The three-dimensional structure of Saturn's equatorial jet at cloud level

The three-dimensional structure of Saturn's intense equatorial jet from latitudes 8° N to 20° S is revealed from detailed measurements of the motions and spectral reflectivity of clouds at visible wavelengths on high resolution images obtained by the Cassini Imaging Science Subsystem (ISS) in 2004 and early 2005. Cloud speeds at two altitude levels are measured in the near infrared filters CB2 and CB3 matching the continuum (effective wavelengths 750 and 939 nm) and in the MT2 and MT3 filters matching two methane absorption bands (effective wavelengths 727 and 889 nm). Radiative transfer models in selective filters covering an ample spectral range (250-950 nm) require the existence of two detached aerosol layers in the equator: an uppermost thin stratospheric haze extending between the pressure levels ∼20 and 40 mbar (tropopause level) and below it, a dense tropospheric haze-cloud layer extending between 50 mbar and the base of the ammonia cloud (between ∼1 and 1.4 bar). Individual cloud elements are detected and tracked in the tropospheric dense haze at 50 and 700 mbar (altitude levels separated by 142 km). Between latitudes 5° N and 12° S the winds increase their velocity with depth from 265 m s⁻¹ at the 50 mbar pressure level to 365 m s⁻¹ at 700 mbar. These values are below the high wind speeds of 475 m s⁻¹ measured at these latitudes during the Voyager era in 1980-1981, indicating that the equatorial jet has suffered a significant intensity change between that period and 1996-2005 or that the tracers of the flow used in the Voyager images were rooted at deeper levels than those in Cassini images.     

Saturn's cloud structure and temporal evolution from ten years of Hubble Space Telescope images (1994-2003)

We present a study of the vertical structure of clouds and hazes in the upper atmosphere of Saturn's Southern Hemisphere during 1994-2003, about one third of a Saturn year, based on Hubble Space Telescope images. The photometrically calibrated WFPC2 images cover the spectral region between the near-UV (218-255 nm) and the near-IR (953-1042 nm), including the 890 nm methane band. Using a radiative transfer code, we have reproduced the observed center-to-limb variations in absolute reflectivity at selected latitudes which allowed us to characterize the vertical structure of the entire hemisphere during this period. A model atmosphere with two haze layers has been used to study the variation of hazes with latitude and to characterize their temporal changes. Both hazes are located above a thick cloud, putatively composed of ammonia ice. An upper thin haze in the stratosphere (between 1 and 10 mbar) is found to be persistent and formed by small particles (radii ∼0.2 μm). The lower thicker haze close to the tropopause level shows a strong latitudinal dependence in its optical thickness (typically τ∼20-40 at the equator but τ∼5 at the pole, at 814 nm). This tropospheric haze is blue-absorbent and extends from 50 to 100 mbar to about ∼400 mbar. Both hazes show temporal variability, but at different time-scales. First, there is a tendency for the optical thickness of the stratospheric haze to increase at all latitudes as insolation increases. Second, the tropospheric haze shows mid-term changes (over time scales from months to 1-2 years) in its optical thickness (typically by a factor of 2). Such changes always occur within a rather narrow latitude band (width ∼5-10°), affecting almost all latitudes but at different times. Third, we detected a long-term (∼10 year) decrease in the blue single-scattering albedo of the tropospheric haze particles, most intense in the equatorial and polar areas. Long-term changes follow seasonal insolation variations smoothly without any apparent delay, suggesting photochemical processes that affect the particles optical properties as well as their size. In contrast, mid-term changes are sudden and show various time-scales, pointing to a dynamical origin.     

Temporal variation of the tropospheric cloud and haze in the jovian equatorial zone

We analyze the temporal variation of the tropospheric cloud and haze in the jovian equatorial zone. In order to investigate the time evolution of the haze, we utilize a comprehensive set of archival WFPC2 images in the 953 and 893-nm wavelengths spanning over a decade of HST observations of Jupiter. We find that the latitude of the peak haze reflectivity experienced a southerly shift in between late-1998 and early-2001 (not to be confused with southerly bulk transport of haze particles themselves); before this shift, the latitude of peak reflectivity had remained relatively stable at +7° (planetographic latitude). We examine the average haze reflectivity at three equatorial latitudes (−5°, 0°, +5°) and find variability of amplitude ±20%. Equatorial clouds, which lie deeper than the haze, showed zonal mean variability with an amplitude of about 5% except during the global upheaval of 2006-2007 in which cloud reflectivity dropped up to 16% depending on latitude. An analysis of temporal correlation between zonally averaged cloud reflectivity and zonally averaged haze reflectivity indicates a time-lag of about 1200 days (with a lower limit of 800 days) between changes in cloud reflectivity and later changes in haze reflectivity, but limitations in the temporal coverage of even this extensive dataset make it impossible to rule out even longer time-lags.     

The haze and methane distributions on Neptune from HST-STIS spectroscopy

We analyzed a data cube of Neptune acquired with the Hubble STIS spectrograph on August 3, 2003. The data covered the full afternoon hemisphere at 0.1 arcsec spatial resolution between 300 and 1000 nm wavelength at 1 nm resolution. Navigation was accurate to 0.004 arcsec and 0.05 nm. We constrained the vertical aerosol structure with radiative transfer calculations. Ultraviolet data confirmed the presence of a stratospheric haze of optical depth 0.04 at 370 nm wavelength. Bright, discrete clouds, most abundant near latitudes −40° and 30°, had their top near the tropopause. They covered 1.7% of the observed disk if they were optically thick. The methane abundance above the cloud tops was 0.0026 and 0.0017 km-am for southern and northern clouds, respectively, identical to earlier observations by Sromovsky et al. (Sromovsky, L.A., Fry, P.M., Dowling, T.E., Baines, K.H., Limaye, S.S., [2001b]. Icarus 149, 459-488). Aside from these clouds, the upper troposphere was essentially clear. Below the 1.4-bar layer, a vertically uniform haze extended at least down to 10 bars with optical depth of 0.10-0.16/bar, depending on the latitude. Haze particles were bright at wavelengths above 600 nm, but darkened toward the ultraviolet, at the equator more so than at mid and high latitudes. A dark band near −60° latitude was caused by a 0.01 decrease of the single scattering albedo in the visible, which was close to unity. A comparison of methane and hydrogen absorptions contradicted the current view that methane is uniformly mixed in latitude and altitude below the ∼1.5-bar layer. The 0.04 ± 0.01 methane mixing ratio is only uniform at low latitudes. At high southern latitudes, it is depressed roughly between the 1.2 and 3.3-bar layers compared to low-latitude values. The maximum depression factor is ∼2.7 at 1.8 bars. We present models with 2° latitude sampling across the full sunlit globe that fit the observed reflectivities to 2.8% rms.     

Vertical structure modeling of Saturn's equatorial region using high spectral resolution imaging

A series of narrow-band images of Saturn was acquired on 7-11 February 2002 with an acousto-optic imaging spectrometer (AImS) at about 160 wavelengths between 500 and 950 nm. Our unique data set with high spectral agility and wide spectral coverage enabled us to extensively study the cloud structure and aerosol properties of Saturn's equatorial region at −10° latitude. Theoretical center-limb profiles based on twelve cloud models were fit to the observations at 23 wavelengths across the 619-, 727-, and 890-nm methane bands. A simultaneous multiwavelength multivariable fitting algorithm was adopted in varying up to 9 free parameters to efficiently explore the vast multidimensional parameter space, and a total of ∼12,000 initial conditions were tested. From the acceptable ranges of the model parameters, we obtained the following major conclusions: (1) the brightening of Saturn's equatorial region observed near 890 nm in February 2002 (I/F∼0.25 at the central meridian) results from high altitudes of a stratospheric haze layer (τ?∼0.05 above ∼0.04-bar level) and an upper tropospheric cloud (τ∼6 above ∼0.25-bar level), (2) if the upper tropospheric cloud is composed of ammonia ice particles and the Mie theory is applied, the mean particle size is larger than about 0.5 μm, (3) an optically thick cloud layer exists at a level of 0.5-2.2 bar below the upper cloud deck in Saturn's equatorial region. The ongoing observations by the Cassini spacecraft over wider spectral range and from various phase angles will further constrain Saturn's cloud structure and aerosol properties.     

Analysis of Cassini/CIRS limb spectra of Titan acquired during the nominal mission II: Aerosol extinction profiles in the 600–1420 cm spectral range

We have analyzed the continuum emission of limb spectra acquired by the Cassini/CIRS infrared spectrometer in order to derive information on haze extinction in the 3–0.02 mbar range (∼150–350 km). We focused on the 600–1420 cm⁻¹ spectral range and studied nine different limb observations acquired during the Cassini nominal mission at 55°S, 20°S, 5°N, 30°N, 40°N, 45°N, 55°N, 70°N and 80°N. By means of an inversion algorithm solving the radiative transfer equation, we derived the vertical profiles of haze extinction coefficients from 17 spectral ranges of 20-cm⁻¹ wide at each of the nine latitudes. At a given latitude, all extinction vertical profiles retrieved from various spectral intervals between 600 and 1120 cm⁻¹ display similar vertical slopes implying similar spectral characteristics of the material at all altitudes. We calculated a mean vertical extinction profile for each latitude and derived the ratio of the haze scale height (H_haze) to the pressure scale height (H_gas) as a function of altitude. We inferred H_haze/H_gas values varying from 0.8 to 2.4. The aerosol scale height varies with altitude and also with latitude. Overall, the haze extinction does not show strong latitudinal variations but, at 1 mbar, an increase by a factor of 1.5 is observed at the north pole compared to high southern latitudes. The vertical optical depths at 0.5 and 1.7 mbar increase from 55°S to 5°N, remain constant between 5°N and 30°N and display little variation at higher latitudes, except the presence of a slight local maximum at 45°N. The spectral dependence of the haze vertical optical depth is uniform with latitude and displays three main spectral features centered at 630 cm⁻¹, 745 cm⁻¹ and 1390 cm⁻¹, the latter showing a wide tail extending down to ∼1000 cm⁻¹. From 600 to 750 cm⁻¹, the optical depth increases by a factor of 3 in contrast with the absorbance of laboratory tholins, which is generally constant. We derived the mass mixing ratio profiles of haze at the nine latitudes. Below the 0.4-mbar level all mass mixing ratio profiles increase with height. Above this pressure level, the profiles at 40°N, 45°N, 55°N, at the edge of the polar vortex, display a decrease-with-height whereas the other profiles increase. The global increase with height of the haze mass mixing ratio suggest a source at high altitudes and a sink at low altitudes. An enrichment of haze is observed at 0.1 mbar around the equator, which could be due to a more efficient photochemistry because of the strongest insolation there or an accumulation of haze due to a balance between sedimentation and upward vertical drag.     

Characterising Saturn's vertical temperature structure from Cassini/CIRS

Thermal infrared spectra of Saturn from 10-1400 cm⁻¹ at 15 cm⁻¹ spectral resolution and a spatial resolution of 1°-2° latitude have been obtained by the Cassini Composite Infrared Spectrometer [Flasar, F.M., and 44 colleagues, 2004. Space Sci. Rev. 115, 169-297]. Many thousands of spectra, acquired over eighteen-months of observations, are analysed using an optimal estimation retrieval code [Irwin, P.G.J., Parrish, P., Fouchet, T., Calcutt, S.B., Taylor, F.W., Simon-Miller, A.A., Nixon, C.A., 2004. Icarus 172, 37-49] to retrieve the temperature structure and para-hydrogen distribution over Saturn's northern (winter) and southern (summer) hemispheres. The vertical temperature structure is analysed in detail to study seasonal asymmetries in the tropopause height (65-90 mbar), the location of the radiative-convective boundary (350-500 mbar), and the variation with latitude of a temperature knee (between 150 and 300 mbar) which was first observed in inversions of Voyager/IRIS spectra [Hanel, R., and 15 colleagues, 1981. Science 212, 192-200; Hanel, R., Conrath, B., Flasar, F.M., Kunde, V., Maguire, W., Pearl, J.C., Pirraglia, J., Samuelson, R., Cruikshank, D.P., Gautier, D., Gierasch, P.J., Horn, L., Ponnamperuma, C., 1982. Science 215, 544-548]. Uncertainties due to both the modelling of spectral absorptions (collision-induced absorption coefficients, tropospheric hazes, helium abundance) and the nature of our retrieval algorithm are quantified.Temperatures in the stratosphere near 1 mbar show a 25-30 K temperature difference between the north pole and south pole. This asymmetry becomes less pronounced with depth as the radiative time constant for the atmospheric response increases at deeper pressure levels. Hemispherically-symmetric small-scale temperature structures associated with zonal winds are superimposed onto the temperature asymmetry for pressures greater than 100 mbar. The para-hydrogen fraction in the 100-400 mbar range is greater than equilibrium predictions for the southern hemisphere and parts of the northern hemisphere, and less than equilibrium predictions polewards of 40° N.The temperature knee between 150-300 mbar is larger in the summer hemisphere than in the winter, smaller and higher at the equator, deeper and larger in the equatorial belts and small at the poles. Solar heating on tropospheric haze is proposed as a possible mechanism for this effect; the increased efficiency of ortho- to para-hydrogen conversion in the southern hemisphere is consistent with the presence of larger aerosols in the summer hemisphere, which we demonstrate to be qualitatively consistent with previous studies of Saturn's tropospheric aerosol distribution.     

Meridional transport of HCN from SL9 impacts on Jupiter

In July 1994, the Shoemaker-Levy 9 (SL9) impacts introduced hydrogen cyanide (HCN) to Jupiter at a well confined latitude band around −44°, over a range of specific longitudes corresponding to each of the 21 fragments (Bézard et al. 1997, Icarus 125, 94-120). This newcomer to Jupiter's stratosphere traces jovian dynamics. HCN rapidly mixed with longitude, so that observations recorded later than several months after impact witnessed primarily the meridional transport of HCN north and south of the impact latitude band. We report spatially resolved spectroscopy of HCN emission 10 months and 6 years following the impacts. We detect a total mass of HCN in Jupiter's stratosphere of 1.5±0.7×10¹³ g in 1995 and 1.7±0.4×10¹³ g in 2000, comparable to that observed several days following the impacts (Bézard et al. 1997, Icarus 125, 94-120). In 1995, 10 months after impact, HCN spread to −30° and −65° latitude (half column masses), consistent with a horizontal eddy diffusion coefficient of K_yy=2-3×10¹⁰ cm² s⁻¹. Six years following impact HCN is observed in the northern hemisphere, while still being concentrated at 44° south latitude. Our meridional distribution of HCN suggests that mixing occurred rapidly north of the equator, with K_yy=2-5×10¹¹ cm² s⁻¹, consistent with the findings of Moreno et al. (2003, Planet. Space Sci. 51, 591-611) and Lellouch et al. (2002, Icarus 159, 112-131). These inferred eddy diffusion coefficients for Jupiter's stratosphere at 0.1-0.5 mbar generally exceed those that characterize transport on Earth. The low abundance of HCN detected at high latitudes suggests that, like on Earth, polar regions are dynamically isolated from lower latitudes.     

Phosphine on Jupiter and Saturn from Cassini/CIRS

The global distribution of phosphine (PH₃) on Jupiter and Saturn is derived using 2.5 cm⁻¹ spectral resolution Cassini/CIRS observations. We extend the preliminary PH₃ analyses on the gas giants [Irwin, P.G.J., and 6 colleagues, 2004. Icarus 172, 37-49; Fletcher, L.N., and 9 colleagues, 2007a. Icarus 188, 72-88] by (a) incorporating a wider range of Cassini/CIRS datasets and by considering a broader spectral range; (b) direct incorporation of thermal infrared opacities due to tropospheric aerosols and (c) using a common retrieval algorithm and spectroscopic line database to allow direct comparison between these two gas giants.The results suggest striking similarities between the tropospheric dynamics in the 100-1000 mbar regions of the giant planets: both demonstrate enhanced PH₃ at the equator, depletion over neighbouring equatorial belts and mid-latitude belt/zone structures. Saturn's polar PH₃ shows depletion within the hot cyclonic polar vortices. Jovian aerosol distributions are consistent with previous independent studies, and on Saturn we demonstrate that CIRS spectra are most consistent with a haze in the 100-400 mbar range with a mean optical depth of 0.1 at 10 μm. Unlike Jupiter, Saturn's tropospheric haze shows a hemispherical asymmetry, being more opaque in the southern summer hemisphere than in the north. Thermal-IR haze opacity is not enhanced at Saturn's equator as it is on Jupiter.Small-scale perturbations to the mean PH₃ abundance are discussed both in terms of a model of meridional overturning and parameterisation as eddy mixing. The large-scale structure of the PH₃ distributions is likely to be related to changes in the photochemical lifetimes and the shielding due to aerosol opacities. On Saturn, the enhanced summer opacity results in shielding and extended photochemical lifetimes for PH₃, permitting elevated PH₃ levels over Saturn's summer hemisphere.     

Wind variations in Jupiter's equatorial atmosphere: A QQO counterpart?

Jupiter's equatorial atmosphere, much like the Earth's, is known to show quasi-periodic variations in temperature, particularly in the stratosphere, but variations in other jovian atmospheric tracers have not been studied for any correlations to these oscillations. Data taken at NASA's Infrared Telescope Facility (IRTF) from 1979 to 2000 were used to obtain temperatures at two levels in the atmosphere, corresponding to the upper troposphere (250 mbar) and to the stratosphere (20 mbar). We find that the data show periodic signals at latitudes corresponding to the troposphere zonal wind jets, with periods ranging from 4.4 (stratosphere, 95% confidence at 4° S planetographic latitude) to 7.7 years (troposphere, 97% confidence at 6° N). We also discuss evidence that at some latitudes the troposphere temperature variations are out of phase from the stratosphere variations, even where no periodicity is evident. Hubble Space Telescope images were used, in conjunction with Voyager and Cassini data, to track small changes in the troposphere zonal winds from 20° N to 20° S latitude over the 1994-2000 time period. Oscillations with a period of 4.5 years are found near 7°-8° S, with 80-85% significance. Further, the strongest evidence for a QQO-induced tropospheric wind change tied to stratospheric temperature change occurs near these latitudes, though tropospheric temperatures show little periodicity here. Comparison of thermal winds and measured zonal winds for three dates indicate that cloud features at other latitudes are likely tracked at pressures that can vary by up to a few hundred millibar, but the cloud altitude change required is too large to explain the wind changes measured at 7° S.     

Saturn's vertical and latitudinal cloud structure 1991-2004 from HST imaging in 30 filters

We analyzed 134 images of Saturn taken by the Hubble Space Telescope between 1991 and 2004. The images cover wavelengths between 231 and 2370 nm in 30 filters. We combined some 10 million calibrated reflectivity measurements into 18,000 center-to-limb curves. We used the method of principal component analysis to find the main latitudinal and temporal variations in Saturn's atmosphere and their spectral characteristics. The first principal variation is a strong latitudinal variation of the aerosol optical depth in the upper troposphere. This structure shifts with Saturn's seasons, but the structure on small scales of latitude stays constant. The second principal variation is a variable optical depth of stratospheric aerosols. The optical depth is large at the poles and small at mid- and low latitudes with a steep gradient in-between. This structure remains essentially constant in time. The third principal variation is a variation in the tropospheric aerosol size, which has only shallow gradients with latitude, but large seasonal variations. Thus, aerosol sizes and their phase functions inferred at a particular season are not representative of Saturn's atmosphere at other seasons. Aerosols are largest in the summer and smallest in the winter. The fourth principal variation is a feature of the tropospheric aerosols with irregular latitudinal structure and fast variability, on the time scale of months. Spherical aerosols do not display the spectral characteristic of that feature. We suspect that variations in the shape of aerosols may play a role. We found a spectral feature of the imaginary index of aerosols, which darkens them near 400 nm wavelength. While we can describe Saturn's variations quite accurately, our presented model of Saturn's average atmosphere is still uncertain due to possible systematic offsets in methane absorption data and limitations of the knowledge about the shape of aerosols. In order to compare our results with those from comparable investigations, which used less than 30 filters, we fit models to spectral subsets of our data. We found very different best-fitting models, depending on the subset of filters, indicating a high sensitivity of results on the spectral sampling.     

The altitude of Neptune cloud features from high-spatial-resolution near-infrared spectra

We report on observations of Neptune from the 10-meter W.M. Keck II Telescope on June 17-18 (UT) 2000 and August 2-3 (UT) 2002 using the adaptive optics (AO) system to obtain a spatial resolution of 0.06 arcseconds. With this spatial resolution we can obtain spectra of individual bright features on the disk of Neptune in a filter centered near 2 microns. The use of a gas-only, simple reflecting layer radiative transfer model allows us to estimate the best fit altitudes of 18 bright features seen on these 4 nights and to set a constraint on the fraction of hydrogen in ortho/para equilibrium. On these nights there were three main types of features observed: northern hemisphere features in the range from +30 to −45 degrees; southern hemisphere features in the range from −30 to −50 degrees; and small southern features at −70 degrees. We find that the altitudes of the northern features are in the range from 0.023-0.064 bar, which places them in Neptune's stratosphere. Southern features at −30 to −50 degrees are mainly at altitudes from 0.10 to 0.14 bars. The small features at −70 degrees are somewhat deeper in the upper troposphere, at 0.17 and 0.27 bars. This pattern of features located at higher altitudes in the northern hemisphere and lower altitudes in the south has also been noted by previous observers. The best fits for all the observed spectra give a value of 1.0 for the fraction of hydrogen in ortho/para equilibrium; the value of the helium fraction is less well constrained by the data at 0.24. We suggest that the southern mid-latitude features are methane haze circulated up from below, while the −70° features may be isolated areas of upwelling in a general area of subsidence. Northern bright features may be due to subsidence of stratospheric haze material rather than upwelling and condensation of methane gas. We suggest that convection efficiently transports methane ice clouds to the tropopause in the Southern mid latitudes and thus plays a key role in the stratospheric haze production cycle.     

On the long-term variability of Jupiter’s winds and brightness as observed from Hubble

Hubble Space Telescope Wide Field Planetary Camera 2 imaging data of Jupiter were combined with wind profiles from Voyager and Cassini data to study long-term variability in Jupiter’s winds and cloud brightness. Searches for evidence of wind velocity periodicity yielded a few latitudes with potential variability; the most significant periods were found nearly symmetrically about the equator at 0°, 10-12°N, and 14-18°S planetographic latitude. The low to mid-latitude signals have components consistent with the measured stratospheric temperature Quasi-Quadrennial Oscillation (QQO) period of 4-5 years, while the equatorial signal is approximately seasonal and could be tied to mesoscale wave formation. Robustness tests indicate that a constant or continuously varying periodic signal near 4.5 years would appear with high significance in the data periodograms as long as uncertainties or noise in the data are not of greater magnitude. However, the lack of a consistent signal over many latitudes makes it difficult to interpret as a QQO-related change. In addition, further analyses of calibrated 410-nm and 953-nm brightness scans found few corresponding changes in troposphere haze and cloud structure on QQO timescales. However, stratospheric haze reflectance at 255-nm did appear to vary on seasonal timescales, though the data do not have enough temporal coverage or photometric accuracy to be conclusive. Sufficient temporal coverage and spacing, as well as data quality, are critical to this type of search.     

The first detection of propane on Saturn

We report the first detection of propane, C₃H₈, in Saturn's stratosphere. Observations taken on September 8, 2002 UT at NASA's IRTF using TEXES, show multiple emission lines due to the 748 cm⁻¹ν₂₁ band of C₃H₈. Using a line-by-line radiative transfer code, we are able to fit the data by scaling the propane vertical mixing ratio profile from the photochemical model of Moses et al. [2000. Icarus 143, 244-298]. Multiplicative factors of 0.7 and 0.65 are required to fit the −20° and −80° planetocentric latitude spectra. The resultant profiles are characterized by a 5 mbar mixing ratio of 2.7±0.8×¹⁰⁻⁸ at −20° and at −80° latitude. These results suggest that the time scale for meridional circulation lies between the net photochemical lifetimes of C₂H₂ and C₃H₈, ≈30-600 years.     

Meridional variations in stratospheric acetylene and ethane in the southern hemisphere of the saturnian atmosphere as determined from Cassini/CIRS measurements

These are the first results from nadir studies of meridional variations in the abundance of stratospheric acetylene and ethane from Cassini/CIRS data in the southern hemisphere of Saturn. High resolution, 0.5 cm⁻¹, CIRS data was used from three data sets taken in June-November 2004 and binned into 2° wide latitudinal strips to increase the signal-to-noise ratio. Tropospheric and stratospheric temperatures were initially retrieved to determine the temperature profile for each latitude bin. The stratospheric temperature at 2 mbar increased by 14 K from 9° to 68° S, including a steep 4 K rise between 60° and 68° S. The tropospheric temperatures showed significantly more meridional variation than the stratospheric ones, the locations of which are strongly correlated to that of the zonal jets. Stratospheric acetylene abundance decreases steadily from 30 to 68° S, by a factor of 1.8 at 2.0 mbar. Between 18° and 30° S the acetylene abundance increases at 2.0 mbar. Global values for acetylene have been calculated as (1.9±0.19)×¹⁰⁻⁷ at 2.0 mbar, (2.6±0.27)×¹⁰⁻⁷ at 1.6 mbar and (3.1±0.32)×¹⁰⁻⁷ at 1.4 mbar. Global values for ethane are also determined and found to be (1.6±0.25)×¹⁰⁻⁵ at 0.5 mbar and (1.4±0.19)×¹⁰⁻⁵ at 1.0 mbar. Ethane abundance in the stratosphere increases towards the south pole by a factor of 2.5 at 2.0 mbar. The increase in stratospheric ethane is especially pronounced polewards of 60° S at 2.0 mbar. The increase of stratospheric ethane towards the south pole supports the presence of a meridional wind system in the stratosphere of Saturn.     

Latitudinal variation of Saturn photochemistry deduced from spatially-resolved ultraviolet spectra

We obtained spatially-resolved ultraviolet spectra of Saturn in 1994 with the Faint Object Spectrometer and Goddard High Resolution Spectrograph of the Hubble Space Telescope. We observed four areas on the planet at 15° N, 33° S, 41° S, and 52° S, with a field-of-view of less than 2 × 2 arcsec², compared to the 16-arcsec planet diameter. The wavelength range, 1550-2300 Å, encompasses absorption from major hydrocarbons (C₂H₆, C₂H₄, C₂H₂, CH₃C₂H, C₄H₂) and water. We find global hydrocarbon abundances and a C₂H₂ vertical distribution compatible with infrared observations, in contrast with previous analyses of ultraviolet spectra. The stratospheric haze opacity decreases from polar region to the equator. Saturn mid-latitudes are photochemically distinct from the rest of the planet. At 33° S, the spectrum requires either (1) a distinctly different C₂H₂ vertical distribution or (2) a locally enhanced water abundance. At 41° S, the hydrocarbon abundance exhibits a local minimum, within a global trend of increasing abundance from equator to pole. This global trend may result from an increased abundance of short-lived hydrocarbons such as C₄H₂. Photochemical models predict a depletion of hydrocarbon molecules in the presence of stratospheric water [Moses et al., 2000. Icarus 143, 166-202]. These results are consistent with a localized influx of water, in the form of high charge to mass ratio particles, flowing into Saturn's atmosphere at latitudes magnetically linked to the rings.     

Solar flux in Saturn's atmosphere: Penetration and heating rates in the aerosol and cloud layers

In this work, we describe an analysis of the internal solar radiation fields in Saturn's atmosphere. The aim of this paper is to study how the solar radiation flux in optical wavelengths (0.25-1.0 μm) is attenuated, primarily by the effect of the aerosols located close to the tropopause level, retrieving also the corresponding solar heating rates. We use a doubling-adding method and previous results on the vertical cloud and haze structure of Saturn's atmosphere. Our study shows that the maximum penetration level (∼250 mbar) for these wavelengths is substantially higher than previously expected because of the huge optical thickness of the tropospheric haze described in all vertical cloud structure models. We compare our results with previous estimates and parameterizations for seasonal climate models and propose a new approach for future models, with an intense and concentrated heating rate close to the top level of the tropospheric haze. Given that our spectral range accounts for about the 70% of the total solar flux, and using previous estimates for the penetration levels of infrared radiation in Saturn's atmosphere, we conclude solar radiation effect is negligible at levels below 600 mbar. This result is fundamental for understanding the role of solar radiation in the general atmospheric circulation of Saturn.     

Uranus in 2003: Zonal winds, banded structure, and discrete features

Imaging of Uranus in 2003 with the Keck 10-m telescope reveals banded zonal structure and dozens of discrete cloud features at J and H bands; several features in the northern hemisphere are also detectable at K′. By tracking features over four days, we extend the zonal wind profile well into the northern hemisphere. We report the first measurements of wind velocities at latitudes −13°, +19°, and northward of +43°, the first direct wind measurements near the equator, and the highest wind velocity seen yet on Uranus (+218 m/s). At northern mid-latitudes (+20° to +40°), the winds appear to have accelerated when compared to earlier HST and Keck observations; southern wind speeds (−20° to −43°) have not changed since Voyager measurements in 1986. The equator of Uranus exhibits a subtle wave structure, indicated by diffuse patches roughly every 30° in longitude. The largest discrete cloud features on Uranus show complex structure extending over tens of degrees, reminiscent of activity seen around Neptune's Great Dark Spot during the Voyager encounter with that planet. There is no sign of a northern “polar collar” as is seen in the south, but a number of discrete features seen at the “expected” latitudes may signal the early stages of development of a northern collar.     

Seasonal variation of Titan's stratospheric ethylene (C2H4) observed

All previous observations of seasonal change on Titan have been of physical phenomena such as clouds and haze. We present here the first observational evidence of chemical change in Titan's atmosphere. Images taken during 1999-2002 (late southern spring on Titan) with the W.M. Keck I 10-meter telescope at 8-13 μm show a significant accumulation of ethylene (C₂H₄) in the south polar stratosphere as well as north-south stratospheric temperature variation (colder at poles). Our observations restrict this newly discovered south polar ethylene accumulation to latitudes south of 60° S. The only other observations of the spatial distribution of C₂H₄ were those of Voyager I, which found a significant north polar accumulation in early northern spring. We see no build-up in the north, although the highest northern latitudes are obstructed from view in the current season. Our observations constrain any unobserved north polar accumulation of C₂H₄ to north of 50° N latitude. Comparison of the Voyager I results with our new results show seasonal chemical change has occurred in Titan's atmosphere.     

Long slit spectropolarimetry of Jupiter and Saturn

We present ground-based limb polarization measurements of Jupiter and Saturn consisting of full disk imaging polarimetry for the wavelength 7300 Å and spatially resolved (long-slit) spectropolarimetry covering the wavelength range 5200-9350 Å.For the polar region of Jupiter we find for λ = 6000 Å a very strong radial (perpendicular to the limb) fractional polarization with a seeing corrected maximum of about +11.5% in the South and +10.0% in the North. This indicates that the polarizing haze layer is thicker at the South pole. The polar haze layers extend down to 58° in latitude. The derived polarization values are much higher than reported in previous studies because of the better spatial resolution of our data and an appropriate consideration of the atmospheric seeing. Model calculations demonstrate that the high limb polarization can be explained by strongly polarizing (p ≈ 1.0), high albedo (ω ≈ 0.98) haze particles with a scattering asymmetry parameter of g ≈ 0.6 as expected for aggregate particles of the type described by West and Smith (West, R.A., Smith, P.H. [1991]. Icarus 90, 330-333). The deduced particle parameters are distinctively different when compared to lower latitude regions.The spectropolarimetry of Jupiter shows a decrease in the polar limb polarization towards longer wavelengths and a significantly enhanced polarization in strong methane bands when compared to the adjacent continuum. This is a natural outcome for a highly polarizing haze layer above an atmosphere where multiple scatterings are suppressed in absorption bands. For lower latitudes the fractional polarization is small, negative, and it depends only little on wavelength except for the strong CH₄-band at 8870 Å.The South pole of Saturn shows a lower polarization (p ≈ 1.0-1.5%) than the poles of Jupiter. The spectropolarimetric signal for Saturn decrease rapidly with wavelength and shows no significant enhancements in the fractional polarization in the absorption bands. These properties can be explained by a vertically extended stratospheric haze region composed of small particles <100 nm as suggested previously by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2005]. Icarus 179, 195-221).In addition we find in the V- and R-band a previously not observed strong polarization feature (p = 1.5-2.0%) near the equator of Saturn. The origin of this polarization signal is unclear but it could be related to a seasonal effect.Finally we discuss the potential of ground-based limb polarization measurements for the investigation of the scattering particles in the atmospheres of Jupiter and Saturn.