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1.
Kusuma G. Rao 《Journal of Earth System Science》1996,105(3):273-287
Using MONTBLEX-90 mean velocity data, roughness lengths and drag coefficients are estimated at Jodhpur and Kharagpur. At Jodhpur,
since the surface is not uniform the roughness length is estimated separately in three different subsectors within the range
of prevailing wind directions and averages to 1.23 cm in the sector between 200° and 230° which is relatively flat with no
obstacles on the ground. At Kharagpur, where the terrain is more nearly homogeneous, the average value (for all prevailing
wind directions) is 1.94 cm.
The drag coefficient CD at Jodhpur shows variation both with the roughness subsector and with wind speed, the average over all directions increasing
rapidly as themean wind speed Ū10 at 10m height drops according to the power lawC
D
= 0.05 Ū
10
t-1.09
in trie range 0.5 < Ū10 < 7 m s−1. At Kharagpur, the drag coefficient is smaller than at Jodhpur by nearly 50% for the same range of wind speeds (> 3 ms−1). 相似文献
2.
Parameterization of sensible heat and momentum fluxes as inferred from an analysis of tower observations archived during MONTBLEX-90
at Jodhpur is proposed, both in terms of standard exchange coefficientsC
H
andC
D
respectively and also according to free convection scaling. Both coefficients increase rapidly at low winds (the latter more
strongly) and with increasing instability. All the sensible heat flux data at Jodhpur (wind speed at 10 m Ū10 < 8 ms−1) also obey free convection scaling, with the flux proportional to the ‘4/3’ power of an appropriate temperature difference
such as that between 1 and 30 m. Furthermore, for Ū10 < 4 ms−1 the momentum flux displays a linear dependence on wind speed. 相似文献
3.
A. Suryachandra Rao Y. Sadhuram V. V. Gopala Krishna 《Journal of Earth System Science》1995,104(4):607-611
We estimate, from the moisture budget the bulk aerodynamic coefficient for latent heat flux (C
e) during the monsoon season over the central Arabian Sea. The average value ofC
eunder active monsoon conditions was found to be 2.25 × 10−3 which is nearly 60% higher than those previously used. 相似文献
4.
Benthic nutrient fluxes in the intertidal flat within the Changjiang (Yangtze River) Estuary 总被引:1,自引:0,他引:1
GAO Lei LI Daoji WANG Yanming YU Lihua KONG Dingjiang LI Mei LI Yun and FANG Tao State Key Laboratory of Marine Geology Tongji University Shanghai China State Key Laboratory of Estuarine Coastal Research East China Normal University Shanghai China 《中国地球化学学报》2008,27(1):58-71
In an annual cycle from March 2005 to February 2006, benthic nutrient fluxes were measured monthly in the Dongtan intertidal flat within the Changjiang (Yangtze River) Estuary. Except for NH4^+, there always showed high fluxes from overlying water into sediment for other four nutrients. Sediments in the high and middle marshes, covered with halophyte and consisting of macrofauna, demonstrated more capabilities of assimilating nutrients from overlying water than the low marsh. Sampling seasons and nutrient concentrations in the overlying water could both exert significant effects on these fluxes. Additionally, according to the model provided by previous study, denitrification rates, that utilizing NO3- transported from overlying water (Dw) in Dongtan sediments, were estimated to be from -16 to 193 μmol·h^-1·m^-2 with an average value of 63 μmol·h^-1·m^-2 (n=18). These estimated values are still underestimates of the in-situ rates owing to the lack of consideration of DN, i.e., denitrification supported by the local NO3^- production via nitrification. 相似文献
5.
A numerical simulation of residual circulation in Tampa Bay. Part I: Low-frequency temporal variations 总被引:1,自引:0,他引:1
Steven D. Meyers Mark E. Luther Monica Wilson Heather Havens Amanda Linville Kristin Sopkin 《Estuaries and Coasts》2007,30(4):679-697
The residual (time-average) salinity and circulation in a numerical ocean model of the Tampa Bay estuary are shown to experience
significant temporal variation under realistic forcing conditions. A version of the Estuarine Coastal Ocean Model developed
for Tampa Bay with 70 by 100 horizontal grid points and 11 sigma levels is examined for the years 2001–2003. Model output
variables are averaged over the entire time of the simulation to generate long-term residual fields. The residual axial current
is found to be dominated by the buoyancy-driven baroclinic circulation with an outflow (southwestward) at the surface and
to the sides of the shipping channel, and an inflow (northeastward) usually occurring subsurface within or above the shipping
channel. Averages over 30 d are used to examine variations in the residual fields. During the simulation the average surface
salinity near the head of Tampa Bay varies with the freshwater inflow, from 12‰ to 33%. At the bay mouth salinity varies from
30%. to 36%.. A localized measure of the baroclinic circulation in the shipping channel indicates the residual circulation
can vary strongly, attaining a magnitude triple the long-term mean value. The baroclinic circulation can be disrupted, going
to near zero or even reversing, when the buoyancy-driven flow is weak and the surface winds are to the northeast. Three time
periods, representing different environmental conditions, are chosen to examine these results in detail. A scaling argument
indicates the relative strength of buoyancy versus wind as ΔρgH2(LC
Dω2)−1, where δρ is head-to-mouth density difference across the bay,g is gravitational acceleration,H is depth,L is bay length,C
D is the surface wind drag coefficient, andw is wind speed. Tampa Bay is usually in the buoyancy dominated regime. The importance of winds in the weak-buoyancy case is
demonstrated in an additional simulation without wind stress. 相似文献
6.
Time variation of surface fluxes of heat, moisture and momentum over a sea station (20°N 89°E) in the north Bay of Bengal has been computed by profile method for the period 18th–25th August 1990 using meteorological data of MONTBLEX-90 from ORVSagarkanya. The fluxes showed synoptic and diurnal variations which are marked during depression (20th–21st August) compared to their variation prior to and after this period. Variations of heat and water vapour fluxes were in phase. Night time fluxes are relatively high compared to day time. Average momentum transfer during depression was two to three times large. Variations in Bowen ratio were relatively large during day time. During depression, it varied between 0·2 in day time and about 0·3 at night and in the undisturbed period between ?0·1 and 0·2 during day time and 0·2 and 0·25 at night. The study shows that the assumptionC D=CH=CE of the exchange coefficients normally used in estimating the fluxes by the bulk aerodynamic method is not appropriate becauseC H/CD≈2,C E/CD≈1·5 andC H/CE≈1·4. 相似文献
7.
We present JHKLM photometry obtained in 1984–2009 for the RCB stars UV Cas and SU Tau. No major fadings characteristic of RCB stars were detected
during the observations of UV Cas, while two events of this kind occurred for SU Tau. The observed flux and color-index variations
can be explained with a changing dust concentration in the line of sight, and possibly variations of the stellar temperature.
We use the measured fluxes, supplemented with observations in the intermediate IR, to compute spherically symmetric dust-shell
models for the stars. The mass-loss rate is estimated to be 1.7 × 10−6
M
⊙ yr−1 for UV Cas and 4.1 × 10−6
M
⊙ yr−1 for SU Tau. 相似文献
8.
Maik Pertermann Alan G. Whittington Anne M. Hofmeister Frank J. Spera John Zayak 《Contributions to Mineralogy and Petrology》2008,155(6):689-702
Thermal diffusivity (D) was measured using laser-flash analysis from oriented single-crystal low-sanidine (K0.92Na0.08Al0.99Fe3+
0.005Si2.95O8), and three glasses near KAlSi3O8. Viscosity measurements of the three supercooled liquids, in the range 106.8 to 1012.3 Pa s, confirm near-Arrhenian behavior, varying subtly with composition. For crystal and glass, D decreases with T, approaching a constant near 1,000 K: D
sat ∼ 0.65 ± 0.3 mm2 s−1 for bulk crystal and ∼0.53 ± 0.03 mm2 s−1 for the glass. A rapid decrease near 1,400 K is consistent with crossing the glass transition. Melt behavior is approximated
by D = 0.475 ± 0.01 mm2 s−1. Thermal conductivity (k
lat) of glass, calculated using previous heat capacity (C
P) and new density data, increases with T because C
P strongly increases with T. For melt, k
lat reaches a plateau near 1.45 W m−1 K−1, and is always below k
lat of the crystal. Melting of potassium feldspars impedes heat transport, providing positive thermal feedback that may promote
further melting in continental crust. 相似文献
9.
As a part of the MONTBLEX-90 observational programme, Kytoon and Doppler sodar observations were taken at Kharagpur. These
data are analysed to study the turbulent characteristics of the atmospheric boundary layer in terms of stability, temperature
structure function (C
T
2
) and velocity structure function (C
v
2
).C
T
2
follows aZ
−4/3 law on most of the days, whereas the variation ofC
V
2
is not systematic.C
V
2
andC
T
2
values are found to vary between 10−5−10−1 m4/3s−2 and 10−5−10−2°C2 m−2/3 respectively. 相似文献
10.
Values of the complete adiabatic elastic tensor for single-crystal chrome-diopside (a monoclinic pyroxene mineral) are presented from 298 to 1,300 K. The data were obtained using resonant ultrasound spectroscopy (RUS). They are the first published results for the temperature T dependences of the 13 individual elastic constants C
ij
of any clinopyroxene mineral. Each C
ij
is appropriately described by a linear function in T throughout the range of T. Values for each (∂C
ij
/∂T)
P
in GPa K−1 are as follows: C
11, −0.0291; C
22, −0.0248; C
33, −0.0179; C
44, −0.0103; C
55, −0.0077; C
66, −0.0152; C
12, −0.0119; C
13, −0.0064; C
23, 0.0000; C
15, 0.0025; C
25, 0.0022; C
35, −0.0046; and C
46, 0.0026. Values of (∂M/∂T)
P
in GPa K−1, where M represents an isotropic bulk property calculated from the C
ij
data, are as follows: adiabatic bulk modulus K
S
, −0.0123; isothermal bulk modulus K
T
, −0.0178; and shear modulus G, −0.00998. Some diopside derivatives, notably (∂K
S
/∂T)
P
, (∂K
T
/∂T)
P
, and (∂V
P
/∂T)
P
, where V
P
is the compressional wave velocity, have smaller magnitudes than all other minerals of importance in Earth’s mantle, thus, confirming predictions from systematics studies. We find several dimensionless quantities for this monoclinic mineral have normal values compared to other mantle minerals. Further, αK
T
(α is the volume coefficient of thermal expansion) for diopside is approximately independent of both T and volume V at elevated temperature, so its equation of state is accurately expressed in simplified form. 相似文献
11.
Zhang Bangtong 《中国地球化学学报》1986,5(3):226-233
It is estimated that the uranium-oxygen bond dissociation energy (D
U
4
−0
+
=1465.38kJ/mol) is higher than silicon-and aluminium-oxygen bond dissociation energies (DSi4
−0
+
=1264.41 kJ/mol and DAl3
−0
+
=1105.32 kJ/mol). During the process of magmatic differentiation with increasing degree of polymerization for silicon-oxygen
complex ion, uranium in granitic melts tends to combine with oxygen to form the coordination polyhedron [UO
x
2x−n
] and to occur in the form of nuclei and crystals of uraninite, as has been demonstrated by the induced fission-track study
of quartz syenite from Huangmeijian. 相似文献
12.
Cation tracer diffusion coefficients, DMe *, for Me=Fe, Mn, Co and Ti, were measured using radioactive isotopes in the spinel solid solution (Ti x Fe 1−x )3−δO4 as a function of the oxygen activity. Experiments were performed at different cationic compositions (x=0, 0.1, 0.2 and 0.3) at 1100, 1200, 1300 and 1400 °C. The oxygen activity dependence of all data for DMe * at constant temperature and cationic composition can be described by equations of the type DMe *=D∘ Me[V]. CV·a O2 2/3+DMe[I] ∘·a O2 −2/3·DMe[V] ∘ and DMe[I] ∘ are constants and CV is a factor of the order of unity which decreases with increasing δ. All log DMe * vs. loga O2 curves obtained for different values of x and for different temperatures go through a minimum due to a change in the type of point defects dominating the cation diffusion with oxygen activity. Cation vacancies prevail for the cation diffusion at high oxygen activities while cation interstitials become dominant at low oxygen activities. At constant values of x, DMe[V] ∘ decreases with increasing temperature while DMe[I] ∘ increases. 相似文献
13.
P. Comodi G. D. Gatta P. F. Zanazzi D. Levy W. Crichton 《Physics and Chemistry of Minerals》2002,29(8):538-544
Powder diffraction measurements at simultaneous high pressure and temperature on samples of 2M1 polytype of muscovite (Ms) and paragonite (Pg) were performed at the beamline ID30 of ESRF (Grenoble), using the Paris-Edinburgh
cell. The bulk moduli of Ms, calculated from the least-squares fitting of V–P data on each isotherm using a second-order Birch–Murnaghan EoS, were: 57.0(6), 55.1(7), 51.1(7) and 48.9(5) GPa on the isotherms
at 298, 573, 723 and 873 K, respectively. The value of (∂K
T
/∂T)
was −0.0146(2) GPa K−1. The thermal expansion coefficient α varied from 35.7(3) × 10−6 K−1 at P ambient to 20.1(3) × 10−6 K−1 at P = 4 GPa [(∂α/∂P)
T
= −3.9(1) × 10−6 GPa−1 K−1]. The corresponding values for Pg on the isotherms at 298, 723 and 823 K were: bulk moduli 59.9(5), 55.7(6) and 53.8(7) GPa,
(∂K
T
/∂T)
−0.0109(1) GPa K−1. The thermal expansion coefficient α varied from 44.1(2) × 10−6 K−1 at P ambient to 32.5(2) × 10−6 K−1 at P = 4 GPa [(∂α/∂P)
T
= −2.9(1) × 10−6 GPa−1 K−1]. Thermoelastic coefficients showed that Pg is stiffer than Ms; Ms softens more rapidly than Pg upon heating; thermal expansion
is greater and its variation with pressure is smaller in Pg than in Ms.
Received: 28 January 2002 / Accepted: 5 April 2002 相似文献
14.
Ana Carolina Ruiz-Fernández José Luis Marrugo-Negrete Roberth Paternina-Uribe Libia Hascibe Pérez-Bernal 《Estuaries and Coasts》2011,34(6):1117-1128
With the aim of evaluating temporal changes in sedimentation and organic carbon (Corg) supplied over the last ~100 years, a sediment core was collected at Soledad Lagoon, a costal ecosystem surrounded by mangroves,
located in the Cispatá Estuary (Caribbean coast of Colombia). The core sediments were characterized by low concentrations
of calcium carbonate (0.2–2.9%), organic matter (3–8%), total nitrogen (0.11–0.38%), and total phosphorus (0.19–0.65 mg g−1). Fe and Al concentrations ranged from 4% to 5%, and Mn from 356 to 1,047 μg g−1. The 210Pb-derived sediment and mass accumulation rates were 1.54 ± 0.18 mm year−1 and 0.08 ± 0.01 g cm−2 year−1, respectively. The sediment core did not provide evidence of human impact, such as enhancement of primary production or nutrient
enrichment, which may result from recent land uses changes or climate change. The Corg fluxes estimated for Soledad Lagoon core lay in the higher side of carbon fluxes to coastal ecosystems (314–409 g m−2 year−1) and the relatively high Corg preservation observed (~45%) indicate that these lagoon sediments has been a net and efficient sink of Corg during the last century, which corroborate the importance of mangrove areas as important sites for carbon burial and therefore,
long-term sequestration of Corg. 相似文献
15.
D. G. Isaak J. D. Carnes O. L. Anderson H. Cynn E. Hake 《Physics and Chemistry of Minerals》1998,26(1):31-43
The ambient pressure elastic properties of single-crystal TiO2 rutile are reported from room temperature (RT) to 1800 K, extending by more than 1200 oK the maximum temperature for which rutile elasticity data are available. The magnitudes
of the temperature derivatives decrease with increasing temperature for five of the six adiabatic elastic moduli (C
ij
). At RT, we find (units, GPa): C
11=268(1); C
33=484(2); C
44=123.8(2); C
66=190.2(5); C
23=147(1); and C
12=175(1). The temperature derivatives (units, GPa K−1) at RT are: (∂C
11/∂T)
P
=−0.042(5); (∂C
33/∂T)
P
=−0.087(6); (∂C
44/∂T)
P
=−0.0187(2); (∂C
66/∂T)
P
=−0.067(2); (∂C
23/∂T)
P
=−0.025; and (∂C
12/∂T)
P
−0.048(5). The values for K
S
(adiabatic bulk modulus) and μ (isotropic shear modulus) and their temperature derivatives are K
S
=212(1) GPa; μ=113(1) GPa; (∂K
S
/∂T)
P
=−0.040(4) GPa K−1; and (∂μ/∂T)
P
=−0.018(1) GPa K−1. We calculate several dimensionless parameters over a large temperature range using our new data. The unusually high values
for the Anderson-Gròneisen parameters at room temperature decrease with increasing temperature. At high T, however, these parameters are still well above those for most other oxides. We also find that for TiO2, anharmonicity, as evidenced by a non-zero value of [∂ln (K
T
)/∂lnV]
T
, is insignificant at high T, implying that for the TiO2 analogue of stishovite, thermal pressure is independent of volume (or pressure). Systematic relations indicate that ∂2
K
S
/∂T∂P is as high as 7×10−4 K−1 for rutile, whereas ∂2μ/∂T∂P is an order of magnitude less.
Received: 19 September 1997 / Revised, accepted: 27 February 1998 相似文献
16.
Time-series Mark VII sediment trap was deployed at 72°58.55′E, 62°28.63°S (north of the Prydz Bay, Antarctica) during the
cruise of CHINARE-15 in cooperation with University of Marine of America. Seasonal variability of deep ocean particle fluxes
and biogenic components were investigated in order to reveal the fluxes and biogeochemistry of sinking particles in the deep
ocean. The results show that the total mass flux of sinking particles at a water depth of 1000 m ranges from 13.00 to 334.59
mg⋅d−1⋅m−2). A marked seasonal variability exists in the fluxes of all particle components reflecting the seasonal changes in upper
water productivity. Biogenic material was a significant component and biogenic silica represented more than 80% of the biogenic
matter, reflecting a diatom dominated system, but a lithogenic fraction is always present. The fact that the POC dominated
over particulate inorganic carbon (as CaCO3) and Cinorg/Corg was always greater than 1, indicate a net removal of CO2 from surface water by biological activity.
__________
Translated from Acta Oceanologica Sinica, 2006, 5: 49–55 [译自:海洋 学报] 相似文献
17.
Cyril Aubaud Marc M. Hirschmann Anthony C. Withers Richard L. Hervig 《Contributions to Mineralogy and Petrology》2008,156(5):607-625
To understand partitioning of hydrogen between hydrous basaltic and andesitic liquids and coexisting clinopyroxene and garnet,
experiments using a mid-ocean ridge basalt (MORB) + 6 wt.% H2O were conducted at 3 GPa and 1,150–1,325°C. These included both isothermal and controlled cooling rate crystallization experiments,
as crystals from the former were too small for ion microprobe (SIMS) analyses. Three runs at lower bulk water content are
also reported. H2O was measured in minerals by SIMS and in glasses by SIMS, Fourier Transform infrared spectroscopy (FTIR), and from oxide
totals of electron microprobe (EMP) analyses. At 3 GPa, the liquidus for MORB with 6 wt.% H2O is between 1,300 and 1,325°C. In the temperature interval investigated, the melt proportion varies from 100 to 45% and the
modes of garnet and clinopyroxene are nearly equal. Liquid composition varies from basaltic to andesitic. The crystallization
experiments starting from above the liquidus failed to nucleate garnets, but those starting from below the liquidus crystallized
both garnet and clinopyroxene. SIMS analyses of glasses with >7 wt.% H2O yield spuriously low concentrations, perhaps owing to hydrogen degassing in the ultra-high vacuum of the ion microprobe
sample chamber. FTIR and EMP analyses show that the glasses have 3.4 to 11.9 wt.% water, whilst SIMS analyses indicate that
clinopyroxenes have 1,340–2,330 ppm and garnets have 98–209 ppm H2O. D
H
cpx−gt is 11 ± 3, D
H
cpx−melt is 0.023 ± 0.005 and D
H
gt−melt is 0.0018 ± 0.0006. Most garnet/melt pairs have low values of D
H
gt−melt, but D
H
gt−melt increases with TiO2 in the garnet. As also found by previous studies, values of D
H
cpx−melt increase with Al2O3 of the crystal. For garnet pyroxenite, estimated values of D
H
pyroxenite−melt decrease from 0.015 at 2.5 GPa to 0.0089 at 5 GPa. Hydration will increase the depth interval between pyroxenite and peridotite
solidi for mantle upwelling beneath ridges or oceanic islands. This is partly because the greater pyroxene/olivine ratio in
pyroxenite will tend to enhance the H2O concentration of pyroxenite, assuming that neighboring pyroxenite and peridotite bodies have similar H2O in their pyroxenes.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
18.
Sensitivity of high-resolution tropical cyclone intensity forecasts to surface flux parameterization
Chi-Sann Liou 《Natural Hazards》2007,41(3):387-399
Surface flux parameterization schemes used in current dynamic models are primarily based upon measurements at low and moderate
wind speeds. Recent studies show that these parameterization schemes may be incorrect at high wind speeds (e.g., tropical
cyclone forecasts). Five high-resolution numerical model experiments are designed to assess the sensitivity of tropical cyclone
intensity forecasts to changes in the surface flux parameterization. The sensitivity experiments are conducted by running
48 h forecasts of the Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS) for six selected tropical cyclones with
individual modifications to surface flux calculation that include: (1) limiting the surface stress for wind speeds greater
than 33 m s−1, or 64 knots (kt); (2) computing the stress at the top of the model bottom grid layer (MBGL) by averaging results from surface
layer similarity and turbulence mixing parameterization for wind speeds greater than 33 m s−1; (3) increasing the roughness lengths for heat and moisture transfer by a factor of ten; (4) setting the roughness lengths
for heat and moisture transfer to 1/10 of the momentum roughness length; and (5) cooling the sea surface temperature (SST)
by a prescribed rate at high winds. Averaged responses for the six storms to these sensitivity tests show that: (i) the limit
on surface stress at high winds significantly increases the cyclone intensity in 48 h forecasts; (ii) the averaged surface
layer stress at high winds increases the cyclone intensity but to a much lesser degree than limiting the surface stress; (iii)
large increases in the roughness lengths for heat and moisture transfer are needed to significantly impact the intensity forecast;
(iv) the different roughness length formula for surface transfer coefficients notably increases C
h/C
d ratio from 0.59 to 0.79 for 25 m s−1 and 0.41 to 0.75 for 50 m s−1 that significantly increases the predicted cyclone intensity; and (v) cooling of the SST by −5.8°C in 48 h reduces the maximum
surface wind speed by −32 kt, or 16.5 m s−1, at 48 h forecast. These results suggest that a surface flux parameterization scheme suitable for tropical cyclone intensity
forecast must correctly model the leveling-off character of surface stress and C
h/C
d ratio at high winds. All modifications to surface flux calculation have little influence on 48 h track forecasts, even though
they may significantly impact the intensity forecasts.
相似文献
Chi-Sann LiouEmail: |
19.
An experimental study has been carried out to determine the partition coefficients of tungsten between aqueous fluids and
granitic melts at 800 °C and 1.5 kb with natural granite as the starting material. The effects of the solutions on the partition
coefficients of tungsten show a sequence of P > CO
3
2−
> B > H2O. The effects are limited (generallyK
D
< 0.3) and the tungsten shows a preferential trend toward the melt over the aqueous fluid. The value ofK
D
increases with increasing concentration of phosphorus; theK
D
increases first and then reduces with the concentration of CO
3
2−
when temperature decreases, theK
D
between the solution of CO
3
2−
and the silicate melt increases, and that between the solution of B4O
7
2−
and the silicate melt decreases. The partition coefficients of phosphorus and sodium between fluids and silicate melts have
been calculated from the concentrations of the elements in the melts. TheK
D
value for phosphorus is 0.38 and that for sodium is 0.56. Evidence shows that the elements tend to become richer and richer
in the melts. 相似文献
20.
Dirk Frei Axel Liebscher Gerhard Franz Bernd Wunder Stephan Klemme Jon Blundy 《Contributions to Mineralogy and Petrology》2009,157(4):473-490
We determined experimentally the Nernst distribution coefficient between orthopyroxene and anhydrous silicate melt for trace elements i in the system Na2O–CaO–MgO–Al2O3–SiO2 (NCMAS) along the dry model lherzolite solidus from 1.1 GPa/1,230°C up to 3.2 GPa/1,535°C in a piston cylinder apparatus.
Major and trace element composition of melt and orthopyroxene were determined with a combination of electron microprobe and
ion probe analyses. We provide partitioning data for trace elements Li, Be, B, K, Sc, Ti, V, Cr, Co, Ni, Rb, Sr, Y, Zr, Nb,
Cs, Ba, La, Ce, Sm, Nd, Yb, Lu, Hf, Ta, Pb, U, and Th. The melts were chosen to be boninitic at 1.1 and 2.0 GPa, picritic
at 2.3 GPa and komatiitic at 2.7 and 3.2 GPa. Orthopyroxene is Tschermakitic with 8 mol% Mg-Tschermaks MgAl[AlSiO6] at 1.1 GPa while at higher pressure it has 18–20 mol%. The rare earth elements show a continuous, significant increase in
compatibility with decreasing ionic radius from D
Laopx−melt ∼ 0.0008 to D
Luopx−melt ∼ 0.15. For the high-field-strength elements compatibility increases from D
Thopx−melt ∼ 0.001 through D
Nbopx−melt ∼ 0.0015, D
Uopx−melt ∼ 0.002, D
Taopx−melt ∼ 0.005, D
Zropx−melt ∼ 0.02 and D
Hfopx−melt ∼ 0.04 to D
Tiopx−melt ∼ 0.14. From mathematical and graphical fits we determined best-fit values for D
0M1, D
0M2, r
0M1, r
0M2, E
0M1, and E
0M2 for the two different M sites in orthopyroxene according to the lattice strain model and calculated the intracrystalline
distribution between M1 and M2. Our data indicate extreme intracrystalline fractionation for most elements in orthopyroxene;
for the divalent cations D
i
M2−M1 varies by three orders of magnitude between D
CoM2−M1 = 0.00098–0.00919 and D
BaM2−M1 = 2.3–28. Trivalent cations Al and Cr almost exclusively substitute on M1 while the other trivalent cations substitute on
M2; D
LaM2−M1 reaches extreme values between 6.5 × 107 and 1.4 × 1016. Tetravalent cations Ti, Hf, and Zr almost exclusively substitute on M1 while U and Th exclusively substitute on M2. Our
new comprehensive data set can be used for polybaric-polythermal melting models along the Earth’s mantle solidus.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献