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1.
Organic matter in astromaterials can provide important information for understanding the chemistry of our solar system and the prebiotic conditions of the early Earth. However, once astromaterials reach the Earth's surface, they can be readily contaminated through contact with the Earth's surface as well as during processing and curation. Here, we investigate how typical handling and curation materials interact with meteorite specimens by documenting hydrophobic organic compound contamination in the laboratory environment and on materials that might be used for their collection and storage. We use gas chromatography–mass spectrometry analysis of soluble organic compounds in dichloromethane extracts of these materials to gain insights into what materials and methods are best for the collection and curation of astromaterials. Our results have implications for how extraterrestrial samples—especially those containing significant intrinsic organic matter—are handled and curated to preserve them in their most pristine states. Following recommendations of other researchers in the area of returned sample curation, we advocate for a thorough investigation into the materials used in handling and curation of meteorites to create a contamination baseline to inform soluble organic analyses on astromaterials and enable the discrimination of terrestrial and extraterrestrial compounds.  相似文献   

2.
Abstract– Weathering of meteorites at the scale of the entire Antarctic Search for Meteorites program population is studied by analyzing the recent version of the online Antarctic meteorite classification database that includes information about 15,263 meteorites. This paper updates, supplements, and expands on the last Antarctic meteorite weathering census by Velbel (1988 , Meteoritics 23:151–159). On average 5% of all Antarctic meteorites are indicated as evaporite bearing in the Antarctic Meteorite Database. Evaporite formation depends on compositional group. Evaporites are much more common on C chondrites than on ordinary chondrites, supporting previous findings. Ordinary chondrites of petrologic type 3 more often have evaporites on their surface than meteorites of other petrologic types. Contrary to previous findings, there is no apparent relation between evaporite formation and meteorite rustiness. Some meteorite‐bearing fields influence the frequency of evaporite‐mineral formation on meteorites. The influence of location is apparently related to differences in environmental conditions, most probably microclimate or/and hydrologic conditions. There is no relation between abundance of evaporite‐bearing meteorites and distance from the sea. Evaporite formation varies with year of collection; however, it was not possible to distinguish whether this is related to annual changes in environment or an artifact of sample categorization or curation.  相似文献   

3.
X‐ray computed tomography has become a popular means for examining the interiors of meteorites and has been advocated for routine curation and for the examination of samples returned by missions. Here, we report the results of a blind test that indicate that CT imaging deposits a considerable radiation dose in a meteorite and seriously compromises its natural radiation record. Ten vials of the Bruderheim L6 chondrite were placed in CT imager and exposed to radiation levels typical for meteorite studies. Half were retained as controls. Their thermoluminescence (TL) properties were then measured in a blind test. Five of the samples had TL data unaltered from their original (~10 cps) while five had very strong signals (~20,000 cps). It was therefore very clear which samples had been in the CT scanner. For comparison, the natural TL signal from Antarctic meteorites is ~5000–50,000 cps. Using the methods developed for Antarctic meteorites, the apparent dose absorbed by the five test samples was calculated to be 83 ± 5 krad, comparable with the highest doses observed in Antarctic meteorites and freshly fallen meteorites. While these results do not preclude the use of CT scanners when scientifically justified, it should be remembered that the record of radiation exposure to ionizing radiations for the sample will be destroyed and that TL, or the related optically stimulated luminescence, are the primary modern techniques for radiation dosimetry. This is particularly important with irreplaceable samples, such as meteorite main masses, returned samples, and samples destined for archive.  相似文献   

4.
Lunar meteorites provide important new samples of the Moon remote from regions visited by the Apollo and Luna sample return missions. Petrologic and geochemical analysis of these meteorites, combined with orbital remote sensing measurements, have enabled additional discoveries about the composition and age of the lunar surface on a global scale. However, the interpretation of these samples is limited by the fact that we do not know the source region of any individual lunar meteorite. Here, we investigate the link between meteorite and source region on the Moon using the Lunar Prospector gamma ray spectrometer remote sensing data set for the elements Fe, Ti, and Th. The approach has been validated using Apollo and Luna bulk regolith samples, and we have applied it to 48 meteorites excluding paired stones. Our approach is able broadly to differentiate the best compositional matches as potential regions of origin for the various classes of lunar meteorites. Basaltic and intermediate Fe regolith breccia meteorites are found to have the best constrained potential launch sites, with some impact breccias and pristine mare basalts also having reasonably well‐defined potential source regions. Launch areas for highland feldspathic meteorites are much less well constrained and the addition of another element, such as Mg, will probably be required to identify potential source regions for these.  相似文献   

5.
Cadmium is a highly volatile element and its abundance in meteorites may help better understand volatility‐controlled processes in the solar nebula and on meteorite parent bodies. The large thermal neutron capture cross section of 113Cd suggests that Cd isotopes might be well suited to quantify neutron fluences in extraterrestrial materials. The aims of this study were (1) to evaluate the range and magnitude of Cd concentrations in magmatic iron meteorites, and (2) to assess the potential of Cd isotopes as a neutron dosimeter for iron meteorites. Our new Cd concentration data determined by isotope dilution demonstrate that Cd concentrations in iron meteorites are significantly lower than in some previous studies. In contrast to large systematic variations in the concentration of moderately volatile elements like Ga and Ge, there is neither systematic variation in Cd concentration amongst troilites, nor amongst metal phases of different iron meteorite groups. Instead, Cd is strongly depleted in all iron meteorite groups, implying that the parent bodies accreted well above the condensation temperature of Cd (i.e., ≈650 K) and thus incorporated only minimal amounts of highly volatile elements. No Cd isotope anomalies were found, whereas Pt and W isotope anomalies for the same iron meteorite samples indicate a significant fluence of epithermal and higher energetic neutrons. This observation demonstrates that owing to the high Fe concentrations in iron meteorites, neutron capture mainly occurs at epithermal and higher energies. The combined Cd‐Pt‐W isotope results from this study thus demonstrate that the relative magnitude of neutron capture‐induced isotope anomalies is strongly affected by the chemical composition of the irradiated material. The resulting low fluence of thermal neutrons in iron meteorites and their very low Cd concentrations make Cd isotopes unsuitable as a neutron dosimeter for iron meteorites.  相似文献   

6.
The rapid recovery of meteorites mitigates the exposure of astromaterials to the terrestrial environment and subsequent contamination. Modern fireball observatories have enabled the more accurate triangulation of fireball trajectories, which has aided in the location of strewn fields, in the case of meteorite-producing events. Despite this advancement, most meteorite searches still use manual searching to locate any meteorite falls, which is often labor-intensive and has a slow coverage rate (km2 day−1). Recent work has begun exploring the application of drone technology to the recovery of meteorites; however, most of this work has focused on falls in arid environments. Our study examines the utilization of drones with thermal imaging technology to aid in the recovery of meteorites that have fallen on a snow-covered field. We created a simulated strewn field that included meteorite specimens as well as Earth rocks with similar properties (“meteowrongs”). Thermal imagery was utilized to determine whether the thermal contrast between meteorites and snow could aid in the identification of meteorites. We found that the thermal contrast was significant enough that meteorites were readily identifiable within thermal images; however, it was not significant enough to distinguish between the meteorites and the meteowrongs. The utilization of thermal imagery in conjunction with visible imagery has the potential to aid in the rapid recovery of meteorites in snow-covered landscapes.  相似文献   

7.
Abstract— Research on extraterrestrial materials plays a critical role in formulating the science rationale and design for spacecraft missions, and, conversely, spaceflight holds great promise for solving perplexing problems in meteoritics. The connections between meteoritics and sample-return missions are obvious: Meteorite research can define sampling strategies, the capabilities of sampling devices, acceptable levels of chemical contamination and physical alteration of samples, and the conditions under which samples are stored prior to and during recovery. For their part, sample-return missions can provide geologic context for meteorites, increased sampling diversity (including materials not sampled as meteorites, such as unconsolidated regolith, ices, and atmosphere), calibration for crater-counting chronology, and ground truth for remote sensing measurements of meteorite parent bodies. Meteoritics also relates to spacecraft flyby, rendezvous, and lander missions that do not necessarily return samples. Specific illustrations of this mutual relationship, based on a selection of recent or planned spacecraft missions include: Identifying source asteroid classes for ordinary and carbonaceous chondrites and reconstructing their thermal and collisional histories (Galileo, NEAR, Clementine II, and Muses-C); determining the extent to which cometary dust and interstellar grains are found as interplanetary dust particles and assessing volatile abundances, isotopic compositions, and molecular species in cometary nuclei (Stardust and Rosetta); understanding the compositions of ancient Martian crust and the mantle sources for SNC meteorites, as well as inventorying the planet's volatile reservoirs and interactions (Mars Pathfinder, Mars Global Surveyor, and Mars Volatiles and Climate Surveyor); assessing whether lunar meteorites provide a more representative chemical sampling of the highlands crust and of mare volcanism than do Apollo samples (Galileo, Clementine, and Lunar Prospector). Spaceflight is the first priority of the space agencies that fund most research on extraterrestrial materials, and the continued level of support for such research may be linked, in part, to its use in exploration by spacecraft.  相似文献   

8.
Abstract— Plagioclase in the Martian lherzolitic shergottite Grove Mountains (GRV) 99027 was shocked, melted, and recrystallized. The recrystallized plagioclase contains lamellae of pyroxene, olivine, and minor ilmenite (<1 μm wide). Both the pyroxene and the olivine inclusions enclosed in plagioclase and grains neighboring the plagioclase were partially melted into plagioclase melt pools. The formation of these lamellar inclusions in plagioclase is attributed to exsolution from recrystallizing melt. Distinct from other Martian meteorites, GRV 99027 contains no maskelynite but does contain recrystallized plagioclase. This shows that the meteorite experienced a slower cooling than maskelynite‐bearing meteorites. We suggest that the parent rock of GRV 99027 could have been embedded in hot rocks, which facilitated a more protracted cooling history.  相似文献   

9.
Except for asteroid sample return missions, measurements of the spectral properties of both meteorites and asteroids offer the best possibility of linking meteorite groups with their parent asteroid(s). Visible plus near‐infrared spectra reveal distinguishing absorption features controlled mainly by the Fe2+ contents and modal abundances of olivine and pyroxene. Meteorite samples provide relationships between spectra and mineralogy. These relationships are useful for estimating the olivine and pyroxene mineralogy of stony (S‐type) asteroid surfaces. Using a suite of 10 samples of the acapulcoite–lodranite clan (ALC), we have developed new correlations between spectral parameters and mafic mineral compositions for partially melted asteroids. A well‐defined relationship exists between Band II center and ferrosilite (Fs) content of orthopyroxene. Furthermore, because Fs in orthopyroxene and fayalite (Fa) content in olivine are well correlated in these meteorites, the derived Fs content can be used to estimate Fa of the coexisting olivine. We derive new equations for determining the mafic silicate compositions of partially melted S‐type asteroid parent bodies. Stony meteorite spectra have previously been used to delineate meteorite analog spectral zones in Band I versus band area ratio (BAR) parameter space for the establishment of asteroid–meteorite connections with S‐type asteroids. However, the spectral parameters of the partially melted ALC overlap with those of ordinary (H) chondrites in this parameter space. We find that Band I versus Band II center parameter space reveals a clear distinction between the ALC and the H chondrites. This work allows the distinction of S‐type asteroids as nebular (ordinary chondrites) or geologically processed (primitive achondrites).  相似文献   

10.
Abstract— The hypothesis that the soluble fraction of the organic compounds present in carbonaceous chondrite meteorites was formed during aqueous alteration of the parent body was tested with mass‐transfer, reaction‐path calculations. In these calculations, we start with likely compositions of the original parent body and asteroidal fluids that are far from thermodynamic equilibrium, and metastable and stable equilibrium constraints are imposed as the total Gibbs free energy of the parent body environment is minimized. The results of these calculations suggest that the classes of soluble organic compounds present in carbonaceous chondrite meteorites could have formed during relatively low temperature aqueous alteration of the meteorite parent body or bodies. The main controls on the potential for synthesis and transformation of organic compounds were the oxidation state of the rock/fluid system, the bulk composition of that system, and the temperatures that were achieved during the alteration event or events. It also appears that the alteration mineral assemblages were influenced by the presence of soluble organic compounds and reaction among them.  相似文献   

11.
The rapid recovery of the Winchcombe meteorite offers a valuable opportunity to study the soluble organic matter (SOM) profile in pristine carbonaceous astromaterials. Our interests in the biologically relevant molecules, amino acids—monomers of protein, and the most prevalent meteoritic organics—polycyclic aromatic hydrocarbons (PAHs) are addressed by analyzing the solvent extracts of a Winchcombe meteorite stone using gas chromatography mass spectrometry. The Winchcombe sample contains an amino acid abundance of ~1132 parts-per-billion that is about 10 times lower than other CM2 meteorites. The detection of terrestrially rare amino acids, including α-aminoisobutyric acid (AIB); isovaline; β-alanine; α-, β-, and γ-amino-n-butyric acids; and 5-aminopentanoic acid, and the racemic enantiomeric ratios (D/L = 1) observed for alanine and isovaline indicate that these amino acids are indigenous to the meteorite and not terrestrial contaminants. The presence of predominantly α-AIB and isovaline is consistent with their formation via the Strecker-cyanohydrin synthetic pathway. The L-enantiomeric excesses in isovaline previously observed for aqueously altered meteorites were viewed as an indicator of parent body aqueous processing; thus, the racemic ratio of isovaline observed for Winchcombe, alongside the overall high free:total amino acid ratio, and the low amino acid concentration suggest that the analyzed stone is derived from a lithology that has experienced brief episode(s) of aqueous alteration. Winchcombe also contains 2- to 6-ring alkylated and nonalkylated PAHs. The low total PAHs abundance (6177 ppb) and high nonalkylated:alkylated ratio are distinct from that observed for heavily aqueously altered CMs. The weak petrographic properties of Winchcombe, as well as the discrepancies observed for the Winchcombe SOM content—a low total amino acid abundance comparable to heavily altered CMs, and yet the high free:total amino acid and nonalkylated:alkylated PAH ratios are on par with the less altered CMs—suggest that Winchcombe could represent a class of weak, poorly lithified meteorite not been previously studied.  相似文献   

12.
Insoluble organic matter (IOM) is the major organic component of chondritic meteorites and may be akin to organic materials from comets and interplanetary dust particles (IDPs). Reflectance spectra of IOM in the range 0.35–25 μm are presented as a tool for interpreting organic chemistry from remote measurements of asteroids, comets, IDPs, and other planetary bodies. Absorptions in the IOM spectra were strongly related to elemental H/C (atom) ratio. The aliphatic 3.4 μm absorption in IOM spectra increased linearly in strength with increasing H/C for H/C > 0.4, but was absent at lower H/C values. When meteorite spectra from the Reflectance Experiment Laboratory (RELAB) spectral catalog (n = 85) were reanalyzed at 3.4 μm, this detection limit (H/C > 0.4) persisted. Aromatic absorption features seen in IOM spectra were not observed in the meteorite spectra due to overlapping absorptions. However, the 3.4 μm aliphatic absorption strength for the bulk meteorites was correlated with both H/C of the meteorite's IOM and bulk C (wt%). Gaussian modeling of the 3 μm region provided an additional estimate of bulk C for the meteorites, along with bulk H (wt%), which is related to phyllosilicate abundance. These relationships lay the foundation for determining organic and phyllosilicate abundances from reflectance spectra. Both the full IOM spectra and the spectral parameters discussed here will aid in the interpretation of data from asteroid missions (e.g., OSIRIS‐REx, Hayabusa2), and may be able to place unknown spectral samples within the context of the meteorite collection.  相似文献   

13.
Abstract— Many lines of evidence indicate that meteorites are derived from the asteroid belt but, in general, identifying any meteorite class with a particular asteroid has been problematical. One exception is asteroid 4 Vesta, where a strong case can be made that it is the ultimate source of the howardite‐eucrite‐diogenite (HED) family of basaltic achondrites. Visible and near‐infrared reflectance spectra first suggested a connection between Vesta and the basaltic achondrites. Experimental petrology demonstrated that the eucrites (the relatively unaltered and unmixed basaltic achondrites) were the product of approximately a 10% melt. Studies of siderophile element partitioning suggested that this melt was the residue of an asteroidal‐scale magma ocean. Mass balance considerations point to a parent body that had its surface excavated, but remains intact. Modern telescopic spectroscopy has identified kilometer‐scale “Vestoids” between Vesta and the 3:1 orbit‐orbit resonance with Jupiter. Dynamical simulations of impact into Vesta demonstrate the plausibility of ejecting relatively unshocked material at velocities consistent with these astronomical observations. Hubble Space Telescope images show a 460 km diameter impact basin at the south pole of Vesta. It seems that nature has provided multiple free sample return missions to a unique asteroid. Major challenges are to establish the geologic context of the HED meteorites on the surface of Vesta and to connect the remaining meteorites to specific asteroids.  相似文献   

14.
Abstract– The Old Woman meteorite, discovered in March 1976 by two prospectors searching for a fabled lost Spanish gold mine in mountains ~270 km east of Los Angeles, has achieved the status of a legend among meteorite hunters and collectors. The question of the ownership of the 2753 kg group IIAB meteorite, the second largest ever found in the United States (34°28′N, 115°14′W), gave rise to disputes involving the finders, the Bureau of Land Management, the Secretary of the Department of the Interior, the State of California, the California members of the U.S. Congress, various museums in California, the Smithsonian Institution, and the Department of Justice. Ultimately, ownership of the meteorite was transferred to the Smithsonian under the powers of the 1906 Antiquities Act, a ruling upheld in a U.S. District Court and a U.S. Court of Appeals. After additional debate, the Smithsonian removed a large cut for study and curation, and for disbursement of specimens to qualified researchers. The main mass was then returned to California on long‐term loan to the Bureau of Land Management’s Desert Discovery Center in Barstow. The Old Woman meteorite litigation served as an important test case for the ownership and control of meteorites found on federal lands. The Old Woman meteorite appears to be structurally unique in containing both hexahedral and coarsest octahedral structures in the same mass, unique oriented schreibersites within hexahedral areas, and polycrystalline parent austenite crystals. These structures suggest that different portions of the meteorite may have transformed via different mechanisms upon subsolidus cooling, making the large slices of Old Woman promising targets for future research.  相似文献   

15.
Abstract— In this review, we summarize the data published up to December 2001 on the porosity and density of stony meteorites. These data were taken from 925 samples of 454 different meteorites by a variety of techniques. Most meteorites have densities on the order of 3 to 4 g/cm3, with lower densities only for some volatile‐rich carbonaceous meteorites and higher densities for stony irons. For the vast majority of stones, porosity data alone cannot distinguish between different meteorite compositions. Average porosities for most meteorite classes are around 10%, though individual samples can range as high as 30% porosity. Unbrecciated basaltic achondrites appear to be systematically less porous unless vesicles are present. The measured density of ordinary chondrites is strongly controlled by the amount of terrestrial weathering the sample has undergone with porosities steadily dropping with exposure to the terrestrial environment. A theoretical grain density based on composition can model “pre‐weathered” porosities. The average model porosity for H and LL chondrites is 10%, while L chondrite model porosities average only 6%, a statistically significant difference.  相似文献   

16.
Abstract— ‐Iron meteorites exhibit a large range in Ni concentrations, from only 4% to nearly 60%. Most previous experiments aimed at understanding the crystallization of iron meteorites have been conducted in systems with about 10% Ni or less. We performed solid metal/liquid metal experiments to determine the effect of Ni on partition coefficients for 20 trace elements pertinent to iron meteorites. Experiments were conducted in both the end‐member Ni‐S system as well as in the Fe‐Ni‐S system with intermediate Ni compositions applicable to high‐Ni iron meteorites. The Ni content of the system affects solid metal/liquid metal partitioning behavior. For a given S concentration, partition coefficients in the Ni‐S system can be over an order of magnitude larger than in the Fe‐S system. However, for compositions relevant to even the most Ni‐rich iron meteorites, the effect of Ni on partitioning behavior is minor, amounting to less than a factor of two for the majority of trace elements studied. Any effect of Ni also appears minor when it is compared to the large influence S has on element partitioning behavior. Thus, we conclude that in the presence of an evolving S‐bearing metallic melt, crystallization models can safely neglect effects from Ni when considering the full range of iron meteorite compositions.  相似文献   

17.
The Orgueil meteorite has become one of the most well‐studied carbonaceous meteorites, after it fell in France 150 yr ago. Extraterrestrial organic compounds such as amino acids and nucleobases in the parts per billion ranges were identified in Orgueil samples with supporting isotopic analyses. However, speculations of terrestrial contamination such as organic inclusions in the form of microbes and seeds accompanied the analyses of the Orgueil meteorite ever since its fall. By using molecular analysis, we performed DNA extractions and spiking experiments combined with 16S and 18S rRNA gene targeted PCR amplification to quantify the level of terrestrial biocontamination. Our results indicate that terrestrial contamination with DNA was insignificant in the investigated meteorite fraction. We also remeasured and confirmed concentrations of amino acids found in previous studies and conclude that their rather high concentrations and distribution cannot be explained by terrestrial contamination with microorganisms alone. These results represent the first analysis using DNA‐directed tools in the analysis of the Orgueil meteorite to determine trace levels of biomarkers.  相似文献   

18.
Abstract– To better explain the unusual distribution and relative abundances of several 6‐ and 7‐carbon amino acids found in meteorites, their thermodynamic properties were studied using accurate ab initio techniques. In addition to optimized structures and relative energies, vibrational frequency and thermochemical analysis of different diastereomers were performed at temperatures relevant to conditions of synthesis of these amino acids in meteorites. The results of calculations were compared with the measured content of the amino acids in the Murchison meteorite. The distribution of several longer chain amino acids in meteorites seems to point to at least some thermodynamic control in their formation. For diastereomeric compounds, on the other hand, the comparison suggests that their synthetic conditions, or those of their precursors, were far from thermodynamic equilibrium.  相似文献   

19.
The Sutter's Mill (SM) meteorite fell in El Dorado County, California, on April 22, 2012. This meteorite is a regolith breccia composed of CM chondrite material and at least one xenolithic phase: oldhamite. The meteorite studied here, SM2 (subsample 5), was one of three meteorites collected before it rained extensively on the debris site, thus preserving the original asteroid regolith mineralogy. Two relatively large (10 μm sized) possible diamond grains were observed in SM2‐5 surrounded by fine‐grained matrix. In the present work, we analyzed a focused ion beam (FIB) milled thin section that transected a region containing these two potential diamond grains as well as the surrounding fine‐grained matrix employing carbon and nitrogen X‐ray absorption near‐edge structure (C‐XANES and N‐XANES) spectroscopy using a scanning transmission X‐ray microscope (STXM) (Beamline 5.3.2 at the Advanced Light Source, Lawrence Berkeley National Laboratory). The STXM analysis revealed that the matrix of SM2‐5 contains C‐rich grains, possibly organic nanoglobules. A single carbonate grain was also detected. The C‐XANES spectrum of the matrix is similar to that of insoluble organic matter (IOM) found in other CM chondrites. However, no significant nitrogen‐bearing functional groups were observed with N‐XANES. One of the possible diamond grains contains a Ca‐bearing inclusion that is not carbonate. C‐XANES features of the diamond‐edges suggest that the diamond might have formed by the CVD process, or in a high‐temperature and ‐pressure environment in the interior of a much larger parent body.  相似文献   

20.
The matching of asteroids and meteorites is a significant step toward a better understanding of the origin, structure, and history of the solar system. We propose a data‐driven approach for investigating common taxonomic structure between asteroids and meteorites; C‐, S‐, and V‐type for the former, and carbonaceous chondrite, ordinary chondrite, and howardite‐eucrite‐diogenite (HED) meteorite for the latter. In the numerical experiments, by checking whether the taxonomy information of meteorites improves classification for asteroid data, we examine the existence of common structure over the two domains. For this purpose, we compare the resultant accuracies of two clustering methods which are with/without the guidance of meteorite data. We observe that the guidance of meteorite taxonomy improves the accuracy for classifying asteroids, either with the reflectance spectra or major chemical compositions of meteorites. This fact serves as a piece of evidence that there is a common taxonomic structure and links between meteorites and asteroids, supporting a long‐standing hypothesis.  相似文献   

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