Influence of mineral weathering reactions on the chemical composition of soil water,Springs, and ground water,Catoctin Mountains,Maryland

During 1983 and 1984, wet precipitation was primarily a solution of dilute sulphuric acid, whereas calcium and bicarbonate were the major ions in springs and ground water in two small watersheds with a deciduous forest cover in central Maryland. Dominant ions in soil water were calcium, magnesium, and sulphate. The relative importance of mineral weathering reactions on the chemical composition of these subsurface waters was compared to the contribution from wet precipitation, biological processes, and road deicing salts. Mineral reaction models, developed from geochemical mass-balance relationships, involved reactions of primary and secondary minerals in metabasalt and metarhyolite with hydrogen ion. Geochemical weathering reactions account for the majority of total ion equivalents in soil water (46 per cent), springs (51 per cent), and ground water (68 to 77 per cent). The net contribution of total ion equivalents from biological processes was 20 and 16 per cent for soil water and springs, respectively, but less than 10 per cent for ground water. The contribution of total ion equivalents from deicing salts (10 to 20 per cent) was related to proximity to roads. Strong acids in precipitation contributed 44 per cent of the total amount of hydrogen ions involved in mineral-weathering reactions for ground water in contact with metarhyolite compared to 25 per cent for ground water in contact with metabasalt, a less resistant rock type to weathering.     

Weathering,erosion and sediment composition in a high‐gradient river,Calabria, Italy

Source rock lithology and immediate modifying processes, such as chemical weathering and mechanical erosion, are primary controls on fluvial sediment supply. Sand composition and Chemical Index of Alteration (CIA) of parent rocks, soil and fluvial sand of the Savuto River watershed, Calabria (Italy), were used to evaluate the modifications of source rocks through different sections of the basin, characterized by different geomorphic processes, in a sub‐humid Mediterranean climate. The headwaters, with gentle topography, produce a coarse‐grained sediment load derived from deeply weathered gneiss, having sand of quartzofeldspathic composition, compositionally very different from in situ degraded bedrock. Maximum estimated CIA values suggest that source rock has been affected significantly by weathering, and it testifies to a climatic threshold on the destruction of the bedrock. The mid‐course has steeper slopes and a deeply incised valley; bedrock consists of mica‐schist and phyllite with a very thin regolith, which provides large cobble to very coarse sand sediments to the main channel. Slope instability, with an areal incidence of over 40 per cent, largely supplies detritus to the main channel. Sand‐sized detritus of soil and fluvial sand is lithic. Estimated CIA value testifies to a significant weathering of the bedrock too, even if in this part of the drainage basin steeper slopes allow erosion to exceed chemical weathering. The lower course has a braided pattern and sediment load is coarse to medium–fine grained. The river cuts across Palaeozoic crystalline rocks and Miocene siliciclastic deposits. Sand‐sized detritus, contributed from these rocks and homogenized by transport processes, has been found in the quartzolithic distal samples. Field and laboratory evidence indicates that landscape development was the result of extensive weathering during the last postglacial temperature maximum in the headwaters, and of mass‐failure and fluvial erosional processes in the mid‐ and low course. Copyright © 2000 John Wiley & Sons, Ltd.     

Tafoni on coastal slopes,South Devon,U.K.

Cavernous weathering (tafoni development) occurs on coastal slopes in greenschist bedrock at elevations up to 40 m above sea level. The freshly weathered surfaces of the cavern interiors are irregular in morphology, discordant to major rock structure, formed by substantially weakened rock and associated with granular weathering debris. The weathering debris contains soluble elements in proportions similar to those present in seawater, and the penetration of elements associated with sea salts into the weathering surface to estimated depths of at least 0·1–0·2 m is indicated by the presence of chlorine. Scanning electron microscopy and microprobe analyses suggest that rock breakdown occurs principally through limited chemical weathering at grain boundaries. The mechanism for the emplacement of marine salts within sheltered rock surfaces in the tafoni is postulated to be a combination of dry deposition under turbulent atmospheric conditions and wetting by coastal fog.     

A new method for determining weathering rates in weathering pits

Determining the rates of rock weathering is difficult because, firstly, the weathering rate of rocks is usually so slow that it is difficult to measure; secondly, it is also difficult to determine the start time and duration of weathering. The Shanxi River Valley in Fujian, China dried up after a reservoir was built upstream in 1959, and became a stone quarry site. Quarrying ceased in 1977, so a large amount of quarry wastes with artificially excavated surfaces were left in the valley. The concave-upward curved rocky surface, broken by manual excavation, easily contains rainwater in its central part, which was easily weathered into a more concave surface. Plaster mould casting was performed in situ on such a concave surface of an excavated stone rock in the valley and scanned with a high-precision 3D scanner to obtain 3D data of the concave-upward rock surface and its more concave middle part, which was considered as an initial weathering pit. The 3D model provided an in-depth understanding of the initial formation process of weathering pits, indicating that: (1) the average weathering rate of a weathering pit is 10.8 ± 0.49 cm ka⁻¹; (2) weathering pits are generally formed by standing water in depressions on a flat near-horizontal rock surface due to weathering actions involving water; (3) the deepening rate of a weathering pit is about four times greater than that of the surrounding area; (4) the growth of a weathering pit can begin in some small concavities on the flat rock surface without pre-existing depressions and gradually expands; (5) a weathering pit is generally wider than deep or with a flat bottom due to expansion with a lateral weathering rate that is greater than that of the vertical, and the lamination of the host rock is not necessary for the formation of flat-floored weathering pits. © 2020 John Wiley & Sons, Ltd.     

Measurement and calibration of weathering using the schmidt hammer,on wave washed moraines on the upper norrland coast,Sweden

The Schmidt hammer has for some years been used to measure the hardness of different rock surfaces and to date relatively boulders in moraine deposits. In this paper applications on isostatically raised boulder-beaches and rocky shores are described. The research area is the northern Swedish Bothnian coast where present isostatic uplift is between 0.8-1.0 cm year^?1. Elevations above sea-level can be converted to a timescale. Rebound values (R) of the Schmidt hammer are correlated with the altitude and the degree of rock weathering can be estimated for each site. Eight sites with boulder-beaches and nine sites with rocky shores have been analysed. For boulder-beaches correlation-coefficients of 0.82-0.97 for weathering values (R) and the elevations above sea-level were obtained. For the rocky shores these values were calculated to 0.75-0.97. This method has applications in both geomorphology and archaeology. For example, a deep layer of weathered dolerite in the Nordingrå region, which previously has been regarded as a post-Weichselian formation, can be shown to be of pre-Weichselian origin. Several archaeological applications are also mentioned in the paper.     

Origin and development of tafoni in Tunnel Spring Tuff,Crystal Peak,Utah, USA

Bedding‐parallel tafoni are well developed over much of the surface of the Tunnel Spring Tuff (Oligocene) exposed in 300‐m‐high Crystal Peak, an inselberg. The Tunnel Spring Tuff is a crudely stratified, non‐welded rhyolite ash‐flow tuff with > 30 per cent porosity. Clasts of Palaeozoic dolomite, limestone and quartzite make up 10 per cent of the tuff. The tafoni are remarkable because of their size (up to 20 m wide but rarely wider than 4 m), shape of the openings (spherical, arch‐like or crescent‐shaped) and abundance (up to 50 per cent of an outcrop face). They are actively forming today. Calcite is abundant (10 to 40 per cent by weight) in tafoni as an efflorescence in spalling flakes of tuff on their roofs and walls. Halite and gypsum generally make up less than 0·01 per cent of the efflorescence. The absence of corroded quartz and feldspar grains in spall fragments indicates that chemical weathering is unimportant in development of the tafoni. Calcite, aragonite, halite and gypsum dust from modern salt pans less than 20 km from Crystal Peak are potential sources of salt in the tuff, but the prevailing winds are in the wrong direction for significant amounts of these evaporite minerals to reach the inselberg. Calcite is the only evaporite mineral present in the tafoni in more than trace amounts, and this mineral is readily available within the tuff itself as a result of rock weathering. We propose that meteoric water containing carbonic acid infiltrates the tuff, dissolves carbonate clasts, and migrates to the steep flanks (>20°) of the peak through abundant megapores and micropores. There it evaporates and precipitates calcite. Crystallization pressure spalls off grains and sheets as the physical manifestation of salt weathering. The quasi‐uniform spacing of tafoni suggests that a self‐organization process is active in the water flow. Copyright © 2000 John Wiley & Sons, Ltd.     

Limestone solution rates and processes in the Waitomo District,New Zealand

Karst solution processes are investigated on Oligocene limestones in the Waitomo district, west central North Island, New Zealand. Estimates of the inputs, throughputs and outputs of water and dissolved calcium and magnesium in two drainage basins were used to establish the rate of limestone solution by autogenic waters. The best estimate for solution loss from the basins during the study year is 69 m³/km². The potential measurement errors inherent in each parameter used in the erosion rate computations were assessed and the probable maximum and minimum erosion rates were estimated to be 88 and 61 m³/km². In both basins approximately 67 per cent of the annual solute load is transported by flows greater than the mean annual discharge, over 15 per cent being transported by flood flows that are exceeded only 5 per cent of the time. Almost half of the annual load is transported during the three winter months (June-August), but no one month accounts for more than 18 per cent or less than 2.7 per cent of the annual total. Approximately 37 per cent of solution takes place within the soil profile, and most of the remainder is concentrated in 5–10 m of weathered bedrock (the subcutaneous zone) beneath this. Thus, it is likely that at least 85 per cent of the total solutional erosion contributes to the surface lowering of soil and bedrock.     

Geophysical constraints on deep weathering and water storage potential in the Southern Sierra Critical Zone Observatory

The conversion of bedrock to regolith marks the inception of critical zone processes, but the factors that regulate it remain poorly understood. Although the thickness and degree of weathering of regolith are widely thought to be important regulators of the development of regolith and its water‐storage potential, the functional relationships between regolith properties and the processes that generate it remain poorly documented. This is due in part to the fact that regolith is difficult to characterize by direct observations over the broad scales needed for process‐based understanding of the critical zone. Here we use seismic refraction and resistivity imaging techniques to estimate variations in regolith thickness and porosity across a forested slope and swampy meadow in the Southern Sierra Critical Zone Observatory (SSCZO). Inferred seismic velocities and electrical resistivities image a weathering zone ranging in thickness from 10 to 35 m (average = 23 m) along one intensively studied transect. The inferred weathering zone consists of roughly equal thicknesses of saprolite (P‐velocity < 2 km s^?1) and moderately weathered bedrock (P‐velocity = 2–4 km s^?1). A minimum‐porosity model assuming dry pore space shows porosities as high as 50% near the surface, decreasing to near zero at the base of weathered rock. Physical properties of saprolite samples from hand augering and push cores are consistent with our rock physics model when variations in pore saturation are taken into account. Our results indicate that saprolite is a crucial reservoir of water, potentially storing an average of 3 m³ m^?2 of water along a forested slope in the headwaters of the SSCZO. When coupled with published erosion rates from cosmogenic nuclides, our geophysical estimates of weathering zone thickness imply regolith residence times on the order of 10⁵ years. Thus, soils at the surface today may integrate weathering over glacial–interglacial fluctuations in climate. Copyright © 2013 John Wiley & Sons, Ltd.     

The effect of rock moisture on Schmidt hammer rebound: tests on rock samples from Marion Island and South Africa

In an assessment of the influence of internal rock moisture content on Schmidt hammer readings, rebound (R) values are found to decrease with increasing moisture content. For samples of basalt, sandstone and dolerite the maximum decrease in R‐values is found between oven dry values and saturated rock rebound values, the magnitude of which varies from 2 to 10 points on the R‐scale. A quartzite block has the greatest decline of 6 points at 60 per cent saturation. For certain rock types under differing site‐to‐site field moisture conditions the moisture effect can be a significant factor in the interpretation of the relative state of weathering from rebound values. Copyright © 2002 John Wiley & Sons, Ltd.     

Impact of textural patterns on modeled rock weathering rates and size distribution of weathered grains

Rock texture has a critical influence on the way rocks weather. The most important textural factors affecting weathering are grain size and the presence of cracks and stylolites. These discontinuities operate as planes of mechanical weakness at which chemical weathering is enhanced. However, it is unclear how different rock textures impact weathering rates and the size of weathered grains. Here, we use a numerical model to simulate weathering of rocks possessing grain boundaries, cracks, and stylolites. We ran simulations with either synthetic or natural patterns of discontinuities. We found that for all patterns, weathering rates increase with discontinuity density. When the density was <~25%, the weathering rate of synthetic patterns followed the order: grid > honeycomb > Voronoi > brick wall. For higher values, all weathering rates were similar. We also found that weathering rates decreased as the tortuosity of the pattern increased. Moreover, we show that textural patterns strongly impact the size distributions of detached grains. Rocks with an initial monomodal grain size distribution produce weathered fragments that are normally distributed. In contrast, rocks with an initial log-normal size distribution produce weathered grains that are log-normally distributed. For the natural patterns, weathering produced lower modality distributions.     

The critical role of climate and saprolite weathering in landscape evolution

Landscapes evolve in response to external forces, such as tectonics and climate, that influence surface processes of erosion and weathering. Internal feedbacks between erosion and weathering also play an integral role in regulating the landscapes response. Our understanding of these internal and external feedbacks is limited to a handful of field‐based studies, only a few of which have explicitly examined saprolite weathering. Here, we report rates of erosion and weathering in saprolite and soil to quantify how climate influences denudation, by focusing on an elevation transect in the western Sierra Nevada Mountains, California. We use an adapted mass balance approach and couple soil‐production rates from the cosmogenic radionuclide (CRN) ¹⁰Be with zirconium concentrations in rock, saprolite and soil. Our approach includes deep saprolite weathering and suggests that previous studies may have underestimated denudation rates across similar landscapes. Along the studied climate gradient, chemical weathering rates peak at middle elevations (1200–2000 m), averaging 112·3 ± 9·7 t km^–2 y^–1 compared to high and low elevation sites (46·8 ± 5·2 t km^?2 y^?1). Measured weathering rates follow similar patterns with climate as those of predicted silica fluxes, modeled using an Arrhenius temperature relationship and a linear relationship between flux and precipitation. Furthermore, chemical weathering and erosion are tightly correlated across our sites, and physical erosion rates increase with both saprolite weathering rates and intensity. Unexpectedly, saprolite and soil weathering intensities are inversely related, such that more weathered saprolites are overlain by weakly weathered soils. These data quantify exciting links between climate, weathering and erosion, and together suggest that climate controls chemical weathering via temperature and moisture control on chemical reaction rates. Our results also suggest that saprolite weathering reduces bedrock coherence, leading to faster rates of soil transport that, in turn, decrease material residence times in the soil column and limit soil weathering. Copyright © 2009 John Wiley & Sons, Ltd.     

Modeling past and future alpine permafrost distribution in the Colorado Front Range

Rock glaciers, a feature associated with at least discontinuous permafrost, provide important topoclimatic information. Active and inactive rock glaciers can be used to model current permafrost distribution. Relict rock glacier locations provide paleoclimatic information to infer past conditions. Future warmer climates could cause permafrost zones to shrink and initiate slope instability hazards such as debris flows or rockslides, thus modeling change remains imperative. This research examines potential past and future permafrost distribution in the Colorado Front Range by calibrating an existing permafrost model using a standard adiabatic rate for mountains (0·5 °C per 100 m) for a 4 °C range of cooler and warmer temperatures. According to the model, permafrost currently covers about 12 per cent (326·1 km²) of the entire study area (2721·5 km²). In a 4 °C cooler climate 73·7 per cent (2004·4 km²) of the study area could be covered by permafrost, whereas in a 4°C warmer climate almost no permafrost would be found. Permafrost would be reduced severely by 93·9 per cent (a loss of 306·2 km²) in a 2·0 °C warmer climate; however, permafrost will likely respond slowly to change. Relict rock glacier distribution indicates that mean annual air temperature (MAAT) was once at least some 3·0 to 4·0 °C cooler during the Pleistocene, with permafrost extending some 600–700 m lower than today. The model is effective at identifying temperature sensitive areas for future monitoring; however, other feedback mechanisms such as precipitation are neglected. Copyright © 2005 John Wiley & Sons, Ltd.     

Strong variation in weathering of layered rock maintains hillslope‐scale strength under high precipitation

The evolution of volcanic landscapes and their landslide potential are both dependent upon the weathering of layered volcanic rock sequences. We characterize critical zone structure using shallow seismic V_p and V_s profiles and vertical exposures of rock across a basaltic climosequence on Kohala peninsula, Hawai’i, and exploit the dramatic gradient in mean annual precipitation (MAP) across the peninsula as a proxy for weathering intensity. Seismic velocity increases rapidly with depth and the velocity–depth gradient is uniform across three sites with 500–600 mm/yr MAP, where the transition to unaltered bedrock occurs at a depth of 4 to 10 m. In contrast, velocity increases with depth less rapidly at wetter sites, but this gradient remains constant across increasing MAP from 1000 to 3000 mm/yr and the transition to unaltered bedrock is near the maximum depth of investigation (15–25 m). In detail, the profiles of seismic velocity and of weathering at wet sites are nowhere monotonic functions of depth. The uniform average velocity gradient and the greater depths of low velocities may be explained by the averaging of velocities over intercalated highly weathered sites with less weathered layers at sites where MAP > 1000 mm/yr. Hence, the main effect of climate is not the progressive deepening of a near‐surface altered layer, but rather the rapid weathering of high permeability zones within rock subjected to precipitation greater than ~1000 mm/yr. Although weathering suggests mechanical weakening, the nearly horizontal orientation of alternating weathered and unweathered horizons with respect to topography also plays a role in the slope stability of these heterogeneous rock masses. We speculate that where steep, rapidly evolving hillslopes exist, the sub‐horizontal orientation of weak/strong horizons allows such sites to remain nearly as strong as their less weathered counterparts at drier sites, as is exemplified by the 50°–60° slopes maintained in the amphitheater canyons on the northwest flank of the island. Copyright © 2017 John Wiley & Sons, Ltd.     

Weathering and erosion of fractured bedrock systems

We explore the contribution of fractures (joints) in controlling the rate of weathering advance for a low‐porosity rock by using methods of homogenization to create averaged weathering equations. The rate of advance of the weathering front can be expressed as the same rate observed in non‐fractured media (or in an individual block) divided by the volume fraction of non‐fractured blocks in the fractured parent material. In the model, the parent has fractures that are filled with a more porous material that contains only inert or completely weathered material. The low‐porosity rock weathers by reaction‐transport processes. As observed in field systems, the model shows that the weathering advance rate is greater for the fractured as compared to the analogous non‐fractured system because the volume fraction of blocks is < 1. The increase in advance rate is attributed both to the increase in weathered material that accompanies higher fracture density, and to the increase in exposure of surface of low‐porosity rock to reaction‐transport. For constant fracture aperture, the weathering advance rate increases when the fracture spacing decreases. Equations describing weathering advance rate are summarized in the ‘List of selected equations’. If erosion is imposed at a constant rate, the weathering systems with fracture‐bounded bedrock blocks attain a steady state. In the erosional transport‐limited regime, bedrock blocks no longer emerge at the air‐regolith boundary because they weather away. In the weathering‐limited (or kinetic) regime, blocks of various size become exhumed at the surface and the average size of these exposed blocks increases with the erosion rate. For convex hillslopes, the block size exposed at the surface increases downslope. This model can explain observations of exhumed rocks weathering in the Luquillo mountains of Puerto Rico. Published 2017. This article is a U.S. Government work and is in the public domain in the USA     

A new technique for non‐destructive field measurement of rock‐surface strength: an application of the Equotip hardness tester to weathering studies

Tafone‐like depressions have developed on the Aoshima sandstone blocks used for a masonry bridge pier in the coastal spray zone. A thin layer of partial granular disintegration was found on the surface in depressions. To evaluate quantitatively the strength of the thin weathered layer, the hardness was measured at the surface of the sandstone blocks using both an Equotip hardness tester and an L‐type Schmidt hammer. Comparison of the two testing results indicates that the Equotip hardness value is more sensitive in evaluating the strength of a thin layer of weathered surface rock than the Schmidt hardness value. By applying two methods, i.e. both the repeated impact method and the single impact method, the Equotip tester can evaluate the strengths of fresh internal and weathered surficial portions of rocks having a thin weathering layer. Comparison of the two strengths enables evaluation of strength reduction due to weathering. Copyright © 2007 John Wiley & Sons, Ltd.     

Stratigraphy,geochemistry, and thermoluminescence ages of lower Mississippi Valley loess

Four periods of loess deposition in the Lower Mississippi Valley can be identified on the basis of geochemical and mineralogical criteria, radiocarbon dating, and thermoluminescence dating. These are designated Loess Units 1,2,3, and 4 in order of increasing age. Carbonate-rich Unit 1 loess comprises more than 70 per cent of the thickness of the loess profiles. ¹⁴C and TL dates indicate this loess was deposited between 9 000 and 20 000 years ago. A maximum sedimentation rate of 2.17 mm yr^?1 has been recorded near Vicksburg just after the last Laurentide glacial maximum, between 17 190 and 15 580 years ago. The Unit 2 loess, which is thin and partly decalcified, was deposited slowly between about 25 000 and 20 000 years ago. The Unit 3 and Unit 4 loess formations, which are both highly weathered, have yielded TL ages of 76 000–85 000 years and 119 000- > 132 000 years, suggesting they were deposited during the Altonian Substage of the early Wisconsinan and the Illinoian glacial stage respectively. The four loess units are stratigraphically equivalent to the Peoria, Farmdale, Roxana, and Loveland loess formations previously recognized in Illinois. The source of dust in both areas was glacial outwash in the Mississippi Valley. During interglacials and interstadials, when the supply of glacial debris was reduced and the Mississippi River changed from a braided to a meandering regime, dust sedimentation in southern Mississippi virtually ceased, allowing weathering and pedogenesis to proceed.     

Coeval biochemical and biophysical weathering processes on Quaternary sandstone terraces south of Rabat (Temara), northwest Morocco

Despite numerous investigations on substrate‐inhabiting microflora, especially lichens, very little is known about the colonization of coastal escarpments by lithobiontic micro‐organisms, inland of a retreating coastline in Africa. Reported herein are the results of a combined field observation and microscopy study focusing on the connection between microrelief of the substrate, colonies of lithobiontic micro‐organisms (in particular the lichen Xanthoria parietina) and microstructures of putative bacterial origin. The occurrence of weathering pits in which the early stages of the biotic development occurs, and the subsequent disintegration of the rock indicate that lichens, mosses and fungi act synergistically by alternating chemical and mechanical weathering. Penetration of grains by expansion and contraction of the hyphae depletes the rock matrix and contributes to the mechanical breakdown of the rock. Calcite rhombs on the weathered surfaces of the calcite‐cemented sandstones are severely etched with well‐developed rhomb‐shaped etch pits (‘spiky calcite’), holes, or has one or more of the faces removed, and their cores exposed and leached. Nanofilaments (c. 100–700 nm) and ‘nanomicrobial’ fruiting bodies (c. 250 nm) emanating from micropores appear to be common on affected crystalline structures. Weddellite present immediately below the thallus is a strong indicator of biomineralization. Quartz responds differently to chemical weathering by producing peeling structures and microbrecciation features. The dissolution of these crystals appears to be a surface reaction‐controlled process mediated by microbial microfilaments and nanofilaments. A model is proposed, firstly indicating early‐stage biochemical weathering, followed by biophysical weathering. Disintegration of the rock outcrops in due to a complex interplay of several events, probably beginning at the nanoscale with penetration of sites on crystal faces. Copyright © 2006 John Wiley & Sons, Ltd.     

Rock fragment distributions and regolith evolution in the Ouachita Mountains,Arkansas, USA

Rock fragments in the regolith are a persistent property that reflects the combined influences of geologic controls, erosion, deposition, bioturbation, and weathering. The distribution of rock fragments in regoliths of the Ouachita Mountains, Arkansas, shows that sandstone fragments are common in all layers, even if sandstone is absent in parent material. Shale and sandstone fragments are produced at the bedrock weathering front, but the shale weathers rapidly and intact fragments are rare in the solum. Sandstone is weathered from ridgetop outcrops and transported downslope. Some of these fragments are moved downward, by faunalturbation and by transport into pits associated with rotting tree stumps. Upward movement by treethrow is common, resulting in a net concentration of rocks near the surface. However, the highest fragment concentrations are in the lower regolith, indicating active production at the weathering front. The regolith is a dynamic feature, reflecting the influences of vertical and horizontal processes, of active weathering at the bedrock interface, and of surficial sediment movements. The role of trees in redistributing rock fragments suggests that significant regolith mixing occurs over time scales associated with forest vegetation communities, and that forest soils have likely been extensively mixed within Holocene and historic time. Copyright © 2005 John Wiley & Sons, Ltd.     

Oxygen and carbon isotope evidence for seawater-hydrothermal alteration of the Macquarie Island ophiolite

Rocks of the Miocene Macquarie Island ophiolite, south of New Zealand, have oxygen and carbon isotopic compositions comparable to those of seafloor rocks. Basalt glass and weathered basalts have δ¹⁸O values at 5.8–6.0‰ and 7.9–9.5‰, respectively, similar to drilled seafloor rocks including samples from the Leg 29 DSDP holes near Macquarie Island. Compared to the basalt glass, the greenschist to amphibolite facies metaintrusives are depleted in¹⁸O (δ¹⁸O=3.2–5.9‰) similar to dredged seafloor samples, whereas the metabasalts are enriched (δ¹⁸O=7.1–9.7‰). Although the gabbros are only slightly altered in thin-section they have exchanged oxygen with a hydrothermal fluid to a depth of at least 4.5 km. There is an approximate balance between¹⁸O depletion and enrichment in the exposed ophiolite section. The carbon isotopic composition of calcite in the weathered basalts (δ¹³C=1.0–2.0‰) is similar to those of drilled basalts, but the metamorphosed rocks have low δ¹³C values (?14.6 to 0.9‰).These data are compatible with two seawater circulation regimes. In the upper regime, basalts were weathered by cold seawater in a circulation system with high water/rock ratios (?1.0). Based on calcite compositions weathering temperatures were less than 20°C and the carbon was derived from a predominantly inorganic marine source. As previously suggested for the Samail ophiolite, it is postulated that the lower hydrothermal regime consisted of two coupled parts. At the deeper levels, seawater circulating at low water/rock ratios (0.2–0.3) and high temperatures (300–600°C) gave rise to¹⁸O-depleted gabbro and sheeted dikes via open system exchange reactions. During reaction the seawater underwent a shift in oxygen isotopic composition (δ¹⁸O=1.0–5.0‰) and subsequently caused¹⁸O enrichment of the overlying metabasalts. In the shallower part of the hydrothermal regime the metabasalts were altered at relatively high water/rock ratios (1.0–10.0) and temperatures in the range 200–300°C. The relatively low water/rock ratios in the hydrothermal regime are supported by the low δ¹³C values of calcite, interpreted as evidence of juvenile carbon in contrast to the inorganic marine carbon found in the weathered basalts.     

A Morphological Study of Greenschist Weathering on Dated Coastal Structures,South Devon,UK

Three dated structures up to 450 years in age display the effects of coastal weathering of the greenschist of which they are constructed. A variety of weathering forms is present. The various topographic surfaces of the structures create variation in weathering environments and consequent weathering processes and rates. Weathering is enhanced by direct exposure to salt-bearing spray and by humid conditions, and apparently limited by direct exposure to solar radiation. The maximum rates of weathering on the three surfaces approximate to 0·6 mm a⁻¹ over this period, consistent with measured contemporary weathering rates for a natural surface formed by this rock type in a nearby coastal location. © 1997 by John Wiley & Sons, Ltd.