The lattice energy of forsterite. Charge distribution and formation enthalpy of the SiO 4 4− ion

In the lattice energy expression of forsterite, based on a Born-Mayer (electrostatic+repulsive+dispersive) potential, the oxygen charge z _o, the hardness parameter ρ and the repulsive radii r _Mg and r _Si appear as unknown parameters. These were determined by calculating the first and second partial derivatives of the energy with respect to the cell edges, and equalizing them to quantities related to the crystal elastic constants; the overdetermined system of equations was solved numerically, minimizing the root-mean-square deviation. To test the results obtained, the SiO ₄ ^4? ion was assumed to move in the unit-cell, and the least-energy configuration was sought and compared with the experimental one. By combining the two methods, the optimum set of parameters was: z _o=?1.34, ρ=0.27 Å, r _Mg=0.72 Å, r _Si=0.64 Å. The values ?8565.12 and ?8927.28 kJ mol^?1 were obtained, respectively, for the lattice energy E _Land for its ionic component E _L ⁰ ,which accounts for interactions between Mg²⁺ and SiO ₄ ^4? ions only. The charge distribution calculated on the SiO ₄ ^4? ion was discussed and compared with other results. Using appropriate thermochemical cycles, the formation enthalpy and the binding energy of SiO ₄ ^4? were estimated to be: ΔH _f(SiO ₄ ^4? )=2117.6 and E(SiO ₄ ^4? )=708.6 kJ mol^?1, respectively.     

Uraninite—An economic uranium mineral in metamorphic uranium deposit No. 3075

Uraninite from the metamorphic deposit investigated is divided into two groups on the basis of its occurrence and physical and chemical properties. Uraninite of the first group occurs as distorted crystals in the form of elongated cubesa {100}; the second group occurs mainly in the form of rhombo-dodecahedrad {100}, all belonging to the GaF₂ type in the isometric system. The chemical formulae are 8UO₂·UO₃·PbO for the first group and 5UO₂·UO₃·PbO for the second. Isotopic dating yields 1,900 and 300 m. y. for the formation time of uraninite in this deposit. The former value corresponds to the main mineralization period and the latter represents the reformation event.     

Magnetic structure and cation distribution in (Fe,Mn)2SiO4 (olivine) by neutron diffraction

The cation distribution in the synthetic samples of olivine-type structure with composition (Fe _x Mn_1?x )₂SiO₄ was determined at room temperature and confirms previous Mössbauer results. At low temperature an antiferromagnetic ordering is observed. The magnetic structures can be described in the crystallographic cell (i.e. k=0). They are interpreted on the basis of the irreducible representations (modes) of the symmetry groups which are compatible with Pnma. The dominant modes observed for all compounds, including Fe₂SiO₄ and Mn₂SiO₄, only differ in their direction. The main direction of magnetization is dominated by the Fe²⁺ single-ion anisotropy. At 4.2K, for x=0.29, it is parallel to the c-axis, whereas for x=0.76 the direction is parallel to the b-axis. The anisotropy of the M1-sites dominates in the first case, whereas M2-anisotropy dominates in the second case. The influence of temperature is demonstrated for x=0.50 where c is the main direction at 4.2K, when it is b at 38K.     

The influence of mussel beds on nutrients in the Western Wadden Sea and Eastern Scheldt estuaries

The uptake and release of materials by intertidal mussel beds were directly measured in two cultivated Dutch estuaries. Generally, chlorophylla, seston, and particulate organic carbon were taken up, while ammonium, orthophosphate, and silicate were released. The observed rates were higher than values computed from organismic observations and similar to those observed for intertidal oyster reefs in South Carolina. Specific estuarine material turnover rates varied from 1 week to 38 weeks when calculated with mussel bed fluxes. The fastest turnover rates were for chlorophylla and ammonium. These results support the idea that dense assemblages of bivalves are major components in the recycling of nutrients in estuaries.     

Modern diversity of the macroalgae of the Sea of Azov,the Black Sea,and the Caspian Sea

Currently, the species list of the macroalgae (excluding Charales) inhabiting the southern seas of Russia includes 388 species, specifically, 362 species in the Black Sea, 46 species in the Sea of Azov, and 70 species in the Caspian Sea. The species list has been increased by approximately 30% (96 species, most of them are registered in the Black Sea), compared to the data obtained 30 years ago. The green and red macroalgae of warm-water Mediterranean and tropical origin (Ceramium, Polysiphonia, Laurencia, Ulva, and Chaetomorpha) and brown algae (Sargassum and Cytoseira) were the key invaders. Nowadays the maximal species diversity is found on the Crimean coast and the Turkish coast of the Black Sea; and the species list of the Turkish coast differs significantly from all the other studied sites of the Black Sea. The number of the algae of the warm-water complex increased the most in 1990s–2000s in the Black Sea; species of boreal-tropical and subtropical origin dominate. However, such a tendency was not observed in the Sea of Azov and in the Caspian Sea, but expansion of the habitats of the brackish green algae has been registered.     

Effect of pressure on the crystal structure of perovskite-type MgSiO3

The crystal structure of perovskite-type MgSiO₃ has been studied up to 96 kbar, using a miniature diamondanvil pressure cell and by means of single-crystal four-circle diffractometry. The observed unit cell compression gives a bulk modulus of K _o=2.47 Mbar, assuming K′_o=4. The unit cell compression is controlled mainly by the tilting of SiO₆ octahedra. The effect of pressure is to change Mg polyhedron towards 8-fold coordination rather than 12-fold coordination. The polyhedral bulk moduli of SiO₆ and MgO₈ are 3.8 Mbar and 1.9 Mbar, respectively.     

Raman scattering and lattice vibrations of Ni2SiO4 spinel at elevated temperature

Raman spectra of Ni₂SiO₄ spinel (O _h ⁷ Z=8) have been measured in the temperature range from 20 to 600 °C and the Raman active vibrations (A _1g +E _g +3F _2g ) have been assigned. A calculation of the optically active lattice vibrations of this spinel has been made, assuming a potential function which combines general valence and short range force constants. The values of the force constants at 20 and 500 °C have been calculated from the vibrational frequencies of the observed Raman spectra and infrared (IR) spectral data. The Ni spinel at 20 °C has a prominently small Si-O bond stretching force constant of K(SiO)=2.356 ～ 2.680 md/Å and a large Ni-O bond stretching constant of K(NiO)=0.843 ～ 1.062 md/Å and these force constants at 500 °C decrease to K(SiO)=2.327 ～ 2.494 md/Å and K(NiO)=0.861 ～ 0.990 md/Å. The Si-O bond is noticeably weakened at high temperatures, despite the small thermal expantion from 1.657 Å (20 °C) to 1.660 Å (500 °C). These changes of the interatomic force constants of the spinel at high temperatures are in accord with the thermal structure changes observed by X-ray diffraction study. The weakened Si-O bond is consistent with the fact that Si atoms in the spinel lattice can diffuse at significant rates at elevated temperature.     

Radiation resistant of native Deinococcus spp. isolated from the Lout desert of Iran “the hottest place on Earth”

Two native ionizing radiation-resistant bacteria were isolated and identified from a soil sample collected from extreme conditions of the Lout desert in Iran. The hottest land surface temperature has been recorded in the Lout desert from 2004 to 2009. Also, it is categorized as a hyper arid place. Both ionizing radiation and desiccation may cause damage on genome. Soil sample was irradiated in order to eliminate sensitive bacteria then cultured in one-tenth-strength tryptic soy broth medium. Bacterial suspension used for radiation treatment. Morphological and physiological characterization and phylogenetic studies based on 16S rRNA gene sequence were used for identification. The cells were rod shape, non-motile, non-spore forming and gram positive. The 16S rRNA gene sequence showed 99.5 % of similarity to Deinococcus ficus. Phylogenetic dendrogram demonstrated that the isolates branched with D. xibeiensis, D. ficus and D. mumbaiensis. Both isolates were resistant to >15 kGy of gamma radiation and >600 J m² of UV radiation. This is the first report on radiation resistant bacteria belonging to genus Deinococcus isolated from the Lout desert of Iran.     

Interpretation of the auger electron spectra (AES) of sulfide minerals

Auger electron spectra (AES) of sulfides are interpreted using published photoelectron spectra, sulfurK _β X-ray emission spectra (XES) and Multiple ScatteringX _α calculations on metal-sulfide molecular clusters and using newly measured spectra for ZnS, Cu₂S and MoS₂. For compounds without appreciable metald-sulfur 3p interactions, only one sulfur LVV peak or a closely spaced doublet is observed. For those with substantial metald-sulfur 3p interactions additional peaks occur, with peaks at lower electron kinetic energy arising from ejection of electrons from orbitals more tightly bound than theS3p, and those with higher kinetic energy arising from electrons in less tightly bound orbitals. Thus, for many sulfide minerals, the sulfur LVV Auger Spectrum is essentially a self-convolution of the valence band density of states weighted by the amount of S3p character, and can be predicted from a knowledge of the sulfurK _β X-ray emission spectra and the X-ray photoelectron spectra.     

Macroinvertebrate associations on the egg masses of the sea hare,Aplysia brasiliana rang (Gastropoda: Opisthobranchia)

We examined the assemblage of macroinvertebrates that inhabits the egg masses of the sea hareAplysia brasiliana Rang. A total of 3,721 individuals belonging to 31 invertebrate species was recovered from 107 egg masses collected in the Indian River Lagoon in east-central Florida. The egg mass associates appeared to be a subset of the surrounding faunal assemblage. Amphipods, polychaetes, and molluscs comprised the majority of the egg mass fauna. Of these, approximately 10 species were abundant, and were collected with high frequency in the egg masses examined. Association analysis of the distribution patterns of the more common species indicates that only positive first order effects and second order interactions were potentially important in this assemblage.     

On the nonstoichiometry and point defects of olivine

This paper presents the point-defect thermodynamics for fayalite and olivine solid solutions (Fe _x Mg_1?x )₂SiO₄. By means of thermogravimetry, the metal-to-oxygen ratio of these silicates has been determined as a function of oxygen potential, compositionx and temperature. Experiments were performed in the range of 1,000° C≦T≦1,280° C and 0.2≦x≦1.0. It is found that V _Me ^″ , Fe _Me ^· and the associate {Fe′ _Si ^′ Fe _Me ^· } are the majority defects. With this knowledge it is possible to calculate the nonstoichiometry at given temperature as a function of \(p_{O_2 } \) and \(a_{SiO_2 } \) . The cation vacancy concentration shows a \(p_{O_2 }^{1/5} \) -dependence (forx≧0.2) and increases at givenT and \(p_{O_2 } \) almost exponentially with compositionx. In the composition range studied here, the silicates show an oxygen excess, and FeO is more soluble in the olivine than SiO₂.     

Feeding ecology of the gulf silverside,Menidia peninsulae,near Crystal River,Florida, with notes on its life history

Feeding habits ofMenidia peninsulae were analyzed monthly over a one year period and compared to planktonic prey available at the capture site. Three feeding stages were found: (1) In early spring, young-of-the-year fed on tychoplankton and detritus. (2) From late spring through winter,M. peninsulae preyed selectively on calanoid copepods and cypris larvae. (3) GravidM. peninsulae fed primarily on amphipods and larval silversides. In the Crystal River area,M. peninsulae reproduce in early spring. Silversides apparently migrate from the higher salinity bays to the lower salinity marshes in the summer, and then move back into the bays in fall.     

Charge distribution from least-energy structure in Ca - Mg orthosilicates

Calcium-olivine, γ-Ca₂SiO₄, larnite, β-Ca₂SiO₄, merwinite, Ca₃Mg(SiO₄)₂, and monticellite, CaMgSiO₄, are considered. According to a rigid oxyanion scheme, eulerian orientation angles of the SiO₄ tetrahedra and translation coordinates of Ca and Si atoms are specified as structural variables τk. All derivatives of the static energy (Born model) contain atomic charges and repulsive parameters as unknowns; the minimum energy conditions ?E _L/?τ_k=0 yield 34 equations which are solved by a least-squares method. The set of energy parameters fitting structural properties of all four phases together is: z _Ca=1.50, z _o=?1.10 e, r _Ca=1.05, ρ=0.25 Å; the Mg charge was fixed at 1.38 e, from a previous study on forsterite. An average shift of 0.04 Å is observed between experimental and least-energy calculated atomic positions. Results are compared with those of Mg₂SiO₄, where the fit was based both on thermoelastic and on structural properties. If no charge values were fixed “a priori”, just ratios between charges could be determined by fitting them to structural data only.     

Biodegradation of polyvinyl alcohol-low linear density polyethylene-blended plastic film by consortium of marine benthic vibrios

Marine bacteria, Vibrio alginolyticus and Vibrio parahemolyticus isolated from sediments were evaluated for their ability as a consortia, to degrade polyvinyl alcohol-low linear density polyethylene (PVA-LLDPE)-blended plastic films in shake flask conditions at 120 rpm at 37 °C over 15 weeks. Results indicated that relatively 20 % decrease in tensile strength of the film could be achieved with 25 and 30 % blend of PVA in the PVA-LLDPE plastic film compared to other ratios. Micrographs obtained with scanning electron microscope showed visible cracks and grooves on the surface of the PVA-LLDPE blend film after 15 weeks of incubation with bacterial consortium. The decrease in tensile strength of the PVA-blended plastic films after treatment and the results of the scanning electron microscopic analysis evidence that the consortium could cause degradation of PVA-LLDPE plastic blends compared to suitable controls. This is the first report on polyvinyl alcohol degrading Vibrio sp. from marine sediments and its application in microbial degradation of polyvinyl alcohol-low linear density polyethylene plastic blends. The study indicated potential of marine benthic vibrios that have novel enzymes and unique characteristics for application in bioremediation and solid waste management particularly in handling synthetic polymers such as PVA-blended plastic films.     

Dislocation strain energy in the Al2SiO5 polymorphs

Molar elastic strain energy arising from dislocations in andalusite and sillimanite were calculated using equations derived from a non-core, linear elasticity model. For perfect (unit) c screw dislocations in these polymorphs, minimum dislocation densities of about 10¹⁰/cm² are necessary to significantly perturb the andalusite=sillimanite equilibrium boundary in P-T space. Compared to unit c dislocations, smaller energy perturbations arise from dissociated c screw dislocations, which are commonly observed in kyanite and sillimanite. A low computed value of stacking fault energy (～30 ergs/cm²) in these polymorphs is compatible with the large separations of dissociated dislocations in these phases. Dislocation densities in naturally occurring Al₂SiO₅ polymorphs are typically <10⁸/cm². Assuming that these densities are representative of those existing during metamorphism, as is supported by the lack of microtextures indicative of strong recovery, it is concluded that molar strain energies corresponding to observed dislocation densities (<10⁸/cm²) result in insignificant perturbation of P-T phase equilibrium boundaries of the Al₂SiO₅ polymorphs.     

High temperature solvent growth of anorthite on the join CaAl2Si2O8-SiO2

Stoichiometric anorthite, CaAl₂Si₂O₈, Pˉ1, with sharp a, b, c, and d diffractions was grown, using a CaV₂O₆ solvent, by cooling at 2 ° C per hour from 1450 to 750 ° C in air. Euhedral crystals up to 5 × 3× 0.5 mm, with prominent {010} and well-developed {110} and {001}, were obtained by spontaneous nucleation. Nonstoichiometric anorthite with excess SiO₂ (CaAl₂Si₂O₈+Si₂Si₂O₈) was grown on the join CaAl₂Si₂O₈-SiO₂. Chemical analysis of the synthetic anorthite, having the highest SiO₂ content, with maximum vacancies on M-site gave □_0.110 Na_0.006Ca_0.884Al_1.80Si_2.20O₈, and X-ray diffraction showed a trend from stoichiometric Pˉ1 through diffuse Pˉ1 to body-centered Iˉ1 probably reflecting increasing disorder caused by a higher Si/Al ratio in the T-sites and the positional disorder accompanied by M-site vancancies. Annealing of the nonstoichiometric diffuse Iˉ1 anorthite in air at 1050 ° C for 14 days resulted in exsolution of minute SiO₂ inclusions due to probable ordering in the T-sites and filling of M-sites by Ca. Stoichiometric Pˉ1 anorthite was not obtained by annealing at 1050 ° due to appreciable solubility of SiO₂ in CaAl₂Si₂O₈. Metastable hexagonal CaAl₂Si₂O₈ was found to be a twinned monoclinic crystal with cell dimensions: a = 10.24 (2), b = 17.74 (3), c= 14.99 (5) ?, β = 92.05 (5) °, space group C2.     

Distribution ofPerkinsus marinus in Gulf Coast oyster populations

Prevalence (percent of oysters infected) ofPerkinsus marinus and infection intensity were measured in oysters from 49 sites in the Gulf of Mexico. Prevalence was less than 50% at only one site. Both prevalence and infection intensity were correlated with condition index, salinity, and a measure of local agricultural activity. The regional distribution ofP. marinus was patchy on spatial scales of 300 km or less and 1,500 km or more. Three regional foci of infection could be distinguished: the north central coast of Texas, central Louisiana west of the Mississippi River, and the southwestern coast of Florida. Lowest infection levels were recorded along the north central and northeastern Gulf, particularly east of the Mississippi River. The spatial distribution of infection varied with the salinity regime; however, other factors also explained part of the regional patterns observed. These included factors associated with man’s activities such as agricultural and industrial activity and the average annual temperature regime.     

The effect of crystal field stabilization on the olivine→spinel transition in the system Mg2SiO4 - Fe2SiO4

Crystal field stabilization (CFS) plays a significant role in determining equilibrium phase boundaries in olivine→spinel transformations involving transition-metal cations, including Fe²⁺ which is a major constituent of the upper mantle. Previous calculations for Fe₂SiO₄ ignored pressure and temperature dependencies of crystal field stabilization enthalpies (CFSE) and the electronic configurational entropy (S _CFS). We have calculated free energy changes (ΔG _CFS) due to differences of crystal field splittings between Fe₂SiO₄ spinel and fayalite from: ΔG _CFS=?ΔCFSE?TΔS _CFS, as functions of P and T, for different energy splittings of t _2g orbital levels of Fe²⁺ in spinel. The results indicate that ΔG _CFS is always negative, suggesting that CFS always promotes the olivine→spinel transition in Fe₂SiO₄, and expands the stability field of spinel at the expense of olivine. Because of crystal field effects, transition pressures for olivine→spinel transformations in compositions (Mg_1?x Fe _x )₂SiO₄ are lowered by approximately 50x kbar, which is equivalent to having raised the olivine→spinel boundary in the upper mantle by about 15 km.     

Deflation processes and their role in desertification of the southern Pre-Balkhash deserts

Deflation processes are important in arid environments such as deserts. The deserts of Kazakhstan mostly cover lowlands and extend from the eastern coast of the Caspian Sea to the piedmonts of the Tien-Shan Mountain. Desert areas are also major source areas of dust/sand storm activities. We considered deflation processes in the southern Pre-Balkhash deserts. In Kazakhstan, desertification processes due to wind erosion in the form of dust/sand storms were observed in semi-desert and desert landscapes. During analysis of numerous long-term meteorological data and cartographic materials, we revealed the sand movement directions which allow prediction of future potential sand movement patterns or processes in southern Pre-Balkhash deserts. The Taukum, Moiynkum deserts, Ili river deltas and valleys, and southern coastal of Lake Balkhash are most prone to dust/sand storms. The most frequent storms were observed in the Bakanas weather station (Ile river valley). Sand/dust transport occurs mainly in the east, south-east north-east direction in the southern Pre-Balkhash deserts. The high amount of sand transportation was observed at the Kuigan weather station; low amounts were encountered at the Naimansuiek weather station. The amount of airborne sand/dust varies in accordance with the general and local meteorological features, the complexity of relief forms, soil conditions and properties, lithology, and various contributions of the human activities. Thus, our study on deflation processes in the southern Pre-Balkhash deserts has great importance towards aiding in the prediction and monitoring of dust/sand storms and movement patterns.