Bemerkungen zu J. Georgi's meteorologischer Solarkonstanten

Summary It is shown thatLinke's definition of the «subzonal» solarconstant meets best the problems of the meteorologist.Georgi's «meteorological» solarconstant neglects waveregions very important in biology and in atmospheric heating and has to be rejected. The «astrophysical» solarconstant needs further knowledge of X-rays, radio and corpuscular radiation in units of energy.     

Zur Bildung von Artefakten und deren Vermeidung bei der Bestimmung leichtflüchtiger Halogenkohlenwasserstoffe in Wasser mittels Headspace-Gaschromatographie unter den Bedingungen der DIN 38407 Teil 5 (DEV-F5). Teil I: Bildung von Dehydrohalogenierungsprodukten aus gesättigten LHKW

Formation of Artefacts and its Suppression during the Determination of Volatile Halogenated Hydrocarbons in Water by Means of Headspace Gas Chromatography under the Standard Conditions of DIN 38407-F5. Part I: Formation of Dehydrohalogenation Products from Saturated Halogenated Hydrocarbons Under the conditions recommended by DIN 38407-F5 for the headspace gas-chromatographic determination of volatile halogenated organic substances in water (equilibration at 60…80°C for a least 60 min) several halocarbons are degraded by dehydrohalogenation resulting in the formation of unsaturated artefacts with one halogen atom less. Thus pentachloroethane and 1,1,2,2-tetrachloroethane are decomposed to form tetrachloroethylene and trichloroethylene, respectively. This leads to low results of the analytes and to false-positive detection of the reaction products. The unwanted degradation reactions can be reduced by decreasing the temperature and duration of equilibration, and they are completely suppressed by acidification of the samples.     

Volles Gewicht einer im Refraktionsmilieu gemessenen Grösse (Teil I)

Summary As regards the concept of complete weight p with which an observed quantity (e.g., the direction of theA–G net) should enter the net adjustment, according to Eq.(1), apart from the fundamental weight p ₀ ), determined by the number of repetitions, it should also contain the time parameter p_t according to Eq.(11), where c>1 is a constant, and t is the number of days of observation, and also the refraction factor p_r according to Eqs(17, 18), where q is the structural weight of the direction. The condition for being able to determine p_r with the directions is observation by means of the three-directional vertex method[2], because it is not possible to localize lateral refraction by angular methods. The theory of complete weight is in favour of observations with a high fundamental weight p ₀ which automatically yield higher values of t, and also of p_t. The introduction of the complete weight into the experimental directional net in Fig. 2 caused the mean value of the uneliminated refraction error to decrease from 0.24 to 0.12, the mean square error of the adjusted direction being 0.17. The value of the constant c was investigated and the method of determining the parameter p_r was derived also for lengths measured electro-optically. Mention is made of the effect of complete weights on the length adjustment of a net in[6].     

Zur Bildung von Artefakten und deren Vermeidung bei der Bestimmung leichtflüchtiger Halogenkohlenwasserstoffe in Wasser mittels Headspace-Gaschromatographie unter den Bedingungen der DIN 38407 Teil 5 (DEV-F5). Teil II: Überhöhte Trihalogenmethanbefunde in gechlortem Schwimmbeckenwasser

Formation of Artefacts and its Suppression during the Determination of Volatile Halogenated Hydrocarbons in Water by Means of Headspace Gas Chromatography under the Standard Conditions of DIN 38407-F5. Part II: Increased Trihalomethane Formation in Chlorinated Swimming-pool Water A comparison of two analytical standard procedures for the determination of trihalomethanes (THM) in water (headspace gas chromatography and pentane extraction/gas chromatography) yielded strongly differing results. Under the conditions recommended by the German Standard Method DIN 38407-F5 (60…80°C for at least 60 min) degradation of thermo-labile chlorination products occurs resulting in elevated THM concentrations. The reactions involved are partly pH-dependant, and these can be suppressed by sample acidification. The degradation of trihalogen acetic acids, however, can only be influenced by minimizing the equilibration time and temperature. Other intermediate chlorination products (haloacetonitriles) are also degraded to THM after preceding hydrolysis to the corresponding carboxylic acids. Comparative results obtained with a purge and trap method at ambient temperature, i.e. without thermal stress during the enrichtment step, are lower than with static headspace GC but still high in comparison to the pentane extraction method. Presumably volatile THM-precursors are also trapped and subsequently decomposed upon thermal desorption from the trap. As the static headspace GC is the most rational method of LHKW determination available, the recommended experimental sample handling conditions should be modified in a way that deterioration reactions are reduced as far as possible.     

Zum Umweltverhalten von Fluortensiden. Teil 2. Untersuchung der biochemischen Abbaubarkeit

In continuation of a publication on the behaviour of fluorotensides in aqueous solution there were tested four selected fluorotensides, among them a noniononic ethoxylated substance and three anion-active substances, in two different equipment with respect to their biochemical degradability. The BOD₅, the potassium permanganate consumption, the dry matter contents and the loss on ignition as well as the dehydrogenase test were used as parameters for judging the degradation behaviour. In all the four cases a high biochemical stability was found, so that they must be classified into the group C “biochemically not degradable or difficult to degrade” in agreement with the results found, according to the water pollutants catalogue.     

Zur Charakterisierung suspendierter Wasserinhaltsstoffe. Teil 2: Erste Ergebnisse der praktischen Anwendung der Analysenmethoden

Nachdem in Teil 1 (Schultz ) die Bedeutung der Feststoffe für den Betrieb von Wasseraufbereitungsanlagen und Analysenmethoden zur Charakterisierung der Feststoffe diskutiert wurden, enthält Teil 2 die Ergebnisse von Untersuchungen an einem ausgewählten Vorfluter. Verschiedene Analysenmethoden werden getestet, miteinander verglichen und ihre Eignung zur Einschätzung des Leistungsverhaltens der Aufbereitungsanlagen überprüft.     

Das Typische Isolinien Grundfeld und Seine Anwendung (2. Teil)

Ohne Zusammenfassung