Laboratory simulations of Mars aqueous geochemistry

We report on laboratory experiments in which we allowed an SNC-derived mineral mix to react with pure water under a simulated Mars atmosphere for 7 months. These experiments were performed at one bar and at three different temperatures in order to simulate the subsurface conditions that most likely exist where liquid water and rock interact on Mars today. The dominant cations dissolved in the solutions we produced, which may be characterized as dilute brines, are Ca²⁺, Mg²⁺, Al³⁺, and Na⁺, while the major anions are dissolved C, F⁻, SO²⁻₄ and Cl⁻. Typical solution pH was in the range of 4.2-6.0. Abundance patterns of elements in our synthetic sulfate-chloride brines are distinctly unlike those of terrestrial ocean water or continental waters, however, they are quite similar to those measured in the martian fines at the Mars Pathfinder and Viking 1 and 2 Landing sites. This suggests that salts present in the martian regolith may have formed over time as a result of the interaction of surface or subsurface liquid water with basalts in the presence of a martian atmosphere similar in composition to that of today. If most of the mobile surface layer was formed during the Noachian when erosion rates were much higher than at present, and if this layer is homogeneous in salt composition, the total amount of salt in the martian fines is approximately the same as in the Earth's oceans. The minimum quantity of circulating water necessary to deposit this amount of salt is approximately equivalent to a global layer 625 m deep.     

Silica-rich deposits and hydrated minerals at Gusev Crater, Mars: Vis-NIR spectral characterization and regional mapping

The Mars Exploration Rover (MER) Spirit has discovered surprisingly high concentrations of amorphous silica in soil and nodular outcrops in the Inner Basin of the Columbia Hills. In Pancam multispectral observations, we find that an absorption feature at the longest Pancam wavelength (1009 nm) appears to be characteristic of these silica-rich materials; however, spectral analyses of amorphous silica suggest that the ∼1009 nm spectral feature is not a direct reflection of their silica-rich nature. Based on comparisons with spectral databases, we hypothesize that the presence of H₂O or OH, either free (as water ice), adsorbed or bound in a mineral structure, is responsible for the spectral feature observed by Pancam. The Gertrude Weise soil, which is nearly pure opaline silica, may have adsorbed water cold-trapped on mineral grains. The origin of the ∼1009 nm Pancam feature observed in the silica-rich nodular outcrops may result from the presence of additional hydrated minerals (specific sulfates, halides, chlorides, sodium silicates, carbonates or borates). Using the ∼1009 nm feature with other spectral parameters as a “hydration signature” we have mapped the occurrence of hydrated materials along the extent of Spirit’s traverse across the Columbia Hills from West Spur to Home Plate (sols 155-1696). We have also mapped this hydration signature across large panoramic images to understand the regional distribution of materials that are spectrally similar to the silica-rich soil and nodular outcrops. Our results suggest that hydrated materials are common in the Columbia Hills.     

A systematic spectroscopic study of eight hydrous ferric sulfates relevant to Mars

Ferric sulfates were observed on Mars during orbital remote sensing and surface explorations. These observations have stimulated our systematic experimental investigation on the formative conditions, stability fields, phase boundaries, and phase transition pathways of these important minerals. We report here the results from the first step of this project: eight synthesized anhydrous and hydrous crystalline ferric sulfates and their structural characters reflected through spectroscopic studies. A few phenomena observed during the 150 sets of on-going experiments for stability field study are also reported, which reveal the structural distortions that can happen under environmental conditions relevant to Mars.     

Antarctic Dry Valleys and indigenous weathering in Mars meteorites: Implications for water and life on Mars

The Dry Valleys of Antarctica are an excellent analog of the environment at the surface of Mars. Soil formation histories involving slow processes of sublimation and migration of water-soluble ions in polar desert environments are characteristic of both Mars and the Dry Valleys. At the present time, the environment in the Dry Valleys is probably the most similar to that in the mid-latitudes on Mars although similar conditions may be found in areas of the polar regions during their respective Mars summers. It is thought that Mars is currently in an interglacial period, and that subsurface water ice is sublimating poleward. Because the Mars sublimation zones seem to be the most similar to the Antarctic Dry Valleys, the Dry Valleys-type Mars climate is migrating towards the poles. Mars has likely undergone drastic obliquity changes, which means that the Dry Valleys analog to Mars may be valid for large parts of Mars, including the polar regions, at different times in geologic history. Dry Valleys soils contain traces of silicate alteration products and secondary salts much like those found in Mars meteorites. A martian origin for some of the meteorite secondary phases has been verified previously; it can be based on the presence of shock effects and other features which could not have formed after the rocks were ejected from Mars, or demonstrable modification of a feature by the passage of the meteorite through Earth's atmosphere (proving the feature to be pre-terrestrial). The martian weathering products provide critical information for deciphering the near-surface history of Mars. Definite martian secondary phases include Ca-carbonate, Ca-sulfate, and Mg-sulfate. These salts are also found in soils from the Dry Valleys of Antarctica. Results of earlier Wright Valley work are consistent with what is now known about Mars based on meteorite and orbital data. Results from recent and current Mars missions support this inference. Aqueous processes are active even in permanently frozen Antarctic Dry Valleys soils, and similar processes are probably also occurring on Mars today, especially at the mid-latitudes. Both weathering products and life in Dry Valleys soils are distributed heterogeneously. Such variations should be taken into account in future studies of martian soils and also in the search for possible life on Mars.     

Ice table depth variability near small rocks at the Phoenix landing site, Mars: A pre-landing assessment

We combine thermal simulations of ground ice stability near small rocks with extrapolations of the abundance of rocks at the Phoenix landing site based on HiRISE rock counts to estimate the degree of ice table depth variability within the 3.8 m² workspace that can be excavated during the mission. Detailed predictions of this kind are important both to test current ground-ice theory and to optimize soil investigations after landing. We find that Phoenix will very likely have access to at least one rock in the diameter range 5 cm to 1 m. Our simulations, which assume the ice to be in diffusive equilibrium with atmospheric water vapor, indicate that all rocks in this size range are associated with an annulus of deep ice-free soil. Ice table depth variability of 1-5 cm is very likely at the landing site due to the presence of small rocks. Further, there are scenarios in which Phoenix might exploit the presence of individual large rocks and/or the arrangement of small rocks to sample soils at depths >10 cm below the average depth predicted from orbit (∼4 cm). Scale analysis to constrain uncertainties in simulation results indicates that estimates of maximum depths may be somewhat conservative and that ice table depressions associated with individual rocks could be deeper and laterally more extended than indicated by formal predictions by mm to cm.     

The H2O and CO2 adsorption properties of phyllosilicate-poor palagonitic dust and smectites under martian environmental conditions

The recent detection of up to ∼10 wt% water-equivalent H heterogeneously distributed in the upper meter of the equatorial regions of the martian surface and the presence of the 3-μm hydrations feature across the entire planet raises the question whether martian surficial dust can account for this water-equivalent H. We have investigated the H₂O and CO₂ adsorption properties of palagonitic dust (<5 μm size fraction of phyllosilicate-poor palagonitic tephra HWMK919) as a martian dust analog and two smectites under simulated martian equatorial surface conditions. Our results show that the palagonitic dust, which contains hydrated and hydroxylated volcanic glass of basaltic composition, accommodates significantly more H₂O under comparable humidity and temperature conditions than do the smectites nontronite and montmorillonite.     

Evidence for and implications of sedimentary diapirism and mud volcanism in the southern Utopia highland-lowland boundary plain, Mars

Several types of spatially associated landforms in the southern Utopia Planitia highland-lowland boundary (HLB) plain appear to have resulted from localized geologic activity, including (1) fractured rises, (2) elliptical mounds, (3) pitted cones with emanating lobate materials, and (4) isolated and coalesced cavi (depressions). Stratigraphic analysis indicates these features are Hesperian or younger and may be associated with resurfacing that preferentially destroyed smaller (<8 km diameter) impact craters. Based on landform geomorphologies and spatial distributions, the documented features do not appear to be specifically related to igneous or periglacial processes or the back-wasting and erosion of the HLB scarp. We propose that these features are genetically related to and formed by sedimentary (mud) diapirs that ascended from zones of regionally confined, poorly consolidated, and mechanically weak material. We note morphologic similarities between the mounds and pitted cones of the southern Utopia boundary plain and terrestrial mud volcanoes in the Absheron Peninsula, Azerbaijan. These analogs provide a context for understanding the geological environments and processes that supported mud diapir-related modification of the HLB. In southern Utopia, mud diapirs near the Elysium volcanic edifice may have resulted in laccolith-like intrusions that produced the fractured rises, while in the central boundary plain mud diapirs could have extruded to form pitted cones, mounds, and lobate flows, perhaps related to compressional stresses that account for wrinkle ridges. The removal of material a few kilometers deep by diapiric processes may have resulted in subsidence and deformation of surface materials to form widespread cavi. Collectively, these inferences suggest that sedimentary diapirism and mud volcanism as well as related surface deformations could have been the dominant Hesperian mechanisms that altered the regional boundary plain. We discuss a model in which detritus would have accumulated thickly in the annular spaces between impact-generated structural rings of Utopia basin. We envision that these materials, and perhaps buried ejecta of Utopia basin, contained volatile-rich, low-density material that could provide the source material for the postulated sedimentary diapirs. Thick, water-rich, low-density sediments buried elsewhere along the HLB and within the lowland plains may account for similar landforms and resurfacing histories.     

Mars Reconnaissance Orbiter observations of light-toned layered deposits and associated fluvial landforms on the plateaus adjacent to Valles Marineris

We have used data from the Mars Reconnaissance Orbiter to study 30-80 m thick light-toned layered deposits on the plateaus adjacent to Valles Marineris at five locations: (1) south of Ius Chasma, (2) south of western Melas Chasma, (3) south of western Candor Chasma, (4) west of Juventae Chasma, and (5) west of Ganges Chasma. The beds within these deposits have unique variations in brightness, color, mineralogy, and erosional properties that are not typically observed in light-toned layered deposits within Valles Marineris or many other equatorial areas on Mars. Reflectance spectra indicate these deposits contain opaline silica and Fe-sulfates, consistent with low-temperature, acidic aqueous alteration of basaltic materials. We have found valley or channel systems associated with the layered deposits at all five locations, and the volcanic plains adjacent to Juventae, Ius, and Ganges exhibit inverted channels composed of light-toned beds. Valleys, channels, and light-toned layering along the walls of Juventae and Melas Chasmata are most likely coeval to the aqueous activity that affected the adjacent plateaus and indicate some hydrological activity occurred after formation of the chasmata. Although the source of water and sediment remains uncertain, the strong correlation between fluvial landforms and light-toned layered deposits argues for sustained precipitation, surface runoff, and fluvial deposition occurring during the Hesperian on the plateaus adjacent to Valles Marineris and along portions of chasmata walls.     

Paleolakes, paleofloods, and depressions in Aurorae and Ophir Plana, Mars: Connectivity of surface and subsurface hydrological systems

The plains of Aurorae and Ophir in the equatorial region of Mars display geomorphic evidence indicative of extensive but generally short-lived paleohydrological processes. Elaver Vallis in Aurorae Planum south of Ganges Chasma is an outflow channel system >180 km long, and here inferred to have formed by cataclysmic spillover flooding from a paleolake(s) contained in the Morella crater basin. Ganges Cavus is an enormous 5-km-deep depression of probable collapse origin located in the Morella basin. The fluid responsible for the infilling of the Morella basin likely emerged at least partially through Ganges Cavus or its incipient depression, and it may have been supplied also from small-scale springs in the basin. Similar paleohydrological processes are inferred also in Ophir Planum. It is reasonable to assume that water, sometimes sediment-laden and/or mixed with gases, was the responsible fluid for these phenomena although some of the observed features could be explained by non-aqueous processes such as volcanism. Water emergence may have occurred as consequences of ground ice melting or breaching of cryosphere to release water from the underlying hydrosphere. Dike intrusion is considered to be an important cause of formation for the cavi and smaller depressions in Aurorae and Ophir Plana, explaining also melting of ground ice or breaching of cryosphere. Alternatively, the depressions and crater basins may have been filled by regional groundwater table rising during the period(s) when cryosphere was absent or considerably thin. The large quantities of water necessary for explaining the paleohydrological processes in Aurorae and Ophir Plana could have been derived through crustal migration from the crust of higher plains in western Ophir Planum where water existed in confined aquifers or was produced by melting of ground ice due to magmatic heating or climatic shift, or from a paleolake in Candor Chasma further west.     

Spectral evidence for zeolite in the dust on Mars

Spectral features observed in Mars Global Surveyor Thermal Emission Spectrometer data (∼1670-220 cm⁻¹) of martian surface dust provide clues to its mineralogy. An emissivity peak at ∼1630 cm⁻¹ is consistent with the presence of an H₂O-bearing mineral. This spectral feature can be mapped globally and shows a distribution related to the classical bright regions on Mars that are known to be dust covered. An important spectral feature at ∼830 cm⁻¹ present in a newly derived average spectrum of surface dust likely is a transparency feature arising from the fine particulate nature of the dust. Its shape and location are consistent with plagioclase feldspars and also zeolites, which essentially are the hydrous form of feldspar. The generally favored visible/near-infrared spectral analog for martian dust, JSC Mars-1 altered tephra, does not display the ∼830 cm⁻¹ feature. Zeolites commonly form from the interaction of low temperature aqueous fluids and volcanic glass in a variety of geologic settings. The combination of spectral features that are consistent with zeolites and the likelihood that Mars has (or had) geologic conditions necessary to produce them makes a strong case for recognizing zeolite minerals as likely components of the martian regolith.     

Hydration state of zeolites, clays, and hydrated salts under present-day martian surface conditions: Can hydrous minerals account for Mars Odyssey observations of near-equatorial water-equivalent hydrogen?

Thermodynamic data for several clays, zeolites, and MgSO₄ salts were combined with calculated yearly mean temperatures and water-vapor pressures on the martian surface to predict mineral hydration states from low to middle latitudes. These predictions were used to evaluate whether the necessary amount and distribution of hydrous minerals were compatible with the Mars Odyssey observations of water-equivalent hydrogen (WEH). Our results indicate that zeolites like chabazite or clay minerals like Ca-montmorillonite would have to be unrealistically abundant in the martian soil (as much as 55 wt%) while Mg-sulfate hydrates at concentrations between 2 and 11 wt% could account for the WEH. However, the geographic distribution of WEH is incompatible with a uniformly distributed mineralogy in equilibrium with the annual mean P-T environment. A heterogeneous distribution of a mixture of different hydrous minerals, reflecting a heterogeneous Mars surface geology, may better explain a significant portion of the observed near-equatorial WEH.     

Mojave Mars simulant—Characterization of a new geologic Mars analog

We have identified and characterized a basaltic Mars simulant that is available as whole rocks, sand and dust. The source rock for the simulant is a basalt mined from the Tertiary Tropico Group in the western Mojave Desert. The Mojave Mars Simulant (MMS) was chosen for its inert hygroscopic characteristics, its availability in a variety of forms, and its physical and chemical characteristics. The MMS dust and MMS sand are produced by mechanically crushing basaltic boulders. This is a process that more closely resembles the weathering/comminution processes on Mars where impact events and aerodynamic interactions provide comminution in the (relative) absence of water and organics. MMS is among the suite of test rocks and soils that was used in the development of the 2007/8 Phoenix Scout and is being used in the 2009 Mars Science Laboratory (MSL) missions. The MMS development team is using the simulant for research that centers on sampling tool interactions in icy soils. Herein we describe the physical properties and chemical composition of this new Mars simulant.     

Light-toned layered deposits in Juventae Chasma, Mars

We examine hypotheses for the formation of light-toned layered deposits in Juventae Chasma using a combination of data from Mars Global Surveyor's Mars Orbiter Camera (MOC), Mars Orbiter Laser Altimeter (MOLA), and Thermal Emission Spectrometer (TES), as well as Mars Odyssey's Thermal Emission Imaging System (THEMIS). We divide Juventae Chasma into geomorphic units of (i) chasm wall rock, (ii) heavily cratered hummocky terrain, (iii) a mobile and largely crater-free sand sheet on the chasm floor, (iv) light-toned layered outcrop (LLO) material, and (v) chaotic terrain. Using surface temperatures derived from THEMIS infrared data and slopes from MOLA, we derive maps of thermal inertia, which are consistent with the geomorphic units that we identify. LLO thermal inertias range from ∼400 to 850 J m⁻² K⁻¹ s^−1/2. Light-toned layered outcrops are distributed over a remarkably wide elevation range () from the chasm floor to the adjacent plateau surface. Geomorphic features, the absence of small craters, and high thermal inertia show that the LLOs are composed of sedimentary rock that is eroding relatively rapidly in the present epoch. We also present evidence for exhumation of LLO material from the west wall of the chasm, within chaotic and hummocky terrains, and within a small depression in the adjacent plateau. The data imply that at least some of the LLO material was deposited long before the adjacent Hesperian plateau basalts, and that Juventae Chasma underwent, and may still be undergoing, enlargement along its west wall due to wall rock collapse, chaotic terrain evolution, and exposure and removal of LLO material. The new data allow us to reassess possible origins of the LLOs. Gypsum, one of the minerals reported elsewhere as found in Juventae Chasma LLO material, forms only at low temperatures () and thus excludes a volcanic origin. Instead, the data are consistent with either multiple occurrences of lacustrine or airfall deposition over an extended period of time prior to emplacement of Hesperian lava flows on the plateau above the chasm.     

Spectral and geological study of the sulfate-rich region of West Candor Chasma, Mars

Sulfates have been discovered by the OMEGA spectrometer in different locations of the planet Mars. They are strongly correlated to light toned layered deposits in the equatorial regions. West Candor Chasma is the canyon with the thickest stack of layers and one with the largest area covered by sulfates. A detailed study coupling mineralogy derived from OMEGA spectral data and geology derived from HRSC imager and other datasets leads to some straightforward issues. The monohydrated sulfate kieserite is found mainly over heavily eroded scarps of light toned material. It likely corresponds to a mineral present in the initial rock formed either during formation and diagenesis of sediments, or during hydrothermal alteration at depth, because it is typically found on outcrops that are eroded and steep. Polyhydrated sulfates, that match any Ca-, Na-, Fe-, or Mg-sulfates with more than one water molecule, are preferentially present on less eroded and darker outcrops than outcrops of kieserite. These variations can be the result of a diversity in the composition and/or of the rehydration of kieserite on surfaces with longer exposure. The latter possibility of rehydration in the current, or recent, atmosphere suggests the low surface temperatures preserve sulfates from desiccation, and, also can rehydrate part of them. Strong signatures of iron oxides are present on sulfate-rich scarps and at the base of layered deposits scarps. They are correlated with TES gray hematite signature and might correspond to iron oxides present in the rock as sand-size grains, or possibly larger concretions, that are eroded and transported down by gravity at the base of the scarp. Pyroxenes are present mainly on sand dunes in the low lying terrains. Pyroxene is strongly depleted or absent in the layered deposits. When mixed with kieserite, local observations favor a spatial mixing with dunes over layered deposits. Sulfates such as those detected in the studied area require the presence of liquid water to form by precipitation, either in an intermittent lacustrine environment or by hydrothermal fluid circulation. Both possibilities require the presence of sulfur-rich groundwater to explain fluid circulation. The elevation of the uppermost sulfate signatures suggests the presence of aquifers up to 2.5 km above datum, only 1 km below the plateau surface.     

Geologically recent gully-polygon relationships on Mars: Insights from the Antarctic Dry Valleys on the roles of permafrost, microclimates, and water sources for surface flow

We describe the morphology and spatial relationships between composite-wedge polygons and Mars-like gullies (consisting of alcoves, channels, and fans) in the hyper-arid Antarctic Dry Valleys (ADV), as a basis for understanding possible origins for martian gullies that also occur in association with polygonally patterned ground. Gullies in the ADV arise in part from the melting of atmospherically-derived, wind-blown snow trapped in polygon troughs. Snowmelt that yields surface flow can occur during peak southern hemisphere summer daytime insolation conditions. Ice-cemented permafrost provides an impermeable substrate over which meltwater flows, but does not significantly contribute to meltwater generation. Relationships between contraction crack polygons and sedimentary fans at the distal ends of gullies show deposition of fan material in polygon troughs, and dissection of fans by expanding polygon troughs. These observations suggest the continuous presence of meters-thick ice-cemented permafrost beneath ADV gullies. We document strong morphological similarities between gullies and polygons on Mars and those observed in the ADV Inland Mixed microclimate zone. On the basis of this morphological comparison, we propose an analogous, top-down melting model for the initiation and evolution of martian gullies that occur on polygonally-patterned, mantled surfaces.     

The effects of the martian regolith on GCM water cycle simulations

This paper describes General Circulation Model (GCM) simulations of the martian water cycle focusing on the effects of an adsorbing regolith. We describe the 10-layer regolith model used in this study which has been adapted from the 1-D model developed by Zent, A.P., Haberle, R.M., Houben, H.C., Jakosky, B.M. [1993. A coupled subsurface-boundary layer model of water on Mars. J. Geophys. Res. 98 (E2), 3319-3337, February]. Even with a 30-min timestep and taking into account the effect of surface water ice, our fully implicit scheme compares well with the results obtained by Zent, A.P., Haberle, R.M., Houben, H.C., Jakosky, B.M. [1993. A coupled subsurface-boundary layer model of water on Mars. J. Geophys. Res. 98 (E2), 3319-3337, February]. This means, however, that the regolith is not able to reproduce the diurnal variations in column water vapour abundance of up to a factor of 2-3 as seen in some observations, with only about 10% of the atmospheric water vapour column exchanging with the subsurface on a daily basis. In 3-D simulations we find that the regolith adsorbs water preferentially in high latitudes. This is especially true in the northern hemisphere, where perennial subsurface water ice builds up poleward of 60° N at depths which are comparable to the Odyssey observations. Much less ice forms in the southern high latitudes, which suggests that the water ice currently present in the martian subsurface is not stable under present conditions and is slowly subliming and being deposited in the northern hemisphere. When initialising the model with an Odyssey-like subsurface water ice distribution the model is capable of forcing the simulated water cycle from an arbitrary state close to the Mars Global Surveyor Thermal Emission Spectrometer observations. Without the actions of the adsorbing regolith the equilibrated water cycle is found to be a factor of 2-4 too wet. The process by which this occurs is by adsorption of water during northern hemisphere summer in northern mid and high latitudes where it remains locked in until northern spring when the seasonal CO₂ ice cap retreats. At this time the water diffuses out of the regolith in response to increased temperature and is returned to the residual water ice cap by eddie transport.     

Spectral reflectance properties of minerals exposed to simulated Mars surface conditions

A number of mineral species were exposed to martian surface conditions of atmospheric pressure and composition, temperature, and UV light regime, and their evolution was monitored using reflectance spectroscopy. The stabilities for different groups varied widely. Phyllosilicate spectra all showed measurable losses of interlayer H₂O, with some structural groups showing more rapid H₂O loss than others. Loss of OH from the phyllosilicates is not always accompanied by a change in metal-OH overtone absorption bands. OH-bearing sulfates, such as jarosite and alunite, show no measurable change in spectral properties, suggesting that they should be spectrally detectable on Mars on the basis of diagnostic absorption bands in the 0.4-2.5 μm region. Fe³⁺- and H₂O-bearing sulfates all showed changes in the appearance and/or reduction in depths of hydroxo-bridged Fe³⁺ absorption bands, particularly at 0.43 μm. The spectral changes were often accompanied by visible color changes, suggesting that subsurface sulfates exposed to the martian surface environment may undergo measurable changes in reflectance spectra and color over short periods of time (days to weeks). Organic-bearing geological materials showed no measurable change in CH related absorption bands, while carbonates and hydroxides also showed no systematic changes in spectral properties. The addition of ultraviolet irradiation did not seem to affect mineral stability or rate of spectral change, with one exception (hexahydrite). In some cases, spectral changes could be related to the formation of specific new phases. The data also suggest that hydrated minerals detected on Mars to date retain their diagnostic spectral properties that allow their unique identification.     

Geological features indicative of processes related to the hematite formation in Meridiani Planum and Aram Chaos, Mars: a comparison with diagenetic hematite deposits in southern Utah, USA

In order to understand the formation of the few but large, hematite deposits on Mars, comparisons are often made with terrestrial hematite occurrences. In southern Utah, hematite concretions have formed within continental sandstones and are exposed as extensive weathered-out beds. The hematite deposits are linked to geological and geomorphological features such as knobs, buttes, bleached beds, fractures and rings. These terrestrial features are visible in aerial and satellite images, which enables a comparison with similar features occurring extensively in the martian hematite-rich areas. The combination of processes involved in the movement and precipitation of iron in southern Utah can provide new insights in the context of the hematite formation on Mars. Here we present a mapping of the analogue geological and geomorphological features in parts of Meridiani Planum and Aram Chaos. Based on mapping comparisons with the Utah occurrences, we present models for the formation of the martian analogues, as well as a model for iron transport and precipitation on Mars. Following the Utah model, high albedo layers and rings in the mapped area on Mars are due to removal or lack of iron, and precipitation of secondary diagenetic minerals as fluids moved up along fractures and permeable materials. Hematite was precipitated intraformationally where the fluid transporting the reduced iron met oxidizing conditions. Our study shows that certain geological/geomorphological features can be linked to the hematite formation on Mars and that pH differences could suffice for the transport of the iron from an orthopyroxene volcanoclastic source rock. The presence of organic compounds can enhance the iron mobilization and precipitation processes. Continued studies will focus on possible influence of biological activity and/or methane in the formation of the hematite concretions in Utah and on Mars.     

Extensive hydrated silica materials in western Hellas Basin,Mars

Near-infrared spectral data indicate the presence of hydrated, poorly crystalline silica where high bulk silica contents have been previously identified in Hellas Basin. No other aqueous phases are identified in these regions and the deposits may be nearly pure. The silica-bearing surfaces are sporadically exposed along a 650 km stretch of the western basin rim within a limited elevation range and display a variety of surface textures suggesting that the materials have been reworked, but not transported large distances. The high abundances and lack of associated aqueous phases indicate that high water to rock ratios were present in the region during the Noachian period but without elevated temperatures or for durations necessary for quartz diagenesis. The silica-bearing materials may have formed via direct precipitation from silica saturated groundwater sources, although other formation mechanisms are also plausible.     

Stability of ice on Mars and the water vapor diurnal cycle: Experimental study of the sublimation of ice through a fine-grained basaltic regolith

In order to advance our understanding of the long-term stability of subsurface ice, the diurnal martian water cycle, and implications for liquid water, we determined diffusion coefficients and adsorption kinetics for the water vapor produced by the sublimation of ice buried beneath various layers of fine-grained (<63, 63-125, and 125-250 μm) basaltic powder under simulated martian conditions. Sublimation rates at shallower depths, <10 mm, were determined to be affected by mass transfer through the atmosphere in addition to the basalt layer. For greater depths, the measured diffusion coefficients for water vapor moving through basalt grains were 1.56±0.53×¹⁰⁻⁴, 2.05±0.82×¹⁰⁻⁴, and for the <63, 63-125, and 125-250 μm basaltic layers, respectively. Through the Brunauer, Emmett and Teller (BET) isotherm, which assumes multiple molecular layers of adsorbed water, we determined the adsorption constants of 52.6±8.3 at 270 K for <63 μm, 39.0±6.4 at 267 K for 63-125 μm, and 54.3±9.3 at 266 K for 125-250 μm, resulting in surface areas of 2.6±0.1×¹⁰⁴, 1.7±0.3×¹⁰⁴, , respectively. These results suggest that while diffusion is too rapid to explain the purported diurnal cycle in water content of the atmosphere, adsorption is efficient and rapid, and does provide an effective mechanism to explain such a cycle. The present diffusion data suggest that very thin, <50 pr μm, shallow, 10 mm, ice deposits would last for >10 h at ∼224 K, just above the freezing point of saturated CaCl₂. Temperatures can remain above ∼224 K over most of the planet, which means that water, even as saturated brine, will sublimate before the freezing point is reached and liquid could be formed. On the other hand, 1 m ice layers below 1 m of fine-grained basaltic regolith at 235 K and 10 Pa of atmospheric water could last 600 to 1300 years. At deeper depths and lower temperatures, ice could last since the last major obliquity change 400,000 years ago.