Evidence for a very high carbon/iridium ratio in the Tunguska impactor

Abstract— We have measured excess Ir and depletion of ¹⁴C, two independent indicators of cosmic material, in peat cores from the central Tunguska impact site. Both Ir and ¹⁴C show pronounced anomalies in the same stratigraphical depth interval. We have estimated an integral deposition of nonradioactive cosmogenic C of 6.8 ± 1.0 mg C cm^?2, and an integrated Ir deposition of 5.9 ± 1.2 pg Ir cm^?2. The very high C/Ir ratio and a deduced δ¹³C value of +55 ± 10% relative to V Pee Dee Belemnite (VPDB) of the impactor material found in this study points towards a cometary type impactor, rather than a chondritic or achondritic asteroidal type impactor.     

Traces of cometary material in the area of the Tunguska impact (1908)

A short overview of the studies of the authors and their colleagues performed over many years, which resulted in the discovery of traces of cometary matter in the peat at the epicenter of the Tunguska catastrophe in 1908, is given here. In the epicenter of the Tunguska cosmic body (TCB) explosion, the shifts in the isotopic composition of hydrogen and carbon relative to their values for the upper and lower layers of the same column were found in the catastrophic layers of peat grown up in 1908. These shifts cannot be attributed to any known terrestrial processes: the conservation of mineral and organic dust in peat, peat humification, the emission of hydrocarbon gases from the Earth, climate changes, and other physical and chemical processes. In the catastrophic layers of the control peat columns, the isotopic shifts are absent. The isotopic data agree well with the increased concentration of iridium and other platinum-group elements in the same peat layers, which is a reliable indicator of the presence of cosmic material in terrestrial objects. The cosmogenic character of the isotopic effects is confirmed by the presence of “dead” carbon (not containing radioactive ¹⁴C) in the catastrophic layers. To provide the shifts observed in the isotopic composition of carbon, cosmic carbon preserved in peat should be isotopically superheavy—from +50‰ to +60‰ according to calculations. Such isotopically heavy carbon is absent both on the Earth and in ordinary meteorites. It occurs only in individual mineral phases of CI carbonaceous chondrites, close to cometary dust in chemical composition, ratios of the content of iridium and other platinoids and rear-earth elements also points to the cometary nature of the TCB. In the near-catastrophic peat layers, the anomalous increase of the concentration of many volatiles was detected, which also suggests that the TCB was a cometary core. The studies of the content and the isotopic composition of nitrogen in the peat revealed traces of heavy acid rains induced by the flyby and explosion of the TCB.     

Nitrate in the Greenland ice sheet in the years following the 1908 tunguska event

The Tunguska event on 30 June 1908 has been subjected to much speculation within different fields of research. Publication of the results of the 1961 expedition to the Tunguska area (Florensky, 1963) supports that a cometary impact caused the event. Based on this interpretation, calculations of the impactor energy release and explosion height have been reported by Ben-Menahem (1975), and velocity, mass, and density of the impactor by Petrov and Stulov (1975). Park (1978) and Turco et al., 1981, Turco et al., 1982, used these numbers to calculate a production of ca. 30 × 10⁶ tons of NO during atmospheric transit. This paper presents a high-resolution study of nitrate concentration in the Greenland ice sheet in ca. 10 years covering the Tunguska event. No signs of excess nitrate are found in three ice cores from two different sites in Greenland in the years following the Tunguska event. By comparing these results with results for other aerosols generally found in the ice, the lack of excess NO₃^? following the Tunguska event can be interpreted as indicating that the impactor nitrate production calculated by Park (1978) and Turco et al., 1981, Turco et al., 1982 are 1–2 orders of magnitude too high. To explain this it is suggested, from other lines of reasoning, that the impactor density determined by Petrov and Stulov (1975) probably is too low.     

Compositional anomaly of Ganymede and Callisto among the ice satellites as inferred from impact crater morphology

Differences in crater morphology between the Jovian and Saturnian-Uranian ice satellites implies a weaker surface strength for Ganymede and Callisto and thus a more concentrated composition of water. This compositional anomaly among the ice satellites is apparently due to a more complete migration of heavy material toward the inner part of the pre-planetary disc of the Jovian system than occurred in the discs of the Saturnian and Uranian systems.     

Alkali elements in the Earth's core: Evidence from enstatite meteorites

Abstract— The abundances of alkali elements in the Earth's core are predicted by assuming that accretion of the Earth started from material similar in composition to enstatite chondrites and that enstatite achondrites (aubrites) provide a natural laboratory to study core-mantle differentiation under extremely reducing conditions. If core formation on the aubrite parent body is comparable with core formation on the early Earth, it is found that 2600 (±1000) ppm Na, 550 (±260) ppm K, 3.4 (±2.1) ppm Rb, and 0.31 (±0.24) ppm Cs can reside in the Earth's core. The alkali-element abundances are consistent with those predicted by independent estimates based on nebula condensation calculations and heat flow data.     

Element composition of dust from a shallow Dunde ice core, Northern China

The Dunde ice cap (38°06'N, 96°24'E, with a summit of 5325 m) is situated at the centre of the northern Chinese deserts and receives dust from these regions. Here, we present the trace and rare earth element (REE) compositions of dust extracted from a shallow ice core from the Dunde ice cap, which provide a framework to trace the source of Dunde dust. Trace and REE parameters of Dunde dust show characteristics of a typical eolian deposit, with an average La/Th ratio of 2.6, a Th/U ratio of 3.7, and a strong negative Eu anomaly (0.61). The dirty layers in the ice core section have the same element characteristics as in the clear layers, indicating that the dust in Dunde is well-mixed and has a stable composition. Trace element and REE ratio plots show that Dunde dust has a similar composition to the finer fraction materials in the Taklimakan desert, suggesting that the Tarim Basin might be an important source for Dunde dust under the present circulation, but not favoring a material contribution from Badain Jaran. Our results reveal distinct differences in composition between Dunde dust and Chinese loess materials, which suggests that they have different sources.     

Impact melt rocks from the Late Paleocene Hiawatha impact structure,northwest Greenland

Impact melt rocks formed during hypervelocity impact events are ideal for studying impact structures. Here, we describe impact melt rock samples collected proximal to the 31 km wide 58 Ma Hiawatha impact structure, northwest Greenland, which is completely covered by the Greenland Ice Sheet. The melt rocks contain diagnostic shock indicators (e.g., planar deformation features [PDF] in quartz and shocked zircon) and form three groups based on melt textures and chemistry: (i) hypocrystalline, (ii) glassy, and (iii) carbonate-based melt rocks. The exposed foreland directly in front of the structure consists of metasedimentary successions and igneous plutons; however, the carbonate-based impactites indicate a mixed target sequence with a significant carbonate-rich component. Well-preserved organic material in some melt rocks indicates that North Greenland at the time of impact was host to abundant organic material, likely a dense high-latitude temperate forest. Geochemical signatures of platinum-group elements in selected samples indicate an extraterrestrial component and support previous identification of a highly fractionated iron impactor in glaciofluvial sand. Our results illustrate the possibility to study impact structures hidden beneath a thick ice sheet based on transported samples and this opens a new avenue for identifying other potential impact craters in Greenland and Antarctica.     

Discovery of probable Tunguska cosmic body material: anomalies of platinum group elements and rare-earth elements in peat near the Explosion Site (1908)

Ten Sphagnum fuscum peat samples collected from different depths of a core including the layer affected by the 1908 Tunguska explosion in the Tunguska area of Central Siberia, Russia, were analyzed by ICP-MS to determine the concentrations of Pd, Rh, Ru, Co, REE, Y, Sr, and Sc. The analytical results indicate that the Pd and Rh concentrations in the event- and lower layers were 14.0–19.9, and 1.23–1.56 ppb, respectively, about 3–9 times and 3 times higher than the background values in the normal layers. In addition, the patterns of CI-chondrite-normalized REE in the event layers were much flatter than in the normal layers, and differed from those in the nearby traps. Hence, it can be inferred from the characteristics of the elemental geochemistry that the explosion was probably associated with extraterrestrial material, and which, most probably, was a small comet core the dust fraction of which was chemically similar to carbonaceous chondrites (CI). In terms of the Pd and REE excess fluxes in the explosion area, it can be estimated that the celestial body that exploded over Tunguska in 1908 weighed more than 10⁶ t, corresponding to a radius of >60 m. If the celestial body was a comet, then its total mass was more than 2×10⁷ t, and it had >160 m radius, and released an energy of >10⁷ t TNT.     

Polar wander of Mars: Evidence from giant impact basins

We investigate the polar wander of Mars in the last ∼4.2 Ga. We identify two sets of basins from the 20 giant impact basins reported by Frey [Frey, H., 2008. Geophys. Res. Lett. 35, L13203] which trace great circles on Mars, and propose that the great circles were the prevailing equators of Mars at the impact times. Monte Carlo tests are conducted to demonstrate that the two sets of basins are most likely not created by random impacts. Also, fitting 63,771 planes to randomly selected sets of 5, 6, or 7 basins indicated that the identified two sets are unique. We propose three different positions for the rotation pole of Mars, besides the present one. Accordingly, Tharsis bulge was initially formed at ∼50 N and moved toward the equator while rotating counterclockwise due to the influence of the two newly forming volcanic constructs, Alba Patera and Elysium Rise. The formation of the giant impact basins, subsequent mass concentrations (mascons) in Argyre, Isidis, and Utopia basins, and surface masses of volcanic mountains such as Ascraeus, Pavonis, Arsia and Olympus, caused further polar wander which rotated Tharsis bulge clockwise to arrive at its present location. The extensive polar motion of Mars during 4.2-3.9 Ga implies a weak lithosphere on a global scale, deduced from a total of 72,000 polar wander models driven by Tharsis bulge, Alba Patera and Elysium Rise as the major mass perturbations. Different compensation states, 0-100%, are examined for each of the surface loads, and nine different thicknesses are considered for an elastic lithosphere. The lithosphere must have been very weak, with an elastic thickness of less than 5 km, if the polar wander was driven by these mass perturbations.     

Evidence for shock‐induced anhydrite recrystallization and decomposition at the UNAM‐7 drill core from the Chicxulub impact structure

Drill core UNAM‐7, obtained 126 km from the center of the Chicxulub impact structure, outside the crater rim, contains a sequence of 126.2 m suevitic, silicate melt‐rich breccia on top of a silicate melt‐poor breccia with anhydrite megablocks. Total reflection X‐ray fluorescence analysis of altered silicate melt particles of the suevitic breccia shows high concentrations of Br, Sr, Cl, and Cu, which may indicate hydrothermal reaction with sea water. Scanning electron microscopy and energy‐dispersive spectrometry reveal recrystallization of silicate components during annealing by superheated impact melt. At anhydrite clasts, recrystallization is represented by a sequence of comparatively large columnar, euhedral to subhedral anhydrite grains and smaller, polygonal to interlobate grains that progressively annealed deformation features. The presence of voids in anhydrite grains indicates SO_x gas release during anhydrite decomposition. The silicate melt‐poor breccia contains carbonate and sulfate particles cemented in a microcrystalline matrix. The matrix is dominated by anhydrite, dolomite, and calcite, with minor celestine and feldspars. Calcite‐dominated inclusions in silicate melt with flow textures between recrystallized anhydrite and silicate melt suggest a former liquid state of these components. Vesicular and spherulitic calcite particles may indicate quenching of carbonate melts in the atmosphere at high cooling rates, and partial decomposition during decompression at postshock conditions. Dolomite particles with a recrystallization sequence of interlobate, polygonal, subhedral to euhedral microstructures may have been formed at a low cooling rate. We conclude that UNAM‐7 provides evidence for solid‐state recrystallization or melting and dissociation of sulfates during the Chicxulub impact event. The lack of anhydrite in the K‐Pg ejecta deposits and rare presence of anhydrite in crater suevites may indicate that sulfates were completely dissociated at high temperature (T > 1465 °C)—whereas ejecta deposited near the outer crater rim experienced postshock conditions that were less effective at dissociation.     

Archaeabacterial lipids in drill core samples from the Bosumtwi impact structure,Ghana

Abstract— Meteorite impacts are associated with locally profound effects for microorganisms living at the terrestrial surface and the subsurface of the impact zone. The Bosumtwi crater in Ghana (West Africa) is a relatively young (1.07 Myr) structure with a rim‐to‐rim diameter of about 10.5 km. In a preliminary study targeting the subsurface microbial life in the impact structure, seven samples of the impact breccia from the central uplift of the Bosumtwi crater were analyzed for the presence of typical archaeal membrane‐lipids (GDGTs). These have been detected in four of the samples, at a maximum depth of 382 m below the lake surface, which is equivalent to 309 m below the surface sediment. The concentration of the GDGTs does not show a trend with depth, and their distribution is dominated by GDGT‐0. Possible origins of these lipids could be related to the soils or rocks predating the impact event, the hydrothermal system generated after the impact, or due to more recent underground water     

Shock-induced melting and vaporization of shatter cone surfaces: Evidence from the Sudbury impact structure

Abstract— Analytical scanning electron microscopy has been used to investigate the surface textures and compositions of newly exposed shatter cones from the 1.85 Ga Sudbury impact structure, Canada. Unusual surface microstructures are observed at the micron scale, including silicate melt smears, melt fibres and melt splats. Silicate and Ni-rich spherules up to 5 μm in diameter adorn earlier-formed surface features, and we interpret these to be condensates formed due to shock-induced vaporization of the shatter cone surfaces. The development of striations on the shatter cones is attributed to shock-related fracture and slip. Formation of melts and spherules indicates that the highest ranks of shock metamorphism (Stages IV and V) were realized, but only on a very localized scale. Shatter cone surfaces are, therefore, likely sites for the development of high-pressure polymorphs and, if the chemistry is appropriate, fullerenes. As such, they may be equivalent to “Type A” pseudotachylytes and shock veins in meteorites.     

Shock metamorphism and impact melting in small impact craters on Earth: Evidence from Kamil crater,Egypt

Kamil is a 45 m diameter impact crater identified in 2008 in southern Egypt. It was generated by the hypervelocity impact of the Gebel Kamil iron meteorite on a sedimentary target, namely layered sandstones with subhorizontal bedding. We have carried out a petrographic study of samples from the crater wall and ejecta deposits collected during our first geophysical campaign (February 2010) in order to investigate shock effects recorded in these rocks. Ejecta samples reveal a wide range of shock features common in quartz‐rich target rocks. They have been divided into two categories, as a function of their abundance at thin section scale: (1) pervasive shock features (the most abundant), including fracturing, planar deformation features, and impact melt lapilli and bombs, and (2) localized shock features (the least abundant) including high‐pressure phases and localized impact melting in the form of intergranular melt, melt veins, and melt films in shatter cones. In particular, Kamil crater is the smallest impact crater where shatter cones, coesite, stishovite, diamond, and melt veins have been reported. Based on experimental calibrations reported in the literature, pervasive shock features suggest that the maximum shock pressure was between 30 and 60 GPa. Using the planar impact approximation, we calculate a vertical component of the impact velocity of at least 3.5 km s^?1. The wide range of shock features and their freshness make Kamil a natural laboratory for studying impact cratering and shock deformation processes in small impact structures.     

Crater modification and geologic activity in Enceladus' heavily cratered plains: Evidence from the impact crater distribution

Although we can observe current activity on Saturn's satellite Enceladus with Cassini, insight into past activity is best achieved (for now) through studying the impact crater distributions. Furthermore, approximation of terrain ages can only be attained through calculations using crater densities and estimations of impact rates in the saturnian system. Here we focus on what the impact crater distribution in Enceladus' heavily cratered plains can tell us about Enceladus' geologic history. We use Cassini ISS images to count craters in the heavily cratered plains on Enceladus, along with Rhea, Dione, Tethys and Mimas as references, to develop and compare their size-frequency distributions. Comparisons of our counts show that Enceladus' cratered plains distribution is unique in that it appears to have a relative deficiency of craters for diameters ?2 km and ?6 km compared to the other satellites' heavily cratered plains. Our data also indicates that the impact crater density within the cratered plains changes with latitude. Specifically, both the north and south mid-latitude regions have approximately three times higher density than the equatorial region. We hypothesize that the “missing” small and large craters in Enceladus' cratered plains is due to a combination of viscous relaxation of the larger craters, and burial of the relaxed large craters and small craters by south polar plume and possibly E-ring material. We also conclude that the spatial density distribution is not consistent with recent polar wander.     

Simulations of a comet impact on the Moon and associated ice deposition in polar cold traps

Modeling results of the water vapor plume produced by a comet impact on the Moon and of the resulting water ice deposits in the lunar cold traps are presented. The water vapor plume is simulated near the point of impact by the SOVA hydrocode and in the far field by the Direct Simulation Monte Carlo (DSMC) method using as input the SOVA hydrocode solution at a fixed hemispherical interface. The SOVA hydrocode models the physics of the impact event such as the surface deformation and material phase changes during the impact. The further transport and retention processes, including gravity, photodestruction processes, and variable surface temperature with local polar cold traps, are modeled by the DSMC method for months after impact. In order to follow the water from the near field of the impact to the full planetary induced atmosphere, the 3D parallel DSMC code used a collision limiting scheme and an unsteady multi-domain approach. 3D results for the 45° oblique impact of a 2 km in diameter comet on the surface of the Moon at 30 km/s are presented. Most of the cometary water is lost due to escape just after impact and only ∼3% of the cometary water is initially retained on the Moon. Early downrange focusing of the water vapor plume is observed but the later material that is moving more slowly takes on a more symmetric shape with time. Several locations for the point of impact were investigated and final retention rates of ∼0.1% of the comet mass were observed. Based on the surface area of the cold traps used in the present simulations, ∼1 mm of ice would have accumulated in the cold traps after such an impact. Estimates for the total mass of water accumulated in the polar cold traps over 1 byr are consistent with recent observations.     

Geochemistry of a confirmed Precambrian impact ejecta deposit: The Grænsesø spherule layer,South Greenland

Samples from a single outcrop of the Graenseso spherule layer, Midternaes, South Greenland, consist of a spherule‐bearing dolomixtite with matrix‐supported intraclasts up to 1 m in size. In addition to field observations, we performed mineralogical and whole rock geochemical analysis, including electron microprobe, neutron activation analysis, X‐ray fluorescence, and mass spectrometry of the horizon and the overlying and underlying strata. We show that the spherules are petrographically similar to those in the Zaonega spherule layer, Karelia, Russia. Our petrographic and chemical results are consistent with the previous suggestion that the Grænsesø layer correlates with the Zaonega layer, and it is possible that both layers are related to the Vredefort impact event. The samples containing spherules, as well as the overlying rocks, have elevated REEs compared to the underlying pre‐impact layer, suggestive of a new continental source of sediment that may be coincident with the impact event. Zircons separated from the lower part of the Grænsesø spherule layer display complex age patterns suggesting that they have genetically different origins based on distinctly different Th/U ratios. Crystallization ages of all groups are ≥ 2.8 Ga, with ~2.8 Ga representing a time of major crustal growth globally. Therefore, we cannot conclusively determine in this study if the zircons are locally derived or if they are transported with the ejecta. The spherule layer was deposited by a high‐energy, subaqueous debris flow, an origin that is consistent with the hypothesis that the layer was deposited by impact‐induced waves and/or currents.     

Bosumtwi impact structure,Ghana: Evidence for fluidized emplacement of the ejecta

The about 10.5 km diameter Bosumtwi impact crater is one of the youngest large impact structures on Earth. The crater rim is readily noticed on topographic maps or in satellite imagery. It defines a circular basin filled by water (Lake Bosumtwi) and lacustrine sediments. The morphology of this impact structure is also characterized by a circular plateau extending beyond the rim and up to 9–10 km from the center of the crater (about 2 crater radii). This feature comprises a shallow ring depression, also described as an annular moat, and a subdued circular ridge at its outer edge. The origin of this outermost feature could so far not be elucidated based on remote sensing data only. Our approach combines detailed topographic analysis, including roughness mapping, with airborne radiometric surveys (mapping near‐surface K, Th, U concentrations) and field observations. This provides evidence that the moat and outer ring are features inherited from the impact event and represent the partially eroded ejecta layer of the Bosumtwi impact structure. The characteristics of the outer ridge indicate that ejecta emplacement was not purely ballistic but requires ejecta fluidization and surface flow. The setting of Bosumtwi ejecta can therefore be considered as a terrestrial analog for rampart craters, which are common on Mars and Venus, and also found on icy bodies of the outer solar system (e.g., Ganymede, Europa, Dione, Tethys, and Charon). Future studies at Bosumtwi may therefore help to elucidate the mechanism of formation of rampart craters.     

Evidence for a spatially extensive hydrothermal system at the Ries impact structure,Germany

The ~15 Ma, 26 km diameter Ries impact structure in south‐central Germany was one of the first terrestrial impact structures where evidence of impact‐associated hydrothermal alteration was recognized. Previous studies suggested that pervasive, high‐temperature hydrothermal activity was restricted to the area within the “inner ring” (i.e., the crater‐fill impactite units). Here we present mineralogical evidence for localized hydrothermal activity in the ejecta beyond the crater rim in two previously unstudied settings: a pervasively altered lens of suevite ejecta directly overlying the Bunte Breccia at the Aumühle quarry; and suevite ejecta at depth overlain by ~20 m of lacustrine sediments sampled by the Wörnitzostheim 1965 drill core. A comprehensive set of X‐ray diffraction analyses indicates five distinct alteration regimes (1) surficial ambient weathering characterized by smectite and a minor illitic component; (2) locally restricted hydrothermal activity characterized by an illitic component and minor smectite; (3) hydrothermal activity at depth characterized by smectite, a minor illitic component, and calcite; (4) hydrothermal activity at depth characterized by smectite, a minor illitic component, calcite, zeolites, and clinochlore; and (5) pervasive hydrothermal activity at depth characterized by smectite, a minor illitic component, and minor clinochlore. These data spatially extend the Ries postimpact hydrothermal system suggesting a much more extensive, complex, and dynamic system than previously thought. Constraining the mineralogical alteration regimes at the Ries impact structure may also further our understanding of impact‐associated phyllosilicate formation on Mars with implications for climate models and habitability.     

Near-infrared identification of the counterpart to X1908+075: a new OB-supergiant X-ray binary

We report the near-infrared (near-IR) identification of the likely counterpart to X1908+075, a highly absorbed Galactic X-ray source recently suspected to belong to the rare class of OB supergiant–neutron star binary systems. Our JHK_s -band imaging of the field reveals the existence within the X-ray error boxes of a near-IR source consistent with an early-type star lying at   d ∼ 7 kpc  and suffering   A_V ∼ 16 mag  of extinction, the latter value being in good agreement with the hydrogen column density derived from modelling of the X-ray spectrum. Our follow-up, near-IR spectroscopic observations confirm the nature of this candidate and lead to a late O-type supergiant classification, thereby supporting the identification of a new Galactic OB-supergiant X-ray binary.     

Shock metamorphism investigations of quartz grains in clasts from impact breccia of the Eyreville B drill core,Chesapeake Bay impact structure,USA

Abstract– The Chesapeake Bay impact structure, approximately 85 km in diameter, has been drilled in 2005–2006 at Eyreville (Virginia, USA), to a total depth of 1766 m. In the drill cores, the abundance of shock metamorphosed material is very variable with depth. Shocked mineral and lithic clasts, as well as melt particles, are most abundant in suevitic impact breccia section (1397–1451 m depth). Shocked quartz (i.e., quartz grains with planar fractures and/or planar deformation features) and melt particles, although rare, are also dispersed in the Exmore Formation unit (444–867 m depth). Other lithologies in the Eyreville drill cores show no clear evidence of shock metamorphism. Here, we report on the investigations of 40 samples from the impact breccia section. A total of more than 27,000 quartz grains were examined in about 200 clasts. The abundance of highly shocked clasts tends to decrease with increasing depth. Crystalline clasts derived from the crystalline basement are commonly only slightly shocked (contain generally <10 rel% of shocked quartz grains). The clasts of metamorphosed sediments show a low proportion of shocked quartz grains (mostly <10 rel%). Sedimentary clasts show a wide range of proportions of shocked quartz grains, with several of them being highly shocked clasts (most values between 0 and 40 rel%). Conglomerates show the highest proportion of shocked quartz grains of all types of clasts (up to 83 rel%). Polycrystalline quartz clasts are also commonly highly shocked (contain mostly between 10 and 40 rel% of shocked quartz grains). These hard nonporous clasts are possibly more liable to show evidence of shock. The investigations suggest that the intensity of shock metamorphism is the result of several parameters, such as original position in the target (both horizontal and vertical) and the properties of each lithology (e.g., grain size, porosity, and amount of matrix). According to the universal‐stage investigations, the dominant orientations of planar deformation features in quartz are , , and also .