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1.
More than 150 landslides originated in the eastern part of the Czech Republic (region of the Flysch Outer Western Carpathians—hereinafter,
OWC) due to soil saturation caused by antecedent precipitation and long lasting and intensive rainfalls on 16–18 May 2010
(>300 mm as measured by some stations). As a consequence, a multitude of small failures originated 88% of which was smaller
than 10 4 m 2. Most landslides are characterised as shallow (<10 m) or middle–deep (10–30 m) incipient (rather short travel) landslides,
debris slides and soil slips spatially clustered to a geological domain underlain by rather weak thin-bedded flysch and unconsolidated
Quaternary deposits. An exception to this is represented by a kilometre-long rockslide (∼2–3 mil m 3) affecting tectonically weakened and weathered claystone/mudstone-dominated flysch on the southern slope of Mt. Girová (the
Beskydy Mountains). The rockslide is one of the largest long runout landslides in the territory of the Czech Republic activated
over the past few decades as it reaches the dimensions of the largest documented Holocene long runout landslides in the Czech
part of the OWC. A majority of the May 2010 landslide events developed inside older (Holocene or historic) landslide terrains,
which points to their spatial persistency and recurrent nature. In spite of the fact that the May 2010 landslide event was
not as destructive as some previous landslide activisation in the OWC region (e.g. July 1997 event), it left many slope failures
at the initial stage of their potential future reactivation. 相似文献
2.
Detailed 10Be and 14C dating and supporting pollen analysis of Alpine Lateglacial glacial and landslide deposits in the Hohen Tauern Mountains (Austria) constrain a sequence‐based stratigraphy comprising a major landslide (13.0±1.1 ka) overlain by till and termino‐lateral moraines of an advancing (12.6±1.0 ka) and retreating (11.3±0.8 ka) glacier in turn overlain by a minor landslide (10.8±1.1 ka). These results define glacier activity during the Younger Dryas age Egesen stadial bracketed by landslide activities during the Bølling‐Allerød interstadial and the Preboreal. In contrast to recent studies on Holocene glaciation in the Alps, no traces of any Holocene glacier advance bigger than during the Little Ice Age are documented. Furthermore, this study demonstrates the advantages of using an allostratigraphical approach based on unconformity‐bounded sedimentary units as a tool for glacial stratigraphy in formerly glaciated mountain regions, rather than a stratigraphy based on either isolated morphological features or lithostratigraphical characteristics. 相似文献
3.
The Zymoetz River landslide is a recent example of an extremely mobile type of landslide known as a rock slide–debris flow. It began as a failure of 900,000 m 3 of bedrock, which mobilized an additional 500,000 m 3 of surficial material in its path, transforming into a large debris flow that traveled over 4 km from its source. Seasonal snow and meltwater in the proximal part of the path were important factors. A recently developed dynamic model that accounts for material entrainment, DAN3D, was used to back-analyze this event. The two distinct phases of motion were modeled using different basal rheologies: a frictional model in the proximal path and a Voellmy model in the distal path, following the initiation of significant entrainment. Very good agreement between the observed and simulated results was achieved, suggesting that entrainment capabilities are essential for the successful simulation of this type of landslide. 相似文献
4.
The basin-like setting of stiff bedrock combined with pre-existing landslide masses can contribute to seismic amplifications
in a wide frequency range (0–10 Hz) and induce a self-excitation process responsible for earthquake-triggered landsliding.
Here, the self-excitation process is proposed to justify the far-field seismic trigger of the Cerda landslide (Sicily, Italy)
which was reactivated by the 6th September 2002 Palermo earthquake ( M
s = 5.4), about 50 km far from the epicentre. The landslide caused damage to farm houses, roads and aqueducts, close to the
village of Cerda, and involved about 40 × 10 6 m 3 of clay shales; the first ground cracks due to the landslide movement formed about 30 min after the main shock. A stress–strain
dynamic numerical modelling, performed by FDM code FLAC 5.0, supports the notion that the combination of local geological
setting and earthquake frequency content played a fundamental role in the landslide reactivation. Since accelerometric records
of the triggering event are not available, dynamic equivalent inputs have been used for the numerical modelling. These inputs
can be regarded as representative for the local ground shaking, having a PGA value up to 0.2 m/s 2, which is the maximum expected in 475 years, according to the Italian seismic hazard maps. A 2D numerical modelling of the
seismic wave propagation in the Cerda landslide area was also performed; it pointed out amplification effects due to both
the structural setting of the stiff bedrock (at about 1 Hz) and the pre-existing landslide mass (in the range 3–6 Hz). The
frequency peaks of the resulting amplification functions ( A( f)) fit well the H/ V spectral ratios from ambient noise and the H/ H spectral ratios to a reference station from earthquake records, obtained by in situ velocimetric measurements. Moreover,
the Fourier spectra of earthquake accelerometric records, whose source and magnitude are consistent with the triggering event,
show a main peak at about 1 Hz. This frequency value well fits the one amplified by the geological setting of the bedrock
in correspondence with the landslide area, which is constituted of marly limestones and characterised by a basin-like geometry. 相似文献
5.
Green Lake Landslide is an ancient giant rock slide in gneiss and granodiorite located in the deeply glaciated Fiordland region of New Zealand. The landslide covers an area of 45 km 2 and has a volume of about 27 km 3. It is believed to be New Zealand's largest landslide, and possibly the largest landslide of its type on Earth. It is one of 39 known very large (10 6–10 7 m 3) and giant (≥10 8 m 3) postglacial landslides in Fiordland discussed in the paper. Green Lake Landslide resulted in the collapse of a 9 km segment of the southern Hunter Mountains. Slide debris moved up to 2.5 km laterally and 700 m vertically, and formed a landslide dam about 800 m high, impounding a lake about 11 km long that was eventually infilled with sediments. Geomorphic evidence supported by radiocarbon dating indicates that Green Lake Landslide probably occurred 12 000–13 000 years ago, near the end of the last (Otira) glaciation. The landslide is described, and its geomorphic significance, age, failure mechanism, cause, and relevance in the region are discussed, in relation to other large landslides and recent earthquake-induced landslides in Fiordland. The slope failure occurred on a low-angle fault zone undercut by glacial erosion, and was probably triggered by strong shaking (MM IX–X) associated with a large (≥ M 7.5–8) earthquake, on the Alpine Fault c. 80 km to the northwest. Geology was a major factor that controlled the style and size of Green Lake landslide, and in that respect it is significantly different from most other gigantic landslides. Future large earthquakes on the Alpine Fault in Fiordland are likely to trigger more very large and giant landslides across the region, causing ground damage and devastation on a scale that has not occurred during the last 160 years, with potentially disastrous effects on towns, tourist centres, roads, and infrastructure. The probability of such an event occurring within the next 50 years may be as high as 45%. 相似文献
6.
Strong earthquakes are among the prime triggering factors of landslides. The 2008 Wenchuan earthquake ( M
w = 7.9) triggered tens of thousands of landslides. Among them, the Daguangbao landslide is the largest one, which covered
an area of 7.8 km 2 with a maximum width of 2.2 km and an estimated volume of 7.5 × 10 8 m 3. The landslide is located on the hanging wall of the seismogenic fault, the Yingxiu–Beichuan fault in Anxian town, Sichuan
Province. The sliding mass travelled about 4.5 km and blocked the Huangdongzi valley, forming a landslide dam nearly 600 m
high. Compared to other coseismic landslides in the study area, the Daguangbao landslide attained phenomenal kinetic energy,
intense cracking, and deformation, exposing a 1-km long head scarp in the rear of the landslide. Based on the field investigation,
we conclude that the occurrence of the landslide is controlled mainly by the seismic, terrain, and geological factors. The
special location of the landslide and the possible topographic amplification of ground motions due to the terrain features
governed the landslide failure. The effects of earthquakes on the stability of slopes were considered in two aspects: First,
the ground shaking may reduce the frictional strength of the substrate by shattering of rock mass. Second, the seismic acceleration
may result in short-lived and episodic changes of the normal (tensile) and shear stresses in the hillshopes during earthquakes.
According to the failure mechanism, the dynamic process of the landslide might contain four stages: (a) the cracking of rock
mass in the rear of the slope mainly due to the tensile stress generated by the ground shaking; (b) the shattering of the
substrate due to the ground shaking, which reduced the frictional strength of the substrate; (c) the shearing failure of the
toe of the landslide due to the large shear stress caused by the landslide gravity; and (d) the deposition stage. 相似文献
7.
In the framework of a regional landslide susceptibility study in southern Sicily, a test has been carried out in the Tumarrano
river basin (about 80 km 2) aimed at characterizing its landslide susceptibility conditions by exporting a “source model”, defined and trained inside
a limited (about 20 km 2) representative sector (the “source area”). Also, the possibility of exploiting Google Earth ™ software and photo-images databank to produce the landslide archives has been checked. The susceptibility model was defined,
according to a multivariate geostatistic approach based on the conditional analysis, using unique condition units (UCUs),
which were obtained by combining four selected controlling factors: outcropping lithology, steepness, plan curvature and topographic
wetness index. The prediction skill of the exported model, trained with 206 landslides, is compared with the one estimated
for the whole studied area, by using a complete landslide archive (703 landslides), to see to what extent the largest time/money
costs needed are accounted for. The investigated area stretches in the fore-deep sector of southern Sicily, where clayey rocks,
mainly referring to the Numidian Flysch and the Terravecchia Formations, largely crop out. The results of the study confirm
both the exploitability of Google Earth ™ to produce landslide archive and possibility to adopt in assessing the landslide susceptibility for large basin, a strategy
based on the exportation of models trained in limited representative sectors. 相似文献
8.
Since the impoundment of the Three Gorges Reservoir in June 2003, a number of new landslides have occurred and existing landslides
have been made worse. The 1,260 × 10 4 m 3 Baishuihe landslide, located at 56 km west of the Three Gorges Dam, began to deform more noticeably after the first impoundment
in early July 2003. The sliding of the two blocks comprising the landslide, one an active block and the other a relatively
stable block, became apparent after approximately 5 years of monitoring. Field recordings show that the landslide displacement
is affected by the combined effects of the rainfall and water level in the reservoir. These effects have been investigated
in the present paper, including the deformation characteristics (movement pattern, direction, displacement and velocity) earmarking
the temporal evolution of the active block. Based on a practical creep model of a large rock slide, alert velocity thresholds
for pre-alert, alert and emergency phases have been computed corresponding to the imminence of failure. The alert velocity
thresholds are being proposed to be included as a part of an early-warning system of an emergency plan drawn up to minimize
the adverse impact in the event of landslide failure. The emergency plan is intended to be implemented as a risk management
tool by the relevant authorities of the Three Gorges Reservoir in the near future. 相似文献
9.
This paper presents a study on an ancient river-damming landslide in the SE Tibet Plateau, China, with a focus on time-dependent gravitational creep leading to slope failure associated with progressive fragmentation during motion. Field investigation shows that the landslide, with an estimated volume of 4.9?×?107 m3, is a translational toe buckling slide. Outcrops of landslide deposits, buckling, toe shear, residual landslide dam, and lacustrine sediments are distributed at the slope base. The landslide deposits formed a landslide dam over 60 m high and at one time blocked the Jinsha River. Optically stimulated luminescence dating for the lacustrine sediments indicates that the landslide occurred at least 2,600 years ago. To investigate the progressive evolution and failure behavior of the landslide, numerical simulations using the distinct element method are conducted. The results show that the evolution of the landslide could be divided into three stages: a time-dependent gravitational creep process, rapid failure, and granular flow deposition. It probably began as a long-term gravitationally induced buckling of amphibolite rock slabs along a weak interlayer composed of mica schist which was followed by progressive fragmentation during flow-like motion, evolving into a flow-like movement, which deposited sediments in the river valley. According to numerical modeling results, the rapid failure stage lasted 35 s from the onset of sudden failure to final deposition, with an estimated maximum movement rate of 26.8 m/s. The simulated topography is close to the post-landslide topography. Based on field investigation and numerical simulation, it can be found that the mica schist interlayer and bedding planes are responsible for the slope instability, while strong toe erosion caused by the Jinsha River caused the layered rock mass to buckle intensively. Rainfall or an earthquake cannot be ruled out as a potential trigger of the landslide, considering the climate condition and the seismic activity on centennial to millennial timescales in the study area. 相似文献
11.
Land subsidence is a serious problem in Taiwan’s Yunlin area due to groundwater overpumping. There are safety risks in the
high-speed railway structures in the areas of Siluo, Huwei, Tuku, and Yuanchang towns that run from north to south in the
Yunlin area. Therefore, it is important to increase the groundwater recharge and to remedy the land subsidence in this area.
The purpose of this study is to use the stream-flow estimation model (SF) and the groundwater flow numerical software MODFLOW
(MF) to estimate the stream infiltration with consideration to the variation of the river water level in the Hsinhuwei River.
The Ferris analytical model (FA) and MF are used to estimate the increased stream infiltration after the water level of the
river rises. The hydraulic parameters required for each model are obtained from field observations and laboratory experiments.
The results indicate that the assessment of the stream infiltration obtained through the SF and MF models are 264.2 × 10 4 and 170.9 × 10 4 m 3/year, respectively. When the river water level increases by about 2.5 m, the annual stream infiltration obtained through
the FA and MF models significantly increases by 31.6 × 10 4 and 26.4 × 10 4 m 3/year, respectively. Taken together, the stream storages estimated using these two models indicate that an increasing efficiency
of groundwater recharge is within the range of 10.0–18.5%. 相似文献
12.
A good understanding of seismic giant landslides could provide favourable guidance for seismic stability evaluation of nearby slopes. Here, an excellent example of a catastrophic seismic landslide named the Mogangling giant landslide (MGL), located upstream along the Dadu River and triggered by the 1786 Moxi M 7.75 earthquake, is analysed for its deposit characteristics, failure mechanism and dammed lake. The MGL, with a volume of approximately 4500?×?104 m3, 450 m long and 1000 m wide, blocked the Dadu River completely and caused over 100 000 deaths when the landslide dam broke. The MGL occurred on the upper part of a narrow granite ridge; a potentially unstable wedge-shaped rock mass was separated from the remaining massif by unloading fissures and an active fault (Detuo fault) that just crossed the slope foot. The Moxi earthquake coupled with strong site amplification triggered the MGL, which blocked the Dadu River; the elevation of the dam crest was approximately 130 m higher than the present river level. The dammed lake had a volume of approximately 9.504?×?108 m3, an area of 19.91 km2 and a length of approximately 31 km; the peak flow of the outburst flood was larger than 7100 m3/s. After hundreds of years of concave bank erosion, the deposit is divided into the right bank deposit (main deposit) and left bank deposit (residual deposit). 相似文献
13.
At Lake Coleridge, Canterbury, New Zealand, at least three rock avalanches have been released from a single source area during
the Holocene. The first of these was of 10 7 m 3 volume and dates to about 9,750 BP, and two with volumes 5 × 10 5 and 4 × 10 4 m 3 occurred about 700 BP. All three crossed the course of the Ryton River; the latter two were emplaced within the part of the
first that had subsequently been eroded by the Ryton River. All three were most likely triggered by, or related to, seismicity.
The first rock avalanche formed a long-lived landslide dam, and no evidence remains to indicate whether its eventual failure
was catastrophic. The second formed a correspondingly smaller dam, but there is no evidence that its lake was long-lived;
however, a set of anomalously steep outwash terraces downstream of the landslide deposits show that it failed catastrophically.
A camping ground is sited about 1 km downstream of the landslide deposits, and proposals to develop it further risk potentially
severe hazards from future rock avalanche activity at the site. 相似文献
14.
Limbe town and surrounding areas, on the SE foot slopes of the active Mt Cameroon Volcano, have experienced numerous small-scale
shallow landslides within the last 20 years. These resulted in the loss of ~30 lives and significant damage to farmland and
properties. Landslides and their scars are identified in the field, and their geometry systematically measured to construct
a landslide inventory map for the study area. Specific landslides are investigated in detail to identify site-specific controlling
and triggering factors. This is to constrain key input parameters and their variability for subsequent susceptibility and
risk modeling, for immediate local and regional applications in land-use planning. It will also enable a rapid exploration
of remediation strategies that are currently lacking in the SW and NW regions of Cameroon. Typical slides within the study
area are small-scale, shallow, translational earth, and debris slides though some rotational earth slides were also documented.
The depletion zones have mean widths of 22 m ± 16.7 m and lengths of 25 ± 23 standard deviation. Estimated aerial extents
of landslide scars and volume of generated debris range from 10 1 to 10 4 m 2 and 2 to 5 × 10 4 m 3, respectively. A key finding is that most slope instabilities within the study area are associated with and appear to be
exacerbated by man-made factors such as excavation, anarchical construction, and deforestation of steep slopes. High intensity
rainfall notably during localized storms is the principal triggering factor identified so far. The findings from this case
study have relevance to understanding some key aspects of locally devastating slope instabilities that commonly occur on intensely
weathered steep terrains across subtropical Africa and in the subtropics worldwide and affecting an ever denser and most vulnerable
population. 相似文献
15.
Large-scale ancient landslides of the area of more than 5 km 2 and volume exceeding 200 × 10 6 m 3 are characteristic features of the valleys incised in the northern periphery of the Crimean Mountains (Ukraine). The largely
affected area is located in the outermost cuesta range of the Crimean Mountains which consists of rigid Sarmatian limestones
overlying weak Middle Miocene and Upper Palaeogene deposits. A giant landslide arose in the Alma water gap as a reflection
of several coincident preparatory factors such as suitable bedrock stratification, smectite-rich bedrock exposed to swelling
activity, presence of faults parallel to the valley trend, and river capture event which preceded the landslide event. The
occurrence of such ancient megaslides is particularly interesting in the area which is characterized by low precipitation
(<500 mm/year) and weak contemporary seismicity. It probably reflects a more dynamic environment in humid phases of the Holocene;
however, seismic triggering along the Mesozoic suture zone cannot be rejected. Compressional features such as gravitational
folds in the central and distal parts of the landslide, which probably correlate with the whole landslide genesis or its significant
reactivation, arose, according to the radiocarbon dating, during the Holocene climatic optimum in the Atlantic period. The
slope deformation has been relatively quiescent since that time, except minor historic reactivization which took place in
the frontal part of the landslide. We suppose that the studied landslide could be classified as a transitional type of slope
deformation with some signs of spreading and translational block slides. 相似文献
16.
The Todagin Creek landslide is located at 57.61° N 129.98° W in Northwest British Columbia. A seismic station 90 km north
of the landslide recorded the event at 1643 hours coordinated universal time (UTC; 0943 hours Pacific daylight time (PDT))
on October 3, 2006. The signal verifies the discovery and relative time bounds provided by a hunting party in the valley.
The landslide initiated as a translational rock slide on sedimentary rock dipping down slope at 34° and striking parallel
to the valley. The landslide transformed into a debris avalanche and had a total volume estimated at 4 Mm 3. An elevation drop of 771 m along a planar length of 1,885 m resulted in a travel angle (fahrb?schung) of 21.3°. The narrowest
part of the landslide through the transport zone is 345 m. The widest part of the divergent toe of the landslide reaches a
width of 1,010 m. Landslide debris impounded a lake of approximately 32 ha and destroyed an additional 67 ha of forest. The
impoundment took 7 to 10 days to fill, with muddied waters observed downstream on October 13. No clear linkage exists with
precipitation and temperature records preceding the landslide, but strong diurnal temperature cycles occurred in the days
prior to the event. The Todagin Creek area appears to have an affinity for large landslides with the deposits of three other
landslides >5 Mm 3 observed in the valley. 相似文献
17.
Landslides and rock avalanches triggered by the 2008 Wenchuan Earthquake produced 257 landslide dams, mainly situated along
the eastern boundary of the Qinghai-Tibet Plateau where rivers descend approximately 3,000 m into the Sichuan Basin. The largest
of these dams blocked the Tongkou River (a tributary of the Fujiang River) at Tangjiashan. The blockage, consisting of 2.04 × 10 7 m 3 of landslide debris, impounded a lake with a projected maximum volume of 3.15 × 10 8 m 3, potentially inundating 8.92 km 2 of terrain. Its creation during the rainy season and the possibility of an uncontrolled release posed a serious, impending
threat to at least 1.3 million people downstream that could add substantially to the total of 69,200 individuals directly
killed by the earthquake. Risk assessment of the blockage indicated that it was unlikely to collapse suddenly, and that eventual
overtopping could be mitigated by notching the structure in order to create an engineered breach and achieve safe drainage
of the lake. In addition to the installation of monitoring and warning instrumentation, for emergency planning we estimated
several outburst scenarios equivalent to 20, 25, 33, and 50% of the dam failing suddenly, creating, respectively, 3.35, 3.84,
4.22, and 4.65 km 2 of flooded area, and overbank water depths of 4.6, 5.1, 5.7, and 6.2 m, respectively, in Mianyang, the second largest city
in Sichuan Province, 48 km downstream from the blockage. Based on these scenarios, recommendations and plans for excavating
a sluiceway, draining the lake, and downstream evacuation were proposed and later were implemented successfully, with the
blockage breached by overtopping on June 10, less than a month after dam emplacement. The peak discharge of the release only
slightly exceeded the flood of record at Mianyang City. No lives were lost, and significant property damage was avoided. Post-breaching
evaluation reveals how future similar mitigation can be improved. Although initial breach erosion was slow, later erosion
was judged uncontrollably rapid; increased slope of the engineered channel and adoption of a compound, trapezoid–triangular
cross-section can be considered, as can other measures to control the rate of breach incision. Evacuees from Mianyang City
spent an unnecessarily long time (12 days) in temporary settlements; more precise risk management planning can reduce this
time in the future. 相似文献
18.
Landslides located beside reservoirs tend to be unstable or are characterized by large deformation during the drawdown process.
This has been accepted by many experts. In this paper, we use Qiaotou Landslide, which is located beside the Three Gorges
Reservoir (TGR), as a typical case study to investigate and predict the deformation mechanism during the drawdown process
of TGR in detail. According to field investigation, the landslide mass is mainly composed of thick, loose silt and clay mixed
with fragments of rock. Bedrock is mainly composed of silty sandstone. Field and laboratory tests indicate that the landslide
mass has a high permeability coefficient. If the water level declines fast, intense seepage force may result. Based on these
data, we establish a three-dimensional geological model of Qiaotou Landslide by FLAC 3D and perform a numerical simulation using the saturated–unsaturated fluid–solid coupling theory. For the simulation, we assume
that the drawdown from 175 to 145 m takes place with a speed of 25 cm/day, which is based on the extreme water level regulation
program of TGR. The simulation shows that this causes a significant deformation in the landslide mass and that the maximum
displacement within the landslide is 24.2 cm. During the drawdown process, the maximum displacement zone is shifting from
the upper part of the landslide where bedrock surface is steeper and thickness of loose deposits is less to the middle part
of the landslide where bedrock surface is less steep and thickness of loose deposits is higher. The deformation mechanism
indicates that in the early stage of the drawdown the deformation of the landslide mass is mainly caused by seepage and in
the later stage mainly by consolidation. 相似文献
19.
This work aims to understand the process of potential landslide damming using slope failure mechanism,dam dimension and dam stability evaluation. The Urni landslide, situated on the right bank of the Satluj River, Himachal Pradesh(India) is taken as the case study. The Urni landslide has evolved into a complex landslide in the last two decade(2000-2016) and has dammed the Satluj River partially since year 2013,damaging ~200 m stretch of the National Highway(NH-05). The crown of the landslide exists at an altitude of ~2180-2190 m above msl, close to the Urni village that has a human population of about 500.The high resolution imagery shows ~50 m long landslide scarp and ~100 m long transverse cracks in the detached mass that implies potential for further slope failure movement. Further analysis shows that the landslide has attained an areal increase of 103,900 ± 1142 m^2 during year 2004-2016. About 86% of this areal increase occurred since year 2013. Abrupt increase in the annual mean rainfall is also observed since the year 2013. The extreme rainfall in the June, 2013; 11 June(~100 mm) and 16 June(~115 mm),are considered to be responsible for the slope failure in the Urni landslide that has partially dammed the river. The finite element modelling(FEM) based slope stability analysis revealed the shear strain in the order of 0.0-0.16 with 0.0-0.6 m total displacement in the detachment zone. Further, kinematic analysis indicated planar and wedge failure condition in the jointed rockmass. The debris flow runout simulation of the detached mass in the landslide showed a velocity of ~25 m/s with a flow height of ~15 m while it(debris flow) reaches the valley floor. Finally, it is also estimated that further slope failure may detach as much as 0.80 ±0.32 million m^3 mass that will completely dam the river to a height of 76±30 m above the river bed. 相似文献
20.
Compositional depth profiles in the leached layer of feldspar surfaces are usually interpreted by using analytical solutions
which introduce oversimplifying assumptions. Here we present a general multicomponent interdiffusion numerical model for simulating
cation release from a preferentially leached layer on feldspar surfaces in acid solutions. The numerical model takes into
account interdiffusion, dissolution of the solid phase (represented by a moving boundary problem), and adsorption in the leached
layer. Effective diffusion coefficients of ions vary with concentration along the leached layer. Governing equations of ions
diffusion in the leached layer are solved numerically with a finite element method implemented in a multicomponent reactive
transport code, CORE 3D, previously verified against analytical solutions of compositional depth profiles. The numerical model is tested with published
X-ray photoelectron spectroscopy (XPS) data on early development of compositional profiles of labradorite leached in pH 2
HCl solutions. Model parameters are estimated by fitting depth profiles of Ca and Al measured at 12, 26, 48, 72, and 143 h.
The best fit is achieved with tracer diffusion coefficients of 4 × 10 −18, 8 × 10 −17, 3.4 × 10 −17, and 7 × 10 −18 cm 2/s for H, Na, Ca, and Al, respectively, which fall within the range of values reported in the literature. Our estimate of
the retreat velocity corresponding to the dissolution rate is 3 × 10 −13 cm/s. Results of sensitivity runs show that computed compositional profiles are sensitive to most model parameters. 相似文献
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