Lava lakes on Io: observations of Io's volcanic activity from Galileo NIMS during the 2001 fly-bys

Galileo's Near-Infrared Mapping Spectrometer (NIMS) obtained its final observations of Io during the spacecraft's fly-bys in August (I31) and October 2001 (I32). We present a summary of the observations and results from these last two fly-bys, focusing on the distribution of thermal emission from Io's many volcanic regions that give insights into the eruption styles of individual hot spots. We include a compilation of hot spot data obtained from Galileo, Voyager, and ground-based observations. At least 152 active volcanic centers are now known on Io, 104 of which were discovered or confirmed by Galileo observations, including 23 from the I31 and I32 Io fly-by observations presented here. We modify the classification scheme of Keszthelyi et al. (2001, J. Geophys. Res. 106 (E12) 33 025-33 052) of Io eruption styles to include three primary types: promethean (lava flow fields emplaced as compound pahoehoe flows with small plumes <200 km high originating from flow fronts), pillanian (violent eruptions generally accompanied by large outbursts, >200 km high plumes and rapidly-emplaced flow fields), and a new style we call “lokian” that includes all eruptions confined within paterae with or without associated plume eruptions). Thermal maps of active paterae from NIMS data reveal hot edges that are characteristic of lava lakes. Comparisons with terrestrial analogs show that Io's lava lakes have thermal properties consistent with relatively inactive lava lakes. The majority of activity on Io, based on locations and longevity of hot spots, appears to be of this third type. This finding has implications for how Io is being resurfaced as our results imply that eruptions of lava are predominantly confined within paterae, thus making it unlikely that resurfacing is done primarily by extensive lava flows. Our conclusion is consistent with the findings of Geissler et al. (2004, Icarus, this issue) that plume eruptions and deposits, rather than the eruption of copious amounts of effusive lavas, are responsible for Io's high resurfacing rates. The origin and longevity of islands within ionian lava lakes remains enigmatic.     

Galileo observations of volcanic plumes on Io

Io's volcanic plumes erupt in a dazzling variety of sizes, shapes, colors and opacities. In general, the plumes fall into two classes, representing distinct source gas temperatures. Most of the Galileo imaging observations were of the smaller, more numerous Prometheus-type plumes that are produced when hot flows of silicate lava impinge on volatile surface ices of SO₂. Few detections were made of the giant, Pele-type plumes that vent high temperature, sulfur-rich gases from the interior of Io; this was partly because of the insensitivity of Galileo's camera to ultraviolet wavelengths. Both gas and dust spout from plumes of each class. Favorably located gas plumes were detected during eclipse, when Io was in Jupiter's shadow. Dense dust columns were imaged in daylight above several Prometheus-type eruptions, reaching heights typically less than 100 km. Comparisons between eclipse observations, sunlit images, and the record of surface changes show that these optically thick dust columns are much smaller in stature than the corresponding gas plumes but are adequate to produce the observed surface deposits. Mie scattering calculations suggest that these conspicuous dust plumes are made up of coarse grained “ash” particles with radii on the order of 100 nm, and total masses on the order of 10⁶ kg per plume. Long exposure images of Thor in sunlight show a faint outer envelope apparently populated by particles small enough to be carried along with the gas flow, perhaps formed by condensation of sulfurous “snowflakes” as suggested by the plasma instrumentation aboard Galileo as it flew through Thor's plume [Frank, L.A., Paterson, W.R., 2002. J. Geophys. Res. (Space Phys.) 107, doi:10.1029/2002JA009240. 31-1]. If so, the total mass of these fine, nearly invisible particles may be comparable to the mass of the gas, and could account for much of Io's rapid resurfacing.     

Mapping of the Culann-Tohil region of Io from Galileo imaging data

We have used Galileo spacecraft data to produce a geomorphologic map of the Culann-Tohil region of Io's antijovian hemisphere. This region includes a newly discovered shield volcano, Ts?i Goab Tholus and a neighboring bright flow field, Ts?i Goab Fluctus, the active Culann Patera and the enigmatic Tohil Mons-Radegast Patera-Tohil Patera complex. Analysis of Voyager global color and Galileo Solid-State Imaging (SSI) high-resolution, regional (50-330 m/pixel), and global color (1.4 km/pixel) images, along with available Galileo Near-Infrared Mapping Spectrometer (NIMS) data, suggests that 16 distinct geologic units can be defined and characterized in this region, including 5 types of diffuse deposits. Ts?i Goab Fluctus is the center of a low-temperature hotspot detected by NIMS late during the Galileo mission, and could represent the best case for active effusive sulfur volcanism detected by Galileo. The Culann volcanic center has produced a range of explosive and effusive deposits, including an outer yellowish ring of enhanced sulfur dioxide (SO₂), an inner red ring of SO₂ with short-chain sulfur (S₃-S₄) contaminants, and two irregular green diffuse deposits (one in Tohil Patera) apparently produced by the interaction of dark, silicate lava flows with sulfurous contaminants ballistically-emplaced from Culann's eruption plume(s). Fresh and red-mantled dark lava flows west of the Culann vent can be contrasted with unusual red-brown flows east of the vent. These red-brown flows have a distinct color that is suggestive of a compositional difference, although whether this is due to surface alteration or distinct lava compositions cannot be determined. The main massif of Tohil Mons is covered with ridges and grooves, defining a unit of tectonically disrupted crustal materials. Tohil Mons also contains a younger unit of mottled crustal materials that were displaced by mass wasting processes. Neighboring Radegast Patera contains a NIMS hotspot and a young lava lake of dark silicate flows, whereas the southwest portion of Tohil Patera contains white flow-like units, perhaps consisting of ‘ponds’ of effusively emplaced SO₂. From 0°-15° S the hummocky bright plains unit away from volcanic centers contains scarps, grooves, pits, graben, and channel-like features, some of which have been modified by erosion. Although the most active volcanic centers appear to be found in structural lows (as indicated by mapping of scarps), DEMs derived from stereo images show that, with the exception of Tohil Mons, there is less than 1 km of relief in the Culann-Tohil region. There is no discernable correlation between centers of active volcanism and topography.     

The final Galileo SSI observations of Io: orbits G28-I33

We present the observations of Io acquired by the Solid State Imaging (SSI) experiment during the Galileo Millennium Mission (GMM) and the strategy we used to plan the exploration of Io. Despite Galileo's tight restrictions on data volume and downlink capability and several spacecraft and camera anomalies due to the intense radiation close to Jupiter, there were many successful SSI observations during GMM. Four giant, high-latitude plumes, including the largest plume ever observed on Io, were documented over a period of eight months; only faint evidence of such plumes had been seen since the Voyager 2 encounter, despite monitoring by Galileo during the previous five years. Moreover, the source of one of the plumes was Tvashtar Catena, demonstrating that a single site can exhibit remarkably diverse eruption styles—from a curtain of lava fountains, to extensive surface flows, and finally a ∼400 km high plume—over a relatively short period of time (∼13 months between orbits I25 and G29). Despite this substantial activity, no evidence of any truly new volcanic center was seen during the six years of Galileo observations. The recent observations also revealed details of mass wasting processes acting on Io. Slumping and landsliding dominate and occur in close proximity to each other, demonstrating spatial variation in material properties over distances of several kilometers. However, despite the ubiquitous evidence for mass wasting, the rate of volcanic resurfacing seems to dominate; the floors of paterae in proximity to mountains are generally free of debris. Finally, the highest resolution observations obtained during Galileo's final encounters with Io provided further evidence for a wide diversity of surface processes at work on Io.     

The Zamama-Thor region of Io: Insights from a synthesis of mapping, topography, and Galileo spacecraft data

We have studied data from the Galileo spacecraft's three remote sensing instruments (Solid-State Imager (SSI), Near-Infrared Mapping Spectrometer (NIMS), and Photopolarimeter-Radiometer (PPR)) covering the Zamama-Thor region of Io's antijovian hemisphere, and produced a geomorphological map of this region. This is the third of three regional maps we are producing from the Galileo spacecraft data. Our goal is to assess the variety of volcanic and tectonic materials and their interrelationships on Io using planetary mapping techniques, supplemented with all available Galileo remote sensing data. Based on the Galileo data analysis and our mapping, we have determined that the most recent geologic activity in the Zamama-Thor region has been dominated by two sites of large-scale volcanic surface changes. The Zamama Eruptive Center is a site of both explosive and effusive eruptions, which emanate from two relatively steep edifices (Zamama Tholi A and B) that appear to be built by both silicate and sulfur volcanism. A ∼100-km long flow field formed sometime after the 1979 Voyager flybys, which appears to be a site of promethean-style compound flows, flow-front SO₂ plumes, and adjacent sulfur flows. Larger, possibly stealthy, plumes have on at least one occasion during the Galileo mission tapped a source that probably includes S and/or Cl to produce a red pyroclastic deposit from the same vent from which silicate lavas were erupted. The Thor Eruptive Center, which may have been active prior to Voyager, became active again during the Galileo mission between May and August 2001. A pillanian-style eruption at Thor included the tallest plume observed to date on Io (at least 500 km high) and new dark lava flows. The plume produced a central dark pyroclastic deposit (probably silicate-rich) and an outlying white diffuse ring that is SO₂-rich. Mapping shows that several of the new dark lava flows around the plume vent have reoccupied sites of earlier flows. Unlike most of the other pillanian eruptions observed during the Galileo mission, the 2001 Thor eruption did not produce a large red ring deposit, indicating a relative lack of S and/or Cl gases interacting with the magma during that eruption. Between these two eruptive centers are two paterae, Thomagata and Reshef. Thomagata Patera is located on a large shield-like mesa and shows no signs of activity. In contrast, Reshef Patera is located on a large, irregular mesa that is apparently undergoing degradation through erosion (perhaps from SO₂-sapping or chemical decomposition of sulfur-rich material) from multiple secondary volcanic centers.     

Geologic mapping of the Zal region of Io

We produced a regional geologic map of the Zal region of Io's antijovian hemisphere using Galileo mission data. We discuss the geologic features, summarize the map units and structures that are present, discuss the nature of volcanic activity, and present an analysis of the volcanic, tectonic, and gradational processes that affect the region. The Zal region consists of five primary types of geologic materials: plains, mountains, paterae floors, flows, and diffuse deposits. The flows and patera floors are similar, but are subdivided based on uncertainties regarding emplacement environments and mechanisms. The Zal region includes two hotspots detected by Galileo: one along the western scarp of the Zal Patera volcano and one at the Rustam Patera volcano (name submitted to IAU). A third hotspot at the nearby At'am Patera volcano (name submitted to IAU) is the source of diffuse and pyroclastic materials that blanket north Zal Mons. The western bounding scarp of Zal Patera is the location of a fissure vent that is the source of multiple silicate lava flows. The floor of Zal Patera has been partially resurfaced by dark lava flows, although portions of the patera floor appear bright and unchanged during the Galileo mission. This suggests that the floor did not undergo complete resurfacing as a flooding lava lake but does contain a compound flow field. Mountain materials exhibit stages of degradation; lineated material degrades into mottled material. We have explored the possibility that north and south Zal Mons were originally one structure. We propose that strike-slip faulting and subsequent rifting separated the mountain units, opened a fissure which serves as a vent for lava flow, and created a depression which, by further extension during the rifting event, became Zal Patera. With comparison to other regional maps of Io, this work provides insight into the general geologic evolution of Io.     

Sulfur volcanism on Io

In February 2003, March 2003 and January 2004 Pele plume transmission spectra were obtained during Jupiter transit with Hubble's Space Telescope Imaging Spectrograph (STIS), using the 0.1″ wide slit and the G230LB grating. The STIS spectra covered the 2100-3100 Å wavelength regions and extended spatially along Io's limb encompassing the region directly above and northward of the vent of the Pele volcano. The S₂ and SO₂ absorption signatures evident in these data indicate that the gas signature at Pele was temporally variable, and that an S₂ absorption signature was present ∼12° from the Pele vent near 6±5 S and 264±15 W, suggesting the presence of another S₂ bearing plume on Io. Contemporaneous with the spectral data, UV and visible-wavelength images of the plume were obtained in reflected sunlight with the Advanced Camera for Surveys (ACS) prior to Jupiter transit. The dust scattering recorded in these data provide an additional qualitative measure of plume activity on Io, indicating that the degree of dust scattering over Pele varied as a function of the date of observation, and that there were several other dust bearing plumes active during the observations. We present constraints on the composition and variability of the gas abundances of the Pele plume as well as the plumes detected by ACS and recorded within the STIS data, as a function of time.     

Photochemistry of a Volcanically Driven Atmosphere on Io: Sulfur and Oxygen Species from a Pele-Type Eruption

To determine how active volcanism might affect the standard picture of sulfur dioxide photochemistry on Io, we have developed a one-dimensional atmospheric model in which a variety of sulfur-, oxygen-, sodium-, potassium-, and chlorine-bearing volatiles are volcanically outgassed at Io's surface and then evolve due to photolysis, chemical kinetics, and diffusion. Thermochemical equilibrium calculations in combination with recent observations of gases in the Pele plume are used to help constrain the composition and physical properties of the exsolved volcanic vapors. Both thermochemical equilibrium calculations (Zolotov and Fegley 1999, Icarus141, 40-52) and the Pele plume observations of Spencer et al. (2000; Science288, 1208-1210) suggest that S₂ may be a common gas emitted in volcanic eruptions on Io. If so, our photochemical models indicate that the composition of Io's atmosphere could differ significantly from the case of an atmosphere in equilibrium with SO₂ frost. The major differences as they relate to oxygen and sulfur species are an increased abundance of S, S₂, S₃, S₄, SO, and S₂O and a decreased abundance of O and O₂ in the Pele-type volcanic models as compared with frost sublimation models. The high observed SO/SO₂ ratio on Io might reflect the importance of a contribution from volcanic SO rather than indicate low eddy diffusion coefficients in Io's atmosphere or low SO “sticking” probabilities at Io's surface; in that case, the SO/SO₂ ratio could be temporally and/or spatially variable as volcanic activity fluctuates. Many of the interesting volcanic species (e.g., S₂, S₃, S₄, and S₂O) are short lived and will be rapidly destroyed once the volcanic plumes shut off; condensation of these species near the source vent is also likely. The diffuse red deposits associated with active volcanic centers on Io may be caused by S₄ radicals that are created and temporarily preserved when sulfur vapor (predominantly S₂) condenses around the volcanic vent. Condensation of SO across the surface and, in particular, in the polar regions might also affect the surface spectral properties. We predict that the S/O ratio in the torus and neutral clouds might be correlated with volcanic activity—during periods when volcanic outgassing of S₂ (or other molecular sulfur vapors) is prevalent, we would expect the escape of sulfur to be enhanced relative to that of oxygen, and the S/O ratio in the torus and neutral clouds could be correspondingly increased.     

Two classes of volcanic plumes on Io

Comparison of Voyager 1 and Voyager 2 images of the south polar region of Io has revealed that a major volcanic eruption occured there during the period between the two spacecraft encounters. An annular deposit ～1400 km in diameter formed around the Aten Patera caldera (311°W, 48°S), the floor of which changed from orange to red-black. The characteristics of this eruption are remarkably similar to those described earlier for an eruption centered on Surt caldera (338°W, 45°N) that occured during the same period, also at high latitude, but in the north. Both volcanic centers were evidently inactive during the Voyager 1 and 2 encounters but were active sometime between the two. The geometric and colorimetric characteristics, as well as scale of the two annular deposits, are virtually identical; both resemble the surface features formed by the eruption of Pele (255°W, 18°S). These three very large plume eruptions suggest a class of eruption distinct from that of six smaller plumes observed to be continously active by both Voyagers 1 and 2. The smaller plumes, of which Prometheus is the type example, are longer-lived, deposit bright, whitish material, erupt at velocities of ～0.5 km sec^?1, and are concentrated at low latitudes in an equatorial belt around the satellite. The very large Pele-type plumes, on the other hand, are relatively short-lived, deposit darker red materials, erupt at ～1.0 km sec^?1, and (rather than restricted to a latitudinal band) are restricted in longitude from 240° to 360°W. Both direct thermal infrared temperature measurements and the implied color temperatures for quenched liquid sulfur suggest that hot spot temperatures of ～650°K are associated with the large plumes and temperatures <400°K with the small plumes. The typical eruption duration of the small plumes is at least several years; that of the large plumes appears to be of the order of days to weeks. The two classes therefore differ by more than two orders of magnitude in duration of eruption. Based on uv, visible, and infrared spectra, the small plumes seem to contain and deposit SO₂ in their annuli whereas the large plumes apparently do not. Two other plumes that occur at either end of the linear feature Loki may be intermediate or hybrid between the two classes, exhibiting attributes of both. Additionally, Loki occurs in the area of overlap in the regional distributions of the two plume classes. Two distinct volcanic systems involving different volatiles may be responsible for the two classes. We propose that the discrete temperatures associated with the two classes are a direct reflection of sulfur's peculiar variation in viscosity with temperature. Over two temperature ranges (～400 to 430°K and >650°K), sulfur is a low-viscosity fluid (orange and black, respectively); at other temperatures it is either solid or has a high viscosity. As a result, there will be two zones in Io's crust in which liquid sulfur will flow freely: a shallow zone of orange sulfur and a deeper zone of black sulfur. A low-temperature system driven by SO₂ heated to 400 to 400°K by the orange sulfur zone seems the best model for the small plumes; a system driven by sulfur heated to >650°K by hot or even molten silicates in the black sulfur zone seems the best explanation for the large plume class. The large Pele-type plumes are apparently concentrated in a region of the satellite in which a thinner sulfur-rich crust overlies the tidally heated silicate lithosphere, so the black sulfur zone may be fairly shallow in this region. The Prometheus-type plumes are possibly confined to the equatorial belt by some process that concentrates SO₂ fluid in the equatorial crust.     

Numerical modeling of ionian volcanic plumes with entrained particulates

Volcanic plumes on Jupiter's moon Io are modeled using the direct simulation Monte Carlo (DSMC) method. The modeled volcanic vent is interpreted as a “virtual” vent. A parametric study of the “virtual” vent gas temperature and velocity is performed to constrain the gas properties at the vent by observables, particularly the plume height and the surrounding condensate deposition ring radius. Also, the flow of refractory nano-size particulates entrained in the gas is modeled with “overlay” techniques which assume that the background gas flow is not altered by the particulates. The column density along the tangential line-of-sight and the shadow cast by the plume are calculated and compared with Voyager and Galileo images. The parametric study indicates that it is possible to obtain a unique solution for the vent temperature and velocity for a large plume like Pele. However, for a small Prometheus-type plume, several different possible combinations of vent temperature and velocity result in both the same shock height and peak deposition ring radius. Pele and Prometheus plume particulates are examined in detail. Encouraging matches with observations are obtained for each plume by varying both the gas and particle parameters. The calculated tangential gas column density of Pele agrees with that obtained from HST observations. An upper limit on the size of particles that track the gas flow well is found to be ∼10 nm, consistent with Voyager observations of Loki. While it is certainly possible for the plumes to contain refractory dust or pyroclastic particles, especially in the vent vicinity, we find that the conditions are favorable for SO₂ condensation into particles away from the vent vicinity for Prometheus. The shadow cast by Prometheus as seen in Galileo images is also reproduced by our simulation. A time averaged frost deposition profile is calculated for Prometheus in an effort to explain the multiple ring structure observed around the source region. However, this multiple ring structure may be better explained by the calculated deposition of entrained particles. The possibility of forming a dust cloud on Io is examined and, based on a lack of any such observed clouds, a subsolar frost temperature of less than 118 K is suggested.     

Characterizing Io’s Pele,Tvashtar and Pillan plumes: Lessons learned from Hubble

Hubble Space Telescope/Wide Field and Planetary Camera 2 (HST/WFPC2) images of Io obtained between 1995 and 2007 between 0.24 and 0.42 μm led to the detection of the Pele plume in reflected sunlight in 1995 and 1999; imaging of the Pele plume via absorption of jovian light in 1996 and 1999; detection of the Prometheus-type Pillan plume in reflected sunlight in 1997; and detection of the 2007 Pele-type Tvashtar plume eruption in reflected sunlight and via absorption of jovian light. Based on a detailed analysis of these observations we characterize and compare the gas and dust properties of each of the detected plumes. In each case, the brightness of the plumes in reflected sunlight is less at 0.26 μm than at 0.33 μm. Mie scattering analysis of the wavelength dependence of each plume’s reflectance signature suggests that range of particle sizes within the plumes is quite narrow. Assuming a normal distribution of particle sizes, the range of mean particle sizes is ～0.035–0.12 μm for the 1997 Pillan eruption, ～0.05–0.08 μm for the 1999 Pele and 2007 Tvasthar plumes, and ～0.05–0.11 μm for the 1995 Pele plume, and in each case the standard deviation in the particle size distribution is <15%. The Mie analysis also suggests that the 2007 Tvashtar eruption released ～10⁹ g of sulfur dust, the 1999 Pele eruption released ～10⁹ g of SO₂ dust, the 1997 Pillan eruption released ～10¹⁰ g of SO₂ dust, and the 1995 Pele plume may have released ～10¹⁰ g of SO₂ dust. Analysis of the plume absorption signatures recorded in the F255W filter bandpass (0.24–0.28 μm) indicates that the opacity of the 2007 Tvashtar plume was 2× that of the 1996 and 1999 Pele plume eruptions. While the sulfur dust density estimated for the Tvashtar from the reflected sunlight data could have produced 61% of the observed plume opacity, <10% of the 1999 Pele F255W plume opacity could have resulted from the SO₂ dust detected in the eruption. Accounting for the remaining F255W opacity level of the Pele and Tvasthar plumes based on SO₂ and S₂ gas absorption, the SO₂ and S₂ gas density inferred for each plume is almost equivalent corresponding to ～2–6 × 10¹⁶ cm^?2 and 3–5 × 10¹⁵ cm^?2, respectively, producing SO₂ and S₂ gas resurfacing rates ～0.04–0.2 cm yr^?1 and 0.007–0.01 cm yr^?1; and SO₂ and S₂ gas masses ～1–4 × 10¹⁰ g and ～2–3 × 10⁹ g; for a total dust to gas ratio in the plumes ～10^?1–10^?2. The 2007 Tvashtar plume was detected by HST at ～380 ± 40 km in both reflected sunlight and absorbed jovian light; in 1999, the detected Pele plume altitude was 500 km in absorbed jovian light, but in reflected sunlight the detected height was ～2× lower. Thus, for the 1999 Pele plume, similar to the 1979 Voyager Pele plume observations, the most efficient dust reflections occurred in the region closest to the plume vent. The 0.33–0.42 μm brightness of the 1997 Pillan plume was 10–20× greater than the Pele or Tvashtar plumes, exceeding by a factor of 3 the average brightness levels observed within 200 km of 1979 Loki eruption vent. But, the 0.26 μm brightness of the 1997 Pillan plume in reflected sunlight was significantly lower than would be predicted by the dust scattering model. Presuming that the 0.26 μm brightness of the 1997 Pillan plume was attenuated by the eruption plume’s gas component, then an SO₂ gas density ～3–6 × 10¹⁸ cm^?2 is inferred from the data (for S₂/SO₂ ratios ?4%), comparable to the 0.3–2 × 10¹⁸ cm^?2 SO₂ density detected at Loki in 1979 (Pearl, J.C. et al. [1979]. Nature 280, 755; Lellouch et al., 1992), and producing an SO₂ gas mass ～3–8 × 10¹¹ g and an SO₂ resurfacing rate ～8–23 cm yr^?1. These results confirm the connection between high (?10¹⁷ cm^?2) SO₂ gas content and plumes that scatter strongly at nearly blue wavelengths, and it validates the occurrence of high density SO₂ gas eruptions on Io. Noting that the SO₂ gas content inferred from a spectrum of the 2003 Pillan plume was significantly lower ～2 × 10¹⁶ cm^?2 (Jessup, K.L., Spencer, J., Yelle, R. [2007]. Icarus 192, 24–40); and that the Pillan caldera was flooded with fresh SO₂ frost/slush just prior to the 1997 Pillan plume eruption (Geissler, P., McEwen, A., Phillips, C., Keszthelyi, L., Spencer, J. [2004a]. Icarus 169, 29–64; Phillips, C.B. [2000]. Voyager and Galileo SSI Views of Volcanic Resurfacing on Io and the Search for Geologic Activity at Europa. Ph.D. Thesis, Univ. of Ariz., Tucson); we propose that the density of SO₂ gas released by this volcano is directly linked to the local SO₂ frost abundance at the time of eruption.     

Mapping of Io's thermal radiation by the Galileo photopolarimeter-radiometer (PPR) instrument

Between 1999 and 2002, the Galileo spacecraft made 6 close flybys of Io during which many observations of Io's thermal radiation were made with the photopolarimeter-radiometer (PPR). While the NIMS instrument could measure thermal emission from hot spots with T>200 K, PPR was the only Galileo instrument capable of mapping the lower temperatures of older, cooling lava flows, and the passive background. We tabulate all data taken by PPR of Io during these flybys and describe some scientific highlights revealed by the data. The data include almost complete coverage of Io at better than 250 km resolution, with extensive regional coverage at higher resolutions. We found a modest poleward drop in nighttime background temperatures and evidence of thermal inertia variations across the surface. Comparison of high spatial resolution temperature measurements with observed daytime SO₂ gas pressures on Io provides evidence for local cold trapping of SO₂ frost on scales smaller than the 60 km resolution of the PPR data. We also calculated the power output from several hot spots and estimated total global heat flow to be about 2.0-2.6 W m⁻². The low-latitude diurnal temperature variations for the regions between obvious hot spots are well matched by a laterally-inhomogeneous thermal model with less than 1 W m⁻² endogenic heat flow.     

Simulation of gas dynamics and radiation in volcanic plumes on Io

Modeling results of volcanic plumes on Jupiter’s moon Io are presented. Two types of low density axisymmetric SO₂ plume flows are modeled using the direct simulation Monte Carlo (DSMC) method. Thermal radiation from all three vibrational bands and overall rotational lines of SO₂ molecules is modeled. A high resolution computation of the flow in the vicinity of the vent was obtained by multidomain sequential calculation to improve the modeling of the radiation signature. The radiation features are examined both by calculating infrared emission spectra along different lines-of-sight through the plume and with the DSMC modeled emission images of the whole flow field. It is found that most of the radiation originates in the vicinity of the vent, and non-LTE (non-local-thermodynamic equilibrium) cooling by SO₂ rotation lines exceeds cooling in the v₂ vibrational band at high altitude.In addition to the general shape of the plumes, the calculated average SO₂ column density (∼10¹⁶ cm⁻²) over a Pele-type plume and the related frost-deposition ring structure (at R ∼ 500 km from the vent) are in agreement with observations. These comparisons partially validate the modeling. It is suggested that an observation with spatial resolution of less than 30 km is needed to measure the large spatial variation of SO₂ near a Pele-type plume center. It is also found that an influx of 1.1 × 10²⁹ SO₂ s⁻¹ (or 1.1 × 10⁴ kg s⁻¹) is sufficient to reproduce the observed SO₂ column density at Pele. The simulation results also show some interesting features such as a multiple bounce shock structure around Prometheus-type plumes and the frost depletion by plume-induced erosion on the sunlit side of Io. The model predicts the existence of a canopy shock, a ballistic region inside the Pele-type plume, and the negligible effect of surface heating by plume emission.     

S2O, polysulfuroxide and sulfur polymer on Io's surface?

To settle the question of disulfur monoxide and sulfur monoxide deposition and occurrence on Io's surface, we performed series of laboratory experiments reproducing the condensation of S₂O at low temperature. Its polymerization has been monitored by recording infrared spectra under conditions of temperature, pressure, mixing with SO₂ and UV-visible radiation simulating that of Io's surface. Our experiments show that S₂O condensates are not chemically stable under ionian conditions. We also demonstrate that SO and S₂O outgassed by Io's volcanoes and condensing on Io's surface should lead to yellow polysulfuroxide deposits or to white deposits of S₂O diluted in sulfur dioxide frost (i.e., S₂O/SO₂ < 0.1%). Thus S₂O condensation cannot be responsible for the red volcanic deposits on Io. Comparison of the laboratory infrared spectra of S₂O and polysulfuroxide with NIMS/Galileo infrared spectra of Io's surface leads us to discuss the possible identification of polysulfuroxide. We also recorded the visible transmission spectra of sulfur samples resulting from polysulfuroxide decomposition. These samples consist in a mixture of sulfur polymer and orthorhombic sulfur. Using the optical constants extracted from these measurements, we show that a linear combination of the reflectance spectra of our samples, the reflectance spectrum of orthorhombic S₈ sulfur and SO₂ reflectance spectrum, leads to a very good matching of Io's visible spectrum between 330 and 520 nm. We conclude then that Io's surface is probably mainly composed of sulfur dioxide and a mixture of sulfur S₈ and sulfur polymer. Some polysulfuroxide could also co-exist with these dominant components, but is probably restricted to some volcanic areas.     

Geology and activity around volcanoes on Io from the analysis of NIMS spectral images

The last two successful flybys of Io by Galileo in 2001 (orbits I31, I32) allowed the Near Infrared Mapping Spectrometer to enrich its collection of IR spectral image cubes of the satellite. These data cover hemispheric portions of Io, several volcanic centers as well as their surroundings with a spatial resolution ranging from 2 to 93 km pixel⁻¹. They map thermal emission from the hot-spots and the distribution of solid SO₂ in the 1.0-4.7 μm spectral range. We obtain maps of SO₂ abundance and granularity from the NIMS data using the method of Douté et al. (2002, Icarus 158, 460-482). The maps are correlated to distinguish four different physical units that indicate zones of SO₂ condensation, metamorphism and sublimation. We relate these information with visible images from Galileo's Solid State Imaging System and with detailed mapping of the thermal emission produced by Io's surface. Our principal goal is to understand the mechanisms controlling how lava, pyroclastics and gas are emitted by different types of volcanoes and how these products evolve. The 800 km diameter white ring of fallout created by a violent “Pillanian” eruption during summer of 2001 is at least partly composed of solid SO₂ and has enriched preexisting regional deposits. Orange materials have been recently or are currently emplaced 240 km south from the main eruption site, possibly as sulfur flows. A similar event may have taken place in the past at Ababinili Patera (12.5° N, 142° W). Carefull study of SO₂ maps covering the Emakong region also suggests that sulfur forms the bright channel-fed flow emerging from the south eastern side of the caldera. Within the main caldera of Tvashtar Catena completely cooled patches of crust exist. Elsewhere, the caldera is still cooling from previous episodes of flooding. We confirm that Amirani emits constantly large amount of SO₂ gas by interaction of fresh lava with the volatiles of the underlying plains. Nevertheless SO₂ frost is not the major component of the bright white ring seen in the SSI images. Over the whole Gish Bar region, SO₂ frost seems barely stable and is constantly regenerated. The stability increases along gray filamentary structures which could be faults filled with materials having peculiar thermal properties. Northwest of Gish Bar Patera, a localized bright deposit shows an unusual spectral signature potentially indicative of H₂O molecules forming ice crystals or being trapped in a nonidentified matrix. The Chaac region may present a thickened old crust reducing the geothermal flux to levels lower than 0.5 W m⁻² and thus creating a cold trap for SO₂. Looking at the abundance and degree of metamorphose of SO₂, we establish the relative age of different flows and ejecta for the Sobo Fluctus. Finally the assumption that the white patches in visible images indicate SO₂ rich deposits is once again challenged. In the Camaxtli region we identify a topographically controlled compact white deposit showing only moderate SO₂ abundance. In contrast, we detect two spots of quite pure SO₂ ice on the gray flanks of Emakong. Furthermore, the close association of fumarolic SO₂ and red S₂ already noted for several volcanic centers is observed at Tupan.     

The atmospheric signature of Io's Prometheus plume and anti-jovian hemisphere: evidence for a sublimation atmosphere

Using the Hubble Space Telescope's Space Telescope Imaging Spectrograph we have obtained for the first time spatially resolved 2000-3000 Å spectra of Io's Prometheus plume and adjoining regions on Io's anti-jovian hemisphere in the latitude range 60° N-60° S, using a 0.1″ slit centered on Prometheus and tilted roughly 45° to the spin axis. The SO₂ column density peaked at 1.25×10¹⁷ cm⁻² near the equator, with an additional 5×10¹⁶ cm⁻² enhancement over Prometheus corresponding to a model volcanic SO₂ output of 10⁵ kg s⁻¹. Apart from the Prometheus peak, the SO₂ column density dropped fairly smoothly away from the subsolar point, even over regions that included potential volcanic sources. At latitudes less than ±30°, the dropoff rate was consistent with control by vapor pressure equilibrium with surface frost with subsolar temperature 117.3±0.6 K, though SO₂ abundance was higher than predicted by vapor pressure control at mid-latitudes, especially in the northern hemisphere. We conclude that, at least at low latitudes on the anti-jovian hemisphere where there are extensive deposits of optically-thick SO₂ frost, the atmosphere is probably primarily supported by sublimation of surface frost. Although the 45° tilt of our slit prevents us from separating the dependence of atmospheric density on solar zenith angle from its dependence on latitude, the pattern is consistent with a sublimation atmosphere regardless of which parameter is the dominant control. The observed drop in gas abundance towards higher latitudes is consistent with the interpretation of previous Lyman alpha images of Io as indicating an atmosphere concentrated at low latitudes. Comparison with previous disk-resolved UV spectroscopy, Lyman-alpha images, and mid-infrared spectroscopy suggests that Io's atmosphere is denser and more widespread on the anti-jovian hemisphere than at other longitudes. SO₂ gas temperatures were in the range of 150-250 K over the majority of the anti-jovian hemisphere, consistent with previous observations. SO was not definitively detected in our spectra, with upper limits to the SO/SO₂ ratio in the range 1-10%, roughly consistent with previous observations. S₂ gas was not seen anywhere, with an upper limit of 7.5×10¹⁴ cm⁻² for the Prometheus plume, confirming that this plume is significantly poorer in S₂ than the Pele plume (S₂ /SO₂<0.005, compared to 0.08-0.3 at Pele). In addition to the gas absorption signatures, we have observed continuum emission in the near ultraviolet (near 2800 Å) for the first time. The brightness of the observed emission was directly correlated with the SO₂ abundance, strongly peaking in the equatorial region over Prometheus. Emission brightness was modestly anti-correlated with the jovian magnetic latitude, decreasing when Io intersected the torus centrifugal equator.     

Alkali and Chlorine Photochemistry in a Volcanically Driven Atmosphere on Io

Observations of the Io plasma torus and neutral clouds indicate that the extended ionian atmosphere must contain sodium, potassium, and chlorine in atomic and/or molecular form. Models that consider sublimation of pure sulfur dioxide frost as the sole mechanism for generating an atmosphere on Io cannot explain the presence of alkali and halogen species in the atmosphere—active volcanoes or surface sputtering must also be considered, or the alkali and halide species must be discharged along with the SO₂ as the frost sublimates. To determine how volcanic outgassing can affect the chemistry of Io's atmosphere, we have developed a one-dimensional photochemical model in which active volcanoes release a rich suite of S-, O-, Na-, K-, and Cl-bearing vapor and in which photolysis, chemical reactions, condensation, and vertical eddy and molecular diffusion affect the subsequent evolution of the volcanic gases. Observations of Pele plume constituents, along with thermochemical equilibrium calculations of the composition of volcanic gases exsolved from high-temperature silicate magmas on Io, are used to constrain the composition of the volcanic vapor. We find that NaCl, Na, Cl, KCl, and K will be the dominant alkali and chlorine gases in atmospheres generated from Pele-like plume eruptions on Io. Although the relative abundances of these species will depend on uncertain model parameters and initial conditions, these five species remain dominant for a wide variety of realistic conditions. Other sodium and chlorine molecules such as NaS, NaO, Na₂, NaS₂, NaO₂, NaOS, NaSO₂, SCl, ClO, Cl₂, S₂Cl, and SO₂Cl₂ will be only minor constituents in the ionian atmosphere because of their low volcanic emission rates and their efficient photochemical destruction mechanisms. Our modeling has implications for the general appearance, properties, and variability of the neutral sodium clouds and jets observed near Io. The neutral NaCl molecules present at high altitudes in atmosph eres generated by active volcanoes might provide the NaX⁺ ion needed to help explain the morphology of the high-velocity sodium “stream” feature observed near Io.     

High-Resolution Keck Adaptive Optics Imaging of Violent Volcanic Activity on Io

Io, the innermost Galilean satellite of Jupiter, is a fascinating world. Data taken by Voyager and Galileo instruments have established that it is by far the most volcanic body in the Solar System and suggest that the nature of this volcanism could radically differ from volcanism on Earth. We report on near-IR observations taken in February 2001 from the Earth-based 10-m W. M. Keck II telescope using its adaptive optics system. After application of an appropriate deconvolution technique (MISTRAL), the resolution, ∼100 km on Io's disk, compares well with the best Galileo/NIMS resolution for global imaging and allows us for the first time to investigate the very nature of individual eruptions. On 19 February, we detected two volcanoes, Amirani and Tvashtar, with temperatures differing from the Galileo observations. On 20 February, we noticed a slight brightening near the Surt volcano. Two days later it had turned into an extremely bright volcanic outburst. The hot spot temperatures (>1400 K) are consistent with a basaltic eruption and, being lower limits, do not exclude an ultramafic eruption. These outburst data have been fitted with a silicate-cooling model, which indicates that this is a highly vigorous eruption with a highly dynamic emplacement mechanism, akin to fire-fountaining. Its integrated thermal output was close to the total estimated output of Io, making this the largest ionian thermal outburst yet witnessed.     

Volcanism on Io: New insights from global geologic mapping

We produced the first complete, 1:15 M-scale global geologic map of Jupiter’s moon Io, based on a set of monochrome and color Galileo-Voyager image mosaics produced at a spatial resolution of 1 km/pixel. The surface of Io was mapped into 19 units based on albedo, color and surface morphology, and is subdivided as follows: plains (65.8% of surface), lava flow fields (28.5%), mountains (3.2%), and patera floors (2.5%). Diffuse deposits (DD) that mantle the other units cover ∼18% of Io’s surface, and are distributed as follows: red (8.6% of surface), white (6.9%), yellow (2.1%), black (0.6%), and green (∼0.01%). Analyses of the geographical and areal distribution of these units yield a number of results, summarized below. (1) The distribution of plains units of different colors is generally geographically constrained: Red-brown plains occur >±30° latitude, and are thought to result from enhanced alteration of other units induced by radiation coming in from the poles. White plains (possibly dominated by SO₂ + contaminants) occur mostly in the equatorial antijovian region (±30°, 90-230°W), possibly indicative of a regional cold trap. Outliers of white, yellow, and red-brown plains in other regions may result from long-term accumulation of white, yellow, and red diffuse deposits, respectively. (2) Bright (possibly sulfur-rich) flow fields make up 30% more lava flow fields than dark (presumably silicate) flows (56.5% vs. 43.5%), and only 18% of bright flow fields occur within 10 km of dark flow fields. These results suggest that secondary sulfurous volcanism (where a bright-dark association is expected) could be responsible for only a fraction of Io’s recent bright flows, and that primary sulfur-rich effusions could be an important component of Io’s recent volcanism. An unusual concentration of bright flows at ∼45-75°N, ∼60-120°W could be indicative of more extensive primary sulfurous volcanism in the recent past. However, it remains unclear whether most bright flows are bright because they are sulfur flows, or because they are cold silicate flows covered in sulfur-rich particles from plume fallout. (3) We mapped 425 paterae (volcano-tectonic depressions), up from 417 previously identified by Radebaugh et al. (Radebaugh, J., Keszthelyi, L.P., McEwen, A.S., Turtle, E.P., Jaeger, W., Milazzo, M. [2001]. J. Geophys. Res. 106, 33005-33020). Although these features cover only 2.5% of Io’s surface, they correspond to 64% of all detected hot spots; 45% of all hot spots are associated with the freshest dark patera floors, reflecting the importance of active silicate volcanism to Io’s heat flow. (4) Mountains cover only ∼3% of the surface, although the transition from mountains to plains is gradational with the available imagery. 49% of all mountains are lineated and presumably layered, showing evidence of linear structures supportive of a tectonic origin. In contrast, only 6% of visible mountains are mottled (showing hummocks indicative of mass wasting) and 4% are tholi (domes or shields), consistent with a volcanic origin. (5) Initial analyses of the geographic distributions of map units show no significant longitudinal variation in the quantity of Io’s mountains or paterae, in contrast to earlier studies. This is because we use the area of mountain and patera materials as opposed to the number of structures, and our result suggests that the previously proposed anti-correlation of mountains and paterae (Schenk, P., Hargitai, H., Wilson, R., McEwen, A., Thomas, P. [2001]. J. Geophys. Res. 106, 33201-33222; Kirchoff, M.R., McKinnon, W.B., Schenk, P.M. [2011]. Earth Planet. Sci. Lett. 301, 22-30) is more complex than previously thought. There is also a slight decrease in surface area of lava flows toward the poles of Io, perhaps indicative of variations in volcanic activity. (6) The freshest bright and dark flows make up about 29% of all of Io’s flow fields, suggesting active emplacement is occurring in less than a third of Io’s visible lava fields. (7) About 47% of Io’s diffuse deposits (by area) are red, presumably deriving their color from condensed sulfur gas, and ∼38% are white, presumably dominated by condensed SO₂. The much greater areal extent of gas-derived diffuse deposits (red + white, 85%) compared to presumably pyroclast-bearing diffuse deposits (dark (silicate tephra) + yellow (sulfur-rich tephra), 15%) indicates that there is effective separation between the transport of tephra and gas in many Ionian explosive eruptions. Future improvements in the geologic mapping of Io can be obtained via (a) investigating the relationships between different color/material units that are geographically and temporally associated, (b) better analysis of the temporal variations in the map units, and (c) additional high-resolution images (spatial resolutions ∼200 m/pixel or better). These improvements would be greatly facilitated by new data, which could be obtained by future missions.