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1.
Evaporation of soil moisture is one of the most important processes affecting water availability in semiarid ecosystems. Biological soil crusts, which are widely distributed ground cover in these ecosystems, play a recognized role on water processes. Where they roughen surfaces, water residence time and thus infiltration can be greatly enhanced, whereas their ability to clog soil pores or cap the soil surface when wetted can greatly decrease infiltration rate, thus affecting evaporative losses. In this work, we compared evaporation in soils covered by physical crusts, biological crusts in different developmental stages and in the soils underlying the different biological crust types. Our results show that during the time of the highest evaporation (Day 1), there was no difference among any of the crust types or the soils underlying them. On Day 2, when soil moisture was moderately low (11%), evaporation was slightly higher in well‐developed biological soil crusts than in physical or poorly developed biological soil crusts. However, crust removal did not cause significant changes in evaporation compared with the respective soil crust type. These results suggest that the small differences we observed in evaporation among crust types could be caused by differences in the properties of the soil underneath the biological crusts. At low soil moisture (<6%), there was no difference in evaporation among crust types or the underlying soils. Water loss for the complete evaporative cycle (from saturation to dry soil) was similar in both crusted and scraped soils. Therefore, we conclude that for the specific crust and soil types tested, the presence or the type of biological soil crust did not greatly modify evaporation with respect to physical crusts or scraped soils. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

2.
Soil surface crusting, a common phenomenon on cultivated soils, has major implications for agriculture and the environment because of its effects on soil hydrological properties, erosion and crop establishment. The objectives of this study were to evaluate land use controls on crust formation and the hydraulic response of soils to crust development for a Patancheru series soil (clayey skeletal, mixed, isohyperthermic Udic Rhodustalf) in south‐central India. Soil aggregates, obtained from cultivated (PL) and naturally vegetated fallow (NV) land, were packed into sample trays and subjected to laboratory rain simulation to form crusts. Thin sections and visual observation indicated that crust development reached a more advanced stage in the PL case compared with NV following 90 min of rain at 40–80 mm h−1 intensity. This was reflected in a thicker crust layer with fewer voids in the former and a less smooth surface with partially disintegrated aggregates in the latter. The hydraulic response of the soil surface with the progression of crust development indicated a more permeable and less dense crust formed on NV than on PL soil. The results suggested that NV soil aggregates were more stable and that crust formation is more gradual for stable aggregates compared with the less stable PL aggregates. A structural crust‐type formed on the Patancheru soil by means of parallel subprocesses involving translocation and illuviation of aggregate disruption by products, and raindrop compaction and particle rearrangement. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

3.
Several studies illustrate the wind and water erosion‐reducing potential of semi‐permanent microbiotic soil crusts in arid and semi‐arid desert environments. In contrast, little is hitherto known on these biological crusts on cropland soils in temperate environments where they are annually destroyed by tillage and quickly regenerate thereafter. This study attempts to fill the research gap through (a) a field survey assessing the occurrence of biological soil crusts on loess‐derived soils in central Belgium in space and time and (b) laboratory flume (2 m long) experiments simulating concentrated runoff on undisturbed topsoil samples (0.4 × 0.1 m2) quantifying the microbiotic crust effect on soil erosion rates. Three stages of microbiotic crust development on cropland soils are distinguished: (1) development of a non‐biological surface seal by raindrop impact, (2) colonization of the soil by algae and gradual development of a continuous algal mat and (3) establishment of a well‐developed microbiotic crust with moss plants as the dominant life‐form. As the silt loam soils in the study area seal quickly after tillage, microbiotic soil crusts are more or less present during a large part of the year under maize, sugar beet and wheat, representing the main cropland area. On average, the early‐successional algae‐dominated crusts of stage 2 reduce soil detachment rates by 37%, whereas the well‐developed moss mat of stage 3 causes an average reduction of 79%. Relative soil detachment rates of soil surfaces with microbiotic crusts compared with bare sealed soil surfaces are shown to decrease exponentially with increasing microbiotic cover (b = 0·024 for moss‐dominated and b = 0·006 for algae‐dominated crusts). In addition to ground surface cover by vegetation and crop residues, microbiotic crust occurrence can therefore not be neglected when modelling small‐scale spatial and temporal variations in soil loss by concentrated flow erosion on cropland soils in temperate environments. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

4.
Space monitoring of Aral Sea degradation   总被引:1,自引:0,他引:1  
The results of remote sensing survey of the Aral Sea in its degradation period are given. Satellite images are used to map shoreline retreat from 1961 to 2008 and to measure the decrease in the area. Seasonal variations in shoreline and water area are identified, suggesting seasonal level variations and correlating well with data of satellite altimetry surveys of sea level. Observations covered surge phenomena, seasonal dynamics of landscapes, and the seasonal salinization rhythm in coastal territories with the subsequent formation and weathering of salt crusts. The character of river runoff input into the Great Sea resulting from overbank flooding in artificial water bodies in the Amu Darya delta is identified.  相似文献   

5.
Sodium accumulating playas (also termed sodic or natric playas) are typically covered by polygonal crusts with different pattern characteristics, but little is known about the short‐term (hours) dynamics of these patterns or how pore water may respond to or drive changing salt crust patterning and surface roughness. It is important to understand these interactions because playa‐crust surface pore‐water and roughness both influence wind erosion and dust emission through controlling erodibility and erosivity. Here we present the first high resolution (10?3 m; hours) co‐located measurements of changing moisture and salt crust topography using terrestrial laser scanning (TLS) and infra‐red imagery for Sua Pan, Botswana. Maximum nocturnal moisture pattern change was found on the crests of ridged surfaces during periods of low temperature and high relative humidity. These peaks experienced non‐elastic expansion overnight, of up to 30 mm and up to an average of 1.5 mm/night during the 39 day measurement period. Continuous crusts however showed little nocturnal change in moisture or elevation. The dynamic nature of salt crusts and the complex feedback patterns identified emphasize how processes both above and below the surface may govern the response of playa surfaces to microclimate diurnal cycles. © 2015 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

6.
Playa systems are driven by evaporation processes, yet the mechanisms by which evaporation occurs through playa salt crusts are still poorly understood. In this study we examine playa evaporation as it relates to land surface energy fluxes, salt crust characteristics, groundwater and climate at the Salar de Atacama, a 3000 km2 playa in northern Chile containing a uniquely broad range of salt crust types. Land surface energy budget measurements were taken at eight representative sites on this playa during winter (August 2001) and summer (January 2002) seasons. Measured values of net all-wave radiation were highest at vegetated and rough halite crust sites and lowest over smooth, highly reflective salt crusts. Over most of the Salar de Atacama, net radiation was dissipated by means of soil and sensible heat fluxes. Dry salt crusts tended to heat and cool very quickly, whereas soil heating and cooling occurred more gradually at wetter vegetated sites. Sensible heating was strongly linked to wind patterns, with highest sensible heat fluxes occurring on summer days with strong afternoon winds. Very little energy available at the land surface was used to evaporate water. Eddy covariance measurements could only constrain evaporation rates to within 0.1 mm d−1, and some measured evaporation rates were less than this margin of uncertainty. Evaporation rates ranged from 0.1 to 1.1 mm d−1 in smooth salt crusts around the margin of the salar and from 0.4 to 2.8 mm d−1 in vegetated areas. No evaporation was detected from the rugged halite salt crust that covers the interior of the salar, though the depth to groundwater is less than 1 m in this area. These crusts therefore represent a previously unrecorded end member condition in which the salt crusts form a practically impermeable barrier to evaporation.  相似文献   

7.
Lirong Lin  Jiazhou Chen 《水文研究》2015,29(9):2079-2088
Rain‐induced erosion and short‐term drought are the two factors that limit the productivity of croplands in the red soil region of subtropical China. The objective of this study was to estimate the effects of conservation practices on hydraulic properties and root‐zone water dynamics of the soil. A 3‐year experiment was performed on a slope at Xianning. Four treatments were evaluated for their ability to reduce soil erosion and improve soil water conditions. Compared with no practices (CK) and living grass strips (GS), the application of polyacrylamide (PAM) significantly reduced soil crust formation during intense rainfall, whereas rice straw mulching (SM) completely abolished soil crust formation. The SM and PAM treatments improved soil water‐stable aggregates, with a redistribution of micro‐aggregates into macro‐aggregates. PAM and SM significantly increased the soil water‐holding capacity. These practices mitigated the degradation of the soil saturated hydraulic conductivity (Ks) during intense rainfalls. These methods increased soil water storage but with limited effects during heavy rainfalls in the wet period. In contrast, during the dry period, SM had the highest soil water storage, followed by PAM and CK. Grass strips had the lowest soil water storage because of the water uptake during the vigorous grass growth. A slight decline in the soil moisture resulted in a significant decrease in the unsaturated hydraulic conductivity (Ku) of the topsoil. Therefore, the hydraulic conductivity in the field is governed by soil moisture, and the remaining soil moisture is more important than improving soil properties to resist short‐term droughts. As a result, SM is the most effective management practice when compared with PAM and GS, although they all protect the soil hydraulic properties during wet periods. These results suggest that mulching is the best strategy for water management in erosion‐threatened and drought‐threatened red soils. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

8.
咸海地处中亚,气候和人类的双重影响下湖面急剧萎缩引发区域生态危机,定量解析其水量平衡互动关系及影响因素对咸海地区水资源管理和生态保护有重要意义.基于1990-2019年密集时序Landsat影像、T/P卫星、Jason1/2测高卫星及咸海数字测深模型(DBM),提取近30年咸海面积、水位变化信息,重建咸海水位-面积-库...  相似文献   

9.
Temporal aspects of the abrasion of microphytic crusts under grain impact   总被引:1,自引:0,他引:1  
Wind‐tunnel simulations of the response of two moss crusts to grain impact indicate that, given sufficient time, these surfaces will deteriorate under very low wind velocities only slightly above u*t for the loose, saltating grains. In parallel with these experiments, the frequency distributions of ultimate strength and penetration energy were determined for each of the two crust types via penetrometry. Pohlia was found to be stronger than Tortula; but, even so, both of these crusts had ultimate strengths 20–350 times higher than the force delivered by a single grain impacting each surface at a velocity of 1 ms?1. In comparison, the modulus of deformation and penetration energy data were very similar for the two surface types, especially for the weakest areas of crust development. This observation is in accord with the wind‐tunnel simulations that also found no consistent difference in the response of these two crust types to impact. In comparison with crusts formed by clay and salt, fibrous microphytic crusts are morphologically complex and typically weak. The notable elasticity of these surfaces does reduce the force of grain impact, and thereby provides some protection against rupture. One of the central conclusions of this study suggests that not only is the particle kinetic energy at impact important in crust breakdown, but also tiny fractures at points of localized stress concentration contribute to a progressive reduction in the integrity of the filament net. In some of the experiments conducted as part of this study, up to 50 or more minutes of constant bombardment was required to produce small abrasion marks on selected areas of the microphytic crust. This study prepares a foundation for future experiments needed to examine the breakdown of complex crusts formed in nature. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

10.
The formation of Namibia's extensive pedogenic gypsum crusts (CaSO4·2H2O) is interpreted in a new light. It is suggested that gypsum primarily precipitates at isolated points of evaporitic concentration, such as inland playas, and that deflation of evaporitic‐rich gypsum dust from these playas contributes to the formation of pedogenic gypsum duricrusts on the coastal gravel plains of the Namib Desert surrounding these playas. This study establishes the nature, extent and distribution of playas in the Central Namib Desert and provides evidence for playa gypsum deflation and gravel plain deposition. Remote sensing shows the distribution of playas, captures ongoing deflation and provides evidence of gypsum deflation. It is proposed that, following primary marine aerosol deposition, both inland playas and coastal sabkhas generate gypsum which through the process of playa deflation and gravel plain redeposition contributes to the extensive pedogenic crusts found in the Namib Desert region. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

11.
The response of runoff and erosion to soil crusts has been extensively investigated in recent decades. However, there have been few attempts to look at the effects of spatial configuration of different soil crusts on erosion processes. Here we investigated the effects of different spatial distributions of physical soil crusts on runoff and erosion in the semi‐arid Loess Plateau region. Soil boxes (1.5 m long × 0.2 m wide) were set to a slope of 17.6% (10°) and simulated rainfall of 120 mm h?1 (60 minutes). The runoff generation and erosion rates were determined for three crust area ratios (depositional crust for 20%, 33%, and 50% of the total slope) and five spatial distribution patterns (depositional crust on the lower, lower‐middle, middle, mid‐upper, and upper slope) of soil crusts. The reduction in sediment loss (‘sediment reduction’) was calculated to evaluate the effects of different spatial distributions of soil crusts on erosion. Sediment yield was influenced by the area ratio and spatial position of different soil crusts. The runoff rate reached a steady state after an initial trend of unsteadily increasing with increasing rainfall duration. Sediment yield was controlled by detachment limitation and then transport limitation under rainfall. The shifting time of erosion from a transport to detachment‐limiting regime decreased with increasing area of depositional crust. No significant differences were observed in the total runoff among treatments, while the total sediment yield varied under different spatial distributions. At the same area ratio, total sediment yield was the largest when the depositional crust was on the upper slope, and it was smallest when the crust was deposited on the lower slope. The sediment reduction of structural crust (42.5–66.5%) was greater than that of depositional crust (16.7–34.3%). These results provide a mechanistic understanding of how different spatial distributions of soil crusts affect runoff and sediment production. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

12.
The top‐soil samples were collected from urban, industrial, agricultural, and rural sites to investigate the modification in the elemental composition due to anthropogenic influence in one of the biggest city of Turkey, namely Izmir. The elemental profiles were dominated by lithophilic elements such as Al, Ca, Fe, Mg, K, and sea salt element, Na, which is typical for Mediterranean region. The trace elemental concentrations showed significant variation with higher concentrations in the industrial sites, particularly in the vicinity of iron‐steel producers from scrap materials (EAF‐Steels). Lead, Zn, and Cd around EAF‐Steels were found to be higher than other sites. Comparison to universal upper crusts and local reference soil has shown that Izmir top‐soils were contaminated in terms of many trace elements, most probably due to anthropogenic activities. Correlation matrix, crustal enrichment factors, and factor analysis were applied to investigate the extent of soil modification and possible sources. The results indicated that the elemental profiles of top‐soils were mainly determined by parent materials; however, anthropogenic activities were found to be factor effective on the profile.  相似文献   

13.
Physical soil crusts likely have significant effects on infiltration and soil erosion, however, little is known on whether the effects of the crusts change during a rainfall event. Further, there is a lack of discussions on the differences among the crusting effects of different soil types. The objectives of this study are as follows: (i) to study the effects of soil crusts on infiltration, runoff, and splash erosion using three typical soils in China, (ii) to distinguish the different effects on hydrology and erosion of the three soils and discuss the primary reasons for these differences, and (iii) to understand the variations in real soil shear strength of the three soils during rainfall events and mathematically model the effects of the crusts on soil erosion. This study showed that the soil crusts delayed the onset of infiltration by 5 to 15 min and reduced the total amount of infiltration by 42.9 to 53.4% during rainfall events. For a purple soil and a loess soil, the initial crust increased the runoff by 2.8% and 3.4%, respectively, and reduced the splash erosion by 3.1% and 8.9%, respectively. For a black soil, the soil crust increased the runoff by 42.9% and unexpectedly increased the splash erosion by 95.2%. In general, the effects of crusts on the purple and loess soils were similar and negligible, but the effects were significant for the black soil. The soil shear strength decreased dynamically and gradually during the rainfall events, and the values of crusted soils were higher than those of incrusted soils, especially during the early stage of the rainfall. Mathematical models were developed to describe the effects of soil crusts on the splash erosion for the three soils as follows: purple soil, Fc= 0.002t- 0.384 ; black soil, Fc. =-0.022t + 3.060 ; and loess soil, Fc = 0.233 In t- 1.239 . Combined with the equation Rc= Fc (Ruc - 1), the splash erosion of the crusted soil can be predicted over time.  相似文献   

14.
The arid Qaidam Basin is the largest (~3.88 × 104 km2) basin on the north‐eastern Tibetan Plateau. Wind erosion in the area has been regarded as an important trigger for intra‐basin tectonic balance upheaval, geomorphologic development and as a major supplier of dust to the Chinese Loess Plateau downwind. An initial estimate of the rate of wind erosion (Kapp et al., 2011) based on geological cross‐sections has suggested up to 3.2 × 104 km3 of sediments has been deflated over the past 2.8 Ma, lowering the landscape by an average of 0.29 mm/yr. In this paper we re‐evaluate this estimate by dating surface crusts present on three playas within the basin. Understanding the development of these playas is crucial to assessing the overall role of the wind in shaping the regional landscape because they are typically capped with a thick salt crust which effectively protects them from wind erosion. Optically stimulated luminescence (OSL) and U‐series dating from a pit section and from the top of a deep drill core, together with results from magnetostratigraphy and a climate proxy record correlated to the marine oxygen isotope record, are used here to determine the age of the playa plains and suggest that the salt crusts have an age of c. 0.1 Ma. This young age and the wide distribution of resistant thick salt crusts of the playa plains indicate a much lower degree of wind erosion than previously suggested. The crusts protect the surface from significant surface erosion (including sediment exhumation and unloading) and whilst some wind erosion does occur, it is unlikely to be sufficient to trigger tectonic uplift of the basin or to be a major dust source for the Loess Plateau as previously suggested. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

15.
A portable field wind tunnel was used to assess the sediment flux rates of loam and sand textured soils in the Mallee region of southeastern Australia. Three levels of crust disturbance (nil, moderate and severe) simulating stock trampling were investigated. The results demonstrated the importance of cryptogamic crusts in binding the soil surface and providing roughness after the soil was moderately disturbed. On the loamy soil, the crust helped maintain sediment flux rates below the erosion control target to 5 g m−1 s−1 for a 65 km h−1 wind measured at 10 m height. Once the crust was severely disturbed, sediment fluxes increased to 1·6 times the erosion target. On the sandy soil, even with no crust disturbance the sediment flux was 1·6 times the erosion control target. Disturbing the crust increased sediment fluxes to a maximum of 6·7 times the erosion control target. Removal of the crust also decreased the threshold wind velocity that resulted in an increase to the risk of erosion from <5 per cent to 20 per cent. © 1998 John Wiley & Sons, Ltd.  相似文献   

16.
Semicircular and crescent-shaped accumulations of salt crystals developed on salt crusts were measured on three Tunisian playas in September 1990. These features have been termed salt ramps. Their morphology and chemistry suggest that they are formed in the late stages of shallow ephemeral lake desiccation in playa basins. They form by salt precipitation from shallow brine lakes that are blown across salt-encrusted playa surfaces by the wind. Moreover, they appear to be short-lived features and their degradation is related to the flooding of playas with less saline water, and possibly rainfall and deflation.  相似文献   

17.
Mineralogical, geochemical and grain‐size composition of soil and pore‐water chemistry parameters were characterized on both eroded (south‐facing) and non‐eroded (north‐facing) clayey‐silt slopes in the Basilicata region (southern Italy). Only a few grain‐size parameters and clay mineralogy discriminate eroded from non‐eroded substrates. Compared with the latter, the former have fractions of over 63 µm and 1–4 µm lower and fractions 4–63 µm higher. Grain‐size characters of crusts did not discriminate with respect to substrate. Bulk rock mineralogy was not distinctive, but the clay mineral assemblage shows that the eroded slope is enriched in kaolinite, mixed layers (illite–smectite) and chlorite, whereas illite decreases, although overlaps are common. Chemical data enable discrimination between eroded and non‐eroded slopes. pH, SAR (sodium adsorption ratio), TDS (total dissolved salts) and PS (percentage of sodium) are distinctive parameters for both eroded and non‐eroded slopes. TDS increases in depth in the non‐eroded slope, whereas the maximum TDS is just below the crust in the eroded one. On average, eroded substrates are higher in pH, SAR and PS than non‐eroded ones. The ESP (exchangeable sodium percentage) of the eroded slope has a higher value than the non‐eroded one. Crusts are less dispersive than eroded substrates, and non‐eroded substrates behave as crusts. This suggests that the portion of the slope most severely exposed to weathering tends to stabilize, due to strong decreases in SAR, PS and ESP. Several diagrams reported in the literature show similarly anomalous crust samples on eroded slopes, compared with other samples coming from greater depths on eroded slopes. In the present case study, the exchangeable form of Na characterizes crusts more than the soluble form. This study describes the erosional mechanism, which involves morphological and geographic exposure and climatic elements, as well as grain size, mineralogy, chemistry and exchangeable processes of soils. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

18.
To study the effects of biological soil crusts (BSCs) on hydrological processes and their implications for disturbance in the Mu Us Sandland, the water infiltration, evaporation and soil moisture of high coverage (100% BSCs), middle coverage (40% BSCs) and low coverage (0% BSCs, bare sand) of moss‐dominated crusts were conducted in this study, respectively. The conclusions are as follows: (1) the main effects of moss‐dominated crusts in the Mu Us Sandland on the infiltration of rainwater were to reduce the infiltration depths and to retain the limited rainwater in shallow soil; (2) moss‐dominated crusts have no significant effects on daily evaporation when the volumetric water content at 4 cm depth in 100% BSCs (VWC4) was over 24.7%, on enhanced daily evaporation when the VWC4 ranged from 6.5% to 24.7% and on reduced daily evaporation when the VWC4 was less than 6.5%; and (3) decreasing the coverage of moss‐dominated crusts (from 100% to 40%) did not significantly change its effects on infiltration, evaporation and soil moisture. Our results demonstrated that for the growth and regeneration of shrubs, which were dominated by Artemisia ordosica in the Mu Us Sandland, high coverage of moss‐dominated crusts has negative effects on hydrological processes, and these negative effects could not be significantly reduced by decreasing the coverage of moss‐dominated crusts from 100% to 40%. Therefore, for the sustained and healthy development of shrub communities in the Mu Us Sandland, it is necessary to take appropriate measures for the well‐developed BSCs in the sites with high vegetation coverage in the rainy season. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

19.
Runoff‐induced sediments were collected in the Hallamish dune field for four years (1990–1994). Runoff and consequently water‐transported sediments were generated on the dunes owing to the presence of a thin microbiotic crust. These sediments were analysed for their particle‐size distribution and carbonate content. In addition, the organic matter content was calculated by measuring the chlorophyll content within the runoff. The results were compared to the slope parent material, i.e. the crust and the underlying sand, as well as to playa sediments, which are scattered within the Hallamish interdunal areas, and which were previously hypothesized to originate from runoff‐induced sediments. Higher amounts of fines (silt and clay) and carbonate characterize the footslopes in comparison to the midslopes. Intermediate contents of fines (17 per cent) and carbonate (8 per cent) characterized the sediments in comparison to the fines (27 per cent) and carbonate (15 per cent) of the crust and to the fines (4 per cent) and carbonate (4 per cent) of the underlying sand. The runoff‐induced fines and carbonate contents were significantly different from those of the playas, suggesting that the playa flats do not originate from runoff‐induced sediments. The sediments were enriched with organic matter. Organic matter which originates from the crust amounted to 0·3–0·4 per cent as compared to ≤0·1 per cent in the bare sand. Nevertheless, the crust was found to be relatively resilient to water flow. Only 0·1–0·5 per cent of the crust was annually eroded off the slope by water, with south‐facing crusts showing higher resilience than north‐facing crusts. The data may thus assist in the evaluation of the crust's residence time. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

20.
Previous research on rock weathering crusts has revealed their large variability depending on the type of host rocks and development of weathering processes. The composition of crusts developed on natural sandstone exposures is less documented in the literature in comparison to those developed on architectonic stones. In both cases, previous research has focused mainly on the progress of salt weathering. This study considers the surfaces of sandstone tors in the Polish Outer Carpathians. The exposed parts of the rocks in this area are often covered by crust, which is up to several centimetres thick, and differs from the internal part in colour and composition. The crusts were characterized using light and electron microscopy, X‐ray diffractometry, thermal analyses, Mössbauer spectroscopy, bulk chemical analyses and sequential chemical extractions. Porosity was estimated by digital image processing. The following two hardened zones were observed: (1) thin (up to 30 µm), black, external layer, rich in carbon and composed of opal‐type silica, covered in places by sulphate incrustations and numerous spherical particles of anthropogenic origin; (2) thicker (up to several millimetres), internal part composed of a set of laminae of variable colouration, enriched in iron (oxyhydr)oxides (goethite and hematite) in comparison to the rock interior. Development of the crust results from silicon and iron redistribution during the sandstone alteration. The chief source of silica is hydrolysis of aluminosilicates, whilst that of iron is decomposition of aluminosilicates, carbonates and sulphides. Hematite is probably a result of goethite transformation. However, air pollutants may play an important role in the formation of sulphates. Silica and iron compounds affect the properties of the rock, hardening the surface and lowering porosity by formation of secondary cement. Crystallization of sulphate salts, in turn, may contribute to mechanical disintegration of the rock. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

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