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1.
Abstract— The recovery of large numbers of meteorites from Antarctica has dramatically increased the amount of extraterrestrial material available for laboratory studies of solar system origin and evolution. Yet, the great age of Antarctic meteorites raises the concern that significant amounts of terrestrial weathering has corrupted their pre‐terrestrial record. Organic matter found in carbonaceous chondrites is one of the components most susceptible to alteration by terrestrial processes. To assess the effects of Antarctic weathering on both non‐Antarctic and Antarctic chondritic organic matter, a number of CM chondrites have been analyzed. Mössbauer spectroscopy has been used to ascertain pre‐terrestrial and terrestrial oxidation levels, while pyrolysis‐gas chromatography‐mass spectrometry was used to determine the constitution of any organic matter present. Increased oxidation levels for iron bearing minerals within the non‐Antarctic chondrites are likely to be a response to increased amounts of parent body aqueous alteration. Parent body processing also appears to remove ether bonds from organic material and alkyl side chains from its constituent units. The iron in Antarctic chondrites is generally more oxidized than that in their non‐Antarctic counterparts, reflecting terrestrial weathering. Antarctic weathering of chondritic organic matter appears to proceed in a similar way to parent body aqueous alteration and simply enhances the organic responses observed in the non‐Antarctic data set. Degradation of the record of preterrestrial processes in Antarctic chondrites should be taken into account when interpreting data from these meteorites.  相似文献   

2.
Some terrestrial areas have climatic and geomorphologic features that favor the preservation, and therefore, accumulation of meteorites. The Atacama Desert in Chile is among the most important of such areas, known as DCA. This desert is the driest on Earth, one of the most arid, uninhabitable localities with semiarid, arid, and hyper‐arid conditions. The meteorites studied here were collected from within the DCA of San Juan and Pampa de Mejillones, located, respectively, in the Central Depression and the Coastal Range of the Atacama Desert. 57Fe Mössbauer spectroscopy was used for quantitative analysis of the degree of weathering of the meteorites, through the determination of the proportions of the various Fe‐bearing phases and in particular the amount of oxidized iron in terrestrial alteration products. The abundance of ferric ions in weathered chondrites can be related to specific precursor compositions and to the level of terrestrial weathering. The aim of the study was the identification, quantification, and differentiation of the weathering products in the ordinary chondrites found in the San Juan and the Pampa de Mejillones areas of the Atacama Desert. The 57Fe Mössbauer spectroscopy study was complemented by synchrotron radiation X‐ray diffraction and magnetic susceptibility measurements. The results allow a clear differentiation of the rate of weathering in meteorite samples collected from the San Juan versus the Pampa de Mejillones areas of the Atacama Desert.  相似文献   

3.
Mössbauer spectra of equilibrated ordinary chondrites consist of two doublets due to paramagnetic iron present in olivines and pyroxenes and two sextets due to magnetically ordered iron present in metallic phases and troilite. The spectral areas of the different mineralogical phases found by Mössbauer spectroscopy in meteorites are proportional to the number of iron atoms in this mineralogical phase. This property of Mössbauer spectra can be the basis for constructing a method for the classification of ordinary chondrites. This idea was first explored at the Mössbauer Laboratory in Kanpur. This group suggested a qualitative method based on 2‐dimensional plots of Mössbauer spectral areas and thus classified properly some meteorites. We constructed a quantitative method using Mössbauer spectral areas, multidimensional discriminant analysis, and Mahalanobis distance (4M method) to determine the probability of a meteorite to be of type H, L, or LL. Based on 59 Mössbauer spectra, we calculated by the 4M method, S cluster , the level of similarity of the Goronyo meteorite to the clusters. On the plot of ferrosilite versus fayalite, the point representing Goronyo is located on the border between H and L areas. Calculated by the 4M method, the meteorite Goronyo is 32% similar to type H, 75% to type L, and 11% to type LL. Additional mineralogical analyses suggested that the Goronyo meteorite would be classified as type L, although it was originally reported as type H in the Meteoritical Bulletin Database.  相似文献   

4.
Abstract— The distribution of white evaporitic deposits differs among different meteorite compositional groups and weathering categories of Antarctic meteorites. Evaporites occur with unusual frequency on carbonaceous chondrites, and are especially common in carbonaceous chondrites of weathering categories A and B. Among achondrites, weathering categories A and A/B show the most examples of evaporite weathering. Unlike carbonaceous chondrites and achondrites, most evaporite-bearing ordinary (H and L) chondrites are from rustier meteorites of weathering categories B and, to a lesser degree, B/C and C. LL chondrites are conspicuous by their complete lack of any evaporitic weathering product. Almost two-thirds of all evaporite-bearing meteorites belong to weathering categories A, A/B, and B. Where chemical data are available, surficial evaporite deposits are associated with elemental anomalies in meteorite interiors. Meteorites of weathering classes B, A/B, and even A may have experienced significant element redistribution and/or contamination as a result of terrestrial exposure. Evaporite formation during terrestrial weathering cannot be neglected in geochemical, cosmochemical, and mineralogical studies of Antarctic meteorites. A lower-case “e” should be added to the weathering classification of evaporite-bearing Antarctic meteorites, to inform meteorite scientists of the presence of evaporite deposits and their associated compositional effects.  相似文献   

5.
Abstract— Mössbauer spectroscopic studies of the Didwana‐Rajod chondrite, which fell on 1991 August 12 in western Rajasthan, India, are presented. The results are compared with the Mössbauer data of several enstatite and ordinary chondrites including the Dhajala chondrite for which Mössbauer data were acquired during the present study. The Didwana‐Rajod chondrite's iron phases and its oxidation states strongly suggest that it should be classified as an H‐type ordinary chondrite instead of the earlier suggestion (based on petrographic studies) that it could be an enstatite chondrite. The present study demonstrates that Mössbauer spectroscopy is a very powerful technique for aiding in the classification of meteorites.  相似文献   

6.
Abstract— We conducted Mössbauer spectroscopic studies on the Ghubara meteorite which had been described as at least two‐generation regolith breccia on the macro scale. The isomer shift and quadrupole splitting of the Fe‐Ni part are quite different from those obtained in ordinary chondrites, reflecting shock effects. We observed a large amount of magnetite that may have come from weathering of, primarily, the silicate fraction. We found very similar iron mineralogy in the Densmore meteorite.  相似文献   

7.
Abstract— An improvement in the velocity resolution and quality of Mössbauer spectra has been applied to a group of ordinary chondrites. This improvement permitted us to carry out a more detailed study of the iron bearing phases in these samples than has previously been possible. Mössbauer spectra of 11 ordinary chondrites of L and H chemical groups were measured using 4096 channels and presented for further analysis in 1024 channels. Subspectra of the metal grains of several chondrites demonstrated the presence of at least two magnetic sextets related to the main Fe(Ni, Co) phases. Moreover, Mössbauer study of extracted metal grains from Tsarev L5 revealed three sextets and one singlet spectral components related to various α‐Fe(Ni, Co), α‘‐Fe(Ni, Co), α2‐Fe(Ni, Co), and γ‐Fe(Ni, Co) phases. Each subspectrum of olivine and pyroxene in Mössbauer spectra of ordinary chondrites was fitted by superposition of two quadrupole doublets related to M1 and M2 sites in minerals for the first time. An analysis of relative areas and Mössbauer hyperfine parameters was performed and some differences for L and H chondrites as well as for M1 and M2 sites were observed. Mössbauer parameters of troilite and oxidized iron were analyzed. In contrast to a previous study with 512‐channel spectra, the presence of oxidized iron was found in all chondrites.  相似文献   

8.
We describe the geological, geomorphological, and paleoclimatic setting of the Sahara of North Africa in particular, focused on the main meteorite dense collection areas (DCA; Morocco, Algeria, Tunisia, and Libya). We report on the outcome of several meteorite recovery field expeditions in Morocco and Tunisia since 2008, by car and by foot, that applied systematic search methods. The number of meteorites collected is 41 ordinary chondrites and one brachinite. The statistics of unpaired ordinary chondrites indicates that H chondrites are more abundant (21) than L chondrites (12), while LL chondrites are rare (2). Our meteorite density estimates for Tunisia and Morocco are in the order of magnitude of 1 met km?2. An estimate of the total maximum number of meteorites that could be recovered from the Sahara is 780,000 meteorites. We selected 23 meteorites from Aridal, Bou Kra, Bir Zar, and Tieret DCAs for 14C dating. The results show a wide range of terrestrial ages from 0.4 to more than 40 kyr with a majority of meteorites showing ages between 0.4 and 20 kyr. The weathering degree of these meteorites is ranges from minor (W1) to strong (W4). The highest weathering grades result from repeated oscillations between high and low humidity in the Sahara. However, there appears to be no correlation between weathering grade and terrestrial age of meteorites.  相似文献   

9.
We present for the first time a detailed report on the discovery of a new meteorite collection region in the Lut Desert, eastern–southeastern Iran, describing its geological, morphological, and climatic setting. Our search campaigns, alongside with the activity of meteorite hunters, yielded >200 meteorite finds. Here, we report on their classification, spatial distribution, and terrestrial weathering. All the collected meteorites are ordinary chondrites (OCs). The most abundant by far are the highly weathered paired H5 distributed in the northwest of Kalut area (central Lut, Kerman dense collection area). The second are well‐preserved paired L5 also found in Kalut region. A detailed study of the geochemistry and mineralogy of selected meteorites reveals significant effects of terrestrial weathering. Fe,Ni metal (hereafter simply metal) and troilite are transformed into Fe oxyhydroxides. A rather unusual type of troilite weathering to pyrite/marcasite is observed in most of the Lut Desert meteorites. Magnetic measurements and X‐ray diffractometry confirm the occurrence of terrestrial weathering products, with the dominance of maghemite, goethite, and hematite. Mobile elements, such as Li, Sr, Mo, Ba, Tl, Th, and U, are enriched with respect to fresh falls. Meanwhile, a decrease in the V, Cr, Co, Rb (and possibly Fe) due to terrestrial weathering is detectable. The total carbon and CaCO3 is higher than in samples from other hot deserts. The weathering effects observed in the Lut Desert OCs can be used as distinctive indicators to distinguish them from meteorites from other regions of the Earth. Measurements of terrestrial age (14C) show a range of 10–30 ka, which is in the range of ages reported for meteorites from other hot deserts except the Atacama Desert (Chile). Considering the high potential of the Lut Desert in meteorite preservation, systematic works should lead to the discovery of more samples giving access to interesting material for future studies.  相似文献   

10.
We have studied the Mukundpura CM2 meteorite for magnetic properties as a function of temperature and magnetic field, as well as its Mössbauer spectrum, at room and low temperatures (up to 5 K). We find that the high temperature paramagnetic phase is followed by two magnetic transitions: a weak transition near 125 K and a strong transition at 8 K. The weak (125 K) magnetic phase can be attributed to complex Fe2+–Fe3+ constituents present in the meteorite. The absence of the characteristic sextet corresponding to magnetite in Mossbauer spectrum indicates that this magnetic phase is not magnetite, which, if present, must be in insignificant amount. The 8 K magnetic ordering is superimposed with weak ferromagnetic ordering, showing spin‐glass transition. The Mössbauer spectrum taken at 5 K substantiates the observed spin‐glassy nature, as very large hyperfine field ~32 T is recorded, causing localized subordering leading to spin‐glass behavior. The Mössbauer spectra also confirm that iron is mainly present in serpentine‐group minerals, both in ferrous and ferric states. The complete serpentinization of basic silicates indicates aggressive hydrous alteration. These results show that the observed spin‐glass signature is a characteristic feature of the cronstedtite phase in CM meteorites. This feature is unique to carbonaceous CM chondrites and could be used for nondestructive, quick, and independent classification of this rare class of meteorites. Furthermore, the absence of olivine and the presence of cronstedtite in Mossbauer spectra show that the degree of aqueous alteration observed is the most severe in Mukundpura CM2 meteorite, as compared to many other CM2 meteorites. The degree of aqueous alteration in CM2 carbonaceous chondrites increases in the sequence: Paris, Murchison, Murray, Mighei, Nogoya, Cold Bokkeveld, and Mukundpura.  相似文献   

11.
Abstract– Although iron isotopes are increasingly used for meteorites studies, no attempt has been made to evaluate the effect of terrestrial weathering on this isotopic tracer. We have thus conducted a petrographic, chemical, and iron isotopic study of equilibrated ordinary chondrites (OC) recovered from hot Moroccan and Algerian Saharan deserts environment. As previously noticed, we observe that terrestrial desertic weathering is characterized by the oxidation of Fe‐Ni metal (Fe0), sulfide and Fe2+ occurring in olivine and pyroxene. It produces Fe‐oxides and oxyhydroxides that partially replace metal, sulfide grains and also fill fractures. The bulk chemical compositions of the ordinary chondrites studied show a strong Sr and Ba enrichment and a S depletion during weathering. Bulk meteoritic iron isotope compositions are well correlated with the degree of weathering and S, Sr, and Ba contents. Most weathered chondrites display the heaviest isotopic composition, by up to 0.1‰, which is of similar magnitude to the isotopic variations resulting from meteorite parent bodies’ formation and evolution. This is probably due to the release of isotopically light Fe2+ to waters on the Earth’s surface. Hence, when subtle Fe isotopic effects have to be studied in chondrites, meteorites with weathering grade above W2 should be avoided.  相似文献   

12.
Abstract– Weathering of meteorites at the scale of the entire Antarctic Search for Meteorites program population is studied by analyzing the recent version of the online Antarctic meteorite classification database that includes information about 15,263 meteorites. This paper updates, supplements, and expands on the last Antarctic meteorite weathering census by Velbel (1988 , Meteoritics 23:151–159). On average 5% of all Antarctic meteorites are indicated as evaporite bearing in the Antarctic Meteorite Database. Evaporite formation depends on compositional group. Evaporites are much more common on C chondrites than on ordinary chondrites, supporting previous findings. Ordinary chondrites of petrologic type 3 more often have evaporites on their surface than meteorites of other petrologic types. Contrary to previous findings, there is no apparent relation between evaporite formation and meteorite rustiness. Some meteorite‐bearing fields influence the frequency of evaporite‐mineral formation on meteorites. The influence of location is apparently related to differences in environmental conditions, most probably microclimate or/and hydrologic conditions. There is no relation between abundance of evaporite‐bearing meteorites and distance from the sea. Evaporite formation varies with year of collection; however, it was not possible to distinguish whether this is related to annual changes in environment or an artifact of sample categorization or curation.  相似文献   

13.
The gamma‐ray activities of 33 meteorite samples (30 ordinary chondrites, 1 Mars meteorite, 1 iron, 1 howardite) collected during Omani‐Swiss meteorite search campaigns 2001–2008 were nondestructively measured using an ultralow background gamma‐ray detector. The results provide several types of information: Potassium and thorium concentrations were found to range within typical values for the meteorite types. Similar mean 26Al activities in groups of ordinary chondrites with (1) weathering degrees W0‐1 and low 14C terrestrial age and (2) weathering degree W3‐4 and high 14C terrestrial age are mostly consistent with activities observed in recent falls. The older group shows no significant depletion in 26Al. Among the least weathered samples, one meteorite (SaU 424) was found to contain detectable 22Na identifying it as a recent fall close to the year 2000. Based on an estimate of the surface area searched, the corresponding fall rate is ~120 events/106 km2*a, consistent with other estimations. Twelve samples from the large JaH 091 strewn field (total mass ~4.5 t) show significant variations of 26Al activities, including the highest values measured, consistent with a meteoroid radius of ~115 cm. Activities of 238U daughter elements demonstrate terrestrial contamination with 226Ra and possible loss of 222Rn. Recent contamination with small amounts of 137Cs is ubiquitous. We conclude that gamma‐ray spectroscopy of a selection of meteorites with low degrees of weathering is particularly useful to detect recent falls among meteorites collected in hot deserts.  相似文献   

14.
We report on the first meteorite search campaign in the United Arab Emirates (UAE). The geology and proximity of our search region suggest that it is the north‐western extension of the Oman meteorite fields. We found 26 ordinary chondrites, bringing the total number of official meteorites from the UAE to 28. The campaign was organized and conducted in close cooperation with the UAE government and the main masses of the meteorites remained in the country where they will become part of an exhibition. The bulk composition of five meteorite and three soil samples indicates an uptake of U, Mo, Sr, Ba, Li, and Pb from the soil into the meteorites during terrestrial weathering. Terrestrial ages determined from 14C decay of 21 meteorites range from recent falls to 24.4 ka, with two meteorites having >37 ka and approximately 39 ka, respectively. Weak correlations between weathering degree, meteorite bulk chemical composition, and terrestrial age suggest highly localized weathering conditions, possibly related to abundant occurrences of sabkhas in the search region.  相似文献   

15.
Abstract— The nature and isotopic composition of carbonaceous components in a variety of ordinary chondrites have been studied using stepped combustion. The samples were chosen to include falls, finds and Antarctic meteorites; specimens from all three chemical groups (H, L and LL) have been analysed. Effort was concentrated mostly on the low petrologic type meteorites (i.e., type 3); however, types 4–6 were also included in the study. Apart from terrestrial contaminants and weathering products, some of the unequilibrated ordinary chondrites appear to contain an indigenous organic component. In addition, most of the samples studied show evidence for an amorphous/graphitic component. This exists as C-rich aggregates or as carbon associated with “Huss” matrix. There does not appear to be any difference in δ13C for this carbon between Antarctic and non-Antarctic meteorites. In contrast, low temperature carbon in Antarctic samples is characterized by a 13C-enrichment. This is thought to be due to the influence of terrestrial weathering products introduced in the Antarctic. Curiously, the low temperature carbon in non-Antarctic finds appears to be intermediate in δ13C between Antarctic finds and non-Antarctic falls. This suggests that the weathering processes which are so obviously apparent from Antarctic samples may also extend, albeit in a more limited way, to non-Antarctic meteorites.  相似文献   

16.
In the last 15 years, more than 2700 meteorites have been recovered and officially classified from the Atacama Desert. Although the number of meteorites collected in the Atacama has risen, the physical and climatic properties of the dense collection areas (DCAs) have not been fully characterized. In this article, we compiled the published data of all classified meteorites found in the Atacama Desert to (i) describe the distribution by meteorite groups, (ii) compare the weathering degree of chondrites among different Atacama DCAs and other hot and cold deserts, and (iii) determine the preservation conditions of chondrites in the main Atacama DCAs in relation with the local climatic conditions. The 35 DCAs so far identified in the Atacama Desert are located in three main morphotectonic units: The Coastal Range (CR), Central Depression (CD), and Pre-Andean Range/Basement. A comparison with reported weathering data from other cold and hot deserts indicates that the mean terrestrial weathering of Atacama chondrites (W1–2), displays less alteration than other hot deserts (W2–3) and resembles the weathering distribution of the Antarctic meteorites (W1–2). The highest abundance of Atacama chondrites with low weathering (≤W2) is localized in the CD (78.8%, N = 1435), which is protected from the coastal fog influence and seasonal rainfalls and displays the oldest surfaces in the Atacama Desert. The morphogenetic classification based on present-day temperatures and precipitations of the main Atacama DCAs reveals similar regional/subregional climatic conditions in the most productive areas and a truly productive surface for meteorite recovery between 5% and 58% of the quadrangles formally defined for each Atacama DCA. Our morphogenetic classification lacks consideration of some meteorological parameters such as the coastal fog, so it cannot fully explain the differences in weathering patterns among CR chondrites. Future studies of chondrite preservation in the Atacama DCAs should consider other meteorological variables such as relative humidity, specific humidity, or dew point, in combination with exposure ages of meteorites and its surfaces.  相似文献   

17.
Abstract— The Burnwell, Kentucky, meteorite fell as a single stone on 1990 September 4. The Burnwell meteorite has lower Fa in olivine (15.8 mol%), Fs in orthopyroxene (13.4 mol%), Co in kamacite (0.36 wt%), FeO from bulk chemical analysis (9.43 wt%), and Δ17O (0.51 ± 0.02%), and higher Fe, Ni, Co metal (19.75 wt% from bulk wet chemical analysis) than observed in H chondrites. The Burnwell meteorite plots on extensions of H-L-LL chondrite trends for each of these properties towards more reducing compositions than in H chondrites. Extensions of this trend have been previously suggested in the case of other low-FeO chondrites or silicate inclusions in the HE iron Netschaëvo, but interpretation of the evidence in these meteorites is complicated by terrestrial weathering, chemical disequilibrium or reduction. In contrast, the Burn-well meteorite is an equilibrated fall that exhibits no evidence for reduction. As such, it provides the first definitive evidence for extension of the H-L-LL ordinary chondrite trend beyond typical H values towards more reducing compositions.  相似文献   

18.
Abstract— Meteoritical Bulletin No. 83 lists information for 898 newly described meteorites. These include 473 from Antarctica, 341 from the Sahara, and 22 from dry lakes in the southwestern United States. Seven of the meteorites are falls: Kunya-Urgench (H5), Lohawat (howardite), Ourique (H4), Portales Valley (H6), San Pedro de Quiles (L6), Talampaya (eucrite), and Zag (H3-6). Also included are a dozen new iron meteorites; several mesosiderites; a pallasite; several HED meteorites; several ureilites; a variety of CM, CO, CV, CR, and R chondrites; and numerous unequilibrated ordinary chondrites. All shock classifications are after Stöffler et al. (1991) and weathering grades are after Wlotzka (1993), except as noted. All italicized abbreviations refer to addresses tabulated at the end of this document.  相似文献   

19.
Meridiani Planum is the first officially recognized meteorite find on the surface of Mars. It was discovered at and named after the landing site of the Mars Exploration Rover Opportunity. Based on its composition, it was classified as a IAB complex iron meteorite. Mössbauer spectra obtained by Opportunity are dominated by kamacite (α‐Fe‐Ni) and exhibit a small contribution of ferric oxide. Several small features in the spectra have been neglected to date. To shed more light on these features, five iron meteorite specimens were investigated as analogs to Meridiani Planum with a laboratory Mössbauer setup. Measurements were performed on (1) their metallic bulk, (2) troilite (FeS) inclusions, (3) cohenite ((Fe,Ni,Co)3C) and schreibersite ((Fe,Ni)3P), and (4) corroded rims. In addition to these room‐temperature measurements, a specimen from the Mundrabilla IAB‐ungrouped meteorite was measured at Mars‐equivalent temperatures. Based on these measurements, the features in Meridiani Planum spectra can be explained with the presence of small amounts of schreibersite and/or cohenite and iron oxides. The iron oxides can be attributed to a previously reported coating on Meridiani Planum. Their presence indicates weathering through the interaction of the meteorite with small amounts of water.  相似文献   

20.
Abstract— The mid-infrared (4000–450 cm?1; 2.5–22.2 μm) transmission spectra of seven Antarctic ureilites and 10 Antarctic H-5 ordinary chondrites are presented. The ureilite spectra show a number of absorption bands, the strongest of which is a wide, complex feature centered near 1000 cm?1 (10 μm) due to Si-O stretching vibrations in silicates. The profiles and positions of the substructure in this feature indicate that Mg-rich olivines and pyroxenes are the main silicates responsible. The relative abundances of these two minerals, as inferred from the spectra, show substantial variation from meteorite to meteorite, but generally indicate olivine is the most abundant (olivine:pyroxene = 60:40 to 95:5). Both the predominance of olivine and the variable olivine-to-pyroxene ratio are consistent with the known composition and heterogeneity of ureilites. The H-5 ordinary chondrites spanned a range of weathering classes and were used to provide a means of addressing the extent to which the ureilite spectra may have been altered by weathering processes. It was found that, while weathering of these meteorites produces some weak bands due to the formation of small amounts of carbonates and hydrates, the profile of the main silicate feature has been little affected by Antarctic exposure in the meteorites studied here. The mid-infrared ureilite spectra provide an additional means of testing potential asteroidal parent bodies for the ureilites. At present, the best candidates include the subset of S-type asteroids having low albedos and weak absorption features in the near infrared.  相似文献   

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