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1.
We studied mineral magnetic properties of a 6-m-long, late Pleistocene through Holocene sediment sequence from Lake Aibi in Dzungaria (Zunggary, Junggar), northern Xinjiang, China. Results were used to infer environmental changes and are compared with previously studied cores from Lake Manas. Both water bodies occupy the deepest parts of the Dzungarian Basin and are remnants of large Holocene lakes. During the Late Pleistocene, the magnetic mineralogy in both lakes was dominated by detrital, iron oxide minerals. Oxic conditions, which dominated during sedimentation and early diagenesis, persisted over the Pleistocene–Holocene transition. Later, during the middle Holocene, lake bottom conditions enabled authigenic formation of iron sulphide minerals such as pyrite (FeS2) in Lake Aibi, and pyrite and greigite (Fe3S4) in Lake Manas. This iron sulphide mineralogy suggests increased biological activity in stagnant, anoxic bottom waters. Anoxic bottom conditions started about 9.8 cal kyr BP in Lake Manas and at about 7.2 cal kyr BP in Lake Aibi. A short dry event recorded in Lake Manas between 6.8 and 5.2 cal kyr BP is not clearly observed in Lake Aibi. In the late Holocene, i.e. the last 2.8 cal kyr, sediments of both lakes are again characterised by iron oxides, suggesting well-mixed, shallow water bodies. For this recent period, it seems that the detrital material in the two lakes had a common origin. Magnetic properties of sediments in Lakes Aibi and Manas show broadly similar environmental evolution during the late Pleistocene and Holocene. Nevertheless, despite the close proximity of the two lakes (~200 km) in the same basin, they display some different magnetic properties and record environmental changes at different times.  相似文献   

2.
Slip rate on the Dead Sea transform fault in northern Araba valley (Jordan)   总被引:11,自引:0,他引:11  
The Araba valley lies between the southern tip of the Dead Sea and the Gulf of Aqaba. This depression, blanketed with alluvial and lacustrine deposits, is cut along its entire length by the Dead Sea fault. In many places the fault is well defined by scarps, and evidence for left-lateral strike-slip faulting is abundant. The slip rate on the fault can be constrained from dated geomorphic features displaced by the fault. A large fan at the mouth of Wadi Dahal has been displaced by about 500 m since the bulk of the fanglomerates were deposited 77–140 kyr ago, as dated from cosmogenic isotope analysis (10Be in chert) of pebbles collected on the fan surface and from the age of transgressive lacustrine sediments capping the fan. Holocene alluvial surfaces are also clearly offset. By correlation with similar surfaces along the Dead Sea lake margin, we propose a chronology for their emplacement. Taken together, our observations suggest an average slip rate over the Late Pleistocene of between 2 and 6 mm yr−1, with a preferred value of 4 mm yr−1. This slip rate is shown to be consistent with other constraints on the kinematics of the Arabian plate, assuming a rotation rate of about 0.396° Myr−1 around a pole at 31.1°N, 26.7°E relative to Africa.  相似文献   

3.
A study of mineral magnetic parameters was carried out on a Late Pleistocene and Holocene sedimentary sequence (of nearly 18 m) from Lake Bledowo (central Poland). Sediments of Lake Bledowo have already been analysed for bulk sediment mineralogy and biogenic materials. The mineral magnetic stratigraphy confirms the major changes in palaeo-environmental conditions that have been deduced from other methods. The most important mineral magnetic change results from the authigenetic formation of ferrimagnetic greigite, Fe3S4, during the beginning of lacustrine conditions (± 12 000 yr BP). Our data also indicate a detrital origin of overlying ferrimagnetic iron oxides. It is suggested that they originate from brown soils developed on the boulder clay constituting the west side of the lake shore. Variations of ferrimagnetic iron oxide size are related to the early diagenetic processes in the sediment. Larger particles are present in periods with early diagenesis of organic matter in anoxic conditions. This indicates the dissolution of fine magnetic particles by iron-oxide-reducing bacteria and results in homogeneous magnetic grain sizes, despite their origin from soils, characterized by a multimodal grain-size distribution.  相似文献   

4.
The Barents Sea ice sheet - a sedimentological discussion   总被引:1,自引:0,他引:1  
Sediment sampling and shallow seismic profiling in the western and northern Barents Sea show that the bedrock in regions with less than 300 m water depth is unconformably overlain by only a thin veneer (<10 m) of sediments. Bedrock exposures are probably common in these areas. The sediments consist of a Holocene top unit, 0.1–1.5 m in thickness, grading into Late Weichselian glaciomarine sediments. Based on average sedimentation rates (14C-dating) of the Holocene sediments, the transition between the two units is estimated to 10,000–12,000 B.P. The glaciomarine sediments are commonly 1–3 m in thickness and underlain by stiff pebbly mud, interpreted as till and/or glaciomarine sediments overrun by a glacier. In regions where the water depth is over 300 m the sediment thickness increases, exceeding 500 m near the shelf edge at the mouth of Bjørnøyrenna. In Bjømøyrenna itself the uppermost 15–20 m seem to consist of soft glaciomarine sediments underlain by a well-defined reflector, probably the surface of the stiff pebbly mud. Local sediment accumulations in the form of moraine ridges and extensive glaciomarine deposits (20–60m in thickness) are found at 250–300m water depth, mainly in association with submarine valleys. Topographic highs, probably moraine ridges, are also present at the shelf edge. Based on the submarine morphology and sediment distribution, an ice sheet is believed to have extended to the shelf edge at least once during the Pleistocene. Spitsbergenbanken and the northern Barents Sea have also probably been covered by an ice sheet in the Late Weichselian. Lack of suitable organic material in the glacigenic deposits has prevented precise dating. Based on the regional geology of eastern Svalbard, a correlation of this younger stage with the Late Weichselian is indicated.  相似文献   

5.
The results of a series of magnetic measurements on sediment samples are illustrated by means of examples selected from a more specialized parallel publication (Hu & Oldfield, submitted). They are interpreted in terms of magnetic components, notably, 'magnetite' of varying grain size/domain state, haematite, goethite and greigite. Wherever possible, some indication is given of changes in the relative importance of the various magnetic grain size and mineral phases through time. The main components of the magnetic assemblage are described for each of the main lithological units identified in the long core which is considered elsewhere in this volume. These assemblages are related to source areas and to depositional processes, especially in the pre-Holocene parts of the core. In the Holocene sediments, the magnetic properties cannot be interpreted solely in terms of shifts in detrital mineral sources. Evidence is presented for the presence of both biogenic magnetite and authigenic greigite. The most recent sediments point to renewed catchment erosion, probably as a result of human activity during historical times.  相似文献   

6.
Combined magnetic and geochemical studies were conducted on sediments from White Rock Lake, a reservoir in suburban Dallas (USA), to investigate how land use has affected sediment and water quality since the reservoir was filled in 1912. The chronology of a 167-cm-long core is constrained by the recognition of the pre-reservoir surface and by 137Cs results. In the reservoir sediments, magnetic susceptibility (MS) and isothermal remanent magnetization (IRM) are largely carried by detrital titanomagnetite that originally formed in igneous rocks. Titanomagnetite and associated hematite are the dominant iron oxides in a sample from the surficial deposit in the watershed but are absent in the underlying Austin Chalk. Therefore, these minerals were transported by wind into the watershed. After about 1960, systematic decreases in Ti, Fe, and Al suggest diminished input of detrital Fe-Ti oxides from the surficial deposits. MS and IRM remain constant over this interval, however, implying compensation by an increase in strongly magnetic material derived from human activity. Anthropogenic magnetite in rust and ferrite spherules (from fly ash?) are more common in sediment deposited after about 1970 than before and may account for the constant magnetization despite the implied decrease in detrital Fe-Ti oxides. An unexpected finding is the presence of authigenic greigite (Fe3S4), the abundance of which is at least partly controlled by climate. Greigite is common in sediments that predate about 1975, with zones of concentration indicated by relatively high IRM/MS. High greigite contents in sediment deposited during the early to mid-1950s and during the mid-1930s correspond to several-year periods of below-average precipitation and drought from historical records. Relatively long water-residence times in the reservoir during these periods may have led to elevated levels of sulfate available for bacterial sulfate reduction. The sulfate was probably derived via the oxidation of pyrite that is common in the underlying Austin Chalk. These results provide a basis for the paleoenvironmental interpretation of greigite occurrence in older lake sediments. The results also indicate that greigite formed rapidly and imply that it can be preserved in the amounts produced over a short time span (in this lake, only a few years). This finding thus suggests that, in some lacustrine settings, greigite is capable of recording paleomagnetic secular variation.  相似文献   

7.
The intensity of rotational remanent magnetization (RRM) acquired by single-domain greigite at a rotation frequency of 5 rps was combined with measurements of anhysteretic remanent magnetization (ARM) to calculate the effective biasing field ( Bg ) that produced the RRM. Samples of single-domain greigite had Bg values between -137 and -84 μT, and a MDFRRM of c. 80 mT. By contrast, a suite of natural and synthetic ferrimagnetic iron oxide samples, including single-domain magnetite and y Fe3O4 tape particles, acquired Bg values between -3 and -14 μT, and MDFRRM ranged between 43 and 68 mT (when RRM was acquired). Multidomain magnetite did not acquire a RRM. Bg values at 5 rps were calculated from previously published data for magnetite particles of different grain sizes, which revealed a minimum Bg value of -24 μT and a MDFRRM of 57 mT for the finest fraction (0.2-0.8 μm in diameter). In a geological example, measurements of Bg and MDFRRM were used to detect the presence of greigite in a 4 m long Late Weichselian sediment core. Variations in inclination, declination and the intensity of the natural remanent magnetization (NRM) correlate with changes in magnetic mineralogy.  相似文献   

8.
The platform limestones of Apulia are usually too weakly magnetic for precise measurement. The East Gargano basin is an autochthonous extension of Apulia and incorporates deeper water limestones which, though weakly magnetic ( J NRM ≃ 50 nG), can be reliably measured using a cryogenic magnetometer. The magnetization is attributed to the presence of detrital magnetite and the pelagic limestones yield a mean magnetic direction for the Late Cretaceous (Dec. = 335°, Inc. = 38°, α95= 6.5°). The circle of confidence associated with this direction overlaps with those associated with Late Cretaceous magnetic directions from Iblei (Sicily) and from the Vicentinian (Southern) Alps. Palaeomagnetic pole positions for Iblei, Gargano/Apulia and the Southern Alps indicate that these three autochthons need not have rotated significantly relative to each other since the Late Cretaceous. An inferred Late Cretaceous pole position for Africa coincides with the pole positions obtained from these Italian data.  相似文献   

9.
Bjørnøya, a small (178 km2) island situated between the mainland of Norway and southern Spitsbergen, provides the opportunity for the reconstruction of early Holocene terrestrial and limnic palaeoenvironments in the southwestern Barents Sea. The AMS 14C dating technique, geochemical, mineral magnetic, micro and macrofossil analyses were applied to sediments recovered from lake Stevatnet and the results are interpreted in terms of palaeoenvironmental conditions between 9800 and 8300 14C bp. After the disappearance of local glaciers before ca 980014C BP, the lake productivity increased rapidly at the same time as pioneer plant communities developed on soils which gradually became more stable. Insect data indicates that strong seasonal contrasts with mean July temperatures around 9°C and mean January temperatures around −12°C prevailed between 9500 and 8300 14C BP. These high summer temperatures, possibly as much as 4-5°C higher than the present, favoured the development of a flora including Dryas and Angelica cf. archangelica . The enhanced freeze/thaw processes led to an increased erosion of minerogenic and organic material. After 8000 14C BP the temperatures may have gradually declined. The environmental reconstruction derived from our data set supports the conceptual insolation model which proposes maximum Holocene seasonality for the Northern Hemisphere at ca 9000 14C BP.  相似文献   

10.
The acquisition of a gyroremanent magnetization (GRM) by single-domain (SD) greigite particles during alternating-field (AF) demagnetization is demonstrated. Previous palaeomagnetic studies failed to identify the presence of authigenic greigite in the glacio-marine clays studied. These clays formed the subject of an earlier debate about the validity of a Late Weichselian geomagnetic excursion (the Gothenburg Flip) in southern Sweden. The greigite carries a stable chemical remanent magnetization (CRM), which coexists with a detrital remanent magnetization (DRM) carried by magnetite. AF demagnetization could not isolate the primary remanence in the sediments where magnetite and greigite coexist, due to the overlapping coercivity spectra of the two minerals and the inability to determine the time lag between sediment deposition and CRM formation. Thermal demagnetization removed the CRM at temperatures below 400 C, but this method was hindered by the unconsolidated nature of the sediments and the formation of secondary magnetic minerals at higher temperatures. The results suggest that the low-coercivity DRM carried by magnetite was mistaken for a 'viscous' component in the earlier studies. Hence the former debate about the record of the Gothenburg Flip may have been based on erroneous palaeomagnetic interpretations or non-reproducible results. AF demagnetization procedures applied to samples suspected of bearing SD magnetic particles (such as greigite) should be carefully selected to recognize and account for GRM acquisition.  相似文献   

11.
The European Alps are a mountain belt that is characterized by a series of discrete orogenic events, which have long been recognized. Despite the inherent episodic nature of orogenic evolution, the Alps have been continuously exhumed, mainly by erosion, but also by normal faulting. Since continental collision started in the late Eocene/Early Oligocene evidence for ongoing erosional exhumation has been preserved in synorogenic sediments that accumulated in basins adjacent to the pro- and retro-side of this double-vergent mountain belt. This long-term erosion record can be used to determine exhumation rates. Lag-times calculated from fission-track (FT) ages of detrital zircon from synorogenic sediments are fairly constant for the European Alps since the Oligocene–Late Miocene. Although the fast exhuming areas were unroofed at rates of 0.4–0.7 km Myr−1, the overall average exhumation rate is between 0.2 and 0.3 km Myr−1 on a regional scale. The detrital and bedrock zircon FT data of the Alps do not detect the increase in erosion rates since the Pliocene over the past ∼5 Myr, as shown elsewhere. This increase cannot be detected yet with the detrital zircon FT method because not enough rock has been removed to widely expose zircons with Pliocene or younger cooling ages in the Alps. Long term (30 Myr) exhumation rates appear to have been approximately constant when averaged over a sliding time window of about 8 Myr, or depth window of 5 to 10 km (ZFT closure depths); shorter-term fluctuations are not identified using this method.  相似文献   

12.
Upper Jurassic red sandstones and red siltstones were collected from 67 layers at 12 localities in the Penglaizhen formation. This formation is in the north of Bazhong county (31.8°N, 106.7°E) in the Sichuan basin, which is located in the northern part of the Yangtze craton. Thermal demagnetization isolated a high-temperature magnetic component with a maximum unblocking temperature of about 690 °C from 45 layers. The primary nature of the magnetization acquisition is ascertained through the presence of magnetostratigraphic sequences with normal and reversed polarities, as well as positive fold and reversal tests at the 95 per cent confidence level. The tilt-corrected mean direction of 36 layers is D = 20.0°, I = 28.8° with α 95 = 5.8°. A Late Jurassic palaeomagentic pole at 64.7°N, 236.0°E with A 95 = 7.0° is calculated from the palaeomagnetic directions of 11 localities. This pole position agrees with the two other Late Jurassic poles from the northern part of the Yangtze craton. A characteristic Late Jurassic pole is calculated from the three poles (68.6°N, 236.0°E with A 95 = 8.0°) for the northern part of the Yangtze craton. This pole position is significantly different from that for the southern part of the Yangtze craton. This suggests that the southern part of the Yangtze craton was subjected to southward extrusion by 1700 ± 1000  km with respect to the northern part. Intracraton deformation occurred within the Yangtze craton.  相似文献   

13.
The Nova Basin contains an upper Miocene to Pliocene supradetachment sedimentary succession that records the unroofing of the Panamint metamorphic core complex, west of Death Valley, California. Basin stratigraphy reflects the evolution of sedimentation processes from landslide emplacement during basin initiation to the development of alluvial fans composed of reworked, uplifted sections of the basin fill. 40Ar/39Ar geochronology of volcanic units in middle and lower parts of the sequence provide age control on the tectonic and depositional evolution of the basin and, more generally, insights regarding the rate of change of depositional environments in supradetachment basins. Our work, along with earlier research, indicate basin deposition from 11.38 Ma to 3.35 Ma. The data imply sedimentation rates, uncorrected for compaction, of ~100 m Myr−1 in the lower, high-energy part to ~1000 m Myr−1 in the middle part characterized by debris-flow fan deposition. The observed variation in sediment flux rate during basin evolution suggests that supradetachment basins have complex depositional histories involving rapid transitions in both the style and rate of sedimentation.  相似文献   

14.
Sediment textural properties and total organic carbon (TOC) contents of three sediment cores from Maxwell Bay, King George Island, West Antarctica, record changes in Holocene glaciomarine sedimentary environments. The lower sedimentary unit is mostly composed of TOC-poor diamictons, indicating advanced coastal glacier margins and rapid iceberg discharge in proximal glaciomarine settings with limited productivity and meltwater supply. Fine-grained, TOC-rich sediments in the upper lithologic unit suggest more open water and warm conditions, leading to enhanced biological productivity due to increased nutrient-rich meltwater supply into the bay. The relationship between TOC and total sulfur (TS) indicates that the additional sulfur within the sediment has not originated from in situ pyrite formation under the reducing condition, but rather may be attributed to the detrital supply of sand-sized pyrite from the hydrothermal-origin, quartz-pyrite rocks widely distributed in King George Island. The evolution of bottom-water hydrography after deglaciation was recorded in the benthic foraminiferal stable-isotopic composition, corroborated by the TOC and lithologic changes. The Ø18O values indicate that bottom-water in Maxwell Bay was probably mixed gradually with intruding 18O-rich seawater from Bransfield Strait. In addition, the Ø13C values reflect a spatial variability in the carbon isotope distribution in Maxwell Bay, depending on marine productivity as well as terrestrial carbon fluxes by meltwater discharge. The distinct lithologic transition, dated to approximately 8000 yr BP (uncorrected) and characterized by textural and geochemical contrasts, highlights the postglacial environmental change by a major coastal glacier retreat in Maxwell Bay.  相似文献   

15.
We use teleseismic three-component digital data from the Trabzon, Turkey broadband seismic station TBZ to model the crustal structure by the receiver function method. The station is located at a structural transition from continental northeastern Anatolia to the oceanic Black Sea basin. Rocks in the region are of volcanic origin covered by young sediments. By forward modelling the radial receiver functions, we construct 1-D crustal shear velocity models that include a lower crustal low-velocity zone, indicating a partial melt mechanism which may be the source of surfacing magmatic rocks and regional volcanism. Within the top 5 km, velocities increase sharply from about 1.5 to 3.5 km s−1. Such near-surface low velocities are caused by sedimentation, extending from the Black Sea basin. Velocities at around 20 km depth have mantle-like values (about 4.25 km s−1 ), which easily correlate to magmatic rocks cropping out on the surface. At 25 km depth there is a thin low-velocity layer of about 4.0 km s−1. The average Moho velocity is about 4.6 km s−1, and its depth changes from 32 to 40 km. Arrivals on the tangential components indicate that the Moho discontinuity dips approximately southwards, in agreement with the crustal thickening to the south. We searched for the solution of receiver functions around the regional surface wave group velocity inversion results, which helped alleviate the multiple solution problem frequently encountered in receiver function modelling.
Station TBZ is a recently deployed broadband seismic station, and the aim of this study is to report on the analysis of new receiver function data. The analysis of new data in such a structurally complex region provides constraining starting models for future structural studies in the region.  相似文献   

16.
Harris Lake, a small, groundwater fed lake in the Cypress Hills area of Saskatchewan, is one of the few lacustrine basins in the Great Plains that contains a complete, uninterrupted record of Holocene sedimentation. The lithostratigraphy and variation in the mineralogical composition of the sediments in this basin provide insight into the paleolimnology and paleohydrology of the lake and surrounding watershed. Although there is no evidence that the basin was dry for extended periods during the Holocene, the lake did experience numerous short-lived episodes of high salinity, as well as significant changes in solute composition during the early to mid-Holocene. An abrupt change, from a lake dominated by detrital sediments to one characterized almost entirely by endogenic deposition, occurred about 4000 years ago in response to the combined influence of forestation of the watershed and diversion of major fluvial and detrital influx by landsliding. These adjustments to the Harris Lake drainage basin were likely the result of the onset of cooler and wetter climatic conditions after 4500 B.P. During the late Holocene, slope failure continued to sporadically provide fresh clastic material to the otherwise endogenic-sediment dominated lake.  相似文献   

17.
Non-glaciated Arctic lowlands in north-east Siberia were subjected to extensive landscape and environmental changes during the Late Quaternary. Coastal cliffs along the Arctic shelf seas expose terrestrial archives containing numerous palaeoenvironmental indicators (e.g., pollen, plant macro-fossils and mammal fossils) preserved in the permafrost. The presented sedimentological (grain size, magnetic susceptibility and biogeochemical parameters), cryolithological, geochronological (radiocarbon, accelerator mass spectrometry and infrared-stimulated luminescence), heavy mineral and palaeoecological records from Cape Mamontov Klyk record the environmental dynamics of an Arctic shelf lowland east of the Taymyr Peninsula, and thus, near the eastern edge of the Eurasian ice sheet, over the last 60 Ky. This region is also considered to be the westernmost part of Beringia, the non-glaciated landmass that lay between the Eurasian and the Laurentian ice caps during the Late Pleistocene. Several units and subunits of sand deposits, peat–sand alternations, ice-rich palaeocryosol sequences (Ice Complex) and peaty fillings of thermokarst depressions and valleys were presented. The recorded proxy data sets reflect cold stadial climate conditions between 60 and 50 Kya, moderate inderstadial conditions between 50 and 25 Kya and cold stadial conditions from 25 to 15 Kya. The Late Pleistocene to Holocene transition, including the Allerød warm period, the early to middle Holocene thermal optimum and the late Holocene cooling, are also recorded. Three phases of landscape dynamic (fluvial/alluvial, irregular slope run-off and thermokarst) were presented in a schematic model, and were subsequently correlated with the supraregional environmental history between the Early Weichselian and the Holocene.  相似文献   

18.
Sediments from the last interglacial, marine isotope stage 5e (MIS 5e), have been studied for their dinoflagellate cyst content in a core retrieved from the Vøring Plateau, Norwegian Sea. Qualitative and quantitative analyses of the data, and comparison with the surface sample and published Holocene data from the core, reveal distinct differences in hydrological surface conditions between the late Holocene and MIS 5e. A higher number of co-dominant, subordinate species in the last interglacial samples suggests there was a more pronounced seasonality of the surface water at this time. This is supported by the significant presence of Bitectatodinium tepikiense , a species that was virtually absent from the area for most of the Holocene. The seasonality signal is further substantiated by transfer-function reconstructions, which also indicates a stronger stratification of the upper water column during MIS 5e. Moreover, the assemblage data clearly show that optimal, fully marine interglacial conditions prevailed only late in MIS 5e (between ca. 117.5 and 116.5 Kya), which is in contrast with the climatic optimum early in the Holocene. Stable oxygen isotope values from planktic foraminifera for this MIS 5e optimum are comparable with the average Holocene values, but are generally ca. 0.3‰ higher than those of the earlier part of the last interglacial ( sensu stricto ). These higher δ18O values are likely to be the result of the enhanced and prolonged influence of Saalian deglacial meltwater, thus corroborating the existence of a quite differently structured sea surface, as suggested by the dinocyst data.  相似文献   

19.
This study focuses on the fluvial sediment input to the Laptev Sea and concentrates on the hydrology of the Lena basin and the geochemistry of the suspended particulate material. The paper presents data on annual water discharge, sediment transport and seasonal variations of sediment transport. The data are based on daily measurements of hydrometeorological stations and additional analyses of the SPM concentrations carried out during expeditions from 1975 to 1981. Samples of the SPM collected during an expedition in 1994 were analysed for major, trace, and rare earth elements by ICP-OES and ICP-MS. Approximately 700 km3 freshwater and 27 times 106 tons of sediment per year are supplied to the Laptev Sea by Siberian rivers, mainly by the Lena River. Due to the climatic situation of the drainage area, almost the entire material is transported between June and September. However, only a minor part of the sediments transported by the Lena River enters the Laptev Sea shelf through the main channels of the delta, while the rest is dispersed within the network of the Lena Delta. Because the Lena River drains a large basin of 2.5 times 106 km2, the chemical composition of the SPM shows a very uniform composition. In contrast, smaller rivers with more restricted catchment areas exhibit significant differences.  相似文献   

20.
Mineral and isothermal magnetic properties of Al-, Mn- and Ni-substituted haematites were characterized and their relationships evaluated in order to interpret better the results of magnetic analyses of soils and recent sediments. Aluminium, manganese and nickel haematites generally behaved as single-domain (SD) particles. The influence of incorporated Al on the magnetic behaviour of haematite was consistent with Al acting as a paramagnetic dilutent. Mass magnetic susceptibility ( χ ) and SIRM800 decreased as the level of Al substitution increased. Incorporation of Mn and Ni increased χ , which could be associated with enhancement of the spin canting effect of haematite. The stability of SIRM800 to demagnetization for Al-haematite appears to be related to a defect mechanism associated with the development of smaller crystallites arising from Al substitution. Magnetic domain rotation or flipping was probably inhibited, being blocked by structural defects during magnetization and demagnetization, and resulted in a low but stable partial SIRM (SIRM800 ). %IRM/SIRM800 demagnetization curves and estimated ( B o )CR values of ≤100  mT for Mn-haematite indicate pseudo-single-domain/multidomain-like behaviour despite Mn-haematite having particle and crystallite dimensions similar to Ni-haematite, which did not show this behaviour. Data indicate that parameters involving unsaturated, partial SIRM should be used with caution in magnetic studies of soils and sediments.  相似文献   

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