A spectroscopic comparison of HED meteorites and V-type asteroids in the inner Main Belt

V-type asteroids in the inner Main Belt (a < 2.5 AU) and the HED meteorites are thought to be genetically related to one another as collisional fragments from the surface of the large basaltic Asteroid 4 Vesta. We investigate this relationship by comparing the near-infrared (0.7-2.5 μm) spectra of 39 V-type asteroids to laboratory spectra of HED meteorites. The central wavelengths and areas spanned by the 1 and 2 μm pyroxene-olivine absorption bands that are characteristic of planetary basalts are measured for both the asteroidal and meteoritic data. The band centers are shown to be well correlated, however the ratio of areas spanned by the 1 and 2 μm absorption bands are much larger for the asteroids than for the meteorites. We argue that this offset in band area ratio is consistent with our currently limited understanding of the effects of space weathering, however we cannot rule out the possibility that this offset is due to compositional differences. Several other possible causes of this offset are discussed.Amongst these inner Main Belt asteroids we do not find evidence for non-Vestoid mineralogies. Instead, these asteroids seem to represent a continuum of compositions, consistent with an origin from a single differentiated parent body. In addition, our analysis shows that V-type asteroids with low inclinations (i < 6°) tend to have band centers slightly shifted towards long wavelengths. This may imply that more than one collision on Vesta’s surface was responsible for producing the observed population of inner belt V-type asteroids. Finally, we offer several predictions that can be tested when the Dawn spacecraft enters into orbit around Vesta in the summer of 2011.     

Investigating the Vesta-vestoid-HED connection

We present spectral observations of Minor Planet 4 Vesta, of five V-type asteroids which are physically near Vesta, and of two V-type NEAs. We use these spectra to determine the presence or absence of a weak feature at 506.5 nm which is indicative of the presence of spin-forbidden Fe²⁺ in sixfold coordination. As with our earlier observations [Cochran and Vilas, Icarus 134 (1998) 207-212], we find this feature at all observed rotational phases of Vesta and again see the trend that spectra at longitudes between 240° and 360° have a smaller 506.5 nm feature equivalent width than spectra obtained at other longitudes. Additionally, we searched for this feature in V-class main-belt and NEA asteroids and positively detected the feature in main-belt Asteroid 2579 Spartacus and possibly in 3376 Armandhammer. The other objects lacked the feature. Our results are compared with previous observations of this feature by Vilas et al. [Icarus 147 (2000) 119-128]. The spatial distribution of the bodies as a function of the presence of this feature was investigated. We discuss the implication of the presence of this feature and the depth of the 0.9 μm pyroxene band for the scenario that pieces of Vesta were transported, via the 3:1 and ν₆ resonances, to the NEAs, and thence to inclusion in our meteorite collections as HED meteorites.     

V-type asteroids in the middle main belt

V-type asteroids are bodies whose surfaces are constituted of basalt. In the Main Asteroid Belt, most of these asteroids are assumed to come from the basaltic crust of Asteroid (4) Vesta. This idea is mainly supported by (i) the fact that almost all the known V-type asteroids are in the same region of the belt as (4) Vesta, i.e., the inner belt (semi-major axis 2.1<a<2.5 AU), (ii) the existence of a dynamical asteroid family associated to (4) Vesta, and (iii) the observational evidence of at least one large craterization event on Vesta's surface. One V-type asteroid that is difficult to fit in this scenario is (1459) Magnya, located in the outer asteroid belt, i.e., too far away from (4) Vesta as to have a real possibility of coming from it. The recent discovery of the first V-type asteroid in the middle belt (2.5<a<2.8 AU), (21238) 1995WV7 [Binzel, R.P., Masi, G., Foglia, S., 2006. Bull. Am. Astron. Soc. 38, 627; Hammergren, M., Gyuk, G., Puckett, A., 2006. ArXiv e-print, astro-ph/0609420], located at ∼2.54 AU, raises the question of whether it came from (4) Vesta or not. In this paper, we present spectroscopic observations indicating the existence of another V-type asteroid at ∼2.53 AU, (40521) 1999RL95, and we investigate the possibility that these two asteroids evolved from the Vesta family to their present orbits by a semi-major axis drift due to the Yarkovsky effect. The main problem with this scenario is that the asteroids need to cross the 3/1 mean motion resonance with Jupiter, which is highly unstable. Combining N-body numerical simulations of the orbital evolution, that include the Yarkovsky effect, with Monte Carlo models, we compute the probability that an asteroid of a given diameter D evolves from the Vesta family and crosses over the 3/1 resonance, reaching a stable orbit in the middle belt. Our results indicate that an asteroid like (21238) 1995WV7 has a low probability (∼1%) of having evolved through this mechanism due to its large size (D∼5 km), because the Yarkovsky effect is not sufficiently efficient for such large asteroids. However, the mechanism might explain the orbits of smaller bodies like (40521) 1999RL95 (D∼3 km) with ∼70-100% probability, provided that we assume that the Vesta family formed ?3.5 Gy ago. We estimate the debiased population of V-type asteroids that might exist in the same region as (21238) and (40521) (2.5<a?2.62 AU) and conclude that about 10 to 30% of the V-type bodies with D>1 km may come from the Vesta family by crossing over the 3/1 resonance. The remaining 70-90% must have a different origin.     

Mineralogy of HED Meteorites Using the Modified Gaussian Model

The correlation between specific meteorites and asteroids is a long-standing problem. The best-known correlation seems to be the HED–Vesta, although several problems still remain to be solved. We report the spectral reflectance analysis (0.4–2.5 μm) of a set of HED meteorites, taken from the RELAB database and three V-type asteroids, taken from MIT-UH-IRTF Joint Campaign for NEO Reconnaissance. We used the Modified Gaussian Model to fit the spectra to a series of overlapping, modified Gaussian absorptions. The fitted individual bands are validated against established laboratory calibrations. With spectral resolution extending to the near-infrared, we are able to resolve the presence of both high-calcium pyroxene (HCP) and low-calcium pyroxene (LCP) and, thus, use the HCP/(HCP + LCP) ratios to remotely trace igneous processing on the parent asteroids. A search of this mineral provides a useful probe of differentiation. The high HCP/(HCP + LCP) ratios found require extensive differentiation of these asteroids and/or their primordial parent body. The degree of melting obtained for the eucrites, using the former ratio, is comparable with that obtained for all V-type asteroids here analyzed, suggesting a comparable geologic history.     

Constraints on the surface composition of Trojan asteroids from near-infrared (0.8-4.0 μm) spectroscopy

We present new near-infrared spectra of 20 Trojan asteroids. The spectra were recorded at the NASA Infrared Telescope Facility (IRTF) using the recently commissioned medium-resolution spectrograph SpeX and at the Multiple Mirror Telescope (MMT) using the instrument FSPEC. Spectra of all of these objects were measured in K-band (1.95-2.5 μm), 8 of these in L-band (2.8-4.0 μm), and 14 in the range 0.8-2.5 μm. These observations nearly double the number of published 0.8-2.5 μm spectra of Trojan asteroids and provide the first systematic study of the L-band region for these distant asteroids. The data show that the red spectral slope measured in the near-IR extends through the L-band, though it is not as steep here as at shorter wavelengths. A significant diversity is apparent in the near-IR spectral slopes of this sampling of objects. Most of the spectra do not contain any definitive absorption features characteristic of surface composition (e.g., H₂O, organics, silicates) as seen on main-belt asteroids and several Centaur and Kuiper Belt objects. A few objects may display spectral activity, and the reliability of these possible features is discussed. While these spectra are generally compatible with silicate surfaces to explain the spectral slope mixed with some fraction of low albedo material, there is no absolute indication of silicates. The spectral slope could also be explained by the presence of hydrocarbons, but the lack of absorption features, especially in L-band where very strong fundamental absorptions from these molecules appear, constrains the character and abundance of these materials at the surface.     

The distribution of basaltic asteroids in the Main Belt

We present the observational results of a survey designed to target and detect asteroids whose photometric colors are similar to those of Vesta family members and thus may be considered as candidates for having a basaltic composition. Fifty basaltic candidates were selected with orbital elements that lie outside of the Vesta dynamical family. Optical and near-infrared spectra were used to assign a taxonomic type to 11 of the 50 candidates. Ten of these were spectroscopically confirmed as V-type asteroids, suggesting that most of the candidates are basaltic and can be used to constrain the distribution of basaltic material in the Main Belt. Using our catalog of V-type candidates and the success rate of the survey, we calculate unbiased size-frequency and semi-major axis distributions of V-type asteroids. These distributions, in addition to an estimate for the total mass of basaltic material, suggest that Vesta was the predominant contributor to the basaltic asteroid inventory of the Main Belt, however scattered planetesimals from the inner Solar System (a<2.0 AU) and other partially/fully differentiated bodies likely contributed to this inventory. In particular, we infer the presence of basaltic fragments in the vicinity of Asteroid 15 Eunomia, which may be derived from a differentiated parent body in the middle Main Belt (2.5<a<2.8). We find no asteroidal evidence for a large number of previously undiscovered basaltic asteroids, which agrees with previous theories suggesting that basaltic fragments from the ∼100 differentiated parent bodies represented in meteorite collections have been “battered to bits” [Burbine, T.H., Meibom, A., Binzel, R.P., 1996. Meteorit. Planet. Sci. 31, 607-620].     

Discovering New V-Type Asteroids in the Vicinity of 4 Vesta

We present results on the identification of two new V-type asteroids, 809 Lundia and 956 Elisa. These asteroids are located in the neighborhood of Asteroid 4 Vesta, but they do not belong to Vesta's dynamical family. Their spectra in the visible wavelength are consistent with the spectra of the Vesta family members (Vestoids) and of other V-type objects in the nearby region too. The possible existence of two spectroscopic groups of V-type asteroids in the Vesta region is discussed.     

Mineralogical characterization of Baptistina Asteroid Family: Implications for K/T impactor source

Bottke et al. [Bottke, W.F., Vokrouhlicky, D., Nesvorný, D., 2007. Nature 449, 48–53] linked the catastrophic formation of Baptistina Asteroid Family (BAF) to the K/T impact event. This linkage was based on dynamical and compositional evidence, which suggested the impactor had a composition similar to CM2 carbonaceous chondrites. However, our recent study [Reddy, V., Emery, J.P., Gaffey, M.J., Bottke, W.F., Cramer, A., Kelley, M.S., 2009. Meteorit. Planet. Sci. 44, 1917–1927] suggests that the composition of (298) Baptistina is similar to LL-type ordinary chondrites rather than CM2 carbonaceous chondrites. This rules out any possibility of it being related to the source of the K/T impactor, if the impactor was of CM-type composition. Mineralogical study of asteroids in the vicinity of BAF has revealed a plethora of compositional types suggesting a complex formation and evolution environment. A detailed compositional analysis of 16 asteroids suggests several distinct surface assemblages including ordinary chondrites (Gaffey SIV subtype), primitive achondrites (Gaffey SIII subtype), basaltic achondrites (Gaffey SVII subtype and V-type), and a carbonaceous chondrite. Based on our mineralogical analysis we conclude that (298) Baptistina is similar to ordinary chondrites (LL-type) based on olivine and pyroxene mineralogy and moderate albedo. S-type and V-type in and around the vicinity of BAF we characterized show mineralogical affinity to (8) Flora and (4) Vesta and could be part of their families. Smaller BAF asteroids with lower SNR spectra showing only a ‘single’ band are compositionally similar to (298) Baptistina and L/LL chondrites. It is unclear at this point why the silicate absorption bands in spectra of asteroids with formal family definition seem suppressed relative to background population, despite having similar mineralogy.     

New V-type asteroids in near-Earth space

We present new visible and near-infrared spectroscopic observations of 4 small, previously unclassified, near-Earth objects (NEOs). They appear to have basaltic surfaces, and hence they can be classified as V-types. Their visible spectra exhibit a closer spectral match with the Main-Belt (MB) Asteroid (4) Vesta than the other, presently known, V-type NEOs and MB asteroids. The near-infrared spectrum of Asteroid 2003 FT3 shows—for the first time among NEOs—a peculiar shape of the 1 μm band, maybe suggesting an overabundance of olivine compared to the other V-types and to (4) Vesta. The presence of V-type objects among NEOs may be a consequence of the delivery processes connecting the inner MB to the near-Earth region. On the basis of the orbital parameters of the NEOs presented here, both the resonances (3:1 and ν₆), usually considered as the most relevant gateways for the production of near-Earth asteroids, should have been active to transfer the bodies from the MB region.     

Small Main-Belt Asteroid Spectroscopic Survey in the Near-Infrared

Near-infrared spectra (∼0.90 to ∼1.65 μm) are presented for 181 main-belt asteroids, more than half having diameters less than 20 km. These spectra were measured using a specialized grism at the NASA Infrared Telescope Facility, where the near-infrared wavelength coverage is designed to complement visible wavelength CCD measurements for enhanced mineralogic interpretation. We have focused our analysis on asteroids that appear to have surfaces dominated by olivine or pyroxene since these objects can be best characterized with spectral coverage only out to 1.65 μm. Olivine-dominated A-type asteroids have distinctly redder slopes than olivine found in meteorites, possibly due to surface alteration effects such as micro-meteoroid bombardment simulated by laser irradiation laboratory experiments. K-type asteroids observed within the Eos family tend to be well matched by laboratory spectra of CO3 chondrites, while those independent of the Eos family have a variety of spectral properties. The revealed structure of the 1-μm band for 3628 Bo?němcová appears to refute its previously proposed match to ordinary chondrite meteorites. Bo?němcová displays a 1-μm band that is unlike that for any currently measured meteorite; however, spectra out to 2.5 μm are needed to conclusively argue that Bo?němcová has a surface mineralogy different from that of ordinary chondrites. Extending the spectral coverage of Vestoids out to ∼1.65 μm continues to be consistent with the “genetic” relationship of almost all observed Vestoids with Vesta and the howardites, eucrites, and diogenites. Eucrites/howardites provide the best spectral matches to the observed Vestoids.     

IRTF spectra for 17 asteroids from the C and X complexes: A discussion of continuum slopes and their relationships to C chondrites and phyllosilicates

In order to gain further insight into their surface compositions and relationships with meteorites, we have obtained spectra for 17 C and X complex asteroids using NASA’s Infrared Telescope Facility and SpeX infrared spectrometer. We augment these spectra with data in the visible region taken from the on-line databases. Only one of the 17 asteroids showed the three features usually associated with water, the UV slope, a 0.7 μm feature and a 3 μm feature, while five show no evidence for water and 11 had one or two of these features. According to DeMeo et al. (2009), whose asteroid classification scheme we use here, 88% of the variance in asteroid spectra is explained by continuum slope so that asteroids can also be characterized by the slopes of their continua. We thus plot the slope of the continuum between 1.8 and 2.5 μm against slope between 1.0 and 1.75 μm, the break at ∼1.8 μm chosen since phyllosilicates show numerous water-related features beyond this wavelength. On such plots, the C complex fields match those of phyllosilicates kaolinite and montmorillonite that have been heated to about 700 °C, while the X complex fields match the fields for phyllosilicates montmorillonite and serpentine that have been similarly heated. We thus suggest that the surface of the C complex asteroids consist of decomposition products of kaolinite or montmorillonite while for the X complex we suggest that surfaces consist of decomposition products of montmorillonite or serpentine. On the basis of overlapping in fields on the continuum plots we suggest that the CI chondrites are linked with the Cgh asteroids, individual CV and CR chondrites are linked with Xc asteroids, a CK chondrite is linked with the Ch or Cgh asteroids, a number of unusual CI/CM meteorites are linked with C asteroids, and the CM chondrites are linked with the Xk asteroids. The associations are in reasonable agreement with chondrite mineralogy and albedo data.     

Near-infrared spectroscopy of primitive asteroid families

We compare 13 near-infrared (0.8-2.4 μm) spectra of two low albedo C complex outer-belt asteroid families: Themis and Veritas. The disruption ages of these two families lie at opposite extremes: 2.5 ± 1.0 Gyr and 8.7 ± 1.7 Myr, respectively. We found striking differences between the two families, which show a range of spectral shapes and slopes. The seven Themis family members (older surfaces) have “red” (positive) slopes in the 1.6-2.4 μm region; in contrast, the six Veritas members (younger surfaces) have significantly “flatter” slopes at these same wavelengths. Moreover, the two families are characterized by different concavity at shorter (1.0-1.5 μm) wavelengths with the Themis group being consistently flat or concave up (smile) and the Veritas group being consistently concave down (frown). Each family contains a broad range of diameters, suggesting our results are not due to comparisons of asteroids of different sizes. The statistically significant clustering of the two spectral groups could be explained by one of the following three possibilities or a combination of them: (1) space weathering effects, (2) differences in original composition, or (3) differences in thermal history perhaps as a result of the difference in parent body sizes. As a result of our analyses, we propose a new method to quantify broad and shallow structures in the spectra of primitive asteroids. We found reasonable matches between the observed asteroids and individual carbonaceous chondrite meteorites. Because these meteoritic fits represent fresh surfaces, space weathering is neither necessary nor ruled out as an explanation of spectral differences between families. The six Veritas family near-infrared (NIR) spectra represent the first NIR analysis of this family, thus significantly increasing our understanding of this family over these wavelengths.     

About mineral composition of geologic units in the northern hemisphere of Vesta

In the present paper we seek to understand the geologic diversity of units in the northern hemisphere of Vesta using HST observations (Binzel et al., 1997). First, we compare colors R(0.673 μm)/R(0.953 μm) and R(0.673 μm)/R(1.042 μm) of Vesta’s units with those of V-type asteroids (vestoids) as well as howardite, eucrite, and diogenite meteorites (HEDs). This comparative analysis showed that: (i) on the color-color plot, regions on Vesta are clustered whereas vestoids and HEDs cover a wide range in color; (ii) very few vestoids or HEDs fall into Vesta’s color region. This implies that Vesta’s units are more homogenous than most vestoids and HEDs examined here and material of the units are slightly different from that of vestoids and HEDs. Assuming reasonable choice of end-member materials, an optical model (Shkuratov et al., 1999) was used to simulate intimate mixtures of particles at the surface of Vesta’s units. Simulation of albedo, colors, and four-point spectra of Vesta’s units reveals that the rock-forming material is nearly equal for all units and has HED-like composition. Diversity of the units depends on the minor constituents such as chromite and a neutral phase. The western units contain more chromite and neutral phase than the eastern, consequently albedo of the western units is lower and their four-point spectra are flatter. Olivine and feldspar are also needed to give the best fit for the calculated and observed albedos and colors of Vesta’s units, but being in minor amount in Vesta’s rocks they play a secondary role in contributing to the optical properties of the units. Questions about the proportions of HED-like rock and the constituent called neutral phase remain open. Spectrophotometric studies of Vesta with both higher spatial and spectral resolution as expected from NASA’s Dawn mission are needed for resolving these problems.     

Near-infrared spectroscopic survey of B-type asteroids: Compositional analysis

We present near-infrared spectra of 23 B-type asteroids obtained with the NICS camera-spectrograph at the 3.56 m Telescopio Nazionale Galileo. We also compile additional visible and near-infrared spectra of another 22 B-type asteroids from the literature. A total of 45 B-types are analyzed. No significant trends in orbital properties of our sample were detected when compared with all known B-types and all known asteroids. The reflectance spectra of the asteroids in the 0.8–2.5 μm range show a continuous shape variation, from a monotonic negative (blue) slope to a positive (red) slope. This continuous spectral trend is filling the gap between the two main groups of B-types published by Clark et al. ([2010]. J. Geophys. Res., 115, 6005–6027). We found no clear correlations between the spectral slope and the asteroids’ sizes or heliocentric distances. We apply a clustering technique to reduce the volume of data to six optimized “average spectra” or “centroids”, representative of the whole sample. These centroids are then compared against meteorite spectra from the RELAB database. We found carbonaceous chondrites as the best meteorite analogs for the six centroids. There is a progressive change in analogs that correlates with the spectral slope: from CM2 chondrites (water-rich, aqueously altered) for the reddest centroid, to CK4 chondrites (dry, heated/thermally altered) for the bluest one.     

Outer Main Belt asteroids: Identification and distribution of four 3-μm spectral groups

This paper examines the distribution and the abundance of hydrated minerals (any mineral that contains H₂O or OH) on outer Main Belt asteroids spanning the 2.5 < a < 4.0 AU region. The hypothesis we are testing is whether planetesimals that accreted closer to the Sun experienced a higher degree of aqueous alteration. We would expect then to see a gradual decline of the abundance of hydrated minerals among the outer Main Belt asteroids with increasing heliocentric distance (2.5 < a < 4.0 AU). We measured spectra (0.8–2.5 μm and 1.9–4.1 μm) of 28 outer Main Belt asteroids using the SpeX spectrograph/imager at the NASA Infrared Telescope Facility (IRTF). We identified four groups on the basis of the shape and the band center of the 3-μm feature. The first group, which we call “sharp”, exhibits a sharp 3-μm feature, attributed to hydrated minerals (phyllosilicates). Most asteroids in this group are located in the 2.5 < a < 3.3 AU region. The second group, which we call “Ceres-like”, consists of 10 Hygiea and 324 Bamberga. Like Asteroid Ceres, these asteroids exhibit a 3-μm feature with a band center of 3.05 ± 0.01 μm that is superimposed on a broader absorption feature from ～2.8 to 3.7 μm. The third group, which we call “Europa-like”, includes 52 Europa, 31 Euphrosyne, and 451 Patientia. Objects in this group exhibit a 3-μm feature with a band center of 3.15 ± 0.01 μm. Both the Ceres-like and Europa-like groups are concentrated in the 2.5 < a < 3.3 AU region. The fourth group, which we call “rounded”, is concentrated in the 3.4 < a < 4.0 AU region. Asteroids in this group are characterized by a rounded 3-μm feature, attributed to H₂O ice. A similar rounded 3-μm feature was also identified in 24 Themis and 65 Cybele. Unlike the sharp group, the rounded group did not experience aqueous alteration. Of the asteroids observed in this study, 140 Siwa, a P-type, is the only one that does not exhibit a 3-μm feature. These results are important to constrain the nature and the degree of aqueous alteration in outer Main Belt asteroids.     

Spectral studies of asteroids 21 lutetia and 4 vesta as objects of space missions

Asteroid 21 Lutetia is one of the objects of the Rosetta mission carried out by the European Space Agency (ESA). The Rosetta spacecraft launched in 2004 is to approach Lutetia in July 2010, and then it will be directed to the comet Churyumov-Gerasimenko. Asteroid 4 Vesta is planned to be investigated in 2011 from the Dawn spacecraft launched by the National Aeronautics and Space Administration (NASA) in 2007 (its second object is the largest asteroid, 1 Ceres). The observed characteristics of Lutetia and Vesta are different and even contradictory. In spite of the intense and versatile ground-based studies, the origin and evolution of these minor planets remain obscure or not completely clear. The types of Lutetia and Vesta (M and V, respectively) determined from their spectra correspond to the high-temperature mineralogy, which agrees with their albedo estimated from the Infrared Astronomical Satellite (IRAS) observations. However, according to the opinion of some researchers, Lutetia is of the C type, and, therefore, its mineralogy is of the lowtemperature type. In turn, hydrosilicate formations have been found in some places on the surface of Vesta. Our observations also testify that at some relative phases of rotation (RP), the reflectance spectra of Lutetia and Vesta demonstrate features confirming the presence of hydrosilicates in the surface material. However, this fact can be reconciled with the magmatic nature of Lutetia and Vesta if the hydrated material was delivered to their surfaces by falling primitive bodies. Such small bodies are probably present everywhere in the main asteroid belt and can be the relicts of silicate-icy planetesimals from Jupiter’s formation zone or the fragments of primitive-type asteroids. When interpreting the reflectance spectra of Lutetia and Vesta, we discuss the spectral classification by Tholen (1984) from the standpoint of its general importance for the estimation of the mineralogical type of the asteroids and the study of their origin and evolution.     

Spectroscopic survey of X-type asteroids

We present reflected light spectral observations from 0.4 to 2.5 μm of 24 asteroids chosen from the population of asteroids initially classified as Tholen X-type objects (Tholen, 1984). The X complex in the Tholen taxonomy comprises the E, M and P classes which have very different inferred mineralogies but which are spectrally similar to each other, with featureless spectra in visible wavelengths.The data were obtained during several observing runs in the 2004-2007 years at the NTT, TNG and IRTF telescopes. Sixteen asteroids were observed in the visible and near-infrared wavelength range, seven objects in the visible wavelength range only, and one object in the near-infrared wavelength range only. We find a large variety of near-infrared spectral behaviors within the X class, and we identify weak absorption bands in spectra of 11 asteroids. Our spectra, together with albedos published by Tedesco et al. (2002), can be used to suggest new Tholen classifications for these objects. We describe 1 A-type (1122), 1 D-type (1328), 1 E-type (possibly, 3447 Burckhalter), 10 M-types (77, 92, 184, 337, 417, 741, 758, 1124, 1146 and 1355), 5 P-types (275, 463, 522, 909, 1902), and 6 C-types (50, 220, 223, 283, 517, and 536). In order to constrain the possible composition of these asteroids, we perform a least-squares search through the RELAB spectral database. Many of the best fits are consistent with meteorite analogue materials suggested in the published literature. In fact, we find that seven of the new M-types can be fit with metallic iron (or pallasite) materials, and that the low albedo C/P-type asteroids are best fitted with CM meteorites, some of which have been subjected to heating episodes or laser irradiation. Our method of searching for meteorite analogues emphasizes the spectral characteristics of brightness and shape, and de-emphasizes minor absorption bands. Indeed, faint absorption features like the 0.9 μm band seen on four newly classified M-type asteroids are not reproduced by the iron meteorites. In these cases, we have searched for geographical mixture models that can fit the asteroid spectrum, minor bands, and albedo. We find that a few percent (less than 3%) of orthopyroxene added to iron or pallasite meteorite, results in good spectral matches, reproducing the weak spectral feature around 0.9 μm seen on 92 Undina, 417 Suevia, and 1124 Stroobantia. For 337 Devosa, a mixture model that better reproduces its spectral behavior and the 0.9 μm feature is made with Esquel pallasite enriched with goethite (2%).Finally, we consider the sample of the X-type asteroids we have when we combine the present observations with previously published observations for a total of 72 bodies. This sample includes M and E-type asteroid data presented in [Fornasier et al., 2008] and [Fornasier et al., 2010]. We find that the mean visible spectral slopes for the different E, M and P Tholen classes are very similar, as expected. An analysis of the X-type asteroid distribution in the main belt is also reported, following both the Tholen and the Bus-DeMeo taxonomies (DeMeo et al., 2009).     

Selecting candidate V-type asteroids from the analysis of the Sloan Digital Sky Survey colors

We present a systematic method to identify possible basaltic (V-type) asteroids using the Moving Objects Catalog (MOC) of the SDSS. The method is based on the Principal Components Analysis of the MOC colors combined with some refined criteria of segregation of the taxonomic classes. We found several V-type candidates outside the Vesta family, most of them in the inner asteroid belt. We also identified a few candidates in the middle/outer belt. Notwithstanding, their basaltic nature still needs to be conformed by spectroscopy, and these candidates are potential targets for observation using large telescopes.     

Rotationally-resolved spectroscopy of Vesta I: 2-4 μm region

We present new infrared (2-4 μm) spectroscopic observations of Vesta obtained in 2001, 2003, and 2004. Together with previously published work, these present a picture of how Vesta's spectrum changes with sub-Earth latitude and longitude. Vesta's albedo and 2-μm band vary regularly with its rotational phase. While establishing the continuum level for Vesta in the 3-μm region is not straightforward, Vesta appears to have a spectrum consistent with the HED meteorites and not requiring a 3-μm water of hydration band. We cannot formally rule out a shallow (∼1%) band, however. We place limits on the extent to which solar-wind implantation and contamination by CM-like impactors has changed the surface spectrum of Vesta.     

Spectroscopic survey of M-type asteroids

M-type asteroids, as defined in the Tholen taxonomy (Tholen, D.J. [1984]. Asteroid Taxonomy from Cluster Analysis of Photometry. Ph.D. Dissertation, University of Arizona, Tucson), are medium albedo bodies supposed to have a metallic composition and to be the progenitors both of differentiated iron–nickel meteorites and enstatite chondrites. We carried out a spectroscopic survey in the visible and near infrared wavelength range (0.4–2.5 μm) of 30 asteroids chosen from the population of asteroids initially classified as Tholen M-types, aiming to investigate their surface composition. The data were obtained during several observing runs during the years 2004–2007 at the TNG, NTT, and IRTF telescopes. We computed the spectral slopes in several wavelength ranges for each observed asteroid, and we searched for diagnostic spectral features. We confirm a large variety of spectral behaviors for these objects as their spectra are extended into the near infrared, including the identification of weak absorption bands, mainly of the 0.9 μm band tentatively attributed to orthopyroxene, and of the 0.43 μm band that may be associated to chlorites and Mg-rich serpentines or pyroxene minerals such us pigeonite or augite. A comparison with previously published data indicates that the surfaces of several asteroids belonging to the M-class may vary significantly.We attempt to constrain the asteroid surface compositions of our sample by looking for meteorite spectral analogs in the RELAB database and by modeling with geographical mixtures of selected meteorites/minerals. We confirm that iron meteorites, pallasites, and enstatite chondrites are the best matches to most objects in our sample, as suggested for M-type asteroids. For 22 Kalliope, we demonstrate that a synthetic mixture obtained enriching a pallasite meteorite with small amounts (1–2%) of silicates well reproduce the spectral behavior including the observed 0.9 μm feature.The presence of subtle absorption features on several asteroids confirms that not all objects defined by the Tholen M-class have a pure metallic composition.A statistical analysis of spectral slope distribution vs. orbital parameters shows that our sample originally defined as Tholen M-types tend to be dark in albedo and red in slope for increasing value of the semi-major axis. However, we note that our sample is statistically limited by our number of objects (30) and slightly varying results are found for different subsets. If confirmed, the albedo and slope trends could be due to a difference in composition of objects belonging to the outer main belt, or alternatively to a combination of surface composition, grain size and space weathering effects.