during the Meso–Cenozoic.     

Sm–Nd and U–Pb dating of high-pressure granulites from the Złote and Rychleby Mts (Bohemian Massif, Poland and Czech Republic)

In the Orlica‐?nie?nik complex at the NE margin of the Bohemian Massif, high‐pressure granulites occur as isolated lenses within partially migmatized orthogneisses. Sm–Nd (different grain‐size fractions of garnet, clinopyroxene and/or whole rock) and U–Pb [isotope dilution‐thermal ionization mass spectrometry (ID‐TIMS) single grain and sensitive high‐resolution ion microprobe (SHRIMP)] ages for granulites, collected in the surroundings of ?ervený D?l (Czech Republic) and at Stary Giera?tów (Poland), constrain the temporal evolution of these rocks during the Variscan orogeny. Most of the new ages cluster at c. 350–340 Ma and are consistent with results previously reported for similar occurrences throughout the Bohemian Massif. This interval is generally interpreted to constrain the time of high‐pressure metamorphism. A more complex evolution is recorded for a mafic granulite from Stary Giera?tów and concerns the unknown duration of metamorphism (single, short‐lived metamorphic cycle or different episodes that are significantly separated in time?). The central grain parts of zircon from this sample yielded a large spread in apparent ²⁰⁶Pb/²³⁸U SHRIMP ages (c. 462–322 Ma) with a distinct cluster at c. 365 Ma. This spread is interpreted to be indicative for variable Pb‐loss that affected magmatic protolith zircon during high‐grade metamorphism. The initiating mechanism and the time of Pb‐loss has yet to be resolved. A connection to high‐pressure metamorphism at c. 350–340 Ma is a reasonable explanation, but this relationship is far from straightforward. An alternative interpretation suggests that resetting is related to a high‐temperature event (not necessarily in the granulite facies and/or at high pressures) around 370–360 Ma, that has previously gone unnoticed. This study indicates that caution is warranted in interpreting U–Pb zircon data of HT rocks, because isotopic rejuvenation may lead to erroneous conclusions.     

Experimental constraints on ultrapotassic magmatism from the Bohemian Massif (durbachite series, Czech Republic)

The equilibrium phase relations of a mafic durbachite (53 wt.% SiO₂) from the Třebíč pluton, representative of the Variscan ultrapotassic magmatism of the Bohemian Massif (338–335 Ma), have been determined as a function of temperature (900–1,100°C), pressure (100–200 MPa), and H₂O activity (1.1–6.1 wt.% H₂O in the melt). Two oxygen fugacity ranges were investigated: close to the Ni–NiO (NNO) buffer and 2.6 log unit above NNO buffer (∆NNO + 2.6). At 1,100°C, olivine is the liquidus phase and co-crystallized with phlogopite and augite at 1,000°C for the whole range of investigated pressure and water content in the melt. At 900°C, the mineral assemblage consists of augite and phlogopite, whereas olivine is not stable. The stability field of both alkali feldspar and plagioclase is restricted to low pressure (100 MPa) at nearly water-saturated conditions (<3–4 wt.% H₂O) and T < 900°C. A comparison between experimental products and natural minerals indicates that mafic durbachites have a near-liquidus assemblage of olivine, augite, Ti-rich phlogopite, apatite and zircon, followed by alkali feldspar and plagioclase, similar to the mineral assemblage of minette magma. Natural amphibole, diopside and orthopyroxene were not reproduced experimentally and probably result from sub-solidus reactions, whereas biotite re-equilibrated at low temperature. The crystallization sequence olivine followed by phlogopite and augite reproduces the sequence inferred in many mica-lamprophyre rocks. The similar fractionation trends observed for durbachites and minettes indicate that mafic durbachites are probably the plutonic equivalents of minettes and that K- and Mg-rich magmas in the Bohemian Massif may have been generated from partial melting of a phlogopite–clinopyroxene-bearing metasomatized peridotite. Experimental melt compositions also suggest that felsic durbachites can be generated by simple fractionation of a more mafic parent and mixing with mantle-derived components at mid crustal pressures.