北大山镁铁质—超镁铁质岩体地球化学特征及形成构造环境

阿拉善地块南缘是镁铁质—超镁铁质岩体的重要分布区,自北向南可分为北大山岩带、龙首山岩带和北海子岩带。本文主要以北大山岩带为研究对象,通过对野芨里岩体、青疙瘩岩体及鄂博沟岩体的岩石学、岩石地球化学、微量元素、稀土元素等研究,探讨了北大山镁铁质—超镁铁质岩体的成因类型和形成构造环境。3个岩体主量元素特征显示Mg#=76~87,橄榄岩类w(Al2O3)=3.2%~5.2%,但辉长岩、辉绿岩类明显高于该值,说明北大山镁铁质—超镁铁质岩熔融程度整体不高,该区岩体属于镁质超基性岩,并且具有富铁趋势;稀土元素特征显示稀土总量(ΣREE)在5.68×10-6~11.5×10-6之间,野芨里岩体LREE稍富集,而青疙瘩及鄂博沟岩体LREE明显富集;微量元素特征显示北大山镁铁质—超镁铁质岩体的成岩构造环境为板内拉张环境,岩浆在侵位过程中受到上地壳的混染作用,微量元素原始地幔标准化蛛网图显示Ni明显亏损,有利于镍成矿。     

阿拉善地块南缘野芨里镁铁-超镁铁质岩体锆石U-Pb年龄及其地质意义

阿拉善地块南缘北大山地区野芨里镁铁-超镁铁质岩体主要由单辉橄榄岩、二辉橄榄岩、橄榄辉长岩组成。岩体局部发现了硫化物,主要由磁黄铁矿、镍黄铁矿与黄铜矿组成,指示岩浆结晶过程中发生了硫化物不混溶作用。岩石地球化学分析显示野芨里岩体属于铁质超基性岩,富集大离子亲石元素,相对亏损高场强元素,具有明显的Nb,Ta负异常,微量元素比值指示岩浆在上升过程中受到了中上地壳物质混染。橄榄辉长岩中锆石SHRIMP U-Pb年龄为286.6±2.5 Ma,属于早二叠世。结合区域构造演化,认为野芨里岩体形成背景可能与古亚洲洋的闭合或俯冲之后的伸展作用相关。     

东昆仑浪木日镁铁质-超镁铁质岩成因：锆石U-Pb年代学和Sr-Nd-Hf同位素特征

浪木日镁铁质-超镁铁质岩体位于东昆仑造山带东段,临近昆中断裂,主要由橄榄岩、橄榄辉石岩、辉石岩和辉长岩组成,且局部发育星点状和浸染状硫化物矿化。辉石岩和橄榄辉石岩获得的锆石U-Pb年龄分别为(421.2±1.2)Ma和(421.10±0.96)Ma,表明岩体侵位于晚志留世。岩石地球化学特征显,浪木日镁铁质-超镁铁质岩具有较高的Mg^#(Mg^#>80),富集LILE(Rb、Th、U等),亏损HFSE(Nb、Ta、Ti等),轻、重稀土元素分馏程度较强((La/Yb)_N=6.28～50.91,(La/Sm)_N=1.45～4.15,(Gd/Yb)_N=1.43～9.71),具有弱的负Eu异常(δEu=0.226～0.824)。锆石Lu-Hf(ε_Hf(t)=-2.9～-10)和全岩Sr-Nd(ε_Nd(t)=-10.3～-8.9)同位素特征显示,其岩浆源区主要来自富集地幔,与俯冲洋壳脱水交代上覆地幔楔活动有关。综合研究表明,浪木日镁铁质-超镁铁...     

内蒙古阿拉善右旗吊井子一带镁铁质—超镁铁质岩石地球化学特征及成因分析

内蒙古自治区西部阿拉善右旗吊井子一带发育有3处镁铁质—超镁铁质岩体,位于华北板块之巴丹吉林坳陷西缘,其主要岩石类型为角闪石岩及橄榄岩。相对比与北大山镁铁质—超镁铁质岩体,本文研究区内角闪石岩分异明显,具有低钾、高钛、高铝、低磷等特征;大离子亲石元素富集,高场强元素亏损,稀土元素分异不明显,La/Sm、La/Ce、La/Yb较低,为亏损地幔来源的(N-MORB)洋中脊玄武岩的特点;橄榄岩富镁贫铁,具有镁质超基性岩的特点,岩浆未发生明显分异,微量元素中Cu、Ni、Co、Cr、V等地幔来源的元素强烈富集,不相容元素富集,稀土元素分异明显,稀土曲线右倾,具有弱Eu异常,La/Sm、La/Ce、La/Yb值较高,岩浆源于富集地幔物质的部分熔融。两种岩石地球化学成分及特征差异较大,不具备同源性特征。     

新疆北山地区罗东镁铁质-超镁铁质层状岩体岩石成因

罗东镁铁质-超镁铁质岩体位于塔里木板块东北部的新疆北山地区,岩体平面形态为眼球状,出露面积约2.1 km2.由纯橄岩、单辉橄榄岩、斜长二辉橄榄岩、橄榄二辉岩、方辉辉石岩、橄长岩、橄榄辉长岩、辉长岩、苏长辉长岩和淡色辉长岩组成,堆晶结构和堆晶韵律发育,属于层状岩体.岩浆演化过程中主要分离结晶/堆晶相是橄榄石和单斜辉石,此...     

龙首山几个镁铁-超镁铁质岩体比较

文章选择龙首山隆起区金川、塔马子沟、毛草泉、小口子、藏布台几个镁铁-超镁铁质岩体进行地质、地球化学比较研究,发现岩体普遍具有橄榄石堆晶特征,中段金川岩体以二辉橄榄岩为主要特征,外围岩体以单辉橄榄岩为特征.地球化学数据显示,这些镁铁-超镁铁质岩体处于相同的岩石系列,源区具有相似性,岩体含矿差异主要源自岩浆演化.结合地质综合场模型,提出金川外围岩体在龙首山隆起区,沿构造带东西长约80～100km范围存在金川深部岩浆房响应的产物.     

金川超镁铁质岩元素及稀有气体同位素地球化学特征

金川超镁铁质岩是金川铜镍硫化物矿床的赋存岩体．采自金川镍矿Ⅰ矿区露天矿第2期侵入岩体的样品其岩石类型主要为含二辉橄榄岩和二辉橄榄岩，见镍黄铁矿、磁黄铁矿、黄铁矿呈成条带状出现，表明其形成时低氧逸度的成岩环境。运用ICP—MS等离子质谱仪和MM5400稀有气体质谱仪分别对全岩样品的稀土元素、微量元素和包体稀有气体同位素进行测定后得到一些认识：金川超镁铁质岩的微量元素丰度与球粒陨石相比，变化曲线基本呈水平分布，但是地壳中高度亏损Cr，Ni元素含量较高，主要富集于超基性的辉石和橄榄石中，说明其成因类型具有明显的幔源特征。岩石中稀土元素总量较高，为轻稀土富集型．重稀土亏损。其中由深至浅稀土元素对La／Yb，Ce／Yb，La／Sm，(La／Sm)N的比值均基本呈现增大趋势．说明其中稀土元素分馏程度呈增大趋势，轻稀土的分馏尤为明显。超镁铁质岩的^3He／^4He值分布于0．847Ra～1．625Ra之间，虽远低于上地幔的^3He／^4He值．但仍存在地幔初始氦的踪迹。研究结果表明，该岩体在侵入过程中发生了明显的分异作用，并与地壳发生了的混染作用和热液交代作用．进一步证明了该岩体为上地幔局部熔融的超基性岩浆上侵形成的。     

新疆北山二叠纪大型镁铁-超镁铁质岩体的动力学背景及成矿潜力

新疆北山地区聚集着坡北、罗东、红石山、漩涡岭和笔架山等众多的二叠纪大型镁铁-超镁铁质杂岩体,主要由橄榄岩、辉石岩和辉长岩组成,具有堆晶韵律层,其形成年龄(260.7~289 Ma)与塔里木大火成岩省年龄接近。岩体橄榄石Fo值与Ni含量正相关;与原始地幔相比,微量元素富集Rb、Sr和Pb,亏损Nb、Ta、Ti、Zr和Hf;稀土元素具LREE亏损-平坦型球粒陨石标准化配分曲线。岩石PGE含量低、具IPGE亏损型原始地幔标准化配分型式。SrNd同位素位于亏损地幔(DM)与OIB范围之间,Re-Os同位素组成与地幔柱岩浆作用形成的Noril'sk铜镍硫化物矿床和峨眉山溢流玄武岩重叠。模拟计算表明,母岩浆Mg O含量高,岩浆初始液相线温度及结晶温度高,岩浆演化过程中经历了分离结晶作用、地壳混染以及早期的硫化物熔离。由此推断北山大型镁铁-超镁铁杂岩体可能是在后碰撞伸展环境叠加地幔柱作用,诱发软流圈上涌、岩石圈底侵,导致俯冲流体交代的岩石圈地幔在高温条件下高程度部分熔融形成的,具有较大的岩浆矿床成矿潜力。     

塔里木板块东北部坡一镁铁质-超镁铁质层状侵入体岩石成因

坡一侵入体位于塔里木板块东北部坡北岩体内,是该岩体第三阶段岩浆活动形成的十几个小侵入体中的一个,锆石U-Pb年龄为278±2Ma。该侵入体属于以超镁铁质岩石为主的层状岩系,堆晶结构与韵律性堆晶层理非常发育。岩浆分异充分,形成了从纯橄岩到石英闪长岩的多种岩石类型。在超镁铁质岩石中,所有的橄榄石和大部分斜方辉石是堆晶相,少量斜方辉石是填隙相,大部分单斜辉石、褐色普通角闪石和黑云母是填隙相。在镁铁质岩石中,橄榄石和斜方辉石全部是堆晶相,单斜辉石与斜长石既可以是堆晶相,也可以是填隙相;褐色普通角闪石、黑云母和石英均为填隙相。超镁铁质岩石属拉斑玄武岩系列,镁铁质岩石属钙碱性系列。侵入体中大量存在的捕掳体、微量元素地球化学、Nd-Sr同位素组成的EMⅡ型演化趋势,充分证明了同化混染作用伴随岩浆演化过程而逐渐增强,并不断促进了岩浆的分异,而且导致了岩石化学系列的转化。PGE和亲硫元素地球化学以及硫同位素组成证明,硫主要来自于岩浆,硫化物形成于岩浆阶段,岩浆未经历过早期硫化物熔离作用,硫化物熔离起始于橄榄岩相结晶的晚期阶段,并伴随着此后的岩浆演化过程而继续熔离。硫化物熔离是岩浆自身演化和同化混染共同作用的结果。橄榄石Fo分子含量和全岩FeO含量显示,原生岩浆是苦橄质岩浆;源区物质应该是石榴石辉石岩;岩浆生成于地幔柱轴部。在塔里木板块东北部还存在分别来自于软流圈和亏损型大陆岩石圈地幔的二叠纪岩浆岩,它们都应该是塔里木大火成岩省的组成部分。     

新疆哈密白石泉含铜镍镁铁-超镁铁质岩体铂族元素特征

新疆哈密白石泉镁铁-超镁铁质岩体的铂族元素研究表明,岩体的铂族元素总含量较低,原始地幔标准化模式具镁铁质岩石的特征,并具Pt 正异常,且铂族元素的分异主要受结晶分异作用的影响.岩体的Cu/Pd、Se/S、Ti/Pd值表明其发生过硫化物的熔离作用.Pd/Ir、Ni/Cu特征表明了岩体系高镁玄武岩岩浆的产物.铂族元素特征揭示了白石泉岩体硫化物的熔离作用是由原始岩浆结晶分异导致的,岩体的形成是原始岩浆发生橄榄石等的结晶,导致硫化物的熔离作用后,其残余岩浆演化的结果.     

金川超大型Ni-Cu-(PGE)矿床橄榄石微量元素特征及地质意义

我国金川超大型铜镍硫化物矿床是世界上第三大在采岩浆硫化物矿床,Ni开采量仅次于俄罗斯Noril'sk-Talnakh和加拿大Sudbury矿床,其成因研究备受关注。利用激光—等离子体质谱(LA-ICP-MS)原位分析了金川岩体中橄榄石微量元素含量,并探讨了影响元素含量变化的因素,进而阐述成岩及成矿过程。分析结果显示橄榄石中元素Ni,Cr与Fo呈负相关,Mn/Fe与Fo呈正相关,而Mn/Zn,Zn/Fe与Fo无相关性。在原始地幔橄榄石多元素标准化图中,金川Ⅰ号和Ⅱ号岩体橄榄石具相同的配分模式,均显示Cr,V,Ni,Co和Ti的亏损,富集不相容元素Zr,Y,Ti,Sc和Ca的特征。元素变化特征暗示Ⅰ号和Ⅱ号岩体具相同的母岩浆成分;与铬尖晶石的共结使橄榄石亏损Cr,V和Ti元素,而熔离的硫化物及其与橄榄石的相互反应共同影响着橄榄石中Ni和Co元素的含量。Ⅱ号岩体橄榄石较Ⅰ号岩体具较低的Cr和V含量,暗示Ⅱ号岩体母岩浆较Ⅰ号岩体经历了更高程度的演化。橄榄石高的Mn/Zn值(>13)和低的Zn/Fe值(<11)指示金川岩体岩浆可能起源于橄榄岩地幔的部分熔融,而非辉石岩地幔源区。     

Trace Elements in Olivines from the Giant Jinchuan Ni-Cu-(PGE) Deposit,NW China,and Its Geological Implication

The giant Jinchuan magmatic sulfide deposit in China is the third largest mining deposits in the world. Although many research have been done, there still exist some debates in the genesis of deposit. This study using the LA-IC-MS to obtain the trace elements concentrations of the olivine in order to discuss the mechanism of influence the element variability and illustrate the process of magmatism and ore-forming. The analytical results show that Ni, Co correlate negatively with Fo in the olivine, Mn/Fe is positively correlate with Fo, while Mn/Zn and Zn/Fe show no obvious correlation with Fo. The primitive mantle olivine-normalized trace element patterns of the Jinchuan olivine show that Jinchuan Ⅰ, Ⅱ intrusions have the same trace elements characteristics, which display negative Cr, V, Ni, Co and Ti anomalies and enrichment of Zr, Y, Ti, Sc and Ca. The multi-element patterns of the Jinchuan olivine imply same parental magma in the intrusion Ⅰ and Ⅱ. The spinel which cocrystallization with the olivine make it display negative Cr, V and Ti anomalies. The contents of Ni and Co in olivine are influenced by the process of sulfide segregation and the reaction between sulfide and olivine. The lower content of Cr and V in olivine of the intrusion Ⅱ compared with the intrusion Ⅰ imply that the parental magma of the intrusion Ⅱ was more evolved. Higher Mn/Zn (>13) ratios and lower Zn/Fe (<11) ratios indicate that the magma of Jinchuan intrusion likely originate from partial melting of peridotite mantle possibly, instead of pyroxene mantle sources.     

GEOCHEMICAL CHARACTERISTICS OF PLATINUM GROUP ELEMENTS IN JINCHUAN SUPER-LARGE SULFIDE COPPER-NICKEL DEPOSIT, JINCHANG CITY, GANSU PROVINCE, CHINA

The platinum-group element geochemistry of rocks and ores from Jinchuan super-large copper-nickel sulfide deposit is systemically studied in this paper. The Cu/Pd mean ratio of Jinchuan intrusion is lower than that of original mantle magma, which indicates that these ultrabasic rocks were crystallized from magma that lost Pd in the form of melting segregation of sulfides. The PGE of the rocks show trend of partial melting, similar to that of mantle peridotite, which shows that magma formation occurs during rock-forming and ore-forming processes. The chondrite normalized PGE patterns of the rocks and ores are well related to each other, which signifies the signatures of multi-episode magmatic intrusion, melting and differentiation in the formation processes of rocks and ores. In addition, analyses about the relation between PGE and S, and study on Re-Os isotopes indicate that few contamination of the crustal substances occurred during the magmatic intrusion and the formation of deposit. However, contamination by crustal substances helps to supply part of the S for the enrichment of PGE. Meanwhile, the hydrothermal process is also advantageous for the enrichment of PGE, especially lbr Pt and Pd, due to deep melting segregation. The characteristic parameters （such as Pt/（Pt＋Pd）, （Pt＋Pd）/（Ru＋Ir＋Os）, Pd/Ir, Cu/（Ni＋Cu）, and so on.） for platinum-group elements for Jinchuan sulfide copper-nickel deposit show the same features as those for sulfide copper-nickel deposit related to basic magma, which also illustrates its original magma property representative of Mg-high tholeiite. Therefore, it is the marie （not ultramafic） magma that resulted in the formation of the superlarge sulfide copper-nickel deposit enriched in Cu and PGE. To sum up, the geochemical characteristics of platinum-group elements in rocks and ores from Jinchuan copper-nickel sulfide deposit are constrained by the continental rift tectonic environment, the parent magma features, the enriched mantel magma source, the complex metallogenesis and PGE geochemical signatures, and this would be rather significant for the study about the genetic mechanism of copper-nickel sulfide deposits.     

金川超大型铜镍硫化物矿床的铂族元素地球化学特征

对金川超大型铜镍岩浆硫化物矿床岩石、矿石的铂族元素地球化学特征研究表明 ,金川岩体的平均Cu/Pd值远大于原生地幔岩浆的Cu/Pd值 ,说明其岩石为因硫化物析离而失去Pd的岩浆所结晶 ;且岩石的PGE具有部分熔融趋势 ,与地幔橄榄岩接近 ,这些均指示存在岩浆熔离作用。该矿床岩石、矿石的PGE球粒陨石标准化分布模式比较对应 ,均可分为两种类型 ,反映了岩浆多次侵入、熔离分异同时成岩成矿的特征。另外 ,PGE S关系分析表明其成岩成矿过程中有少量地壳物质混染。PGE地球化学特征参数还指示了其高镁拉斑玄武质母岩浆的性质。     

龙首山岩带典型镁铁-超镁铁质岩体岩石地球化学特征

通过龙首山岩带中几个典型镁铁-超镁铁质岩体样品的岩石地球化学分析,对金川超镁铁质岩体与其外围镁铁-超镁铁质岩体的形成演化关系进行探讨,结果发现:这些岩体处于相同的构造环境,样品点整体为亚碱性拉斑玄武岩系列,随M g#值的增加,C aO,A l2O3,N a2O,K2O值具有连续减少的趋势,指示了它们存在连续的岩浆演化关系;稀土与微量元素分析,蛛网图整体具有右倾特征,龙首山岩带中段岩体有明显δEu负异常,东、西段岩体样品有δEu正异常或无异常,暗示中段岩体较外围岩体经历了更完全的分离结晶作用;结合前人对金川所做的S r-N d同位素等资料,证明金川岩体的岩浆源区为富集型地幔。     

西秦岭造山带礼县地区中川岩体LA-ICP-MS锆石U-Pb定年及其构造环境

中川复式岩体位于西秦岭中带,与成矿关系密切,主体岩性为黑云母二长花岗岩,一般认为其形成于印支期。对中川岩体采集样品并进行了LA-ICP-MS锆石U-Pb定年和岩石化学分析。结果表明,岩体钾钠含量较高,Na2O/K2O〈1;里特曼指数δ值为1.70～2.17,主体属高钾钙碱性系列;轻稀土元素富集,具中等程度的负Eu异常;K、Th、Rb等大离子亲石元素富集,同时显示出低Sr、低Yb的地球化学特征,形成于地壳加厚的构造环境。锆石U-Pb定年指示了08-49号样品黑云母二长花岗岩的形成时代最早为264.4Ma±1.3Ma,即二叠纪末期,略早于前人研究的结果。结合其构造环境,认为西秦岭从二叠纪末就开始了陆陆俯冲和地壳加厚的造山活动,并一直持续到三叠纪。     

The Jinchuan Ultramafic Intrusion: Cumulate of a High-Mg Basaltic Magma

The Jinchuan intrusion, situated in Gansu province, China, isan ultramafic dyke-like body emplaced in the Longshoushan upliftedterrain on the southwest margin of the Sino-Korea platform.The intrusion is 6 km long, 350 m wide and hosts a major Ni-Cusulfide deposit. It comprises three subchambers: the west, west-central,and east. The two western subchambers are narrow and deep, andboth are laterally zoned from dunite in the core through Iherzoliteto olivine pyroxenite toward the margins. The eastern subchamberis shallow and wide, and it shows vertical stratification gradingfrom dunite at the base upward into Iherzolite and plagioclaseIherzolite, then back to Iherzolite at the top. Sixty rock samples from the Jinchuan intrusion have been analyzedfor major and trace elements, and 54 samples were also analyzedfor the REE. All samples contain > 24 wt.% MgO, with themajority having > 35% when recalculated to 100% anhydrous.Negative linear correlations are observed between MgO and mostother constituents (except for a few such as Na₂O, K₂O, Sr,and Rb, which may have been affected by alteration), and itappears that the rocks were essentially formed as mixtures ofcumulus olivine and primary magma. Electron microprobe analyses show olivine compositions fromFo₇₉ to Fo₈₆, with most between Fo₈₃ and Fo₈₅. The MgO/(MgO+ FeO) value of the primary magma is calculated to have been 0.64, and its MgO content is estimated to have been 12 wt.%.Thus, the Jinchuan igneous body is probably the ultramafic cumulateportion of an intrusion of a high-magnesium basaltic magma relatedto continental rifting. We suggest that the two western subchambers of the Jinchuanintrusion represent the main conduit to the original magma chamberand that their zoning was formed by flow differentiation. Theeastern subchamber probably represents a higher level of themagma chamber, where crystallization was marked by convectionand periodic replenishment. After consolidation, the Jinchuanintrusion was tilted to the east so the deeper parts of thewestern subchambers are now exposed to the same erosion levelas the shallower part of the eastern subchamber.     

云南祥云马厂箐富碱斑岩体的地球化学特征及其形成的构造环境

云南祥云马厂箐岩体处于扬子板块西缘与NW向的金沙江—哀牢山深大断裂带东侧交汇部位,属于哀牢山—金沙江富碱侵入岩带的组成部分。马厂箐岩体主要为花岗斑岩、二长斑岩和正长斑岩,岩体化学成分具有富碱、富铝和高钾的特点。岩石富集大离子亲石元素(Rb、Sr、Ba、Th和U)和轻稀土元素(LREE)、相对亏损高场强元素(Ta、Nb和Ti),且Ta、Nb和Ti具"TNT"负异常;LREE/HREE值为8.04～23.99,δEu值为0.72～0.88,负Eu异常不明显;n(87Sr)/n(86Sr)值范围为0.7072～0.7086,均值为0.7080,高于原始地幔现代值0.7045;n(143Nd)/n(144Nd)值范围为0.5121～0.5124,均值0.5123,低于原始地幔现代值0.512638;ISr值范围为0.7061～0.7075,均值为0.7070;εNd值范围为(3.1～(10.2,均值为(6.8。马厂箐岩体既不属于传统的含碱性暗色矿物的碱性岩类,也不同于典型的A型花岗岩,应属于富碱侵入岩类;岩体的岩浆起源于壳—幔物质混合的一种所谓EMⅡ型富集地幔源;其壳幔混合特征,主要是俯冲进入上地幔的地壳物质与地幔物质发生了源区混合作用的结果;形成于碰撞后的板内构造环境。     

内蒙古扎赉特旗神山铁铜矿床成岩成矿年代学及其地质意义

内蒙古神山铁铜矿床是大兴安岭中段具有代表性的矽卡岩型铁铜矿床。笔者就该矿床成矿岩体的地球化学及锆石LA-ICP-MS U-Pb年代学开展相关研究。研究表明：矿区中与成矿有关的伊力特岩体岩石类型为英云闪长岩,属I型花岗岩类,铝过饱和,高钾钙碱性系列和磁铁矿系列;岩石富集轻稀土（LREE）、大离子亲石元素（LILE）,亏损高场强元素（HFSE）,铕异常不明显（δEu为0.97~1.17）,存在弱铈异常（δCe为0.86~0.92）;锆石LA-ICP-MS U-Pb测年显示,与成矿有关的伊力特岩体形成于晚侏罗世（（155.3±1.3）Ma）,因此推测神山铁铜矿床成矿时代为晚侏罗世。综合研究认为神山铁铜矿床形成于地壳加厚和构造活化的构造环境。