Thermal anomalies and paleoclimatic diffusive and advective phenomena: example of the Anglo-Paris Basin,northern France

This study is the first quantification of the combined impact of diffusive and advective paleoclimatic phenomena to explain the weak vertical thermal flux anomaly in the upper part of the Anglo-Paris intracratonic sedimentary basin in northern France. The aim of the research is to understand the mechanisms at the origin of the thermal flux anomaly at the level of the Meso-Cenozoic sediment pile. Based on a temperature profile representative of the basin, transient thermo-hydraulic simulations were performed along a representative vertical cross-section of about 400 km within the Lower Cretaceous multi-layer aquifer. Four paleoclimatic scenarios are the combination of two paleotemperature climatic forcings and two hydrodynamic regimes, one of them taking into account the interruption of the recharge linked to permafrost development. The simulation results clearly show the transient nature of the basin’s thermal regime. Then, for the reference well, the majority of the thermal flux anomaly can be explained by advective and paleoclimatic mechanisms with a decrease in geothermal flux simulated up to a little over 30 mW/m², depending on the scenarios. Decrease in heat flux because of basin-scale subsurface flows in the Lower Cretaceous is around 15 mW/m². There are several ways forward from this first simple model, including simulation of development of permafrost and also the integration of vertical flows in the basin by use of a three-dimensional model to better explain the data.     

Mercury speciation in soils of the industrialised Thur River catchment (Alsace,France)

Methylmercury (MeHg) and total Hg (THg) concentrations in soil profiles were monitored in the Thur River basin (Alsace, France), where a chlor-alkali plant has been located in the city of Vieux-Thann since the 1930s. Three soil types were studied according to their characteristics and location in the catchment: industrial soil, grassland soil and alluvial soil. Contamination of MeHg and THg in soil was important in the vicinity of the plant, especially in industrial and alluvial soil. Concentrations of MeHg reached 27 ng g⁻¹ and 29,000 ng g⁻¹ for THg, exceeding the predictable no effect concentration. Significant ecotoxicological risk exists in this area and remedial actions on several soil types are suggested. In each type of soil, MeHg concentrations were highest in topsoil, which decreased with depth. Concentrations of MeHg were negatively correlated with soil organic matter and total S, particularly when MeHg concentrations exceeded 8 ng g⁻¹. Under these conditions, MeHg concentrations in soil seemed to be influenced by THg, soil organic matter and total S concentrations. It was found that high MeHg/THg ratios (near 2%) in soil were mainly related to the combined soil environmental conditions such as low THg concentrations, low organic C/N ratios (<11) and relatively low pH (5–5.5). Nevertheless, even when the MeHg/THg ratio was low (∼0.04%), MeHg and THg concentrations were elevated, up to 13 ng g⁻¹ and to 29,000 ng g⁻¹, respectively. Thus, both THg and MeHg concentrations should be taken into account to assess potential environmental risks of Hg.     

Structural controls on topography and river morphodynamics in Upper Assam Valley,India

The basement in Upper Assam foreland basin exhibits a typical flexure pattern. An elongated continuous subsurface basement high has developed between Himalaya and Naga-Patkai ranges. A few prominent basement lows have developed adjacent to the foothill regions. It is noticed that the general topographic slope near the foothill regions is not only controlled by aggradation process, but also influenced by the flexured basement of the region. The basement lows have influenced the overlying topography significantly. Rivers flowing over those regions have shown unidirectional lateral migration. North bank tributaries like Subansiri, Jiadhal and Dikrang have been affected by the Subansiri basement low. Coseismic subsidence of sediments over Subansiri basement low had resulted subsidence of the North Lakhimpur-Ranga Nadi region in 1950 Assam earthquake. Some south bank tributaries like Disang and Dikhow have been affected by Nazira basement low. Topographic elevation along the Subansiri river is lower than that part of the Brahmaputra located south of Majuli. This typical topographic setting of the region makes the mouth of the Subansiri river and Majuli region highly susceptible to erosion.     

Characterization and correlation of Upper Jurassic (Oxfordian) bentonite deposits in the Paris Basin and the Subalpine Basin, France

Abstract Explosive volcanic activity is recorded in the Upper Jurassic of the Paris Basin and the Subalpine Basin of France by the identification of five bentonite horizons. These layers occur in Lower Oxfordian (cordatum ammonite zone) to Middle Oxfordian (plicatilis zone) clays and silty clays deposited in outer platform environments. In the Paris Basin, a thick bentonite (10–15 cm), identified in boreholes and in outcrop, is dominated by dioctahedral smectite (95%) with trace amounts of kaolinite, illite and chlorite. In contrast, five bentonites identified in the Subalpine Basin, where burial diagenesis and fluid circulation were more important, are composed of a mixture of kaolinite and regular or random illite/smectite mixed-layer clays in variable proportions, indicating a K-bentonite. In the Subalpine Basin, a 2–15 cm thick bentonite underlain by a layer affected by sulphate–carbonate mineralization can be correlated over 2000 km². Euhedral zircon, apatite and biotite crystals have been identified in all the bentonites. The geochemical composition of the bentonites in both basins is characterized by high concentrations of Hf, Nb, Pb, Ta, Th, Ti, U, Y, Zr and low concentrations of Cr, Cs and Rb. Biostratigraphical and geochemical data suggest that the thick bentonite in the Paris Basin correlates with the thickest bentonite in the Subalpine Basin, located 400 km to the south. These horizons indicate that significant explosive volcanic events occurred during the Middle Oxfordian and provide potential long-distance isochronous marker beds. Immobile element discrimination diagrams and rare-earth element characteristics indicate that the original ash compositions of the thickest bentonites correspond to a trachyandesitic source from a within-plate alkaline series that was probably related to North Atlantic rifting.     

Changes in hydrodynamic process dominance (wave,tide or river) in foreland sequences: The subalpine Miocene Molasse revisited (France)

A comprehensive sedimentological study was undertaken in the Miocene of the subalpine massifs and southern Jura (France) with the aim to constrain the evolution of process changes in third-order sequences of peripheral foreland basins during the overfilled phase (i.e. sediment supply higher than accommodation space). Fieldwork analyses based on 35 sedimentological sections allowed the identification of four depositional models: wave dominated, mixed wave-tide, river to tide and river dominated. The sections were dated using chemostratigraphy (i.e. marine strontium isotopic ratios), revealing three-third-order sequences between the Upper Aquitanian and the Langhian. Chronostratigraphical and sedimentological results document prominent and recurrent changes in depositional models along third-order sequences: (i) in the earliest stage of the transgression, mixed-energy coastal environments influenced by the local coastal morphology prevailed (in palaeo-highs or incised valleys); (ii) during the course of the transgression, Gilbert delta deposits suggest a prominent steepening linked to a tectonic uplift in the proximal depozone (between the tectonically active frontal part of the orogenic wedge and the proximal foredeep). Instead, in the distal depozone (between the proximal foredeep and the proximal border of the flexural uplifted forebulge), deposits were characterized either by wave-dominated or mixed wave-tide environments and are likely eustatically-driven; (iii) during the maximum flooding stage, water depth remained shallow below the storm-weather wave base; and (iv) during the regression, the proximal depozone is characterized by the progradation of gravel-rich fan deltas. In the distal depozone, mixed wave-tide systems preceded the development of river to tidal depositional environments. These results were integrated and compared with facies models from other basin analogues worldwide. A model tackling the evolution of process changes within third-order sequences (of the overfilled phase) of foreland basins is proposed, thereby improving sequence stratigraphic predictions in foreland basins.     

Carbonate platform-to-basin correlation by means of grain-composition logs: an example from the Vercors (Cretaceous, SE France)

Quantitative logs of grain composition for several sections of platform top and flank of the Vercors carbonate platform (Early Cretaceous, SE France) provide platform-to-basin correlation with a resolution of a few metres over an area of 70 km². Grain composition was determined by point-counting thin sections. Point-count groups that characterize palaeoenvironmental realms (i.e. open sea, platform margin) were defined for the platform–basin trajectory. Grain-composition logs revealed marked peaks in the number of open-sea biota and peaks in ooid abundance. The peaks in open-sea biota correspond to back-stepping intervals and deepening upward facies successions at the platform margin. These peaks probably relate to incipient drowning of the platform and may be used to delineate marine-flooding surface-bounded sequences. Peaks in ooid occurrence show no relationship with the progradation, aggradation or retreat of the platform. Apparently, the oolitic sands were not part of a facies tract that shifted up and down the platform. Instead, they represent a depositional mode that was either on or off. Times of prolific ooid production and shedding probably occurred during wide but shallow submergence of the platform, accompanied by suitable water chemistry. Peaks in both ooids and open-sea biota are excellent markers for platform-to-basin correlation, as they are recorded in successions on the platform top as well as on the flank. Altogether, the grain-composition logs show that each of the lithologically rather similar platform tongues of the Vercors has a unique signature or compositional fingerprint. These compositional fingerprints are most helpful in evaluating the lateral extent of different stratigraphic units. In outcrops of the Vercors platform, the physical tracing of bedding surfaces delineate wedges of toe-of-slope sediments that show a conspicuous thinning towards the platform. However, our correlation shows that these sediment bodies are not truly basin-restricted wedges but have a platform top equivalent. This implies that these units were, at least partly, deposited during high stands of sea level that flooded the platform.     

Muscovite recrystallization and saddle-shaped Ar/Ar age spectra: example from the Blond granite (Massif Central, France)

Muscovites from the Blond granite (West French Massif Central) were dated by the ⁴⁰Ar/³⁹Ar single-grain method. The ⁴⁰Ar/³⁹Ar ages obtained vary from 305.5 ± 0.3 Ma to 311.3 ± 0.5 Ma, and most of the age spectra are slightly saddle-shaped. The analyzed muscovites show phengitic recrystallization under optical microscope observations, SEM images, and electron microprobe chemical analyses. It is proposed that the saddle-shaped age spectra result from a partial recrystallization, which produced three different isotopic reservoirs in the analyzed white mica single grains: domains of early muscovite, domains of neocrystallized muscovite formed by phengitic and Al-Fe substitutions, and “low-activation energy sites.”     

Comparative behaviour of recently deposited radiostrontium and atmospheric common strontium in soils (Vosges mountains,France)

The vertical distribution of atmospheric ⁸⁷Sr/⁸⁶Sr isotope ratios in soil is compared to the distribution of recent atmospheric ⁹⁰Sr deposition. ⁸⁷Sr/⁸⁶Sr isotope ratios of soil leachates are correlated with ⁹⁰Sr activities. Samples from the uppermost part of a soil profile have low ⁸⁷Sr/⁸⁶Sr ratios and high ⁹⁰Sr activities. Samples from the deeper part of the soil profile, however, have high ⁸⁷Sr/⁸⁶Sr but low ⁹⁰Sr activities. This points to mixing between an atmospheric and a geogenic component. Mixing calculations indicate that 50–80% of the Sr in the topsoil of a small catchment in the Vosges mountains is of atmospheric origin. Similarly ⁸⁷Sr/⁸⁶Sr of roots point to the presence of an atmospheric and geogenic component. ⁸⁷Sr/⁸⁶Sr ratios of soil leachates and corresponding roots are very similar indicating, that the roots integrate at each level of the soil profile the leachable Sr of the corresponding soil.     

Multi-isotopic (Li,B, Sr,Nd) approach for geothermal reservoir characterization in the Limagne Basin (Massif Central,France)

A multi-isotopic study of thermo-mineral waters from the Limagne Basin (French Massif Central) is reported. Lithium, B, Sr and Nd isotopic signatures in thermo-mineral waters and bedrocks were combined in order to determine the origin of these fluids from a reservoir point of view. Strontium and Nd isotopic systems showed that the thermo-mineral waters are mostly derived from a granitic reservoir type, with the exception of a few water samples having Sr and Nd isotopic signatures also reflecting a volcanic contribution (basalts). In a second step, Li and B isotopes were investigated, given that Li and B isotopic systematics are potentially affected by mass dependent fractionation during water/rock interaction and could provide some information on what takes place during this process. A great diversity of thermo-mineral waters within the Aigueperse area was clearly observed, which is directly related to the origin of these thermal waters in terms of reservoirs. These different geothermal reservoirs are characterized by different geological settings and intensity of water/rock interaction (i.e. depth and temperature).     

Molecular and bulk isotopic analyses of organic matter in marls of the Mulhouse Basin (Tertiary, Alsace, France)

Contents of 13C in kerogens and carbonates in 21 samples from a core of the MAX borehole, Mulhouse Evaporite Basin, range from -27.3 to -23.5 and -3.7 to -1.8% vs PDB, respectively. Organic nitrogen in the same samples is enriched in 15N relative to atmospheric N2 by 12.2-15.7%. Hydrogen indices and delta values for kerogens vary systematically with facies, averaging 493 mg HC/g Corg and -25.7% in the most saline facies (dominated by inputs from aquatic sources) and 267 mg HC/g Corg and -23.7% in the least saline facies (50/50 aquatic/terrigenous). Values of delta were measured for individual aliphatic hydrocarbons from three samples representing three different organic facies. For all samples, terrigenous inputs were unusually rich in 13C, the estimated delta value for bulk terrigenous debris, apparently derived partly from CAM plants, being -22.5%. In the most saline facies, isotopic evidence indicates the mixing of 13C-depleted products of photosynthetic bacteria with 13C-enriched products of halotolerant eukaryotic algae. At lower salinities, a change in the producer community is marked by a decrease in the 13C content of algal lipids. The content of 13C in algal lipids increases in the least saline facies, due either to succession of different organisms or to decreased concentrations of dissolved CO2.     

Chromium and nickel distribution in soils, active river, overbank sediments and dust around the Burrel chromium smelter (Albania)

Chromium ore was treated to produce ferrochromium from 1979 until 2000 in a smelter in Burrel, 35 km NE of Tirana (Albania). As a consequence, large amounts of solid waste, i.e. slags (about 9.10⁶ m³) have been disposed next to the smelter, disfiguring the landscape. In an attempt to define contaminated sites, heavy metal content of the different sampling media have been compared with respective background samples.In the study area, the determination of background values in soil samples is complicated due to the different geological substrates. Cr and Ni background concentrations in serpentinite-derived soils, west of the smelting plant, are markedly higher than in the Pliocene gravel/sandy soils, where the smelter is situated (Cr 2147 and 193 mg/kg, respectively; Ni 2356 and 264 mg/kg). These values are clearly lower than those encountered around the smelter. Average total Cr and Ni concentrations in soils around the smelter are 3117 and 1243 mg/kg, respectively. The highest concentrations of Cr (up to 2.3 wt.%), were recorded in samples taken near the smelting compartment within the industrial plant and next to the slags clearly indicating that the smelter forms a point source of Cr contamination. The Cr / Fe ratio is the best indicator to differentiate non-polluted (Cr / Fe Serpentinite soil: 130–390; Pliocene soils: < 130) from polluted areas (> 390 smelting nearby of the slags).Cr and Ni values for local backgrounds in stream and overbank sediments were taken in the Mat river 6 km upstream and to the east of the smelter (268 and 430 mg/kg for Cr, and 306 and 604 mg/kg for Ni, respectively). Equivalent sediments taken from the Zalli i Germanit river, which drains the smelter area are respectively 816 and 1126 mg/kg for Cr and 1115 and 1185 mg/kg for Ni.Dust samples, taken from the lofts of houses up to 2 km from the smelter, display high concentrations of Cr, Ni and Zn (average contents of 2899, 436 and 902 mg/kg, respectively). The later concentrations in the dust samples have been confirmed by mineralogical analysis where Cr-bearing mineral phases such as ferrochromium and chromium oxides, clearly relate to the activity of the smelter. Consequently, atmospheric deposition of dust particles forms a serious problem and can also be responsible for the elevated contents encountered in soil samples around the smelter.All these data show that the degree of contamination caused by industrial activity of the Burrel Cr-smelter is severe, although no Cr(VI) was detected in soil water extractions nor in the surface or groundwater where concentrations were < 0.01 mg/kg.     

U-Pb zircon and Rb-Sr whole-rock dating of low-grade metasediments example: Montagne Noire (Southern France)

Three detrital, Proterozoic zircon suites extracted from siltstones progressively metamorphosed between chlorite- and staurolite-grade independently date the major Caledonian metamorphism within the gneiss dome of the Montagne Noire (Southern France). From this, the following conclusions concerning U-Pb systematics of zircons in low-, medium- and highgrade metamorphic rocks can be drawn:

1. Temperatures of at most 350–400 °C are sufficient to open U-Pb systems of metamict zircons or domains within zircons.
2. The observed open U-Pb system behaviour during metamorphism of the host rocks was found to be due to a low-temperature recrystallisation of highly radiation damaged zircon lattices, probably enhanced by high concentrations of fluid phases in the dehydrating rock volumes.
3. Recrystallisation of metamict zircons under low temperatures causes maximum U-Pb ages for the thermal climax of metamorphism of medium-and high-grade metamorphic rocks, as annealing and accompaning closing of U-Pb systems took place before the maximum temperatures of metamorphism were reached.
4. Low-temperature recrystallisation of old — generally Proterozoic—zircons can readily help to explain the fact that the numerous zircon suites from ancient shield areas yield “lower intercept ages” which are not correlated to any known geological event. Thus, either a weak thermal pulse, not necessarily registered by the mineral assemblage of the host rock, and/or elevated temperatures during burial in the crust might supply enough energy for a structural reordering and simultaneous lead loss of at least the most disordered lattice domains.

In contrast to the U-Pb zircon method, no unambiguous dating of the Caledonian main metamorphism was possible using the Rb-Sr whole-rock technique for phyllites and mica schists sampled in the same metamorphic profile from which the zircon samples were taken. The scatter of data points can best be explained by their rotation around a probable Caledonian isochron. This rotation very probably took place during the later Hercynian orogeny, not significantly affecting the slope of the least square regression line through the scattered data points.     

Erosion, sedimentation and engineering geological problems in the DaDu river valley, China

Reaches with very thick deposits alternate with deeply incised reaches in the DaDu river valley. The river sediments are described and a number of ¹⁴C dates are given. The deposits are alluvium, Pleistocene slope-wash deposits, marginal moraines and beds of fluvio-lacustrine origin. The valley development is explained as the result of neotectonic movement and glacial aggradation. From the point of view of water-power development, three different types of valley can be distinguished, each with its own consequences for hydraulic engineering works.     

Organic matter of the Mulhouse Basin, France: a synthesis

The lower Oligocene evaporite sequence of the Mulhouse Basin (France) contains organic matter-rich marl deposits. These marls display an overall cyclic variation of sedimentation rate, organic carbon content, hydrogen index and selected molecular parameters over a 30 m thick stratigraphic interval. The integration of all sedimentological and geochemical parameters has allowed the reconstruction and characterization of the paleoenvironment of deposition. The marls were deposited in a perennial lake that was at times connected to the sea. Two organic facies end members could be assigned to a lake stage with a marine connection and a lake stage that received dominantly continental water input. The overall stratigraphic variation in the organic matter content is interpreted to reflect the adaptation of the Oligocene flora to the changing paleoclimate and environmental conditions.     

Classifying chalk microtextures: Sedimentary versus diagenetic origin (Cenomanian–Santonian,Paris Basin,France)

Microtexture describes the type of particles and their arrangement in matrix samples at scanning electron microscopy scale. Although a microtexture classification exists for micritic limestone, it cannot be directly applied to chalk. This study therefore proposes a classification of chalk microtextures and discusses the origin of microtexture variability. Chalk was sampled at thirteen spatio‐temporal locations along the coastline of northern France (Cenomanian–Santonian). Four criteria are defined to describe, characterize and determine chalk matrix microtexture: (i) mineralogical content; (ii) biogenic fraction; (iii) micritic fraction; and (iv) cement fraction. From these criteria, two major groups are defined: Pure Chalk Microtexture Group, with seven classes, and Impure Chalk Microtexture Group, divided into two subgroups: Argillaceous Microtexture with four classes and Siliceous Microtexture with two classes. Microtexture variability is related both to initial sedimentation and to diagenesis. Sedimentological conditions (for example, climate and distance from shore) affect chalk composition (carbonate content and type of insoluble particles), thus influencing microtexture. Changes in Pure Chalk Microtexture are the result of increasing diagenetic intensity. This classification can also be used to characterize the microtexture of subsurface chalk reservoirs. Reservoir quality depends on the petrophysical and mechanical properties of reservoir rocks, which can be better understood by exploring their sedimentary and diagenetic history, revealed by the study of chalk microtexture variability.     

Correlation of reefal Oxfordian episodes and climatic implications in the eastern Paris Basin (France)

Oxfordian reefal episodes of Lorraine and Burgundy have a long time been considered as contemporaneous. Biostratigraphic data and sequential evolutions peculiar to each region indicate their structural autonomy during Oxfordian times. A north‐south‐oriented well‐logging transect shows that, during the Middle Oxfordian, a shallow reefal platform developed in Lorraine while thin deeper deposits occurred in Burgundy. In spite of their different ages, reefal episodes of Middle Oxfordian in Lorraine and Upper Oxfordian in Burgundy exhibit a broadly similar vertical evolution of coral communities. During the Late Oxfordian, the contemporaneous occurrence of a diversified assemblage in the Burgundy region, a colder coral assemblage characterized by eurytopic genera and the decrease in seawater isotopic temperatures in Lorraine can be explained by a shift in trophic conditions, a climatic change related to structural rearrangements in this strategic place and a modification of oceanic circulations between the arctic and the Tethyan regions.     

The protection of karst water resources: the example of the Larzac karst plateau (south of France)

Wide karst plateaus extend in the carbonate rocks of the Grands Causses area, north of Montpellier (south of France). They are surrounded by a hard rock base that feeds important rivers, such as the Tarn River and tributaries, and crosses the plateaus creating deep gorges. The Larzac plateau, the most southern, makes a link with the Mediterranean region. It is traversed by one of the main national roads and another main road under construction from Clermont-Ferrand to Montpellier and Spain. The karst water resource of the plateau, from springs, is used as a water supply for the Millau area (30,000 inhabitants); but it also recharges surface rivers, mainly during the summer and fall when the water level is low, in a region that is well known for water recreation activities, for fish farming and, above all, for sheep farming and Roquefort cheese production. The fundamental question was should the karst and its water resource be fully protected by strict regulations (for example as a nature reservation) in land-use management of the plateau based upon the knowledge of its hydrogeological functioning and its karst structure? Decisions, concerning the ～500-km² area were elaborated from detailed hydrogeological studies, which included natural and artificial tracing, analysis of karst aquifer functioning, landscape analysis, and risk assessment and mapping. Recommendations were proposed to local and regional decision makers to define what were the preferences in terms of water resource protection and water quality restoration. Following such an approach in a karst area is not easy for hydrogeologists or for decision makers. In non-karstic regions, protection zones currently extend over small areas of a few square kilometers, which can be easily placed under the control of a small municipality. In the present example, the main water supplies are two springs that recharge areas that extend respectively over 100 and 110?km². Included are several municipalities, some of which use them for their water supply, whereas others are concerned with pollution risks and land management projects. The recent French Water Act, which considers water as a common heritage, allows for general management by all the users, and it deals with the water and the terrain in which it flows. The regulation tools seem very well suited to karst region management. However, time is needed to educate users and decision makers, and with the help of karst scientists, to work together in a framework that is larger than the usual municipal limits.     

Estimation of runoff distribution within river systems: Application to the Lena Basin (Siberia)

A channel account approach is proposed to estimate longitudinal changes in runoff along large river systems. This new method provides a quantitative basis for describing the fluvial transport of suspended particulate material and dissolved substances. This method includes an evaluation of basic elements of water balance in separate sections of the river network and subsequent correction of channel accounting equations for the entire system using a maximum likelihood principle. To calculate water discharges of tributaries that have no hydrological information, structural analysis of river network is performed. This approach provides less error in comparison with traditional methods of estimating lateral inflow. The method is used to trace water discharge with increasing distance along the Lena river basin and to evaluate the contribution of geologically and lithologically uneven sub-basins in water discharge formation during a summer low water period.