Legacies from three former manufactured-gas plants: impacts on groundwater quality

Groundwater contamination due to accidental releases of mono- and polycyclic aromatic compounds (MAHs and PAHs) from decommissioned manufactured-gas plants is an ongoing and litigious problem. The MAHs and PAHs are derived from coal tar, which was a by-product of the gas-manufacturing process. While originally designed to contain coal tar, the manufactured-gas plant structures that remain today have often degraded over time and are not completely leak-proof. Over a period of many years, subsurface water has seeped into and out of the structures, resulting in groundwater contamination. This was particularly true once the tops of the structures were removed. In this study, process-based simulations were conducted to estimate the groundwater-quality impacts of accidental releases of dissolved naphthalene (C₁₀H₈) from the sites of three former manufactured-gas plants. The results from one-dimensional, transient, unsaturated, near-surface fluid-flow and solute-transport simulations served as input to three-dimensional saturated subsurface fluid-flow and solute-transport simulations. The simulation results and sensitivity analysis reported here indicate that accidental releases of naphthalene had significant, negative impacts on groundwater quality at each of the three sites. Electronic Publication     

Geological impacts on groundwater pollution: a case study in Khuzestan Province

The main aims of this study were to examine the sources of pollution with an emphasis on geogenic sources and to predict the groundwater quality with reasonable accuracy. For this purpose, factor analysis/principal component analysis and partial least squares regression were used to analyze a data set of groundwater quality containing 17 parameters measured at 45 different sampling wells in Andimeshk Aquifer during 2006–2013 time period. Factor analysis identified three factors, which were responsible for the data structure explaining 78.3 % of the total variance of the data set. There were various sources of groundwater contamination, based on factor analysis, in which geological formations next to agricultural activities had the most influential effects. Partial least squares regression could predict the quality of groundwater according to the value of water quality index. The amounts of R-squared (0.79) and MSE (0.21) using seven PLS components showed that this method has been successful in the prediction of water quality in the study area.     

Physicochemical and biological interfacial interactions: impacts on soil ecosystem and biodiversity

Soil is a vital biological habitat, which is of primary importance in determining and regulating biological activity and biodiversity. Therefore, it is Earth’s most important resource in sustaining both belowground and aboveground biological activities. Biodiversity versus landscape diversity and land use practices in multifunctional landscapes have been addressed. Humans have so manipulated nature that few locations in the world remain without human influence, causing unforeseen changes in ecosystem continuously and biodiversity. Among the environmental compartments, about 90 % of environmental pollutants are bound with soil particles. The soil-bound pollutants may be released to the soil solution through physical, chemical and biological interfacial interactions and pose a threat to biodiversity and ecosystem integrity. These interfacial interactions are especially important in the rhizosphere, where the kinds and concentrations of biomolecules are different from the bulk soil because of intense biological activity. These biomolecules affect biogeochemical processes, soil microbial ecology, nutrient and contaminant dynamics, abiotic and biotic factors, and soil biodiversity through allelopathic interactions. Soil interfacial interactions under different pedogenic processes and anthropogenic activity in relation to belowground biodiversity and the impact on aboveground biodiversity, productivity and integrity should be an important and exciting area of science for years to come.     

Present groundwater status in Egypt and the environmental impacts

This article is an attempt to give a brief review on the status of groundwater studies in Egypt, their results, and the present plans for groundwater development that are usually based on the hydrogeological characteristics of the groundwater resources as well as on the environmental control of the discharge area.In terms of groundwater hydrology, Egypt can be divided into the following groundwater provinces: (1) the Western Desert, (2) the Eastern Desert, (3) the Nile Valley including the delta, (4) the Sinai Peninsula, (5) the Northern Coastal Zone, and (6) Wadi El-Natrun.The studies of volume and nature of groundwater and the environmental impact studies that were carried out in each of these provinces differed according to the importance given to development of projects in areas of interest and to the availability of funds. Recent studies and the surveys conducted for groundwater hydrological research by local and international organizations are described separately for each province. Special reference is made to groundwater hydro-geological setting, groundwater resources evaluation, and present and future utilization. The New Valley is the largest Egyptian irrigated agricultural development project that is solely dependent on groundwater resources. An outline showing its nature, objective, and size is included as an example of groundwater development.     

Optimizing groundwater monitoring systems for landfills with random leaks under heterogeneous subsurface conditions

Landfills are one of the most common human activities threatening the natural groundwater quality. The landfill may leak, and the corresponding plumes may contaminate an area, entailing costly remediation measures. The objective of the installation of monitoring systems at landfill sites is to detect the contaminant plumes before they reach the regulatory compliance boundary in order to enable cost-effective counter measures. In this study, a classical decision analysis approach is linked to a stochastic simulation model to determine the optimal groundwater monitoring system given uncertainties due to the hydrogeological conditions and contaminant source characteristics. A Monte Carlo approach is used to incorporate uncertainties. Hydraulic conductivity and the leak location are the random inputs of the simulation model. The design objectives are to: (1) maximize the detection probability, (2) minimize the area of contamination at the time of detection, and (3) minimize the total cost of the monitoring system. A synthetic test case based on a real-world case in the Netherlands is analyzed. The results show that monitoring systems located close to the source are optimal except for the cases with very high unit installation and sampling cost and/or very cheap unit remediation.     

Helium, carbon dioxide and oxygen soil gases: Small-scale variations over fractured ground

To investigate the control on small-scale variation of He in soil gas exercised by minor fracturing, shallow surveys have been carried out over a cave system formed along an approximately orthogonal set of fractures in Devonian limestone in southwest England. The possibilities that He variation could be related to deep-seated, major fractures or hidden mineralisation, and that other soil gases may also be affected by minor fracturing were assessed by contemporary surveys for CO₂ and O₂. Comparisons of soil gas values with variations in electrical apparent resistivity were also carried out. Location of fractures with direct connection to the cave system was determined by spiking the cave atmosphere with He and then resurveying after equilibration.The results for CO₂ and O₂ show anomalies of low magnitude (with respect to atmospheric concentrations), and although they display an antithetic relationship, this is generally poor. There is also no strong correlation with the results of the He surveys either before or after spiking, or with the apparent resistivity values. Moreover, anomalies in CO₂ + O₂ do not support the pattern of variation shown by the individual gases. These negative results suggest the absence of deep-seated fractures or hidden mineralisation, and show that CO₂ and O₂ values are independent of minor fracturing. The origin of the variation is attributed to bacteriological productivity.He soil gas concentrations were obtained as disequilibrium values relative to Field Atmospheric Air (ΔHe/ppb-FAA). Positive ΔHe values were generally found to correlate with areas of thin, dry soil cover, enhancement occurring along fracture lines. Negative ΔHe values were also found to correlate with fracture lines, but in these areas the fractures are overlain by a thick soil cover with a high moisture content. It is considered that distinctions can be drawn between water-conducting and dry fractures, and that negative ΔHe values are likely only to be encountered with shallow soil gas samples. Results of spiking with He show a clear distribution of enhanced values along the set of orthogonal fractures, irrespective of the sign of the natural He anomaly. It is considered, therefore, that major deep-seated fractures may result in positive He anomalies superimposed upon negative ΔHe values. This implies that He anomalies must always be related to a local datum value. It is concluded that resolution of interacting variables in the interpretation of soil gas data is facilitated by integrated soil gas surveys.     

The impacts of pasture- and manure-spreading on microbial groundwater quality in carbonate aquifers

Hydrogeological and microbiological research is in progress to analyze the interaction between groundwater and microbial pollutants, produced by pasture and/or manure spreading, in the areas of different carbonate aquifers of southern Italy. Several springs and wells were studied, and the precipitation, the discharge, the groundwater level and the classic microbial indicators of pollution were monitored weekly or daily. The experimental results show that the pasture and the manure spreading produced microbial contamination of the groundwater, even if runoff infiltration in swallow holes does not exist. The time dependence of microbial contamination shows a series of peaks irregularly distributed, related to the precipitation that produce effective infiltration.     

Modelling climate-change impacts on groundwater recharge in the Murray-Darling Basin, Australia

A methodology is presented for assessing the average changes in groundwater recharge under a future climate. The method is applied to the 1,060,000 km² Murray-Darling Basin (MDB) in Australia. Climate sequences were developed based upon three scenarios for a 2030 climate relative to a 1990 climate from the outputs of 15 global climate models. Dryland diffuse groundwater recharge was modelled in WAVES using these 45 climate scenarios and fitted to a Pearson Type III probability distribution to condense the 45 scenarios down to three: a wet future, a median future and a dry future. The use of a probability distribution allowed the significance of any change in recharge to be assessed. This study found that for the median future, climate recharge is projected to increase on average by 5% across the MDB but this is not spatially uniform. In the wet and dry future scenarios the recharge is projected to increase by 32% and decrease by 12% on average across the MDB, respectively. The differences between the climate sequences generated by the 15 different global climate models makes it difficult to project the direction of the change in recharge for a 2030 climate, let alone the magnitude.     

GIS支持下人类活动对地下水动态影响的定量分析

应用地球动力学原理分析和研究了人类活动对水资源变化的影响,提出可将人为作用影响作为一个综合性的抽象指数,通过求取其它因素的变化利用余差法反求得到的计算思路.借助于GIS技术,建立了度量人为作用对地下水动态影响的通用数学模型,并用实例进行了验证,计算结果与实际情况相符,表明所提的方法是可行的.     

Remote sensing of soil moisture: implications for groundwater recharge

Remote sensing provides information on the land surface. Therefore, linkages must be established if these data are to be used in groundwater and recharge analyses. Keys to this process are the use of remote sensing techniques that provide information on soil moisture and water-balance models that tie these observations to the recharge. Microwave remote sensing techniques are used to map the spatial domain of surface soil moisture and to monitor its temporal dynamics, information that cannot be measured using other techniques. The physical basis of this approach is presented with examples of how microwave remote sensing is utilized in groundwater recharge and related studies. Electronic Publication     

Analysis of impact of outfalls on surrounding soil and groundwater environment

With certain outfalls in Baoding as an example and in combination with test results of soil and water samples taken from both sides of such outfalls, the organic contamination compounds influence on the surrounding soil and groundwater environment was analysed, the distribution features of the main organic contamination in soil and groundwater in different depth were discussed, and the vertical and longitudinal migration rule of all kinds of main organic contamination compounds in soil and groundwater in the sewage irrigation area was studied.     

Climate-induced hydrological impacts on the groundwater system of the Pingtung Plain,Taiwan

The Pingtung Plain is one of the most important groundwater-resource areas in southwestern Taiwan. The overexploitation of groundwater in the last two decades has led to serious deterioration in the quantity and quality of groundwater resources in this area. Furthermore, the manifestation of climate change tends to induce the instability of surface-water resources and strengthen the importance of the groundwater resources. Southwestern Taiwan in particular shows decreasing tendencies in both the annual amount of precipitation and annual precipitation days. To effectively manage the groundwater resources of the Pingtung Plain, a numerical modeling approach is adopted to investigate the response of the groundwater system to climate variability. A hydrogeological model is constructed based on the information from geology, hydrogeology, and geochemistry. Applying the linear regression model of precipitation to the next two decades, the modeling result shows that the lowering water level in the proximal fan raises an alarm regarding the decrease of available groundwater in the stress of climate change, and the enlargement of the low-groundwater-level area on the coast signals the deterioration of water quantity and quality in the future. Suitable strategies for water-resource management in response to hydrological impacts of future climatic change are imperative.

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Resumen La llanura Pingtung constituye uno de los recursos de aguas subterráneas más importantes en el Suroeste de Taiwan. La sobreexplotación de las aguas subterráneas en las dos últimas décadas ha dado lugar a un serio deterioro de la calidad y la cantidad de los recursos subterráneos en esta área. En particular el Suroeste de Taiwan muestra una tendencia decreciente en las cantidades de precipitación y en los días anuales de lluvia. Para gestionar de forma efectiva los recursos subterráneos en la Llanura Pingtung, se ha utilizado un modelo numérico aproximado para investigar la respuesta de las aguas subterráneas a la variabilidad climática. Un modelo hidrogeológico se construye a partir de la información geológica, hidrogeológica y geoquímica. Aplicando el modelo de regresión linear de la precipitación para las próximas dos décadas, el modelo resultante muestra que el descenso de los niveles de agua en el abanico proximal es alarmante, observándose el descenso del agua subterránea disponible en la presión del cambio climático, y el crecimiento del área de descensos de niveles de agua subterránea en la costa apunta a un deterioro de la cantidad y calidad del agua subterránea en el futuro. Se imponen pues, estrategias apropiadas para la gestión de los recursos hídricos en respuesta a los impactos hidrológicos del futuro cambio climático.

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Résumé La plaine de Pingtung est l’une des plus importantes zones de ressource en eau souterraine du Sud-Ouest de Taiwan. La surexploitation de l’eau souterraine durant les deux dernières décennies a conduit à une sérieuse détérioration de la quantité et de la qualité des ressources en eau souterraine dans cette zone. De plus, la manifestation des changements climatiques tend à induire une instabilité des ressources en eau souterraine et renforce l’importance des ressources en eau souterraine. Le Sud-Ouest de Taiwan montre, en particulier, des précipitations annuelles et des nombres annuels de jour de pluie à la baisse. Pour gérer efficacement les ressources en eau souterraine de la Plaine de Pingtung, une approche par modélisation numérique est adoptée pour étudier la réponse du système hydrogéologique aux variabilités climatiques. La construction du modèle hydrogéologique est basée sur les informations géologiques, hydrogéologiques et géochimiques. En appliquant le modèle de régression linéaire aux précipitations pour les deux prochaines décades, le résultat de la modélisation montre que la baisse du niveau d’eau atteint un état alarmant au regard de la décroissance des eaux souterraines disponibles et la contrainte du changement climatique, tandis que l’extension de la zone de niveau bas des eaux souterraines à la cote indique une détérioration de la quantité et de la qualité de l’eau dans le futur. Des stratégies convenables pour la gestion des ressources en eau souterraine en réponse aux impacts hydrologiques de futurs changements climatiques sont impératifs.

     

Potential impacts of climate change on groundwater levels on the Kerdi-Shirazi plain,Iran

It is important to predict how groundwater levels in an aquifer will respond to various climate change scenarios to effectively plan for how groundwater resources will be used in the future. Due to the overuse of groundwater resources and the multi-year drought in the Kerdi-Shirazi plain in Iran, some land subsidence and a drop in groundwater levels has taken place, and without active management, further degradation of the groundwater resource is possible under predicted future climate change scenarios in the country. To determine the potential impacts of climate change on groundwater levels in the region, the groundwater model GMS was coupled with the atmospheric circulation model HADCM3 using scenarios A1B, A2 and B1 for the period 2016–2030. The results of the climate modelling suggest that the Kerdi-Shirazi plain will experience an increase in minimum temperature and maximum temperature of, respectively, between 0.03 and 0.47, and 0.32–0.45 °C for this time period. The results of the groundwater modelling suggest that water levels on the Kerdi-Shirazi plain will continue to decline over the forecast period with decreases of 34.51, 36.57 and 33.58 m being predicted, respectively, for climate scenarios A1B, A2 and B1. Consequently, groundwater resources in the Kerdi-Shirazi plain will urgently need active management to minimize the effects of ongoing water level decline and to prevent saltwater intrusion and desertification in the region.     

Impact of polluted canal water on adjacent soil and groundwater systems

Received, 12 May 1999 · Accepted, 2 August 1999     

Environmental impacts of groundwater overdraft: selected case studies in the southwestern United States

The southwestern United States—this papers study region—is home to large urban centers and features a thriving agro-industrial economic sector. This region is also one of the driest in North America, with highly variable seasonal and inter-annual precipitation regimes and frequent droughts. The combination of a large demand for usable water and semi-arid climate has led to groundwater overdraft in many important aquifers of the region. Groundwater overdraft develops when long-term groundwater extraction exceeds aquifer recharge, producing declining trends in aquifer storage and hydraulic head. In conjunction with overdraft, declines in surface-water levels and streamflow, reduction or elimination of vegetation, land subsidence, and seawater intrusion are well documented in many aquifers of the southwestern United States. This work reviews case studies of groundwater overdraft in this region, focusing on its causes, consequences, and remedial methods applied to counter it.     

雨季苏打盐渍土地区土壤水-地下水转化规律研究

通过野外定位观测,分析了苏打碱土土壤水和地下水的转化规律。微地貌格局是制约水分迁移的主要因素,并由此形成了土壤水-地下水转化的特殊模式。雨季,坡地土壤(苏打碱土)的整个土层含水率变化不显著,地表径流为水分迁移的关键环节;洼地土壤(盐化草甸土)成为地表水和地下水转化的通道,大量洼地积水垂直下渗,补给地下水。运用Vensim对土壤水-地下水的转化过程进行了模拟,结果与观测数据基本一致。     

Potential approaches to the management of third-party impacts from groundwater transfers

Groundwater extraction can have varied and diffuse effects. Negative external effects may include costs imposed on other groundwater users and on surrounding ecosystems. Environmental damages are commonly not reflected in market transactions. Groundwater transfers have the potential to cause spatial redistribution, concentration, and qualitative transformation of the impacts from pumping. An economically and environmentally sound groundwater transfer scheme would ensure that marginal costs from trades do not exceed marginal benefits, accounting for all third-party impacts, including those of a non-monetary nature as well as delayed effects. This paper proposes a menu of possible management strategies that would help preclude unacceptable impacts by restricting transfers with certain attributes, ideally ensuring that permitted transfers are at least welfare-neutral. Management tools would require that transfers limit or reduce environmental impacts, and provide for the compensation of financial impacts. Three management tools are described. While these tools can limit impacts from a given level of extraction, they cannot substitute for sustainable overall withdrawal limits. Careful implementation of transfer limits and exchange rates, and the strategic use of management area boundaries, may enable a transfer system to restrict negative externalities mainly to monetary costs. Provision for compensation of these costs could be built into the system.