BIOREGIS Software Platform Based on GIS Technology to Support in‐Situ Remediation of Petroleum Contaminated Sites. Case Study: Razvad – Dambovita County,Romania

With a need for the management of petroleum contaminated sites on Romanian territory, an experimental software platform involving ESRI‐ArcGIS technologies (BIOREGIS) is presented in this study. The BIOREGIS platform is aimed to: (i) Build the structure of relational, standardized databases to store spatial and textual characteristic information on polluted sites for further risk analysis and planning of remediation actions, (ii) improve the pollution risk assessment methodology for Romanian petroleum contaminated sites and its informatics implementation, and (iii) develop and operate the software platform for pollution risk based management involving GIS/remote sensing technologies and remediation activities. The operation of BIOREGIS has been tested for a pilot contaminated area situated at Razvad – Dambovita County, which has been subjected to in situ remediation procedures involving both bioremediation and electrokinetic processes.     

Hydrogenolysis of Glycerol to 1,2‐Propanediol over Ru–Cu Bimetals Supported on Different Supports

Glycerol is a low‐cost and renewable resource, and its utilization is of great interest for chemical industry and sustainable development. In this work, a series of Ru–Cu bimetallic catalysts were prepared using different supports in an attempt to develop highly efficient catalysts. Hydrogenolysis of aqueous solution of glycerol was performed with the supported Ru–Cu catalysts. The bimetallic catalysts were very efficient for catalyzing the hydrogenolysis of glycerol compared with the corresponding monometallic catalysts. One hundred percent of glycerol conversion and 78.5% of 1,2‐propanediol yield could be achieved at 180°C and 8 MPa.     

Response of deep groundwater to land use change in desert basins of the Trans‐Pecos region,Texas, USA: Effects on infiltration,recharge, and nitrogen fluxes

Quantifying the effects of anthropogenic processes on groundwater in arid regions can be complicated by thick unsaturated zones with long transit times. Human activities can alter water and nutrient fluxes, but their impact on groundwater is not always clear. This study of basins in the Trans‐Pecos region of Texas links anthropogenic land use and vegetation change with alterations to unsaturated zone fluxes and regional increases in basin groundwater NO₃^? concentrations. Median increases in groundwater NO₃^? (by 0.7–0.9 mg‐N/l over periods ranging from 10 to 50+ years) occurred despite low precipitation (220–360 mm/year), high potential evapotranspiration (~1570 mm/year), and thick unsaturated zones (10–150+ m). Recent model simulations indicate net infiltration and groundwater recharge can occur beneath Trans‐Pecos basin floors, and may have increased due to irrigation and vegetation change. These processes were investigated further with chemical and isotopic data from groundwater and unsaturated zone cores. Some unsaturated zone solute profiles indicate flushing of natural salt accumulations has occurred. Results are consistent with human‐influenced flushing of naturally accumulated unsaturated zone nitrogen as an important source of NO₃^? to the groundwater. Regional mass balance calculations indicate the mass of natural unsaturated zone NO₃^? (122–910 kg‐N/ha) was sufficient to cause the observed groundwater NO₃^? increases, especially if augmented locally with the addition of fertilizer N. Groundwater NO₃^? trends can be explained by small volumes of high NO₃^? modern recharge mixed with larger volumes of older groundwater in wells. This study illustrates the importance of combining long‐term monitoring and targeted process studies to improve understanding of human impacts on recharge and nutrient cycling in arid regions, which are vulnerable to the effects of climate change and increasing human reliance on dryland ecosystems.     

Effects of bathymetry on tsunami propagation: Application of ray tracing to tsunamis

Ray tracing of seismic surface waves is applied to tsunami propagation to examine bathymetric effect along its propagation path. Computations are made for trans-Pacific tsunamis and for near-field tsunamis in the Japan Sea. For tsunamis across the Pacific Ocean, the comparison to a uniform ocean shows that focusing and defocusing, due to bathymetry, are significant for some combinations of source and receiver. For example, the refraction of rays is predominant at the East Pacific Rise for the tsunami from Chile. The tsunamis in the Japan Sea are strongly affected by the shallow Yamato Rise. The predicted arrival time and amplitude distribution generally agree with the observations from an actual tsunami. Since the computation can be made very quickly, the method is useful for preliminary analysis of tsunami propagation, such as in an operational warning system or in the determination of computational area for finite-difference computation.     

Application of the qda–md method of environmental discrimination to particle size analyses of fine sediments by pipette and sedigraph methods: A comparative study

The results of particle size analyses by the low-technology pipette method and by the modern SediGraph, of a suite of fine lacustrine bottom sediment samples, are compared. Good correlations between the two data sets are observed, although the SediGraph consistently indicates finer grain sizes and better sorting of distributions. The QDa-Md method of environmental discrimination, originally established on the basis of traditional methods of size analysis, is found to be sufficiently versatile to accommodate the SediGraph data into the appropriate trend envelopes, despite the considerable differences in derived grain size parameters.     

River adjustment to changes in sediment load: The effects of tin mining on the Ringarooma River,Tasmania, 1875–1984

The mining of alluvial tin in the Ringarooma basin began in 1875, reached a peak in 1900–20, and had virtually ceased by 1982. During that time 40 million m³ of mining waste were supplied to the main river, quickly replacing the natural bed material and requiring major adjustments to the channel. Based on estimates of sediment supply from more than 50 widely scattered mines and the frequency of flows capable of transporting the introduced load, the river's transport history is reconstructed using a mass-conservation model. Because of the lengthy time period (110 years) and river distance (75 km) involved, the model cannot predict detailed change but it does reproduce the main pattern of sediment movement in which successive phases of aggradation and degradation progress downstream. Peak storage is predicted in that part of the river where braiding and anastomosis are best developed. Aggradation was most rapid in the upper reaches close to major supply points, becoming slower and later with distance downstream. Channel width increased by up to 300 per cent where the valley floor was broad and braiding became relatively common. Bridges had frequently to be replaced. While bed levels were still rising in lower reaches, degradation began in upper ones, notably after 1950, and by 1984 had progressed downriver over 30 km. Rates of incision reached 0·5 m yr^?1, especially in the early 1970s when record high flows occurred. As a result of degradation the bed material became gravelly through either reexposure of the original bed or lag concentration of coarser fractions. Also a narrower unbraided channel has developed. The river is beginning to heal itself and upper reaches now have reasonably stable beds but at least another 50 years will be required for the river to cleanse its channel of mining debris.     

Towards a long-term monitoring of Central European water mite faunas (Acari: Hydrachnidia and Halacaridae) – considerations on the background of data from 1900 to 2000

The state of knowledge of the Central European water mite fauna and the research history are briefly surveyed. Several areas for which we are provided with rich data sets are of high value for the monitoring of faunistic trends on the background of local and global environmental change. The need for a database combining historical and actual faunistic information is stressed. It should facilitate the access to all data from former times, give a survey on actual activities by regular updates, and help for a better organization of future research activities. On the base of an update of the Limnofauna Europaea (K.O. Viets 1978, Gerecke in www.watermite.org) a first attempt is made to (1) recognize changes in the Central European fauna during the past 100 years; (2) emphasize species which may be endangered or have disappeared during the past 100 years. At the present state of knowledge, the degree of threat to water mite species in this area is best calculated from their preference for particular habitat types which are rare and in danger to disappear in cultivated landscapes. Our knowledge concerning neozoic water mites in the study area is discussed.     

Experimental study on reduction of U (VI) by an anaerobic bacterium, <Emphasis Type="Italic">Shewanella putrefaciens</Emphasis>: Application to sandstone-hosted interlayer oxidation-zone type uranium deposits,China

An experimental study on reduction of U (VI) by anaerobic bacteria, Shewanella putrefaciens, is first reported here in China. The experimental conditions were: 35°C and pH= 7.0-7.4, corresponding to a physicochemical environments in which the sandstone-hosted interlayer oxidation-zone type uranium deposit formed in Northwest China’s Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural environment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2-4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water environments and for underground dissolving extraction of the sandstone-hosted uranium ores.