BIOGEOCHEMISTRY RESEARCH OF FLUORIDE IN ANTARCTIC OCEAN Ⅱ. THE VARIATION CHARACTERISTICS AND CONCENTRATION CAUSE OF FLUORIDE IN THE CUTICLE OF ANTARCTIC KRILL

The cause of the concentration of fluoride in Antaractic krill is studied by the analysis of the characteristics of fluoride change in the cuticle of the krill before and after moulting. Associated with other related information, the source and accumulating mechanism of fluoride in krill are also disscussed. Results show that as an inorganic medium the cuticle of krill has the second concentrating function and action to fluoride after moulting, which has nothing to do with the biological action of the krill. The fluoride is concentrated from seawater, which is prosecuted mainly in the form of ion exchange.     

ANOMEALY OF FLUORINE IN A SEDIMENTARY SYSTEM, WESTERN ANTARCTIC OCEAN

Fluorine content in bulk sediment and its pore water in Western Antarctic Ocean is 200～395μg/g and 1.18～1.92ug/ml respectively, far below the average reported previously in the world oceans (540 ug/g and 2.7t~g/ml, respectively). This study also shows that the distribution of fluorine in the sediments of the area is mainly controlled by the chemical composition of the material from the surrounding islands, and the element seems to be mostly incorporated in the hornblende, thus the correlation between the element and the hornblende amount in the sediments can be expressed statistically as following: F=217+ln Vh. The low concentration of fluorine in the pore water is largely due to the weak weathering process on the islands and the precipitation of the element with calcium. It can be indicated well by the lower value of anion-exchangeable (HCO_3~-) F- in the studied area, which is only about one tenth of that in Pacific Ocean and a quarter in South China sea and a half in the sea east of Zhejiang. In a     

THE EFFECT OF MEAN CENTERING ON PREDICTION IN MULTIVARIATE CALIBRATION

Traditionally,one form of preprocessing in multivariate calibration methods such as principal componentregression and partial least squares is mean centering the independent variables(responses)and thedependent variables(concentrations).However,upon examination of the statistical issue of errorpropagation in multivariate calibration,it was found that mean centering is not advised for some datastructures.In this paper it is shown that for response data which(i)vary linearly with concentration,(ii)have no baseline(when there is a component with a non-zero response that does not change inconcentration)and(iii)have no closure in the concentrations(for each sample the concentrations of allcomponents add to a constant,e.g.100%)it is better not to mean center the calibration data.That is,the prediction errors as evaluated by a root mean square error statistic will be smaller for a model madewith the raw data than a model made with mean-centered data.With simulated data relativeimprovements ranging from 1% to 13% were observed depending on the amount of error in thecalibration concentrations and responses.     

A quantitative assessment on groundwater salinization in the Tarim River lower reaches, Northwest China

Based on monitored data from 840 samples, we assessed the spatial and temporal variability of groundwater salinization in the Tarim River lower reaches combining classical statistics and geostatistics. Results show that total dissolved solids （TDS） is significantly correlated with other related ions, such as Na＋, Mg2＋, Ca2-, C1- and K＋. TDS and underground water level have characteristics of spatial autocorrelation, both of which present the isotropic characteristic and con- form to the spherical model in each year from 2001-2009. TDS is basically greater than 1 g/L but less than 2 g/L in the Tarim River lower reaches, which indicates that salt stagnation pollution is more serious. The most serious salinization （3 g/L 〈 TDS _〈 35 g/L） contaminated area is mainly in the middle and lower part of the study area.     

ESTIMATION OF ERRORS IN ABSORBANCE RATIO MEASUREMENTS

Ratio measurements are commonly used to address a variety of analytical problems in environmental,forensic and pharmaceutical laboratories.In absorbance ratioing techniques,analytical chemists rely onthe spectral features of the analyte(s)of interest.The absorbances at two wavelengths are monitored andthe ratio of these two absorbances is computed.This ratio is then used to confirm the identity of theanalyte(s)of interest,the purity of a product or the overlap of chromatographic peaks.These decisionsoften have far-reaching consequences(e.g.the identification of the source,biogenic or petrogenic,ofhydrocarbons in biological tissues or water).Given the cost and the liabilities associated with suchdecisions,it is unfortunate that these ratios are seldom reported with any statistical confidence.Thepurpose of this study is to delineate the parameters that affect absorbance ratio measurements.Themodels that can be used to estimate the statistical confidence in these measurements are derived andevaluated experimentally.The results show that these models can estimate the relative standard deviationsin absorbance ratios accurately.They can also estimate the effect of signal-to-noise ratio and the choiceof wavelengths on the precision of absorbance ratios.     

ASSESSMENT OF 17β-ESTRADIOL IN AQUATIC ENVIRONMENTS AROUND KLANG VALLEY, MALAYSIA

This study was conducted to assess the existing concentration of 17β-estradiol(E2)in the surface water samples collected from rivers and lakes around Klang Valley,Malaysia.E2,which is a natural feminizing chemical produced in female organisms,regularly used to compare with other environmental estrogens because they behave similarly and react effectively as a hormone at a very low concentration.It was found that the average concentration of E2 in the aquatic environment of Klang Valley was(14.08 ±3.67)pg/mL,which was 14 times higher than those in the Japanese aquatic environment in this study.The river system had the average concentration of(20.02±5.26)pg/mL while the lake had an average concentration of(5.91±3.39)pg/mL.The E2 concentration was presumed high if the sources occurred nearby the area.Current levels of E2 in the aquatic environment may possess threats to existing aquatic organisms.Since high level of E2 has been discovered in the aquatic environment around Klang Valley,further studies and monitoring of E2 and other EDCs concentrations are needed to determine their levels in Malaysian aquatic environment and help to control these chemicals pollution in the aquatic environment.     

FINDING CAUSES OF OUTLIERS IN MULTIVARIATE ENVIRONMENTAL DATA

Multivariate outliers in environmental data sets are often caused by atypical measurement error in a singlevariable.From a quality assurance perspective it is important to identify these variables efficiently so thatcorrective actions may be performed.We demonstrate a procedure for using two multivariate tests toidentify which variable‘caused’each outlier.The procedure is tested with simulated data sets that havethe same correlation structure as selected water chemistry variables from a survey of lakes in the WesternUnited States.The success rates are evaluated for three of the variables for sample sizes of 50 and 100,significance levels of 0.01 and 0.05 and various amounts of mean shift.The procedure works best forhighly correlated variables.     

基于Hurst指数的1982–2013年蒙古高原植被动态变化趋势及其影响因素分析（英文）

This study analyzed the spatial and temporal variations in the Normalized Difference Vegetation Index(NDVI) on the Mongolian Plateau from 1982–2013 using Global Inventory Modeling and Mapping Studies(GIMMS) NDVI3 g data and explored the effects of climate factors and human activities on vegetation. The results indicate that NDVI has slight upward trend in the Mongolian Plateau over the last 32 years. The area in which NDVI increased was much larger than that in which it decreased. Increased NDVI was primarily distributed in the southern part of the plateau, especially in the agro-pastoral ecotone of Inner Mongolia. Improvement in the vegetative cover is predicted for a larger area compared to that in which degradation is predicted based on Hurst exponent analysis. The NDVI-indicated vegetation growth in the Mongolian Plateau is a combined result of climate variations and human activities. Specifically, the precipitation has been the dominant factor and the recent human effort in protecting the ecological environments has left readily detectable imprints in the NDVI data series.     

A study on the Antarctic circumpolar wave mode-A coexistence system of standing and traveling wave

The Antarctic circumpolar wave(ACW)has become a focus of the air-sea coupled Southern Ocean study since 1996,when it was discovered as an air-sea coupled interannual signal propagating eastward in the region of the Antarctic C i rcumpolar Current(ACC).In order to analyze the mechanism of discontinuity alon g the latitudinal propagation,a new idea that ACW is a system with a traveling wave in the Southern Pacific and Atlantic Ocean and with a concurrent standing w ave in the southern Indian Ocean is proposed in this paper.Based on the ideal w ave principle,the average wave parameters of ACW is achieved using a non-linea r approximation method,by which we find that the standing part and the travelin g part possess similar radius frequency,proving their belonging to an integral s ystem.We also give the latitudinal distribution of wave speed with which we cou ld tell the reason for steady propagation during the same period.The spatial di stribution of the propagation reveals complex process with variant spatial and t emporal scales—The ENSO scale oscillation greatly impacts on the traveling process,while the result at the south of Australia indicates little connection betw een the Indian Ocean and the Pacific,which may be blocked by the vibration at t he west of the Pacific.The advective effect of ACC on the propagation process s hould be examined clearly through dynamical method.     

苏北废黄河三角洲近岸沉积物分异特征及输运趋势(英文)

The delta evolution and erosion process of the abandoned Yellow River Delta(AYRD) have been extensively studied. However, the variation of sediment at a large littoral scale along the north coast of Jiangsu is less understood. In this study, the data of surface sediment samples obtained in the littoral area of the Yellow River Delta in 2006 and 2012 is used to study the sediment variability and sediment transport trends by using the geostatistics analysis tool and the grain size trend analysis model. In order to ensure the applicability of the model, the geostatistics method is used to determine the characteristic distance(Dc) with the average range value(Ao) of grain size parameter. Filtering method(removing data that not at a sampling station) is used to improve accuracy of data selection. The results show that sedimentary spatial correlation in Lianyun Port area and southern part of the abandoned Yellow River Delta(AS) is better than that in the northern part of the abandoned Yellow River Delta(AN). Sediment in the area is found to be anisotropy at the northeast–southeast direction. The grain size trend analysis reveals that the sediment trend is towards bayhead and southerly in the Haizhou Bay, southeasterly along the shoreline in the south Lianyun Port, northwesterly in AN and easterly–southeasterly in AS respectively. The investigation of possible relationships between Dc, Ao, sediment transport and delta evolution shows a close link between Dc and Ao of one sediment combination. It is also found that sediment transport trends could reasonably represent the delta evolution to a certain degree.     

WATER QUALITY STUDIES IN MALAYSIAN DISUSED MAN MADE LAKFS FOR SUITABILITY OF AN AQUACULTURE PROJECT

A study has been conducted on the status of water quality in two disused man made lakes, which have potential for cage aquaculture project. This study highlights the quality of water analyzed with reference to various physical - chemical parameters in two selected lakes and their suitability for fish farming. A number of parameters were measured including the amount of NH3 - N, NO3 - N, NO2 - N and total phosphorus while in - situ measurement including DO, pH, temperature, conductivity, TDS and Secchi disk visibility. Beside the physical -chemical of water, the location, morphometry and climate conditions were also investigated. The chemical data analyzed for six months indicated that Lake A and Lake B are characterized by relatively high DO, slightly neutral pH and low TSS. The concentration of NH3 -N and NO2 -N was very low （0. 058 mg/L and 0. 04 mg/L, respectively） and total phosphorus was usually in low concentration and sometimes would seem negligible. Besides, NO3 - N occurred in slightly higher concentration （1.75 mg/L）. Results obtained indicated that the study site has high potentiality for development of inland fisheries practices.     

基于区域划分方法的中国人口分布格局及变化研究——从1953年到2010年（英文）

This study uses six censuses(1953, 1964, 1982, 1990, 2000, and 2010) at the county level since the foundation of the People's Republic of China to examine the changes of population density pattern in mainland China over time. Based on the Gini coefficient, the change of disparity in population density followed a "U-shaped" trend, i.e., decreasing during 1953–1982 and increasing during 1982–2010. The shrinking disparity in the pre-reform periods was largely attributable to various ill-conceived political movements, and the enlarging gap in population growth rates in the post-reform era reflected a natural outcome of urbanization, which will continue in the foreseeable future. In addition, this research employs a GIS-automated regionalization method, REDCAP, to uncover a natural demarcation line like the classic "Hu Line" that divides China into two regions of similar area sizes but a strong contrast in population. The results show that the regionalization-derived lines were largely consistent with the Hu Line over time. Therefore, the disparity between the high-density southeast and low-density northwest regions is likely due to differing physical environments that form a natural barrier. Any public policy to overcome this barrier at a large scale is destined to be a vain attempt.     

A RESEARCH ON THE BENTHIC ECOLOGY ENVIRONMENT, ANTARCTIC OCEAN: Ⅰ. MAXWELL BAY AND ADMIRALTY BAY

Analyzing the information on benthic organisms and geochemistry, obtained from the Chinese First Expedition on Antarctic Ocean and its succeeded works and comparing with that of other oceans, this paper shows that in the circumstances of the researched area benthic organisms are rich. However, the prodsperity of the organisms is limited below 5-10 cm of the profiles in which the environment is mainly dominated by sulfate reducing reaction. On the condition of low temperature in Antarctic Ocean, the solubility of carbonates is higher than that of other latitudes of oceans, but the concentration of calcium in overlying water and pore water of the benthic environment is not higher than that in other oceans, which results in the difficulty for the crustaceas and mollusks to obtain sufficient calcium carbonate to form their solid shell as well as to bring about the lower ratios of these animals both in abundance and biomass in the researched ocean. Futhermore, there is a positive relationship between the dis     

Using remote-sensing technologies in combination with Cesium-137 measurements to estimate soil-erosion quantity in semi-arid steppe areas

Soil erosion by wind is one of the most important processes in the changing the earth’s surface in semi-arid areas,Thus it is of great importance to study soil-erosion action.Using integrated technologies of remote sensing and geochemistry radioactivity iso-tope to extract regional soil-erosion information and to calculate quantity of soil erosion is accomplished successfully in this paper by means of beneficial experiments in the Talatan region of the Gonghe Basin,which is located in northeastern Qinghai-Tibet Pla-teau in China.The results show that the soil erosion by wind is not intensive in this region;the erosion types belong to the classes of very-soft erosion and soft-erosion type,which account for 47.12 percent and 35.58 percent,respectively,of the total study area.In total,two kinds of soil erosion account for 82.70 percent of the study area;only a small area belongs to the classes of severe erosion and very-severe erosion;this area is about 22.14 km2.Severe deposition activity has taken place in this region,and has appeared in a large area(322.67 km2),which accounts for 11.78 percent of the total study area.The results of this study show that soil erosion and deposition inventories are 870,000-1,150,000 tons and 550,000-780,000 tons,respectively,per year.The soil in-ventory shows about 320,000-370,000 tons from Talatan to Longyangxia reservoir per year.Using remote-sensing technology and 137Cs techniques is a valid means to analyze and to evaluate the quantity of soil erosion by wind in semi-arid environments.     

BOX-COX TRANSFORMATIONS IN THE ANALYSIS OF COMPOSITIONAL DATA

The statistical analysis of compositional data is of fundamental importance to practitioners in generaland to chemists in particular.The existing methodology is principally due to Aitchison,who effectivelyuses two transformations,a ratio followed by the logarithmic,to create a useful,coherent theory thatin principle allows the plethora of normal-based multivariate techniques to be used on the transformeddata.This paper suggests that the well-known class of Box-Cox transformations can be employed inplace of the logarithmic to significantly improve the existing methodology.This is supported in part byshowing that one of the most basic problems that Aitchison managed to overcome,namely thespecification of an interpretable covariance structure for compositional data,can be resolved,or nearlyresolved,once the ratio transformation has been applied.Hence the resolution is not directly dependenton the logarithmic transformation.It is then verified that access to the general Box-Cox family will allowa more accurate use of the normal-based multivariate techniques,simply because better fits to normalitycan be achieved.Finally,maximum likelihood estimation and some associated asymptotics are employedto construct confidence intervals for ratios of the true,unknown compositional constituents.Heretoforethis had not been done even in the context of the logarithmic transformation.Applications to real dataare presented.     

基于MODIS数据的南极半岛北部冰架表面流速估算（英文）

The ice shelves in the northern Antarctic Peninsula are highly sensitive to variations of temperature and have therefore served as indicators of global warming. In this study,we estimate the velocities of the ice shelves in the northern Antarctic Peninsula using co-registration of optically sensed images and correlation module(COSI-Corr) in the Environment for Visualizing Images(ENVI) based on Moderate Resolution Imaging Spectroradiometer(MODIS) images during 2000–2012,from which we conclude that the ice flow directions generally match the peninsulas pattern and the crevasse,ice flows mainly eastward into the Weddell Sea. The spatial pattern of velocity field exhibits an increasing trend from the western grounding line to the maximum at the middle part of the ice shelf front on Larsen C with a velocity of approximately 700 ma–1,and the velocity field shows relatively higher values in its southerly neighboring ice shelf(e.g. Smith Inlet). Additionally,ice flows are relatively quicker in the outer part of the ice shelf than in the inner parts. Temporal changes in surface velocities show a continuous increase from 2000 to 2012. It is worth noting that,the acceleration rate during 2000–2009 is relatively higher than that during 2009–2012,while the ice movement on the southern Larsen C and Smith Inlet shows a deceleration from 2009 to 2012.     

APPLICATION OF PATTERN RECOGNITION TO SPECIATION DATA OF HEAVY METALS IN SUSPENDED PARTICULATES OF URBAN AIR

In order to get a better knowledge of the air pollution levels of the urban air of Barcelona,twelvesamples from three stations of the air-monitoring control network were analysed.Each control station isrepresentative of a different environmental situation.Thus the station at Plaa Molina responds to asimple domestic and urban traffic situation;the station at Poble Nou to the influence of medium andsmall industries,mainly metallurgical;and the station at Montcada to a zone in which there existimportant industries,a cement factory,two highways and railroads.The total content of unsedimentable particles,three inorganic anions(chlorides,sulphates andnitrates)and six heavy metals(Fe,Pb,Cu,Mn,Cr and Cd)were determined on all the samples obtainedduring the same period of time.The use of an analytical scheme of sequential extraction has alsopermitted the subdivision of the total content of each metal into the following four fractions:(1)solubleor exchangeable;(2)associated with carbonates and/or with iron and manganese oxides;(3)bound toorganic matter;and(4)residual.The use of principal component analysis applied to the data as a whole showed the associations andcorrelations between the various parameters as well as between the different above mentioned fractions.The predominant presence of Cd in the‘soluble or exchangeable’fraction is confirmed,while the othermetals are mainly associated with the‘carbonates and/or Fe and Mn oxides’and‘bound to organicmatter’fractions.Hierarchical cluster analysis applied to the twelve samples showed clearly the presence of threedifferent classes closely related to the origin(station)of the samples.Thus it becomes feasible to proposefor each station a possible profile of the content in terms of the different parameters considered.     

黑河流域土地利用变化对土壤有机碳和全氮储量的影响——元分析（英文）

Land use and cover change(LUCC) is an important indicator of the human-earth system under climate/environmental change,which also serves as a key impact factor of carbon balance,and a major source/sink of soil carbon cycles.The Heihe River Basin(HRB) is known as a typical ecologically fragile area in the arid/semi-arid regions of northwestern China,which makes it more sensitive to the LUCC.However,its sensitivity varies in a broad range of controlling factors,such as soil layers,LUCCs and calculation methods(e.g.the fixed depth method,FD,and the equivalent mass method,ESM).In this study,we performed a meta-analysis to assess the response of soil organic carbon(SOC) and total nitrogen(TN) storage to the LUCC as well as method bias based on 383 sets of SOC data and 148 sets of TN data from the HRB.We first evaluated the calculation methods and found that based on the FD method,the LUCC caused SOC and TN storage to decrease by 17.39% and 14.27%,respectively;while the losses estimated using the ESM method were 19.31% and 18.52%,respectively.The deviations between two methods were mainly due to the fact that the FD method ignores the heterogeneity of soil bulk density(BD),which may underestimate the results subsequently.We then analyzed the response of SOC and TN storage to various types of the LUCC.In particular,when woodland and grassland were converted into cultivated land or other land types,SOC and TN suffered from heavy losses,while other LUCCs had minor influences.Finally,we showed that increasing the depth of the soil layers would reduce the losses of SOC and TN storage.In summary,we identified a series of controlling factors(e.g.soil layer,the LUCC and calculation method) to evaluate the impact of the LUCC on SOC and TN storage in the HRB,which should be considered in future research.     

BODY DIAGONALIZATION OF CORE MATRICES IN THREE-WAY PRINCIPAL COMPONENTS ANALYSIS:THEORETICAL BOUNDS AND SIMULATION

In contrast with conventional PCA,a direct superposition and joint interpretation of loading plots is notpossible in three-way PCA,since there may be data variance which is described by unequal componentsof different modes.The contributions to variance of all possible combinations of components aredescribed in the core matrix.Body diagonalization,which is achieved by appropriate rotation ofcomponent matrices,is an essential tool for simplifying the core matrix structure.The maximum degreeof body diagonality which may be obtained from such transformations is analysed from both themathematical and simulation viewpoints.It is shown that,at least in the average case,high degrees canbe expected,which makes the procedure reasonable for many practical applications.Furthermore,simulation as well as theoretical derivation show that the success of body diagonality depends on the so-called polarity of the core array.The methodology is illustrated by a three-way data example fromenvironmental chemistry.     

Glacier service value and influence on human well-being in Qilian Mountains

Global warming is causing melting of glaciers, which is affecting socioeconomic development. It is essential to study the combined influence of changes in structures of glaciers on human well-being and socioeconomic systems. Herein, we considered Qilian Mountains as an example, quantified the regional socioeconomic benefits of glaciers and human well-being, and attempted to draw a correlation between glacier service value and human well-being. The findings of our study reveal that the value of g...