江西周潭群斜长角闪岩的地球化学特征及其成因

周潭群斜长角闪岩的基本组成矿物是斜长石和角闪石，不同样品中还可以出现黑云母、石英和碱性长石等。所有斜长角闪岩显示石英拉斑系列特征，其稀土元素配分曲线呈平坦型，显示轻微的轻稀土亏损和Eu亏损，与由岛弧及洋拉斑玄武岩形成的斜长角闪岩的稀土分布型式及稀土特征一致。根据微量元素蛛网图的斜率和Nb、Zr异常情况以及低的Zr/Nb比值、V-Ti、Y－Cr、Zr-Ti-Sr、Zr-Y相关性，认为斜长角闪岩之原岩为岛弧型玄武岩，周潭群的原岩形成于岛弧环境。元素地球化学和Nd同位素特征指示它们的母岩浆起源于亏损程度低的地幔或来源于亏损地幔的岩浆受到地壳物质的混染。     

南辽河群斜长角闪岩的地球化学特征及地质意义:以三家子地区为例

基于详细的野外地质调查,对南辽河群下部里尔峪组斜长角闪岩进行了岩相学和地球化学研究。岩相学研究表明,南辽河群下部里尔峪组斜长角闪岩属于正变质岩。地球化学研究显示,这些斜长角闪岩原岩属于高铁拉斑玄武岩系列(Nb/Y=0.16~0.4),SiO_2含量为47.27%~50.68%,具有较低的TiO_2含量(0.92%~1.61%),亏损高场强元素(Nb、Ta、Zr、Hf等),表明其原岩形成于岛弧或活动大陆边缘,而非前人所说的大陆裂谷。综合岩相学和地球化学特征,初步认为其岩石成因与活动大陆边缘有关。     

闽西北建瓯马面山俯冲增生杂岩带内斜长角闪岩的地球化学、年代学特征及其地质意义

闽西北建瓯马面山俯冲增生杂岩由岩块和基质组成,其中变基性岩岩块有2类不同构造产状的斜长角闪岩:第一类与透辉石岩或大理岩呈似互层状产出;第二类单独呈构造岩块、团块状产于基质中,原岩均为玄武岩类,为幔源岩浆部分熔融的产物。通过元素地球化学特征分析,前者斜长角闪岩原岩为形成于类似洋岛-海山环境的碱性玄武岩;后者斜长角闪岩的原岩分别为岛弧钙碱性玄武岩和洋壳内部初始俯冲背景下前弧环境的MORB-like(类洋中脊)型岛弧拉斑玄武岩。通过锆石测年,前者斜长角闪岩的2组变质年龄为(399±3.5) Ma(MSWD=0.45)、(388±1.8) Ma(MSWD=1.19);后者斜长角闪岩的原岩结晶年龄为(441.8±4.7)Ma(MSWD=0.32),变质年龄为(411±19)Ma(MSWD=0.095)。通过对马面山俯冲增生杂岩带内发育的在空间上共生的斜长角闪岩类研究,其原岩形成于洋岛、前弧和岛弧等环境,结合锆石年龄和前人研究成果,认为华夏地块内部闽西北、浙西南一带发育早古生代末-晚古生代初的洋壳俯冲-弧陆碰撞(增生)造山作用。     

河南箕山登封岩群变质中基性火山岩的地球化学及年代学研究

对登封岩群 TTG杂岩区内的斜长角闪质表壳岩包体以及绿岩区的变质中基性火山岩对比研究表明 ,其主元素、微量元素、稀土元素和同位素地球化学特征等指示该区的变质中基性火山岩同时同源 ,具有由拉斑玄武岩向钙碱性玄武岩演变的趋势.登封岩群上下部 2件 Sm Nd等时线年龄极为一致 ,可以合并为一条等时线 ,年龄为 (2 512± 19) Ma,ε Nd(t)=2.40± 0.16.综合分析认为 ,箕山地区的登封岩群稍晚于嵩山地区 ,是在新太古代末期一个非常短暂的时间内形成的 ,形成于类似现代岛弧的构造环境.     

周口店官地杂岩中斜长角闪岩的年代学、地球化学及其地质意义

周口店房山岩体南北两侧的官地杂岩主要由长英质片麻岩、斜长角闪岩和混合岩组成。笔者首次对东岭子官地杂岩中斜长角闪岩进行研究,斜长角闪岩LA-ICP-MS锆石U-Pb测年上交点年龄为(2 551±37)Ma,代表岩浆结晶年龄。其地球化学显示具有低TiO_2,高MgO的特点,Mg~#平均值为70,LREE与HREE分异度高,具有Eu的负异常。地球化学特征和岩相学揭示其岩浆经历分离结晶作用,原岩矿物主要由辉石、斜长石组成。锆石Hf同位素ε_(Hf)(t)处于亏损地幔演化线和球粒陨石之间示踪源区为岩石圈富集地幔,微量元素方面富集LILE(Rb,Ba,K),亏损HFSE(Nb,Ta,Zr)的特点显示岛弧有关的富集地幔源区。初步认为大洋板片向东俯冲于增生岛弧和东部陆块之下,镁铁质成岩物质来源于大洋板片重熔流体交代的岩石圈地幔楔,同时,对于华北地块新太古宙末期大陆地壳生长的时间提供约束。     

阿尔金环形山榴辉岩岩石地球化学及地质意义

调查研究发现,阿尔金南缘环形山榴辉岩呈透镜体状产于新元古代石榴石二长花岗片麻岩中,岩石经退变质作用,白眼圈构造发育,石榴石变少,石英及金红石等矿物较少,未见峰期矿物组合。绿辉石被次透辉石及角闪石替代,岩石为榴辉岩、榴闪岩及斜长角闪岩。主量及微量元素地球化学分析显示:主量元素Al2O3、TiO2、MgO、P2O5及稀土Nb/Ta、Zr/Hf、Zr/Nb、La/Nb、Y/Nb特征比值与洋脊玄武岩一致;稀土标准化模式图、微量元素原始地幔标准化图及MORB标准化图指示岩石具洋脊玄武岩特征,原岩可能为地幔岩经15%~30%的部分熔融形成。结合榴辉岩围岩年龄、变质作用等分析认为,该榴辉岩为似洋脊玄武岩的基性岩浆侵入花岗岩后,于500 Ma左右发生大陆俯冲折返形成。     

青藏高原东南缘“三江”地区含角闪石变质岩石的地球化学特征

青藏高原东南缘"三江"地区变质杂岩带中的岩石类型十分复杂,斜长角闪岩和含角闪石斜长片麻岩是本区常见的变质岩石类型。斜长角闪岩可进一步划分为由石榴辉石岩退变而成的和基性原岩经角闪岩相-麻粒岩相变质形成的两种类型。斜长角闪岩的SiO2平均含量50.0%,具有高铝低钛的特点,轻稀土元素相对富集,铕无异常或略具负异常,Zr含量较低,Zr/Y比值较小,其原岩的主微量元素组成具有岛弧玄武岩的特点,反映其原岩形成于俯冲碰撞的构造环境。含角闪石斜长片麻岩的SiO2平均含量63.64%,MgO和TiO2含量低,轻、重稀土元素分馏,轻稀土元素明显富集而重稀土元素相对亏损,具有中等负Eu异常,大离子亲石元素K、Rb、Ba、Th强烈富集,高场强元素Ti、Zr、Hf、Nb和Ta含量较低,其原岩具有安山质岩石或安山质/玄武质岩石的特点,主要形成于板块聚敛边缘的构造环境。     

变质玄武岩体系相平衡及矿物 熔体微量元素分配：限定TTG/埃达克岩形成条件和大陆壳生长模型

埃达克质岩石是高Na、Al和Sr、低Y和HREE以及Nb、Ta亏损的钠质花岗质岩石,奥长花岗岩-英云闪长岩-花岗闪长岩(TTG)是早期(太古宙)大陆壳主要组分,成分与埃达克质岩石相似,这些成分独特的岩石总体上认为是俯冲洋壳、下地壳和拆沉的下地壳中变质玄武岩部分熔融的产物。文中综述我们近年来在变质玄武岩体系相平衡和矿物-熔体微量元素分配实验研究成果:相平衡实验和熔体微量元素特征研究表明,变质玄武岩部分熔融过程中金红石是导致TTG/埃达克岩浆Nb、Ta亏损的必要残留矿物,从而否定了前人“TTG由无金红石的角闪岩熔融产生”的观点;证实金红石仅仅在压力1.5GPa以上才能稳定存在,从而限定TTG/埃达克岩熔体必定产生在大约50km以上,表明TTG/埃达克岩是在相对较深的含金红石榴辉岩相条件下熔融产生的。矿物(石榴子石、角闪石,单斜辉石和金红石)-熔体微量元素分配系数测定和部分熔融模拟结果进一步限定俯冲洋壳和下地壳起源的TTG/埃达克岩浆由含金红石角闪榴辉岩熔融产生,而拆沉下地壳起源的埃达克岩浆的产生要求软流圈地幔高温,由无水或含有少量含水矿物的榴辉岩熔融产生。     

金塔南山岩带形成环境的地质地球化学证据

地质地球化学证据表明金塔南山岩带是通过转换挤压作用把性质各异、形成于不同构造环境的岩石会聚而成的变质地质体 ,其中主要组分斜长角闪岩的Sm -Nd等时年龄为 74 5±59Ma ,原岩为玄武岩 ,分属钙碱性系列和拉斑系列。稀土元素配分型式为平坦型 (拉斑系列 )到富集型 (钙碱性系列 ) ;相对N—MORB ,低Ti,富集LILE ,相对亏损HFSE ,Nb、Ta、Ti表现为明显的负异常 (钙碱性系列 )到无异常 (拉斑系列 ) ;INd(t) =0 51193,14 3 Nd/14 4 Nd =0 512 878,εNd(t)=+4 9± 0 2 ,推测斜长角闪岩应为不同程度部分熔融的岛弧岩浆作用的产物。提示本岩带是在新元古代中期华北克拉通与塔里木克拉通之间的古大洋俯冲消减的结果。     

敦煌地块敖包山晶质石墨矿集区矿床地质特征、变质岩原岩恢复及形成环境

【研究目的】为解决敦煌地块敖包山晶质石墨矿集区晶质石墨矿床研究程度较低的问题,通过对该区变质岩原岩特征及古构造环境进行深入研究,以期为该区的成矿规律研究提供地质依据。【研究方法】本文运用岩石地球化学方法对该区变质岩进行原岩恢复,探讨其形成时的古构造环境。【研究结果】二云石英片岩、黑云斜长片麻岩和斜长角闪岩均具有轻稀土富集的特征。斜长角闪岩K₂O2O,具有弱的Nb、Ta亏损和强烈的Zr、Hf亏损,LREE/HREE=2.21～6.97,轻重稀土元素分馏程度较弱;黑云斜长片麻岩和二云石英片岩K₂O>Na₂O,富集大离子亲石元素Rb、K等,亏损Ba、Nb、Ta、Zr、Hf、Ti、Sr等元素,具有明显的Eu负异常,LREE/HREE平均值分别为12.44和8.89,轻重稀土元素分异较强烈。【结论】敖包山晶质石墨矿集区变质岩原岩形成于浅水区,水动力环境较弱。斜长角闪岩的原岩为亚碱性基性火山岩,形成于岛弧环境;二云石英片岩和黑云斜长片麻岩的原岩为页岩、黏土岩,构造环境为活动大陆边缘,古沉积环境...     

长白山新生代火山岩之下新太古代基底年代学及地球化学特征

对长白山第四系玄武岩覆盖区零星出露的花岗质岩石和片麻岩进行LA-ICPMS锆石U-Pb年龄测定及地球化学分析,结果显示花岗质岩石的年龄为2 509~2 558 Ma;斜长角闪片麻岩的年龄为2 475~2 553 Ma。地球化学特征上,这些岩石均属奥长花岗岩-英云闪长岩-石英闪长岩系列(TTG),稀土元素配分模式图呈右倾型,轻重稀土元素分馏明显(LREE/HREE=3.85~34.48),白云母二长花岗岩具有铕的负异常(δEu=0.41~0.54),富集Rb、K、Th等元素,亏损Nb、Sr、P、Ti等元素;黑云斜长角闪石片麻岩具有铕负异常(δEu=0.67~0.76),富集Rb、K、La、Nd等元素,亏损Th、Nb、Sr、P、Yb等元素;花岗质片麻岩和黑云斜长片麻岩具有铕的弱负-正异常(δEu=0.87~3.3),富集Rb、K、Sr等元素,亏损Nb、Th、P等元素。年代学和地球化学特征与白山地块和和龙地块中的同类岩石基本一致,表明白山地块与和龙地块在晚太古代是同一个陆块(龙岗陆块),二者目前的分布格局是后期北东向左行断裂构造改造的结果。     

河南嵩山地区新太古代TTG质片麻岩的成因及其地质意义：来自岩石学、地球化学及同位素年代学的制约

河南嵩山地区位于华北克拉通南缘,是我国记录前寒武纪地质的典型地区之一。该区广泛出露新太古代TTG质片麻岩套,主要以英云闪长岩类为主,闪长岩类次之,测得的锆石SHRIMP年龄在2600~2500Ma。该套TTG质片麻岩富Na₂O(3%~7%)、SiO₂(>67%)、贫铁、镁,高的Na₂O/K₂O比值（多在1.5~5.2）,Al₂O₃=13.72%~16.37%,A/CNK=0.97~1.21,属英云闪长岩-奥长花岗岩系列,显示新太古代富铝型TTG岩石特征。岩石富Sr (平均433×10^-6),Rb/Sr比值(<0.5) 较低,Sr/Y比值高(平均165),Nb、Ta和Ti负异常,∑REE偏低,强烈分异((La/Yb) _N=27~150),基本无Eu异常,低的Nb/Ta(14左右)、La/Nb (平均约为7)比值及其它微量元素特征表明其与岛弧或大陆边缘弧玄武质岩石特征相似。全岩Nd同位素和锆石Hf同位素数据显示岩石源区是来自亏损地幔的约2.66Ga的初生地壳;Mg^#值变化较大反映存在地幔楔不同程度的混染。地球化学特征指示该岩浆是在较高温度和压力(约700~1000℃,>1.5Gpa)下由俯冲的含水玄武质洋壳部分熔融形成,残留相中有石榴石和角闪石而不含斜长石。嵩山地区TTG片麻岩的这种成因机制表明当时陆壳以水平方式增生,也说明在随后的2.5Ga左右微陆块碰撞拼合事件之前不同陆块之间很可能被一个古大洋所分隔。     

Mineralkogical and Petrochemical Characterisitics and Genesis of Laoniugou Geneiss in Jiapigou Gold Mine,Jilin Province

Detailed mineralogical and petrochemical studies show that the Laoniugou gneiss of the Jiapigou gold mine is composed mainly of plagioclase gneiss and irregular to lentiform plagioclase amphibolite melanic enclaves.The major element contents show an obvious bimodal and trondhjemitic series evolutional trend.This situation is significantly different from that encountered in bimodal calc-alkalic volcanic rocks in the rift-type Archaean greenstone belt.The contents of Rb,Sr and Ba are 7-21 ppm,153-363ppm and 201-1451 ppm respectively ,close to those of common Archaean grey gneisses.All the samples of plagioclase gneisses show positive Eu anomalies (even up to 4.6).The protoliths of the plagioclase gneiss are high-Al2O3 trondhjemitic series rocks,belonging to typical TTG of Archaean high-grade metamorphic terrain .The gneiss is quite similar to the B-type Amitsoq gneiss of W.Greenland .The authors believe that the plagioclase amphibolite enclaves are the relics of ancient oceanic crust while the plagioclase gneiss is the TTG ancient intrusive rock resulting from partial melting of the oceanic crust.     

Contrasting geochemical and Sm-Nd isotopic compositions of Archean metasediments from the Kongling high-grade terrain of the Yangtze craton: evidence for cratonic evolution and redistribution of REE during crustal anatexis

Twenty-three clastic metasediments from the Kongling high-grade terrain of the Yangtze craton, South China were analyzed for major, trace and rare earth elements and Sm-Nd isotopic ratios. Associated dioritic-tonalitic-trondhjemitic (DTT) and granitic gneisses as well as amphibolites were also analyzed in order to constrain provenance. The results show that the clastic metasediments can be classified into 3 distinct groups in terms of mineralogical, geochemical and Sm-Nd isotopic compositions. Group A is characterized by having no to slight negative Eu anomalies (Eu/Eu1 = 0.82–1.07), being high in Cr (191–396 ppm) and Ni (68–137 ppm), and low in Th (3.3–7.8 ppm) and REE (ΣREE = 99–156 ppm). These characteristics are similar to those of metasediments from Archean greenstone belts. In addition, the Group A metasediments have the value of the Chemical Index of Alteration (CIW) close to felsic gneisses. Their Sm-Nd isotopic, REE and trace element compositions can be interpreted by mixtures of the DTT gneisses and amphibolites. Dating of detrital zircons from 2 Group A samples by SHRIMP reveals a major concordant age group of 2.87–3.0 Ga, which is identical to the age of the trondhjemitic gneiss. These results strongly suggest that Group A was principally the first-cycle erosion product of the local Kongling DTT gneiss and amphibolite. Moreover, the higher than amphibolite Cr content and slight Eu depletion exhibited by some samples from this group infer that ultramafic rocks like komatiite and granite of probably 3.0–3.3 Ga in age also played a role.Group B is characterized by the presence of graphite and shows a more evolved composition similar to post-Archean shales with a prominent negative Eu anomaly (Eu/Eu1 = 0.48–0.77) and high CIW. On paired Cr/Th vs La/Co and Co/Th plots, Group B samples conform to a two-end member mixing line of the Kongling granitic gneiss and amphibolite. However, data on Nd model age and CIW suggest that the granite component should be younger than the sampled granitic gneiss and derived from a distal source.Both Groups A and B exhibit a clear positive correlation between CIW and T_DM and a negative one between CIW and Eu/Eu1. These correlations point to the crustal evolution of the Yangtze craton towards coupled increasing CIW and Eu depletion with decreasing age. This in turn reflects the change of granitoid magmatism from local Na-rich dioritic-tonalitic-trondhjemitic rocks to widespread K-feldspar granite. The change led to the intracrustal differentiation, stabilization and growth of the craton.Group C is restite and contains abundant sillimanite and garnet and unusually high ilmenite (7–11vol%), which can be seen to be dehydration melting products of biotite under the microscope. This group shows extremely varied REE distributions from LREE enriched to depleted and from negative to strong positive (Eu/Eu1 = 1.63) Eu anomalies. Compared to Groups A and B, Group C is severely depleted in Na₂O, K₂O, LREE, Rb and Ba, whereas TiO₂, Co, V, Sc and HREE and Y are considerably enriched. This is accompanied by anomalous high Sm/Nd (0.21–0.28), ¹⁴⁷Sm/¹⁴⁴Nd (0.1361–0.1738) and ¹⁴³Nd/¹⁴⁴Nd (0.511589–0.511958) ratios. T_DM correlates clearly with Sm/Nd ratio and 2 out of 3 samples give significantly older to unrealistic T_DM (3.9–4.9 Ga). The results document redistribution of REE and an open behavior of the Sm-Nd isotope system during the biotite dehydration melting of metasediments.     

Major and trace element geochemistry of plutonic rocks from Francistown, NE Botswana: evidence for a Neoarchaean continental active margin in the Zimbabwe craton

The Neoarchaean Tati granite–greenstone terrane occurs within the southwestern part of the Zimbabwe craton in NE Botswana. It comprises 10 intrusive bodies forming part of three distinct plutonic suites: (1) an earlier TTG suite dominated by tonalites, trondhjemites, Na-granites distributed into high-Al (Group 1) and low-Al (Group 2) TTG sub-suite rocks; (2) a Sanukitoid suite including gabbros and Mg-diorites; and (3) a younger high-K granite suite displaying I-type, calc-alkaline affinities.

The Group 1 TTG sub-suite rocks are marked by high Sr/Y values and strongly fractionated chondrite-normalized rare earth element (REE) patterns, with no Eu anomaly. The Group 2 TTG sub-suite displays higher LREE contents, negative Eu anomaly and small to no fractionation of HREE. The primordial mantle-normalized patterns of the Francistown TTGs are marked by negative Nb–Ti anomalies. The geochemical characteristics of the TTG rocks are consistent with features of silicate melts from partial melting of flat subducting slabs for the Group 1 sub-suite and partial melting of arc mafic magmas underplated in the lower crust for the Group 2 sub-suite. The gabbros and high-Mg diorites of the Sanukitoid suite are marked by Mg#>0.5, high Al₂O₃ (>>16%), low TiO₂ (<0.6%) and variable enrichment of HFSE and LILE. Their chondrite-normalized REE patterns are flat in gabbros and mildly to substantially fractionated in high-Mg diorites, with minor negative or positive Eu anomalies. The primordial mantle-normalized diagrams display negative Nb–Ti (and Zr in gabbros) anomalies. Variable but high Sr/Y, Sr/Ce, La/Nb, Th/Ta and Cs/La and low Ce/Pb ratios mark the Sanukitoid suite rocks. These geochemical features are consistent with melting of a sub-arc heterogeneously metasomatised mantle wedge source predominantly enriched by earlier TTG melts and fluids from dehydration of a subducting slab. Melting of the mantle wedge is consistent with a steeper subduction system. The late to post-kinematic high-K granite suite includes I-type calc-alkaline rocks generated through crustal partial melting of earlier TTG material. The Neoarchaean tectonic evolution of the Zimbabwe craton is shown to mark a broad continental magmatic arc (and related accretionary thrusts and sedimentary basins) linked to a subduction zone, which operated within the Limpopo–Shashe belt at 2.8–2.65 Ga. The detachment of the subducting slab led to the uprise of a hotter mantle section as the source of heat inducing crustal partial melting of juvenile TTG material to produce the high-K granite suite.     

藏南也拉香波早渐新世富钠过铝质淡色花岗岩的成因机制及其构造动力学意义

藏南也拉香波穹隆位于近东西向展布的北喜马拉雅片麻岩穹隆(NHGD)最东端,主要由石榴角闪岩、石榴石云母片麻岩、二云母花岗岩和淡色花岗岩组成.SHRIMP锆石U/Pb定年结果表明也拉淡色花岗岩的结晶年龄为35.3±1.1Ma,明显老于位于该穹隆以西类似的淡色花岗岩(年龄普遍<25Ma).全岩元素和Sr-Nd同位素测试结果揭示：(1)也拉香波淡色花岗岩为过铝质富钠花岗岩;(2)与片麻岩相似,也拉香波淡色花岗岩富集大离子亲石元素(LILE,如K,Sr,Rb和Ba),但亏损Ti,Y,Yb,Sc和Cr;(3)和片麻岩或角闪岩相比,也拉香波淡色花岗岩同时亏损LREE和HREE,但与HREE相比,LREE相对富集;(4)在Sr-Nd同位素系统特征上.淡色花岗岩初始Sr同位素比值与角闪岩的相当,在0.711949～0.719344之间;但远小于片麻岩.而Nd同位素组成在片麻岩和角闪岩之间,在-8.9～-15.0之间.以石榴角闪岩和片麻岩为端元,简单混合计算表明：由石榴角闪岩为主和片麻岩为辅组成的混合源区发生部分熔融作用,各自产生的熔体进行不同程度的混合,可形成类似于也拉香波淡色花岗岩成分的岩浆,其中角闪岩的部分熔融起主要作用.使用Zr在岩浆中的饱和浓度温度计得出岩浆的平均温度为673℃,在此温度下,变泥质片麻岩在高压(～10kbar)条件下的水致部分熔融和角闪岩部分熔融都可形成也拉过铝质富钠淡色花岗岩,但角闪岩的脱水部分熔融起主导作用.在地壳增厚条件下,下地壳角闪岩的部分熔融可能是导致喜玛拉雅造山带从缩短增厚向伸展垮塌转换的主要因素之一.     

Exotic rifted passive margin of a back-arc basin off western Pangea: geochemical evidence from the Early Mesozoic Ayú Complex,southern Mexico

Recent detrital zircon studies of metamorphosed and polydeformed rocks of the early Mesozoic Ayú Complex in southern Mexico suggest an allochthonous origin along the western Pangean margin. Bulk-rock geochemistry of the ca. 170–200 Ma ortho-amphibolites suggests a composition ranging from alkalic and transitional basalts to normalized mid-ocean ridge basalt (N-MORB) tholeiites. Rare earth element (REE) patterns of alkaline basalts (Group I) are characterized by steep negative slopes, whereas transitional basalts (Group II) show moderate light REE (LREE) enrichment. Subalkalic Group III displays slight LREE enrichment and Group IV has relatively flat REE patterns with slight depletion in LREEs. Multiple trace element plots of Group III–IV amphibolites reveal strongly negative Nb–Ta anomalies caused by subduction zone contamination. Initial ?_Nd values (t = 190 Ma) of the amphibolites range from +9.01 to –2.16. Alkalic basalts have negative ?_Nd values, suggesting derivation from an older subcontinental mantle source (T _DM = 877 and 791 Ma). Group II–IV amphibolites have positive ?_Nd values ranging from +2.31 to +9.01, indicating a transition from an older to a relatively juvenile mantle source that is typical of a back-arc setting. The geochemistry of the metasedimentary rocks suggests derivation from an acid-arc source. Chondrite-normalized REE patterns are characterized by enriched LREEs, flat HREE, and negative Eu anomalies. Sm–Nd systematics indicate that most samples were derived from cratonic basement and plot within the Oaxacan Complex envelope with ?_Nd values (t = 195 Ma) ranging from –5.53 to –7.65. We interpret two samples with higher ?_Nd values (–1.42 and +1.06) to reflect the additional influence of a more juvenile component. The amphibolites and metasedimentary rocks of the Ayú Complex document back-arc activity and are inferred to be correlative with various western Mexican Triassic–Jurassic mafic suites and the Potosí fan that formed along the western rifted margin of Pangea.     

河北滦平周台子条带状铁矿地质特征、围岩时代及其地质意义

河北滦平县周台子铁矿位于华北克拉通北缘,是产于前寒武纪单塔子群变质岩系中的鞍山式铁矿,具有条带状铁建造(BIF)特征。矿石主要呈条带状构造,有的呈条纹和致密块状构造。矿石类型主要以石英磁铁矿型为主,含铁介于30%~35%。前寒武纪变质岩是矿床的主要围岩,出露有黑云母(角闪)斜长片麻岩和斜长角闪岩,局部见花岗片麻岩。原岩恢复表明,黑云母(角闪)斜长片麻岩的原岩为英安岩-流纹岩,斜长角闪岩原岩为玄武岩。花岗片麻岩的SiO₂含量大于56%,MgO含量小于3%,Al₂O₃含量大于15%,Sr含量大于500×10^-6,Yb含量均小于1.9×10^-6,轻重稀土元素分异明显,重稀土元素强烈亏损,并且Eu负异常不明显,表明该片麻岩具埃达克质岩石的地球化学特征。锆石U-Pb定年结果显示出几组年龄,分别是2512±21Ma, 2452±9.6Ma,2394±55Ma。大体看,2512Ma代表了火山喷发和周台子铁矿BIF沉淀年龄,2452Ma左右的锆石年龄代表了TTG质花岗片麻岩的侵位结晶年龄,2394Ma锆石年龄代表了周台子铁矿经历了一次变质作用,并对原有的岩石和矿石进行了改造。锆石Hf同位素特征显示斜长角闪岩和TTG质片麻岩的岩浆源区受到过古老地壳物质的混染。周台子铁矿构造环境可能是与裂谷有关的张性环境。     

河北小觉地区阜平岩群斜长角闪岩及深熔产物的稀土和Nd同位素地球化学研究

工作中重点对河北平山小觉地区阜平岩群两类角闪质岩石深熔作用的地球化学进行了研究。一类为厚层状斜长角闪岩，相邻新生浅色体常量元素组成上向TTG花岗质岩石方向转化，稀土和高场强元素含量明显降低，轻重稀土分离程度增高，tDM减小，εNd(t0)增大。另一类为与黑云变粒岩－片麻岩互层的条带状、石香肠状斜长角闪岩，相邻新生浅色体与之存在不同的地球化学关系：（1）稀土总量相对增高，轻重稀土分离程度有所降低；（2）稀土总量和轻重稀土分离程度都有明显增高。后者Nd同位素组成与斜长角闪岩也存在很大区别。这些现象可用熔融母岩、形成条件等差异得到合理的解释。