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1.
扬子地台西南缘古元古代末的裂解事件——来自武定地区辉绿岩锆石U Pb年龄和地球化学证据 总被引:7,自引:0,他引:7
云南省武定地区广泛出露元古宙辉绿岩体,本文报道了武定地区海孜辉绿岩的地球化学特征及锆石的LA-ICP-MS U-Pb年龄,结果为1767±15Ma(MSWD=0.19,n=17),表明本区广泛出露的辉绿岩群侵位时代为古元古代晚期。辉绿岩岩石化学表现为低SiO2、MgO以及高TiO2(3.24%~4.02%)、碱(K2O+Na2O)和P2O5含量(0.32%~0.45%),具有偏碱性的拉斑质玄武岩的岩石化学特征。辉绿岩的大离子半径元素如K、Rb、Ba等富集,高场强元素如Ta、Nb和Zr、Hf没有明显的亏损,其地球化学参数也多与夏威夷碱性洋岛玄武岩相近。辉绿岩的微量、稀土元素的配分模式与典型的OIB和峨眉山高Ti玄武岩具有高度一致性。海孜辉绿岩原始岩浆形成于相对较富集的过渡型地幔的部分熔融,其源区为尖晶石橄榄岩相,演化过程中,有少量下地壳物质的加入。海孜辉绿岩与扬子地台西南缘广泛出露古元古代晚期的岩浆岩一致,形成于全球性Columbia超级大陆裂解的大地构造背景。海孜辉绿岩OIB的地球化学属性,为古元古代晚期全球性Columbia超级大陆裂解的地幔柱活动提供了最重要的地球化学证据。 相似文献
2.
《矿物岩石》2016,(2)
大竹棚流纹岩产出于扬子地台西南缘武定-元江裂陷槽内,其形成时代和地球化学特征的研究对完善扬子地台西南缘的岩浆岩系统和大地构造历史具有重要意义。应用激光烧蚀多接收器电感耦合等离子质谱仪(LA-ICP-MS)方法对大竹棚流纹岩进行精确的锆石U-Pb定年。结果表明产出于因民组之中的大竹棚流纹岩岩浆锆石加权平均年龄为1 730 Ma±4 Ma(MSWD=0.85),该年代学结果较为精确地限定了大竹棚流纹岩的形成年龄。岩相学及地球化学的研究结果显示大竹棚流纹岩具高硅(w(SiO_2)=71.97%~80.02%)、过铝质(w(Al_2O_3)=10.1%~12.64%)、A/CNK=1.19~1.66、低钛、富集轻稀土(LREE/HREE=0.61~3.0)及高场强元素,亏损大离子亲石元素等特征,其化学性质类似于A2型花岗岩,可能由同源玄武质岩浆经结晶分异作用形成。综合研究推测大竹棚流纹岩很有可能形成于碰撞后的大陆伸展或者裂谷环境中,是扬子地台西南缘昆阳裂谷在古元古代(1.73Ga)时裂解的产物,这可以视为Columbia超大陆裂解在扬子地台西南缘的一个响应证据。 相似文献
3.
云南省武定县迤纳厂铁铜矿区广泛出露元古宙辉绿岩体。前人对区内基性岩浆岩研究程度较低,缺乏辉绿岩的形成时代资料。本文报道了区内海孜辉绿岩中锆石的LA-ICP-MS U-Pb年龄,为1728±4 Ma。此年龄与古元古代晚期扬子地台西南缘大规模非造山型岩浆活动及全球性Columbia超级大陆裂解时代高度一致,表明其可能为Columbia超级大陆裂解的产物。辉绿岩与区内铁铜矿床成矿时代大致相当,反映了古元古代晚期扬子地台西南缘大规模的岩浆活动也可能是一次重要的成矿事件,可能为铁、铜成矿作用提供主要的成矿物质来源。武定地区被辉绿岩侵入接触的原"美党组"地层的沉积时代应大于辉绿岩的侵位时代,应划入下元古界汤丹群,是昆阳陆内裂谷拉张以前就已存在的基底地层。 相似文献
4.
扬子克拉通西缘1.73Ga非造山型花岗斑岩的发现及其地质意义 总被引:2,自引:0,他引:2
首次发现扬子克拉通西缘古元古代晚期海孜斜长花岗斑岩岩体.本文报道了其锆石的LA-ICP-MS U-Pb年龄,为1730±15Ma(MSWD=4.0,n=15).岩石具有高SiO2(69.77%~73.83%)、高碱(ALK=5.46~6.65)、低钾(K2O/Na2O=0.02~0.14)含量.里特曼指数1.04~1.65,A/CNK值为1.11~1.25,平均值为1.18(>1.1),10000 Ga/Al=3.96~7.34(均值为5.18>2.6),较高的含铁指数[FeO/(FeO+MgO) =0.95~0.99],总体显示了低钾钙碱性过铝质(SP)铁质A型花岗岩的特点.岩石富集Nb、Ta、Zr和Hf等高场强元素,强烈亏损K、Sr和Ba等大离子亲石元素,稀土元素总量∑REE=390.70×10-6~674.91×10-6,LREE/HREE=1.74~3.29(均值2.18),轻稀土分异作用明显,相对富集,表现出强烈的负Eu异常.地球化学特征显示,海孜花岗斑岩岩体为形成于板内伸展构造环境,可能与同期基性岩浆活动的底侵作用相关.海孜花岗岩的年龄和地球化学表明,扬子克拉通西缘存在古元古代晚期与全球性Columbia超级大陆裂解同期的双峰式岩浆岩组合. 相似文献
5.
扬子地台周边地区已陆续发现基性—超基性岩,但其成因一直存在争议。九岭南缘安义珠洛山变质基底地层中也发育有辉绿岩岩墙群,其形成时代及成因未作过研究。笔者通过1∶25万上高县幅区域地质调查,获得其单颗粒锆石U-Pb法同位素年龄为(796±1)Ma,属新元古代基性岩。该基性岩岩墙群地球化学成分相当于拉斑玄武岩序列,形成于板内环境。它与九岭强过铝质花岗岩构成双峰式侵入岩套,可能形成于碰撞后伸展构造环境,而与Rod in ia超大陆裂解无关。 相似文献
6.
扬子西缘澄江组底部玄武岩形成时代新证据及其地质意义 总被引:1,自引:0,他引:1
扬子西缘新元古代澄江组底部发育一套玄武岩,其形成时代一直未能准确限定。本文在野外地质调查的基础上,对云南武定罗茨地区澄江组底部玄武岩进行了较为系统的岩石学和同位素年代学研究。结果表明,最年轻一组锆石206Pb/238U年龄加权平均值为804±6 Ma(MSWD=0.40),可以代表澄江组玄武岩的形成时代,从而进一步确定澄江组底界年龄为800 Ma左右。武定罗茨地区澄江组底部玄武岩显示低Si O2,高(K2O+Na2O)、Ti O2和Al2O3的特点,具有大陆裂谷碱性玄武岩的性质。结合区域相关研究资料,认为扬子西缘可能存在一个自~800 Ma持续至725 Ma的幕式双峰式岩浆岩带,而澄江组底部玄武岩和苏雄组火山岩均为~800 Ma双峰式岩浆活动的产物,并推测该双峰式岩浆岩带可能形成于大陆裂谷环境。此外,玄武岩中捕获的锆石年龄信息指示扬子西缘可能存在2.5 Ga、1.8~1.6 Ga及1.0 Ga等数期重要的区域构造-热事件。 相似文献
7.
云南新平地区大红山群出露于扬子地块西南缘,主要由低绿片岩相-角闪岩相变质的火山-沉积岩组成。大红山群的岩石成因、年代格架及其形成的构造背景缺乏系统研究,制约了地质学家们全面认识和理解扬子西南缘<~1.75 Ga的构造演化历史。本文以大红山群底部老厂河组变沉积岩及其内部变火山岩夹层为重点研究对象,开展岩相学、全岩地球化学和锆石U-Pb定年等综合研究。岩石地球化学研究结果表明,变沉积岩的化学成分与大陆上地壳沉积物成分接近,原岩为成熟度较高的泥岩/页岩,未经历沉积再循环,形成于被动大陆边缘的构造背景;变火山岩原岩化学成分相当于钙碱性过铝质A型流纹岩,形成于造山后的大陆裂谷拉张环境。锆石U-Pb定年结果显示,老厂河组变沉积岩的碎屑锆石记录了2.3~2.2 Ga和1.9~1.75 Ga两个主年龄峰以及2.7~2.6 Ga次年龄峰。结合前人研究结果,表明大红山群物源主要来源于扬子地块西南缘的太古宙-古元古代基底岩石。变火山岩样品的岩浆锆石核部记录了1 713~1 711 Ma的年龄,应代表老厂河组原岩的形成时代,锆石的变质增生边限定峰期变质时代为约843 Ma。综合前人研究结果表明,大红山群普遍经历了849~837 Ma的新元古代变质事件。综上所述,扬子地块西南缘的大红山群完好记录了与Columbia超大陆裂解有关的非造山岩浆活动,新元古代变质事件可能与Rodinia超大陆裂解和聚合过程密切相关。 相似文献
8.
扬子西南缘是我国重要的铁铜金矿产资源产区,分布许多铁铜多金属矿床,而本次研究的大红山矿床属扬子西南缘内最大的铁铜多金属矿床之一.铁、铜矿化方解石脉中方解石测年结果表明,Sm-Nd等时线年龄为(818士3) Ma,代表方解石脉中磁铁矿、黄铜矿矿化年龄为818Ma.结合扬子西南缘成岩成矿关系、背景研究,揭示该矿化事件与Rodinia超大陆裂解期大陆裂谷环境有关.据方解石Sm-Nd同位素体系中(143Nd/144Nd)i值0.5112649和εNd(t=818Ma)值范围介于-6.3~-6.2之间的组成特点,指示方解石中Nd为壳幔混源,且以幔源为主. 相似文献
9.
黔东南新元古代岩浆岩单颗粒锆石 U- Pb年龄及其构造意义 总被引:20,自引:1,他引:20
对黔东南地区摩天岭花岗岩、下江群基性火山岩及加榜基性侵入岩进行了精确的锆石 U- Pb法定年,年龄结果分别为 (825.0± 2.4) Ma, (815.8± 4.9) Ma和 (788.4± 2.6) Ma,形成时代均为新元古代中期.下江群的沉积上限应不晚于 788 Ma.下江群地层在所研究基性火山岩下厚度仅数百米,在其上厚度达数千米至近万米,可以推测下江群开始接受沉积的年代应接近于 815 Ma.在 815~ 788 Ma较短时间内沉积地层之厚,可见当时地壳上升和剥蚀速度都较快.前人的研究发现,扬子地块周缘和内部都存在着与摩天岭花岗岩年代相近的花岗岩体,以及扬子地块周缘和华夏地块都存在与下江群基性火山岩年代相近的包括双峰式在内的火山岩.另外,桂北黔东南和湖北黄陵地区新元古代的花岗岩和基性侵入岩在时代和地球化学特征上比较相近.认为桂北黔东南的新元古代岩浆岩的形成与地幔柱导致的 Rodinia超大陆裂解有关. 相似文献
10.
昆阳群的形成时代、沉积环境、源岩性质等一直存在较大争议,为了查明滇中地区昆阳群的物源及其形成的构造环境,文章在分析昆阳群沉积组合和沉积相的基础上,对昆阳群3件变质砂岩样品中的碎屑锆石进行LA-ICPMS锆石U-Pb年龄测定,对昆阳群20件极低级变质碎屑岩进行地球化学分析。从昆阳群黄草岭组、黑山头组和美党组中分别获得了最年轻的谐和年龄为984.0 Ma、945.0 Ma和954.0 Ma;碎屑锆石年龄峰谱显示,在1.0 Ga、1.35Ga、1.73 Ga和2.44 Ga出现了统计峰值,其年龄主要集中在1.73 Ga和1.35 Ga。表明昆阳群源区主要经历了1.0 Ga、1.35 Ga、1.73 Ga和2.44 Ga的构造热事件,资料显示扬子地块西南缘出露的大红山群形成时代为1.7 Ga,格林威尔期的构造热事件时期为1.0~1.3 Ga。此外,地球化学分析结果表明昆阳群源岩主要是形成于大陆岛弧—活动大陆边缘的石英质旋回沉积、长英质岩石和少量镁铁质岩石。在中元古代晚期—新元古代早期(0.95~1.0 Ga),Rodinia超大陆形成阶段,在扬子地块西南缘的弧后前陆盆地中形成昆阳群的沉积组合,物源主要来自扬子地块西南缘的大红山群和格林威尔期岛弧的岩石。 相似文献
11.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
12.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10 μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提出了具体测定要求。 相似文献
13.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
14.
Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引:1,自引:0,他引:1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
15.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
16.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
17.
河南郁山铝土矿区包括郁山、李村、杏树洼、煤窑洼4个铝土矿段。本溪组含铝岩系的分布、埋深及岩相特征直接控制铝土矿的赋存和空间特征。区内构造对含矿岩系的分布、产状、埋深及完整性等有重要的控制作用。含铝岩系厚度与铝土矿厚度及品位一般呈正变关系,即含铝岩系厚度大,铝土矿层厚而富。铝土矿物沉积于古地形中,大的凹陷沉积盆地控制着铝土矿带的分布范围和展布方向,其中小的洼地、溶洞、溶斗等具体控制铝土矿的矿体形态、产状、规模。河南郁山铝土矿为典型的喀斯特型铝土矿。铝土矿成矿物质均来自上地壳,为上地壳岩石经过风化而成,非花岗岩以及玄武岩等岩石类型;铝土矿物质来源与基底碳酸盐岩关系不大,具有一定距离的搬运,说明铝土矿物质来源非原地,而是异地来源;秦岭古陆提供了重要成矿物质。 相似文献
18.
S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
19.