Lithophile elements in Huronian low-Ti continental tholeiites from Canada, and evolution of the Precambrian mantle

Huronian basalts from central Ontario, Canada, dated at about 2450 Ma and associated with an early rifting episode, are classified as siliceous, low-TiNb tholeiites. They display strong enrichment in large-ion lithophile (LILE) and light rare earth (LREE) elements compared to modern oceanic lavas. The tectonic setting and geochemistry resemble Mesozoic rift-related low-Ti flood basalts, including the Ferrar Group of Antarctica, and the Parana and equivalent Etendeka volcanics of south Brazil and Namibia, respectively. High LILE/LREE ratios are also similar to subduction-related island arc tholeiites, and it is suggested that enrichment of the Huronian lithospheric mantle source occurred through ancient subduction of crustal material, probably during formation and consolidation of the Archean continental crust.Melting models suggest that Huronian subcontinental mantle source compositions, derived from least contaminated, aphyric, mafic end-members, had already undergone a complex evolution, including withdrawal of Archean basalts and hydrous enrichment in incompatible components. Despite several subsequent melting episodes and a second, probably magmatic, enrichment event, however, many aspects of the Huronian source signature were preserved, and appeared in later basaltic products of this mantle mass. Keweenawan volcanics, for example, dated at about 1100 Ma, preserve low P, Zr, Ti and HREE abundances.     

汤加地区地幔结构及俯冲演化的地球动力学研究

汤加的俯冲板块结构复杂,板块形态的起因和形成机制不是很清晰.为了探索其演化,我们借助于板块运动学、海底年龄和关键的大地构造特征,用地球动力学模型模拟了本区域40 Ma之后的俯冲历史.通过研究我们发现,沿着海沟的分布位置,不同的黏度、流体的吸力与浮力比特征控制着板块的力学强度,从而影响着板块的俯冲角度和形态.我们的模型显示在俯冲板块形成前,研究区表面西侧的黏度剖面形成的弱化带为水平低黏度区,它对俯冲的发生有一定的引导作用,高黏度的上覆板块的存在和俯冲导致的地幔流体的吸力降低了俯冲板块的倾角,15°S附近的俯冲板块的分离发生在16-8 Ma之间.最后我们通过匹配实际的构造特征,包括贝尼奥夫带和波速结构剖面,用所得的相关性最佳的模型对本区的地幔结构随时间演化提供探索.

     

Magnetic stratigraphy and magnetic-petrologic properties of Precambrian Gardar lavas,South Greenland

We present major and trace element data for olivines and rapidly quenched groundmass material separated from eight samples of basaltic rock. From these data apparent olivine/liquid distribution coefficients (D) for the elements Mg, Mn, Ni, Co, Cr, Sc, Na, Sm, and Ca have been calculated. Petrographic and electron microprobe studies indicate that olivines in most of these samples are but slightly zoned and groundmass glasses are essentially uniform in composition; these data suggest that the co-existing olivine-groundmass pairs are in equilibrium. In addition, olivine crystallization temperatures were calculated using experimental calibrations of lnD vs.1/T for the elements Mg, Fe, Mn, Ni, and Co. A high degree of concordancy for the resulting temperatures, based on five different elements for most samples, also suggests that olivine-groundmass equilibrium was obtained. We conclude that the apparent olivine/liquidD's derived from this study are representative of equilibriumD's, but emphasize that variations in temperature, and possibly bulk composition, strongly affect suchD's in natural magmas.     

Precambrian glaciations and the evolution of the atmosphere

Precambrian glaciations appear to be confined to two periods, one in the early Proterozoic between 2.5 and 2 Gyears BP (Before Present) and the other in the late Proterozoic between 1 and 0.57 Gyear BP. Possible reasons for these broad features of the Precambrian climate have been investigated using a simple model for the mean surface temperature of the Earth that partially compensates for the evolution of the Sun by variations in the atmospheric CO₂ content caused by outgassing, the formation of continents and the weathering of the Earth’s land surface. It is shown that the model can explain the main changes in the Precambrian climate if the early Proterozoic glaciations were caused by a major episode of continental land building commencing about 3 Gyears BP while the late Proterozoic glaciations resulted from biologicallyenhanced weathering of the land surface due to the proliferation of life forms in the transition from the Proterozoic to the Phanerozoic that began about 1 Gyear BP.     

Lagging mantle convection,the geoid and mantle structure

In numerical models of convection incorporating migration of a simulated subduction zone, the main descending flow lags far behind the migrating trench, and a geoid low is associated with the main descending flow. This provides physical plausibility for the suggestion by Chase and Sprowl that present very long-wavelength (degree 2–4) geoid lows are associated with Mesozoic trench locations, and suggests further that the present long-wavelength geoid, deep mantle structure and hotspot distribution may be straightforward consequences of plate evolution since the Upper Paleozoic.     

Rare gas systematics: formation of the atmosphere, evolution and structure of the Earth's mantle

To explain the rare gas content and isotopic composition measured in modern terrestrial materials we explore in this paper an Earth model based on four reservoirs: atmosphere, continental crust, upper mantle and lower mantle.This exploration employs three tools: mass balance equations, the concept of mean age of outgassing and the systematic use of all of the rare gases involving both absolute amount and isotopic composition.The results obtained are as follows: half of the Earth's mantle is 99% outgassed. Outgassing occurred in an early very intense stage within the first 50 Ma of Earth history and a slow continuous stage which continues to the present day. The mean age of the atmosphere is 4.4 Ga.Our model with four main reservoirs explains quantitatively both isotopic and chemical ratios, assuming that He migrates from the lower to the upper mantle whereas the heavy rare gases did not.Noble gas fluxes for He, Ar and Xe from different reservoirs have been estimated. The results constrain the K content in the earth to 278 ppm. Several geodynamic consequences are discussed.     

Chemical heterogeneity of the Archaean mantle,composition of the earth and mantle evolution

New rare earth element (REE) data for Archaean basalts and spinifex-textured peridotites (STP) show a range of La/Sm ratios (chondrite-normalized) from 0.36 to 3.5, with the bulk of the data in the range 0.7–1.3. This supports the hypothesis, based on Sr isotope initial ratios, that the Archaean mantle was chemically heterogeneous. We suggest that the bulk mantle source for Archaean basaltic magmas was close to an undepleted earth material. An average chemical composition of the Archaean mantle is estimated using chemical regularities observed in Archaean STP and high-magnesian basalts. TiO₂ and MgO data show an inverse correlation which intersects the MgO axis at about 50% MgO (Fo₉₂). TiO₂ abundance in the mantle source is measured on this plot by assigning anMgO= 38% for the mantle. Concentrations of other elements are also estimated and these data are then used to obtain a composition for the bulk earth. We suggest an earth model with about 1.35 times ordinary chondrite abundances of refractory lithophile elements and about 0.2 times carbonaceous type 1 chondrite abundances of moderately volatile elements (such as Na, Rb, K, Mn). P shows severe depletion in the model earth relative to carbonaceous chondrites, a feature either due to volatilization or core formation (preferred). Our data support the hypothesis of Ringwood that the source material for the earth is a carbonaceous chondrite-like material.The generation of mid-ocean ridge basalts (MORB) is examined in the light of the model earth composition and Al₂O₃/TiO₂, CaO/TiO₂ ratios. It is suggested that for primitive basalts, these values can be used to predict the residual phases in their source. Comparison of chemical characteristics of inferred sources for 2.7-b.y. Archaean basalts and modern “normal” MORB indicates that the MORB source is severely depleted in highly incompatible elements such as Cs, Ba, Rb, U, Th, K, La and Nb, but has comparable abundances of less incompatible elements such as Ti, Zr, Y, Yb. The cause of the depletion in the MORB source is examined in terms of crust formation and extraction of silica-undersaturated melts. The latter seems to be a more likely explanation, since the degree of enrichment of highly incompatible elements in the crust only accounts for up to 40% of their abundances in the bulk earth and cannot match the depletion pattern in normal MORB. A large volume of material, less depleted than the source for normal MORB must therefore exist in the mantle and can serve as the source for the ocean island basalts and “normal” MORB.Three different mantle evolution models are examined and each suggests that the mantle is stratified with respect to abundances of incompatible trace elements. We suggest that no satisfactory model is available to fully explain the spectrum of geochemical and geophysical data. In particular the Pb and Sr isotope data on oceanic basalts, the depletion patterns of MORB and the balance between lithophile abundances in the crust and mantle, are important geochemical constraints to mantle models. Further modelling of the mantle evolution will be dependent on firmer information on the role of subduction, mantle convection pattern, and basalt production through geologic time together with a better understanding of the nature of Archaean crustal genesis.     

Isotopic evolution of lavas from Haleakala Crater, Hawaii

Pb and Sr isotopic ratios have been determined for tholeiitic shield-building, alkalic cap, and post-erosional stage lavas from Haleakala Crater. Pb isotopic compositions of the tholeiites overlap those of the alkalic cap lavas, although⁸⁷Sr/⁸⁶Sr ratios of these two suites are distinct. Alkalic cap and post-erosional lavas appear to be indistinguishable on the basis of Sr and Pb isotopic composition.Sr and Pb isotopic ratios of Haleakala post-shield-building lavas are positively correlated. Such a trend is previously undocumented for any suite of Hawaiian lavas and contrasts with the general negative correlation observed for data from Hawaiian tholeiites. These relations are consistent with a three-component petrogenetic mixing model. Specifically, it is proposed that magma batches at individual Hawaiian volcanoes formed by: (1) mixing of melts generated from mantle plumes containing two isotopically distinct mantle components (primitive vs. enriched), and (2) subsequent variable degrees of interaction between these plume melts and a third (MORB signature) mantle reservoir prior to their emplacement in a crustal magma chamber. These observations and inferences provide new constraints on physical models of Hawaiian magmatism. Based on observed temporal isotopic variations of Haleakala lavas, it is suggested that the ratio of enriched: primitive mantle components in the Hawaiian plume source decreases during the waning stages of alkalic volcanism. Over the same time interval, both decreasing melt production and protracted residence of ascending melts within the upper mantle contribute to a systematic increase in the ratio of depleted vs. plume component.     

Komatiites and the structure of the Archaean mantle

The existence of Archaean komatiites with eruption temperatures greater than 1650°C requires that the mantle be vertically differentiated by the time of komatiite eruption. If in the unlikely event that undifferentiated mantle had survived primordial planetary differentiation and had been hot enough to deliver 1650°C komatiite, it would have been extensively molten to depths of ～250 km, resulting in rapid, profound, vertical differentiation anyway. During primordial differentiation (or Archaean komatiite petrogenesis) the high density and compressibility of ultrabasic melt allowed storage of a global melt layer beneath a buoyant residue of dunite and/or harzburgite. This refractory cap segregated by extraction of melt both upwards and downwards from the depth at which the density contrast between crystals and liquid vanishes. Eruption of komatiite from the melt layer by corrosion of the cap was the Archaean earth's principal means of dissipating excess heat. This subterranean magma ocean precluded vertical homogenization of the Archaean mantle by convection but effectively absorbed lateral mantle heterogeneities and imposed the relative uniformity of maximum eruption temperature and MgO contents (～32%) seen in primitive Archaean komatiites on all continents.Verification of the postulated density relations of liquids and crystals to 100 kbar becomes a pressing concern in view of the expected consequences these relations may have had.     

Isotopic inferences on the chemical structure of the mantle

Variations in the isotopic composition of rocks derived from the upper mantle can be used to infer the chemical history and structure of the Earth's interior. The most prominent material in the upper mantle is the source of mid-ocean ridge basalts (MORB). The MORB source is characterized by a general depletion in incompatible elements caused by the extraction of the continental crust from the mantle. At least three other isotopically distinct components are recognized in the suboceanic mantle. All three could be generated by the recycling of near surface materials (oceanic crust, pelagic sediments, continental lithospheric mantle) into the mantle by subduction. Therefore, the isotope data do not require a compositionally layered mantle, but neither do they deny the existence of such layering. Correlations between the volumetric output of plume volcanism with the reversal frequency of the Earth's magnetic field, and between the geographic distribution of isotopic variability in oceanic volcanism with seismic tomography suggest input of deep mantle material to surface volcanism in the form of deep mantle plumes. Volcanism on the continents shows a much wider range in isotopic composition than does oceanic volcanism. The extreme isotopic compositions observed for some continental magmas and mantle xenoliths indicate long-term (up to 3.3 Gyr) preservation of compositionally distinct material in thick (>200 km) sections of continental lithospheric mantle.     

The progressive onset and evolution of Precambrian subduction and plate tectonics

Science China Earth Sciences - The regime of plate tectonics on early Earth is one of the fundamental problems in Earth sciences. Precambrian era takes the majority (ca. 88%) of Earth’s...     

中国地幔结构及物性研究的进展

对2004——2007年中国地球物理学家在地幔内部结构和物质性质方面的研究工作进行了总结. 对地幔结构的地震波速度成像,地幔介质的各向异性,地幔间断面,地幔对流,以及地幔介质物性进行了综述,指出了各方面的主要内容,使用的主要方法和主要结果. 从这4年的研究可以发现,一些原有的研究领域工作更加深入,方法更加先进,而且进行了广泛的国际合作,合作的范围也逐渐扩大,方式多样,并出现了一些新的研究方向.      

Small-scale seismic heterogeneity and mantle structure

George Helffrich discusses the links between seismology and geochemistry in the Bullerwell Lecture 2005, delivered at the annual meeting of the European Union of Geosciences in Vienna.     

Tracking the lithium isotopic evolution of the mantle using carbonatites

Carbonatites are mantle-derived, intraplate magmas that provide a means of documenting isotopic variations of the Earth's mantle through time. To investigate the secular Li isotopic evolution of the mantle and to test whether Li isotopes document systematic recycling of material processed at or near the Earth's surface into the mantle, we analyzed the Li isotopic compositions of carbonatites and spatially associated mafic silicate rocks. The Li isotopic compositions of Archean (2.7 Ga) to Recent carbonatites (δ⁷Li = 4.1 ± 1.3 (n = 23, 1σ)) overlap the range typical for modern mantle-derived rocks, and do not change with time, despite ongoing crustal recycling. Thus, the average Li isotopic composition of recycled crustal components has not deviated greatly from the mantle value (~ + 4) and/or Li diffusion is sufficiently fast to attenuate significant heterogeneities over timescales of 10⁸ years. Modeling of Li diffusion at mantle temperatures suggests that limited δ⁷Li variation in the mantle through time reflects the more effective homogenization of Li in the mantle compared to radiogenic isotope systems. The real (but limited) variations in δ⁷Li that exist in modern mantle-derived magmas as well as carbonatites studied here may reflect isotopic fractionation associated with shallow-level processes, such as crustal assimilation and diffusive isotopic fractionation in magmatic systems, with some of the scatter possibly related to low-temperature alteration.     

Oceanic island Pb: Two-stage histories and mantle evolution

Leads in basaltic suites from seven oceanic islands form linear arrays on²⁰⁶Pb/²⁰⁴Pb versus²⁰⁷Pb/²⁰⁴Pb diagrams. These arrays are more reasonably interpreted as secondary isochrons than as mixing lines, because of their systematic relationship. Separate two-stage histories calculated for the leads from each island indicate that the source materials for the magmas were derived from a single primary reservoir with present²³⁸U/²⁰⁴Pb of 7.91 ± 0.04 by secondary enrichment in U/Pb at different times from 2.5 to 1 Ga ago. This is confirmed by a plot of isochron slope versus intercept, on which the points describing each island's Pb-Pb array all lie very near a single straight line. The isochrons for the Canary Islands and Hawaii, at least, are significantly different. The²⁰⁸Pb/²⁰⁴Pb versus²⁰⁶Pb/²⁰⁴Pb relationships are less coherent. The lead isotopic characteristics are consistent with a model in which lead in the oceanic island magmas is derived from ancient subducted oceanic crust. In particular, this explains the close relationship between lead in mid-ocean ridge and oceanic island basalts without invoking mixing.     

海南地幔柱上地幔结构新的地震学约束

给出了由近震和远震数据确定的海南地幔柱上地幔高分辨率层析成像结果。远震到时数据是由海南岛和雷州半岛9个固定地震台站记录的地震波形中精确提取的。我们的结果显示,在海南热点下方从地表到250km深度,地壳中存在高达-5％而在地幔仅-2％的明显低速异常。海南地幔柱被成像为西北-东南向倾斜的、直径约80km的连续低速柱状异常体。由于较密集数据覆盖和精细模型参数化,我们的结果相对于先前的局部和全球层析成像研究有了明显的改进。海南地幔柱的这种倾斜可以用数值模拟的结果来解释。地幔柱在上地幔中的倾斜可能与海洋板块的俯冲有关,特别是与菲律宾海板块和欧亚板块的挤压有关。但最可能的是,这种倾斜是地幔柱在下地幔扭曲后靠浮力上浮至上地幔形成的。     

Nature and secular evolution of the lithospheric mantle beneath the North China Craton

The Archean mantle lithosphere beneath the North China Craton(NCC) was transformed in the Mesozoic, leading to the craton destruction. Despite the significant breakthroughs in the craton studies, lithospheric transformation mechanisms are yet to be fully understood. Compositional variations of mantle-derived rocks and xenoliths provide insights into the nature of the mantle lithosphere before and after the craton destruction. The Paleozoic lithosphere of the NCC is ～200 km thick. It has a refractory mantle with an evolved isotopic signature. The Mesozoic mantle lithosphere was relatively fertile and highly heterogeneous. In the Cenozoic, the lithosphere in the eastern NCC is about 60–80 km thick. It has an oceanic-type mantle that is fertile in composition and depleted in the Sr-Nd isotopic signature. The Central Zone lithosphere is 100 km thick and has a double-layer mantle with an old upper layer and a new lower layer. The Western Block has a lithosphere of ～200 km thick. The lithospheric mantle beneath the southern and northern margins and eastern part of the NCC has been transformed significantly by peridotite-melt reactions due to the multiple subductions of adjacent plates since the Paleozoic. Paleo-Pacific subduction and the associated dynamic processes significantly alter the lithosphere based on the distribution of craton destruction. The involved mechanisms include mechanical intrusion of subduction plates, melt/fluid erosion, and local delamination. The lithospheric thinning of ～120 km is relevant to the continental extension caused by subduction plate rollback and trench retreat.     

Progress in studies on the structure and physical properties of the mantle in China

The studies on the structure and physical properties of the mantle by Chinese geophysicists from 2003 to 2007 are reviewed in this report. It mainly contains studies on the seismic velocity structure of the mantle,anisotropy of the mantle,mantle discontinuities,mantle convection and the physical properties of mantle. The review concerns mainly the contents,the methods used and the results of the studies. It can be found that new progress in the study on the structure and physical properties of mantle has been made in the last four years in China. In some preexis-tent areas much progress has been made,advanced methods have been adopted,extensive international co-operation has been conducted in many ways,and the scope of the co-operation has gradually expanded. More-over,some new fields appear as well.     

Chemical structure and evolution of the mantle and continents determined by inversion of Nd and Sr isotopic data,I. Theoretical methods

While the chemical structure of the earth's mantle is probably rather complex, multi-box models have been used as a first approximation to evaluate this structure. Most commonly, a three-box model is used, involving the continental crust, the upper mantle and the lower mantle. The depleted upper mantle and the continental crust are assumed to represe1nt complementary reservoirs, related by crust formation processes occurring during geologic history.Here we investigate the Rb/Sr and Sm/Nd isotopic systematics of several three-box models, using mass balance equations and the definition of the mean age of the reservoirs. The geochemical uniqueness of the models, chosen from a large family of possible models, is evaluated from elementary graph theory, and these models are then solved using a total inversion approach. This paper (Part I) describes the methodology of the procedure; the companion paper (Part II) discusses the application of this approach to multi-box mantle models.