Comparing impacts to shallow-water habitas through time and space

Impacts to shallow-water estuarine habitats should be assessed in a holistic context reflecting both the interrelatedness of habitats that characterize these environments and the history of impacts, human and natural, that have shaped their present ecology. In a holistic context these habitats are considered to be dynamic associations of macrohabitats and micro-habitats, interacting through time to affect the quantity (Q₁), quality (Q₂), and timing (T) of material and energy transfer within the system. Where data are available, this holistic approach (Q₁, Q₂ and T or Q₂T) allows impacts to be evaluated in a multidimensional framework of time and space. Unfortunately, few data are available to evaluate the long-term implications of timing, the T factor. Recorded observations of most estuarine systems cover tens of years, periods not extensive enough to assess long-term changes to the environment or to distinguish man's impacts from those of nature. Sustained droughts, for example, can cause massive disruption in estuaries, altering habitats and species composition. When these changes occur over periods of 5–10 yr, the changes are difficult to identify and may be attributed to man's activities rather than nature's Using the Hudson River estuary as an example, we have knowledge of historical impacts extending back to the 1700s, ranging from dredging to major droughts. For the Hudson River, recorded observations of rainfall and river flow extend back about 70 yr; however, tree rings provide a more extensive record since tree growth increments are directly dependent upon rainfall. The Hudson River drought record was extended back to 1694 using tree rings. Using the reconstructed record, the relationship between today's conditions—flow and average location of the ocean-derived salt front—can be placed in a historical context. This historical perspective allows us to place present-day human impacts into the contex of long-term natural impacts and to discriminate among these effects. The drought example is particularly relevant to shallow-water habitats because these habitats provide an interface between fresh and marine waters. *** DIRECT SUPPORT *** A01BY074 00008     

Groundwater resources of the middle and upper Odra River basin, southwestern Poland

 The total amount of groundwater resources in the middle and upper Odra River basin is 5200×10³ m³/d, or about 7.7% of the disposable groundwater resources of Poland. The average modulus of groundwater resources is about 1.4 L/s/km². Of the 180 'Major Groundwater Basins' (MGWB) in Poland, 43 are partly or totally located within the study area. The MGWB in southwestern Poland have an average modulus of groundwater resources about 2.28 L/s/km² and thus have abundant water resources in comparison to MGWB from other parts of the country. Several types of mineral waters occur in the middle and upper Odra River basin. These waters are concentrated especially in the Sudety Mountains. Carbon-dioxide waters, with yields of 414 m³/h, are the most widespread of Sudetic mineral waters. The fresh waters of the crystalline basement have a low mineralization, commonly less than 100 mg/L; they are a HCO₃–Ca–Mg or SO₄–Ca–Mg type of water. Various hydrochemical compositions characterize the groundwater in sedimentary rocks. The shallow aquifers are under risk of atmospheric pollution and anthropogenic effects. To prevent the degradation of groundwater resources in the middle and upper Odra River basin, Critical Protection Areas have been designated within the MGWB. Received, January 1995 Revised, May 1996, August 1997 Accepted, August 1997     

苏干湖盆地水资源与生态环境及其向区外调水的影响

苏干湖水系属于柴达木内流水系西北端的一个独立水系, 在现状条件下, 苏干湖盆地水循环关系为大小哈尔腾河-苏干湖的"补给-蒸发"相平衡.大小苏干湖为盆地水资源的尾闾汇集区, 生态景观大部分为戈壁荒漠, 生态植被集中分布在湖外围地下水埋深小于5 m的浅埋带.在评价分析现状水均衡的基础上, 分析了盆地水循环过程, 结合氢氧同位素测试和遥感信息提取, 得出大、 小苏干湖水体的补给来源不同, 河流来水量的变化主要反映在大苏干湖水域, 对小苏干湖水体影响较小.初步建立了苏干湖盆地生态植被变化模式, 结合引哈济党工程, 分析了不同调水情景下, 大苏干湖水体面积的变化、 地下水浅埋带的变化及生态变化. 结果表明: 在大哈尔腾河调水1.0×10⁸m³时, 不会对苏干湖水系生态状况造成明显的影响, 因而可对敦煌生态保护起到积极作用.     

Absence of overall feedback in a benthic estuarine community: A system potentially buffered from impacts of biological invasions

Species introductions are among the most dramatic human-induced impacts on aquatic and terrestrial ecosystems around the world. Stability patterns of an estuarine benthic community were investigated through guild interaction models representing the community before and after human-mediated species invasions. The study area was Yaquina Bay, a developed estuary on the central Oregon coast, U.S., where at least 12 species of nonindigenous invertebrates have been inadvertently introduced. Three of the introduced species (the polychaetes Hobsonia florida and Pseudopolydora kempi and the cumacean Nippoleucon hinumensis) are probably among the 10 most abundant invertebrate species in the intertidal benthic community. To estimate effects and potential risks of species introductions on the native community we constructed 2 types of community models based on functional-group interactions, namely, activity guild models and trophic guild models. In both cases we observed that overall feedback has a strong tendency towards zero in pre-invasion and post-invasion models. We generated 12,000 random models of similar size and could not detect this tendency. We suggest that the weak or absent overall feedback in this community may be an ecological property and not an intrinsic property of large systems as such. The reduced response to input from either invertebrate invasions or removal of native top predators, may to some extent buffer the community from such impacts. Alternative guild models suggested increased risk of stability decline in the invaded community even after accounting for potential complexity effects on stabllity. Further species introductions in this intermediately invaded estuary should be avoided.     

Food resources and habitat selection of a diverse vertebrate fauna from the upper lower Campanian of the Kristianstad Basin,southern Sweden

During the latest early Campanian, a diverse vertebrate assemblage inhabited the shallow coastal waters of the Kristianstad Basin, southernmost Sweden. The taxon-rich fauna includes numerous species of sharks, rays, chimaeroids, bony fish, mosasaurs, plesiosaurs, aquatic birds, crocodiles, and turtles. Vertebrate fossils have been found at several localities within the basin, representing at least three different environments: near-shore waters around a rocky island, presumably murky, shallow waters adjacent to a river mouth, and more open coastal waters. Many vertebrates in the marine faunal community were high-level predators, others were piscivorous, bottom-dwellers that fed primarily on benthic invertebrates and fish, or omnivores that fed on algae and invertebrates. The fauna thus exploited a wide range of food sources and habitats. Six trophic levels, ranging from primary producers to fifth-level consumers, are recognised, indicating a high loss of energy and reflecting a mixture of shallow coastal and more open water ecosystems. The trophic structure suggests that the basin was a rich palaeoenvironment with high faunal diversity and productivity.     

Age- and sex-dependent migrations of striped bass in the Hudson River as determined by chemical microanalysis of otoliths

Patterns of habitat utilization and migration of Hudson River striped bass,Morone saxatilis, were estimated using otolith microchemical analysis to chart age- and sex-dependent movements. Otoliths from 25 males and 25 females were analyzed for seasonal and age-specific patterns in strontium: calcium level. These levels were converted into salinity estimates based upon a relationship derived from experimental studies. Seasonal patterns in salinity habitation indicated annual up-estuary migrations in mature age-classes of males and females, and may represent spawning migrations. Early emigration of young striped bass (<3 yr old) into polyhaline and euhaline waters was observed for both sexes, but females tended to reside at higher salinities throughout their life span. Otolith microchemical analysis indicated that 68% of the sampled females and 28% of the sampled males spent significant portions of their lives in euhaline coastal waters. A positive relationship between down-estuary movements and age was observed for both sexes, supporting the hypothesis of size-related dispersion and anadromy in striped bass populations. Individuals collected during the same season or from the same segment of the river had similar lifetime salinities. This result suggests that group cohesion (schooling) could persist for substantial periods of an individual’s life span. The most cohesive group was fall-collected males, which may reside permanently in fresh water and estuarine waters. Cohesive migratory groups would have important implications for investigations on effects of contaminants and fishing pressure on Hudson River striped bass.     

Impacts of climate change on flow regime and sequential threats to riverine ecosystem in the source region of the Yellow River

Climate change is expected to have substantial impacts on flow regime in the Upper Yellow River (UYR) basin that is one of the most important biodiversity hotspots in the world. These impacts will most possibly exert negative effects on the habitat availability for riverine species. Thus, it is necessary to understand the alteration of river flow regime under climate scenarios. In this paper, we use the modified hydrological model HBV in conjunction with three general circulation models under three representative concentration pathways (RCP 2.6, 4.5, and 8.5) to address changes in flow regime under climate change for the UYR basin in the mid-term (2050s) and end-term (2080s) of the twenty-first century. Flow regime is quantified using the Indicators of hydrological alteration approach. Thereafter, the potential threats to riverine ecosystem in the UYR basin are identified based on the projected alterations of various flow characteristics and their ecological influences. The results showed that the magnitude of monthly flow would increase during the dry period. The date of the annual 1-day minimum streamflow will likely shift toward earlier time under different scenarios, and significant increases in magnitude of annual minimum flow of different durations were detected under both RCP 4.5 and 8.5 scenarios in the 2080s. In addition, assessments of the modification degree of the overall flow regime revealed that climate change would remarkably modify (medium level) the overall flow regime in the UYR basin, particularly by the end of the twenty-first century or under the high emission scenarios. Besides, destruction of habitat and reduced availability of food induced by substantially increased hydrological instability in the 2080s would make two endangered fishes more vulnerable in the UYR basin. These findings provide insights into potential adaptive countermeasures for water resource management and environmental system restoration in the Upper Yellow River.     

Long-term improvements in water quality due to sewage abatement in the lower Hudson River

Long-trend trends in dissolved oxygen (DO) and total coliform bacteria concentrations are used to evaluate the impact of almost 60 yr of sewage abatement and treatment in the lower Hudson River near New York City. Although some water pollution control plants have been in operation in the region since the 1930s, the most significant abatement of untreated sewage in the lower Hudson River has occurred since the late 1970s, when most of the existing plants were upgraded to secondary treatment, and additional plants were constructed. From at least 1922 through the early 1960s, average summer DO percent saturation varied between 35% and 50% in surface waters and 25% and 40% in bottom waters. Beginning in the late 1970s, DO concentrations generally increased through the 1980s and especially into the 1990s, coinciding with the upgrading of the 7.4 m³ s^?1 (170 million gallons per day, mgd) North River plant to secondary treatment in the spring of 1991. Average summer percent saturation in the early 1990s exceeded 80% in surface waters and 60% in bottom waters. In addition, summer DO minima have increased from less than 1.5 mg 1^?1 in the early 1970s to greater than 3.0 mg 1^?1 in the 1990s, and the duration of hypoxia during summer months has been reduced. Total coliforms also display strong declining trends from the 1970s into the 1990s, with declines attributed to plant upgrades, construction of two New York City plants (North River and Red Hook) in the mid 1980s, and improved operation of the sewer system.     

The loss of native biodiversity and continuing nonindigenous species introductions in freshwater, estuarine, and wetland communities of Pearl Harbor, Oahu, Hawaiian Islands

The benthic invertebrates and fishes of the estuarine, lower stream areas, and wetlands of Pearl Harbor were sampled from 1997–1998 as a companion study to marine inventories conducted in Pearl Harbor. The first comprehensive assessment of the area found that nonindigenous species comprise the dominant portion of the biota. A total of 191 aquatic species in 8 phyla were identified in the estuarine reaches of Pearl Harbor. Nonindigenous species dominated and comprised 48% of the species, whereas only 33% were native and 19% were cryptogenic. Two new nonindigenous species to Hawaii were found during this study: a species of fang-toothed blenny (Omobranchus ferox) and an estuarine hydrobiid snail (Pyrgophorus cf.coronatus) introduced from the Philippine Islands and the Caribbean, respectively. No single geographic region predominates as a source of aquatic species introductions into the Pearl Harbor area, although more species come from the Americas than other areas. Fifty-seven percent originated from the Americas, 30% from Asia and the Pacific, 5% from Australia/New Zealand, 5% show a world-wide distribution, and fewer than 3% of species originated from Africa. The majority of nonindigenous species appear to arrive from five major sources: intentional and accidental aquarium releases; intentional biocontrol releases; intentional food source releases; ballast water or hull fouling releases; and brought in with airplanes. Non-native species will likely continue to increase in the freshwater and estuarine portions Pearl Harbor because of the wide variety of sources from which introductions take place.     

Sustainable management of Mogan and Eymir Lakes in Central Turkey

Mogan and Eymir Lakes, located 20 km south of Ankara in Central Turkey, are important aesthetic, recreational, and ecological resources. Dikilitas and Ikizce reservoirs, constructed on upstream surface waters, are two man-made structures in the basin encompassing an area of 985 km². The purpose of this study is to quantify groundwater components in lakes’ budgets and to assess the potential impacts of upstream reservoirs on lake levels for sustainable management of the system. Available data have been used to develop a conceptual model of the system. A three-dimensional groundwater model, incorporating a lake component, has been developed for the system. The model has been calibrated successfully under transient conditions over a period of 6 years using monthly periods. The results show that groundwater inflows and outflows have the lowest contribution to the overall lakes’ budget. The model has been subsequently used to evaluate the impacts of upstream reservoirs. The results show that these reservoirs have a significant effect on lake stages but not on groundwater levels. A trade-off curve between the quantum of water released and the average stage in Lake Mogan has been developed to enhance decision makers’ ability for sustainable management of the system in the long term.     

Genetic differentiation of three key anadromous fish populations of the Hudson River

Large, recreationally or commercially important populations of Atlantic sturgeon (Acipenser oxyrinchus), American shad (Alosa sapidissima), and striped bass (Morone saxatilis) occur in the Hudson River. Members of the Hudson River populations of these fishes also occur over a broad range along the Atlantic coast where they mix with conspecifics from other anadromous populations. For management purposes, it is imperative to be able to discriminate among individual stocks so that weak stocks may be protected and harvest may be allocated equitably. Because of their sensitivity and resistance to environmentally-induced temporal variation, molecular approaches have been increasingly employed in stock identification studies. However, post-Pleistocene recolonization of the Hudson River must have occurred less than 10,000 years ago—a relatively brief period for genetic divergence among populations. We tested whether various measures of DNA variation between Hudson River populations and adjacent populations of Atlantic sturgeon, American shad, and striped bass were sufficient to discriminate among their conspecific populations. American shad populations surveyed for mtDNA variation were highly diverse genotypically, but genotypic frequencies among the populations of the Connecticut, Hudson, and Delaware rivers were statistically homogenous (p>0.05). In contrast, Atlantic sturgeon (surveyed for mtDNA variation) and striped bass (surveyed for mtDNA and nuclear DNA variation) populations of the Hudson River were not genotypically diverse, but they were differentiated from northern and southern populations. Our results suggest higher gene flow (and lesser homing fidelity) among American shad populations in comparison with the two other species.     

Modeling water,sediment and organic carbon discharges in the Hudson-Mohawk basin: Coupling to terrestrial sources

A previous modeling study (Howarth et al. 1991) showed the potential of a simple watershed hydrology model, the Generalized Watershed Loading Function model (GWLF, Haith and Shoemaker 1987) for estimating annual loads of sediment and organic carbon to the Hudson River from various land uses in the upper portion of the basin. We examined the quality and accuracy of model outputs after making two major modifications. First, we used a geographic information system (GIS) and several environmental databases to improve model estimates of several parameters. Second, we evaluated alternative methods for incorporating weather data.We examined seasonal variation of model output as well as annual averages. Annual fluxes increased over those of Howarth et al. (1991) by 10% for sediment and 20% for TOC for the Hudson-Mohawk basin, resulting in closer agreement with measurement-based estimates. The estimated fluxes exhibited a strong seasonal component, with greates sediment load occurring during a few sping events. Finally, model estimates of fluxes associated with forested and agricultural scenarios, characteristic of earlier periods of the region’s history, predicted a doubling of sediment and TOC loading in an agriculturally dominated Hudson basin but a reduction of sediment by 90% and of TOC by 60% in a completely forested basin.     

恒河流域地下水As中毒的特征及其对中国区域生态地球化学评价的启示

恒河流域地下水舡中毒事件始于20世纪80年代。通过对恒河流域地下水舡中毒例案的时空演变、生态效应和成因的分析，指出中国正在开展的区域生态地球化学评价应从恒河流域舡中毒事件中吸取教训，尤其应关注中国长江流域发现的Cd异常带。沿江各省应有全局观念，把长江流域作为一个整体，开展Cd异常的区域生态地球化学评价。     

Morphological and genetic variation among shortnose sturgeonAcipenser brevirostrum from adjacent and distant rivers

Shortnose sturgeon,Acipenser brevirostrum, is a small, endangered species which occurs in 19 estuary systems along the east coast of North America. These populations are considered as separate entities by the U. S. National Marine Fisheries Service although evidence of morphologic or genetic differentiation among populations has not been documented. The purpose of this study was to compare morphological and genetic atributes among shortnose sturgeon collected from the Kennebec and Androscoggin Rivers, Maine, and the Hudson River, New York. Six morphometric and five meristic characteristics were quantified. Multivariate and univariate analyses of covariance and variance were used to assess differences among populations. Our analyses provided evidence for distinct populations in the Androscoggin and Kennebec Rivers, but character differentiation was greater between fish from these two locations and the Hudson River. Analysis of morphometric characters indicated significant differences in fish shape among the three rivers, with Hudson River sturgeon differing from the Maine rivers for the characters of head length, snout length, and mouth width. Significant differences were observed for meristic characters, but pairwise comparisons did not reflect a clear pattern of variability. Sequencing of a portion of the mitochondrial DNA control region revealed 15 haplotypes among 73 total specimens from the three rivers. Shortnose sturgeon from the Kennebec and Androscoggin Rivers were different from each other (p=0.0260); both differed significantly (p<0.0001) from the Hudson River collection. Gene flow was estimated at approximately 7 female migrants per generation between the two Maine populations and about 1 per generation between each of the Maine populations and the Hudson River population. Such strong stock structuring among presumably recently established post-Pleistocene (<10,000 yr) populations suggests that this species occurs in highly discrete units. Morphological and genetic variation observed in this study combined with current knowledge of life history attributes of shortnose sturgeon indicate that conservative management decisions are necessary until the patterns and extent of differentiation among populations species-wide can be investigated further.     

黑河流域生态水文传感器网络设计

在黑河上游八宝河流域和中游盈科灌区,以无线传感器网络为纽带,高效集成流域尺度内密集分布的、多源异构传感器的各种气象、水文及生态观测项目,建立自动化、智能化、时空协同的、各观测节点远程可控的生态水文传感器综合观测网络;通过优化地面采样方案,精细观测和准确度量流域尺度内空间异质性较强的关键水文生态要素的时空动态过程、时空变异性和不确定性;研究针对星载/机载遥感真实性检验的地面传感器采样方案,精细验证遥感反演精度,深入挖掘各种遥感手段在流域综合观测中的作用和潜力;全面提高流域水文生态过程的综合观测能力和观测自动化水平。     

Statistical Models of Temperature in the Sacramento–San Joaquin Delta Under Climate-Change Scenarios and Ecological Implications

Changes in water temperatures caused by climate change in California’s Sacramento–San Joaquin Delta will affect the ecosystem through physiological rates of fishes and invertebrates. This study presents statistical models that can be used to forecast water temperature within the Delta as a response to atmospheric conditions. The daily average model performed well (R ² values greater than 0.93 during verification periods) for all stations within the Delta and San Francisco Bay provided there was at least 1 year of calibration data. To provide long-term projections of Delta water temperature, we forced the model with downscaled data from climate scenarios. Based on these projections, the ecological implications for the delta smelt, a key species, were assessed based on temperature thresholds. The model forecasts increases in the number of days above temperatures causing high mortality (especially along the Sacramento River) and a shift in thermal conditions for spawning to earlier in the year.     

Determining the seasonality of groundwater recharge using water isotopes: a case study from the upper North Han River basin,Korea

The stable isotopes of oxygen and hydrogen were used to determine the seasonal contributions of precipitation to groundwater recharge at a forested catchment area in the upper North Han River basin, Korea. A comparison of the stable isotopic signatures of groundwater and precipitation indicates that the precipitations which occurred during both the dry and rainy seasons are the important source of groundwater recharge in this region. A stable isotopic signature shown in the stream waters at the upstream reaches is similar to that of groundwaters, indicating that stream waters are mostly fed by groundwater discharge. Reservoir waters in the downstream flood control dams have lower deuterium excess values or d-values compared with those of the upstream waters, indicating a secondary evaporative enrichment. These results can provide a basis for the effective management of groundwater and stream water resources in the North Han River basin.     

Atmospheric oxygen exchange in the Hudson River: Dome measurements and comparison with other natural waters

The measurement of metabolism using diel free-water oxygen techniques requires the estimation of atmospheric oxygen exchanges. We measured such exchange on nine different occasions in the freshwater, tidally-influenced Hudson River estuary using a floating dome technique. We also analyzed previously published data on the exchange of a variety of gases measured in lakes, estuaries, and open ocean waters using a wide variety of techniques. Data were expressed as a “transfer velocity” and normalized to an exchange of oxygen at 20°C. Considered together, these data indicate a significant predictive relationship when the natural log of transfer velocity is regressed with measured wind speed (r² = 0.55; p = 0.0001). The influence of wind was particularly pronounced in estuaries and in lakes. Data from open-ocean waters showed much less influence of wind, probably because surface turbulence in these deeper waters can be temporally and spatially decoupled from wind. Our Hudson data agreed well with data collected in other systems. In general, data from estuaries—including the Hudson—indicated slightly higher transfer velocities at any given wind speed than do data from lakes (although this difference was less pronounced for our Hudson data than for other estuaries). The difference may result from some interaction of wind and tidal currents, or it may reflect a bias in the dome method of measurements; all of the estuarine data were collected using the dome approach, while the majority of the lake data were determined using an added tracer. If the dome method actually gives a biased, high estimate of oxygen flux, this is in contradiction to previous criticisms of this method that domes may underestimate fluxes by blocking wind at the water surface. We have used the regression of the natural log of transfer velocity versus wind speed developed here to estimate respiration in the Hudson estuary from diel changes in dissolved oxygen. To allow for possible biases in technique and for measurement error, we estimated 95% confidence limits around the regression. Estimates of respiration in the Hudson determined using the upper and lower 95% confidence limits are 30% higher and 12% lower than that determined when using the best-fit regression. An independently-constrained carbon budget for the tidally-influenced, freshwater Hudson River estuary indicates that respiration rates cannot be much higher than our mean estimate as calculated using the linear regression of the gas transfer and wind data to correct for air-water oxygen exchange. Gas transfer in natural systems is difficult to measure and is controlled by many interrelated physical factors. In the absence of extensive, system-specific field studies, the regression presented here should be useful in estimating atmospheric oxygen exchange in other estuarine or riverine ecosystems which are relatively deep and wide.     

Widespread distribution of some estuarine crustaceans (Cyathura polita,Chiridotea almyra,Almyracuma proximoculi) in the limnetic zone of the lower Hudson River,New York

From June through September 1983, a survey was conducted to document the occurrence, abundance and distribution of benthic macroinvertebrates in the main channel, Hudson River Estuary. The survey was restricted to a 118-km reach of the limnetic zone from just below Albany to New Hamburg, New York. Results indicated that two crustacean species,Cyathura polita (Stimpson) andChiridotea almyra Bowman, are widely distributed and common throughout the limnetic zone, including areas more than 100 km upstream from the northernmost(=most upstream) intrusion of ocean-derived brackish water.Almyracuma proximoculi Jones and Burbanck was much less common, but also was found in areas well removed from any brackish-water influences. All three species previously have been thought to occur primarily in estuarine waters with at least some salinity. We could find no evidence to suggest that non-ocean derived sources were supplementing the levels of dissolved ions in the river water or sediments. Therefore, it appears that all three species have established permant populations in a truly freshwater habitat.     

Sources and history of heavy metal contamination and sediment deposition in Tivoli South Bay, Hudson River, New York

Persistent inorganic constitutents preserved in sediments of aquatic ecosystems record temporal variability of biogeochemical functioning and anthropogenic impacts.²¹⁰Pb and¹³⁷Cs dating techniques were used to study the past variations of heavy metals (Pb, Cu, and Zn) and accumulation rates of sediments for Tivoli South Bay, in the Hudson River National Estuarine Research Reserve ecosystem. South Bay, a tidal freshwater embayment of the Hudson, may play an important role in the sediment dynamics of this important river. The measured sedimentation rate range of 0.59 to 2.92 cm yr⁻¹ suggests that rapid accumulation occurred during the time period represented by the length of the cores (approximately the past 50 yr). Direct measurements of sediment exchange with the Hudson River reveal high variability in the sediment flux from one tidal cycle to the next. Net exchange does not seem to be adequate to explain sediment accumulation rates in the bay as measured by²¹⁰Pb and¹³⁷Cs. The difference may be supplied from upland streams or the Hudson River during storm events. Concentrations of the metals Pb, Cu and Zn were found to be well correlated with each other within individual cores at five of six sites tested. This suggests a common proximate source for the three metals at a specific site. The evidence is consistent with mixing in some environmental compartment before delivery to the bay. While metals self-correlate within individual cores, absolute concentrations, depth distribution patterns, and ratios of the metals to each other vary among the cores collected at different locations within the bay. Organic matter, Fe content, and particle size distribution of sediments do not account for the intercore variations in metal concentration. It is likely that cores collected from different sites may have derived metals from different sources, such as watershed streams and tidal exchange with the Hudson River.