Effects of space weathering on diagnostic spectral features: Results from He+ irradiation experiments

We performed ion irradiation of mineral samples with 50 keV He⁺, aimed to investigate ion irradiation effects on diagnostic spectral features. Reflectance spectra of samples in 0.375–2.5 μm are measured before and after ion irradiation. Silicates, including Luobusha olivine, plagioclase and basaltic glass, have shown reddening and darkening of reflectance spectra at the VIS–NIR range. Olivine is more sensitive to ion irradiation than plagioclase and basaltic glass. Irradiated Panzhihua ilmenite exhibits higher reflectance and stronger absorption features, which is totally different from lunar soil and analog silicate materials in other experiments. Using continuum removal and MGM fit, we extracted and compared absorption features of olivine spectra before and after irradiation. Ion irradiation can induce band strength decrease of olivine but negligible band centers shift. We estimate band centers shift caused by ion irradiation are quite limited, even less than variations due to chemical composition in silicates. It provides one possible explanation for no systematic shift in band positions in lunar soil. Irradiated Luobusha olivine spectrum matches spectra of olivine-dominated asteroids. Our results suggest space weathering should be new clues to explain the subtle difference between A-type asteroid spectra and laboratory spectra of olivine.     

Elastic collisions in ion irradiation experiments: A mechanism for space weathering of silicates

Ion irradiation experiments have been performed on silicates (bulk samples) rich of olivine, pyroxene, and serpentine to simulate the effects of space weathering induced on asteroids by solar wind ions. We have used different ions (H⁺, He⁺, Ar⁺, Ar²⁺) having different energies (from 60 to 400 keV) to weather the samples, probed by Raman spectroscopy and UV-vis-NIR reflectance spectroscopy. All the irradiated materials have shown reddening and darkening of reflectance spectra in the 0.25-2.7 μm spectral range. We have found that the increase of the spectral slope of the continuum across the 1-μm band is strongly related with the number of displacements caused by colliding ions because of elastic collisions with the target nuclei. The spectral slopes have been compared, at increasing ion fluence, with those from irradiated Epinal meteorite. We show that formation of nuclear displacements by solar wind ion irradiation is a physical mechanism that reddens the asteroidal surfaces on a time-scale lower than 10⁶ years.     

Space weathering of silicates simulated by nanosecond pulse UV excimer laser

Laser irradiation experiments have been performed on powdered silicates (othopyroxene, clinopyroxene, and olivine) using a nanosecond pulse UV excimer laser (193 and 248 nm) to simulate the effects of space weathering induced on minor bodies of the Solar System by micrometeorite bombardment. We have used different fluences (from 0.05 to 2 J/cm²) to weather the samples, experimenting below and above the ablation threshold. All the irradiated materials have shown reddening and darkening of their UV-vis-NIR reflectance spectra. In addition we have found that: (1) below ablation threshold, weathering effects increase with increasing number of laser pulses, and with increasing fluence, confirming that a thermal process is active; (2) above ablation threshold, weathering is much stronger and efficient than in the previous case, and is independent on the number of pulses. We show that astrophysical time-scales, i.e. times necessary to obtain similar effects on planetary objects, are of about 10⁸ yr for both olivine and pyroxene in the case of ablation. The time grows up to 10¹⁰ yr in the case of thermal effects. We infer that micrometeorite bombardment can be rightly simulated by laser irradiation only considering congruent laser ablation.     

Low‐energy helium ion irradiation‐induced amorphization and chemical changes in olivine: Insights for silicate dust evolution in the interstellar medium

Abstract— We present the results of irradiation experiments aimed at understanding the structural and chemical evolution of silicate grains in the interstellar medium. A series of He+ irradiation experiments have been performed on ultra‐thin olivine, (Mg,Fe)₂SiO₄, samples having a high surface/volume (S/V) ratio, comparable to the expected S/V ratio of interstellar dust. The energies and fluences of the helium ions used in this study have been chosen to simulate the irradiation of interstellar dust grains in supernovae shock waves. The samples were mainly studied using analytical transmission electron microscopy. Our results show that olivine is amorphized by low‐energy ion irradiation. Changes in composition are also observed. In particular, irradiation leads to a decrease of the atomic ratios O/Si and Mg/Si as determined by x‐ray photoelectron spectroscopy and by x‐ray energy dispersive spectroscopy. This chemical evolution is due to the differential sputtering of atoms near the surfaces. We also observe a reduction process resulting in the formation of metallic iron. The use of very thin samples emphasizes the role of surface/volume ratio and thus the importance of the particle size in the irradiation‐induced effects. These results allow us to account qualitatively for the observed properties of interstellar grains in different environments, that is, at different stages of their evolution: chemical and structural evolution in the interstellar medium, from olivine to pyroxene‐type and from crystalline to amorphous silicates, porosity of cometary grains as well as the formation of metallic inclusions in silicates.     

Optical characterization of laser ablated silicates

We perform an optical characterization of UV laser ablated silicates (olivine, pyroxene), starting from their reflectance spectra in the 0.3-2.5 μm spectral range. The goal is to provide useful tools to model space weathering effects on surfaces of asteroids and TNOs (trans-neptunian objects). We determine that the reddening and darkening spectral trend is compatible with the Hapke's space weathering model, using the optical constants of metallic iron in a silicate matrix. This result is supported by new magnetic susceptibility measurements on laser ablated orthopyroxene. We also investigate the potential contribution of formation of amorphous silicates in the process. Applying our results to silicate-rich surfaces in the Solar System, we investigate the possibility of a weathered olivine component on the surface of Centaur 5145 Pholus. Inclusion of this component slightly decreases the amount of complex organics and water ice from those previously estimated. Thus, the current Pholus spectrum is consistent with the presence of either unweathered or weathered olivine, or potentially both materials.     

Laboratory simulations of redeposition of impact ejecta on mineral surfaces

We present quantitative laboratory studies that simulate the effect of redeposition of impact-ejecta on mineral surfaces. We produced deposits of natural olivine (Fo90) and forsterite on olivine and forsterite powder samples by ns-pulsed laser ablation. The deposits produce changes in the optical reflectance (0.66-2.5 μm). We show that significant darkening and reddening of the surface occurs when the deposit is olivine but not if it is forsterite. This is attributed to the formation of metallic iron nanoparticles in the olivine deposits. We also characterized structural and chemical changes using scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy (XPS). In situ XPS measurements show that the olivine deposits are reduced, with 50% of the iron becoming metallic. Transmission electron microscope studies confirm the presence of 2-3 nm crystalline iron nanoparticles in the olivine deposits. The scanning electron microscope shows that both olivine and forsterite deposits smoothen the topography of the powder surface, which could have effects on processes such as exosphere-surface interactions and sputtering. We conclude that the effect of coatings produced by micrometeorite impacts will not be uniform on airless bodies but will depend on the composition of the terrain.     

On the application of magnetic methods for the characterisation of space weathering products

Space weathering is now commonly accepted to modify the optical and magnetic properties of airless body regoliths throughout the Solar System. Although the precise formation processes are not well understood, the presence of ubiquitous sub-microscopic metallic iron (SMFe) grains in lunar soils and corresponding spectral analyses have explained both the unique optical and magnetic properties of such soils. More recently, a variety of ion irradiation, laser melting and vaporisation and impact experiments have been shown to reproduce these effects in the laboratory. Such experiments are crucial to the study of the formation of SMFe under controlled conditions. To date, more emphasis has been placed on optical analyses of laboratory samples, as these address directly the mineralogical interpretation of remote sensing data. However, the magnetic analyses performed on the Apollo and Luna samples have provided useful qualitative and quantitative evaluation of regolith metallic iron content. These techniques are reviewed here, demonstrated on pulsed laser irradiated olivine powder, and their utility for determining the quantity and size distribution of this metallic iron discussed. Ferromagnetic resonance, multi-frequency magnetic susceptibility, vibrating sample magnetometry and thermomagnetic measurements were carried out. Each showed trends expected for the conversion of paramagnetic Fe²⁺ in olivine to fine-grained Fe⁰, with some grains in the superparamagnetic size range. Although evidence for superparamagnetic iron was found, the quantity of sub-microscopic metallic iron produced in these experiments proved insufficient to make conclusive measurements of either the quantity or size distribution of this iron. Improvements to both the experimental and analytical procedures are discussed to better enable such measurements in the future.     

MUSES‐C target asteroid (25143) 1998 SF36: A reddened ordinary chondrite

Abstract— Near‐Earth asteroid (25143) 1998 SF36 is a planned target for the Japanese MUSES‐C sample return mission. High signal‐to‐noise and relatively high‐resolution (50 Å) visible and near‐infrared spectroscopic measurements obtained during this asteroid's favorable 2001 apparition reveal it to have a red‐sloped S(IV)‐type spectrum with strong 1 and 2 μm absorption bands analogous to those measured for ordinary chondrite meteorites. This red slope, which is the primary spectral difference between (25143) 1998 SF36 and ordinary chondrite meteorites, is well modeled by the spectrum of 0.05% nanophase iron (npFe⁰) proposed as a weathering mechanism by Pieters et al. (2000). Asteroid 1998 SF36 appears to have a surface composition corresponding to that of ordinary chondrite meteorites and is most similar in spectral characteristics and modeled olivine/pyroxene content to the LL chondrite class.     

Jiddat al Harasis 422: A ureilite with an extremely high degree of shock melting

The Jiddat al Harasis (JaH) 422 ureilite was found in the Sultanate of Oman; it is classified as a ureilitic impact melt breccia. The meteorite consists of rounded polycrystalline olivine clasts (35%), pores (8%), and microcrystalline matrix (57%). Clasts and matrix have oxygen isotopic values and chemical compositions (major and trace elements) characteristic of the ureilite group. The matrix contains olivine (Fo_83–90), low‐Ca pyroxene (En_84–92Wo_0–5), augite (En_71–56Wo_20–31), graphite, diamond, Fe‐metal, sulfides, chromite, and felsic glass. Pores are partly filled by secondary Fe‐oxihydroxide and desert alteration products. Pores are surrounded by strongly reduced silicates. Clasts consist of fine‐grained aggregates of polygonal olivine. These clasts have an approximately 250 μm wide reaction rim, in which olivine composition evolves progressively from the core composition (Fo_79–81) to the matrix composition (Fo_84–87). Veins crossing the clasts comprise pyroxene, Fe‐oxihydroxide, C‐phases, and chromite. Clasts contain Ca‐, Al‐, and Cr‐rich glass along olivine grain boundaries (<1 μm wide). We suggest that a significant portion of JaH 422, including olivine and all the pyroxenes, was molten as a result of an impact. In comparison with other impact‐melted ureilites, JaH 422 shows the highest melt portion. Based on textural and compositional considerations, clasts and matrix probably originated from the same protolith, with the clasts representing relict olivine that survived, but was recrystallized in the impact melt. During the melt stage, the high availability of FeO and elevated temperatures controlled oxygen fugacity at values high enough to stabilize olivine with Fo_～83–87 and chromite. Along pores, high Mg# compositions of silicates indicate that in a late stage or after melt crystallization FeO became less available and fO₂ conditions were controlled by C?CO + CO₂.     

Al Huwaysah 010: The most reduced brachinite,so far

Al Huwaysah 010 is an ungrouped achondrite meteorite, recently referred to as a brachinite-like meteorite. This meteorite, showing a fine-grained assemblage of low-Ca pyroxene and opaque phases, is strongly reduced in comparison to other reduced brachinites. The occurrence of some tiny plates of graphite and oldhamite in this meteorite suggests that a partial melt residue has experienced a further reduction process. Olivine, the most abundant phase, is compositionally homogeneous (Fo_83.3) as well as the clinopyroxene (En_45.5Fs_10.8Wo_43.7) and the plagioclase (Ab_69.5). Orthopyroxene (En_85.4Fs_13.9Wo_0.7) also occurs but only in a fine intergrowth. Other accessory phases are Fe metal grains (Ni-free or Cr-bearing Fe-Ni alloy), troilite, chlorapatite, pentlandite (as inclusions in chromite). The sample shows two different closure temperatures: the highest (≈900°C) is determined via the olivine–chromite intercrystalline geothermometer and the lowest temperature (≈520°C) is determined via the pyroxene-based intracrystalline geothermometer. These temperatures may represent, respectively, the closure temperature associated with the formation and a subsequent impact event excavating the sample from the parental body. The visible to near-infrared (VNIR) reflectance spectra of Al Huwaysah 010 exhibit low reflectance, consistent with the presence of darkening components, and weak absorptions indicative of olivine and pyroxene. Comparing the spectral parameters of Al Huwaysah 010 to potential parent bodies characterized by olivine–pyroxene mineralogy, we find that it falls within the field previously attributed to the SIII type asteroids. These results lead us to classify the Al Huwaysah 010 meteorite as the most reduced brachinite, whose VNIR spectral features show strong affinities with those of SIII asteroids.     

NWA 1152 and Sahara 00182: New primitive carbonaceous chondrites with affinities to the CR and CV groups

Abstract— We have investigated the mineralogy, petrography, bulk chemistry, and light element isotope composition of the ungrouped chondrites North West Africa (NWA) 1152 and Sahara 00182. NWA 1152 contains predominantly type 1 porphyritic olivine (PO) and porphyritic olivinepyroxene (POP) chondrules. Chondrule silicates are magnesium‐rich (Fo_{98.8 ± 1.2}, n = 36; Fs_{2.3 ± 2.1} Wo_{1.2 ± 0.3}, n = 23). Matrix comprises ?40 vol% of the sample and is composed of a micron sized silicate groundmass with larger silicate, sulfide, magnetite, and Fe‐Ni metal (Ni ?50 wt%) grains. Phyllosilicates were not observed in the matrix. Refractory inclusions are rare (0.3 vol%) and are spinel pyroxene aggregates or amoeboid olivine aggregates; melilite is absent from the refractory inclusions. Sahara 00182 contains predominantly type 1 PO chondrules, POP chondrules are less common. Most chondrules contain blebs of, and are often rimmed with, Fe‐Ni metal and sulfide. Chondrule phenocrysts are magnesium‐rich (Fo_{92.2 ± 0.6}, n = 129; Fs_{4.4 ± 1.8} Wo_{1.3 ± 1.1}, n = 16). Matrix comprises ?30 vol% of the meteorite and is predominantly sub‐micron silicates, with rare larger silicate gains. Matrix Fe‐Ni metal (mean Ni = 5.8 wt%) and sulfide grains are up to mm scale. No phyllosilicates were observed in the matrix. Refractory inclusions are rare (1.1 vol%) and melilite is absent. The oxygen isotope composition of NWA 1152 falls within the range of the CV chondrites with δ¹⁷O = ?3.43%0 δ¹⁸O = 0.70%0 and is similar to Sahara 00182, δ¹⁷O = ?3.89%0, δ¹⁸O = ?0.19%0 (Grossman and Zipfel 2001). Based on mineralogical and petrographic characteristics, we suggest NWA 1152 and Sahara 00182 show many similarities with the CR chondrites, however, oxygen isotopes suggest affinity with the CVs. Thus, neither sample can be assigned to any of the currently known carbonaceous chondrite groups based on traditionally recognized characteristics. Both samples demonstrate the complexity of inter‐ and intra‐group relationships of the carbonaceous chondrites. Whatever their classification, N WA 1152 and Sahara 00182 represent a source of relatively pristine solar system material.     

Chemical and isotopic characteristics of the Didwana‐Rajod (H5) chondrite

Abstract— The mineralogical and chemical characteristics of the Didwana‐Rajod chondrite are described. The mean mineral composition is found to be olivine (Fo_83.2) and pyroxene (En_83.5Wo_0.7Fs_15.8), and feldspar is mainly oligoclase. Oxygen isotopic analysis shows δ¹⁸O = +3.8%0 and δ¹⁷O = +2.59%0. The nitrogen content of Didwana‐Rajod is ～2 ppm with δ¹⁵N ? 3.4%0. Based on microscopic, chemical, isotopic and electron probe microanalysis, the meteorite is classified as an H5 chondrite. Cosmogenic tracks, radionuclides and the isotopic composition of rare gases were also measured in this meteorite. The track density in olivines varies in a narrow range with an average value of (6.5 ± 0.5) × 10⁵/cm² for four spot samples taken at the four corners of the stone. The cosmic‐ray exposure age based on neon and argon is 9.8 Ma. ²²Na/²⁶Al ? 0.94 is lower than the solar‐cycle average value of ～1.5 and is consistent with irradiation of the meteoroid to lower galactic cosmic‐ray fluxes as expected at the solar maximum. The track density, rare gas isotopic ratios, ⁶⁰Co activity and other radionuclide data are consistent with a preatmospheric radius of ～15 cm, corresponding to a mass of ～50 kg. The cosmogenic properties are consistent with a simple exposure history in interplanetary space.     

Mineralogical study of brown olivine in Northwest Africa 1950 shergottite and implications for the formation mechanism of iron nanoparticles

Martian meteorites, in particular shergottites, contain darkened olivine (so‐called “brown olivine”) whose color is induced by iron nanoparticles formed in olivine during a shock event. The formation process and conditions of brown olivine have been discussed in the Northwest Africa 2737 (NWA 2737) chassignite. However, formation conditions of brown olivine in NWA 2737 cannot be applied to shergottites because NWA 2737 has a different shock history from that of shergottites. Therefore, this study observed brown olivine in the NWA 1950 shergottite and discusses the general formation process and conditions of brown olivine in shergottites. Our observation of NWA 1950 revealed that olivine is heterogeneously darkened between and within grains different from brown olivine in NWA 2737. XANES analysis showed that brown olivine contains small amounts of Fe³⁺ and TEM/STEM observation revealed that there is no SiO‐rich phase around iron metal nanoparticles. These observations indicate that iron nanoparticles were formed by a disproportionation reaction of olivine (3Fe²⁺_olivine → Fe⁰_metal + 2Fe³⁺_olivine + V_olivine, where V_olivine means a vacancy in olivine). Some parts of brown olivine show lamellar textures in SEM observation and Raman peaks in addition to those expected for olivine, implying that brown olivine experienced a phase transition (to e.g., ringwoodite). In order to induce heterogeneous darkening, heterogeneous high temperature of about 1500–1700 K and shock duration of at least ~90 ms are required. This heterogeneous high temperature resulted in high postshock temperature (>900 K) inducing back‐transformation of most high‐pressure phases. Therefore, in spite of lack of high‐pressure phases, NWA 1950 (= Martian meteorites with brown olivine) experienced higher pressure and temperature compared to other highly shocked meteorite groups.     

LIME silicates in amoeboid olivine aggregates in carbonaceous chondrites: Indicator of nebular and asteroidal processes

MnO/FeO ratios in olivine from amoeboid olivine aggregates (AOAs) reflect conditions of nebular condensation and can be used in concert with matrix textures to compare metamorphic conditions in carbonaceous chondrites. LIME (low‐iron, Mn‐enriched) olivine was identified in AOAs from Y‐81020 (CO3.05), Kaba (CV~3.1), and in Y‐86009 (CV3), Y‐86751 (CV3), NWA 1152 (CR/CV3), but was not identified in AOAs from Efremovka (CV3.1–3.4) or Allende (CV>3.6). According to thermodynamic models of nebular condensation, LIME olivine is stable at lower temperatures than Mn‐poor olivine and at low oxygen fugacities (dust enrichment <10× solar). Although this set of samples does not represent a single metamorphic sequence, the higher subtypes tend to have AOA olivine with lower Mn/Fe, suggesting that Mn/Fe decreases during parent body metamorphism. Y‐81020 has the lowest subtype and most forsteritic AOA olivine (Fo_>95) in our study, whereas Efremovka AOAs are slightly Fe‐rich (Fo_>92). AOA olivines from Kaba are mostly forsteritic, but rare Fe‐rich olivine precipitated from an aqueous fluid. A combination of precipitation of Fe‐rich olivine and diffusion of Fe into primary olivine grains resulted in iron‐rich compositions (Fo_97–59) in Allende AOAs. Variations from fine‐grained, nonporous matrix toward higher porosity and coarser lath‐like matrix olivine can be divided into six stages represented by (1) Y‐81020, Efremovka, NWA 1152; (2) Y‐86751 lithology B; (3) Y‐86009; (4) Kaba; (5) Y‐86751 lithology A; (6) Allende. These stages are inferred to represent general degree of metamorphism, although the specific roles of thermally driven grain growth and diffusion versus aqueous dissolution and precipitation remain uncertain.     

Localized shock melting in lherzolitic shergottite Northwest Africa 1950: Comparison with Allan Hills 77005

Abstract— The lherzolitic Martian meteorite Northwest Africa (NWA) 1950 consists of two distinct zones: 1) low‐Ca pyroxene poikilically enclosing cumulate olivine (Fo_70–75) and chromite, and 2) areas interstitial to the oikocrysts comprised of maskelynite, low‐ and high‐Ca pyroxene, cumulate olivine (Fo_68–71) and chromite. Shock metamorphic effects, most likely associated with ejection from the Martian subsurface by large‐scale impact, include mechanical deformation of host rock olivine and pyroxene, transformation of plagioclase to maskelynite, and localized melting (pockets and veins). These shock effects indicate that NWA 1950 experienced an equilibration shock pressure of 35–45 GPa. Large (millimeter‐size) melt pockets have crystallized magnesian olivine (Fo_78–87) and chromite, embedded in an Fe‐rich, Al‐poor basaltic to picro‐basaltic glass. Within the melt pockets strong thermal gradients (minimum 1 °C/μm) existed at the onset of crystallization, giving rise to a heterogeneous distribution of nucleation sites, resulting in gradational textures of olivine and chromite. Dendritic and skeletal olivine, crystallized in the melt pocket center, has a nucleation density (1.0 × 10³ crystals/mm²) that is two orders of magnitude lower than olivine euhedra near the melt margin (1.6 × 10⁵ crystals/mm²). Based on petrography and minor element abundances, melt pocket formation occurred by in situ melting of host rock constituents by shock, as opposed to melt injected into the lherzolitic target. Despite a common origin, NWA 1950 is shocked to a lesser extent compared to Allan Hills (ALH) 77005 (45–55 GPa). Assuming ejection in a single shock event by spallation, this places NWA 1950 near to ALH 77005, but at a shallower depth within the Martian subsurface. Extensive shock melt networks, the interconnectivity between melt pockets, and the ubiquitous presence of highly vesiculated plagioclase glass in ALH 77005 suggests that this meteorite may be transitional between discreet shock melting and bulk rock melting.     

Martian meteorite Tissint records unique petrogenesis among the depleted shergottites

Tissint, a new unaltered piece of Martian volcanic materials, is the most silica‐poor and Mg‐Fe‐rich igneous rock among the “depleted” olivine‐phyric shergottites. Fe‐Mg zoning of olivine suggests equilibrium growth (<0.1 °C h^?1) in the range of Fo_80–56 and olivine overgrowth (Fo_55–18) through a process of rapid disequilibrium (~1.0–5.0 °C h^?1). The spatially extended (up to 600 μm) flat‐top Fe‐Mg profiles of olivine indicates that the early‐stage cooling rate of Tissint was slower than the other shergottites. The chemically metastable outer rim of olivine (55) consists of oscillatory phosphorus zoning at the impact‐induced melt domains and grew rapidly compared to the early to intermediate‐stage crystallization of the Tissint bulk. High‐Ca pyroxene to low‐Ca pyroxene and high‐Ca pyroxene to plagioclase ratios of Tissint are more comparable to the enriched basaltic and enriched olivine‐phyric shergottites. Dominance of augite over plagioclase induced augite to control the Ca‐buffer in the residual melt suppressing the plagioclase crystallization, which also caused a profound effect on the Al‐content in the late‐crystallized pyroxenes. Mineral chemical stability, phase‐assemblage saturation, and pressure–temperature path of evolution indicates that the parent magma entered the solidus and left the liquidus field at a depth of 40–80 km in the upper mantle. Petrogenesis of Tissint appears to be similar to LAR 06319, an enriched olivine‐phyric shergottite, during the early to intermediate stage of crystallization. A severe shock‐induced deformation resulted in remelting (10–15 vol%), recrystallization (most Fe‐rich phases), and exhumation of Tissint in a time scale of 1–8 yr. Tissint possesses some distinct characteristics, e.g., impact‐induced melting and deformation, forming phosphorus‐rich recrystallization rims of olivine, and shock‐induced melt domains without relative enrichment of LREEs compared to the bulk; and shared characteristics, e.g., modal composition and magmatic evolution with the enriched basaltic shergottites, evidently reflecting unique mantle source in comparison to the clan of the depleted members.     

THE CORREO AND SUWANEE SPRING METEORITES: TWO NEW ORDINARY CHONDRITE FINDS

Two new ordinary chondrites were found about 40 km west of Albuquerque, New Mexico. Correo is an H4 chondrite with distinct chondrules and major olivine (Fo_81.4), orthopyroxene (En_82.3) and plagioclase (An₁₂). Suwanee Spring is an L5 chondrite with few distinct chondrules and a highly recrystallized matrix. Major minerals are olivine (Fo_75.4), orthopyroxene (En_77.7) and plagioclase (An₉). The metallic Ni-Fe phases of both meteorites are typical of slowly-cooled ordinary chondrites.     

In situ micro‐Raman and X‐ray diffraction study of diamonds and petrology of the new ureilite UAE 001 from the United Arab Emirates

Abstract— A new olivine‐pigeonite ureilite containing abundant diamonds and graphite was found in the United Arab Emirates. This is the first report of a meteorite in this country. The sample is heavily altered, of medium shock level, and has a total weight of 155 g. Bulk rock, olivine (Fo_79.8–81.8) and pyroxene (En_73.9–75.2, Fs_15.5–16.9, Wo_8.8–9.5) compositions are typical of ureilites. Olivine rims are reduced with Fo increasing up to Fo_96.1–96.8. Metal in these rims is completely altered to Fehydroxide during terrestrial weathering. We studied diamond and graphite using micro‐Raman and in situ synchrotron X‐ray diffraction. The main diamond Raman band (LO = TO mode at ?1332 cm^?1) is broadened when compared to well‐ordered diamond single crystals. Full widths at half maximum (FWHM) values scatter around 7 cm^?1. These values resemble FWHM values obtained from chemical vapor deposition (CVD) diamond. In situ XRD measurements show that diamonds have large grain sizes, up to >5 μm. Some of the graphite measured is compressed graphite. We explore the possibilities of CVD versus impact shock origin of diamonds and conclude that a shock origin is much more plausible. The broadening of the Raman bands might be explained by prolonged shock pressure resulting in a transitional Raman signal between experimentally shock‐produced and natural diamonds.     

Space weathering on airless bodies: Resolving a mystery with lunar samples

Abstract— Using new techniques to examine the products of space weathering of lunar soils, we demonstrate that nanophase reduced iron (npFe⁰) is produced on the surface of grains by a combination of vapor deposition and irradiation effects. The optical properties of soils (both measured and modeled) are shown to be highly dependent on the cumulative amount of npFe⁰, which varies with different starting materials and the energetics of different parts of the solar system. The measured properties of intermediate albedo asteroids, the abundant S‐type asteroids in particular, are shown to directly mimic the effects predicted for small amounts of npFe⁰ on grains of an ordinary chondrite regolith. This measurement and characterization of space weathering products seems to remove a final obstacle hindering a link between the abundant ordinary chondrite meteorites and common asteroids.     

Occurrence and implications of secondary olivine veinlets in lunar highland breccia Northwest Africa 11273

Lunar breccias preserve the records of geologic processes on the Moon. In this study, we report the occurrence, petrography, mineralogy, and geologic significance of the observed secondary olivine veinlets in lunar feldspathic breccia meteorite Northwest Africa (NWA) 11273. Bulk‐rock composition measurements show that this meteorite is geochemically similar to other lunar highland meteorites. In NWA 11273, five clasts are observed to host veinlets that are dominated by interconnecting olivine mineral grains. The host clasts are mainly composed of mafic minerals (i.e., pyroxene and olivine) and probably sourced from a basaltic lithology. The studied olivine veinlets (~5 to 30 μm in width) are distributed within the mafic mineral host, but do not extend into the adjacent plagioclase. Chemically, these olivine veinlets are Fe‐richer (Fo_41.4–51.9), compared with other olivine grains (Fo_54.3–83.1) in lithic clasts and matrix of NWA 11273. By analogy with the secondary olivine veinlets observed in meteorites from asteroid Vesta (howardite–eucrite–diogenite group samples) and lunar mare samples, our study suggests that the newly observed olivine veinlets in NWA 11273 are likely formed by secondary deposition from a lunar fluid, rather than by crystallization from a high‐temperature silicate melt. Such fluid could be sulfur‐ and phosphorous‐poor and likely had an endogenic origin on the Moon. The new occurrence of secondary olivine veinlets in breccia NWA 11273 reveals that the fluid mobility and deposition could be a previously underappreciated geological process on the Moon.