Zircon and whole-rock Nd-Pb isotopic provenance of Middle and Upper Ordovician siliciclastic rocks, Argentine Precordillera

Graptolite‐bearing Middle and Upper Ordovician siliciclastic facies of the Argentine Precordillera fold‐thrust belt record the disintegration of a long‐lived Cambro‐Mid Ordovician carbonate platform into a series of tectonically partitioned basins. A combination of stratigraphic, petrographic, U‐Pb detrital zircon, and Nd‐Pb whole‐rock isotopic data provide evidence for a variety of clastic sediment sources. Four Upper Ordovician quartzo‐lithic sandstones collected in the eastern and central Precordillera yield complex U‐Pb zircon age spectra dominated by 1·05–1·10 Ga zircons, secondary populations of 1·22, 1·30, and 1·46 Ga, rare 2·2 and 1·8 Ga zircons, and a minor population (<2%) of concordant zircons in the 600–700 Ma range. Archaean‐age grains comprise <1% of all zircons analysed from these rocks. In contrast, a feldspathic arenite from the Middle Ordovician Estancia San Isidro Formation of the central Precordillera has two well‐defined peaks at 1·41 and 1·43 Ga, with no grains in the 600–1200 Ma range and none older than 1·70 Ga. The zircon age spectrum in this unit is similar to that of a Middle Cambrian quartz arenite from the La Laja Formation, suggesting that local basement rocks were a regional source of ca 1·4 Ga detrital zircons in the Precordillera Terrane from the Cambrian onwards. The lack of grains younger than 600 Ma in Upper Ordovician units reinforces petrographic data indicating that Ordovician volcanic arc sources did not supply significant material directly to these sedimentary basins. Nd isotopic data (n = 32) for Middle and Upper Ordovician graptolitic shales from six localities define a poorly mixed signal [ɛ_Nd(450 Ma) = −9·6 to −4·5] that becomes more regionally homogenized in Upper Ordovician rocks (−6·2 ± 1·0; T_DM = 1·51 ± 0·15 Ga; n = 17), a trend reinforced by the U‐Pb detrital zircon data. It is concluded that proximal, recycled orogenic sources dominated the siliciclastic sediment supply for these basins, consistent with rapid unroofing of the Precordillera Terrane platform succession and basement starting in Mid Ordovician time. Common Pb data for Middle and Upper Ordovician shales from the western and eastern Precordillera (n = 15) provide evidence for a minor (<30%) component that was likely derived from a high‐μ (U/Pb) terrane.     

Palaeoenvironmental significance of rounded pyrite in siliciclastic sequences of the Late Archaean Witwatersrand Basin: oxygen‐deficient atmosphere or hydrothermal alteration?

Petrographic and sulphur isotope studies support the long‐held contention that rounded grains of pyrite in siliciclastic sequences of the Late Archaean Witwatersrand Supergroup originated as placer grains. The grains are concentrated at sites where detrital heavy minerals are abundant within quartz‐pebble conglomerates and quartzose sandstones. Depositional sites with abundant pyrite are: (1) within the matrix of bar‐type, clast‐supported conglomerates; (2) on scoured or winnowed surfaces; and (3) on stratification planes. The grains are internally compact or porous, with truncation of internal structure at outer margins indicating fragmentation and rounding of pyritic source‐rocks during erosion and sediment transport. A large range in textures reflects source‐rock lithologies, with known varieties linked to sedimentary‐hosted diagenetic pyrite, volcanic‐hosted massive sulphide deposits and hydrothermal pyrite. Laser ablation sulphur isotope analysis of pyrite reveals a broader range in δ³⁴S values (? 5·3 to + 6·7‰) than that of previously reported conventional bulk‐grain analyses (? 1 to + 4‰). Rounded pyrite from the Steyn Reef has significant variation in δ³⁴S values (? 4·7 to + 6·7‰) that establishes heterogeneous sulphur compositions, with even adjacent grains having diverse isotopic signatures. The heterogeneity supports a placer origin for rounded pyrite. Euhedral pyrite and pyrite overgrowths which are undoubtedly authigenic have restricted δ³⁴S values (? 0·5 to + 2·5‰), are chemically distinct from rounded pyrite and are probably the products of metamorphism or hydrothermal alteration. The placer origin of rounded pyrite indicates that pyrite was a stable heavy mineral during erosion and transport in the early atmosphere. Its distribution in three sequences (Witwatersrand Supergroup, Ventersdorp Contact Reef and Black Reef), and in other sequences not linked to Witwatersrand‐type Au‐U ore deposits, implies deposition of redox‐sensitive detrital heavy minerals during the Late Archaean. Consequently, rounded grains of detrital pyrite are strong indicators of an oxygen‐poor atmosphere. While not confirming a placer origin for gold in Witwatersrand Au‐U ore deposits, the palaeoenvironmental significance of rounded pyrite negates its link to hydrothermal mineralization.     

The Numidian Sequence between Guelma and Constantine (Eastern Tell,Algeria)*

The Numidian Sequence represents one of the main tectono-stratigraphic units involved in the geological evolution of the Maghrebian orogen during the Upper Oligocene-Lower Miocene. Geo-structural aqalysis led to the reconstruction of tectonc-stratigraphic units and recognition of two main tectonic phases (Eocene and Lower Miocene). Sedimentological analysis of the studied sections has resulted in the distinction of arenaceous and conglomeratic facies generated by debris flows or high-density turbidity currents on a submarine slope, present within the pelitic-arenaceous and arenaceous-pelitic sequences which also contain slumped units in places. Previous and new micropalaeontological data indicate Late Oligocene-Early Burdigalian ages for the Numidian sequences of the Constantine Mountains. On the basis of petrographic study the Numidian rocks can be classified as poorly sorted quartzarenites containing siliciclastic matrix. The overall petrographic data indicate that the Continental intercalaire (Hoggar, Tassili and Fezzan) and Series Pharusienne (Hoggar and Eglab) are possible supply areas for the Numidian quartz.     

Diagenesis and formation water chemistry of Triassic reservoir sandstones from southern Tunisia

The fluvial Triassic reservoir subarkoses and arkoses (2409·5–2519·45 m) of the El Borma oilfield, southern Tunisia, were subjected to cementation by haematite, anatase, infiltrated clays, kaolinite and K-feldspar at shallow burial depths from meteoric waters. Subsequently, basinal brines controlled the diagenetic evolution of the sandstones and resulted initially in the precipitation of quartz overgrowths, magnesian siderite, minor ferroan magnesite and anhydrite. The enrichment of siderite in ¹²C isotope (δ¹³C_PDB= - 14·5 to - 9‰) results from derivation of carbon from the thermal decarboxylation of organic matter. During further burial, the precipitation of dickite and pervasive transformation of kaolinite into dickite occurred, followed by the formation of microcrystalline K-feldspar and quartz, chlorite and illite, prior to the emplacement of oil. Present day formation waters are Na-Ca-Cl brines evolved by the evaporation of seawater and water/mineral interaction and are in equilibrium with the deep burial (≤ 3·1 km) minerals. These waters are suggested to be derived from the underlying Silurian and Devonian dolomitic mudstones.     

Diagenetic processes in cretaceous sandstones from occidental Brazilian Equatorial Margin

Despite a great interest in Brazilian Equatorial Margin exploration, very little was published on the diagenesis of sandstones from that area. A wide recognition petrographic study was performed to identify the major diagenetic processes that impacted the porosity of Lower Cretaceous sandstones of the Pará-Maranhão, São Luís, Bragança-Viseu and Barreirinhas basins. Arkoses from the Pará-Maranhão Basin show neoformed or infiltrated clay coatings, mica replacement and expansion by kaolinite and vermiculite, and precipitation of grain-replacive and pore-filling quartz, kaolinite, albite, chlorite, calcite, dolomite, siderite, pyrite and titanium oxides. Compaction, quartz and calcite cementation were the main porosity-reducing processes. Barreirinhas Basin lithic arkoses and subarkoses display clay coatings, compaction of metamorphic fragments into pseudomatrix, and precipitation of grain-replacive and pore-filling kaolinite, quartz, albite, chlorite, calcite, dolomite, TiO₂ and pyrite. The main porosity-reducing processes were calcite cementation in the subarkoses, and compaction and quartz cementation in lithic arkoses. Quartzarenites from this basin were early- and pervasively cemented by dolomite. Arkoses and lithic arkoses of the São Luís and Bragança-Viseu basins show clay coatings, pseudomatrix from mud intraclasts compaction, and precipitation of pore-filling and grain-replacive kaolinite, vermiculite, smectite, quartz, albite, chlorite, illite, calcite, dolomite, hematite, TiO₂ and pyrite. Compaction of mud intraclasts and dissolution of feldspars and heavy minerals were the main porosity-modification processes. These preliminary results may contribute to the understanding of the spatial and temporal distribution of the diagenetic processes and their impacts on the porosity of the sandstones from these basins.     

Petrofacies,provenance, and paleocurrent analysis of Pachmarhi sandstone (Early Triassic), Satpura basin,Central India

The Satpura Gondwana basin hosts a ～5 km thick siliciclastic succession that unconformably overlies the Precambrian basement. The Gondwana sequence in this basin starts from Early Permian (Talchir Formation) to Lower Cretaceous (Jabalpur Formation). The aim of this study is to (1) identify the source rock (provenance) for Early Triassic Pachmarhi sediments in the Satpura Gondwana succession and (2) to understand the relative role of tectonics and climate in determining the sandstone composition. These sandstones are medium to coarse-grained, moderately to moderately well sorted, subangular to subrounded, of moderate sphericity, and composed of several varieties of quartz, feldspar, rock fragments, and micas. Petrographically, the Pachmarhi sandstones are mostly quartzarenite and subarkose. The petrofacies in Qt–F–L and Qm–F–Lt triangular diagrams show that the bulk of the Pachmarhi was derived from continental (cratonic) source, especially from craton interior. Petrofacies, together with paleocurrent data, suggest that Pachmarhi Formation was deposited by a network of braided river system, which flowed dominantly from southeast to northwest. The study suggests that the sediments were mostly derived from Precambrian granites, gneiss, and metasedimentary basement rocks straddling the southern margin of the basin. Paleocurrent data also corroborates this contention.     

Petrology of lower-middle Miocene Zoumi Flysch Fm. (Mesorif sub-domain,Rif belt,Morocco): first evidence of mixed mode provenance and geodynamic setting

The Zoumi Basin was generated in a collisional tectonic setting during the Lower-Middle Miocene. The syn-orogenic flysch deposits of the basin have been well investigated by petrographic and geochemical studies to characterize the composition, source to sink routing system, and tectonic setting of the Zoumi flysch. Forty-three sandstone samples and 45 mudstone samples have been gathered from six measured stratigraphic sections. These samples have been analyzed using XRD, XRF, inductively coupled plasma-mass spectrometry (ICP-MS) for mudrocks and petrographic investigation for sandstones. The Lower-Middle Miocene Zoumi flysch is defined as sublitharenites and quartzarenites according to mineralogical content. Detrital grains are commonly subangular to subrounded, poorly sorted, and rich in quartz grains. Point counting modal analysis leads to craton interior and recycled orogen provenance with significant first-cycle sediment supply and low sedimentary recycling. Several chemical ratios (Al₂O₃/TiO₂, La/Th, Cr/Th, Th/Sc, Zr/Sc) as well as chondrite-normalized REE patterns with flat HREE, LREE enrichment, and negative Eu anomaly suggest a dominant felsic rock sources. However, V-Ni-La*4, V-Ni-Th*10, and Th/Sc vs. Cr/Th plots do not exclude a mafic supply source nature which is evidenced by numerous ophiolitic outcrops scattered throughout the Mesorifan Subdomain (Mesorifan Ophiolitic Suture Zone).     

Recycling and chemical weathering in tectonically controlled Mesozoic–Cenozoic basins of New Zealand

Sedimentation in molasse basins is controlled by tectonics, however, recycling and chemical weathering play a critical role in the compositional evolution of a sedimentary succession. The Cretaceous to Pliocene molasse deposits of Central Otago, New Zealand are excellent examples of tectonically related deposits that were governed by the effects of chemical weathering and recycling. Preserved in fault-controlled basins floored by flysch deposits of the Otago Schist, the clastic successions contain ubiquitous unconformities and lithofacies consistent with alluvial, fluvial and lacustrine depositional settings. Textural analysis of Central Otago sandstones establishes a general quartz enrichment and increased mixing of angular and well-rounded quartz varieties up-section, consistent with a history of sediment recycling. Rare earth element (REE) patterns, which reflect upper crustal compositions, are similar for the flysch-type Otago Schist (Permian–Early Cretaceous), a palaeo-weathering profile, and the overlying molasse deposits. The development of quartz arenites is also consistent with high degrees of chemical weathering, and erosion of the schist basement, which contains numerous quartz veins. Although recycling has occurred, SiO₂ and TiO₂ do not consistently show a negative correlation over time. This reflects erosion of previously deposited quartz-rich sediment and the Otago weathering profile, which produced an inverse stratigraphy. CIA values range from 52 for lithic-rich, coarse-grained sandstones and polymictic conglomerate matrices, to 93 for coarse-grained to pebble-rich quartz arenites. Individual samples were split into finer- and coarser-grained pairs (<2·5φ and 2·5 to −1φ) and were analysed separately. The results show that finer-grained samples contain higher REE abundances and less SiO₂, but the coarser-grained Miocene–Pliocene samples have higher CIA values than their finer-grained counterparts. These coarse-grained deposits are quartz-rich and plot erratically on tectonic discrimination diagrams, implying that using SiO₂-poor samples is more reliable for geochemical analysis. Overall, the petrographic and geochemical results indicate that the main factors controlling the composition of the Central Otago molasse deposits were source composition, chemical weathering and recycling. Studies of this nature can be conducted in Archaean tectonically controlled molasse basins that are affected by similar allocyclic factors.     

Mineral chemistry of tourmaline from Mashak Pahar,South Purulia Shear Zone (SPSZ), eastern Indian Shield

The area of investigation at and around Mashak Pahar, Bankura district, West Bengal, India comprises a number of rock types namely: granite gneiss, migmatized quartz tourmaline gneiss, quartz pebble conglomerate, ferruginous quartzite, quartz tourmaline veins (as veins) and graphite schists. Interestingly, the study area lies in the region extending South Purulia Shear Zone (～Tamar–Porapahar Shear Zone) which marks the boundary between two contrasting tectonic blocks of eastern India, namely, the Chhotanagpur Gneissic Terrane (CGC) to the north and Singhbhum Group of rocks to the south. The rocks of the study area are poly-phasedly deformed by three phases of folding, namely, F₁, F₂ and F₃. All the tourmalines are classified to be of ‘Alkali Group’. Chemistry of tourmalines from migmatized quartz tourmaline gneiss and those from quartz tourmaline veins are in conformity with their relation to (earthquake induced) shear system evolution in this terrain. In general, the compositional evolution of tourmaline during prograde metamorphism (～400°–730°C) has been supported by both petrographic and chemical evidences. Assessment of mineral–chemical data of constituent tourmaline grains clearly suggests compositional variations across zonal boundaries within tourmaline that was controlled by changing metamorphic milieu in this terrane. Field and petrographic evidences clearly indicate activation of earlier and later shears in this region accompanied by infiltration of boron and formation of zoned tourmaline crystals.     

Origin of Lower Cretaceous (‘Nubian’) sandstones of North‐east Africa and Arabia from detrital zircon U‐Pb SHRIMP dating

Lower Cretaceous sandstones of the type exposed in Israel, deposited over much of North Africa and Arabia as widespread sandstone sheets, typically are mineralogically and texturally mature. Previous petrographic examinations suggested that the Lower Cretaceous sandstones are at least partly a product of recycling and the present study supports this notion. The results of U‐Pb Sensitive High Resolution Ion Micro‐Probe (SHRIMP) dating of detrital zircons from the Lower Cretaceous section exposed in Israel indicate that they are dominated by detrital zircons of Neoproterozoic age, mainly concentrated in the 0·55 to 0·65 Ga interval, with various amounts of older (pre‐Neoproterozoic) zircons (of 0·95 to 1·10, 1·7 to 2·0 and 2·6 to 2·65 Ga age groups). The overall age signal is similar to detrital zircon age spectra previously obtained from the Cambrian–Ordovician sections of Israel and Jordan. Remarkably, the detrital zircon spectra remained almost unchanged for nearly 400 Myr. Thus, the most probable provenance of the Lower Cretaceous sandstone is the recycling of relatively proximal Palaeozoic sandstone. Since first unroofed from above pan‐African terranes closer to the secession of orogeny, the ensuing siliciclastics were recycled repeatedly throughout the Phanerozoic with little additional basement denudation. The Lower Cretaceous sandstone comprises quartz sand that was first eroded from above pan‐African orogens ca 400 Myr prior to deposition.     

Search for provenance of Oligocene Barail sandstones in and around Jotsoma,Kohima, Nagaland

Provenance of the Oligocene Barail sandstones has been ascertained by means of petrographic and heavy mineral studies. Petrography reveals an abundance of angular to sub-rounded monocrystalline, non-undulatory quartz followed by lithic fragments. The overall composition of sandstones matches with those of sublith-arenites. The heavy mineral suite of Barail sandstones displays rounded to sub-rounded as well as euhedral / angular grains of iron oxide, zircon, tourmaline, rutile, kyanite, sillimanite and staurolite in decreasing order of abundance. Petrography coupled with heavy mineral suite suggests for a mixed provenance dominated by a sedimentary source of recycled orogenic provenance in a foreland basin setup.     

Geochemistry of sedimentary rocks from Permian–Triassic boundary sections of Tethys Himalaya: implications for paleo-weathering,provenance, and tectonic setting

The geochemical characteristics of two sections—the Permian–Triassic boundary (PTB) Guryul Ravine section, Kashmir Valley, Jammu and Kashmir, India; and the Attargoo section, Spiti Valley, Himachal Pradesh, India—have been studied in the context of provenance, paleo-weathering, and plate tectonic setting. These sections represent the siliciclastic sedimentary sequence from the Tethys Himalaya. The PTB siliciclastic sedimentary sequence in these regions primarily consists of sandstones and shales with variable thickness. Present studied sandstones and shales of both sections had chemical index of alteration values between 65 and 74; such values reveal low-to-moderate degree of chemical weathering. The chemical index of weathering in studied samples ranged from 71 to 94, suggesting a minor K-metasomatism effect on these samples. Plagioclase index of alteration in studied sections ranged from 68 to 92, indicating a moderate degree of weathering of plagioclase feldspars. The provenance discriminant function diagram suggests that the detritus involved in the formation of present studied siliciclastic sedimentary rocks fall in quartzose sedimentary and felsic igneous provenances. These sediments were deposited in a passive continental margin plate tectonic setting according to their location on a Si₂O versus K₂O/Na₂O tectonic setting diagram.     

Geochemistry of Carboniferous Sandstones (Sardar Formation), East‐Central Iran: Implication for Provenance and Tectonic Setting

Geochemical analysis of sandstones from the Sardar Formation (from two stratigraphic successions) in east-central Iran were used for identification of geochemical characterization of sandstones, provenance and tectonic setting. Sandstones in the two lithostratigraphic successions have similar chemical compositions suggesting a common provenance. Bulk-rock geochemistry analysis of Carboniferous sandstones from Sardar Formation indicates that they are mainly quartz dominated and are classified as quartzarenites, sublitharenites and subarkoses, derived from acid igneous to intermediate igneous rocks. Discrimination function analysis indicates that the sandstones of Sardar Formation were derived from quartzose sedimentary provenance in a recycled orogenic setting. Also, major and trace elements in sandstones of Sardar Formation (e.g., K2O/Na2O vs. SiO2) indicate deposition in a stable passive continental margin (PM). Chemical index of alteration (CIA) for these rocks (> 65%) suggests a moderate to relatively high degree of weathering in the source area.     

Provenance of the Bosnian Flysch

Sandwiched between the Adriatic Carbonate Platform and the Dinaride Ophiolite Zone, the Bosnian Flysch forms a c. 3000 m thick, intensely folded stack of Upper Jurassic to Cretaceous mixed carbonate and siliciclastic sediments in the Dinarides. New petrographic, heavy mineral, zircon U/Pb and fission-track data as well as biostratigraphic evidence allow us to reconstruct the palaeogeology of the source areas of the Bosnian Flysch basin in late Mesozoic times. Middle Jurassic intraoceanic subduction of the Neotethys was shortly followed by exhumation of the overriding oceanic plate. Trench sedimentation was controlled by a dual sediment supply from the sub-ophiolitic high-grade metamorphic soles and from the distal continental margin of the Adriatic plate. Following obduction onto Adria, from the Jurassic–Cretaceous transition onwards a vast clastic wedge (Vranduk Formation) was developed in front of the leading edge, fed by continental basement units of Adria that experienced Early Cretaceous synsedimentary cooling, by the overlying ophiolitic thrust sheets and by redeposited elements of coeval Urgonian facies reefs grown on the thrust wedge complex. Following mid-Cretaceous deformation and thermal overprint of the Vranduk Formation, the depozone migrated further towards SW and received increasing amounts of redeposited carbonate detritus released from the Adriatic Carbonate Platform margin (Ugar Formation). Subordinate siliciclastic source components indicate changing source rocks on the upper plate, with ophiolites becoming subordinate. The zone of the continental basement previously affected by the Late Jurassic–Early Cretaceous thermal imprint has been removed; instead, the basement mostly supplied detritus with a wide range of pre-Jurassic cooling ages. However, a c. 80 Ma, largely synsedimentary cooling event is also recorded by the Ugar Formation, that contrasts the predominantly Early Cretaceous cooling of the Adriatic basement and suggests, at least locally, a fast exhumation.     

The effect of deformation on the TitaniQ geothermobarometer: an experimental study

We performed high strain (up to 47 %) axial compression experiments on natural quartz single crystals with added rutile powder (TiO₂) and ~0.2 wt% H₂O to investigate the effects of deformation on the titanium-in-quartz (TitaniQ) geothermobarometer. One of the objectives was to study the relationships between different deformation mechanisms and incorporation of Ti into recrystallized quartz grains. Experiments were performed in a Griggs-type solid-medium deformation apparatus at confining pressures of 1.0–1.5 GPa and temperatures of 800–1,000 °C, at constant strain rates of 1 × 10^?6 or 1 × 10^?7 s^?1. Mobility of Ti in the fluid phase and saturation of rutile at grain boundaries during the deformation experiments are indicated by precipitation of secondary rutile in cracks and along the grain boundaries of newly recrystallized quartz grains. Microstructural analysis by light and scanning electron microscopy (the latter including electron backscatter diffraction mapping of grain misorientations) shows that the strongly deformed quartz single crystals contain a wide variety of deformation microstructures and shows evidence for subgrain rotation (SGR) and grain boundary migration recrystallization (GBMR). In addition, substantial grain growth occurred in annealing experiments after deformation. The GBMR and grain growth are evidence of moving grain boundaries, a microstructure favored by high temperatures. Electron microprobe analysis shows no significant increase in Ti content in recrystallized quartz grains formed by SGR or by GBMR, nor in grains grown by annealing. This result indicates that neither SGR nor moving grain boundaries during GBMR and grain growth are adequate processes to facilitate re-equilibration of the Ti content in experimentally deformed quartz crystals at the investigated conditions. More generally, our results suggest that exchange of Ti in quartz at low H₂O contents (which may be realistic for natural deformation conditions) is still not fully understood. Thus, the application of the TitaniQ geothermobarometer to deformed metamorphic rocks at low fluid contents may not be as straightforward as previously thought and requires further research.     

Petrography and provenance of silicified early Archaean volcaniclastic sandstones, eastern Pilbara Block, Western Australia

Intense post-depositional alteration has profoundly affected sandstones in the volcanic portions of Early Archaean (3·5–3·3 Ga) greenstone belts. The mineralogy and bulk compositions of most grains have been completely destroyed by pervasive metasomatism, but grain textures are commonly well preserved. Consequently, microtextural information coupled with present alteration compositions as determined petrographically can be used to estimate original framework modes. Silicified Early Archaean volcaniclastic sandstones assigned to the Panorama Formation and Duffer Formation, Warrawoona Group, eastern Pilbara Block, Western Australia, were originally composed of volcanic (VRF) and sedimentary (SRF) rock fragments, volcanic quartz, feldspar, traces of ferromagnesian minerals and pumice. Only volcanic megaquartz remained stable during alteration. All other primary components were replaced by granular microcrystalline quartz (GMC) and sericite. In most areas, the sandstones were composed of dacitic to rhyolitic VRFs, now totally replaced by sericite-poor GMC and recognized by preserved microporphyritic textures. In a few areas, quartz-poor dacitic to andesitic(?) VRFs dominated the detrital assemblage. Minor SRFs and mafic VRFs, now replaced by GMC, are recognized on the basis of colour, internal structures, and internal textures, including skeletal, possible spinifex textures. Detrital feldspar is represented by blocky, sericite-rich grain pseudomorphs. A semi-quantitative point-count scheme, developed for the analysis of heavily altered sandstones, indicates the following primary detrital-mode ranges for Panorama arenites: quartz, 0–28%; feldspar, 0–28%, VRFs, 58–86%, and SRFs 0–25%. In about half the point-counted samples, feldspar could not be distinguished from rock fragments. In such cases, both were counted as one grain type, Lv', which makes up from 84 to 100% of the framework modes of these rocks. These sands were derived from a terrane composed largely of fresh felsic volcanic rocks and sediments, but locally including minor mafic, ultramafic, and sedimentary rocks. Much, but not all, of the felsic volcaniclastic sand represents reworked pyroclastic debris. There is no evidence for contributions from plutonic or metamorphic sources. The Panorama modal assemblage represents a provenance that is lithologically more restricted than that of Archaean greywackes and other siliciclastic units common in the sedimentary portions of these same Early Archaean greenstone belts and younger greenstone belts (3·0–2·7 Ga).     

Geochemistry of the sandstones of Punagarh basin: Implications for two source terranes and Arabian - Nubian connection of Aravalli craton?

Sandstones of Punagarh basin of Trans Aravalli region, NW Indian shield were analyzed for their major and trace element contents in conjunction with petrographic modes. The Punagarh basin comprises four formations (Sojat, Bambolai, Khamal and Sowania), amongst which the Sojat Formation in uncoformable contact with overlying formations, is significantly older and enjoys separate status as rest of the formations constitute Punagarh Group. Petrographic attributes suggest that Sojat sandstones contain distinct modal abundances like high content of quartz and low content of feldspar, mica, matrix, rock fragments and cement. In general there is a decrease in the average modal abundance of quartz and mica with concomitant increase of feldspar, chert and rock fragments from base to top in Punagarh sandstones. Sojat sandstones are also geochemically distinct as they possess high SiO₂/Al₂O₃, Th/U and Cr/Th ratios coupled with lowest Na₂O/K₂O ratio and Zr content, least fractionated LREE, more fractionated HREE and largest Eu* anomaly compared to Punagarh sandstones. The weathering indices suggest intense chemical weathering for Sojat sandstones and low to moderate for Punagarh sandstones. Compositionally all the sandstones of the Punagarh basin come under the category of quartzarenite. Compared to PAAS and UCC, both suite of sandstones are generally depleted in REE, HFSE (with exception of Zr, Hf and Ta), and enriched in ferromagnesian trace elements particularly Cr and Co. The chemical data indicate that the sediments were derived from the source(s) of mixed felsic - mafic composition, with the former being dominant. The source rocks were granites, TTG, basalts, and rhyolites. The Sojat sandstones owe their source form Archean crust while Punagarh sandstones got detritus from Mesoproterozic crust. Immobile element ratios and REE abundances of Sojat sandstones closely match with Paleoproterozoic metagreywackes of Ghana of African craton while Punagarh sandstones show near geochemical characteristic with Gogunda, Kumbalgarh and Vindhyan quartzites of Aravalli craton. This geochemical similarity of Sojat sandstones provides credence to the hypothesis that Trans–Aravalli region of India had been an integral part of Arabian - Nubian shield. The chemical data advocate the deposition of these sandstones in a tectonic setting comparable to modern back arc setting.     

Detrital zircon geochronology of the Speewah Group,Kimberley region,Western Australia: evidence for intracratonic development of the Paleoproterozoic Speewah Basin

Field observations integrated with new petrographic and sensitive high-resolution ion microprobe (SHRIMP) U–Pb age data for detrital zircons from the Paleoproterozoic Speewah Group of northern Western Australia provide evidence of depositional conditions, source of detritus, timing and evolution of the sedimentary rocks in the Speewah Basin. The Speewah Group is a 1.5 km-thick succession of poorly outcropping, predominantly siliciclastic rocks that preserve a fluviatile to marine, transgressive and regressive event. The Speewah Group unconformably overlies crystalline rocks of the Lamboo Province that were stabilised by the 1870–1850 Ma Hooper Orogeny, then accreted as the Kimberley region onto the North Australian Craton during the 1835–1810 Ma Halls Creek Orogeny. Unconformably overlying the Speewah Group is about 4 km of predominantly siliciclastic marine sedimentary rocks of the Kimberley Group in the Kimberley Basin. This study has detected a detrital zircon component within the Speewah Basin at 1814 ± 10 Ma, with a youngest zircon at 1803 ± 12 Ma (1σ) in fluviatile sandstones located beneath a volcaniclastic rock with magmatic zircons that have been dated at ca 1835 Ma. Previous studies proposed that the Speewah Basin developed as a retro-arc foreland basin during accretion of the North Australian Craton. We interpret the ca 1835 Ma zircons in the volcaniclastic rocks to be xenocrystic in origin. This new 20 million years younger maximum depositional age indicates that the Speewah Group in the Speewah Basin, similarly to the overlying Kimberley Group in the Kimberley Basin, developed in a post-orogenic setting on the North Australian Craton rather than in a syn-orogenic setting associated with the 1835–1810 Ma Halls Creek Orogeny.     

Petrography and geochemistry of Jumara Dome sediments,Kachchh Basin: Implications for provenance,tectonic setting and weathering intensity

In the Kachchh Mainland, the Jumara Dome mixed carbonate-siliciclastic succession is represented by the Jhurio and Patcham formations and siliciclastic-dominating Chari Formation （Bathonian to Oxfordian）. The Ju- mara Dome sediments were deposited during sea-level fluctuating, and were interrupted by storms in the shallow marine environment. The sandstones are generally medium-grained, moderately sorted, subangular to subrounded and of low sphericity. The sandstones are mineralogically mature and mainly composed of quartzarenite and subar- kose. The plots of petrofacies in the Qt-F-L, Qm-F-Lt, Qp-Lv-Ls and Qm-P-K ternary diagrams suggest mainly the basement uplift source （craton interior） in rifted continental margin basin setting. The sandstones were cemented by carbonate, iron oxide and silica overgrowth. The Chemical Index of Alteration values （73% sandstone and 81% shale） indicate high weathering conditions in the source area. Overall study suggests that such strong chemical weathering conditions are of unconformity with worldwide humid and warm climates during the Jurassic period. Positive correlations between A1203 and Fe203, TiO2, Na20, MgO, K20 are evident. A high correlation coefficient between A1203 and K20 in shale samples suggests that clay minerals control the major oxides, The analogous con- tents of Si, A1, Ti, LREE and TTE in the shale to PAAS with slightly depleted values of other elements ascribe a PAAS like source （granitic gneiss and minor mafics） to the present study. The petrographic and geochemical data strongly suggest that the studied sandstones/shales were deposited on a passive margin of the stable intracratonic basin.     

Provenance of sandstones from the Neoproterozoic Bombouaka Group of the Volta Basin,northeastern Ghana

The provenance and tectonic setting of sandstones from the Bombouaka Group of the Voltaian Supergroup, in the northeastern part of Ghana, have been constrained from their petrography and whole-rock geochemistry. Modal analysis carried out by point-counting sandstone samples indicates that they are quartz arenites. The index of compositional variability values and SiO₂/Al₂O₃, Zr/Sc, and Th/Sc values indicates that the sediments are mature. The sandstones are depleted in CaO and Na₂O. They are, however, enriched in K₂O, Ba, and Rb relative to average Neoproterozoic upper crust. These characteristics reflect intense chemical weathering in the source region as proven by high weathering indices (i.e., CIA, PIA, and CIW). In comparison with average Neoproterozoic upper crust, the sandstones show depletion by transition metals and enrichment by high field strength elements. They generally show chondrite-normalized fractionated light rare-earth element (LREE) patterns (average La_N/Sm_N = 4.40), negative Eu anomalies (average Eu/Eu* = 0.61), and generally flat heavy rare-earth elements (HREE) (average Gd_N/Yb_N = 1.13). The sandstones have La/Sc, Th/Sc, La/Co, Th/Co, Th/Cr, and Eu/Eu* ratios similar to those of sandstones derived from felsic source. Mixing calculations using the rare-earth elements (REE) suggests 48% tonalite–trondhjemite–granodiorite and 52% granite as possible proportions for the source of the sandstones. Both the petrographic and whole-rock geochemical data point to a passive margin setting for the sandstones from the Bombouaka Group.