Petrogenesis of mafic enclaves from the north Taihang Yanshanian intermediate to felsic plutons: Evidence from petrological,geochemical, and zircon Hf-O isotopic data

We report the zircon Hf-O isotopic data for mafic enclaves from the Taihang Yanshanian intermediate to felsic plutons, and use them, along with the petrological, whole-rock chemical and Nd-Sr isotopic data, to reveal the petrogenesis of mafic enclaves. Mafic enclaves show magmatic textures and are finer-grained than host rocks. In places they are highly elongated due to stretching within the partially crystallized, convective felsic magma, but show no solid-state deformation. These data suggest that mafic e...     

Magma underplating and Hannuoba present crust-mantle transitional zone composition: Xenolith petrological and geochemical evidence

Studies on the deep-seated xenoliths from global volcanoes reveal that the present petrological crust-mantle boundary between the lower crust and the upper mantle actually is a transitional layer from mainly mafic granulites to ultramafic spinel lher-zolites[1,2], i.e. a transitional zone distinctive from the seismological Moho[3]. Oceanic lithosphere crust- mantle transitional zone can be established from the study on the exposed ophiolites. However, as for the continental lithosphere, since …     

Crude oil as carrier of gold: petrological and geochemical evidence from Lannigou gold deposit in southwestern Guizhou, China

Organic matter is related closely to mineralization of Lannigou gold deposit in southwestern Guizhou, China. Regionally, the distribution of organic carbon agrees well with that of faults within which gold deposits are hosted. Studies on organic petrology show that pyrobitumen, which is related most closely to mineralization, adheres to quartz vein or fills quartz veinlet. Proton-induced X-ray emission (PIXE) analysis shows an evident abundance of Au in pyrobitumen. Pyrobitumen paragenetically associates with pyrite and arsenopyrite which are the main carrier minerals of Au. The thermal simulation experiment indicates that about 99% of Au will be concentrated in oil phase in the coexisting system of oil and brine and rock. The role of crude oil in ore-forming process is: as carrier of Au, crude oil moves upwards, and undergoes thermal decomposition and thermochemical reduction when it encounters the oxidizing fluid within the Trassic turbidity; Au is thus released from crude oil, reduced and precipitated. Project supported by the Climbing Project (No. PA30) and the National Natural Science Foundation of China (Grant No. 49673190).     

Evaluation of magmatic processes for the products of the Nevado del Ruiz Volcano, Colombia from geochemical and petrological data

Trace-element concentrations of the eruptive products from the Nevado del Ruiz volcano indicate that at least for the last 1 Ma, the major controlling factor in the evolution of the magma has been a simple fractional crystallization.The Zr/Hf ratios suggest that the source material is mantle-like in origin and whilst subduction-related contamination of the source material has taken place, there is no evidence that assimilation of continental crust has affected the series.No convincing geochemical evidence for magma mixing was found, and data on banded pumices of Pleistocene, Historic and the 1985 eruptions strongly support a crystal fractionation model to explain the compositional variation of their glasses. Therefore, if mixing has taken place it can only be a mixing of layers within a stratified or partially stratified magma chamber.Modeling of fractional crystallization using a stepwise program has been undertaken and least-squares approximations with small residuals are commensurate with analyzed samples. Crystal fractionation models with plagioclase dominating two-pyroxenes and iron oxides give good fits for all calculations. We conclude that simple crystal fractionation is the process most consistent with major- and trace-element variations in the Ruiz series. This closed-system model requires at least 77% crystal fractionation of a basaltic parent to generate the observed compositions of dacites.     

Anatexis in Himalayan crust: Evidence from geochemical and chronological investigations of Higher Himalayan Crystallines

The Higher Himalayan leucogranites (HHL) are of great interest for the following reasons: (1) determin- ing the correlations of HHL with HHC may help us to understand metamorphism, deformation and magam- tism during the post-collision period; (2) the Himala- yan orogeny provides an ideal spot to validate the ex- isting models and theories of granite origin during the post-collision period, and to understand the role of anatexis on orogenic crustal evolution. Although nu- merous attempts ha…     

Geochemical and petrological relations in some deccan basalts, Western Maharashtra, India

Petrographic and geochemical data are given for some basaltic rocks from the Koynaghat, Ambaghat and Panvel sections of the western Deccan volcanic province. This study confirms geochemical features established earlier for the Deccan basalts but brings out minor additional characters. Mineralogical and major-element compositions of the basaltic flows from the Koyna and Panvel sections indicate tholeiitic affinity; the Ambaghat flows exhibit a slight affinity towards alkali basalt. Rare earth element (REE) distribution patterns and trace-element abundances suggest minor fractionation of olivine and plagioclase during the evolution of the flows. The general similarity of chemical and mineralogical features over a wide area and the lack of conspicuous inter-element relationships suggest that the flows reflect the combined effects of partial melting, minor mineral fractionation and selective crustal contamination.     

Himalayan metamorphism and deformations in the North Himalayan Belt (southern Tibet,China)

The Kangmar Massif which has been attributed to the North Himalayan Belt of two-mica granites in southern Tibet (China) is shown to be an orthogneiss in the core of a dome which displays an intermediate high-pressure type metamorphism, Himalayan in age (40 to 20 Ma) and above the Main Central Sheet. This metamorphism took place during high shear strain deformation, and it is not recorded to the west where North Himalayan plutons have developed contact metamorphism.     

petrological and geochemical characteristics of quarternary volcanic rocks in haixing area,eastern north china

Field investigation and lab analysis on samples were carried out for Quaternary volcanoes, including Xiaoshan volcano, Dashan volcano and Bianzhuang hidden volcano, in Haixing area, east of North China. Results show that Xiaoshan volcano with the eruptive material of volcanic scoria, crystal fragments and volcanic ash is a maar volcano, the eruptive pattern is pheatomagmatic eruption, and the influence scope is near the crater. Dashan volcano exploded in the early stage, and then the magma intruded, forming the volcanic neck. The eruption strength and scale are limited, and the eruptive materials are scoria, volcanic agglomerate and dense lava neck. The volcanic rocks in Bianzhuang are porosity and dense volcanic rocks and volcanic breccia, reflecting the pattern of weak explosive eruption and lava flow, and the K-Ar age dating on volcanic rocks indicates that the eruption happened in early Pleistocene. Xiaoshan volcanic scoria and Bianzhuang hidden volcanic rocks are mainly basaltic, Dashan volcanic rocks with lower SiO₂ content are nephelinite in composition. Their oxide contents have no linear relationship, indicating that there is no magma evolution relationship between these magmas from the three places. Three volcanic rocks all have enrichment of light rare earth. The Bianzhuang volcanic rocks are rich in large ion lithophile elements, and have no high field strength elements Zr and Hf, Ti losses. The volcanic materials from Xiaoshan and Dashan are intensively rich in Th, U, Nb and Ta, and significantly poor in K and Ti. Although the magmas from these three places in Haixing area may all come from asthenosphere, the volcanic materials have different petrological and geochemical features, and relatively independent volcanic structures, therefore, they experienced different magma processes.     

Cumulate nodules as evidence for convective fractionation in a phonolite magma chamber

The physical mechanism by which chemical zonation develops in magma chambers has been controversial partly because unambiguous geological constraints have been lacking. The 11,000 years B.P. eruption of Laacher See Volcano produced a zoned tephra deposit and also ejected crystal-rich nodules which provide a snapshot of the materials crystallising at the magma chamber margins. New data on petrography and chemical compositions of nodules, their cumulate minerals and interstitial glasses are used to deduce the chemical evolution of the phonolite melt due to fractional crystallisation of the mineral assemblages. These data, together with those on the vertical zonation of the melt in the bulk of the chamber, are shown to be consistent with a model of stratification of the chamber by convective fractionation, in which a thin boundary layer of residual melt from fractional crystallisation ascends at the chamber side and accumulates at the roof. Crystallisation could have provided buoyancy to drive convection by enriching incompatible volatile components (mainly water) in the residual melt. Available fluid dynamic studies of single- and double-diffusive boundary layers are used to assess convection in the Laacher See chamber. The boundary layer is likely to have been: (1) laminar, which implies that the density gradient in the chamber steepened upwards; (2) in the counterflow regime, in which compositional and thermal layers flow in opposite directions; and (3) thin ( 10 cm), estimated from theory for a flat wall, suggesting that wall morphology could be important in determining boundary layer characteristics. Estimates of mass transfer rates due to this mechanism suggest that the chamber could have become stratified in a time of the order of 10³ years.     

Variations in surface manifestations at vulcano (Aeolian Islands,Italy) as a possible evidence of deep processes

Five years of geochemical surveillance at Vulcano have shown interesting changes in the physico-chemical characters of the fumaroles at the crater and of the phreatic waters in the surrounding area. In particular, 1) The maximum temperature of the fumaroles, which had been of about 200°C for at least 30 years, rose suddenly to above 300°C: after a period of rather constant values, a decreasing trend has recently been observed; 2) An increase of CO₂, S compounds and HF with respect to HCl, B, Br occurred in the gas composition contemporaneous to the rise in temperature. This increase is now gradually declining; 3) Higher concentrations of sulphate ion and silica in phreatic waters accompanied the thermal changes observed at the fumaroles. According to a model previously proposed (Martini et al., 1980), the increase in the above mentioned factors would reflect an increasing magmatic contribution to the volcanic system, which might be due to an increased permeability to fluids at depth. Because a sensible seismic shock occurred in the area a few months after the first chemical and thermal variations had been observed, such variations may be regarded as forerunners of the seismic event, and may be used to forecast some months in advance changes occurring at depth. The work was carried out within the research programme of C.N.R. Centro di Studio per la Mineralogia e la Geochimica dei Sedimenti, Florence, Italy.     

Hydroclimatic significance of stable isotopes in precipitation from glaciers of Garhwal Himalaya,Upper Ganga Basin (UGB), India

Stable isotopic composition of precipitation as preserved in continental proxy climate archives (e.g., ice cores, lacustrine sediments, tree rings, groundwater, and organic matter) can sensitively record fluctuations in local meteorological variables. These are important natural climatic tracers to understand the atmospheric circulation patterns and hydrological cycle and to reconstruct past climate from archives. Precipitation was collected at Dokriani Glacier to understand the response of glaciers to climate change in the Garhwal Central Himalaya, Upper Ganga Basin. The local meteoric water line deviates from the global meteoric water line and is useful for the identification of moisture source in the region. The data suggest different clusters of isotopic signals, that is, summer (June–September) and winter (November–April); the mean values of δ¹⁸O, δD, and d ‰ during summer are ?13.03‰, ?84.49‰, and 19.78 ‰, respectively, whereas during winter, the mean values of δ¹⁸O, δD, and d ‰ are ?7.59‰, ?36.28‰, and 24.46 ‰, respectively. Backward wind trajectory analysis ascertains that the major source of precipitation during summer is from the Indian Summer Monsoon and during winter from the westerlies. Regression analysis has been carried out in order to establish interrelationship between the precipitation isotopic signatures and meteorological variables such as air temperature, relative humidity, and precipitation. Temperature and precipitation have good correlation with the isotopic signatures of precipitation with R² values >.5, suggesting that both temperature and amount effects prevail in the study region. Multiple regression analysis found strong relationships for both the seasons. The relationship of deuterium excess with δ¹⁸O, relative humidity, and precipitation are significant for the winter season. No significant relationships of deuterium excess were found with other meteorological variables such as temperature and radiation. The correlation and regression analysis performed are significant and valuable for interpretation of processes in the hydrological cycle as well as for interpretation of palaeoclimate records from the region.     

Origin of Baotoudong syenites in North China Craton: Petrological,mineralogical and geochemical evidence

Baotoudong syenite pluton is located to the east of Baotou City, Inner Mongolia, the westernmost part of the Triassic alkaline magmatic belt along the northern margin of the North China Craton(NCC). Zircon U-Pb age, petrological, mineralogical and geochemical data of the pluton were obtained in this paper, to constrain its origin and mantle source characteristics. The pluton is composed of nepheline-clinopyroxene syenite and alkali-feldspar syenite, with zircon U-Pb age of 214.7±1.1 Ma. Diopside(cores)-aegirine-augite(rims), biotite, orthoclase and nepheline are the major minerals. The Baotoudong syenites have high contents of rare earth elements(REE), and are characterized by enrichment in light rare earth elements(LREE) and large ion lithophile elements(LILE; e.g., Rb, Ba, Sr), depletion in heavy rare earth elements(HREE) and high field strength elements(HFSE). They show enriched Sr-Nd isotopic compositions with initial ~87Sr/~86Sr ranging from 0.7061 to 0.7067 and ε_Nd(t) values from –9.0 to –11.2. Mineralogy, petrology and geochemical studies show that the parental magma of the syenites is SiO_2-undersaturated potassic-ultrapotassic, and is characterized by high contents of Ca O, Fe_2O_3, K_2O, Na_2O and fluid compositions(H_2O), and by high temperature and high oxygen fugacity. The syenites were originated from a phlogopite-rich, enriched lithospheric mantle source in garnet-stable area(80 km). The occurrence of the Baotoudong syenites, together with many other ultrapotassic, alkaline complexes of similar ages on the northern margin of the NCC in Late Triassic implies that the lithospheric mantle beneath the northern margin of the NCC was previously metasomatized by melts/fluids from the subducted, altered paleo-Mongolian oceanic crust, and the northern margin of the craton has entered into an extensively extensional regime as a destructive continental margin in Late Triassic.     

Rare earth abundances in hornblende and clinopyroxene of a hornblende lherzolite xenolith: Implications for upper mantle fractionation processes

Hornblende and clinopyroxene of one of a suite of hornblende lherzolite xenoliths probably derived from the upper mantle are rich in light rare earths compared with clinopyroxenes from spinel lherzolite xenoliths. Partial melting of this hornblende lherzolite assemblage could yield a liquid with the rare earths, uranium and potassium abundances of a nephelinite.     

Hydrogeochemistry and quality of groundwater in a part of Damodar Valley,Eastern India: an integrated geochemical and statistical approach

The influence of geochemical processes and quality of groundwater in a rural tract of Damodar Valley region were investigated. The study has distinguished the groundwater as fresh, soft to moderately hard and mainly CaHCO₃ type. The paired samples student’s t test shows the significant seasonal variations of pH, HCO₃^?, and Fe. Amphoteric exchange has lessened HCO₃^? concentration in post-monsoon which subsequently has caused to drop pH. Quite the reverse, the monsoon precipitation has triggered the additional release of Fe from iron-bearing sediments. The contaminant Cl^? is from the domestic wastewater as is evidenced by field observations. The inter-variable relations, cation and anion mechanisms, and mineral saturation indices reveal that the dissolutions of silicate and carbonate minerals are the primary sources of major ions in groundwater. The chloro-alkaline indices showed the role of ion exchange too in water chemistry. The R-mode factor analysis also successfully identified two dominant processes regulating water chemistry—geogenic sources (Ca²⁺, Mg²⁺, Na⁺, and HCO₃^?) and anthropogenic inputs (mainly Cl^?). The groundwater is found unsuitable for drinking at 82 and 93% of wells in pre- and post-monsoon seasons, respectively mainly due to elevated Fe content. The water from more than 90% of wells is appropriate for irrigation uses. The study recommends the proper treatment of contaminated water for consumption and measures to protect the groundwater from the waste water infiltration.     

Impact of forest degradation on streamflow regime and runoff response to rainfall in the Garhwal Himalaya,Northwest India

Baseflows have declined for decades in the Lesser Himalaya but the causes are still debated. This paper compares variations in streamflow response over three years for two similar headwater catchments in northwest India with largely undisturbed (Arnigad) and highly degraded (Bansigad) oak forest. Hydrograph analysis suggested no catchment leakage, thereby allowing meaningful comparisons. The mean annual runoff coefficient for Arnigad was 54% (range 44–61%) against 62% (53–69%) at Bansigad. Despite greater total runoff Q_t (by 250 mm year^–1), baseflow at Bansigad ceased by March, but was perennial at Arnigad (making up 90% of Q_t vs. 51% at Bansigad). Arnigad storm flows, Q_s, were modest (8–11% of Q_t) and occurred mostly during monsoons (78–98%), while Q_s at Bansigad was 49% of Q_t and occurred also during post-monsoon seasons. Our results underscore the importance of maintaining soil water retention capacity after forest removal to maintain baseflow levels.

EDITOR D. Koutsoyiannis; ASSOCIATE EDITOR D. Gerten     

Groundwater mineralisation processes in Mediterranean semi‐arid systems (Cap‐Bon,North east of Tunisia): hydrogeological and geochemical approaches

The groundwater of the Korba plain represents major water resources in Tunisia. The Plio‐Quaternary unconfined aquifer of the Cap‐Bon (north‐east Tunisia) is subject to the intensive agricultural activities and high groundwater pumping rates due to the increasing of the groundwater extraction. The degradation of the groundwater quality is characterized by the salinization phenomena. Groundwater were sampled and analysed for physic‐chemical parameters: Ca²⁺, Mg²⁺, Na⁺, K⁺, Cl^‐, SO₄^2‐, HCO₃^‐, NO₃^‐, pH, electrical conductivity (EC), and the temperature (T°). The hydrochemical analysis is coupled with the calculation of the saturation indexes (SI gypsum, SI halite, SI calcite and SI dolomite), ionic derivation and with the ion correlations compared to chloride concentrations: Na⁺/ Cl^‐, Ca²⁺/ Cl^‐ and Mg²⁺/ Cl^‐ ratios. Seawater fractions in the groundwater were calculated using the chloride concentration. Those processes can be used as indicators of seawater intrusion progression. EC methods were also conducted to obtain new informations on the spatial scales and dynamics of the fresh water–seawater interface of coastal groundwater exchange. The mixing zone between freshwater and saltwater was clearly observed from the EC profile in the investigated area where a strong increase in EC with depth was observed, corresponding to the freshwater and saltwater interface. Results of hydrochemical study revealed the presence of direct cation exchange linked to seawater intrusion and dissolution processes associated with cations exchange. These results, together with EC investigation, indicated that the groundwater is affected by seawater intrusion and is still major actor as a source of salinization of the groundwater in Korba coastal plain. Further isotopic and hydrological investigations will be necessary to identify and more understood the underlying mechanisms. Copyright © 2012 John Wiley & Sons, Ltd.     

Limnological Studies in a Subtropical System (Lake Sattal,India)

A limnological study was carried out in the subtropical Lake Sattal (Kumaun Himalaya) during 1979. The lake was thermally stratified during warm months and a low percentage saturation of dissolved oxygen occurred in the bottom waters. Two maxima of phytoplankton occurred in the Eastern basin in contrast to only one in the Western basin. The peak in the latter developed more than a month (October) after the second peak in the former (August). Bacillariophyceae contributed highest in the Western basin (43.2%) whereas the Dinophyceae had the least share in the Eastern basin (8.0%). Most of the dominant phytoplankters were: Synedra ulna, Fragilaria, Gymnodinium, Crucigenia and Closteridium siamensis. Interestingly, blue-green alga Nostoc, dominated for some time in autumn. A total of 12 genera of rotifers, 6 genera of cladocerans and 1 genus of copepods were found in Lake Sattal basins. Dominant zooplankters included Keratella, Cyclops, Anuraeopsis, Polyarthra and Trichocerca, and there is a high ratio of rotifers to copepods and cladocerans. On comparing the averaged values of both the basins, the Eastern basin showed a 64% larger population of zooplankton than the Western basin. A comparison is made with the plankton of the other subtropical lake-systems of this region.     

Genesis and evolution of the fumaroles of vulcano (Aeolian Islands,Italy): a geochemical model

A geochemical model explaining the presence of fumaroles having different gas composition and temperature at the top of the crater and along the northeastern coast of Vulcano island is proposed. A pressurized biphase (liquid-vapor) reservoir at the depth of about 2 km is hypothesized. Energy and mass balance sheets controlP-T conditions in the system.P-T must vary along a boiling curve of brine as liquid is present. The CO₂ content in the steam is governed by the thermodynamic properties of the fluids in the H₂-NaCl-CO₂ system. On the assumption that oxygen fugacity in the system is between the HM-FMQ oxygen buffers, observed SO₂/H₂S, CO₂/CO, CO/CH₄ ratios in the fumarolic gases at the Fossa crater appear in equilibrium with a temperature higher than that observed, such as may exist at depth. The more reduced gas phases present on the sea-side may result from re-equilibrium processes in shallower aquifers. The suggested model would help in monitoring changes in volcanic activity by analyzing fumarolic gases.     

Varicolored and vesiculated tuffs from La Fossa volcano,Vulcano Island (Aeolian Archipelago,Italy): evidence of syndepositional alteration processes

Chemical and mineralogical data for samples collected from a surge sequence from La Fossa cone (Vulcano Island, Italy) show a wide variety of alteration states between adjoining beds, the macroscopic features of which are expressed by various degrees of reddening. The effects of the alteration processes on pyroclastic rocks are as follows: hydration and oxidation of each component of the pyroclastic rocks to varying degrees; formation of authigenic smectite; precipitation of a large variety of soluble salts; and corrosion on the surface of glass fragments (pitting). Dry surge beds, emplaced from a two-phase, dry steam + solid, suspension do not show significant alteration. By contrast, wet surge deposits, suggesting an emplacement from free water-bearing turbulent flows, show an increasing degree of alteration, passing from grey to red coloured beds. The strict relationship between the present alteration state and the depositional unit rules out any post-depositional processes. The occurrence of alteration in wet surge beds and the lack of alteration in dry beds shows that the main controlling agent was water condensed from the eruptive cloud and suggests a syn-depositional character to the alteration itself. These observed differences can be ascribed to the different chemical reactivities of the water, probably related to the amounts of acidic species carried by the eruptive cloud and/or by the efficiency of their capture during the condensation of the water vapour.     

Petrogenesis of Shangyu gabbro-diorites in western Shandong: Geochronological and geochemical evidence

Chronology and geochemistry of the Shangyu gabbro-diorite in western Shandong were studied to understand their petrogenesis and the nature of the Mesozoic lithospheric mantle. The Shangyu intru-sion is mainly composed of a suite of gabbro-diorite. Zircons from the intrusion display eu-hedral-subhedral in shape and have high Th/U ratios (1.23―2.87), implying their magmatic origin. LA-ICP-MS zircon U-Pb dating results for two samples indicate that they were formed in the Early Cre-taceous, yielding weighted mean 206Pb/238U ages of 129±1Ma and 134±2Ma, respectively. Except for early cumulate such as sample QT-19, their SiO2 and MgO contents range from 50.12% to 56.37% and from 3.52% to 6.37%, respectively. Moreover, the gabbro-diorites are characterized by high Mg# (0.54―0.63), enrichment in Na (Na2O/K2O ratios more than 1), Cr (73×10-6―217×10-6) and Ni (34×10-6―241×10-6), and intensive enrichments in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) and depletion in high field strength elements (HFSEs). Their initial 87Sr/86Sr ratios and ε Nd(t) values range from 0.70962 to 0.71081 and from-16.60 to-13.04, respectively. Taken together with the Early Creta-ceous high-Mg diorites and the mantle xenoliths from the Tietonggou and Jinling as well as basalts from the Fangcheng and Feixian, it is suggested that the primary magma for the Shangyu gab-bro-diorites should be derived from the enriched lithospheric mantle intensively modified by conti-nental crust. The Sr-Nd-Pb isotopic compositions for the Early Cretaceous high-Mg diorites in western Shandong display a trend of spatial variations, i.e., initial 87Sr/86Sr, 207Pb/204Pb and 208Pb/204Pb ratios de-creasing and ε Nd(t) values increasing from southeast to northwest in western Shandong, which is con-sistent with the tectonic model that the Yangtze Craton subducted beneath the North China Craton oriented in north-west direction in the Early Mesozoic.