High-resolution seismic characterization of the gas and gas hydrate system at Green Canyon 955, Gulf of Mexico,USA

The Pliocene and Pleistocene sediments at lease block Green Canyon 955 (GC955) in the Gulf of Mexico include sand-rich strata with high saturations of gas hydrate; these gas hydrate accumulations and the associated geology have been characterized over the past decade using conventional industry three-dimensional (3D) seismic data and dedicated logging-while-drilling (LWD) borehole data. To improve structural and stratigraphic characterization and to address questions of gas flow and reservoir properties, in 2013 the U.S. Geological Survey acquired high-resolution two-dimensional (2D) seismic data at GC955. Combined analysis of all available data improves our understanding of the geological evolution of the study area, which includes basin-scale migration of the Mississippi River sediment influx as well as local-scale shifting of sedimentary channels at GC955 in response to salt-driven uplift, structural deformation associated with the salt uplift, and upward gas migration from deeper sediments that charges the main gas hydrate reservoir and shallower strata. The 2D data confirm that the sand-rich reservoir is composed principally of sediments deposited in a proximal levee setting and that episodes of channel scour, interspersed with levee deposition, have resulted in an assemblage of many individual proximal levee deposit “pods” each with horizontal extent up to several hundred meters. Joint analysis of the 2D and 3D data reveals new detail of a complex fault network that controls the fluid-flow system; large east-west trending normal faults allow fluid flow through the reservoir-sealing fine-grained unit, and smaller north-south oriented faults provide focused fluid-flow pathways (chimneys) through the shallower sediments. This system has enabled the flow of gas from the main reservoir to the seafloor throughout the recent history at GC955, and its intricacies help explain the distributed occurrences of gas hydrate in the intervening strata.     

The distribution of phenylalkanes in the modern sediment associated with gas hydrate from the Gulf of Mexico

Phenylalkanes with carbon numbers between 16 and 19, characterized by the main carbon-18, have been identified in the modern sediments collected from gas hydrate area from the Gulf of Mexico. The structure of phenylalkanes with four isomers for every carbon number was determined by means of their mass spectra and previous studies. The distribution of the series characterized by a low molecular mass was similar to the distribution of n-alkane, alkylcyclohexanes and alkylbenzenes in each sample. There were differences in the distribution of the phenylalkane series between the S - 1, S - 4, S - 7, S - 9 samples and the S - 8, S - 10 and S - 11 samples. The phenylalkanes might be derived from Archaea associated with anaerobic oxidation of methane （AOM） processes in S - 1, S -4, S -7 and S -9 samples according to their distribution resembled with the distribution of the extract from a type of Archaea. The distribution of alkylcyclohexanes and alkylbenzenes in S - 1, S - 4, S - 7 and S - 9 sample was found to be similar to each other. The odd-over-even predominance of alkylcyclohexanes was seen as the input of some bac- terial.     

墨西哥湾天然气水合物矿产资源预测模型及其应用

墨西哥湾是世界上研究天然气水合物较深入的海区,调查资料丰富,已在50多处采集到天然气水合物样品,具备建立天然气水合物矿产资源预测模型的条件。选择34处已知天然气水合物矿点和34处已知无矿点作为训练区,建立矿点存在与否的预测模型。模型的相关系数值表明墨西哥湾天然气水合物与盐底辟关系密切。将该模型应用于整个墨西哥湾北部,初步获得了天然气水合物存在可能性概率分布图;概率大于0.7的预测单元包含已知矿点中的30个,利用该阈值圈定了墨西哥湾天然气水合物潜在资源分布区。     

Time series video analysis of bubble release processes at natural hydrocarbon seeps in the Northern Gulf of Mexico

This research quantifies the rate and volume of oil and gas released from two natural seep sites in the Gulf of Mexico: lease blocks GC600 (1200 m depth) and MC118 (850 m depth). Our objectives were to determine variability in release rates and bubble size at five individual vents and to investigate the effects of tidal fluctuations on bubble release. Observations with autonomous video cameras captured the formation of individual bubbles as they were released through partially exposed deposits of gas hydrate. Image processing techniques determined bubble type (oily, gaseous, and mixed: oily and gaseous), size distribution, release rate, and temporal variations (observation intervals ranged from 3 h to 26 d). A semi-automatic bubble counting algorithm was developed to analyze bubble count and release rates from video data. This method is suitable for discrete vents with small bubble streams commonly seen at seeps and is adaptable to multiple in situ set-ups. Two vents at GC600 (Birthday Candles 1 and Birthday Candles 2) were analyzed. They released oily bubbles with an average diameter of 5.0 mm at a rate of 4.7 bubbles s⁻¹, and 1.3 bubbles s⁻¹, respectively. Approximately 1 km away, within the GC600 seep site, two more vents (Mega Plume 1 and Mega Plume 2) were analyzed. These vents released a mixture of oily and gaseous bubbles with an average diameter of 3.9 mm at a rate of 49 bubbles s⁻¹, and 81 bubbles s⁻¹, respectively. The fifth vent at MC118 (Rudyville) released gaseous bubbles with an average diameter of 3.0 mm at a rate of 127 bubbles s⁻¹. Pressure records at Mega Plume and Rudyville showed a diurnal tidal cycle (24.5 h). Rudyville was the only vent that demonstrated any positive correlation (ρ = 0.60) to the 24.5 h diurnal tidal cycle. However, these observations were not conclusive regarding tidal effects on bubble release.     

Microstructures of structure I and II gas hydrates from the Gulf of Mexico

Gas hydrate samples from various locations in the Gulf of Mexico (GOM) differ considerably in their microstructure. Distinct microstructure characteristics coincide with discrete crystallographic structures, gas compositions and calculated thermodynamic stabilities.     

Secondary production of Ampelisca mississippiana Soliman and Wicksten 2007 (Amphipoda, Crustacea) in the head of the Mississippi Canyon, northern Gulf of Mexico

Annual production was calculated for the dominant ampeliscid amphipod Ampelisca mississippiana [Soliman, Y., Wicksten, M., 2007. Ampelisca mississippiana a new species (Amphipoda: Gammaredea) dominated the head of the Mississippi Canyon (Northern Gulf of Mexico). Zootaxa, submitted] at the head of the Mississippi Canyon in the northern Gulf of Mexico. Average densities were 12,094±2499 ind m⁻², with secondary production of 6.93 g dry wt m⁻² yr⁻¹, based on the “size-frequency method” [Hynes-Hamilton, H.B.N., Coleman, M., 1968. A simple method for assessing the annual production of stream benthos. Limnology and Oceanography 13, 569–573; Menzies, C.A., 1980. A note on the Hynes-Hamilton method of estimating secondary production. Limnology and Oceanography 25(4), 770–773], with a production/biomass (P/B) ratio of 3.11. Growth rates of this magnitude are comparable to available data for freshwater and shallow marine ampeliscids, but are unexpectedly high for deep-ocean habitats. Growth efficiency appeared to be approximately 35% (Growth/Assimilation×100).     

墨西哥湾西北陆坡天然气水合物资源评价

墨西哥湾西北陆坡天然气水合物发育广泛,水合物天然气资源量估计约(10～14)×1012m3。构造控制的混合成因(生物甲烷和热成因天然气)水合物含量高、资源密度大,经济潜力高;盆地生物成因甲烷水合物呈细分散状发育,沉积物中水合物含量低、资源密度小、经济潜力低。综合地质、技术和开采成本3方面因素,在目前全球几个工程程度较高的水合物发育区中,墨西哥湾水合物的经济潜力最大,其中工作程度最高的7个水合物发育区中,MC852/853区的经济潜力最高。     

Impacts of frontal stability and topography on cross-shelf exchange in the Northern Gulf of Mexico

The shelfbreak wintertime thermal front in the Northeastern Gulf of Mexico often exhibits meandering, eddy formation and warm-water intrusion. A high level of frontal variability plays an essential role in exchange processes across the shelf. This study examines the impacts of local frontal instability and bottom topography on turbulent heat exchange across the front using the results of two numerical models. Analysis of a series of numerical experiments reveals that the flow is baroclinically unstable. Predicted frontal instability contributes significantly to cross-frontal exchange and accounts for about 35% of the total eddy heat flux. Onshore eddy heat flux has the highest intensity at the frontal position. In addition, eddy activity and heat flux are sensitive to variation of bottom topography. For topographic features and frontal characteristics that are typical of the area, bottom steepness enhances the flux and is nearly proportional to the cross-frontal heat exchange. The study attempts to explain physical mechanisms that drive frontal circulation in the area and to quantify heat transport across the shelf. Estimated heat fluxes can provide important information for climate and ecosystem modeling of the Mississippi Bight.     

Cenozoic evolution of sediment accumulation in deltaic and shore-zone depositional systems, Northern Gulf of Mexico Basin

Paleogeographic and volumetric lithofacies mapping of 18 Cenozoic genetic sequences within the Northern Gulf of Mexico Basin quantifies the proportional sequestering of sediment within wave-dominated shore-zone vs. deltaic systems through time. Three long-term depositional phases are revealed by plots, based on paleogeographic and sediment isochore maps, of total shore-zone system area and volume to total delta system area and volume (SZ/D). (1) SZ/D area and volume ratios are highly variable in Paleocene through Eocene sequences. However, typical volume ratios for major genetic sequences (Upper, Middle, and Lower Wilcox; Queen City (QC), and Yegua) range between 0.2 and 0.6. Minor sequences (Sparta (SP), Jackson (JS)), which record very low rates and volumes of sediment accumulation, have the greatest variability in their ratios. (2) Oligocene and Miocene sequences display consistently high proportions of shore-zone sediment. SZ/D area ratios range from 0.6 to 1.0, and volume ratios cluster between 0.4 and 0.8. (3) A substantial late Neogene decrease in SZ/D ratios is presaged in the late Miocene sequence. Pliocene and Pleistocene sequences are uniformly characterized by very low ratios of <0.2. Consistently high Oligocene–Miocene ratios reflect a post-Eocene period of strong E–W climate gradient across the Northern Gulf margin. Shore-zone volume displays no correlation to overall rate of sediment supply. The late Neogene decrease in proportional shore-zone system importance corresponds to development of the West Antarctic and Northern Hemisphere ice sheets and related increase in amplitude and frequency of glacioeustatic sea level cycling.     

Occurrence of larval fishes in the surf zone of a northern Gulf of Mexico barrier island

Larval fishes were collected from the surf zone of Horn Island, Mississippi between March 1978 and April 1979. A standardized total of 39 435 larvae were taken from 222 collections in the inner and outer surf zone regions, representing fish in 69 taxa. Overall, considerably more larvae were collected in the outer surf zone (78·3%) than in the inner surf zone (21·7%). Engraulids, Chloroscombrus chrysurus and Symphurus spp. were the most abundant larvae taken from the outer surf zone while engraulids, Leiostomus xanthurus, Brevoortia patronus and Trinectes maculatus were the numerically dominant larvae in the inner surf zone. Seasonal peaks in abundance occurred at the outer surf zone stations during May and June and at the inner surf zone stations during December. Larval densities were significantly greater in night collections than in day collections.The occurrence of early larvae, late larvae and juveniles suggests that the surf zone habitat is important to several species of coastal marine fishes. Menticirrhus littoralis, Harengula jaguana and Trachinotus carolinus appear to most readily utilize the surf zone as a nursery area.     

In situ hydrocarbon concentrations from pressurized cores in surface sediments, Northern Gulf of Mexico

Two newly developed coring devices, the Multi-Autoclave-Corer and the Dynamic Autoclave Piston Corer were deployed in shallow gas hydrate-bearing sediments in the northern Gulf of Mexico during research cruise SO174 (Oct–Nov 2003). For the first time, they enable the retrieval of near-surface sediment cores under ambient pressure. This enables the determination of in situ methane concentrations and amounts of gas hydrate in sediment depths where bottom water temperature and pressure changes most strongly influence gas/hydrate relationships. At seep sites of GC185 (Bush Hill) and the newly discovered sites at GC415, we determined the volume of low-weight hydrocarbons (C₁ through C₅) from nine pressurized cores via controlled degassing. The resulting in situ methane concentrations vary by two orders of magnitudes between 0.031 and 0.985 mol kg^− 1 pore water below the zone of sulfate depletion. This includes dissolved, free, and hydrate-bound CH₄. Combined with results from conventional cores, this establishes a variability of methane concentrations in close proximity to seep sites of five orders of magnitude. In total four out of nine pressure cores had CH₄ concentrations above equilibrium with gas hydrates. Two of them contain gas hydrate volumes of 15% (GC185) and 18% (GC415) of pore space. The measurements prove that the highest methane concentrations are not necessarily related to the highest advection rates. Brine advection inhibits gas hydrate stability a few centimeters below the sediment surface at the depth of anaerobic oxidation of methane and thus inhibits the storage of enhanced methane volumes. Here, computerized tomography (CT) of the pressure cores detected small amounts of free gas. This finding has major implications for methane distribution, possible consumption, and escape into the bottom water in fluid flow systems related to halokinesis.     

Distinctiveness of the mesopelagic fish fauna in the Gulf of Mexico

We quantify the similarity of the Gulf of Mexico mesopelagic fish fauna to that in adjacent oceanic regions, the Venezuelan and Colombian Basins of the Caribbean Sea and the North and South Sargasso Seas. The South Sargasso and Colombian are the least similar of the areas in terms of their faunal composition, and the Venezuelan and Colombian Basins are the most similar. The Gulf fauna lies somewhere in between, and is a composite of that in the Sargasso and Caribbean Seas. The Gulf of Mexico displays the greatest abundance, biomass and richness (S=140 species), and is an intermediate in evenness (J=0.66) and percent endemism (7.1%). Our findings support the view that the centrally located Gulf is an oceanic ecotone between the Atlantic Tropical and Subtropical faunal regions.     

Rock physics-based seismic trace analysis of unconsolidated sediments containing gas hydrate and free gas in Green Canyon 955, Northern Gulf of Mexico

The gas hydrate petroleum system at the 2009 Gulf of Mexico Gas Hydrate Joint Industry Project Leg II (JIP Leg II) Green Canyon 955 (GC955) site shows a complex seismic amplitude and waveform response of highly negative and positive amplitudes with continuous and discontinuous character within inferred gas-hydrate- and gas-bearing sand reservoirs. Logging-while-drilling (LWD) data obtained during JIP Leg II and conventional 3-D seismic data allowed for the identification of thick highly concentrated hydrate layers by integrating rock physics modeling, amplitude and thin layer analysis, and spectral decomposition. Rock physics modeling with constraints from three JIP LWD holes allowed for the analysis of variations in acoustic amplitude characteristics as a product of hydrate saturation, gas saturation, and reservoir thickness. Using the well log-derived acoustic models, thick highly concentrated gas hydrate with and without underlying free gas accumulations have been identified. These results suggest that thick highly concentrated gas-hydrate-bearing sand units (with thicknesses greater than half of the seismic tuning thickness and gas hydrate saturations greater than 50%) underlain by gas can be differentiated from sands containing only gas, but thin gas-hydrate-bearing sand units with low gas hydrate concentrations (with thicknesses less than half of the seismic tuning thickness and gas hydrate saturations less than 50%) are difficult to identify from post-stack seismic amplitude data alone. Within GC955, we have identified six zones with seismic amplitude anomalies interpreted as being caused by gas hydrate deposits with variable lateral extent, thickness and saturation, and in some cases overlying free-gas-bearing intervals. Synthetic seismic images produced from well-log- and model-derived velocity and density distributions mimic similar reflection characteristics in the corresponding field seismic data.     

Sediment community oxygen consumption in the deep Gulf of Mexico

Sediment community oxygen consumption (SCOC) has been measured from the continental shelf out to the Sigsbee Abyssal Plain in the NE Gulf of Mexico (GoM). SCOC rates on the continental shelf were an order of magnitude higher than those on the adjacent continental slope (450–2750 m depth) and two orders of magnitude higher than those on the abyssal plain at depths of 3.4–3.65 km. Oxygen penetration depth into the sediment was inversely correlated with SCOC measured within incubation chambers, but rates of SCOC calculated from either the gradient of the [O₂] profiles or the total oxygen penetration depth were generally lower than those derived from chamber incubations. SCOC rates seaward of the continental shelf were lower than at equivalent depths on most continental margins where similar studies have been conducted, and this is presumed to be related to the relatively low rates of pelagic production in the GoM. The SCOC, however, was considerably higher than the input of organic detritus from the surface-water plankton estimated from surface-water pigment concentrations, suggesting that a significant fraction of the organic matter nourishing the deep GoM biota is imported laterally down slope from the continental margin.     

High-resolution seismic-reflection investigation of the northern Gulf of Mexico gas-hydrate-stability zone

We recorded high-resolution seismic-reflection data in the northern Gulf of Mexico to study gas and gas-hydrate distribution and their relation to seafloor slides. Gas hydrate is widely reported near the seafloor, but is described at only one deep drill site. Our data show high-reflectivity zones (HRZs) near faults, diapirs, and gas vents and interbedded within sedimentary sections at shallow depth (<1 km). The HRZs lie below the gas-hydrate-stability zone (GHSZ) as well as within the zone (less common), and they coincide with zones of shallow water-flows. Bottom simulating reflections are rare in the Gulf, and not documented in our data.We infer HRZs result largely from free gas in sandy beds, with gas hydrate within the GHSZ. Our estimates for the base BHSZ correlate reasonably with the top of HRZs in some thick well-layered basin sections, but poorly where shallow sediments are thin and strongly deformed. The equivocal correlation results from large natural variability of parameters that are used to calculate the base of the GHSZ. The HRZs may, however, be potential indicators of nearby gas hydrate. The HRZs also lie at the base of at least two large seafloor slides (e.g. up to 250 km²) that may be actively moving along decollement faults that sole within the GHSZ or close to the estimated base of the GHSZ. We suspect that water/gas flow along these and other faults such as ‘chimney’ features provide gas to permit crystallization of gas hydrate in the GHSZ. Such flows weaken sediment that slide down salt-oversteepened slopes when triggered by earthquakes.     

Allochthonous salt, structure and stratigraphy of the north-eastern Gulf of Mexico. Part I: Stratigraphy

Major sequence boundaries associated with eustatic sea level changes are correlated to the general stratigraphy of the north-eastern Gulf of Mexico. The details of a Middle Cretaceous Flooding Surface, marking a major break in sedimentation, are documented. The sequence stratigraphic work provides an example of the ‘stratigraphic signature of the Neogene’. Three major episodes of sediment accumulation are represented by: (1) Late Jurassic (150.5 Ma) to Middle Cretaceous (94 Ma) aggradation and progradation of sediments with significant sediment accumulation in the present shelf and slope areas; (2) an extended period of starved sedimentation during 94-30 Ma corresponding to Middle Cretaceous flooding events (93.5 and 91.5 Ma) and the lack of sediment supply; and (3) since Late Oligocene time, unusually rapid sedimentation rates that characterize the deep water study area. These patterns of sediment accumulation directly affect the formation of allochthonous salt in the study area.     

Petrographic and geochemical characterization of seep carbonate from Bush Hill (GC 185) gas vent and hydrate site of the Gulf of Mexico

Authigenic carbonates are common at cold seep sites as a result of microbial oxidation of hydrocarbons. Seep carbonate samples were collected from the surface of the Bush Hill (Green Canyon Block 185, Gulf of Mexico), a mound containing gas hydrate. The carbonates consisted of oily, porous limestone slabs and blocks containing bioclasts and matrix. Analysis by X-ray diffraction shows that aragonite is the dominant mineral (89–99 wt% with an average of 94 wt%) in the matrix of seep carbonate. This cement occurs in microcrystalline, microspar, and sparite forms. The moderate ¹³C depletion of the seep carbonate (the most depleted one has δ¹³C value of −29.4‰, and 26 of 38 subsamples have δ¹³C values >−20.0‰) indicates that the non-methane hydrocarbons was incorporated during seep carbonate precipitation. Relative enrichment of ¹⁸O may be related to localized destabilization of gas hydrate or derived from ¹⁸O-enriched pore water originated from smectite–illite transition in the deep sediments. The total content of rare earth elements (REE) of the 5% HNO₃-treated solution of the carbonates is from 0.40 ppm to 30.9 ppm. The shale-normalized REE patterns show varied Ce anomalies from significantly negative, slightly negative, and no to positive Ce anomalies. Variable content of trace elements, total REE, and Ce anomalies in different samples and even in the different carbonate mineral forms (microcrystalline, microspar and sparite) of the same sample suggest that the formation condition of the Bush Hill seep carbonate is variable and complex, which is possibly controlled by the rate of fluid flux.     

Seasonality and interannual variability of freshwater inflow to a large oligohaline estuary in the Northern Gulf of Mexico

Quantity, timing, duration, and fluctuation of freshwater inflow are important factors affecting the development and health of aquatic and adjacent wetland ecosystems in coastal estuaries. This study assessed six decades of freshwater inflow from the Amite River, Tickfaw River, and Tangipahoa River watersheds to Lake Pontchartrain, a large oligohaline estuary in the Northern Gulf of Mexico, whose flood waters caused recent damage to the city of New Orleans in the aftermath of Hurricane Katrina. By utilizing the long-term (1940–2002) river discharge and climatic data from the three major tributary watersheds, monthly and annual freshwater inflows have been quantified and their spatial and temporal variations have been analyzed. On average, the three rivers discharged (±standard error) 0.27 ± 0.04 km³ freshwater monthly and 3.29 ± 0.15 km³ freshwater annually into the lake estuarine system, with the highest inflow from the Amite River (0.16 ± 0.03 m³ mon⁻¹, and 1.91 ± 0.09 km³ yr⁻¹) and the lowest inflow from the Tickfaw River (0.03 ± 0.00 km³ mon⁻¹, and 0.34 ± 0.02 km³ yr⁻¹). A distinct seasonality was evident with over 69% of the total annual inflow occurring during December and May (wet months) and with a low flow period from August to November (dry months). The monthly inflow during the wet months was positively correlated with the monthly precipitation (r² = 0.64), while the monthly inflow during the dry months was subject to evapotranspiration. Furthermore, the study found a 20-year low flow period from 1954–1973 (2.76 ± 0.24 km³ yr⁻¹) and a 24-year high flow period from 1975–1998 (3.84 ± 0.24 km³ yr⁻¹), coinciding with both the climate variation and population growth in the watersheds.