Depositional processes,bedform development and hybrid bed formation in rapidly decelerated cohesive (mud–sand) sediment flows

Flows with high suspended sediment concentrations are common in many sedimentary environments, and their flow properties may show a transitional behaviour between fully turbulent and quasi‐laminar plug flows. The characteristics of these transitional flows are known to be a function of both clay concentration and type, as well as the applied fluid stress, but so far the interaction of these transitional flows with a loose sediment bed has received little attention. Information on this type of interaction is essential for the recognition and prediction of sedimentary structures formed by cohesive transitional flows in, for example, fluvial, estuarine and deep‐marine deposits. This paper investigates the behaviour of rapidly decelerated to steady flows that contain a mixture of sand, silt and clay, and explores the effect of different clay (kaolin) concentrations on the dynamics of flow over a mobile bed, and the bedforms and stratification produced. Experiments were conducted in a recirculating slurry flume capable of transporting high clay concentrations. Ultrasonic Doppler velocity profiling was used to measure the flow velocity within these concentrated suspension flows. The development of current ripples under decelerated flows of differing kaolin concentration was documented and evolution of their height, wavelength and migration rate quantified. This work confirms past work over smooth, fixed beds which showed that, as clay concentration rises, a distinct sequence of flow types is generated: turbulent flow, turbulence‐enhanced transitional flow, lower transitional plug flow, upper transitional plug flow and a quasi‐laminar plug flow. Each of these flow types produces an initial flat bed upon rapid flow deceleration, followed by reworking of these deposits through the development of current ripples during the subsequent steady flow in turbulent flow, turbulence‐enhanced transitional flow and lower transitional plug flow. The initial flat beds are structureless, but have diagnostic textural properties, caused by differential settling of sand, silt and cohesive mud, which forms characteristic bipartite beds that initially consist of sand overlain by silt or clay. As clay concentration in the formative flow increases, ripples first increase in mean height and wavelength under turbulence‐enhanced transitional flow and lower transitional plug‐flow regimes, which is attributed to the additional turbulence generated under these flows that subsequently causes greater lee side erosion. As clay concentration increases further from a lower transitional plug flow, ripples cease to exist under the upper transitional plug flow and quasi‐laminar plug flow conditions investigated herein. This disappearance of ripples appears due to both turbulence suppression at higher clay concentrations, as well as the increasing shear strength of the bed sediment that becomes more difficult to erode as clay concentration increases. The stratification within the ripples formed after rapid deceleration of the transitional flows reflects the availability of sediment from the bipartite bed. The exact nature of the ripple cross‐stratification in these flows is a direct function of the duration of the formative flow and the texture of the initial flat bed, and ripples do not form in cohesive flows with a Reynolds number smaller than ca 12 000. Examples are given of how the unique properties of the current ripples and plane beds, developing below decelerated transitional flows, could aid in the interpretation of depositional processes in modern and ancient sediments. This interpretation includes a new model for hybrid beds that explains their formation in terms of a combination of vertical grain‐size segregation and longitudinal flow transformation.     

Sliding-no sliding zone effect and age determination of ice cores

At present the age of ice from ice cores taken at depths where the seasonal isotope fluctuations no longer are measurable is estimated from the Dansgaard-Johnsen-Nye analysis of the longitudinal thinning of ice sheets. A significant error occurs in such an age estimate if ice cores are taken from a hole drilled through ice that has flowed from a region of the ice sheet where ice slides over its bed to a region where it cannot slide over its bed. The Camp Century drill hole is in ice which may have had such a flow history. In the zone where sliding ceases to take place, the horizontal ice velocity decreases in magnitude in the lower part of the ice sheet while it increases in the upper part. The average ice velocity remains unchanged in value. As a consequence the upper part of the ice sheet is stretched and the lower part is compressed as ice moves through the sliding-no sliding transition zone. The upper part is stretched to a strain of the order of $\text{1}\text{2}$ and the lower part is compressed to a strain that is of the order of $\text{?}\text{1}\text{2}$. The age of ice from the Dansgaard-Johnsen-Nye analysis is underestimated; the error in the age is of the order of h/a, where h is the ice thickness and a is the accumulation rate. (Larger errors occur if the theory of Johnsen et al. is used to determine the age of the ice.) An error in age of a similar magnitude exists if ice flows from a region in which sliding does not take place into a region in which it does. The Byrd Station drill hole is in ice which probably has such a flow history. In this situation the age of the ice is overestimated. If the annual isotope fluctuations are detectable the sliding-no sliding zone effect will make it appear that a sudden change in the accumulation rate occurred at the time the ice at the upper surface of the ice sheet passed over this zone.     

长江中游动床阻力计算

动床阻力计算是水沙数学模型中的重要研究内容。三峡工程运用后，进入长江中游河段的沙量剧减引起河床冲刷及床沙粗化，导致动床阻力的变化特点更复杂，有必要研究长江中游动床阻力的计算方法。采用长江中游枝城、沙市及汉口等5个水文站2001—2012年的1 266组实测数据，选取弗劳德数（Fr）和相对水深（h/D₅₀）作为动床阻力计算的主要影响因子，建立基于水流能态分区的动床阻力公式并利用多元非线性回归的方法率定相关参数，采用长江中游上述5个水文站2013—2017年的651组实测数据对公式进行验证。结果表明：① 长江中游的动床阻力主要处于低能态区和过渡区；② 基于水流能态分区动床阻力公式的计算精度明显高于现有阻力公式，决定系数（R²）约为0.89，阻力系数n的计算偏差小于±30%的数据达97.7%。     

长江中游动床阻力计算

动床阻力计算是水沙数学模型中的重要研究内容。三峡工程运用后，进入长江中游河段的沙量剧减引起河床冲刷及床沙粗化，导致动床阻力的变化特点更复杂，有必要研究长江中游动床阻力的计算方法。采用长江中游枝城、沙市及汉口等5个水文站2001—2012年的1 266组实测数据，选取弗劳德数（Fr）和相对水深（h/D₅₀）作为动床阻力计算的主要影响因子，建立基于水流能态分区的动床阻力公式并利用多元非线性回归的方法率定相关参数，采用长江中游上述5个水文站2013—2017年的651组实测数据对公式进行验证。结果表明:①长江中游的动床阻力主要处于低能态区和过渡区；②基于水流能态分区动床阻力公式的计算精度明显高于现有阻力公式，决定系数（R2）约为0.89，阻力系数n的计算偏差小于±30%的数据达97.7%。     

Slurry-flow deposits in the Britannia Formation (Lower Cretaceous), North Sea: a new perspective on the turbidity current and debris flow problem

The Lower Cretaceous Britannia Formation (North Sea) includes an assemblage of sandstone beds interpreted here to be the deposits of turbidity currents, debris flows and a spectrum of intermediate flow types termed slurry flows. The term ‘slurry flow’ is used here to refer to watery flows transitional between turbidity currents, in which particles are supported primarily by flow turbulence, and debris flows, in which particles are supported by flow strength. Thick, clean, dish‐structured sandstones and associated thin‐bedded sandstones showing Bouma T_b–e divisions were deposited by high‐ and low‐density turbidity currents respectively. Debris flow deposits are marked by deformed, intraformational mudstone and sandstone masses suspended within a sand‐rich mudstone matrix. Most Britannia slurry‐flow deposits contain 10–35% detrital mud matrix and are grain supported. Individual beds vary in thickness from a few centimetres to over 30 m. Seven sedimentary structure division types are recognized in slurry‐flow beds: (M₁) current structured and massive divisions; (M₂) banded units; (M₃) wispy laminated sandstone; (M₄) dish‐structured divisions; (M₅) fine‐grained, microbanded to flat‐laminated units; (M₆) foundered and mixed layers that were originally laminated to microbanded; and (M₇) vertically water‐escape structured divisions. Water‐escape structures are abundant in slurry‐flow deposits, including a variety of vertical to subvertical pipe‐ and sheet‐like fluid‐escape conduits, dish structures and load structures. Structuring of Britannia slurry‐flow beds suggests that most flows began deposition as turbidity currents: fully turbulent flows characterized by turbulent grain suspension and, commonly, bed‐load transport and deposition (M₁). Mud was apparently transported largely as hydrodynamically silt‐ to sand‐sized grains. As the flows waned, both mud and mineral grains settled, increasing near‐bed grain concentration and flow density. Low‐density mud grains settling into the denser near‐bed layers were trapped because of their reduced settling velocities, whereas denser quartz and feldspar continued settling to the bed. The result of this kinetic sieving was an increasing mud content and particle concentration in the near‐bed layers. Disaggregation of mud grains in the near‐bed zone as a result of intense shear and abrasion against rigid mineral grains caused a rapid increase in effective clay surface area and, hence, near‐bed cohesion, shear resistance and viscosity. Eventually, turbulence was suppressed in a layer immediately adjacent to the bed, which was transformed into a cohesion‐dominated viscous sublayer. The banding and lamination in M₂ are thought to reflect the formation, evolution and deposition of such cohesion‐dominated sublayers. More rapid fallout from suspension in less muddy flows resulted in the development of thin, short‐lived viscous sublayers to form wispy laminated divisions (M₃) and, in the least muddy flows with the highest suspended‐load fallout rates, direct suspension sedimentation formed dish‐structured M₄ divisions. Markov chain analysis indicates that these divisions are stacked to form a range of bed types: (I) dish‐structured beds; (II) dish‐structured and wispy laminated beds; (III) banded, wispy laminated and/or dish‐structured beds; (IV) predominantly banded beds; and (V) thickly banded and mixed slurried beds. These different bed types form mainly in response to the varying mud contents of the depositing flows and the influence of mud on suspended‐load fallout rates. The Britannia sandstones provide a remarkable and perhaps unique window on the mechanics of sediment‐gravity flows transitional between turbidity currents and debris flows and the textures and structuring of their deposits.     

Reflected sediment gravity flows and their deposits in flysch of Middle Dalmatia, Yugoslavia

The Eocene flysch of Middle Dalmatia comprises several beds that are interpreted to have been deposited from reflected sediment gravity flows. Their compositions are similar and two bed types are differentiated: complex beds that are debrite-plus-turbidite couplets, and turbidites. The sequence alternations in the turbidite part of the bed, opposing ripples within the same bed, and opposite flow directions indicated by flutes and ripples are indicative of flow reflections. The influence of seiches is suggested by the occurrence of symmetrical (oscillation) ripples. The palaeotransport directions of reflected flows show wide dispersal. A geometry of small, fault-controlled sub-basins with centripetal palaeotransport patterns is proposed.     

THE NATURE AND ORIGIN OF BED-FORM HIERARCHIES

The bed forms generated by liquid flows over loose-grain boundaries assume only two orientations relative to flow, being either transverse or longitudinal, but range enormously in physical scale. Two types of bed form, current ripples and parting lineations, take a characteristic length (2) which is independent of boundary conditions as expressed by flow depth (d). We have that: λ^L≤ 0.025 m (parting lineations) λ^R≤ 0.60 m (ripples). The characteristic length of other kinds of bed form is correlated with flow depth, according to the equations: λ^D= 1.16D1.^1.55 (dunes) λ^A 6.3d (antidunes, Fr = 1.0) λ^SR= 1.35d^1.31 (sand ribbons) λ^M - 672d^1.11 (meander bars) λ^T= 116d² (tidal current ridges) From these relationships can be deduced the compositions of theoretical hierarchies of bed forms, where a hierarchy is defined as a series of bed forms graded as to size which in combination are adapted to a single overall flow condition. The compositions of these hierarchies, which are closely matched by naturally occurring hierarchies, are broadly related to available flow depth, general flow conditions (lower or upper regime), and availability of sediment. Bed forms are considered to be due to unstable interactions between the bed material and the over-bed flow, of liquid or grains or both. Hierarchies of bed forms arise because the quantities determining the flow are suficiently numerous that several mutually unstable combinations can exist, each combination being expressed in terms of a bed form of a characteristic physical scale and orientation relative to flow.     

Chemical exchange during hydrothermal alteration of basalt by seawater—II. Experimental results for Fe,Mn, and sulfur species

Fresh mid-ocean ridge basalts of varying crystallinity and an andesite were reacted with seawater and with a Na-K-Ca-Cl solution at 200–500°C and 500–1000 bar in sealed gold capsules. $\text{Water}\text{rock}$ mass ratios of one to three were used and durations ranged from two to twenty months. The concentrations of Fe, Mn, and reduced and oxidized sulfur species in solution reached steady state in most of the experiments at 400–500°C, but not in those at 200–300°. The concentrations of Fe and Mn were a few ppm at 200–300° and increased greatly with temperature between 300 and 500°. The low values at 200–300° are probably related to the uptake of Fe and Mn by smectite at the in situ pH, which was slightly acid at 200° and slightly alkaline at 300°. The quench pH values decreased with increasing temperature above 300°. The only reliable data for the concentration of Zn in solution were obtained at 400°, where values 1–2 ppm were found. Copper was extensively leached from basalt and andesite and was deposited as part of a Cu-Au alloy in the capsule walls or, in some experiments, as chalcopyrite.Reduced sulfur was readily leached from basalt into solution, and was also produced by the reduction of seawater sulfate by ferrous iron derived from the basalts. The proportion of seawater sulfate which was reduced in the experiments with a $\text{water}\text{rock}$ ratio of one varied from 5–10% at 300°C to > 95% at 500°. The rate of sulfate reduction depended on the run temperature, on the crystallinity and initial sulfur content of the rocks used as starting materials, and on the $\text{water}\text{rock}$ ratio. The final concentration of reduced sulfur in solution increased greatly with temperature, and generally exceeded that of Fe on a molal basis.The oxide-sulfide assemblages produced in the experiments resemble those in the basalt-seawater geothermal system at Reykjanes, Iceland, and in hydrothermally altered basalts and gabbros from the oceanic crust; they include pyrite, pyrrhotite. chalcopyrite, hematite, and probably magnetite. The particular assemblage varied systematically with the temperature, rock type, and crystallinity of each run. Anhydrite precipitated in all experiments with seawater, at all temperatures from 200–500°C. However, its persistence to the end of the runs was apparently metastable, as it should have reacted with the final solutions to produce pyrite or pyrrhotite.     

The dynamics of turbulent, transitional and laminar clay-laden flow over a fixed current ripple

Most aqueous sedimentary environments contain varying concentrations of fine‐grained, often clay‐rich, sediment that is transported in suspension and may modify the properties of the flow and underlying mobile bed. This paper presents results from a series of laboratory experiments examining the mean and turbulent properties of clay‐laden (kaolinite) flows, of various volumetric sediment concentrations between 0·046% and 12·7%, moving over a fixed, idealized current ripple. As the kaolinite concentration was raised, with flow velocity and depth constant, four flow types were observed to occur: (i) turbulent flow, in which flow separation is dominant in the leeside of the ripple; (ii) turbulence‐enhanced transitional flow, in which turbulence in the leeside separation zone region is enhanced; (iii) turbulence‐attenuated transitional flow, in which turbulence along the separation zone shear layer and in the free flow above it becomes damped, eventually leading to a reduction in the size of the separation zone wake region; and (iv) laminar plug flow, in which turbulence is damped and flow is almost stagnant in the lee of the ripple. Such modulation of turbulence by increasing clay concentrations suggests that many paradigms of flow and bedform dynamics, which have been based on extensive past work in clear water flows, require revision. The present results highlight a need to fully characterize the boundary conditions for turbulence modulation as a function of clay type and applied flow conditions, and the effects of such flows on fully mobile cohesionless beds.     

An experimental investigation of sand–mud suspension settling behaviour: implications for bimodal mud contents of submarine flow deposits

The settling behaviour of particulate suspensions and their deposits has been documented using a series of settling tube experiments. Suspensions comprised saline solution and noncohesive glass‐ballotini sand of particle size 35·5 μm < d < 250 μm and volume fractions, φ_s, up to 0·6 and cohesive kaolinite clay of particle size d < 35·5 μm and volume fractions, φ_m, up to 0·15. Five texturally distinct deposits were found, associated with different settling regimes: (I) clean, graded sand beds produced by incremental deposition under unhindered or hindered settling conditions; (II) partially graded, clean sand beds with an ungraded base and a graded top, produced by incremental deposition under hindered settling conditions; (III) graded muddy sands produced by compaction with significant particle sorting by elutriation; (IV) ungraded clean sand produced by compaction and (V) ungraded muddy sand produced by compaction. A transition from particle size segregation (regime I) to suppressed size segregation (regime II or III) to virtually no size segregation (IV or V) occurred as sediment concentration was increased. In noncohesive particulate suspensions, segregation was initially suppressed at φ_s ～ 0·2 and entirely inhibited at φ_s ≥ 0·6. In noncohesive and cohesive mixtures with low sand concentrations (φ_s < 0·2), particle segregation was initially suppressed at φ_m ～ 0·07 and entirely suppressed at φ_m ≥ 0·13. The experimental results have a number of implications for the depositional dynamics of submarine sediment gravity flows and other particulate flows that carry sand and mud; because the influence of moving flow is ignored in these experiments, the results will only be applicable to flows in which settling processes, in the depositional boundary, dominate over shear‐flow processes, as might be the case for rapidly decelerating currents with high suspended load fallout rates. The ‘abrupt’ change in settling regimes between regime I and V, over a relatively small change in mud concentration (<5% by volume), favours the development of either mud‐poor, graded sandy deposits or mud‐rich, ungraded sandy deposits. This may explain the bimodality in sediment texture (clean ‘turbidite’ or muddy ‘debrite’ sand or sandstone) found in some turbidite systems. Furthermore, it supports the notion that distal ‘linked’ debrites could form because of a relatively small increase in the mud concentration of turbidity currents, perhaps associated with erosion of a muddy sea floor. Ungraded, clean sand deposits were formed by noncohesive suspensions with concentrations 0·2 ≤ φ_s ≤ 0·4. Hydrodynamic sorting is interpreted as being suppressed in this case by relatively high bed aggradation rates which could also occur in association with sustained, stratified turbidity currents or noncohesive debris flows with relatively high near‐bed sediment concentrations.     

过渡型流体转换对洪水型重力流沉积研究的启示及地质意义

洪水型重力流是重力流沉积学的研究热点,以往研究认为洪水型重力流具有紊流支撑的流体性质,对于其流体性质转化及其沉积记录的识别不够深入。近年研究揭示重力流沉积过程中可形成多种过渡型流体,具有特殊流体转换机制和沉积特征。通过调研国内外最新文献,系统介绍了过渡型流体基本特征、沉积机制方面的研究进展,并讨论了其对洪水型重力流沉积研究的启示及地质意义。研究结果表明：在少量黏土矿物影响下,沉积物重力流流体的性质即可由紊流向层流转化,形成特殊的过渡型流体。转化过程主要取决于黏土矿物含量和类型控制的流体内聚力和流速控制的紊流应力二者之间的相互作用。过渡型流体可以产生大型流水沙纹(large current ripple)、砂质纹层—泥质纹层间互形成的低幅度沙波(low amplitude bed wave)等独特的底床类型。尽管实验研究揭示了过渡型流体可能形成的沉积底床特征,针对洪水型重力流沉积记录中过渡型流体的解释仍十分缺乏,尤其是过渡型流体转换机制及其沉积响应仍亟待深入探索。过渡型流体的沉积底形是研究洪水型重力流沉积动力机制的重要载体,可为深入理解洪水型重力流沉积过程提供新视角,同时可能具有更广泛的...     

过渡型流体转换对洪水型重力流沉积研究的启示及地质意义

洪水型重力流是重力流沉积学的研究热点,以往研究认为洪水型重力流具有紊流支撑的流体性质,对于其流体性质转化及其沉积记录的识别不够深入。近年研究揭示重力流沉积过程中可形成多种过渡型流体,具有特殊流体转换机制和沉积特征。通过调研国内外最新文献,系统介绍了过渡型流体基本特征、沉积机制方面的研究进展,并讨论了其对洪水型重力流沉积研究的启示及地质意义。研究结果表明：在少量黏土矿物影响下,沉积物重力流流体的性质即可由紊流向层流转化,形成特殊的过渡型流体。转化过程主要取决于黏土矿物含量和类型控制的流体内聚力和流速控制的紊流应力二者之间的相互作用。过渡型流体可以产生大型流水沙纹（large current ripple）、砂质纹层—泥质纹层间互形成的低幅度沙波（low amplitude bed wave）等独特的底床类型。尽管实验研究揭示了过渡型流体可能形成的沉积底床特征,针对洪水型重力流沉积记录中过渡型流体的解释仍十分缺乏,尤其是过渡型流体转换机制及其沉积响应仍亟待深入探索。过渡型流体的沉积底形是研究洪水型重力流沉积动力机制的重要载体,可为深入理解洪水型重力流沉积过程提供新视角,同时可能具有更广泛的沉积学研究价值。     

Hydration, 18O enrichment and oxidation during ocean floor hydrothermal metamorphism of ophiolitic metabasic rocks from E. Liguria,Italy

During ocean-floor hydrothermal metamorphism of a 225 m thick allochthonous Jurassic sequence of ophiolitic pillow lavas and underlying material in E. Liguria, Italy, the rocks were hydrated, enriched in ¹⁸O and oxidised. H₂O⁺ contents increased from ~0.3 to 3.8 wt.%, δ¹⁸O values increased from ~ +6‰ to values as high as +13.2‰, and ($\text{Fe}{}_2\text{O}{}_3\text{FeO}$1) increased from 0.18 to ratios as high as 1.0. Both δ¹⁸O values and oxidation ratios decrease in the original direction of increasing depth. Pillow margins are consistently more enriched in ¹⁸O and are more oxidised than cores.These observations are qualitatively interpreted in terms of a non-isothermal, heterogeneous reaction model of interaction of basalt with oxygen-bearing sea water during flow through the packed bed of pillows. Fluid flow approximated undirectional downward motion, and occurred in the recharge part of a cycle of single pass convection. Mass transfer through the pile was by flow (infiltration metasomatism), whereas intra-pillow mass transfer was diffusional. Oxygen isotope exchange and oxidation did not occur under conditions of perfect incremental equilibrium. An integrated bulk volumetric water/rock ratio of ~2 × 10³:1 is estimated from the oxidation profile.     

黄河下游动床阻力变化及其计算方法

动床阻力在冲积河道洪水演进与河床冲淤计算中具有十分重要的作用。黄河下游不同水沙条件下的床面形态变化较大,动床阻力变化规律十分复杂,因此需要研究动床阻力的计算方法。利用黄河下游花园口、高村、利津等7个水文站1958—1990年的686组实测数据,确定了影响动床阻力变化的关键水沙因子——水流弗劳德数（Fr）与相对水深（h/D₅₀）,前者表示水流强度,后者表示床面相对粗糙度;建立了基于水流能态分区的动床阻力计算公式,并采用这些实测数据率定了公式中的相关参数;利用黄河下游各水文站1991—2016年的2 288组实测资料,进一步验证了公式的计算精度。计算结果表明:动床阻力的大小随弗劳德数或相对水深的增加而减小;基于水流能态分区动床阻力公式的计算精度明显高于未分区的公式及其他4个动床阻力公式,且决定系数（R2）总体接近0.80,说明水流强度与床面相对粗糙度对动床阻力影响十分显著。     

The compositional classification of chondrites: IV. Ungrouped chondritic meteorites and clasts

Six specimens of unusual chondritic materials were analyzed by neutron activation for 30 elements in order to assess their degree of chondritic compositional pristinity and to search for evidence of genetic links to other chondrites. Five have highly recrystallized textures; the other, the Cumberland Falls chondrite, has suffered minor metamorphic recrystallization. Acapulco and Allan Hills A77081, are closely related and have subpristine compositions; they are more distantly related to Enon which has an altered composition. Udei Station appears to be a IAB meteorite even though its $\text{FeO}\text{(FeO + MgO)}$ ratio is slightly above the IAB field. The highly weathered meteorite Tierra Bianca is closely related to IAB but has a δ¹⁸O value 5 standard deviations higher than the IAB mean and is designated ungrouped. Udei Station and Tierra Bianca have altered compositions; rare earth element patterns indicate loss of a phosphate phase. The elemental composition of the Cumberland Falls chondrite is virtually identical to that of LL chondrites and its O-isotope composition is closely similar to those of some unequilibrated ordinary chondrites including LL Semarkona. The $\text{FeO}\text{(FeO + MgO)}$ ratios in its olivine are generally much lower than those in pyroxene, a relationship we show to be indicative of in situ reduction resulting from exchange with the aubritic host. The names winonaites and forsterite chondrites have no taxonomic utility.     

Thermochemistry of the high structural state plagioclases

The enthalpies of solution of a suite of 19 high-structural state synthetic plagioclases were measured in a Pb₂B₂O₅ melt at 970 K. The samples were crystallized from analyzed glasses at 1200°C and 20 kbar pressure in a piston-cylinder apparatus. A number of runs were also made on Amelia albite and Amelia albite synthetically disordered at 1050–1080°C and one bar for one month and at 1200°C and 20 kbar for 10 hr. The component oxides of anorthite, CaO, Al₂O₃ and SiO₂, were remeasured.The ΔH of disorder of albite inferred in the present study from albite crystallized from glass is 3.23 kcal, which agrees with the 3.4 found by Holm and Kleppa (1968). It is not certain whether this value includes the ΔH of a reversible displacive transition to monoclinic symmetry, as suggested by Helgesonet al. (1978) for the Holm-Kleppa results. The enthalpy of solution value for albite accepted for the solid solution series is based on the heat-treated Amelia albite and is 2.86 kcal less than for untreated Amelia albite.The enthalpy of formation from the oxides at 970 K of synthetic anorthite is ?24.06 ± 0.31 kcal, significantly higher than the ?23.16 kcal found by Charluet al. (1978), and in good agreement with the value of ?23.89 ± 0.82 given by Robieet al. (1979), based on acid calorimetry.The excess enthalpy of mixing in high plagioclase can be represented by the expression, valid at 970 K: ΔH^ex(±0.16 kcal) = 6.7461 X_abX²_An + 2.0247 X_AnX²_Ab where X_Ab and X_An are, respectively, the mole fractions of NaAlSi₃O₈ and CaAl₂Si₂O₈. This ΔH^ex, together with the mixing entropy of Kerrick and Darken's (1975) Al-avoidance model, reproduces almost perfectly the free energy of mixing found by Orville (1972) in aqueous cation-exchange experiments at 700°C. It is likely that Al-avoidance is the significant stabilizing factor in the high plagioclase series, at least for X_An≥ 0.3. At high temperatures the plagioclases have nearly the free energies of ideal one-site solid solutions. The Al-avoidance model leads to the following Gibbs energy of mixing for the high plagioclase series: $\text{ΔG}{}^{\mathrm{mix}}\text{= ΔH}{}^{\mathrm{ex}}\text{+ RT X}{}_{\mathrm{Ab}}\text{ln[X}{}^2{}_{\mathrm{Ab}}\text{(2 ? X}{}_{\mathrm{Ab}}\text{)]+ X}{}_{\mathrm{An}}\text{ln}\text{[X}{}_{\mathrm{An}}\text{(1+X}{}_{\mathrm{An}}\text{)}{}^2\text{]}\text{4}$. The entropy and enthalpy of mixing should be very nearly independent of temperature because of the unlikelihood of excess heat capacity in the albite-anorthite join.     

Oxygen and sulfur isotope equilibria in the BaSO4HSO4−H2O system from 110 to 350°C and applications

Oxygen isotope exchange between BaSO₄ and H₂O from 110 to 350°C was studied using 1 m H₂SO₄-1 m NaCl and 1 m NaCl solutions to recrystallize the barite. The slow exchange rate (only 7% exchange after 1 yr at 110°C and 91% exchange after 22 days at 350°C in 1 m NaCl solution) prompted the use of the partial equilibrium technique. However, runs at 300 and 350°C were checked by complete exchange experiments. The temperature calibration curve for the isotope exchange is calculated giving most weight to the high temperature runs where the partial equilibrium technique can be tested. Oxygen isotope fractionation factors (α) in 1 m NaCl solution (110–350°C), assuming a value of 1.0407 for α_CO2H2O at 25°C, are:

.These data, when corrected for ion hydration effects in solution (Truesdell, 1974), give the fractionation factors in pure water:

.In the 1 m H₂SO₄-1 m NaCl runs, sulfur isotope fractionation between HSO^?₄ and BaSO₄ is less than the detection limit of 0.4%. A barite-sulfide geothermometer is obtained by combining HSO^?₄H₂S and sulfide-H₂S calibration data.Barite in the Derbyshire ore field, U.K., appears to have precipitated in isotopic equilibrium with water and sulfur in the ore fluid at temperatures less than 150°C. At the Tui Mine, New Zealand, the barite-water geothermometer indicates temperatures of late stage mineralization in the range 100–200°C. A temperature of 350 ± 20°C is obtained from the barite-pyrite geothermometer at the Yauricocha copper deposit, Peru, and oxygen isotope analyses of the barite are consistent with a magmatic origin for the ore fluids.     

Suspended-load fallout rate as an independent variable in the analysis of current structures

The dynamic interpretation of most current-structure sequences derives directly from experiments on the succession of bedforms produced by flows in flumes. The results of these and related studies have been used to construct stability field diagrams in which the fields of individual bedforms are usually expressed as a function of flow intensity (power, velocity, bed shear stress, etc.) and grain size. The data underlying existing stability-field diagrams were collected largely from the study of flows carrying coarse-grained sediment entrained through particle-by-particle bed erosion. Many flows, however, do not entrain sediment through simple bed erosion. Most turbidity currents originate by the development of turbulence in slumps, slides, and other slope failures. Such flows generally form with highly concentrated suspended loads and their bed-load layers derive sediment from the collapsing suspended-sediment clouds. Because the collapse properties of such clouds may be related as much to suspended particle concentration, size distribution, particle interactions, and other factors as to flow intensity, the stability fields of bedforms developed beneath such flows may differ in flow intensity-grain-size relationships from those beneath flows deriving sediment from bed erosion alone. Useful stability-field diagrams for turbidity currents must include suspended-load fallout rate as a third variable, independent of flow intensity and mean grain size. A preliminary stability-field diagram of this type indicates that Bouma T_abc sequences may theoretically form with essentially no velocity variation of the attendant flow. This type of analysis may have considerable relevance to the interpretation not only of turbidites but also of other deposits formed where bed-load layers are fed from above rather than below. These include shallow-shelf storm units deposited from highly concentrated flows and volcaniclastic layers formed where pyroclastic debris falls directly into moving water.     

Evolution of a classic sand ridge field: Maryland sector, North American inner shelf

The ridge and swale topography of the Middle Atlantic Bight is best developed on the Delaware-Maryland inner shelf. Here sand ridges can be seen in all stages of formation. Several aspects of the ridge field are pertinent to the problem of ridge genesis. The first is ridge morphology. There is a systematic morphologic change from shoreface ridges through nearshore ridges to offshore ridges, which reflects the changing hydraulic regime. As successively more seaward ridges are examined, maximum side slope decreases, the ratio of maximum seaward slope to maximum landward slope decreases, and the cross-sectional area increases. These changes in ridge morphology with depth and distance from shore appear to be equivalent to the morphologic changes experienced by a single ridge during the course of the Holocene transgression. A second aspect is the change in bottom sediment characteristics that accompanies these large-scale morphologic changes. Megaripples, sand waves and mud lenses appear in the troughs between nearshore and offshore ridges. These changes indicate that the storm flows which maintain ridges are less frequently experienced in the deeper sector, and that the role of high-frequency wave surge becomes less important relative to the role of the mean flow component in shaping the sea-floor. A third aspect is the systematic relationship of grain size to topography. Grain size is 90° out of phase with topography, so that the coarsest sand lies between the axis of the landward trough and the ridge crest, while the finest sand lies between the ridge crest and the axis of the seaward trough. This relationship is characteristic of large-scale bedforms. Finally, flow was measured and transport calculated on the same ridge during a one-month period (November 1976). Threshold was exceeded only during storm events. Mean transport was southerly and a little seaward with respect to both the ridge crest and the shoreline. These flow measurements are in conformity with the pattern of smaller bedforms. A 43-year time series of bathymetric change for this ridge reveals a systematic pattern of landward flank erosion, seaward flank deposition, and seaward crest migration. Sand ridges are considered the consequence of constructive feedback between an initial topography and the resulting distribution of bottom shear stress. The relationship between grain size and topography supports this model, but does not account directly for the oblique angle of the ridge with respect to the coastline. This feature may be due to a more rapid alongshore migration rate of the inshore edge of the ridge than the offshore edge, and the relationship between this migration rate, and the rate of shoreface retreat.     

An integrated law of the wall for hydrodynamically transitional flow over plane beds

The velocity profile for unidirectional currents is usually determined by two forms of the law of the wall, which are valid for smooth and rough boundaries, respectively. The law of the wall for smooth boundaries outside the viscous sublayer and buffer layer applies where the boundary Reynolds number (Re_*) is less than 5. The velocity in this case depends only on the dimensionless distance (y_d) from the bottom. For rough boundaries where Re_* is more than 65, the law of the wall is independent of the boundary Reynolds number, but the bottom roughness (k) has to be taken into account. The mean or median particle grain size (D) is commonly substituted for bottom roughness. At present, there is no generally accepted law of the wall for the transitional flow regime between hydrodynamically smooth and rough conditions. In this paper, an integrated law of the wall is proposed for the transitional regime, yielding velocity profiles that correspond well to observed velocity profiles under these conditions. The result is applied to a set of flume data, using an improved procedure to determine the bedload transport rate.