Hydrous Silicates and Water on Venus

We used thermochemical equilibrium calculations to predict stabilities of pure rock-forming hydrous silicates on Venus' surface as a function of elevation, atmospheric H₂O and SO₂concentrations, and oxygen fugacity (f_O2). About 50 different hydrous silicates were included in our calculations. We find that many of these are unstable on Venus's surface because of the low atmospheric H₂O content of 30–45 parts per million by volume (ppmv) and the high surface temperatures (660 K on Maxwell Montes to 740 K in the plains). Hydrous Fe²⁺-bearing silicates are unstable due to oxidation to magnetite and/or hematite at the f_O2of the near-surface atmosphere. Ca-bearing hydrous silicates are unstable because of sulfatization to anhydrite. Some Fe-free micas (e.g., eastonite, eastonite–phlogopite micas), and some alkali amphiboles might be stable on Venus' surface, especially in the lower temperature highlands. We discuss hydrous mineral formation in the interior and on the surface of Venus. We review the literature on mica and amphibole thermal decomposition and find that dehydration of phlogopitic micas and fibrous amphiboles produces (metastable) dehydroxylated anhydrides that decompose to more stable minerals at temperatures hundreds of degrees higher than the onset of dehydroxylation. These observations raise the possibility that anhydrides formed from hydrous silicates, which may have been present during a wetter period in Venus' history, may persist somewhere on Venus' present surface. We discuss experiments that could be used on future spacecraft missions to detect hydroxyl in rocks and hydrous silicates on Venus. Finally, we review estimates of the amount of water and OH (hydroxyl) in the Earth's mantle. Based on this review, we suggest that even if no hydrous silicates are stable on Venus, significant amounts of water are plausibly present in surface rocks as OH in nominally anhydrous minerals.     

New wind measurements in Venus’ lower mesosphere from visible spectroscopy

The dynamics of Venus’ mesosphere (70–110 km) is characterized by the superposition of two different wind regimes: (1) Venus’ retrograde superrotation; (2) a sub-solar to anti-solar (SS–AS) flow pattern, driven by solar EUV heating on the sunlit hemisphere. Here, we report on new ground-based velocity measurements in the lower part of the mesosphere. We took advantage of two essentially symmetric Venus elongations in 2001 and 2002 to perform high-resolution Doppler spectroscopy (R=120,000) in ¹²C¹⁶O₂ visible lines of the 5ν₃ band and in a few solar Fraunhofer lines near 8700 Å. These measurements, mapped over several points on Venus’ illuminated hemisphere, probe the region of cloud tops. More precisely, the solar Fraunhofer lines sample levels a few kilometers below the UV features (i.e. near ∼67 km), while the CO₂ lines probe an altitude higher by about 7 km. The wind field over Venus’ disk is retrieved with an rms uncertainty of 15–25 m s⁻¹ on individual measurements. Kinematical fit to a one- or two-component circulation model indicates the dominance of the zonal retrograde flow with a mean equatorial velocity of ∼75 m s⁻¹, exhibiting very strong day-to-day variations (±65 m s⁻¹). Results are very consistent for the two kinds of lines, suggesting a negligible vertical wind shear over 67–74 km. The SS–AS flow is not detected in single-day observations, but combining the results from all data suggests that this component may invade the lower mesosphere with a ∼40 m s⁻¹ velocity.     

The planetary fourier spectrometer (PFS) onboard the European Venus Express mission

The planetary fourier spectrometer (PFS) for the Venus Express mission is an infrared spectrometer optimized for atmospheric studies. This instrument has a short wavelength (SW) channel that covers the spectral range from 1700 to 11400 cm⁻¹ (0.9–5.5 μm) and a long wavelength (LW) channel that covers 250–1700 cm⁻¹ (5.5–45 μm). Both channels have a uniform spectral resolution of 1.3 cm⁻¹. The instrument field of view FOV is about 1.6 ° (FWHM) for the short wavelength channel and 2.8 ° for the LW channel which corresponds to a spatial resolution of 7 and 12 km when Venus is observed from an altitude of 250 km. PFS can provide unique data necessary to improve our knowledge not only of the atmospheric properties but also surface properties (temperature) and the surface-atmosphere interaction (volcanic activity).PFS works primarily around the pericentre of the orbit, only occasionally observing Venus from larger distances. Each measurements takes 4.5 s, with a repetition time of 11.5 s. By working roughly 1.5 h around pericentre, a total of 460 measurements per orbit will be acquired plus 60 for calibrations. PFS is able to take measurements at all local times, enabling the retrieval of atmospheric vertical temperature profiles on both the day and the night side.The PFS measures a host of atmospheric and surface phenomena on Venus. These include the:(1) thermal surface flux at several wavelengths near 1 μm, with concurrent constraints on surface temperature and emissivity (indicative of composition); (2) the abundances of several highly-diagnostic trace molecular species; (3) atmospheric temperatures from 55 to 100 km altitude; (4) cloud opacities and cloud-tracked winds in the lower-level cloud layers near 50-km altitudes; (5) cloud top pressures of the uppermost haze/cloud region near 70–80 km altitude; and (6) oxygen airglow near the 100 km level. All of these will be observed repeatedly during the 500-day nominal mission of Venus Express to yield an increased understanding of meteorological, dynamical, photochemical, and thermo-chemical processes in the Venus atmosphere. Additionally, PFS will search for and characterize current volcanic activity through spatial and temporal anomalies in both the surface thermal flux and the abundances of volcanic trace species in the lower atmosphere.Measurement of the 15 μm CO₂ band is very important. Its profile gives, by means of a complex temperature profile retrieval technique, the vertical pressure-temperature relation, basis of the global atmospheric study.PFS is made of four modules called O, E, P and S being, respectively, the interferometer and proximity electronics, the digital control unit, the power supply and the pointing device.     

Sulfur chemistry in the middle atmosphere of Venus

Venus Express measurements of the vertical profiles of SO and SO₂ in the middle atmosphere of Venus provide an opportunity to revisit the sulfur chemistry above the middle cloud tops (～58 km). A one dimensional photochemistry-diffusion model is used to simulate the behavior of the whole chemical system including oxygen-, hydrogen-, chlorine-, sulfur-, and nitrogen-bearing species. A sulfur source is required to explain the SO₂ inversion layer above 80 km. The evaporation of the aerosols composed of sulfuric acid (model A) or polysulfur (model B) above 90 km could provide the sulfur source. Measurements of SO₃ and SO (a¹Δ → X³Σ^-) emission at 1.7 μm may be the key to distinguish between the two models.     

Venus Monitoring Camera for Venus Express

The Venus Express mission will focus on a global investigation of the Venus atmosphere and plasma environment, while additionally measuring some surface properties from orbit. The instruments PFS and SPICAV inherited from the Mars Express mission and VIRTIS from Rosetta form a powerful spectrometric and spectro-imaging payload suite. Venus Monitoring Camera (VMC)—a miniature wide-angle camera with 17.5° field of view—was specifically designed and built to complement these experiments and provide imaging context for the whole mission. VMC will take images of Venus in four narrow band filters (365, 513, 965, and 1000 nm) all sharing one CCD. Spatial resolution on the cloud tops will range from 0.2 km/px at pericentre to 45 km/px at apocentre when the full Venus disc will be in the field of view. VMC will fulfill the following science goals: (1) study of the distribution and nature of the unknown UV absorber; (2) determination of the wind field at the cloud tops (70 km) by tracking the UV features; (3) thermal mapping of the surface in the 1 μm transparency “window” on the night side; (4) determination of the global wind field in the main cloud deck (50 km) by tracking near-IR features; (5) study of the lapse rate and H₂O content in the lower 6–10 km; (6) mapping O₂ night-glow and its variability.     

High-resolution spectroscopy of Venus: Detection of OCS, upper limit to H2S, and latitudinal variations of CO and HF in the upper cloud layer

Venus was observed at 2.4 and 3.7 μm with a resolving power of 4×¹⁰⁴ using the long-slit high-resolution spectrograph CSHELL at NASA IRTF. The observations were made along a chord that covered a latitude range of ± 60° at a local time near 8:00. The continuous reflectivity and limb brightening at 2.4 μm are fitted by the clouds with a single scattering albedo 1−a=0.01 and a pure absorbing layer with τ=0.09 above the clouds. The value of 1−a agrees with the refractive index of H₂SO₄ (85%) and the particle radius of 1 μm. The absorbing layer is similar to that observed by the UV spectrometer at the Pioneer Venus orbiter. However, its nature is puzzling. CO₂ was measured using its R32 and R34 lines. The retrieved product of the CO₂ abundance and airmass is constant at 1.9 km-atm along the instrument slit in the latitude range of ± 60°. The CO mixing ratio (measured using the P21 line) is rather constant at 70 ppm, and its variations of ∼10% may be caused by atmospheric dynamics. The observed value is higher than the 50 ppm retrieved previously from a spectrum of the full disk, possibly, because of some downward extension of the mesospheric morningside bulge of CO. The observations of the HF R3 line reveal a constant HF mixing ratio of 3.5±0.5 ppb within ± 60° of latitude, which is within the scatter in the previous measurements of HF. OCS has been detected for the first time at the cloud tops by summing 17 lines of the P-branch. The previous detections of OCS refer to the lower atmosphere at 30-35 km. The retrieved OCS mixing ratio varies with a scale height of 1 to 3 km. The mean OCS mixing ratio is ∼2 ppb at 70 km and ∼14 ppb at 64 km. Vertical motions in the atmosphere may change the OCS abundance. The detected OCS should significantly affect Venus' photochemistry. A sensitive search for H₂S using its line at 2688.93 cm⁻¹ results in a 3 sigma upper limit of 23 ppb, which is more restrictive than the previous limit of 100 ppb.     

Atomic oxygen on the Venus nightside: Global distribution deduced from airglow mapping

The Visible and Infra-Red Thermal Imaging Spectrometer (VIRTIS) instrument on board the Venus Express spacecraft has measured the O₂(a¹Δ) nightglow distribution at 1.27 μm in the Venus mesosphere for more than two years. Nadir observations have been used to create a statistical map of the emission on Venus nightside. It appears that the statistical 1.6 MR maximum of the emission is located around the antisolar point. Limb observations provide information on the altitude and on the shape of the emission layer. We combine nadir observations essentially covering the southern hemisphere, corrected for the thermal emission of the lower atmosphere, with limb profiles of the northern hemisphere to generate a global map of the Venus nightside emission at 1.27 μm. Given all the O₂(a¹Δ) intensity profiles, O₂(a¹Δ) and O density profiles have been calculated and three-dimensional maps of metastable molecular and atomic oxygen densities have been generated. This global O density nightside distribution improves that available from the VTS3 model, which was based on measurements made above 145 km. The O₂(a¹Δ) hemispheric average density is 2.1 × 10⁹ cm^?3, with a maximum value of 6.5 × 10⁹ cm^?3 at 99.2 km. The O density profiles have been derived from the nightglow data using CO₂ profiles from the empirical VTS3 model or from SPICAV stellar occultations. The O hemispheric average density is 1.9 × 10¹¹ cm^?3 in both cases, with a mean altitude of the peak located at 106.1 km and 103.4 km, respectively. These results tend to confirm the modeled values of 2.8 × 10¹¹ cm^?3 at 104 km and 2.0 × 10¹¹ cm^?3 at 110 km obtained by Brecht et al. [Brecht, A., Bougher, S.W., Gérard, J.-C., Parkinson, C.D., Rafkin, S., Foster, B., 2011a. J. Geophys. Res., in press] and Krasnopolsky [Krasnopolsky, V.A., 2010. Icarus 207, 17–27], respectively. Comparing the oxygen density map derived from the O₂(a¹Δ) nightglow observations, it appears that the morphology is very different and that the densities obtained in this study are about three times higher than those predicted by the VTS3 model.     

Radio science investigations by VeRa onboard the Venus Express spacecraft

The Venus Express Radio Science Experiment (VeRa) uses radio signals at wavelengths of 3.6 and 13 cm (“X”- and “S”-band, respectively) to investigate the Venus surface, neutral atmosphere, ionosphere, and gravity field, as well as the interplanetary medium. An ultrastable oscillator (USO) provides a high quality onboard reference frequency source; instrumentation on Earth is used to record amplitude, phase, propagation time, and polarization of the received signals. Simultaneous, coherent measurements at the two wavelengths allow separation of dispersive media effects from classical Doppler shift.VeRa science objectives include the following:

• (1)Determination of neutral atmospheric structure from the cloud deck (approximately 40 km altitude) to 100 km altitude from vertical profiles of neutral mass density, temperature, and pressure as a function of local time and season. Within the atmospheric structure, search for, and if detected, study of the vertical structure of localized buoyancy waves, and the presence and properties of planetary waves.
• (2)Study of the H₂SO₄ vapor absorbing layer in the atmosphere by variations in signal intensity and application of this information to tracing atmospheric motions. Scintillation effects caused by radio wave diffraction within the atmosphere can also provide information on small-scale atmospheric turbulence.
• (3)Investigation of ionospheric structure from approximately 80 km to the ionopause (<600 km), allowing study of the interaction between solar wind plasma and the Venus atmosphere.
• (4)Observation of forward-scattered surface echoes obliquely reflected from selected high-elevation targets with anomalous radar properties (such as Maxwell Montes). More generally, such bistatic radar measurements provide information on the roughness and density of the surface material on scales of centimeters to meters.
• (5)Detection of gravity anomalies, thereby providing insight into the properties of the Venus crust and lithosphere.
• (6)Measurement of the Doppler shift, propagation time, and frequency fluctuations along the interplanetary ray path, especially during periods of superior conjunction, thus enabling investigation of dynamical processes in the solar corona.

     

Vertical profiling of SO2 and SO above Venus’ clouds by SPICAV/SOIR solar occultations

New measurements of sulfur dioxide (SO₂) and monoxide (SO) in the atmosphere of Venus by SPICAV/SOIR instrument onboard Venus Express orbiter provide ample statistics to study the behavior of these gases above Venus’ clouds. The instrument (a set of three spectrometers) is capable to sound atmospheric structure above the clouds in several observation modes (nadir, solar and stellar occultations) either in the UV or in the near IR spectral ranges. We present the results from solar occultations in the absorption ranges of SO₂ (190–230 nm, and at 4 μm) and SO (190–230 nm). The dioxide was detected by the SOIR spectrometer at the altitudes of 65–80 km in the IR and by the SPICAV spectrometer at 85–105 km in the UV. The monoxide’s absorption was measured only by SPICAV at 85–105 km. We analyzed 39 sessions of solar occultation, where boresights of both spectrometers are oriented identically, to provide complete vertical profiling of SO₂ of the Venus’ mesosphere (65–105 km). Here we report the first firm detection and measurements of two SO₂ layers. In the lower layer SO₂ mixing ratio is within 0.02–0.5 ppmv. The upper layer, also conceivable from microwave measurements by Sandor et al. (Sandor, B.J., Todd Clancy, R., Moriarty-Schieven, G., Mills, F.P. [2010]. Icarus 208, 49–60) is characterized by SO₂ increasing with the altitude from 0.05 to 2 ppmv, and the [SO₂]/[SO] ratio varying from 1 to 5. The presence of the high-altitude SO_x species could be explained by H₂SO₄ photodissociation under somewhat warmer temperature conditions in Venus mesosphere. At 90–100 km the content of the sulfur dioxide correlates with temperature increasing from 0.1 ppmv at 165–170 K to 0.5–1 ppmv at 190–192 K. It supports the hypothesis of SO₂ production by the evaporation of H₂SO₄ from droplets and its subsequent photolysis at around 100 km.     

The modeling of Venus' degassing in terms of K-Ar system

In terms of Ozima's model of argon degassing the Venus' model is presented based on Pioneer Venus and Venera space mission atmospheric composition data. The geochemical conclusions are obtained as following: the Venus' crust is presumably basaltic with potassium content lower than 0.5%; the exterior nonradiogenic³⁶Ar contribution to the total argon inventory is estimated as at least 95%; almost complete argon degassing in the first 0.5 m.y. is supposed. The model is in agreement only with low volcanic productivity on Venus (<5 km³ yr^–1).This value is consistent with the assumption on the lithospheric conductivity as a dominating contribution to the heat losses of Venus' interior in contrast to the hot spot mechanism.     

Direct wind measurements from November 2007 in Venus’ upper atmosphere using ground-based heterodyne spectroscopy of CO2 at 10 μm wavelength

Between November 23 and 28, 2007, the Cologne Tuneable Heterodyne Infrared Spectrometer THIS was installed at the McMath-Pierce Solar Telescope (Kitt Peak, Arizona, USA) to determine zonal wind velocities and to estimate the subsolar-to-antisolar flow. We investigate dynamics in the upper atmosphere of Venus by measuring the Doppler shift of fully-resolved non-LTE CO₂ emission lines at 959.3917 cm^?1 (10.423 μm), which probe a narrow altitude region in Venus’ atmosphere around 110 ± 10 km (～1 μbar). The results show no significant zonal wind velocity at the equator. An increase with latitude up to 43 ± 13 m/s at a latitude of 33°N was observed. This confirms the deduction of a minor influence of Venus superrotation at an altitude of 110 km from previous measurements in May 2007 (Sornig et al., 2008). The specific observing geometry enables estimating the maximum cross terminator velocity of the subsolar-to-antisolar flow at 72 ± 47 m/s.     

Latitudinal distribution of HDO abundance above Venus’ clouds by ground-based 2.3 μm spectroscopy

The abundance of HDO above the clouds in the dayside atmosphere of Venus was measured by ground-based 2.3 μm spectroscopy over 4 days. This is the first HDO observation above the clouds in this wavelength region corresponding to a new height region. The latitudinal distributions found show no clearly defined structure. The disk-averaged mixing ratio is 0.22 ± 0.03 ppm for a representative height region of 62–67 km. This is consistent with measurements found in previous studies. Based on previous H₂O measurements, the HDO/H₂O ratio is found to be 140 ± 20 times larger than the telluric ratio. This lies between the ratios of 120 ± 40 and 240 ± 25, respectively, reported for the 30–40 km region by ground-based nightside spectroscopy and for the 80–100 km region by solar occultation measurement on board the Venus Express.     

The global budget of impact-derived sediments on Venus

The observed record of impact craters on the surface of the planet Venus can be used to calculate the contribution of fine materials generated by impact processes to the global sedimentary cycle. Using various methods for the extending the population of impact craters with diameters larger than 8 km observed on the northern 25% of the Venus to the entire surface area of the planet, we have estimated how materials ejected from the integrated record of impact cratering over the past 0.5 to 1.0 æ might have been globally distributed. Relationships for computing the fraction of ejected materials from impact craters in a given size range originally developed for the Moon (and for terrestrial nuclear explosion cratering experiments) were scaled for Venus conditions, and the ejecta fragments with sizes less than 30 m were considered to represent those with the greatest potential for global transport and eventual fallout. A similar set of calculations were carried out using the observed terrestrial cratering record, corrected for the missing population of small craters and oceanic impacts that have either been eroded or are unobserved (due to water cover). Our calculations suggest that both Venus and the Earth should have experienced approximately 6000 impact events over the past 0.5 to 1 æ (in the size range from 1 km to about 180 km). The cumulative global thickness of impact-derived fine materials that could have produced from this record of impacts in this time period is most likely between 1–2 mm for Venus, and certainly no more than 6 mm (assuming an enhanced population of large 150–200 km scale impact events). For Earth, the global cumulative thickness is most likely 0.2 to 0.3 mm, and certainly no more than 2 to 3 mm. The cumulative volume of impact ejecta (independent of particle size) for Venus generated over the past 1 æ, when spread out over the global surface area to form a uniform layer, would fall between 2 and 12 meters, although 99% of this material would be deposited in the near rim ejecta blanket (from 1 to 2.3 crater radii from the rim crest), and only 0.02% would be available for global transport as dust-sized particles. Thus, our conclusion is that Venus, as with the Earth, cannot have formed a substantial impact-derived regolith layer over the past billion years of its history as is typical for smaller silicate planets such as the Moon and Mercury. This conclusion suggests that there must be other extant mechanisms for sediment formation and redistribution in the Venus environment, on the basis of Venera Lander surface panoramas which demonstrate the occurrence of local sediment accumulations.'Geology and Tectonics of Venus', special issue edited by Alexander T. Basilevsky (USSR Acad. of Sci. Moscow), James W. Head (Brown University, Providence), Gordon H. Pettengill (MIT, Cambridge, Massachusetts) and R. S. Saunders (J.P.L., Pasadena).     

Water vapor variations in the Venus mesosphere from microwave spectra

Mm-wave spectra of HDO in the Venus mesosphere (65-100 km) were obtained over the period March 1998 to June 2004. Each spectrum is a measurement of the hemispheric-average H₂O vapor mixing ratio in the Venus mesosphere. Observations were conducted for wide ranges of Venus solar elongations (46° W to 47° E), and fractional disk illuminations (f=0% to 99%), yielding water vapor abundances on 17 dates and over a full range of local solar time (LST) at the sub-Earth point on Venus. Our mesopheric H₂O values are more numerous and far more precise than the earliest mm-derived H₂O measurements [Encrenaz, Th., Lellouch, E., Paubert, G., Gulkis, S., 1991. First detection of HDO in the atmosphere of Venus at radio wavelengths: An estimate of the H₂O vertical distribution. Astron. Astrophys. 246, L63-L66; Encrenaz, Th., Lellouch, E., Cernicharo, J., Paubert, G., Gulkis, S., Spilker, T., 1995. The thermal profile and water abundance in the Venus mesosphere from H₂O and HDO millimeter observations. Icarus 117, 162-172], allowing an analysis of variability that was previously impossible. Measured 65-100 km H₂O ranged from 0.0±0.06 to 3.5±0.3 ppmv, with significantly different variability than found in previous infrared (lower altitude, cloudtop) studies. Strong global variability on a 1-2 month timescale is clear and unambiguous. A limited number of excellent s/n measurements tentatively indicate the 1-2 month variability manifests most rapidly as change in the lower mesosphere, and more slowly as change in the upper mesosphere. Neither long term (1998-2004) nor diurnal variability in 65-100 km H₂O is evident. While six-year and/or diurnal variabilities are not ruled out, they are weaker than the 1-2 month timescale variation. These conclusions are supported by initial (2004) sub-mm measurements.     

Observation of DCl and upper limit to NH3 on Venus

To search for DCl in the Venus atmosphere, a spectrum near the D³⁵Cl (1–0) R4 line at 2141.54 cm^?1 was observed using the CSHELL spectrograph at NASA IRTF. Least square fitting to the spectrum by a synthetic spectrum results in a DCl mixing ratio of 17.8 ± 6.8 ppb. Comparing to the HCl abundance of 400 ± 30 ppb (Krasnopolsky [2010a] Icarus, 208, 314–322), the DCl/HCl ratio is equal to 280 ± 110 times the terrestrial D/H = 1.56 × 10^?4. This ratio is similar to that of HDO/H₂O = 240 ± 25 times the terrestrial HDO/H₂O from the VEX/SOIR occultations at 70–110 km. Photochemistry in the Venus mesosphere converts H from HCl to that in H₂O with a rate of 1.9 × 10⁹ cm^?2 s^?1 (Krasnopolsky [2012] Icarus, 218, 230–246). The conversion involves photolysis of HCl; therefore, the photochemistry tends to enrich D/H in HCl and deplete in H₂O. Formation of the sulfuric acid clouds may affect HDO/H₂O as well. The enriched HCl moves down by mixing to the lower atmosphere where thermodynamic equilibriums for H₂ and HCl near the surface correspond to D/H = 0.71 and 0.74 times that in H₂O, respectively. Time to establish these equilibriums is estimated at ～3 years and comparable to the mixing time in the lower atmosphere. Therefore, the enriched HCl from the mesosphere gives D back to H₂O near the surface. Comparison of chemical and mixing times favors a constant HDO/H₂O up to ～100 km and DCl/HCl equal to D/H in H₂O times 0.74.Ammonia is an abundant form of nitrogen in the reducing environments. Thermodynamic equilibriums with N₂ and NO near the surface of Venus give its mixing ratio of 10^?14 and 6 × 10^?7, respectively. A spectrum of Venus near the NH₃ line at 4481.11 cm^?1 was observed at NASA IRTF and resulted in a two-sigma upper limit of 6 ppb for NH₃ above the Venus clouds. This is an improvement of the previous upper limit by a factor of 5. If ammonia exists at the ppb level or less in the lower atmosphere, it quickly dissociates in the mesosphere and weakly affects its photochemistry.     

Processes of crustal formation and evolution on Venus: An analysis of topography,hypsometry, and crustal thickness variations

On Venus, present evidence indicates a crust of predominantly basaltic composition and a relatively young average age for the surface (several hundreds of millions of years). Estimates of crustal thickness from several approaches suggest an average crustal thickness of 10–20 km for much of the lowlands and rolling plains and a total volume of crust of about 1 × 10¹⁰ km³, approximately comparable to the present crustal volume of the Earth (1.02 × 10¹⁰ km³). The Earth's oceanic crust is thought to have been recycled at least 10–20 times over Earth history. The near-coincidence in present crustal volumes for the Earth and Venus suggests that either: (1) the presently observed crust of Venus represents the total volume that has accumulated over the history of the planet and that crustal production rates are thus very low, or (2) that crustal production rates are higher and that there is a large volume of missing crust unaccounted for on Venus which may have been lost by processes of crustal recycling.Known processes of crustal formation and thickening (impact-related magma ocean, vertical differentiation, and crustal spreading) are reviewed and are used as a guide to assess regional geologic evidence for the importance of these processes on Venus. Geologic evidence for variations in crustal thickness on Venus (range and frequency distribution of topography, regional slopes, etc.) are outlined. The hypothesis that the topography of Venus could result solely from crustal thickness variations is assessed and tested as an end-member hypothesis. A map of crustal thickness distribution is compiled on the basis of a simple model of Airy isostasy and global Venus topography. An assessment is then made of the significance of crustal thickness variations in explaining the topography of Venus. It is found that the distinctive unimodal hypsometric curve could be explained by: (1) a crust of relatively uniform thickness (most likely 10–20 km thick) comprising over 75% of the surface, (2) local plateaus (tessera) of thickened crust (about 20–30 km) forming less than 15% of the surface, (3) regions of apparent crustal thicknesses of 30–50 km (Beta, Ovda, Thetis, Atla Regiones and Western Ishtar Terra) forming less than 10% of the surface and showing some geologic evidence of crustal thickening processes (these areas can be explained on the basis of geologic observations and gravity data as combinations of thermal effects and crustal thickening), and (4) areas in which Airy isostasy predicts crustal thicknesses in excess of 50 km (the linear orogenic belts of Western Ishtar Terra, less than 1% of the surface).It is concluded that Venus hypsometry can be reasonably explained by a global crust of generally similar thickness with variations in topography being related to (1) crustal thickening processes (orogenic belts and plateau formation) and (2) local variations in the thermal structure (spatially varying thermal expansion in response to spatially varying heat flow). The most likely candidates for the formation and evolution of the crust are vertical differentiation and/or lateral crustal spreading processes. The small average crustal thickness (10–20 km) and the relatively small present crustal volume suggest that if vertical crustal growth processes are the dominant mechanism of crustal growth, than vertical growth has not commonly proceeded to the point where recycling by basal melting or density inversion will occur, and that therefore, rates of crustal production must have been much lower in the past than in recent history. Crustal spreading processes provide a mechanism for crustal formation and evolution that is consistent with observed crustal thicknesses. Crustal spreading processes would be characterized by higher (perhaps more Earth-like) crustal production rates than would characterize vertical differentiation processes, and crust created earlier in the history of Venus and not now observed (missing crust) would be accounted for by loss of crust through recycling processes. Lateral crustal spreading processes for the formation and evolution of the crust of Venus are interpreted to be consistent with many of the observations derived from presently available data. Resurfacing through vertical differentiation processes also clearly occurs, and if it is the major contributor to the total volume of the crust, then very low resurfacing rates are required.Although thermal effects on topography are clearly present and important on both Venus and the Earth, the major difference between the hypsometric curves on Earth (bimodal) and Venus (unimodal) is attributed primarily to the contrast in relative average thickness of the crust between the two terrains on Earth (continental/oceanic; 40/5 km = 35 km, 8:1) and Venus (upland plateaus/lowlands; about 30/15 km = 15 km, 2:1) (35 – 20 km = a difference of 20 km). The Venus unimodal distribution is thus attributed primarily to the large percentage of terrain with relatively uniform crustal thickness, with the skewness toward higher elevations due to the relatively small percentage of crust that is thickened by only about a factor of two. The Earth, in contrast, has a larger percentage of highlands (continents), whose crust is thicker by a factor of eight, on the average, leading to the distinctive bimodal hypsometric curve.Data necessary to firmly establish the dominant type of crustal formation and thickening processes operating and to determine the exact proportion of the topography of Venus that is due to thermal effects versus crustal thickness variations include: (1) global imaging data (to determine the age of the surface, the distribution and age of regions of high heat flux, and evidence for the nature and global distribution of processes of crustal formation and crustal loss), and (2) high resolution global gravity and topography data (to model crustal thickness variations and thermal contributions and to test various hypotheses of crustal growth).'Geology and Tectonics of Venus', special issue edited by Alexander T. Basilevsky (USSR Acad. of Sci. Moscow), James W. Head (Brown University, Providence), Gordon H. Pettengill (MIT, Cambridge, Massachusetts) and R. S. Saunders (J.P.L., Pasadena).     

Half-widths, their temperature dependence, and line shifts for the HDO-CO2 collision system for applications to CO2-rich planetary atmospheres

Measurements of water vapor in the atmospheres of Venus or Mars by spectroscopic techniques in the infrared range are being made routinely by instruments onboard the Venus Express and the Mars Reconnaissance Orbiter. The interpretation of these measurements in the 2250-4450 cm⁻¹ region is being complicated by the presence of HDO lines absorbing radiation in this region. These spectra cannot be modeled properly because line shape parameters for CO₂ broadening (principal gas in these atmospheres) of HDO are not available. Here semi-classical line shape calculations for the HDO-CO₂ collision system are made using the Robert-Bonamy formalism for some 2300 rotational band transitions of HDO. From these calculations, the half-width, its temperature dependence, and the line shift are determined to aid in the reduction of the measured spectra. These data will greatly reduce the uncertainty of the reduced profiles from the Venus and Mars measurements and will also allow better estimates of the D/H ratio on these planets.     

Diurnal CO variations in the Venus mesophere from CO microwave spectra

Microwave spectra of carbon monoxide (¹²CO) in the mesosphere of Venus were measured in December 1978, May and December 1980, and January, September, and November 1982. These spectra are analyzed to provide mixing profiles of CO in the Venus mesosphere and best constrain the mixing profile of CO between ～ 100 and 80 km altitude. From the January 1982 measurement (which, of all our spectra, best constrains the abundance of CO below 80 km altitude) we find an upper limit for the CO mixing ratio below 80 km altitude that is two to three times smaller than the stratospheric (～65 km) value of 4.5 ± 1.0 × 10^?5 determined by P. Connes, J. Connes, L.D. Kaplan, and W. S. Benedict (1968, Astrophys. J.152, 731–743) in 1967, indicating a possible long-term change in the lower atmospheric concentration of CO. Intercomparison among the individual CO profiles derived from our spectra indicates considerable short-term temporal and/or spatial variation in the profile of CO mixing in the Venus mesosphere above 80 km. A more complete comparison with previously published CO microwave spectra from a number of authors specifies the basic diurnal nature of mesospheric CO variability. CO abundance above ～ 95 km in the Venus atmosphere shows approximately a factor of 2–4 enhancement on the nightside relative to the dayside of Venus. Peak nightside CO abundance above ～95 km occurs very near to the antisolar point on Venus (local time of peak CO abundance above ～95 km occurs at 0.6_?0.6^+0.7 hr after midnight on Venus), strongly suggesting that retrograde zonal flow is substantially reduced at an altitude of 100 km in the Venus mesosphere. In contrast, CO abundances between 80 and 90 km altitude show a maximum that is shifted from the antisolar point toward the morningside of Venus (local time of peak CO abundance between 80 and 90 km occurs at 8.5 ± 1.0 hr past midnight on Venus). The magnitude of the diurnal variation of CO abundance between 80 and 90 km is again, approximately a factor of 2–4. Disk-averaged spectra of Venus do not determine the exact form for the diurnal distribution of CO in the Venus mesosphere as indicated by comparison of synthetic spectra, based upon model distributions, and the measured spectra. However, the offset in phase for the diurnal variation for the >95 km and 80–90-km-altitude regions requires an asymmetric (in solar zenith angle) distribution.     

Geology of the Venus equatorial region from Pioneer Venus radar imaging

Pioneer Venus radar data has provided images (resolution 20- to 40-km) of approximately 50% of the total surface of Venus in a band between 45 ° N to 15 ° S. These data are used to map the broad radar characteristics of the equatorial region on the basis of radar brightness and texture. Seven radar units are defined and are used to assess the geologic character of the equatorial region. These units fall into two distinct classes, those that are radar-bright (35% of the equatorial region) which correspond to highlands and zones of intense tectonic deformation, and radar-dark units, corresponding primarily to plains (65% of the equatorial region). The correspondence between features in the 15 ° region of overlap between the Pioneer Venus and Venera 15/16 images is examined and used to extend units mapped in the northern high latitudes into the equatorial region. On the basis of the distribution of the radar units, properties of RMS slope, reflectivity, the scattering behavior of the surface, and topographic signature, seven physiographic units are mapped in the equatorial region and are identified by increasing complexity as plains (undivided), dark halo plains, upland rises, upland plateaus, interhighland tectonic zones, tectonically segmented linear highlands, and tectonic junctions. The physiographic units are distributed in a nearly continuous interconnecting zone of volcanic rises and tectonic features that extends for nearly 360 ° around the equator of the planet. The distribution of large circular structures interpreted as coronae is also examined and it is concluded that the abundances of the largest structures, diameters greater than 500 km, is less than in the northern high latitudes with a notable absence of smaller coronae. The absence of small coronae may be due to the resolution limit of the Pioneer Venus data since analyses of higher resolution Arecibo and Goldstone imagery suggests that a number of corona-like features not identified in the PV data are present.'Geology and Tectonics of Venus', special issue edited by Alexander T. Basilevsky (USSR Acad. of Sci. Moscow), James W. Head (Brown University, Providence), Gordon H. Pettengill (MIT, Cambridge, Massachusetts) and R. S. Saunders (J.P.L., Pasadena).     

Thermospheric/mesospheric temperatures on Venus: Results from ground-based high-resolution spectroscopy of CO2 in 1990/1991 and comparison to results from 2009 and between other techniques

We report temperatures in Venus’ upper mesosphere/lower thermosphere, deduced from reanalyzing very high resolution infrared spectroscopy of CO₂ emission lines acquired in 1990 and 1991. Kinetic temperatures at ～110 km altitude (0.15 Pa) are derived from the Doppler width of fully-resolved single line profiles measured near 10.4 μm wavelength using the NASA GSFC Infrared Heterodyne Spectrometer (IRHS) at the NASA IRTF on Mauna Kea, HI, close to Venus inferior conjunction and two Venus solstices. Measured temperatures range from ～200 to 240 K with uncertainty typically less than 10 K. Temperatures retrieved from similar measurement in 2009 using the Cologne Tuneable Heterodyne Infrared Spectrometer (THIS) at the NOAO McMath Telescope at Kitt Peak, AZ are 10–20 K lower. Temperatures retrieved more recently from the SOIR instrument on Venus EXpress are consistent with these results when the geometry of observation is accounted for. It is difficult to compare ground-based sub-mm retrievals extrapolated to 110 km due to their much larger field of view, which includes the night side regions not accessible to infrared heterodyne observations. Temperature variability appears to be high on day-to-day as well as longer timescales. Observed short term and long term variability may be attributed to atmospheric dynamics, diurnal variability and changes over solar activity and seasons. The Venus International Reference Atmosphere (VIRA) model predicts cooler temperatures at the sampled altitudes in the lower thermosphere/upper mesosphere and is not consistent with these measurements.