Age limit and age underestimation using different OSL signals from lacustrine quartz and polymineral fine grains

As part of a systematic palaeohydrological reconstruction of lake level fluctuations during the Last Glacial Maximum, a transect of cores from ancient Lake Xinias in central Greece has already been studied with respect to pollen, sediment and mineral magnetic analyses. The chronology was based on ¹⁴C AMS dating of terrestrial plant macrofossil remains from peat and clayey peat (Palaeogeog. Palaeoclimatol. Palaeoecol. 158 (2000) 65). This site thus provides an opportunity for the comparison of fine grain optically stimulated luminescence (OSL) ages of water–lain sediments with an independent chronology. We present here infrared (IR), post-IR blue and blue OSL characteristics of the fine grain sediments from Lake Xinias and a preliminary comparison with independent ages. The equivalent doses based on the IR results are about 40% of those based on post-IR blue stimulation, which in turn are 10–15% below those based on quartz OSL. We discuss the ages derived from the 3 signals in terms of the independent chronology, and draw conclusions about initial bleaching of the quartz and feldspar components, and the reliability of the post-IR blue signal as a chronometer.     

旧石器遗址强烈化学风化沉积物细粒混合矿物的光释光信号特征及其测年应用

中国南方地区一些旧石器考古遗址的沉积物因遭受强烈化学风化而粒径较细、长石含量低,难以单独提取长石颗粒进行测年。本研究利用从湖南省北部赤山岛枫树嘴旧石器遗址剖面第2、第3和第4考古层位采集的3个沉积物样品中提取的细粒混合矿物,尝试对其红外释光（IRSL）信号进行研究。实验表明,虽然长石IRSL信号很弱,但仍可以测得信噪比足够高的红外激发后高温红外激发释光（post-IR IRSL）信号。与此同时,样品存在明显的红外激发后蓝光释光（post-IR OSL）信号,并且样品的IRSL与post-IR OSL信号均以快组分为主,这为该地区沉积物利用长石光释光信号定年提供了新的可能。鉴于长石IRSL信号较弱,根据剂量恢复实验结果,本研究采用post-IR IRSL SAR法（50℃红外激发后270℃高温红外激发,pIRIR270℃）进行等效剂量测量,同时也应用post-IR OSL SAR法定年进行比较。实验结果表明,细粒混合矿物的pIRIR270℃等效剂量分别为418.8±13.2 Gy、562.3±18.2 Gy和694.8±17.9 Gy,相对应的post-IR OSL SAR等效剂量结果为345.0±29.4 Gy、409.6±33.7 Gy和424.7±32.2 Gy。假设强烈化学风化未对沉积物的剂量率造成很大影响,基于长石pIRIR270℃信号的释光年龄为89±6 ka、118±8 ka和152±9 ka,比前人所得的石英OSL SAR法年龄老30%~55%（约20~55 ka）。通过对比不同测量条件下获得的等效剂量值来评估长石IRSL信号是否存在晒退问题,没有发现长石post-IR IRSL信号存在晒退不完全的证据。根据本研究post-IR IRSL SAR法测年结果,赤山岛枫树嘴旧石器遗址似阿舍利技术类型的石器出现在倒数第二次冰期（MIS 6）后期至末次间冰期（MIS 5）前期,比湖南道县福岩洞现代人类牙齿化石年龄（80~120 ka）稍老。作为似阿舍利技术石器制造者的赤山岛古人与福岩洞现代人的关系将是我国旧石器时代考古学和古人类学研究的一个重要课题。

     

Bleaching of the post‐IR IRSL signal: new insights for feldspar luminescence dating

Post‐infrared (pIR) stimulated luminescence dating of sedimentary feldspar largely avoids the effects of anomalous fading that affect conventional infrared stimulated luminescence (IRSL) dating. However, optical resetting of pIR signals is more difficult than resetting the conventional IRSL signal, which may undermine the crucial assumption that pIR signals were effectively bleached upon deposition and burial of sediment grains. In this study, we quantify the bleaching properties of several pIR signals on various samples using laboratory‐simulated bleaching in full sunlight and water‐attenuated sunlight. Our data show that bleaching is most efficient under full spectrum conditions for all pIR signals and that pIR signals measured at elevated temperature are increasingly harder to bleach than IR and pIR signals measured at low temperature (e.g. IR at 50°C). All bleaching curves exhibit a very slow and steady decrease, indicating that a fixed un‐bleachable residual level cannot be reached within the 11 days of solar simulator exposure undertaken here. We show that the magnitude of a laboratory‐determined residual dose depends on the adopted bleaching protocol and cannot be used as a proxy for the dose that remains in the sample at the time of burial (remnant dose). Our data emphasize the importance of finding a balance between sufficient signal stability and a minimized contribution of a remnant dose when using pIR procedures for feldspar luminescence dating.     

A detailed post‐IR IRSL dating study of the Niuyangzigou loess site in northeastern China

In this study, we report standard quartz SAR OSL and post‐IR infrared (IR) stimulated luminescence (post‐IR IRSL; pIRIR₂₉₀) measurements made on sand‐sized quartz and K‐feldspar extracts from the loess‐palaeosol sequence at Niuyangzigou in northeastern China. The quartz OSL characteristics are satisfactory. Extensive pIRIR_50,290 dose recovery tests were performed by adding doses on top of the natural dose. We found that dose recovery ratios improve significantly when the test dose ranges between ~15 and ~80% of the total dose, and good dose recovery (within ±5% of unity) can be obtained up to ～800 Gy. Otherwise, the dose recovery ratio deviates from unity. The D_e values also depend on the test dose size and so we conclude that the effect of test dose size should be routinely considered in pIRIR dating. First IR stimulation plateau pIRIR₂₉₀ results are compared with multiple elevated temperature ‐pIRIR (MET‐pIRIR) data. It appears that the low temperature MET‐pIRIR data are strongly affected by poor dose recovery, but this is not the case for the pIRIR₂₉₀ results. Natural signal measurements at the highest (first IR) stimulation temperature on a sample expected to be in field saturation suggest that ~10% signal loss occurs in pIRIR signals. Long‐term laboratory bleaching experiments (>80 days) show that a constant (or very difficult to bleach) residual pIRIR₂₉₀ signal is reached after ~300 h, corresponding to a dose of 6.2±0.7 Gy. Quartz OSL and feldspar pIRIR_50,290 ages are in good agreement at least back to c. 70 ka. Beyond this the quartz ages begin to underestimate but the feldspar ages are in agreement with the expected Last Interglacial age palaeosol.     

Stability of fine‐grained TT‐OSL and post‐IR IRSL signals from a c. 1 Ma sequence of aeolian and lacustrine deposits from the Nihewan Basin (northern China)

We tested the suitability of the fine‐grained quartz (4–11 μm) Optical Stimulated Luminescence (OSL) and thermally‐transferred OSL (TT‐OSL), and the fine‐grained polymineral (4–11 μm) post‐infrared IRSL (post‐IR IRSL or pIRIR) signals for dating samples from aeolian‐lacustrine deposits from the Xiaochangliang archaeological profile in the Nihewan Basin, China; these deposits include material from the Jaramillo subchron (c. 1.0 Ma). In the upper aeolian section, the OSL and pIRIR₂₉₀ ages are consistent with each other, and show that the upper 8.8 m was deposited between c. 0.3 and c. 140 ka. The luminescence ages indicate a major discontinuity in deposition between the aeolian and the older lacustrine deposits. Below this hiatus at 9.4 m (i.e. in the lacustrine sediments) all three signals are found to be in field saturation (no further systematic increase in burial dose with depth) despite the TT‐OSL signal (apparent mean burial dose ~880 Gy) being well below saturation on the laboratory growth curve. This is in contrast to the pIRIR₂₉₀ signal, which saturates in the field at a level consistent with laboratory saturation. This results in a practical upper limit to the measured burial dose of ~900 Gy (2D₀). Thus for the TT‐OSL and pIRIR₂₉₀ signals, the upper limits for dating lacustrine deposits are <260 ka and c. 240 ka, respectively. These results have major implications for the appropriate future application of these signals. The ages of our lacustrine samples cannot be regarded as necessarily accurate ones; nevertheless, these ages provide the first long series absolute chronology for study of local palaeolithic and geomorphic evolution history aside from the magnetostratigraphical results available before this research.     

Chronology of a lacustrine core from Lake Linggo Co using a combination of OSL, 14C and 210Pb dating: implications for the dating of lacustrine sediments from the Tibetan Plateau

Vast palaeolakes once occupied the Qinghai‐Tibetan Plateau (TP). Analyses of the sedimentary records of these lakes could potentially provide an extensive dating archive. Many previously constructed age‐depth models simulating lacustrine cores have been principally based on radiocarbon (¹⁴C) dating. However, such dating could have been hampered by the so‐called ‘lake reservoir effect’ (LRE) and the reworking of lakebed sediments, resulting in inaccurate ¹⁴C age‐depth models and limiting interpretations of existing lacustrine palaeoclimatic records. Lake Linggo Co is located on the central TP, in one of the coldest and most arid regions of Tibet. We dated a 9.87‐m‐long lacustrine core extracted from the lakebed at a water depth of ~60 m using a combination of ²¹⁰Pb, ¹⁴C and optically stimulated luminescence (OSL) techniques. Some ¹⁴C ages showed significant age reversals; all the ¹⁴C ages were much older than the ²¹⁰Pb and OSL ages for the same depths. This could possibly be attributed to the presence of old, inherited carbon, causing the inherited ¹⁴C age to appear unstable during the deposition period. The ²¹⁰Pb and OSL ages were roughly concordant, and were also consistent with the stratigraphical succession. We therefore suggest that ¹⁴C dating may, on its own, be inadequate for accurate dating of lacustrine sediment sites on the TP, and that the OSL method should also be applied in order to evaluate the reliability of any ¹⁴C ages. With this approach, we constructed an age‐depth model, revealing sedimentation rates of 1.7, 0.8, 6.8 and 0.6 mm a⁻¹ between 0–1.9, 1.9–4.2, 4.2–4.4 and 4.4–9.4 ka, respectively.     

Synchronous pattern of moisture availability on the southern Tibetan Plateau since 17.5 cal. ka BP – the Tangra Yumco lake sediment record

A possible asynchronicity of the spatial and temporal moisture availability on the Tibetan Plateau has been a controversial subject of discussion in recent years. Here we present the first attempt to systematically investigate possible spatial and temporal variations in moisture availability by examining two lakes, Tangra Yumco and Nam Co, on an east–west transect on the southern Tibetan Plateau using identical proxies for palaeoenvironmental reconstruction. In this study, an independent record from Tangra Yumco was analysed applying a multi‐proxy approach to reconstruct variations in moisture availability since the Lateglacial. Results were subsequently compared with previously published records from Nam Co and additional records from Tso Moriri (northwestern Himalaya) and Naleng Co (southeastern Tibetan Plateau). Our results show that Tangra Yumco was at least partially ice covered prior to 17.1 cal. ka BP. A temperature rise after 17.1 cal. ka BP probably resulted in thawing of the permafrost. At 16.0 cal. ka BP moisture availability increased, representing an initial monsoonal intensification. Warmer conditions between 13.0 and 12.4 cal. ka BP and cooler conditions between 12.4 cal. ka BP and the onset of the Holocene reflect the Bølling‐Allerød and Younger Dryas. At the onset of the Holocene moisture availability rapidly increased, with moisture highest prior to 8.5 cal. ka BP when temperatures were also highest. After 8.5 cal. ka BP the moisture availability gradually decreased and showed only minor amplitude variations. These findings are consistent with the records from large lakes like Nam Co, Tso Moriri, and Naleng Co, revealing a synchronous pattern of moisture availability on the southern Tibetan Plateau.     

Luminescence dating of Würmian (Weichselian) proglacial sediments from Switzerland: methodological aspects and stratigraphical conclusions

Proglacial deposits from three independently dated sites in the Swiss lowlands were investigated by optically stimulated luminescence (OSL) to test the reliability of the applied dating approach. Using the single-aliquot regenerative-dose technique applied to small aliquots of quartz revealed that in all samples the OSL signal was differentially bleached prior to deposition. A statistical approach is introduced to extract the fraction of aliquots in which the OSL was apparently set to zero at deposition. The statistical treatment provided OSL ages in good consistency with independent age control. However, some uncertainties remain with this approach, since it is difficult to assess the natural scatter caused by dose-rate inhomogeneity exactly. The available data set implies that glaciers reached the Swiss lowlands prior to about 25 000 yr ago. Previously published data from other sites demonstrate that glaciers were present in lowland Switzerland up to about 20000 yr ago. Furthermore, one OSL date of about 70 000 yr for proglacial outwash sediments points to the presence of the Rhône Glacier in the Lake Neuchâtel area during the middle part of the Late Pleistocene.     

Highstands in the interior of the Qinghai–Tibetan Plateau since the last interglacial: evidence from grain‐size analysis of lacustrine core sediments in Zabuye Salt Lake

Highstands in the Marine Isotope Stage (MIS) 3 based on ¹⁴C dating in the Qinghai–Tibetan Plateau (QTP) are widely documented. Recent records from shoreline sediments dated using U‐series and/or optically stimulated luminescence (OSL), however, reveal that the highstands originally dated in MIS 3 should now be considered to fall in MIS 5. This paper provides new evidence from the interior of the QTP, based on the grain‐size from a continuous lake core in the Zabuye Salt Lake, to verify the MIS 5 highstand in the QTP. Grain‐size analysis of the core sediments also distinguishes two other highstands in MIS 3 and MIS 2, respectively. The MIS 5 highstand is considered as the maximum lake level since the Last Interglacial, as cored sediments contain very low values of Median Diameter (Md) during MIS 5. Compared with the discontinuous records from lake shorelines sediments, the grain‐size records from the continuous lake centre core sediments provide a more complete dataset to infer lake level variations, and make it possible to make wider palaeoclimatic and palaeoenvironmental interpretation. In the interior of the QTP, highstands might have continued into cold climate periods due to the reduced evaporation rates in the latter. The influence of the moisture‐bearing southerly‐shifted Westerly wind pathway may also have contributed to the highstands in the glacial period. Copyright © 2015 John Wiley & Sons, Ltd.     

Optically Stimulated Luminescence (OSL) dating of glacial sediments from Arctic Russia - depositional bleaching and methodological aspects

Optical dating has been extensively used for stratigraphical correlation in the reconstruction of Eurasian ice-sheet dynamics and palaeoenvironmental changes during the last glaciation. In recent terrestrial studies in Arctic Russia, Optically Stimulated Luminescence (OSL) is the main chronological tool, and has been used across the whole of the Eurasian north. We report new OSL ages obtained on glaciofluvial and glaciolacustrine sediments from the Arkhangelsk and Taymyr regions of Arctic Russia and discuss the characteristics of the quartz OSL signal in terms of its saturation limit, variability among samples from the same location, and initial signal resetting in different depositional environments. It is shown that effect of partial bleaching in our mainly Weichselian samples is trivial because: modern analogues are well zeroed; there is good agreement between OSL and ¹⁴C ages in young samples; and skewness in the dose distribution of relatively older samples is mainly due to varying shapes of the growth curves. The overall reliability of the OSL ages from Arctic Russia, when compared with the limited independent age controls available, appears to be good.     

Age of the Pomeranian ice‐marginal position in northeastern Germany determined by Optically Stimulated Luminescence (OSL) dating of glaciofluvial sediments

Lüthgens, C., Böse, M. & Preusser, F. 2011: Age of the Pomeranian ice‐marginal position in northeastern Germany determined by Optically Stimulated Luminescence (OSL) dating of glaciofluvial sediments. Boreas, 10.1111/j.1502‐3885.2011.00211.x. ISSN 0300‐9843 The Pomeranian ice margin is one of the most prominent ice‐marginal features of the Weichselian glaciation in northern Europe. Previous results of surface‐exposure dating (SED) of this ice margin disagree with established chronologies and ice retreat patterns, i.e. are much younger than previously expected. We crosscheck the age of the Pomeranian ice‐marginal position in northeastern Germany using single‐grain quartz Optically Stimulated Luminescence (OSL) dating of glaciofluvial sediments. OSL dating indicates an active ice margin between 20.1±1.6 ka and 19.4±2.4 ka forming outwash plains attributed to the Pomeranian ice‐marginal position. On the basis of these results, we suggest a critical reassessment of previous SED data available for the Pomeranian ice‐marginal position within their respective regional geomorphological contexts. From a process‐based point of view, SED ages derived from glacigenic boulders document the stabilization of the landscape after melting of dead ice and landscape transformation under periglacial conditions rather than the presence of an ice margin. SED indicates a first phase of boulder stabilization at around 16.4±0.7 ka, followed by landscape stabilization within the area attributed to the recessional Gerswalder subphase around 15.2±0.5 ka. A final phase of accumulation of glaciolacustrine and glaciofluvial sediments at around 14.7±1.0 ka documents the melting of buried dead ice at that time.     

Holocene evolution of the Indian Summer Monsoon inferred from a lacustrine record of Lake Wuxu,south‐east Tibetan Plateau

A continuous sediment record since 12.3 cal ka bp from Lake Wuxu (south‐eastern Tibetan Plateau) was investigated in terms of the Holocene evolution of the Indian Summer Monsoon. The molar C/N ratio and stable C isotope were used to identify the source of the organic matter as well as climate conditions. The evolution of Lake Wuxu was summarized wihtin two periods. During the first period (early to mid‐Holocene), the lake received increased fluvially transported materials, reflecting variation in the summer monsoon with solar insolation. The lake level declined and water residence time increased because of reduced river discharge during the second period (late Holocene) corresponding to a weakening of the summer monsoon. The organic material revealed a major contribution from lake primary productivity, which showed identical patterns with a high‐resolution isotope record from Dongge Cave, as well as total solar irradiance. Our record from Lake Wuxu indicates that the Holocene evolution of the Indian Summer Monsoon has been driven by the solar forcing at decadal/centennial to millennial time scales. Furthermore, an abrupt decline in the monsoon was detected at around 4.0 cal ka bp , which is probably caused by an increased frequency of EI Nino‐Southern Oscillation events. Copyright © 2019 John Wiley & Sons, Ltd.     

Predominance of even carbon-numbered n-alkanes from lacustrine sediments in Linxia Basin,NE Tibetan Plateau: Implications for climate change

This study reports the first observation of predominant even C-numbered n-alkanes from sediments in the continuous lacustrine-sedimentary section (Maogou) from the Late Miocene to the Early Pliocene (13–4.4 Ma) in the Linxia Basin, NE Tibetan Plateau. The n-alkanes showed a bimodal distribution that is characterised by a centre at n-C₁₆–n-C₂₀ with maximum values at n-C₁₈ and n-C₂₇–n-C₃₁ as well as at n-C₂₉. The first mode shows a strong even C-number predominance (OEP_16–20 0.34–0.66). In contrast, the second mode has a strong odd C-number predominance (OEP_27–31 1.20–2.45). Certain types of special autochthonous bacteria are a possible source for this distribution of even C-numbered n-alkanes in lacustrine sediments. These bacteria may have a high production rate in weak oxic–anoxic and arid depositional environments, in which a variety of geochemical parameters have recorded palaeoclimate change.     

Early formation of K-feldspar in shallow-marine sediments at near-surface temperatures (southern Israel): evidence from K-Ar dating

Authigenic K‐feldspar was investigated in two Albian to Turonian sections in Israel using K‐Ar and Ar‐Ar dating, X‐ray diffraction, scanning electron microscopy and chemical analysis. Both sections comprise a similar succession of shallow‐marine limestones, dolomites and marls, with some sandstone and shale beds of continental origin. The HCl‐insoluble residue fraction of the studied samples consists of clays, quartz, feldspars, goethite and trace amounts of heavy minerals. Most of the insoluble residues have a relatively high K‐feldspar content that has an adularia habit and is concentrated in the 4–7 µm size fraction. The authigenic origin of the K‐feldspar in the fine silt fraction is indicated by its high content relative to quartz, the uniform and idiomorphic shape of the crystals and its limited size range. Of the fine silt (4–7 or 4–10 µm) separates, 40% have ages that are similar to stratigraphic ages within the analytical and biostratigraphic errors. Ar‐Ar dating of a fine silt fraction with 94% K‐feldspar (4–10 µm, sample GYP 7) yields a plateau age identical to the total gas age and similar to the stratigraphic age. These results indicate that the K‐Ar age is not a mixture between detrital and late diagenetic K‐feldspar ages, but is rather an age of formation within a few million years after deposition. It is suggested that the early formation of the K‐feldspar was associated with dolomitization and was induced by residual brines as part of a reflux process.     

藏南羊卓雍错近代沉积物碳酸盐氧同位素特征及其环境意义

20世纪80年代以来气候变暖加剧,青藏高原冰川物质负平衡趋势增强,导致众多湖泊水位上升,但位于藏南地区的羊卓雍错,湖泊水位近年来却呈现出显著的波动下降趋势。本研究通过对羊卓雍错YZYC2沉积岩芯(长23 cm)进行²¹⁰Pb活度测定,建立沉积物的年代序列;分析公元1989年以来沉积物全样碳酸盐含量及其氧同位素组成,并结合现代气象及水文观测数据,揭示羊卓雍错沉积物碳酸盐氧同位素(δ¹⁸O)的环境意义及其对气候变化的响应过程与机制。结果表明,YZYC2岩芯碳酸盐矿物以自生成因的文石为主,其含量变化范围为23.3 % ~39.7 %,δ¹⁸O值变化范围为-4.7 ‰ ~-3.2 ‰。沉积物碳酸盐δ¹⁸O值总体呈波动上升趋势,较好地记录了近30年来羊卓雍错湖泊水位变化。1989~2019年羊卓雍错水位变化总体由降水与蒸发共同作用下的湖区有效湿度变化主导,同时也可能受到羊湖电站运行的影响。

     

Identification of Permian palaeowind direction from wave-dominated lacustrine sediments (Lodève Basin, France)

Lacustrine environments are an excellent indicator of continental palaeoclimate. In particular, the sedimentary record of waves in lakes may be used to constrain atmospheric palaeocirculation. Wave ripples have been identified in a Permian lacustrine basin (the Salagou Formation, 260–250 Ma, Lodève Basin) located in the southern French Massif Central, part of the western European Hercynian mountain chain. Wave ripple patterns are interpreted with regards to hydrodynamics and water palaeodepth. It is shown that, in the case of the Salagou Formation, wave ripple orientations were controlled by the direction of the prevailing palaeowind. The Late Permian wind blew from between north and 20° east of north, possibly over several millions of years and certainly throughout the period of deposition of about 2000 m of strata in the Lodève Basin. Permian lacustrine sedimentation is widespread and well preserved on the Earth's surface and so wave ripple data may help constrain numerical modelling of the Earth's past climates, especially with regards to Permian times outside of desert regions.     

Optical dating of sand wedges and ice‐wedge casts from Qinghai Lake area on the northeastern Qinghai‐Tibetan Plateau and its palaeoenvironmental implications

Sand wedges and ice‐wedge casts in the Qinghai Lake area on the northeastern Qinghai‐Tibetan Plateau (QTP) occur within alluvial gravel or river terrace deposits. In this study, we report the results of quartz Optically Stimulated Luminescence (OSL) dating of the infill of five relict sand wedges and one ice‐wedge cast. Combining our dating results with previously published luminescence ages of permafrost wedges in the Qinghai Lake area, we show that sand/ice wedges formed at c. 62 ka, c. 45 ka and between 30 and 15 ka, and that the mean annual air temperature (MAAT) was depressed by at least ～3°C relative to present during the sand/ice‐wedge formation periods. This new work is partially corroborated by post‐LGM proxy records from lakes and aeolian deposits reported from the northeastern QTP. It also significantly extends the palaeoenvironmental record in the region in the period before the LGM, when other proxy records are rare, allowing a better understanding of the palaeoenvironmental conditions on the northeastern QTP.