A search for millimeter-wave emission from HCN and other molecules in Comet Bradfield (1979l)

Millimeter-wave emission from HCN, CS, CH₃OH, and two unidentified lines (previously observed in Comet Kohoutek (1973 XII)) was sought and not detected from Comet Bradfield (1979l) after perihelion passage. Limits on column densities and production rates are derived. In the case of HCN, the production rate is less than that reported for Comet Kohoutek, even after scaling relative to the observed OH emission from each comet.     

Radioastronomical observations of comets IRAS-Araki-Alcock (1983d) and Sugano-Saigusa-Fujikawa (1983e)

Detections and upper limits to the continuum emission (1 ≤ λ ≤6 cm) and spectral line emission (OH, CO, CS, HCN, HCO⁺, CN, CH₃CN, CH₃C₂H, NH₃, H₂O, HC₃N, CH₃CH₂CN) are reported from radio observations of Comets 1983d and 1983e. Comparison is made with observations of CN at optical wavelengths. These results may be useful in planning future cometary observations.     

Molecule searches in Comet Kohoutek (1973f) at microwave frequencies

Nine transitions of the possible parent molecules H₂O, NH₃, CH₃OH and N₂O as well as the OH radical were searched for in Comet Kohoutek (1973f) in the frequency range 22.2–25.2 GHz. These molecules were not detected, but the upper limits for the optical depth, mean column density and the production rate are derived for each of the molecules. These results are discussed and compared with the reported detections of HCN and CH₃CN emission and OH absorption.     

Spectroscopic Observations of Comet C/1996 B2 (Hyakutake) with the Caltech Submillimeter Observatory

The apparition of Comet C/1996 B2 (Hyakutake) offered an unexpected and rare opportunity to probe the inner atmosphere of a comet with high spatial resolution and to investigate with unprecedented sensitivity its chemical composition. We present observations of over 30 submillimeter transitions of HCN, H¹³CN, HNC, HNCO, CO, CH₃OH, and H₂CO in Comet Hyakutake carried out between 1996 March 18 and April 9 at the Caltech Submillimeter Observatory. Detections of the H¹³CN (4–3) and HNCO (16_0,16–15_0,15) transitions represent the first observations of these species in a comet. In addition, several other transitions, including HCN (8–7), CO (4–3), and CO (6–5) are detected for the first time in a comet as is the hyperfine structure of the HCN (4–3) line. The observed intensities of the HCN (4–3) hyperfine components indicate a line center optical depth of 0.9 ± 0.2 on March 22.5 UT. The HCN/HNC abundance ratio in Comet Hyakutake at a heliocentric distance of 1 AU is similar to that measured in the Orion extended ridge— a warm, quiescent molecular cloud. The HCN/H¹³CN abundance ratio implied by our observations is 34 ± 12, similar to that measured in giant molecular clouds in the galactic disk but significantly lower than the Solar System¹²C/¹³C ratio. The low HCN/H¹³CN abundance ratio may be in part due to contamination by an SO₂line blended with the H¹³CN (4–3) line. In addition, chemical models suggest that the HCN/H¹³CN ratio can be affected by fractionation during the collapse phase of the protosolar nebula; hence a low HCN/H¹³CN ratio observed in a comet is not inconsistent with the solar system¹²C/¹³C isotopic ratio. The abundance of HNCO relative to water derived from our observations is (7 ± 3) × 10⁻⁴. The HCN/HNCO abundance ratio is similar to that measured in the core of Sagittarius B2 molecular cloud. Although a photo-dissociative channel of HNCO leads to CO, the CO produced by HNCO is a negligible component of cometary atmospheres. Production rates of HCN, CO, H₂CO, and CH₃OH are presented. Inferred molecular abundances relative to water are typical of those measured in comets at 1 AU from the Sun. The exception is CO, for which we derive a large relative abundance of 30%. The evolution of the HCN production rate between March 20 and March 30 suggests that the increased activity of the comet was the cause of the fragmentation of the nucleus. The time evolution of the H₂CO emission suggests production of this species from dust grains.     

Spectrophotometry of Comet Bradfield (1987s)

Spectral scans of Comet Bradfield (1987s) at heliocentric distance of 1.539 AU have been observed spectrophotometrically. The column densities and production rates of C₂ and CN have been derived.     

Radio Investigations Of 19p/Borrelly In Support To The Deep Space 1 Flyby

NASA's Deep Space 1 mission flew by Comet 19P/Borrelly on September 22, 2001.We present observations of molecular species obtained with the 30-m telescope of theInstitut de Radioastronomie Millimétrique (IRAM) and the Nançay radio telescopeat and near the time of this flyby. OH, HCN, and CS production rates were measured,while upper limits were deduced for CO, H₂CO and H₂S.     

The organic composition of C/2001 A2 (LINEAR): II. Search for heterogeneity within a comet nucleus

The nucleus of Comet C/2001 A2 (LINEAR) split several times during its recent apparition, presenting an unusual opportunity to search for chemical differences in freshly exposed material. We conducted this search using NIRSPEC at the W.M. Keck Observatory on four dates in 2001: 9.5 and 10.5 July and 4.4 and 10.5 August. We detected the R0 and R1 lines of the ν₃ vibrational band of CH₄ near 3.3 μm on all dates. The R2 line was detected on 4.4 and 10.5 August. When we compare production rates of CH₄ to H₂O, we find evidence of a significant enhancement in August relative to that found in July. H₂CO was securely detected via its ν₁ and ν₅ bands on 9.5 July. On 10.5 July, H₂CO emission was much weaker, and its mixing ratio had dropped by a factor of about four. The mixing ratios for other detected volatile species did not change significantly over the course of the observations. We discuss the implications of this evidence for chemical heterogeneity in the nucleus of Comet C/2001 A2.     

A multi-wavelength study of parent volatile abundances in Comet C/2006 M4 (SWAN)

Volatile organic emissions were detected post-perihelion in the long-period Comet C/2006 M4 (SWAN) in October and November 2006. Our study combines target-of-opportunity infrared observations using the Cryogenic Echelle Spectrometer (CSHELL) at the NASA-IRTF 3-m telescope, and millimeter wavelength observations using the Arizona Radio Observatory (ARO) 12-m telescope. Five parent volatiles were measured with CSHELL (H₂O, CO, CH₃OH, CH₄, and C₂H₆), and two additional species (HCN and CS) were measured with the ARO 12-m. These revealed highly depleted CO and somewhat enriched CH₃OH compared with abundances observed in the dominant group of long-period (Oort cloud) comets in our sample and similar to those observed recently in Comet 8P/Tuttle. This may indicate highly efficient H-atom addition to CO at very low temperature (∼10-20 K) on the surfaces of interstellar (pre-cometary) grains. Comet C/2006 M4 had nearly “normal” C₂H₆ and CH₄, suggesting a processing history similar to that experienced by the dominant group. When compared with estimated water production at the time of the millimeter observations, HCN was slightly depleted compared with the normal abundance in comets based on IR observations but was consistent with the majority of values from the millimeter. The ratio CS/HCN in C/2006 M4 was within the range measured in ten comets at millimeter wavelengths. The higher apparent H-atom conversion efficiency compared with most comets may indicate that the icy grains incorporated into C/2006 M4 were exposed to higher H-atom densities, or alternatively to similar densities but for a longer period of time.     

Chemical Composition Diversity Among 24 Comets Observed At Radio Wavelengths

We present a comparative study on molecular abundances in comets basedon millimetre/submillimetre observations made with the IRAM 30-m,JCMT, CSO and SEST telescopes. This study concerns a sample of 24comets (6 Jupiter-family, 3 Halley-family, 15 long-period) observedfrom 1986 to 2001 and 8 molecular species (HCN, HNC, CH₃CN,CH₃OH, H₂CO, CO, CS, H₂S). HCN was detected in all comets,while at least 2 molecules were detected in 19 comets. From the sub-sample of comets for which contemporary H₂O productionrates are available, we infer that the HCN abundance relative to water variesfrom 0.08% to 0.25%. With respect to other species, HCN is the moleculewhich exhibits the lowest abundance variation from comet to comet. Therefore,production rates relative to that of HCN can be used for a comparative study ofmolecular abundances in the 19 comets. It is found that: CH₃OH/HCN varies from ≤ 9 to 64; CO/HCN varies from ≤ 24 to 180; H₂CO/HCN varies between 1.6 and 10; and H₂S/HCN varies between 1.5 and 7.6. This study does not show any clear correlation between the relative abundancesand the dynamical origins of the comets, or their dust-to-gas ratios.     

Morphology of HCN and CN in Comet Hale-Bopp (1995 O1)

We compare images of Comet Hale-Bopp (1995 O1) in HCN and CN taken near perihelion (April 1, 1997) to determine the origin of CN in comets. We imaged the J=1→0 transition of HCN at λ=3 mm with the BIMA Array. Data from two weeks around perihelion were summed within four phase bins based on the rotational period of the comet. This increases both the signal-to-noise ratio and the u-v coverage while decreasing the smearing of the spatial features. The similarly phased narrowband CN images were taken at Lowell Observatory within the same range of dates as the HCN images. We find that there is a better correlation between HCN and CN than between HCN and the optically dominant dust. If the CN in jets does have a dust source it would have to have a very low albedo and/or small particle size. The production rates are consistent with HCN being a primary parent of CN, although there are discrepancies between the HCN destruction scalelength and the CN production scalelength which we discuss.     

The outgassing and composition of Comet 19P/Borrelly from radio observations

Radio spectroscopic observations of Comet 19P/Borrelly were performed during the 1994 apparition and at, and near, the time of the Deep Space 1 flyby in 2001. HCN, CS, CH₃OH, and H₂CO were detected using the 30-m telescope of the Institut de Radioastronomie Millimétrique and the James Clerk Maxwell Telescope, and their production rates relative to water are estimated to be 0.06-0.11, 0.07, 1.7, and 0.4%, respectively. Only upper limits are derived for H₂S and CO. The upper limit for CO/H₂O (<15%) is not very constraining, while the upper limit for the H₂S/H₂O ratio of 0.45% is near the bottom of the range of values measured for other comets. Observations of the OH radical at the Nançay radio telescope provide water production rates a few weeks before the 1994 and 2001 perihelia. Observations of the 1₁₀-1₀₁ water line at 557 GHz with the Odin satellite yield a water production rate of (2.5±0.5)×10²⁸ s⁻¹ on September 22, 2001, at the time of the Deep Space 1 encounter, and (3.3±0.6)×10²⁸ s⁻¹ averaged over the September 22-24, 2001 period. The line shapes are asymmetric and blueshifted by V₀∼−0.18 km s⁻¹ for the best observed HCN lines recorded one week after perihelion. The HCN line shapes, and the similar OH and HCN velocity shifts over the September-November 1994 and August-September 2001 periods, favor anisotropic outgassing towards the Sun. Strong outgassing directed along the primary dust jet seen on visible images is not excluded by the HCN line shapes, but unrealistically high gas expansion velocities are required to explain the line shapes in that case.     

An analysis of spectrophotometric observations of comets Austin (1982g) and Bradfield (1980t)

Post-perihelion observed emission fluxes at 388 nm (CN) and 516 nm (C₂) of the coma of comets Austin (1982g) and Bradfield (1980t) are analysed in the framework of the Haser model. Ratios of Haser model CN and C₂ parent production rates with expansion velocity show that each comet behaves normally. For comet Austin (1982g), the Q _CN/v and Q _c2/v values decrease with increase of heliocentric distance of comet. For an assumed %; activity of the total spherical surface area of the nucleus, the water vaporization theory coupled with derived water production rates from the International Ultraviolet Explorer H and OH flux data yields a nuclear diameter of about 6 km for comet Austin (1982g). For comet Bradfield (1980t), the derived nuclear diameter is expected to be of about 1 km. In each comet, the dust mass production rates as well as ratio of dust-to-gas mass production rates decrease with increase of heliocentric distance of comet.     

A search for millimeter wave spectral lines from comet Sugano-Saigusa-Fujikawa (1983e)

The search for radio spectral lines from Comet Sugano-Saigusa-Fujikawa (1983e) was conducted using the 45-m telescope of Nobeyama Radio Observatory. The frequency ranges of 44.0–46.0 and 47.5–49.5 GHz were surveyed down to $\text{ΔT}{}_{\mathrm{<mtext>A</mtext>}}{}^1\text{(}\text{rms}\text{) = 20–30}\text{mK}$, with a beam size of ～35 arc sec. Upper limits have been established for spectral lines of atomic hydrogen, CS, OCS, SO₂, H₂CO, CH₃OH, HCCCCCN, HCOOCH₃, CH₃OCH₃, and CH₃CH₂CN. The J = 5?4 line from HCCCN in the vibrational ground state possibly has been detected but not confirmed. The suggested total amount of HCCCN in the coma is consistent with the possible picture that HCCCN is the main parent molecule of CN.     

Infrared study of ion-irradiated N2-dominated ices relevant to Triton and Pluto: formation of HCN and HNC

Infrared spectra and radiation chemical behavior of N₂-dominated ices relevant to the surfaces of Triton and Pluto are presented. This is the first systematic IR study of proton-irradiated N₂-rich ices containing CH₄ and CO. Experiments at 12 K show that HCN, HNC, and diazomethane (CH₂N₂) form in the solid phase, along with several radicals. NH₃ is also identified in irradiated N₂ + CH₄ and N₂ + CH₄ + CO. We show that HCN and HNC are made in irradiated binary ice mixtures having initial N₂/CH₄ ratios from 100 to 4, and in three-component mixtures have an initial N₂/(CH₄ + CO) ratio of 50. HCN and HNC are not detected in N₂-dominated ices when CH₄ is replaced with C₂H₆, C₂H₂, or CH₃OH.The intrinsic band strengths of HCN and HNC are measured and used to calculate G(HCN) and G(HNC) in irradiated N₂ + CH₄ and N₂ + CH₄ + CO ices. In addition, the HNC/HCN ratio is calculated to be ∼1 in both icy mixtures. These radiolysis results reveal, for the first time, solid-phase synthesis of both HCN and HNC in N₂-rich ices containing CH₄.We examine the evolution of spectral features due to acid-base reactions (acids such as HCN, HNC, and HNCO and a base, NH₃) triggered by warming irradiated ices from 12 K to 30-35 K. We identify anions (OCN⁻, CN⁻, and N3−) in ices warmed to 35 K. These ions are expected to form and survive on the surfaces of Triton and Pluto. Our results have astrobiological implications since many of these products (HCN, HNC, HNCO, NH₃, NH₄OCN, and NH₄CN) are involved in the syntheses of biomolecules such as amino acids and polypeptides.     

Spectroscopy of Comet Hale-Bopp in the infrared

High resolution infrared spectra of Comet C/1995 O1 (Hale-Bopp) were obtained during 2-5 March 1997 UT from the NASA Infrared Telescope Facility on Mauna Kea, Hawaii, when the comet was at r≈1.0 AU from the Sun pre-perihelion. Emission lines of CH₄, C₂H₆, HCN, C₂H₂, CH₃OH, H₂O, CO, and OH were detected. The rotational temperature of CH₄ in the inner coma was T_rot=110±20 K. Spatial profiles of CH₄, C₂H₆, and H₂O were consistent with release solely from the nucleus. The centroid of the CO emission was offset from that of the dust continuum and H₂O. Spatial profiles of the CO lines were much broader than those of the other molecules and asymmetric. We estimate the CO production rate using a simplified outflow model: constant, symmetric outflow from the peak position. A model of the excitation of CO that includes optical depth effects using an escape probability method is presented. Optical depth effects are not sufficient to explain the broad spatial extent. Using a parent+extended-source model, the broad extent of the CO lines can be explained by CO being produced mostly (∼90% on 5 March) from an extended source in the coma. The CO rotational temperature was near 100 K. Abundances relative to H₂O (in percent) were 1.1±0.3 (CH₄), 0.39±0.10 (C₂H₆), 0.18±0.04 (HCN), 0.17±0.04 (C₂H₂), 1.7±0.5 (CH₃OH), and 37-41 (CO, parent+extended source). These are roughly comparable to those obtained for other long-period comets also observed in the infrared, though CO appears to vary.     

The millimeter spectrum of Titan: Detectability of HCN,HC3N,and CH3CN and the CO abundance

The flux emitted by Titan's disk in millimeter lines of HCN, HC₃N, CH₃CN, and CO is calculated by means of a radiative transfer formulation which takes into account the sphericity of the atmosphere. It is demonstrated that the plane-parallel approximation for radiative transfer is no longer valid, especially in the core of emission lines, when Titan is not spatially resolved. The antenna temperatures which would be measured by large radiotelescopes observing Titan at frequencies of (1?0) and (2?1) transitions of CO, of (1?0), (2?1), and (3?2) transitions of HCN, and of selected transitions of HC₃N and CH₃CN in the range 80–300 GHz are calculated. The observability of these transitions is investigated. It is concluded that there is the possibility of inferring the vertical stratospheric distribution of these species from line shape measurements to be achieved with existing or forthcoming radioastronomical instrumentation. The determination of the CO abundance by D. O. Muhleman, G. L. Berge, and R. T. Clancy (1984, (Science (Washington, D.C.), 223, 393–396) from measurements at 115.3 GHz in two 200 MHz bands, is reinterpreted by means of this radiative transfer formulation. A CO mixing ratio between 3 × 10^?5 and 18 × 10^?5, with a most plausible value of 7.5 × 10^?5, is found.     

New Millimeter Heterodyne Observations of Titan: Vertical Distributions of Nitriles HCN, HC3N, CH3CN, and the Isotopic Ratio N/N in Its Atmosphere

High sensitivity observations were performed at 1.2- and 3-mm wavelengths with the IRAM 30-m telescope (Spain) between April 1996 and December 1999 to investigate the nitrile composition of Titan's stratosphere. A part of our dataset consists of high resolution spectra of HC¹⁴N taken at 88.6 GHz as well as spectra of HC¹⁵N recorded at 258.16 GHz. From a thorough analysis of both lines and with the help of appropriate radiative transfer calculations we show that the isotopic ratio ¹⁵N/¹⁴N is strongly enhanced compared to the terrestrial value. We propose that the range 3.9-4.5 should be considered as a basis for the enrichment factor. Five individual lines of HC₃N were measured at 39-kHz resolution using a frequency-switched technique. Several CH₃CN features were recorded at 78-kHz resolution in two transitions around 147.6 and 220.7 GHz. The high spectral resolution and the good signal-to-noise ratio affecting the spectra permit us to retrieve disk-averaged vertical profiles for HCN up to 450 km and for HC₃N and CH₃CN up to 500 km. Comparison of our inferred vertical profiles with relevant results of presently published photochemical models is presented. We show that the profiles of HCN and HC₃N predicted by various authors below 450-km altitude appear inconsistent with our new observations. We find that the three distributions present very different gradients of abundance below 200-km altitude down to the condensation levels around 80 km. In the upper stratosphere HC₃N and CH₃CN have approximately the same mixing ratio of about 4×10⁻⁸ at 450 km, at least one order of magnitude lower than that of HCN. In the same time, another nitrile HC₅N has been searched for by observing four transitions located between 109 and 221 GHz. As no spectral features could be detected after several hours of integration time, we propose an upper limit for the mixing ratio equal to 4×10⁻¹⁰ assuming a uniform distribution of this compound in the lower stratosphere.     

A search for H2O and Ch4 in Comet Kohoutek

A spectroscopic search for H₂O and CH₄ in Comet Kohoutek (1973f) was made using a Pepsios interferometer. No evidence was found for either molecule, allowing us to set an upper limit on their production rates (on about 21 January 1974) of Q(H₂O) < 6.2 × 10²⁸ sec^?1 and Q(CH₄) < 2.0 × 10³⁰ sec^?1. If the cometary surface is water-ice, this production rate leads to a product (1 ? A)·(πR₀²) < 2.2 km², where A is the Bond albedo, R₀ is the nuclear radius, and we assume that all the absorbed solar energy is used to evaporate H₂O.     

The spectrum of comet C/2009 R1 (McNaught) in 4140–5240 Å wavelength region

The spectroscopic observations of comet C/2009 R1 (McNaught) were carried out with the 2 m Zeiss-RCC Telescope of Pik Terskol Observatory operated by the International Center for Astronomical and Medico-Ecological Research (Ukraine, Russia). The Multi Mode Cassegrain spectrometer was used to obtain spectra of moderate spectral resolving power with a wavelength coverage from 4140 to 5240 Å. The spectrum is characterized by the extremely low continuum level and strong molecular features. 192 emission lines of C₂, CN, CH, NH₂, CO⁺, and CH⁺ have been identified by the comparison of the observed and theoretical spectra of the molecules. The ratios of the gas production rates of Q(C₂)/Q(CN)=1.32, Q(CH)/Q(CN)=0.49, and Q(NH₂)/Q(CN)=0.81 were derived using a Haser model.     

The 1995–2002 Long-Term Monitoring of Comet C/1995 O1 (HALE–BOPP) at Radio Wavelength

The bright comet Hale–Bopp provided the first opportunity to follow the outgassing rates of a number of molecular species over a large range of heliocentric distances. We present the results of our observing campaign at radio wavelengths which began in August 1995 and ended in January 2002. The observations were carried out with the telescopes of Nançay, IRAM, JCMT, CSO and, since September 1997, SEST. The lines of nine molecules (OH, CO, HCN, CH₃OH, H₂CO, H₂S, CS, CH₃CN and HNC) were monitored. CS, H₂S, H₂CO, CH₃CN were detected up to r_h= 3–4 AU from the Sun, while HCN and CH₃OH were detected up to 6 AU. CO, which is the main driver of cometary activity at heliocentric distances larger than 3–4 AU, was last detected in August 2001, at r_h= 14 AU. The gas production rates obtained from this programme contain important information on the nature of cometary ices, their thermal properties and sublimation mechanisms.Line shapes allow to measure gas expansion velocities, which, at large heliocentric distances, might be directly connected to the temperature of the nucleus surface. Inferred expansion velocity of the gas varied as r_h ^-0.4 within 7 AU from the Sun, but remained close to 0.4 km s^-1 further away. The CO spectra obtained at large r_hare strongly blueshifted and indicative of an important day-to-night asymmetry in outgassing and expansion velocity. The kinetic temperature of the coma, estimated from the relative intensities of the CH₃OH and CO lines, increased with decreasing r_h, from about 10 K at 7 AU to 110 K around perihelion.