Saline wetlands related to groundwater flows from low permeability Tertiary formations in the Somontano area of Huesca,Spain

Presence of groundwater flow in the ‘Somontano de Huesca’ Area, derived from low‐permeability detrital Tertiary rocks, is considered. A groundwater flow model is constructed for these Tertiary rocks. This model explains both water flow through them and the chemical characteristics of the water. Groundwater flow has clear surface manifestations: it causes wetlands (which are called ‘paules’ in the area) with sodic waters, it produces saline, sodic or alkaline soils, and it produces modifies the chemical composition of rivers in Somontano. Irrigation has increased the volume of filtered water, especially in the interfluve areas, causing the extension of the wetlands in the valley thalwegs, and also the greater movement of salts has increased the problems of saline and/or sodic soils in the area. Copyright © 2001 John Wiley & Sons, Ltd.     

Origin and evolution of closed depressions in central Belgium,European loess belt

Closed depressions (CDs) are lower lying areas where the sediment eroded from the surrounding soil surfaces draining towards the CD is trapped in the system. CDs have been reported in several regions of the European loess belt and are attributed either to natural processes (e.g. dissolution of subsurface horizons) or to human intervention (e.g. quarrying). Previous studies focussed mainly on cropland areas where, however, only few and largely filled in CDs remain. The objectives of this study were to i) assess the spatial distribution of CDs under forest and cropland, ii) to determine and compare the morphology of CDs under forest and under cropland, and iii) to determine the origin and age of these CDs under forest. In a study area located partly in ancient forest (13 km²) and partly in cropland (29 km²), a systematic survey revealed the presence of 71 CDs under forest (5·3 CD.km^?2) and 30 CDs under cropland (1 CD.km^?2). Comparison of their morphology showed that CDs under forest were significantly deeper, with steeper sidewalls and a smaller surface area because of the erosion and deposition processes acting on the CDs under cropland. By comparing CDs that had been under cropland for different time intervals, the rate of this morphological evolution could be reconstructed. Analysis of the soil stratigraphy of two representative CDs in the ancient forest area confirmed their origin as quarries. Most probably, calcareous loess was excavated since this soil horizon, about two to five meters thick, was completely absent within the CDs. Dating of the infilling of one CD by optically stimulated luminescence (OSL) shows that the CD filled in between the first century BC and the fourth century AD. This dating corresponds to the dating of sediment deposits in nearby, human‐induced gullies that were attributed to an agricultural land use phase between the 18th century BC and the third century AD.     

Mapping groundwater quality variables using PCA and geostatistics: a case study of Bajo Andarax,southeastern Spain

Abstract

A case study is presented for the application of statistical and geostatistical methods to the problem of estimating groundwater quality variables. This methodology has been applied to the investigation of the detrital aquifer of the Bajo Andarax (Almería, Spain). The use of principal components analysis is proposed, as a first step, for identifying relevant types of groundwater and the processes that bring about a change in their quality. As a result of this application, three factors were obtained, which were used as three new variables (VI: sulphate influence; V2: thermal influence; and V3: marine influence). Analysis of their spatial distribution was performed through the calculation of experimental and theoretical variograms, which served as input for geostatistical modelling using ordinary block kriging. This analysis has allowed a probabilistic representation of the data to be obtained by mapping the three variables throughout the aquifer for each sampling point. In this way, one can evaluate the spatial and temporal variation of the principal physico-chemical processes associated with the three variables VI, V2 and V3 implicated in the groundwater quality of the detrital aquifer.     

Numerical modelling of the potential effects of a dam on a coastal aquifer in S. Spain

This study presents the results of a three‐dimensional variable‐density numerical modelling of the Motril‐Salobreña coastal aquifer and the possible effects of the entry into service in May 2005 of the Rules Dam, located just 17 km from the coast. Present parameters of the Motril‐Salobreña aquifer show that the system's conditions are very similar to a natural regime. The dam will substantially alter aquifer recharge, as the entry flow through the alluvial sediments of the Guadalfeo River will be entirely cut off or drastically reduced. Different scenarios reproducing the possible evolution of the aquifer under operation of the Rules Dam have been modelled. In most cases, results indicate that the conditions of the aquifer would worsen, with a general advance of the freshwater–saltwater interface. The area with most risk of saltwater intrusion is the old mouth of the Guadalfeo River, where the mixing zone could advance 1200 m inland. It is proposed that maintaining a 5–6 Mm³ year^?1 ‘ecological flow’ in the Guadalfeo River could prevent this saline advance. This application demonstrates that variable‐density models are potentially useful tools for estimating the effects of dams on the hydrodynamic and hydrochemical conditions of a coastal aquifer. Copyright © 2009 John Wiley & Sons, Ltd.     

Bridging the gap between field data and global models: current strategies in aeolian research

Modern global models of earth‐atmosphere‐ocean processes are becoming increasingly sophisticated but still require validation against empirical data and observations. This commentary reports on international initiatives amongst aeolian researchers that seek to combine field‐based data sets and geomorphological frameworks for improving the quality of data available to constrain and validate global models. These include a second iteration of the Dust Indicators and Records from Terrestrial Marine Palaeoenvironments (DIRTMAP2) database, the Digital Atlas of Sand Seas and Dunefields of the World and a new geomorphology‐based land surface map produced by the QUEST (Quantifying Uncertainties in the Earth System) Working Group on Dust. Copyright © 2010 John Wiley & Sons, Ltd.     

On the importance of river hydrodynamics in simulating groundwater levels and baseflows

Research to date affirmed the key role of stream–aquifer interactions in integrated water resources management. The importance of river hydrodynamics on the spatial and temporal behaviour of groundwater was, however, not yet fully investigated. In contrast to the common approach where topography-based estimates of riverbed elevation may lead to inappropriate discretization and constant river stages, this study couples a fully hydrodynamic and one-dimensional river model to a two-dimensional catchment hydrological model. The surface and subsurface runoff, groundwater, and river components are integrated into a single modelling framework. The coupled model was applied to a medium sized catchment in Belgium with three model setups, in which the level of detail of representation of river hydrodynamics varies. Further model iterations were carried out for the most exhaustive setup to assess the importance of the bi-directional interactions between model components. Results show that higher details of river hydrodynamics help to improve the simulation of time-averaged groundwater levels. However, the impacts were not that clear for the time-varying groundwater levels. Moreover, visual and statistical model performance evaluation indicates a strong enhancement of the coupled models compared to the output from the hydrological model with respect to river discharge observations at catchment outlet and at internal stations. It also reveals the impact of river hydrodynamics on groundwater discharges when the most detailed setting delivered the highest performance among the three coupled models.     

Impact of soil compaction and irrigation practices on salt dynamics in the presence of a saline shallow groundwater: An experimental and modelling study

Soil salt accumulation is a widespread problem leading to diminished crop yield and threatening food security in many regions of the world. The soil salinization problem is particularly acute in areas that lack adequate soil water drainage and where a saline shallow water table (WT) is present. In this study, we present laboratory-scale column experiments, extending over a period of more than 400 days that focus on the processes contributing to soil salinization. We specifically examine the combined impact of soil compaction, surface water application model and water quality on salt dynamics in the presence of a saline shallow WT. The soil columns (60 cm height and 16 cm diameter) were packed with an agricultural soil with bulk densities of 1.15 and 1.34 g/cm⁻³ for uncompacted and compacted layers, respectively, and automatically monitored for water content, salinity and pressure. Two surface water compositions are considered: fresh (deionized, DI) and saline water (~3.4 mS/cm). To assess the sensitivity of compaction on salt dynamics, the experiments were numerically modelled with the HYDRUS-1D computer program. The results show that the saline WT led to rapid salinization of the soil column due to capillarity, with the salinity reaching levels much higher than that at the WT. However, compaction layer provided a barrier that limited the downwards moisture percolation and solute transport. Furthermore, the numerical simulations showed that the application of freshwater can temporarily reverse the accumulation of salts in agricultural soils. This irrigation strategy can help, in the short-term, alleviate soil salinization problem. The soil hydraulic properties, WT depth, water quality, evaporation demand and the availability of freshwater all play a role in the practicability of such short-term solutions. The presence of a saline shallow WT would, however, rapidly reverse these temporary measures, leading to the recurrence of topsoil salinization.     

Multiple calcrete profiles in the Tabernas Basin,southeast Spain: their origins and geomorphic implications

The paper describes a sequence of Pliocene(? ) to Quaternary age calcretes developed within alluvial fan and fluvial gravels in the Tabernas Basin, Almería Province, southeast Spain. Calcrete profiles are described from sites adjacent to major tributaries of the Rambla de Tabernas. Six distinct calcrete units are identified within the basin. These have variable distributions but have developed in an identifiable evolutionary sequence. Two pairs of calcrete units are widely present across the basin preserving two former land surfaces. Each of the former land surfaces has been planated and subsequently buried by alluvial fan or fluvial gravels. A massive calcrete unit is present at the base of each gravel sequence, immediately in contact with the underlying bedrock, with a less well developed calcrete unit situated at the top of the gravel sequence. The lowest two calcrete units within the basin are more spatially restricted and are confined to the floors and flanks of incised drainage lines. The geochemistry, macro- and micromorphological properties and geomorphological positions of the calcrete units are outlined and, on the basis of this information, their mode of origin identified. Two main modes of calcrete genesis appear to be present: massive calcretes situated in direct contact with bedrock are suggested to have formed by groundwater processes, whilst calcretes situated at the top of gravel sequences are likely to have developed by pedogenic processes. Calcrete genesis is subsequently considered in the context of the reconstruction of the early phases of landscape development, and is suggested to have been controlled by phases of uplift and stability within the Tabernas Basin. © 1998 John Wiley & Sons, Ltd.     

Characterization and evaluation of processes governing the groundwater quality in parts of the Sabarmati basin,Gujarat using hydrochemistry integrated with GIS

Intense agricultural and industrial activities in any area are likely to make groundwater vulnerable with respect to its quality. In one such area which is a part of Sabarmati river basin of Gujarat, factors influencing the groundwater hydrochemistry in pre‐ and post‐monsoon season were evaluated. Groundwater samples were collected from 5 km × 5 km grids on the basis of spectral signature of vegetation and soil, observed on satellite image. Integration of Conventional graphical plots, Piper plot, saturation index values (estimated using PHREEQC) and GIS was helpful not only to create the database for analysis of spatial variation in respective water quality parameters but also to decipher the hydrogeochemical process occurring in such a large area. USSL diagram and % sodium were used to characterise the suitability of groundwater for irrigation. It was observed that leaching of wastes disposed from anthropogenic activities and agrichemicals is the major factor influencing the groundwater quality, in addition to the natural processes such as weathering, dissolution and ion exchange. Sea water relics are also impacting the groundwater quality. Control of indiscriminate and unplanned exploitation of groundwater, application of fertilizers and disposal of industrial wastes in the affected areas can possibly ensure groundwater protection from further pollution and depletion. Copyright © 2011 John Wiley & Sons, Ltd.     

Evolution of the Variscan foreland-basin: modelling the interactions between tectonics and surface processes

The geology of Western and Central Europe is significantly influenced by the Variscan orogen that developed during Devonian and Carboniferous time. Numerical models are essential in understanding and quantifying the involved endogenous and exogenous processes and their interactions. These are mainly based on the large-scale mass redistribution caused by erosion and fluvial sedimentary transport. The sedimentary mass flux leads to changing loads on the lithosphere and affects therefore the evolution of the orogen and the foreland-basin. The complex feedback-mechanism of the surface and tectonic processes is studied by three-dimensional elastic–plastic numerical models. The calculated uplift rates are used to model the interaction between tectonic and surface processes such as erosion and sedimentation. An iterative application of the numerical models for the tectonic and surface processes yields a detailed view of the evolution of the foreland-basin. The tectonic model itself (excluding surface processes) already shows some of the palinspastically reconstructed important features of the lower Carboniferous like the London-Brabant Massif, and the northward propagation of the Variscan deformation front. The results obtained from the coupled analysis can be compared to studies of the sedimentary record (i.e. time, thickness, and sedimentation rates) and other geological concepts (i.e. stability of geological provinces). The results demonstrate that both processes are essential in understanding the complex structural evolution of the Variscides and their foreland. The numerical approach on the tectonic–surface process interaction can also be applied easily to other geological settings.     

Overexploitation and continuous drought effects on groundwater yield and marine intrusion: considerations arising from the modelling of Mamora coastal aquifer,Morocco

This paper studies the effect of drought and pumping discharge on groundwater supplies and marine intrusion. The investigation concerns the Mamora coastal aquifer, northwest of Morocco. A large‐scale groundwater model was established to model (a) the amount of freshwater discharge towards the ocean and the sea water volumes flowing inland as a consequence of the inverse hydraulic gradient, (b) the impact of drought and pumping discharge on the water table level and, as a consequence, on marine water intrusion. In fact, the simulated submarine groundwater discharge (SGWD) would decrease from 864 m³/d/km in 1987 to 425 m³/d/km in 2000. The simulated volumes of sea water intruding the aquifer as a result of inverse hydraulic gradient would increase from 0·25 Mm³/y in 1987 to 0·3 Mm³/y in 2000. As a consequence of a negative rainfall gradient of −5 mm/y, the simulated SGWD would decline to 9 m³/d/km and the sea water intrusion (SWI) would increase to 0·35 Mm³/y since the year 2010. Due to insufficient data on the trend of pumping discharge, a hypothetical increase of this latter from 38·3 Mm³/y to 53·2 Mm³/y is simulated to induce an increase of marine water intrusion from 0·25 Mm³/y to 0·9 Mm³/y. Consequently, to optimally exploit this seemingly fragile coastal aquifer, a plan of future actions to implement is proposed. Copyright © 2005 John Wiley & Sons, Ltd.     

Hydrogeological and hydrogeochemical control of groundwater salinity in an arid inland basin: Dunhuang Basin,northwestern China

High groundwater salinity has become a major concern in the arid alluvial plain of the Dunhuang Basin in northwestern China because it poses a significant challenge to water resource management. Isotopic and geochemical analyses were conducted on 55 water samples from springs, boreholes and surface water to identify potential sources of groundwater salinity and analyse the processes that control increasing salinity. The total dissolved solid (TDS) content in the groundwater ranged from 400 to 41 000 mg/l, and high TDS values were commonly associated with shallow water tables and flow‐through and discharge zones in unconfined aquifers. Various groundwater contributions from rainwater, agricultural irrigation, river water infiltration and lateral inflows from mountains were identified by major ions and δD and δ¹⁸O. In general, HCO₃^? and SO₄^2? were the dominant anions in groundwater with a salinity of <2500 mg/l, whereas Cl^? and SO₄^2? were the dominant anions in groundwater with a salinity of >2500 mg/l. The major ion concentrations indicated that mineral weathering, including carbonate and evaporite dissolution, primarily affected groundwater salinity in recharge areas. Evapotranspiration controlled the major ion concentration evolution and salinity distribution in the unconfined groundwaters in the flow‐through and discharge areas, although it had a limited effect on groundwater in the recharge areas and confined aquifers. Agricultural irrigation increased the water table and enhanced evapotranspiration in the oasis areas of the basin. TDS and Cl became more concentrated, but H and O isotopes were not enriched in the irrigation district, indicating that transpiration dominated the increasing salinity. For other places in the basin, as indicated by TDS, Cl, δD and δ¹⁸O characteristics, evaporation, transpiration and water–rock interactions dominated at different hydrogeological zones, depending on the plant coverage and hydrogeological conditions. Groundwater ages of ³H, and δD and δ¹⁸O compositions and distributions suggest that most of the groundwaters in Dunhuang Basin have a paleometeoric origin and experienced a long residence time. These results can contribute to groundwater management and future water allocation programmes in the Dunhuang Basin. Copyright © 2015 John Wiley & Sons, Ltd.     

Isotopic composition (δ18O and δD) of precipitation and groundwater in a semi‐arid,mountainous area (Guadiana Menor basin,Southeast Spain)

We characterize the precipitation and groundwater in a mountainous (peaks slightly above 3000 m a.s.l.), semi‐arid river basin in SE Spain in terms of the isotopes ¹⁸O and ²H. This basin, with an extension of about 7000 km², is an ideal site for such a study because fronts from the Atlantic and the Mediterranean converge here. Much of the land is farmed and irrigated both by groundwater and runoff water collected in reservoirs. A total of approximately 100 water samples from precipitation and 300 from groundwater have been analysed. To sample precipitation we set up a network of 39 stations at different altitudes (800–1700 m a.s.l.), with which we were able to collect the rain and snowfall from 29 separate events between July 2005 and April 2007 and take monthly samples during the periods of maximum recharge of the aquifers. To characterize the groundwater we set up a control network of 43 points (23 springs and 20 wells) to sample every 3 months the main aquifers and both the thermal and non‐thermal groundwater. We also sampled two shallow‐water sites (a reservoir and a river). The isotope composition of the precipitation forms a local meteoric water line (LMWL) characterized by the equation δD = 7·72δ¹⁸O + 9·90, with mean values for δ¹⁸O and δD of − 10·28‰ and − 69·33‰, respectively, and 12·9‰ for the d‐excess value. To correlate the isotope composition of the rainfall water with groundwater we calculated the weighted local meteoric water line (WLMWL), characterized by the equation δD = 7·40δ¹⁸O + 7·24, which takes into account the quantity of water precipitated during each event. These values of (dδD/dδ¹⁸O)< 8 and d‐excess (δD–8δ¹⁸O)< 10 in each curve bear witness to the ‘amount effect’, an effect which is more manifest between May and September, when the ground temperature is higher. Other effects noted in the basin were those of altitude and the continental influence. The isotopic compositions of the groundwater are represented by the equation δD = 4·79δ¹⁸O − 18·64. The groundwater is richer in heavy isotopes than the rainfall, with mean values of − 8·48‰ for δ¹⁸O and − 59·27‰ for δD. The isotope enrichment processes detected include a higher rate of evaporation from detrital aquifers than from carbonate ones, the effects of recharging aquifers from irrigation return flow and/or from reservoirs' leakage and enrichment in δ¹⁸O from thermal water. Copyright © 2010 John Wiley & Sons, Ltd.     

Long‐term effects of aquifer overdraft and recovery on groundwater quality in a Ramsar wetland: Las Tablas de Daimiel National Park,Spain

Las Tablas de Daimiel National Park is one of Spain's most representative groundwater‐dependent ecosystems. Under natural conditions, water inflows combined brackish surface water from River Gigüela with freshwater inputs from River Guadiana and the underlying aquifer. Since the mid‐1970s, aquifer overexploitation caused the desiccation of the wetlands and neighbouring springs. The National Park remained in precarious hydrological conditions for three decades, with the only exception of rapid floods due to extreme rainfall events and sporadic water transfers from other basins. In the late 2000s, a decrease in groundwater abstraction and an extraordinarily wet period reversed the trend. The aquifer experienced an unexpected recovery of groundwater levels (over 20 m in some areas), thus restoring groundwater discharge to springs and wetlands. The complex historical evolution of the water balance in this site has resulted in substantial changes in surface and groundwater quality. This becomes evident when comparing the pre‐1980 groundwater quality and the hydrochemical status in the wetland in two different periods, under “dry” and “wet” conditions. Although the system is close to full recovery from the groundwater‐level viewpoint, bouncing back in the major hydrochemical constituents has not yet been obtained. These still appear to evolve in response to the previous overexploitation state. Moreover, in some sectors, there are groundwater‐dependent ecosystems that remain different to those found in preoverexploitation times. The experience of Las Tablas de Damiel provides an observatory of long‐term changes in wetland water quality, demonstrating that the effects of aquifer overexploitation on aquatic ecosystems are more than a mere alteration of the water balance and that groundwater quality is the key to aquifer and aquatic ecosystem sustainability.     

Assessment of CHADFDM satellite-based input dataset for the groundwater recharge estimation in arid and data scarce regions

Aquifer natural recharge estimations are a prerequisite for understanding hydrologic systems and sustainable water resources management. As meteorological data series collection is difficult in arid and semiarid areas, satellite products have recently become an alternative for water resources studies. A daily groundwater recharge estimation in the NW part of the Lake Chad Basin, using a soil–plant-atmosphere model (VisualBALAN), from ground- and satellite-based meteorological input dataset for non-irrigated and irrigated land and for the 2005–2014 period is presented. Average annual values were 284 mm and 30°C for precipitation and temperature in ground-based gauge stations. For the satellite-model-based Lake Chad Basin Flood and Drought Monitor System platform (CHADFDM), average annual precipitation and temperature were 417 mm and 29°C, respectively. Uncertainties derived from satellite data measurement could account for the rainfall difference. The estimated mean annual aquifer recharge was always higher from satellite- than ground-based data, with differences up to 46% for dryland and 23% in irrigated areas. Recharge response to rainfall events was very variable and results were very sensitive to: wilting point, field capacity and curve number for runoff estimation. Obtained results provide plausible recharge values beyond the uncertainty related to data input and modelling approach. This work prevents on the important deviations in recharge estimation from weighted-ensemble satellite-based data, informing in decision making to both stakeholders and policy makers.     

Quantifying the impacts of climate change and land use on hydrological processes: A comparison between mountain and lowland agricultural watersheds

Mountain and lowland watersheds are two distinct geographical units with considerably different hydrological processes. Understanding their hydrological processes in the context of future climate change and land use scenarios is important for water resource management. This study investigated hydrological processes and their driving factors and eco-hydrological impacts for these two geographical units in the Xitiaoxi watershed, East China, and quantified their differences through hydrological modelling. Hydrological processes in 24 mountain watersheds and 143 lowland watersheds were simulated based on a raster-based Xin'anjiang model and a Nitrogen Dynamic Polder (NDP) model, respectively. These two models were calibrated and validated with an acceptable performance (Nash-Sutcliffe efficiency coefficients of 0.81 and 0.50, respectively) for simulating discharge for mountain watersheds and water level for lowland watersheds. Then, an Indicators of Hydrological Alteration (IHA) model was used to help quantify the alterations to the hydrological process and their resulting eco-hydrological impacts. Based on the validated models, scenario analysis was conducted to evaluate the impacts of climate and land use changes on the hydrological processes. The simulation results revealed that (a) climate change would cause a larger increase in annual runoff than that under land use scenario in the mountain watersheds, with variations of 19.9 and 10.5% for the 2050s, respectively. (b) Land use change was more responsible for the streamflow increment than climate change in the lowland watersheds, causing an annual runoff to increase by 27.4 and 16.2% for the 2050s, respectively. (c) Land use can enhance the response of streamflow to the climatic variation. (d) The above-mentioned hydrological variations were notable in flood and dry season in the mountain watersheds, and they were significant in rice season in the lowland watersheds. (e) Their resulting degradation of ecological diversity was more susceptible to future climate change in the two watersheds. This study demonstrated that mountain and lowland watersheds showed distinct differences in hydrological processes and their responses to climate and land use changes.     

Origin and type of rainfall for recharge of a karstic aquifer in the western Mediterranean: a case study from the Sierra de Gador–Campo de Dalias (southeast Spain)

Isotope signatures in precipitation from the Global Network for Isotopes in Precipitation around the Mediterranean basin and literature data are compared with isotopic data from a large karstic aquifer in southeast Spain to explain the origin and type of the precipitation events dominating recharge. Analysis of the deuterium excess d at the scale of the Mediterranean basin and at the regional scale allows us to understand the isotopic context of the study area: Campo de Dalias and the Sierra de Gador (Almería province). The origin of precipitation can be determined from its d value. The d value changes as a function of the initial evaporation condition. It depends on the relative humidity and temperature during the evaporation producing the water vapour of the clouds. The water vapour, which dominates the study area, is generated in two areas: the Atlantic Ocean (d = 10‰) and the western Mediterranean basin (d = 15‰). With increasing precipitation volume, the western Mediterranean character dominates. These heavier storms contribute mainly to recharge, as illustrated by the d value of 13·6‰ in deep groundwater of the Campo de Dalias. Weighted d values increase with the volume of precipitation, giving a significant relationship for the southern and eastern coasts of the Iberian Peninsula. This selectivity of d to monthly precipitation was used to estimate the return period of precipitation leading to aquifer recharge at 0·9–4·9 years. Moderate rainfall, which occurs more frequently, still represents ～60–90% of the total precipitation. One of the challenges to meet ever‐growing water demands is to increase recharge from moderate events yielding intermediate quantities per event, but forming the bulk of the annual precipitation. Copyright © 2006 John Wiley & Sons, Ltd.     

Investigating the use of spatial discretization of hydrological processes in conceptual rainfall runoff modelling: a case study for the meso‐scale

In this study a simple modelling approach was applied to identify the need for spatial complexity in representing hydrological processes and their variability over different scales. A data set of 18 basins was used, ranging between 8 and 4011 km² in area, located in the Nahe basin (Germany), with daily discharge values for over 30 years. Two different parsimoniously structured models were applied in lumped as well as in spatially distributed according to two distribution classifications: (1) a simple classification based on the lithology expressed in three permeability types and (2) a more complex classification based on seven dominating runoff production processes. The objective of the study was to compare the performances of the models on a local and on a regional scale as well as between the models with a view to identifying the accuracy in capturing the spatial variability of the rainfall‐runoff relationships. It was shown that the presence of a specific basin characteristic or process of the distribution classification was not related with higher model performance; only a larger basin size promoted higher model performance. The results of this study also indicated that the permeability generally contained more useful information on the spatial heterogeneity of the hydrological behaviour of the natural system than did a more detailed classification on dominating runoff generation processes. Although model performance was slightly lower for the model that used permeability as a distribution classification, consistency in its parameter values was found, which was lacking with the more complex distribution classification. The latter distribution classification had a higher flexibility to optimize towards the variability of the runoff, which resulted in higher performance, however, process representation was applied inconsistently. Copyright © 2007 John Wiley & Sons, Ltd.     

Hydrochemical characteristics and salinization processes of groundwater in the shallow aquifer of Eastern Laizhou Bay,China

Groundwater salinization has become a crucial environmental problem worldwide and is considered the most widespread form of groundwater contamination in the coastal zone. In this study, a hydrochemical investigation was conducted in the eastern coastal shallow aquifer of Laizhou Bay to identify the hydrochemical characteristics and the salinity of groundwater using ionic ratios, deficit or excess of each ions, saturation indices and factor analysis. The results indicate that groundwater in the study area showed wide ranges and high standard deviations for most of hydrochemical parameters and can be classified into two hydrochemical facies, Ca²⁺‐Mg²⁺‐Cl^‐ facies and Na⁺‐Cl^‐ facies. The ionic ratio, deficit or excess of each ions and SI were applied to evaluate hydrochemical processes. The results obtained indicate that the salinization processes in the coastal zones were inverse cation exchange, dissolution of calcite and dolomite, and intensive agricultural practices. Factor analysis shows that three factors were determined (Factor 1: TDS, EC, Cl^‐, Mg²⁺, Na⁺, K⁺, Ca²⁺ and SO₄^2‐; Factor 2: HCO₃^‐ and pH; Factor 3: NO₃^‐ and pH), representing the signature of seawater intrusion in the coastal zone, weathering of water–soil/rock interaction, and nitrate contamination, respectively. Copyright © 2011 John Wiley & Sons, Ltd.     

Using chlorofluorocarbons (CFCs) and tritium to improve conceptual model of groundwater flow in the South Coast Aquifers of Laizhou Bay,China

The southern coastal plain of Laizhou Bay, which is the area most seriously affected by salt water intrusion in north China, is a large alluvial depression, which represents one of the most important hydrogeological units in the coastal region of northern China. Chlorofluorocarbons (CFCs, including CFC‐11, CFC‐12 and CFC‐113) and tritium were used together for dating groundwater up to 50 years old in the study area. There are two cones of depression, caused by intensive over‐exploitation of fresh groundwater in the south and brine water in the north. The assigned CFC apparent ages for shallow groundwater range from 8 a to >50 a. A binary mixing model based on CFC‐113 and CFC‐12 concentrations in groundwater was used to estimate fractions of young and pre‐modern water in shallow aquifers and to identify groundwater mixing processes during saltwater intrusion. Discordance between concentrations of different CFC compounds indicate that shallow groundwater around the Changyi cone of depression is vulnerable to contamination. Pumping activities, CFC contamination, mixing and/or a large unsaturated zone thickness (e.g. >20 m) may be reasons for some groundwater containing CFCs without tritium. Saline intrusion mainly occurs because of large head gradients between fresh groundwater in the south and saline water bodies in the north, forming a wedge of saline water below/within fresh aquifer layers. Both CFC and tritium dates indicate that the majority of the saline water is from >50 a, with little or no modern seawater component. Based on the distribution of CFC apparent ages, tritium contents plus chemical and physical data, a conceptual model of groundwater flow along the investigated Changyi‐Xiaying transect has been developed to describe the hydrogeological processes. Three regimes are identified from south to north: (i) fresh groundwater zone, with a mixing fraction of 0.80–0.65 ‘young’ water calculated with the CFC binary mixing model (groundwater ages <34 a) and 1.9–7.8TU of tritium; (ii) mixing zone characterized by a mixing fraction of 0.05–0.65 young groundwater (ages of 23–44 a), accompanied by local vertical recharge and upward leakage of older groundwater; and (iii) salt water zone, mostly comprising waters with ages beyond the dating range of both CFCs and tritium. Some shallow groundwater in the north of the Changyi groundwater depression belongs to the >50a water group (iii), indicating slow velocity of groundwater circulation and possible drawing in of saline or deep groundwater that is tracer‐free. Copyright © 2012 John Wiley & Sons, Ltd.