Titan's 5-micron lightcurve

We report on repeated mid-resolution (R∼2000) spectroscopic observations of Titan, acquired between November 2002 and January 2003 with ISAAC at the ESO/VLT and covering the 4.84-5.05 μm range. These observations, which sample four different positions of Titan around Saturn, clearly indicate a variability of the 5-μm continuum albedo, with Titan's geometric albedo decreasing by ∼40% from Titan's leading side to the trailing side. This Titan 5-μm “lightcurve” appears to be in phase with the other near-infrared lightcurves. This can be understood in terms of a surface model in which water ice coexists in minor and variable proportions (13-25%, if pure) with a second, dark, component.     

Optical constants of Titan tholins at mid-infrared wavelengths (2.5–25 μm) and the possible chemical nature of Titan’s haze particles

Complex organic materials may exist as haze layers in the atmosphere of Titan and as dark coloring agents on icy satellite surfaces. Laboratory measurements of optical constants of plausible complex organic materials are necessary for quantitative evaluation from remote sensing observations, and to document the existence of complex organic materials in the extraterrestrial environments. The recent Cassini VIMS and CIRS observations provide new constraints on Titan’s haze properties in the mid-infrared wavelength region. Here, we present the optical constants (2.5–25 μm) of Titan tholins generated with cold plasma irradiation of a N₂/CH₄ (90/10) gas mixture at pressures of 0.26 mbar, 1.6 mbar, and 23 mbar. Our new optical constants of three types of Titan tholins suggest that no single Titan tholin in this study fulfills all the observational constraints of the Titan haze material. The discrepancy remains a challenge for future modeling and laboratory efforts that aim toward a better understanding of Titan’s haze material.     

Seasonal photometric variability of Titan, 1972–2006

Measurements at Lowell Observatory of Titan in the b (472 nm) and y (551 nm) filters of the Strömgren photometric system at thirty four consecutive apparitions (282 nights) from 1971/72 to 2006 show a 10% sinusoidal variation that lags seasonal extremes by about 1/8 of a Titan year. The seasonal variations are asymmetric: the autumn lightcurve maxima of the northern and southern hemispheres differ significantly as do the spring lightcurve minima. Changes also occur from one Titan year to the next: Titan was ∼3% fainter in b and ∼1% fainter in y following the 2002 southern summer solstice than it was one Titan year earlier in 1973. These changes appear to be intrinsic to Titan's atmosphere and cannot be explained by instrumental effects and changing geometries. Orbital variations visible in recent Hubble Space Telescope images at 673 nm and Voyager orange images (590–640 nm) may have a small (0.002±0.001 mag) counterpart in the b, y photometric record (eastern elongation brighter, consistent with the Cassini near-infrared albedo map).     

Persistent rings in and around Jupiter’s anticyclones – Observations and theory

We present observations and theoretical calculations to derive the vertical structure of and secondary circulation in jovian vortices, a necessary piece of information to ultimately explain the red color in the annular ring inside Jupiter’s Oval BA. The observations were taken with the near-infrared detector NIRC2 coupled to the adaptive optics system on the 10-m W.M. Keck telescope (UT 21 July 2006; UT 11 May 2008) and with the Hubble Space Telescope at visible wavelengths (UT 24 and 25 April 2006 using ACS; UT 9 and 10 May 2008 using WFPC2). The spatial resolution in the near-IR (∼0.1–0.15″ at 1–5 μm) is comparable to that obtained at UV–visible wavelengths (∼0.05–0.1″ at 250–890 nm). At 5 μm we are sensitive to Jupiter’s thermal emission, whereas at shorter wavelengths we view the planet in reflected sunlight. These datasets are complementary, as images at 0.25–1.8 μm provide information on the clouds/hazes in the troposphere–stratosphere, while the 5-μm emission maps yield information on deeper layers in the atmosphere, in regions without clouds. At the latter wavelength numerous tiny ovals can be discerned at latitudes between ∼45°S and 60°S, which show up as rings with diameters ?1000 km surrounding small ovals visible in HST data. Several white ovals at 41°S, as well as a new red oval that was discovered to the west of the GRS, also reveal 5-μm bright rings around their peripheries, which coincide with dark/blue rings at visible wavelengths. Typical brightness temperatures in these 5-μm bright rings are 225–250 K, indicative of regions that are cloud-free down to at least the ∼4 bar level, and perhaps down to 5–7 bar, i.e., well within the water cloud.Radiative transfer modeling of the 1–2 μm observations indicates that all ovals, i.e., including the Great Red Spot (GRS), Red Oval BA, and the white ovals at 41°S, are overall very similar in vertical structure. The main distinction between the ovals is caused by variations in the particle densities in the tropospheric–stratospheric hazes (2–650 mbar). These are 5–8 times higher above the red ovals than above the white ones at 41°S. The combination of the 5-μm rings and the vertical structure derived from near-IR data suggests anticyclones to extend vertically from (at least) the water cloud (∼5 bar) up to the tropopause (∼100–200 mbar), and in some cases into the stratosphere.Based upon our observations, we propose that air is rising along the center of a vortex, and descending around the outer periphery, producing the 5-μm bright rings. Observationally, we constrain the maximum radius of these rings to be less than twice the local Rossby deformation radius, L_R. If the radius of the visible oval (i.e., the clouds that make the oval visible) is >3000 km, our observations suggest that the descending part of the secondary circulation must be within these ovals. For the Red Oval BA, we postulate that the return flow is at the location of its red annulus, which has a radius of ∼3000 km.We develop a theory for the secondary circulation, where air is (baroclinically) rising along the center of a vortex in a subadiabatic atmosphere, and descending at a distance not exceeding ∼2× the local Rossby deformation radius. Using this model, we find a timescale for mixing throughout the vortex of order several months, which suggests that the chromophores that are responsible for the red color of Oval BA’s red annulus must be produced locally, at the location of the annulus. This production most likely results from the adiabatic heating in the descending part of the secondary circulation. Such higher-than-ambient temperature causes NH₃–ice to sublime, which will expose the condensation nuclei, such as the red chromophores.     

The near-IR spectrum of Titan modeled with an improved methane line list

We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ∼5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8 m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to ∼2.1 μm. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 μm. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 μm and allow us to model regions, such as the 1.55 μm window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 μm and 2 μm windows. After the methane lines are modeled our observations are sensitive to additional absorptions, and we use the data in the 1.55 μm region to determine a D/H ratio of 1.77 ± 0.20 × 10⁻⁴, and a CO mixing ratio of 50 ± 11 ppmv. In the 2 μm window we detect absorption features that can be identified with the ν₅ + 3ν₆ and 2ν₃ + 2ν₆ bands of CH₃D.     

The role of organic haze in Titan's atmospheric chemistry: I. Laboratory investigation on heterogeneous reaction of atomic hydrogen with Titan tholin

In Titan's atmosphere consisting of N₂ and CH₄, large amounts of atomic hydrogen are produced by photochemical reactions during the formation of complex organics. This atomic hydrogen may undergo heterogeneous reactions with organic aerosol in the stratosphere and mesosphere of Titan. In order to investigate both the mechanisms and kinetics of the heterogeneous reactions, atomic deuterium is irradiated onto Titan tholin formed from N₂ and CH₄ gas mixtures at various surface-temperatures of the tholin ranging from 160 to 310 K. The combined analyses of the gas species and the exposed tholin indicate that the interaction mechanisms of atomic deuterium with the tholin are composed of three reactions; (a) abstraction of hydrogen from tholin resulting in gaseous HD formation (HD recombination), (b) addition of D atom into tholin (hydrogenation), and (c) removal of carbon and/or nitrogen (chemical erosion). The reaction probabilities of HD recombination and hydrogenation are obtained as ηabst=1.9(±0.6)×¹⁰⁻³×exp(−300/T) and ηhydro=2.08(±0.64)×exp(−1000/T), respectively. The chemical erosion process is very inefficient under the conditions of temperature range of Titan's stratosphere and mesosphere. Under Titan conditions, the rates of hydrogenation > HD recombination ? chemical erosion. Our measured HD recombination rate is about 10 times (with an uncertainty of a factor of 3-5) the prediction of previous theoretical model. These results imply that organic aerosol can remove atomic hydrogen efficiently from Titan's atmosphere through the heterogeneous reactions and that the presence of aerosol may affect the subsequent organic chemistry.     

Ultraviolet spectroscopy of Asteroid (4) Vesta

We report a comprehensive review of the UV–visible spectrum and rotational lightcurve of Vesta combining new observations by Hubble Space Telescope and Swift Gamma-ray Burst Observatory with archival International Ultraviolet Explorer observations. The geometric albedos of Vesta from 220 nm to 953 nm are derived by carefully comparing these observations from various instruments at different times and observing geometries. Vesta has a rotationally averaged geometric albedo of 0.09 at 250 nm, 0.14 at 300 nm, 0.26 at 373 nm, 0.38 at 673 nm, and 0.30 at 950 nm. The linear spectral slope as measured between 240 and 320 nm in the ultraviolet displays a sharp minimum near a sub-Earth longitude of 20°, and maximum in the eastern hemisphere. This is consistent with the longitudinal distribution of the spectral slope in the visible wavelength. The photometric uncertainty in the ultraviolet is ∼20%, and in the visible wavelengths it is better than 10%. The amplitude of Vesta’s rotational lightcurves is ∼10% throughout the range of wavelengths we observed, but is smaller at 950 nm (∼6%) near the 1-μm band center. Contrary to earlier reports, we found no evidence for any difference between the phasing of the ultraviolet and visible/near-infrared lightcurves with respect to sub-Earth longitude. Vesta’s average spectrum between 220 and 950 nm can well be described by measured reflectance spectra of fine particle howardite-like materials of basaltic achondrite meteorites. Combining this with the in-phase behavior of the ultraviolet, visible, and near-infrared lightcurves, and the spectral slopes with respect to the rotational phase, we conclude that there is no global ultraviolet/visible reversal on Vesta. Consequently, this implies a lack of global space weathering on Vesta, as previously inferred from visible–near-infrared data.     

Laboratory experiments of Titan tholin formed in cold plasma at various pressures: implications for nitrogen-containing polycyclic aromatic compounds in Titan haze

Titan, the largest satellite of Saturn, has a thick nitrogen/methane atmosphere with a thick global organic haze. A laboratory analogue of Titan's haze, called tholin, was formed in an inductively coupled plasma from nitrogen/methane=90/10 gas mixture at various pressures ranging from 13 to 2300 Pa. Chemical and optical properties of the resulting tholin depend on the deposition pressure in cold plasma. Structural analyses by IR and UV/VIS spectroscopy, microprobe laser desorption/ionization mass spectrometry, and Raman spectroscopy suggest that larger amounts of aromatic ring structures with larger cluster size are formed at lower pressures (13 and 26 Pa) than at higher pressures (160 and 2300 Pa). Nitrogen is more likely to incorporate into carbon networks in tholins formed at lower pressures, while nitrogen is bonded as terminal groups at higher pressures. Elemental analysis reveals that the carbon/nitrogen ratio in tholins increases from 1.5-2 at lower pressures to 3 at 2300 Pa. The increase in the aromatic compounds and the decrease in C/N ratio in tholin formed at low pressures indicate the presence of the nitrogen-containing polycyclic aromatic compounds in tholin formed at low pressures. Tholin formed at high pressure (2300 Pa) consists of a polymer-like branched chain structure terminated with CH₃, NH₂, and CN with few aromatic compounds. Reddish-brown tholin films formed at low pressures (13-26 Pa) shows stronger absorptions (almost 10 times larger k-value) in the UV/VIS range than the yellowish tholin films formed at high pressures (160 and 2300 Pa). The tholins formed at low pressures may be better representations of Titan's haze than those formed at high pressures, because the optical properties of tholin formed at low pressures agree well with that of Khare et al. (1984a, Icarus 60, 127-137), which have been shown to account for Titan's observed geometric albedo. Thus, the nitrogen-containing polycyclic aromatic compounds we find in tholin formed at low pressure may be present in Titan's haze. These aromatic compounds may have a significant influence on the thermal structure and complex organic chemistry in Titan's atmosphere, because they are efficient absorbers of UV radiation and efficient charge exchange intermediaries. Our results also indicate that the haze layers at various altitudes might have different chemical and optical properties.     

Channel morphometry, sediment transport, and implications for tectonic activity and surficial ages of Titan basins

Fluvial features on Titan and drainage basins on Earth are remarkably similar despite differences in gravity and surface composition. We determined network bifurcation (R_b) ratios for five Titan and three terrestrial analog basins. Tectonically-modified Earth basins have R_b values greater than the expected range (3.0-5.0) for dendritic networks; comparisons with R_b values determined for Titan basins, in conjunction with similarities in network patterns, suggest that portions of Titan’s north polar region are modified by tectonic forces. Sufficient elevation data existed to calculate bed slope and potential fluvial sediment transport rates in at least one Titan basin, indicating that 75 mm water ice grains (observed at the Huygens landing site) should be readily entrained given sufficient flow depths of liquid hydrocarbons. Volumetric sediment transport estimates suggest that ∼6700-10,000 Titan years (∼2.0-3.0 × 10⁵ Earth years) are required to erode this basin to its minimum relief (assuming constant 1 m and 1.5 m flows); these lowering rates increase to ∼27,000-41,000 Titan years (∼8.0-12.0 × 10⁵ Earth years) when flows in the north polar region are restricted to summer months.     

A multi-wavelength study of the 2009 impact on Jupiter: Comparison of high resolution images from Gemini,Keck and HST

Within several days of A. Wesley’s announcement that Jupiter was hit by an object on UT 19 July 2009, we observed the impact site with (1) the Hubble Space Telescope (HST) at UV through visible (225–924 nm) wavelengths, (2) the 10-m W.M. Keck II telescope in the near-infrared (1–5 μm), and (3) the 8-m Gemini-North telescope in the mid-infrared (7.7–18 μm). All observations reported here were obtained between 22 and 25 July 2009. Observations at visible and near-infrared wavelengths show that large (～0.75-μm radius) dark (imaginary index of refraction m_i ～ 0.01–0.1) particulates were deposited at atmospheric pressures between 10 and 200–300 mbar; analysis of HST-UV data reveals that in addition smaller-sized (～0.1 μm radius) material must have been deposited at the highest altitudes (～10 mbar). Differences in morphology between the UV and visible/near-IR images suggest three-dimensional variations in particle size and density across the impact site, which probably were induced during the explosion and associated events. At mid-infrared wavelengths the brightness temperature increased due to both an enhancement in the stratospheric NH₃ gas abundance and the physical temperature of the atmosphere. This high brightness temperature coincides with the center part of the impact site as seen with HST. This observation, combined with (published) numerical simulations of the Shoemaker-Levy 9 impacts on Jupiter and the Tunguska airburst on Earth, suggests that the downward jet from the terminal explosion probably penetrated down to the ～700-mbar level.     

Europa’s ridged plains and smooth low albedo plains: Distinctive compositions and compositional gradients at the leading side-trailing side boundary

This investigation uses linear mixture modeling employing cryogenic laboratory reference spectra to estimate surface compositions and water ice grain sizes of Europa’s ridged plains and smooth low albedo plains. Near-infrared spectra for 23 exposures of ridged plains materials are analyzed along with 11 spectra representing low albedo plains. Modeling indicates that these geologic units differ both in the relative abundance of non-ice hydrated species and in the abundance and grain sizes of water ice. The background ridged plains in our study area appear to consist predominantly of water ice (∼46%) with approximately equal amounts (on average) of hydrated sulfuric acid (∼27%) and hydrated salts (∼27%). The solutions for the smooth low albedo plains are dominated by hydrated salts (∼62%), with a relatively low mean abundance of water ice (∼10%), and an abundance of hydrated sulfuric acid similar to that found in ridged plains (∼27%). The model yields larger water ice grain sizes (100 μm versus 50-75 μm) in the ridged plains. The 1.5-μm water ice absorption band minimum is found at shorter wavelengths in the low albedo plains deposits than in the ridged plains (1.498 ± .003 μm versus 1.504 ± .001 μm). The 2.0-μm band minimum in the low albedo plains exhibits a somewhat larger blueshift (1.964 ± .006 μm versus 1.983 ± .006 μm for the ridged plains).The study area spans longitudes from 168° to 185°W, which includes Europa’s leading side-trailing side boundary. A well-defined spatial gradient of sulfuric acid hydrate abundance is found for both geologic units, with concentrations increasing in the direction of the trailing side apex. We associate this distribution with the exogenic effects of magnetospheric charged particle bombardment and associated chemical processing of surface materials (the radiolytic sulfur cycle). However, one family of low albedo plains exposures exhibits sulfuric acid hydrate abundances up to 33% lower than found for adjacent exposures, suggesting that these materials have undergone less processing, thus implying that these deposits may have been emplaced more recently.Modeling identifies high abundances (to 30%) of magnesium sulfate brines in the low albedo plains exposures. Our investigation marks the first spectroscopic identification of MgSO₄ brine on Europa. We also find significantly higher abundances of sodium-bearing species (bloedite and mirabilite) in the low albedo plains. The results illuminate the role of radiolytic processes in modifying the surface composition of Europa, and may provide new constraints for models of the composition of Europa’s putative subsurface ocean.     

Evidence for asteroid space weathering from the Sloan Digital Sky Survey

By studying color variations between young and old asteroid families we find evidence for processes that modify colors of asteroids over time. We show that colors of aging surfaces of S-type asteroids become increasingly ‘redder’ and measure the rate of these spectral changes. We estimate that the mean spectral slope between 0.35 and 0.9 μm increases with time t (given in My) as ≈0.01 μm⁻¹×log₁₀t. This empirical fit is valid only for 2.5?t?3000 My (the time interval where we have data) and for the mean spectral slope determined from wide-wavelength filter photometry obtained by the Sloan Digital Sky Survey. We also find that Gy-old terrains of S-type asteroids reflect about 15% more light at ∼1-μm wavelengths than an ∼5-My-old S-type asteroid surface when the flux is normalized by the reflected light at 0.55 μm. We attribute these effects to space weathering. This result has important implications for asteroid geology and the origin of meteorites that reach the Earth. Our results also suggest that surfaces of C-type asteroids exhibit color alterations opposite to those of the S-type asteroids.     

Titan: Preliminary results on surface properties and photometry from VIMS observations of the early flybys

Cassini observations of the surface of Titan offer unprecedented views of its surface through atmospheric windows in the 1-5 μm region. Images obtained in windows for which the haze opacity is low can be used to derive quantitative photometric parameters such as albedo and albedo distribution, and physical properties such as roughness and particle characteristics. Images from the early Titan flybys, particularly T0, Ta, and T5 have been analyzed to create albedo maps in the 2.01 and 2.73 μm windows. We find the average normal reflectance at these two wavelengths to be 0.15±0.02 and 0.035±0.003, respectively. Titan's surface is bifurcated into two albedo regimes, particularly at 2.01 μm. Analysis of these two regimes to understand the physical character of the surface was accomplished with a macroscopic roughness model. We find that the two types of surface have substantially different roughness, with the low-albedo surface exhibiting mean slope angles of ∼18°, and the high-albedo terrain having a much more substantial roughness with a mean slope angle of ∼34°. A single-scattering phase function approximated by a one-term Henyey-Greenstein equation was also fit to each unit. Titan's surface is back-scattering (g∼0.3-0.4), and does not exhibit substantially different backscattering behavior between the two terrains. Our results suggest that two distinct geophysical domains exist on Titan: a bright region cut by deep drainage channels and a relatively smooth surface. The two terrains are covered by a film or a coating of particles perhaps precipitated from the satellite's haze layer and transported by eolian processes. Our results are preliminary: more accurate values for the surface albedo and physical parameters will be derived as more data is gathered by the Cassini spacecraft and as a more complete radiative transfer model is developed from both Cassini orbiter and Huygens Lander measurements.     

Threshold of wave generation on Titan’s lakes and seas: Effect of viscosity and implications for Cassini observations

Motivated by radar and near-infrared data indicating that Titan’s polar lakes are extremely smooth, we consider the conditions under which a lake surface will be ruffled by wind to form capillary waves. We evaluate laboratory data on wind generation and derive, without scaling for surface tension effects, a threshold for pure methane/ethane of ∼0.5-1 m/s. However, we compute the physical properties of predicted Titan lake compositions using the National Institute for Standards Technology (NIST) code and note that dissolved amounts of C3 and C4 compounds are likely to make Titan lakes much more viscous than pure ethane or methane, even without allowing for suspended particulates which would increase the viscosity further. Wind tunnel experiments show a strong dependence of capillary wave growth on liquid viscosity, and this effect may explain the apparent absence so far of waves, contrary to prior expectations that generation of gravity waves by wind should be easy on Titan. On the other hand, we note that winds over Titan lakes predicted with the TitanWRF Global Circulation Model indicate radar observations so far have in any case been when winds have been low (∼0.5-0.7 m/s), possibly below the wave generation threshold, while peak winds during summer may reach 1-2 m/s. Thus observations of Titan’s northern lakes during the coming years by the Cassini Solstice mission offer the highest probability of observing wind-roughening of lake surfaces, while observations of Ontario Lacus in the south will likely continue to show it to be flat and smooth.     

On Titan’s Xanadu region

A large, circular marking ∼1800 km across is seen in near-infrared images of Titan. The feature is centered at 10°S, 120°W on Titan, encompasses much of Titan’s western Xanadu region, and has an off-center, quasi-circular, inner margin about 700 km across, with lobate outer margins extending 200-500 km from the inner margin. On the feature’s southern flank is Tui Regio, an area that has very high reflectivity at 5 μm, and is hypothesized to exhibit geologically recent cryovolcanic flows (Barnes, J.W. et al. [2006]. Geophys. Res. Lett. 33), similar to flows seen in Hotei Regio, a cryovolcanic area whose morphology may be controlled by pre-existing, crustal fractures resulting from an ancient impact (Soderblom, L.A. et al. [2009]. Icarus, 204). The spectral reflectivity of the large, circular feature is quite different than that of its surroundings, making it compositionally distinct, and radar measurements of its topography, brightness temperature and volume scattering also suggest that the feature is quite distinct from its surroundings. These and several other lines of evidence, in addition to the feature’s morphology, suggest that it may occupy the site of an ancient impact.     

Near-Infrared Spectrophotometry of Phobos and Deimos

We have observed the leading and trailing hemispheres of Phobos from 1.65 to 3.5 μm and Deimos from 1.65 to 3.12 μm near opposition. We find the trailing hemisphere of Phobos to be brighter than its leading hemisphere by 0.24±0.06 magnitude at 1.65 μm and brighter than Deimos by 0.98±0.07 magnitude at 1.65 μm. We see no difference larger than observational uncertainties in spectral slope between the leading and trailing hemispheres when the spectra are normalized to 1.65 μm. We find no 3-μm absorption feature due to hydrated minerals on either hemisphere to a level of ∼5-10% on Phobos and ∼20% on Deimos. When the infrared data are joined to visible and near-IR data obtained by previous workers, our data suggest the leading (Stickney-dominated) side of Phobos is best matched by T-class asteroids. The spectral slope of the trailing side of Phobos and leading side of Deimos are bracketed by the D-class asteroids. The best laboratory spectral matches to these parts of Phobos are mature lunar soils and heated carbonaceous chondrites. The lack of 3-μm absorption features on either side of Phobos argues against the presence of a large interior reservoir of water ice according to current models of Phobos' interior (F. P. Fanale and J. R. Salvail 1989, Geophys. Res. Lett.16, 287-290; Icarus88, 380-395).     

Composition of Titan''s surface from Cassini VIMS

Titan's bulk density along with Solar System formation models indicates considerable water as well as silicates as its major constituents. This satellite's dense atmosphere of nitrogen with methane is unique. Deposits or even oceans of organic compounds have been suggested to exist on Titan's solid surface due to UV-induced photochemistry in the atmosphere. Thus, the composition of the surface is a major piece of evidence needed to determine Titan's history. However, studies of the surface are hindered by the thick, absorbing, hazy and in some places cloudy atmosphere. Ground-based telescope investigations of the integral disk of Titan attempted to observe the surface albedo in spectral windows between methane absorptions by calculating and removing the haze effects. Their results were reported to be consistent with water ice on the surface that is contaminated with a small amount of dark material, perhaps organic material like tholin. We analyze here the recent Cassini Mission's visual and infrared mapping spectrometer (VIMS) observations that resolve regions on Titan. VIMS is able to see surface features and shows that there are spectral and therefore likely compositional units. By several methods, spectral albedo estimates within methane absorption windows between 0.75 and 5 μm were obtained for different surface units using VIMS image cubes from the Cassini-Huygens Titan T_a encounter. Of the spots studied, there appears to be two compositional classes present that are associated with the lower albedo and the higher albedo materials, with some variety among the brighter regions. These were compared with spectra of several different candidate materials. Our results show that the spectrum of water ice contaminated with a darker material matches the reflectance of the lower albedo Titan regions if the spectral slope from 2.71 to 2.79 μm in the poorly understood 2.8-μm methane window is ignored. The spectra for brighter regions are not matched by the spectrum of water ice or unoxidized tholin, in pure form or in mixtures with sufficient ice or tholin present to allow the water ice or tholin spectral features to be discerned. We find that the 2.8-μm methane absorption window is complex and seems to consist of two weak subwindows at 2.7 and 2.8 μm that have unknown opacities. A ratio image at these two wavelengths reveals an anomalous region on Titan that has a reflectance unlike any material so far identified, but it is unclear how much the reflectances in these two subwindows pertain to the surface.     

Correlations between Cassini VIMS spectra and RADAR SAR images: Implications for Titan's surface composition and the character of the Huygens Probe Landing Site

Titan's vast equatorial fields of RADAR-dark longitudinal dunes seen in Cassini RADAR synthetic aperture images correlate with one of two dark surface units discriminated as “brown” and “blue” in Visible and Infrared Mapping Spectrometer (VIMS) color composites of short-wavelength infrared spectral cubes (RGB as 2.0, 1.6, 1.3 μm). In such composites bluer materials exhibit higher reflectance at 1.3 μm and lower at 1.6 and 2.0 μm. The dark brown unit is highly correlated with the RADAR-dark dunes. The dark brown unit shows less evidence of water ice suggesting that the saltating grains of the dunes are largely composed of hydrocarbons and/or nitriles. In general, the bright units also show less evidence of absorption due to water ice and are inferred to consist of deposits of bright fine precipitating tholin aerosol dust. Some set of chemical/mechanical processes may be converting the bright fine-grained aerosol deposits into the dark saltating hydrocarbon and/or nitrile grains. Alternatively the dark dune materials may be derived from a different type of air aerosol photochemical product than are the bright materials. In our model, both the bright aerosol and dark hydrocarbon dune deposits mantle the VIMS dark blue water ice-rich substrate. We postulate that the bright mantles are effectively invisible (transparent) in RADAR synthetic aperture radar (SAR) images leading to lack of correlation in the RADAR images with optically bright mantling units. RADAR images mostly show only dark dunes and the water ice substrate that varies in roughness, fracturing, and porosity. If the rate of deposition of bright aerosol is 0.001–0.01 μm/yr, the surface would be coated (to optical instruments) in hundreds-to-thousands of years unless cleansing processes are active. The dark dunes must be mobile on this very short timescale to prevent the accumulation of bright coatings. Huygens landed in a region of the VIMS bright and dark blue materials and about 30 km south of the nearest occurrence of dunes visible in the RADAR SAR images. Fluvial/pluvial processes, every few centuries or millennia, must be cleansing the dark floors of the incised channels and scouring the dark plains at the Huygens landing site both imaged by Descent Imager/Spectral Radiometer (DISR).     

Optical constants of organic tholins produced in a simulated Titanian atmosphere: From soft x-ray to microwave frequencies

As part of a continuing series of experiments on the production of dark reddish organic solids, called tholins, by irradiation of cosmically abundant reducing gases, the synthesis from a simulated Titanian atmosphere of a tholin with a visible reflection spectrum similar to that of the high altitude aerosols responsible for the albedo and reddish color of Titan has been reported Sagan and Khare, 1981, Sagan and Khare, 1982, Orig. Life. 12, 280) and [C. Sagan, B. N. Khare, and J. Lewis, in press. In Saturn (M. S. Matthews and T. Gehrels, Eds.), Univ. of Arizona Press, Tucson]. The determination of the real (n) and imaginary (k) parts of the complex refractive index of thin films of such tholin prepared by continuous D.C. discharge through a 0.9 N₂/0.1 CH₄ gas mixture at 0.2 mb are reported. For $\text{250}\text{A}\text{?}\text{≤ γ ≤ 1000 μ}\text{m}\text{, n}\text{and}\text{k}$ have been determined from a combination of transmittance, specular reflectance, interferometric, Brewster angle, and ellipsometric polarization measurements; experimental uncertainties in n are estimated to be ±0.5, and in k ± 30%. Values of n(?1.65) and k (?0.004 to 0.08) in the visible range are consistent with deductions made by ground-based and spacecraft observations of Titan. Maximum values of k (?0.8) are near 1000 Å, and minimum values (?4 × 10^?4) are near 1.5 μm. Many infrared absorption features are present in k(γ), including the 4.6-μm nitrile band.