Potassium isotopic compositions of enstatite meteorites

Enstatite chondrites and aubrites are meteorites that show the closest similarities to the Earth in many isotope systems that undergo mass‐independent and mass‐dependent isotopic fractionations. Due to the analytical challenges to obtain high‐precision K isotopic compositions in the past, potential differences in K isotopic compositions between enstatite meteorites and the Earth remained uncertain. We report the first high‐precision K isotopic compositions of eight enstatite chondrites and four aubrites and find that there is a significant variation of K isotopic compositions among enstatite meteorites (from ?2.34‰ to ?0.18‰). However, K isotopic compositions of nearly all enstatite meteorites scatter around the bulk silicate earth (BSE) value. The average K isotopic composition of the eight enstatite chondrites (?0.47 ± 0.57‰) is indistinguishable from the BSE value (?0.48 ± 0.03‰), thus further corroborating the isotopic similarity between Earth's building blocks and enstatite meteorite precursors. We found no correlation of K isotopic compositions with the chemical groups, petrological types, shock degrees, and terrestrial weathering conditions; however, the variation of K isotopes among enstatite meteorite can be attributed to the parent‐body processing. Our sample of the main‐group aubrite MIL 13004 is exceptional and has an extremely light K isotopic composition (δ⁴¹K = ?2.34 ± 0.12‰). We attribute this unique K isotopic feature to the presence of abundant djerfisherite inclusions in our sample because this K‐bearing sulfide mineral is predicted to be enriched in ³⁹K during equilibrium exchange with silicates.     

Are high‐temperature fractionations in the solar nebula preserved in highly siderophile element systematics of the Earth's mantle?

Abstract— The relative abundances of the highly siderophile elements (HSE) Os, Ir, Ru, Pt, Rh, and Pd in relatively pristine lherzolites differ from solar abundance ratios and are several orders of magnitude higher than predicted for equilibrium distribution between metal/silicate (core‐mantle). The samples are characterized by a mean Ca/Al ratio of 1.18 ± 0.09 σ_M and a mean Ca/Si ratio of 0.10 ± 0.01 σ_M, overlapping with a mean Ca/Al of 1.069 ± 0.044 σ_M and a mean Ca/Si of 0.081 ± 0.023 σ_M found in chondrites (Wasson and Kallemeyn 1988). Interestingly, the CI‐normalized abundance pattern shows decreasing solar system normalized abundances with increasing condensation temperatures. The abundance of the moderately volatile element Pd is about 2x higher than those in the most refractory siderophiles Ir and Os. Thus, the HSE systematics of upper mantle samples suggest that the late bombardment, which added these elements to the accreting Earth, more closely resembles materials of highly reduced EH or EL chondrites than carbonaceous chondrites. In fact, the HSE in the Earth mantle are even more fractionated than the enstatite chondrites—an indication that some inner solar system materials were more highly fractionated than the latter.     

Length of the day and evolution of the Earth's core in the geological past

In this paper, we study quantitatively the effect of the Earth's core formation on the secular rate of change of the length of day (LOD). We find that for the present epoch, a growth rate of the core comprised between 1 and 10 mm/cy seems to be a plausible guess, leading to a relative de crease of LOD comprised roughly between 10 and 100 μs/cy. Such values do not affect significantly the observed secular in crease of LOD caused by tidal braking, which amounts to about 1.79 ms/cy. However, in the remote geological past, before the Phanerozoic, the effects of core growth may have been much more important, because the total change of LOD associated with core formation has been estimated by Birch in 1965 to be 2.4 hours for an initially undifferentiated cold Earth, and 3.1 hours for an initially undifferentiated hot Earth. We consider a number of scenarios, some of them corresponding to very early and/or very fast core formation, others corresponding to slow and/or late core formation. We show that palaeo‐LOD measurements seem to favour slow core formation during the Proterozoic, contrarily to the now largely prevailing hypothesis based on geochemical arguments that the iron core formed very early in the Earth's history and during a geologically short time interval (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Theoretische Betrachtungen zum Verhalten des Magnetfeldes in einem sphärischen Erdmodell

The theoreticl treatment of several geophysical problems presupposes the solution of field equations of the magnetic field in the Earth's mantle. The field equations are given in a scalar form for a spherical model of the Earth. It will be shown that analytical solutions are possible in all cases. The boundary conditions are discussed with regard to the dynamo process in the Earth's core and the existence of a field representation, which is investigated on the Earth's surface. The question is discussed, to what extend the mantle's field is given by this field representation, when some special assumptions about the Earth's model are made.     

Nitrogen and noble gases in micrometeorites

Abstract— Micrometeorites (MMs) currently represent the largest steady‐state mass flux of extraterrestrial matter to Earth and may have delivered a significant fraction of volatile elements and organics to the Earth's surface. Nitrogen and noble gases contents and isotopic ratios have been measured in a suite of 17 micrometeorites recovered in Antarctica (sampled in blue ice at Cap Prudhomme) and Greenland (separated from cryoconite) that have experienced variable thermal metamorphism during atmospheric entry. MMs were pyrolized using a CO₂ laser and the released gases were analyzed for nitrogen and noble gas abundances and isotopic ratios by static mass spectrometry after specific purification. Noble gases are a mixture of cosmogenic, solar, atmospheric, and possibly chondritic components, with atmospheric being predominant in severely heated MMs. δ¹⁵N values vary between ?240 ± 62‰ and +206 ± 12‰, with most values being within the range of terrestrial and chondritic signatures, given the uncertainties. Crystalline MMs present very high noble gas contents up to two orders of magnitude higher than carbonaceous chondrite concentrations. In contrast, nitrogen contents between 4 ppm and 165 ppm are much lower than those of carbonaceous chondrites, evidencing either initially low N content in MMs and/or degradation of phases hosting nitrogen during atmospheric entry heating and terrestrial weathering. Assuming that the original N content of MMs was comparable to that of carbonaceous chondrites, the contribution of nitrogen delivery by these objects to the terrestrial environment would have been probably marginal from 3.8 Gyr ago to present but could have been significant (?10%) in the Hadean, and even predominant during the latest stages of terrestrial accretion.     

Nanophase magnetite in matrix of anomalous EL3 chondrite Northwest Africa (NWA) 8785

NWA 8785 is a remarkable EL3 chondrite with a high abundance (~34 vol%) of an Fe-rich matrix. This is the highest matrix abundance known among enstatite chondrites (ECs) and more similar to the matrix abundances in some carbonaceous and Rumuruti chondrites. X-ray diffraction and TEM data indicate that the fine-grained portion of the NWA 8785 matrix consists of nanoscale magnetite mixed with a noncrystalline silicate material and submicron-sized enstatite and plagioclase grains. This is the first report of magnetite nanoparticles in an EL3. The Si content of the metal (0.7 wt%), presence of ferroan alabandite, and its O isotopic composition indicate NWA 8785 is EL3-related. Having more abundant matrix than in other ECs, and that the matrix is rich in magnetite nanoparticles, which are not present in any other EC, suggest classification as an EL3 anomalous. Although we cannot completely exclude any of the mechanisms or environments for formation of the magnetite, we find a secondary origin to be the most compelling. We suggest that the magnetite formed due to hydrothermal activity in the meteorite parent body. Although ECs are relatively dry and likely formed within the nebular snow line, ices may have drifted inward from just beyond the snow line to the region where the EL chondrites were accreting, or more likely the snow line migrated inward during the early evolution of the solar system. This may have resulted in the condensation of ices and provided an ice-rich region for accretion of the EL3 parent body. Thus, the EL3 parent body may have had hydrothermal activity and if Earth formed near the EC accretion zone, similar bodies may have contributed to the Earth's water supply. NWA 8785 greatly extends the range of known characteristics of ECs and EC parent body processes.     

Itqiy: A study of noble gases and oxygen isotopes including its terrestrial age and a comparison with Zakłodzie

Abstract— We report noble gas, oxygen isotope, ¹⁴C and ¹⁰Be data of Itqiy as well as noble gas, ¹⁴C and ¹⁰Be results for Zak?odzie. Both samples have been recently classified as anomalous enstatite meteorites and have been compared in terms of their mineralogy and chemical composition. The composition of enstatite and kamacite and the occurrence of specific sulfide phases in Itqiy indicate it formed under similar reducing conditions to those postulated for enstatite chondrites. The new results now seem to point at a direct spatial link. The noble gas record of Itqiy exhibits the presence of a trapped subsolar component, which is diagnostic for petrologic types 4–6 among enstatite chondrites. The concentration of radiogenic ⁴He is very low in Itqiy and indicates a recent thermal event. Its ²¹Ne cosmic‐ray exposure age is 30.1 ± 3.0 Ma and matches the most common age range of enstatite chondrites (mostly EL6 chondrites) but not that of Zak?odzie. Itqiy's isotopic composition of oxygen is in good agreement with that observed in Zak?odzie as well as those found in enstatite meteorites suggesting an origin from a common oxygen pool. The noble gas results, on the other hand, give reason to believe that the origin and evolution of Itqiy and Zak?odzie are not directly connected. Itqiy's terrestrial age of 5800 ± 500 years sheds crucial light on the uncertain circumstances of its recovery and proves that Itqiy is not a modern fall, whereas the ¹⁴C results from Zak?odzie suggest it hit Earth only recently.     

Clues on the importance of comets in the origin and evolution of the atmospheres of Titan and Earth

Earth and Titan are two planetary bodies formed far from each other. Nevertheless the chemical composition of their atmospheres exhibits common indications of being produced by the accretion, plus ulterior in-situ processing of cometary materials. This is remarkable because while the Earth formed in the inner part of the disk, presumably from the accretion of rocky planetesimals depleted in oxygen and exhibiting a chemical similitude with enstatite chondrites, Titan formed within Saturn's sub-nebula from oxygen- and volatile-rich bodies, called cometesimals. From a cosmochemical and astrobiological perspective, the study of the H, C, N, and O isotopes on Earth and Titan could be the key to decipher the processes occurred in the early stages of formation of both planetary bodies. The main goal of this paper is to quantify the presumable ways of chemical evolution of both planetary bodies, in particular the abundance of CO and N₂ in their early atmospheres. In order to do that the primeval atmospheres and evolution of Titan and Earth have been analyzed from a thermodynamic point of view. The most relevant chemical reactions involving these species and presumably important at their early stages are discussed. Then, we have interpreted the results of this study in light of the results obtained by the Cassini–Huygens mission on these species and their isotopes. Given that H, C, N, and O were preferentially depleted from inner disk materials that formed our planet, the observed similitude of their isotopic fractionation, and subsequent close evolution of Earth's and Titan's atmospheres points towards a cometary origin of Earth atmosphere. Consequently, our scenario also supports the key role of late veneers (comets and water-rich carbonaceous asteroids) enriching the volatile content of the Earth at the time of the late heavy bombardment of terrestrial planets.     

Interrelationships among meteoric metals,meteors, interplanetary dust,micrometeorites, and meteorites

Abstract— Meteor science, aeronomy, and meteoritics are different disciplines with natural interfaces. This paper is an effort to integrate the chemistry and mineralogy of collected interplanetary dust particles (IDPs), micrometeorites, and meteorites with meteoric data and with atmospheric metal abundances. Evaporation, ablation, and melting of decelerating materials in the Earth's atmosphere are the sources of the observed metal abundances in the upper atmosphere. Many variables ultimately produce the materials and phenomena we can analyze, such as different accretion and parent‐body histories of incoming extraterrestrial materials, different interactions of meteors with the Earth's middle atmosphere, meteor data reduction, and complex chemical interactions of the metals and ions with the ambient atmosphere. The IDP‐like and unequilibrated ordinary chondrite matrix materials are reasonable sources for observed meteoric and atmospheric metals. The hypothesis of hierarchical dust accretion predicts that low, correlated refractory element abundances in cometary meteors may be real. It implies that the CI or cosmic standard is not useful to appreciate the chemistry of incoming petrologically heterogeneous cometary matter. The quasi steady‐state metal abundances in the lower thermosphere and upper mesosphere are derived predominantly from materials with cometary orbital characteristics and velocities such as comets proper and near‐Earth asteroids. The exact influence of atmospheric chemistry on these abundances still needs further evaluation. Metal abundances in the lower mesosphere and upper stratosphere region are mostly from materials from the asteroidal belt and the Kuiper belt.     

Niobium and tantalum in carbonaceous chondrites: Constraints on the solar system and primitive mantle niobium/tantalum,zirconium/niobium,and niobium/uranium ratio

Abstract— We have determined Nb, Y, and Zr abundances in the carbonaceous chondrites Orgueil (CI), Murray (CM2), Murchison (CM2), Allende (CV3), and Karoonda (CK4), and in the eucrites, Pasamonte and Juvinas, by a recently developed spark source mass spectrometric technique using multiple ion counting (MIC‐SSMS). The abundance of Ta was determined in the same meteorites by radiochemical neutron activation analysis (RNAA). Precision of the MIC‐SSMS and RNAA techniques is ～3% and ≤ 5%, respectively. The new abundances for CI chondrites are: Nb = 0.247, Ta = 0.0142, Zr = 3.86, Y = 1.56 μg/g; or 0.699, 0.0202, 11.2, and 4.64 atoms/10⁶ Si atoms, respectively. The values agree with earlier compilations, but they are a factor of 2 more precise than earlier analyses. Trace element concentrations in the CM, CV, and CK chondrites are higher than in the CI chondrite Orgueil by about 37, 86, and 120%, respectively, in agreement with the variable absolute contents of refractory lithophile elements in different groups of carbonaceous chondrites. Of particular interest are the chondritic Nb/Ta, Zr/Nb, and Nb/U ratios, because these ratios are important tools for interpreting the chemical evolution of planetary bodies. We obtained Nb/Ta = 17.4 ± 0.5 for the carbonaceous chondrites and the Juvinas‐type eucrites investigated. Though this value is similar to previous estimates, it is much more precise. The same is true for Zr/Nb (15.5 ± 0.2) and Zr/Y (2.32 ± 0.12). In combination with recently published MIC‐SSMS U data for carbonaceous chondrites, we obtained a chondritic Nb/U ratio of 29 ± 2. Because Nb, Ta, Zr, Y, and U are refractory lithophile elements and presumably partitioned into the silicate phase of the Earth during core formation, the elemental ratios may also be used to constrain evolution of the Earth's primitive mantle and, with the more precise determinations fractionation of Nb and Ta during magmatic processes and mantle‐crust interactions, can now be interpreted with greater confidence.     

Ice clathrate as a possible source of the atmospheres of the terrestrial planets

The presence and compositions of atmospheres on the terrestrial planets do not follow directly from condensation models which would have Earth accreting near 500°K. No single mechanism yet proposed adequately accounts for the abundances of noble gases and carbon and nitrogen in the atmospheres. We show that the composition of clathrates forming at low temperatures in cold regions of the nebula can be predicted. Addition of about 1 ppm clathrate material to the Earth can explain observed abundances of Ar, Kr, and Xe. Condensation and adsorption processes occuring at 400–500°K are necessary to explain the observed abundances of Ne, H₂O, C, and N. Possible sources of clathrates could be cometary bodies formed in the outer solar system.     

Effect of silicon on activity coefficients of Bi,Cd, Sn,and Ag in liquid Fe‐Si,and implications for differentiation and core formation

The depletion of volatile siderophile elements (VSE) Sn, Ag, Bi, Cd, and P in mantles of differentiated planetary bodies can be attributed to volatile‐depleted precursor materials (building blocks), fractionation during core formation, fractionation into and retention in sulfide minerals, and/or volatile loss associated with magmatism. Quantitative models to constrain the fractionation due to core formation have not been possible due to the lack of activity and partitioning data. Interaction parameters in Fe‐Si liquids have been measured at 1 GPa, 1600 °C and increase in the order Cd (~6), Ag (~10), Sn (~28), Bi (~46), and P (~58). These large and positive values contrast with smaller and negative values in Fe‐S liquids indicating that any chalcophile behavior exhibited by these elements will be erased by dissolution of a small amount of Si in the metallic liquid. A newly updated activity model is applied to Earth, Mars, and Vesta. Five elements (P, Zn, Sn, Cd, and In) in Earth's primitive upper mantle can largely be explained by metal‐silicate equilibrium at high PT conditions where the core‐forming metal is a Fe‐Ni‐S‐Si‐C metallic liquid, but two other—Ag and Bi—become overabundant during core formation and require a removal mechanism such as late sulfide segregation. All of the VSE in the mantle of Mars are consistent with core formation in a volatile element depleted body, and do not require any additional processes. Only P and Ag in Vesta's mantle are consistent with combined core formation and volatile‐depleted precursors, whereas the rest require accretion of chondritic or volatile‐bearing material after core formation. The concentrations of Zn, Ag, and Cd modeled for Vesta's core are similar to the concentration range measured in magmatic iron meteorites indicating that these volatile elements were already depleted in Vesta's precursor materials.     

Evidence in a glassy cosmic spherule from Antarctica for grazing incidence encounters with the Earth's atmosphere

Abstract— Cosmic dust accreted by the Earth can be extensively reprocessed during atmospheric encounters. The textures and compositions of reprocessed material provide important constraints by which the processes affecting extraterrestrial matter in the Earth's atmosphere can be better understood. Here we report results on an unusual Antarctic glassy cosmic spherule that demonstrates strong textural evidence for at least two grazing incidence encounters with the Earth's atmosphere prior to final reentry. The particle consists of a central glassy core with four peripheral glass lobes that transect a silicate particle rim. The texture of the particle confirms previous theoretical speculations that some high velocity, low incidence angle interplanetary particles experience numerous encounters with the Earth's atmosphere and also indicates that micrometeorites demonstrating multiple melting episodes should be interpreted with caution.     

On some aspects of the albedo effect application to the ERS-1 satellite

Some aspects of the perturbative influence of radiation reflected by the Earth's surface on the motion of an artificial satellite are discussed. We concentrate on consequences of the extreme models with anisotropic reflection on the Earth's surface (specular reflection, clouds with anisotropic phase function). The possible effects of Lála's modification of the Earth's albedo nominal value are investigated. The role of the satellite surface optical properties is pointed out in the context of the albedo effect. All mentioned models are purely numerical. The whole message of the paper can be summarized in the following items

-It is very doubtful that the 10^?8 ÷ 10^?9 m s^?2 level is reached when determining the perturbing accelerations caused by the albedo effect in the case of the ERS-1 satellite due to poorly defined optical characteristics of the Earth's atmosphere, the Earth and the satellite's surface.

-In the general case this albedo effect uncertainty level is about 50% with respect to the averaged values, and probably as high as 100% with respect to the instantaneous values of the perturbing accelerations.

     

Trace elements in mineral separates of the Peña Blanca Spring aubrite: Implications for the evolution of the aubrite parent body

Abstract— The origin of the aubrite parent body (APB) and its relation to the enstatite chondrites is still unclear. Therefore we began a detailed chemical study of the aubrite Peña Blanca Spring. Bulk samples and mineral separates (oldhamite, troilite, alabandite, pyroxene) of Peña Blanca Spring were analyzed for major and trace elements by instrumental neutron activation analysis (INAA). In addition, a leaching experiment was performed on a powdered bulk sample to study the distribution of trace elements in aubrite minerals. The elemental abundances in Peña Blanca Spring are compared to abundances in EH-chondrites and EL-chondrites in an attempt to distinguish volatility related fractionations (evaporation, condensation) from planetary differentiation (melting and core formation). Low abundances of siderophile (e.g., Ir) and chalcophile (e.g., V) elements in bulk samples indicate that 25% (by mass) metal and about 6% (by mass) sulfide separated from an enstatite chondrite like-parent body to form a core and a residual mantle with aubrite composition. We argue that the high observed rare earth element (REE) abundances in oldhamite (>100 × EH-chondrite normalized) reflect REE incorporation into oldhamite during nebular condensation. Thus, oldhamite in aubrites is, at least in part, a relict phase as originally proposed by Lodders and Palme (1990). Some re-equilibration of CaS with silicates has, however, occurred, leading to partial redistribution of REE, as exemplified by the uptake of Eu by plagioclase. The distribution of the REE among aubritic minerals cannot be the result of fractional crystallization, which would occur if high degrees of partial melting took place on the APB. Instead, the REE distributions indicate incomplete equilibrium of oldhamite and other phases. Therefore, a short non-equlibrium melting episode led to segregation of metal and sulfides.     

VANADIUM AND COPPER IN CHONDRITES

Emission spectrographic analyses for vanadium and copper in sixty-seven chondritic meteorites including members from ordinary, carbonaceous, and enstatite chondrite groups give a total range of 41–84 ppm vanadium and a total range of 77–180 ppm copper. The respective average values are 61 ± 7 ppm and 115 ± 12 ppm. Detailed patterns of vanadium and copper distributions between different chondrite groups are discussed in light of recent mechanisms for chemical fractionations in meteorites     

The solution for seasonal variations in the Earth's rate of rotation

New physical principles for an explanation of seasonal variations in the Earth's rate of rotation are proposed. It is thought that the variations are caused by a variation of the total energy of the Earth's atmosphere in the course of the planet's revolution about the Sun in elliptic orbit. Jacobi's virial equation for the Earth's atmosphere is derived from the Eulerian equations. The virial theorem is obtained. The existence of the relationship between Jacobi's function and potential energy of the atmosphere is confirmed. In the framework of this relationship, Jacobi's equation is reduced to the equation of unperturbed virial oscillations. The solution of the above-mentioned equation expresses the periodic virial oscillations of Jacobi's function (moment of inertia) of the Earth's atmosphere with time. The solution of the perturbed virial oscillation problem of the atmosphere-solid Earth system is obtained. The perturbation term in Jacobi's virial equation regards, in explicit form, the energy changes occurring in the atmosphere in the course of the planet's revolution about the Sun in elliptic orbit. The annual and semi-annual periodic variations in the Earth's rate of rotation can be considered as an astrometrical result following from the obtained solution. A satisfactory accord of the theoretical results with experimental data is shown.     

Magnetization of celestial bodies with special application to the primeval Earth and Moon

The magnetic fields of celestial bodies are usually supposed to be due to a ‘hydromagnetic dynamo’. This term refers to a number of rather speculative processes which are supposed to take place in the liquid core of a celestial body. In this paper we shall follow another approach which is more closely connected with hydromagnetic processes well-known from the laboratory, and hence basically less speculative. The paper should be regarded as part of a general program to connect cosmical phenomena with phenomena studied in the laboratory. As has been demonstrated by laboratory experiments, a poloidal magnetic field may be increased by the transfer of energy from a toroidal magnetic field through kink instability of the current system. This mechanism can be applied to the fluid core of a celestial body. Any differential rotation will produce a toroidal field from an existing poloidal field, and the kink instability will feed toroidal energy back to the poloidal field, and hence amplify it. In the Earth-Moon system the tidal braking of the Earth's mantle acts to produce a differential angular velocity between core and mantle. The braking will be transferred to the core by hydromagnetic forces which at the same time give rise to a strong magnetic field. The strength of the field will be determined by the rate of tidal braking. It is suggested that the magnetization of lunar rocks from the period ?4 to ?3 Gyears derives from the Earth's magnetic field. As the interior of the Moon immediately after accretion probably was too cool to be melted, the Moon could not produce a magnetic field by hydromagnetic effects in its core. The observed lunar magnetization could be produced by such an amplified Earth field even if the Moon never came closer than 10 or 20 Earth's radii. This hypothesis might be checked by magnetic measurements on the Earth during the same period.     

Discovery of Earth's quasi‐satellite

Abstract— The newly discovered asteroid 2003 YN₁₀₇ is currently a quasi‐satellite of the Earth, making a satellite‐like orbit of high inclination with apparent period of one year. The term quasi‐satellite is used since these large orbits are not completely closed, but rather perturbed portions of the asteroid's orbit around the Sun. Due to its extremely Earth‐like orbit, this asteroid is influenced by Earth's gravity to remain within 0.1 AU of the Earth for approximately 10 years (1997 to 2006). Prior to this, it had been on a horseshoe orbit closely following Earth's orbit for several hundred years. It will re‐enter such an orbit, and make one final libration of 123 years, after which it will have a close interaction with the Earth and transition to a circulating orbit. Chaotic effects limit our ability to determine the origin or fate of this object.     

The Chinese comet observation in AD 773 January

The strong ¹⁴C increase in the year AD 774/5 detected in one German and two Japanese trees was recently suggested to have been caused by an impact of a comet onto Earth and a deposition of large amounts of ¹⁴C into the atmosphere (Liu et al. 2014). The authors supported their claim using a report of a historic Chinese observation of a comet ostensibly colliding with Earth's atmosphere in AD 773 January. We show here that the Chinese text presented by those authors is not an original historic text, but that it is comprised of several different sources. Moreover, the translation presented in Liu et al. is misleading and inaccurate. We give the exact Chinese wordings and our English translations. According to the original sources, the Chinese observed a comet in mid January 773, but they report neither a collision nor a large coma, just a long tail. Also, there is no report in any of the source texts about “dust rain in the daytime” as claimed by Liu et al. (2014), but simply a normal dust storm. Ho (1962) reports sightings of this comet in China on AD 773 Jan 15 and/or 17 and in Japan on AD 773 Jan 20 (Ho 1962). At the relevant historic time, the Chinese held that comets were produced within the Earth's atmosphere, so that it would have been impossible for them to report a “collision” of a comet with Earth's atmosphere. The translation and conclusions made by Liu et al. (2014) are not supported by the historical record. Therefore, postulating a sudden increase in ¹⁴C in corals off the Chinese coast precisely in mid January 773 (Liu et al. 2014) is not justified given just the ²³⁰Th dating for AD 783 ± 14. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)