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1.
Seymour L. Hess 《Icarus》1976,28(2):269-278
Calculations are performed of the vertical distribution of water vapor and condensate in an adiabatic atmosphere on Mars taking into account turbulent diffusion and terminal velocity. The distributions are found to be substantially different when terminal velocity is included. The eddy-diffusion coefficient in the troposphere cannot be much greater than 105 cm2sec?1 if optical depths are to be kept low enough to be consistent with observations. Processes in the boundary layer are also discussed. We conclude that virtually all the water vapor is to be found in the lowest 6–10 km and that the lowest 2km should have a greate r concentration than the rest of that layer. Some observational tests of these ideas and conclusion can be performed by the Viking missions to Mars.  相似文献   

2.
A model is presented for the photochemistry of PH3 in the upper troposphere and lower stratosphere of Saturn that includes the effects of coupling with NH3 and hydrocarbon photochemistry, specifically the C2H2 catalyzed photodissociation of CH4. PH3 is rapidly depleted with altitude (scale height ~35 km) in the upper troposphere when K~104cm2sec?1; an upper limit for K at the tropopause is estimated at ~105cm2sec?1. If there is no gas phase P2H4 because of sublimation, P2 and P4 formation is unlikely unless the rate of the spin-forbidden recombination reaction PH + H2 + M → PH3 + M is exceedingly slow. An upper limit P4 column density of ~2×1015cm?2 is estimated in the limit of no recombination. If sublimation does not remove all gas phase P2H4, P2 and P4 may be produced in potentially larger quantities, although they would be restricted almost entirely to the lowest levels of our model, where T?100°K. Potentially observable amounts of the organophosphorus compounds CH3P2H2 and HCP are predicted, with column densities of >1017 cm?2 and production rates of ~2×108cm?2sec?1. The possible importance of electronically excited states of PHx and additional PH3/hydrocarbon photochemical coupling paths are also considered.  相似文献   

3.
The calculation of number densities of CO2, H2O and N2 photolysis products was carried out for the Martian atmosphere at heights up to 60 km. The ozone distributed in the atmosphere as a layer of 10 km width with [O3] max = 2.5 × 109 cm3 at height of 35 km which agree well with the results of u.v. observations on the evening terminator from the Mars-5 satellite. The calculated densities of O2, CO and H2O are also in good agreement with the measured data. The eddy diffusion coefficient is equal to 3 × 106 in the troposphere (h ? 30 km) and 108 cm2 s?1 above 40 km. The dependence of the total ozone content on water vapour amount in the atmosphere is considered; the hypothesis about the influence of water ice aerosol on the ozone formation is proposed to explain the high concentrations of ozone in the morning.  相似文献   

4.
Calculations of the steady-state photoelectron energy and angular distribution in the altitude region between 120 and 1000 km are presented. The distribution is found to be isotropic at all altitudes below 250 km, while above this altitude anisotropies in both pitch angle and energy are found. The isotropy found in the angular distribution below 250 km implies that photoelectron transport below 250 km is insignificant, while the angular anisotropy found above this altitude implies a net photoelectron current in the upward direction. The energy anisotropy above 500 km arises from the selective backscattering of the low energy photoelectron population of the upward flux component by Coulomb collisions with the ambient ions. The total photoelectron flux attains its maximum value between about 40 and 70 km above the altitude at which the photoelectron production rate is maximum. The displacement of the maximum of the equilibrium flux is attributed to an increasing (with altitude) photoelectron lifetime. Photoelectrons at altitudes above that where the flux is maximum are on the average more energetic than those below that altitude. The flux of photoelectrons escaping to the protonosphere at dawn was found to be 2.6 × 108 cm?2 sec?1, while the escaping flux at noon was found to be 1.5 × 108 cm?2 sec?1. The corresponding escaping energy fluxes are: 4.4 × 109 eV cm?2 sec?1 and 2.7 × 109 eV cm?2 sec?1.  相似文献   

5.
In an updating of energy characteristics of lightnings on Venus obtained from Venera-9 and -10 optical observations, the flash energy is given as 8 × 108 J and the mean energy release of lightnings is 1 erg cm?2 s which is 25 times as high as that on the Earth. Lightnings were observed in the cloud layer. The stroke rate in the near-surface atmosphere is less than 5 s?1 over the entire planet if the light energy of the stroke exceeds 4 × 105 J and less than 15 s?1 for (1–4) × 105 J.The average NO production due to lightnings equals 5 × 108 cm?2 s?1, the atomic nitrogen production is equal to 7 × 109 cm?2s?1,the N flux toward the nightside is 3.2 × 109 cm?2s?1, the number densities [N] = 3 × 107cm?3 and [NO] = 1.8 × 106cm?3 at 135 km. Almost all NO molecules in the upper atmosphere vanish interacting with N and the resulting NO flux at 90-80 km equals 5 × 105cm?2s?1, which is negligibly small as compared with lightning production. If the predissociation at 80–90 km is regarded as the single sink of NO, its mixing ratio, fNO, is 4 × 10?8, for the case of a surface sink fNO = 0.8 × 10?9 at 50 km. Excess amounts, fNO ? 4 × 10?8, may exist in the thunderstorm region.  相似文献   

6.
The u.v. spectrometer polarimeter on the Solar Maximum Mission has been utilized to measure mesospheric ozone vs altitude profiles by the technique of solar occultation. Sunset data are presented for 1980, during the fall equinoctal period within ± 20° of the geographic equator. Mean O3, concentrations are 4.0 × 1010 cm?3at 50 km, 1.6 × 1010 cm?3 at 55 km. 5.5 × 109 cm?3 at 60 km and 1.5 × 109 cm?3 at 65 km. Som profiles exhibit altitude structure which is wavelike. The mean ozone profile is fit best with the results of a time-dependent model if the assumed water vapor mixing ratio employed varies from 6 ppm at 50 km to 2–4 ppm at 65 km.  相似文献   

7.
The giant post-flare arch of 6 November 1980 revived 11 hr and 25 hr after its formation. Both these revivals were caused by two-ribbon flares with growing systems of loops. The first two brightenings of the arch were homologous events with brightness maxima moving upwards through the corona with rather constant speed; during all three brightenings the arch showed a velocity pattern with two components: a slow one (8–12 km?1), related to the moving maxima of brightness, and a fast one (~ 35 km s?1), the source of which is unknown. During the first revival, at an altitude of 100000 km, temperature in the arch peaked ~ 1 hr, brightness ~ 2 hr, and emission measure ~ 3.5 hr after the onset of the brightening. Thus the arch looks like a magnified flare, with the scales both in size and time increased by an order of magnitude. At ~ 100000 km altitude the maximum temperature was ?14 × 106K, max.n e? 2.5 × 109cm?3, and max. energy density ? 11.2 erg cm?3. The volume of the whole arch can be estimated to 1.1 × 1030 cm3, total energy ?1.2 × 1031 erg, and total mass ?4.4 × 1015g. The density decreased with the increasing altitude and remained below 7 × 109 cm?3 anywhere in the arch. The arch cooled very slowly through radiation whereas conductive cooling was inhibited. Since its onset the revived arch was subject to energy input within the whole extent of the preexisting arch while a thermal disturbance (a new arch?) propagated slowly from below. We suggest that the first heating of the revived arch was due to reconnection of some of the distended flare loops with the magnetic field of the old preexisting arch. The formation of the ‘post’-flare loop system was delayed and started only some 30–40 min later. Since that time a new arch began to be formed above the loops and the velocities we found reflect this formation.  相似文献   

8.
Results of analysis of about 150 autocorrelation functions are presented for the period from about 2300 hr on 5 October to about 1200 hr on 7 October 1967. A large percentage concentration of helium ions are observed. It reaches a value as high as 50 per cent with a maximum at around 800 km. Downward heat fluxes deduced from the temperature variations yield a value of about 2–2.5 × 109 eV cm?2 sec?1 during the period 1200–1600 hr and a value of about 1.5 × 108 eV cm?2 sec?1 during the period 0100–0400 hr at night. These agree well with other measurements. The O+ ions are found not to be in diffusive equilibrium, and from the O+ fluxes and the electron density profiles, the O+ drift velocity has been estimated. It is found that the speed can be as high as 1–5 × 103 cm sec?1 even at altitudes as high as 700 km.  相似文献   

9.
Four surveys in which the geometrical parameters were suitable for observations on weak scattering objects were carried out by the Venera 9, 10 orbiters using 3000–8000 Å spectrometers. The results of one survey can be explained by a dust layer at the height of sighting h = 100–700 km. Its absence in other sessions suggests a ring structure. The spectrum of dust scattering is a power function of the wavelength with the index varying from ?2.1 at 100km to ?1.3 at 500km. A method is proposed for obtaining the optical thickness, density and size distribution of dust particles from the scattering spectra. For m > 10?14 g the number of dust particles with a mass higher than m is proportional to m?1.3. The radial optical thickness τ is 0.7 × 10?5 at 5000 Å assuming the geometric thickness δ to be 100 km. The maximum optical thickness along the normal to the plane of the ring is τn = 4 × 10?6. The mass of the ring is 20 tons or 5 × 10?3 g cm?1 per unit circumference length; the maximum mass in a column normal to the ring plane is 10?10g cm?2; the maximum density (for δ = 100 km) is 10?17 g cm?3. A satellite of Venus gradually destroyed by temperature effects and by meteorite streams and plasma fluxes is suggested as the source of dust in the ring. One of 1 km radius could sustain such a ring for a billion years. The zodiacal light intensity near Venus is estimated.  相似文献   

10.
This paper discusses SPA's measured at long VLF propagation paths in the lower ionosphere and their association with solar X-ray bursts observed by USNRL satellites in the 0–3 Å, 0–8 Å and 8–20 Å bands. Excellent correlations were found between the SPA importances (in degrees per Mm) and the logarithm of the X-ray burst peak intensities. A hardening of the X-ray burst spectra is evident for increasing importance of SPA's; the threshold energy required for the occurrence of such anomalies was estimated, it is 4.3×10?5 ergs cm?2 sec?1 in the main ionizing band of 0–3 Å. It was also possible to derive the effective recombination coefficient at the normal D-region height of 70 km, this beingα r≈6×10?6 cm3 sec?1; furthermore ion production rates were estimated during SPA's at heights below the reference level.  相似文献   

11.
Interference filter photometry was taken of Comet Encke on June 14, 1974 (1.07 AU heliocentric distance, postperihelion) at the CTIO (Cerro Tololo Interamerican Observatory) 150-cm reflector. Production rates were calculated of 4.1 × 1023 mol sec?1 of CN, 5.3 × 1023 mol sec?1 of C3, and 4.3 × 1024 mol sec?1 of C2. These are about three times smaller than at comparable heliocentric distance preperihelion, assuming a value of 100 for the ratio H2O/ (C2 + C3 + CN). An upper limit was placed on the production of nonvolatiles at about one-third that of volatiles in mass by assuming a bulk density of 1 g cm?3, a particle geometric albedo of 0.1, and a phase function of 0.2.  相似文献   

12.
Altitude dependences of [CO2] and [CO2+] are deduced from Mariner 6 and 7 CO2+ airglow measurements. CO2 densities are also obtained from ne radio occultation measurements. Both [CO2] profiles are similar and correspond to the model atmosphere of Barth et al. (1972) at 120 km, but at higher altitudes they diverge and at 200–220 km the obtained [CO2] values are three times less the model. Both the airglow and radio occultation observations show that a correction factor of 2.5 should be included into the values for solar ionization flux given by Hinteregger (1970). The ratio of [CO2+]/ne is 0.15–0.2 and, hence, [O]/[CO2] is ~3% at 135 km. An atmospheric and ionospheric model is developed for 120–220 km. The calculated temperature profile is characterized by a value of T ≈ 370°K at h ? 220 km, a steep gradient (~2°/km) at 200-160 km, a bend in the profile at 160 km, a small gradient (~0.7°/km) below and a value of T ≈ 250°K at 120 km. The upper point agrees well with the results of the Lyman-α measurements; the steep gradient may be explained by molecular viscosity dissipation of gravity and acoustical waves (the corresponding energy flux is 4 × 10?2 erg cm?2sec?1 at 180 km). The bend at 160 km may be caused by a sharp decrease of the eddy diffusion coefficient and defines K ≈ 2 × 108cm2sec?1; and the low gradient gives an estimate of the efficiency of the atmosphere heating by the solar radiation as ? ≈ 0.1.  相似文献   

13.
A mechanism has been proposed for uv-accelerated desorption from Fe2+ sites on mineral surfaces that satisfies kinetic constraints determined in the laboratory by Huguenin. The process is an integral step of the photochemical weathering mechanism for producing dust on Mars, and it now appears that it may play primary roles in stabilizing CO2 against dissociation by sunlight and in controlling the oxidation state of the atmosphere. We propose that adsorption occurs at octahedrally coordinated Fe2+ surface sites to form seven-coordinate transition-state complexes. These complexes acquire 16–18 kcal mole?1 of ligand field stabilization energy. During illumination (λ ≤ 0.35 μm), electrons are photoemitted from the surfaced Fe2+, temporarily oxidizing them to Fe3+. Fe3+ has no ligand field stabilization energy, and the complexes lose 16–18 kcal mole?1 of stabilization energy. This is a large fraction of the 19- to 28-kcal mole?1 activation energy for dissociating the complexes, and desorption should proceed spontaneously. The gases that were observed to undergo adsorption-photodesorption include O2, CO2, CO, H2O, N2, and Ar. Photodesorption can drive several catalytic reactions, one of which is the oxidation of CO to CO2. The rate of this reaction should be limited by the supply of CO and O2 to the surface to ~2 × 1012 cm?2 sec?1 (column photodissociation rate of CO2). By including this surface reaction in models of Martian atmospheric CO2 chemistry, CO2 can be stabilized against photodissociation with eddy diffusion coefficients of only 3 × 105?1 × 107 cm2 sec?1 below 40 km, raising to ~ 109 cm2 sec?1 at 140 km. Odd hydrogen is not needed to catalyze the oxidation of CO below 40 km, and odd hydrogen mixing ratios need only to be fH ? 10?10 to depress ozone concentrations below the observed upper limit in equatorial regions. Another catalytic reaction that should be driven by photodesorption on Mars is 20H?(ads)H2O + 12O2(g) + 2e?crystal. This is an important source of atmospheric O2, amounting to 7 × 1013?2 × 1017 O2 molecules cm?2 yr?1, and it could have a significant effect on atmospheric oxidation state.  相似文献   

14.
Shock wave and thermodynamic data for rock-forming and volatile-bearing minerals are used to determine minimum impact velocities (vcr) and minimum impact pressures (pcr) required to form a primary H2O atmosphere during planetary accretion from chondritelike planetesimals. The escape of initially released water from an accreting planet is controlled by the dehydration efficiency. Since different planetary surface porosities will result from formation of a regolith, vcr and pcr can vary from 1.5 to 5.8 km/sec and from 90 to 600 kbar, respectively, for target porosities between 0 and ~45%. On the basis of experimental data, hydration rates for forsterite and enstatite are derived. For a global regolith layer on the Earth's surface, the maximum hydration rate equals 6 × 1010 g H2O sec?1 during accretion of the Earth. Attenuation of impact-induced shock pressure is modeled to the extent that the amount of released water as a function of projectile radius, impact velocity, weight fraction of water in the target, target porosity, and dehydration efficiency can be estimated. The two primary processes considered are the impact release of water bound in hydrous minerals (e.g., serpentine) and the subsequent reincorporation of free water by hydration of forsterite and enstatite. These processes are described in terms of model calculations for the accretion of the Earth. Parameters which lead to a primary atmosphere/hydrosphere are: an accretion time of ? 1.6 × 108years, the use of an accretion model defined by Weidenschilling (1974, 1976), a mean planetesimal radius of 0.5 km, a hydration rate of 6 × 1010 g H2O sec?1 inferred from a mean porosity of ~ 10% for the upper 1 km of the accreting Earth, and values for the dehydration efficiency, DE, of 0.55 and 0.07 for the maximum and minimum pressure decay model, respectively. Conditions which prohibit the formation of a primary atmosphere include an accretion time much longer than 1.6 × 108 years, a hydration rate for forsterite and enstatite well in excess of 6 × 1010 g H2O sec?1, and a dehydration efficiency DE < 0.07. We conclude that the concept of dehydration efficiency is of dominant importance in determining the degree to which an accreting planet acquires an atmosphere during its formation.  相似文献   

15.
The temperature dependence of the binary recombination coefficient, α2, for the reaction NO++NO2? → products has been obtained over the range 185–530 K. It is found that the corresponding mean cross section σ is described by the power law σ ? A · T?0.9, and that α2 ? B · T?0.4. Data has also been obtained for two cluster ion recombination reactions which indicate that their recombination cross sections are only about 40% larger than for the parent ions at a given temperature, the cross sections for these reactions also apparently increasing with decreasing temperature. In the light of this data and by considering the most probable positive and negative ions existing at various altitudes up to 90km in the atmosphere, the most appropriate ionic recombination coefficients in various altitude ranges are deduced. Thus, between 30 and 90 km, where the recombination process is two-body, the coefficient varies over the narrow range 5–9 × 10?8 cm3s?1, while below 30 km the process is predominantly three-body with an effective two-body rate increasing rapidly to a maximum value ≈3 × 10?6 cm3s?1 in the troposphere, these deductions being based on published laboratory determinations of three-body recombination coefficients.  相似文献   

16.
Infrared spectral observations of Mars, Jupiter, and Saturn were made from 100 to 470 cm?1 using NASA's G. P. Kuiper Airborne Observatory. Taking Mars as a calibration source, we determined brightness temperatures of Jupiter and Saturn with approximately 5 cm?1 resolution. The data are used to determine the internal luminosities of the giant planets, for which more than 75% of the thermally emitted power is estimated to be in the measured bandpass: for Jupiter LJ = (8.0 ± 2.0) × 10?10L and for Saturn LS = (3.6 ± 0.9) × 10?10. The ratio R of thermally emitted power to solar power absorbed was estimated to be RJ = 1.6 ± 0.2, and RS = 2.7 ± 0.8 from the observations when both planets were near perihelion. The Jupiter spectrum clearly shows the presence of the rotational ammonia transitions which strongly influence the opacity at frequencies ?250 cm?1. Comparison of the data with spectra predicted from current models of Jupiter and Saturn permits inferences regarding the structure of the planetary atmospheres below the temperature inversion. In particular, an opacity source in addition to gaseous hydrogen and ammonia, such as ammonia ice crystals as suggested by Orton, may be necessary to explain the observed Jupiter spectrum in the vicinity of 250 cm?1.  相似文献   

17.
F.P. Fanale 《Icarus》1976,28(2):179-202
Observations of Mars and cosmochemical considerations imply that the total inventory of degassed volatiles on Mars is 102 to 103 times that present in Mars' atmosphere and polar caps. The degassed volatiles have been physically and chemically incorporated into a layer of unconsolidated surface rubble (a “megaregolith”) up to 2km thick. Tentative lines of evidence suggest a high concentration (~5g/cm2) of 40 Ar in the atmosphere of Mars. If correct, this would be consistent with a degassing model for Mars in which the Martian “surface” volatile inventory is presumed identical to that of Earth but scaled to Mars' smaller mass and surface area. The implied inventory would be: (40Ar) = 4g/cm2, (H2O) = 1 × 105g/cm2, (CO2) = 7 × 103g/cm2, (N2) = 3 × 102g/cm2, (Cl) = 2 × 103g/cm2, and (S) = 2 × 102g/cm2. Such a model is useful for testing, but differences in composition and planetary energy history may be anticipated between Mars and Earth on theoretical grounds. Also, the model demands huge regolith sinks for the volatiles listed.If the regolith were in physical equilibrium with the atmosphere, as much as 2 × 104g/cm2 of H2O could be stored in it as hard-frozen permafrost, or 5 × 104g/cm2 if equilibrium with the atmosphere were inhibited. Spectral measurements of Martian regolith material and laboratory measurement of weathering kinetics on simulated regolith material suggest large amounts of hydrated iron oxides and clay minerals exist in the regolith; the amount of chemically bound H2O could be from 1 × 104 to 4 × 104g/cm2. In an Earth-analogous model, a 2 km mixed regolith must contain the following concentrations of other volatile-containing compounds by weight: carbonates = 1.5%, nitrates = 0·3%, chlorides = 0.6%, and sulfates = 0.1%. Such concentrations would be undetectable by current Earth-based spectral reflectance measurements, and (except the nitrates) formation of the “required” amounts of these compounds could result from interaction of adsorbed H2O and ice with primary silicates expected on Mars. Most of the CO2 could be physically adsorbed on the regolith.Thus, maximum amounts of H2O and other volatiles which could be stored in the Mars regolith are marginally compatible with those required by an Earth-analogous model, although a lower atmospheric 40Ar concentration and regolith volatile inventory would be easier to reconcile with observational constraints. Differences in the ratios of H2O and other volatiles to 40Ar between surface volatiles on the real Mars and on an Earth-analogous Mars could result from and reflect differences in bulk composition and time history of degassing between Mars and Earth. Models relating Viking-observable parameters, e.g., (40Ar) and (36Ar), to the time history and overall intensity of Mars degassing are given.  相似文献   

18.
In the laboratory, reactions with flourine species proceed rapidly with high rates but under mesospheric conditions the effeciency of these compounds is low due to the rapid formation of HF and to the lack of reactivity of this species. Even if diffusion processes are included, the result of calculations leads to fluorie concentrations typically less than 20 cm?3. The low photodissociation coeffecient of HF leads to the expectation of a scale height of HF greater than or equal to the mean scale height. If the troposphere appears to be a sink for hydrofluoric acid, the maximum value of fluorine is obtained with a downward flux of 1.3 × 108 HF atoms cm?2 sec?1 at the level of the clouds.  相似文献   

19.
Spectrograph and multiple-band polarimeter observations of the 24 April 1981 white-light flare indicate the presence of an optical continuum with intensity increasing strongly below 4000 Å. The flare emission (lines and continuum combined) is unpolarized and, at 3600 Å, exceeds the brightness of the background solar surface by 360%. Analysis of the spectrum between 3600 and 8200 Å, at a location three arc sec from the brightest point in the kernel, yields a probable temperature of 6700 K for the continuum emitting layer. The wavelength dependence of the continuum indicates emission by both negative hydrogen (H?) and Balmer continuum, with the H? probably originating in the upper photosphere at a height (above τ5000 Å = 1) in the range 200–300 km. Analysis of the Balmer lines and continuum yields an electron density 5.3 × 1013 cm?3 and a second-level hydrogen column density 1.1 × 1016 cm?2. The peak radiative output integrated over wavelength is 6.1 × 1027 erg s?1. The observed continuum intensity, if originating at a height of 300 km, implies an energy loss rate of 103 erg s?1 cm?3.  相似文献   

20.
Previous studies based on radio scintillation measurements of the atmosphere of Venus have identified two regions of small-scale temperature fluctuations located in the vicinity of 45 and 60 km. A global study of the fluctuations near 60 km, which are consistent with wind-shear-generated turbulence, was conducted using the Pioneer Venus measurements. The structure constants of refractive index fluctuations cn2 and temperature fluctuations cT2 increase poleward, peak near 70° latitude, and decrease over the pole; cn2 varies from 2 × 10?15 to 1.5 × 10?14m23 and cT2 from 4 × 10?3 to 7 × 10?2°K2m?23. These results indicate greater turbulent activity at the higher latitudes. In the region near 45 km the refractive index fluctuations and the corresponding temperature fluctuations are substantially lower. Based on the analysis of one representative occultation measurement, cn2 = 2 × 10?16m?23and cT2 = 7.3 × 10?4°K2m?23 in the 45-km region. The fluctuations in this region also appear to be consistent with wind-shear-generated turbulence. The turbulence level is considerably weaker than that at 60 km; the energy dissipation rate ε is 4.9 × 10?5m2sec?3 and the small-scale eddy diffusion coefficient K is 2 × 103 cm2 sec?1.  相似文献   

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