Studying the Volga R. in the voyage of the R/V Akademik Topchiev

The expedition for studying the Volga R. was organized by the Institute of Oceanology, Russian Academy of Sciences and the Institute of Inland Water Biology, Russian Academy of Sciences, with the participation of the Institute of Geochemistry and Analytical Chemistry on the r/v Akademik Topchiev (June 2–18, 2016). The main objective of the expedition studies of the Institute of Oceanology, Russian Academy of Sciences, was to examine the sedimentation and biogeochemical processes in the mixing zone of the Volga and its tributaries with the aim to assess the present-day water quality and trends in its changes in the recent years. In this context, the study was focused on the aerosols of near-water layer, surface water, and bottom sediments along the route the Rybinsk Reservoir (Borok Settl.)–Lower Volga (Astrakhan C.). The methodology was based on a multidisciplinary study of dissolved compounds and suspended particles (<1 μm). The main attention was focused on studying the spatial variations of biogenic substances, organic compounds (Corg in suspension and solution), the suspension itself, and hydrcarbons.     

Ecological and toxicological assessment of water and bottom sediments in the Novosibirsk Reservoir

The toxicological state of individual parts of the Novosibirsk Reservoir was assessed with the help of bioassay tests of water and water extracts from bottom sediments with the use of two species of protococcus algae (Scenedesmus quadricauda (Turp.) Breb., Chlorella vulgaris Beijer) and two species of entomostracans (Daphnia magna Straus, Ceriodaphnia affinis Lillijeborg). It was found that the Ob R. near Kamenon-Ob is more polluted in terms of water and less polluted in terms of bottom sediments, compared with those in the lower part of the reservoir. The bioassay results are in agreement with the results of benthos-based bioindication and studies of chlorophyll a and pollutant concentrations in water.     

State of heterotrophic bacterioplankton of Yenisei estuary and the zone of Ob–Yenisei discharge in autumn in relation with environmental factors

In September 2011, variations of the total abundance of bacteria were studied, including, for the first time, the abundance of bacteria with intact membranes and active electron transport chains, as well as chlorophyll a concentrations and some hydrological and hydrochemical characteristics of water in Yenisei estuary and the zone of Ob–Yenisei river discharge. The study found abundant, viable, and actively functioning bacterioplankton to exist in the region. The absolute values of all microbiological characteristics were found to decrease with the distance from the freshened waters of Yenisei estuary toward the seawater of the Ob–Yenisei river discharge, while the percentage of bacteria with intact membranes and actively functioning microorganisms in bacterioplankton increased in the same direction. Positive correlations were found to exist between the values of all examined microbiological characteristics and the concentration in water of chlorophyll a, silicium, organic nitrogen, and oxygen, as well as water temperature. The same biological characteristics showed negative correlations with water salinity and phosphates. The spatial distribution of bacteria in the examined water body was supposed to be due mostly to the intensity of hydrodynamic processes, rather than the biogenic matter content of water.     

Assessment of Bottom Sediment Quality Based on Application of Statistical Methods of Data Analysis: Case Study of the Sestra River

Statistical methods of data analysis have been used to study the correlation between the benthic characteristics and the geochemical and toxicological characteristics of bottom sediments of the small river of Sestra. As shown, a relatively wide scope of biological and chemical data is needed to assess the quality of bottom sediments of the Sestra River.     

Hydrocarbons at the Geochemical Barrier the Northern Dvina–the White Sea

Water Resources - Aliphatic and polycyclic aromatic hydrocarbons have been studied in suspended matter and bottom sediments at the geochemical barrier the Northern Dvina–Dvina Bay during...     

Effect of Anthropogenic Pollution on Macrozoobenthos Structure in Barnaulka River (Upper Ob Basin)

The effect of anthropogenic pollution on the structure of benthic animal communities in the Barnaulka R. (Ob tributary) has been studied. Statistical analysis was used to assess the effect of habitat factors on macrozoobenthos structure. The structure characteristics of benthic macroinvertebrate communities and the bioindication indices calculated from them are shown to depend on the hydrophysical and hydrochemical characteristics of water and bottom sediments.     

Particulate matter fluxes in the southern and central Kara Sea compared to sediments: Bulk fluxes, amino acids, stable carbon and nitrogen isotopes, sterols and fatty acids

The Kara Sea is one of the arctic marginal seas strongly influenced by fresh water and river suspension. The highly seasonal discharge by the two major rivers Yenisei and Ob induces seasonal changes in hydrography, sea surface temperature, ice cover, primary production and sedimentation. In order to obtain a seasonal pattern of sedimentation in the Kara Sea, sediment traps were deployed near the river mouth of the Yenisei (Yen) as well as in the central Kara Sea (Kara) within the framework of the German–Russian project “Siberian River run-off; SIRRO”. Two and a half years of time-series flux data were obtained between September 2000 and April 2003 and were analyzed for bulk components, amino acids, stable carbon and nitrogen isotopes as well as sterols and fatty acids.Sediment trap data show that much of the annual deposition occurred under ice cover, possibly enhanced by zooplanktonic activity and sediment resuspension. An early bloom of ice-associated algae in April/May occurred in the polynya area and may have been very important to sustain the life cycles of higher organisms after the light limitation of the winter months due to no/low insolation and ice cover. The strong river input dominated the months June–August in the southern part of the Kara Sea. The central Kara Sea had a much shorter productive period starting in August and was less affected by the river plumes. Despite different time-scales of sampling and trapping biases, total annual fluxes from traps were in the same order of magnitude as accumulation rates in surface sediments. Terrestrial organic carbon accumulation decreased from 10.7 to 0.3 g C m⁻² a⁻¹ from the riverine source to the central Kara Sea. Parallel to this, preservation of marine organic matter decreased from 10% to 2% of primary productivity which was probably related to decreasing rates of sedimentation.     

Studying chemical exchange across the water-bed interface in Golubaya Bay,the Black Sea

The results of first application of automated bottom station for studying chemical exchange across the water-bed interface (IO RAS lander) were obtained for the case of sediments in the northwestern Black Sea near Gelendzhik (Golubaya Bay). The lander is equipped with bottom chambers, sensors of environmental characteristics, and samplers, allowing fluxes of chemical elements through the water-bed interface to be determined directly. Bottom sediments were represented by organogenous silts containing hydrogen sulfide. The high activity of diagenetic processes resulted in a higher consumption of O₂ by sediments (the flux from the bottom water was 130 mM/(m²/day), high fluxes of biogenic elements (P, Si,) and metals (Mn, Fe). At the same time, fluxes across the water-bed interface were evaluated based on the difference between concentrations of these elements in the near-bed and silt water (Fick’s law). The obtained data demonstrate the priority of direct measurements of fluxes (lander) over the calculation method. The first application of the lander suggests the need for methodological improvements both of engineering character and in chemical-analytical support.     

Hydrocarbons in the modern sediments of the Caspian Sea

The presented results have been obtained in a study of the concentrations and composition of aliphatic and polycyclic hydrocarbons in bottom sediments of Volga delta branches and in its shallow zone (2009–2010), as well as the Caspian Sea proper (2010–2013). Oil hydrocarbon pollution has been found to manifest itself mostly in Volga delta branches, which, despite the low concentrations (up to 54.5 μg/g), showed higher hydrocarbons share in C_org (up to 33.8%), while the composition of alkanes suggested their oil genesis. The geochemical barrier the Volga–the Caspian Sea prevents anthropogenic hydrocarbons from entering the open parts of the Caspian. Bottom sediments in the shallow zone of the Northern Caspian, represented by coarse-grained material, are now polluted by oil hydrocarbons to a lesser extent compared with other areas. The highest concentrations of aliphatic hydrocarbons (up to 178 μg/g) were recorded in the deepsea bottom sediments of Derbent Depression and in depressions of the Middle and Southern Caspian. These areas show a higher concentration of C_org (up to 9.884%) and a low concentration of hydrocarbons in C_org (up to 0.16%), while odd high-molecular homologues (n-C₂₅–C₃₁) dominate in the composition of alkanes.     

Establishing and validation of a standard for oil content of bottom sediments in surface water bodies

Model experiments with oil-polluted bottom sediments and aquatic organisms (bacteria, protozoa, rooted plants, worms, maggots insects, mollusks, crustaceans, benthos-eating fish), whose life cycle is associated with the bed of water bodies, where used to establish the lethal, sublethal, and threshold concentrations, as well as the maximal allowable oil concentration in bottom sediments as a standard established basing on the response of most sensitive test-organisms. The established standard??0.02 g/kg absolutely dry bottom sediment??was validated in rivers of the Ob basin and approved as a regional standard for water bodies of Khanty-Mansi Autonomous Area (Yugra).     

Variable source contributions to river bed sediments across three size fractions

Sediment tracing using geochemical properties is an efficient way to identify the spatial sources of transported sediments delivered to waterways. Here, the contribution of soil sources to river bed sediments has been quantified in Emu Creek, a headwater catchment in south eastern Queensland, Australia. Soil samples were collected from the eight major rock types present in the catchment and were related to river bed sediments collected from eight sites along the main channel. Geochemistry, as characterized by 39 elemental concentrations, was measured using inductively coupled plasma mass spectrometry and inductively coupled plasma optical emission spectrometry. Three particle size fractions were examined, <10, 10–63 and 63–212 µm, with the three resultant mixing models showing divergent results. We conclude that the results of sediment mixing models based on the analysis of one grain size should not be assumed to apply across the entire particle size range of transported sediment, emphasizing the need to match the size fraction used in tracing studies to that size fraction of interest in downstream sinks. Furthermore, we present results highlighting the control transport distance plays in source dominance, with this particularly evident in the coarser fraction, where local sources dominate over more distant sources. Copyright © 2015 John Wiley & Sons, Ltd.     

The hydrological regime of large river basins in Northern Eurasia in the XX–XXI centuries

The ability of present-day climate models to reproduce the mean annual regime of river runoff and its within-year distribution is evaluated for major Eurasian basins, including the basins of the Volga and Amur and the major Siberian rivers: the Ob, Yenisei, and Lena. Estimates are made for possible variations in seasonal runoff and characteristics of daily precipitation (the amount, rate, and probability) in drainage areas for the late XXI century. The analysis involved the use of the results of calculations by climatic general circulation models carried out under international Coupled Model Intercomparison Project.     

Physicochemical state and assessment of technogenic geochemical anomalies in bottom sediments of the Kyibyshev Reservoir near Ulyanovsk City

The results of studying physicochemical properties of bottom sediments in the Kuibyshev Reservoir are given. The evaluated characteristics include their porosity, specific surface area and density, and chemical state characteristics (pH, oil products, organic matter, phenols, and the mobile and total forms of heavy metals). Technogenic geochemical anomalies of bottom sediments are evaluated. The obtained results characterize the environmental state of bottom sediments in the study area.     

Zooplankton response to the lake restoration in the drinking-water source in Meiliang Bay of subtropical eutrophic Lake Taihu, China

A 3-year ecological engineering project was carried out from 2003 to 2005 in the drinking water source in Meiliang Bay, Lake Taihu, China. The project area was divided into three zones: Zone C (outside the area), Zone B (pelagic part within the area) and Zone A (littoral part within the area). The community composition, density and biomass of zooplankton were studied as a part in the lake restoration study. Also, the abundance, biomass and composition of fish in the engineering area were annually analyzed in the littoral zone (Zone A). The average density of cladocerans decreased from the outer part to the inner part of the lake, i.e., from Zone C to Zone A, while the average density of copepod did not significantly vary among the 3 zones. The average densities of rotifer and ciliate increased from Zone C to Zone A. RDA analysis indicated that Microcystis biomass more impacted the zooplankton compositions after temperature. In Zone A, many planktivorous fishes, e.g., Coilia nasus, Hemiculter leucisculus, Pseudorasbora parva, dominated the fish community, which caused a marked decrease in the abundance of cladocerans, especially large-sized cladoceran Daphnia galeata and Daphnia obtusa. Our results suggested that both fish predation and other environmental factors such as the Microcystis bloom greatly affected the zooplankton community during the restoration of subtropical eutrophic lakes.     

First Order Seismic Microzonation of Haldia, Bengal Basin (India) Using a GIS Platform

The seismic microzonation of the Bengal Basin, Haldia region, India is carried out using the Analytical Hierarchy Process (AHP) on the Geographic Information System (GIS). Three themes are used for the seismic microzonation, namely Peak Ground Acceleration (PGA), predominant frequency and elevation map. An analysis of the maximum magnitude (m _max) and the b value is carried out after preparing the earthquake catalogue from various sources. On the basis of the tectonic set up and seismicity of the region, five seismic zones are delineated which can be a threat to Haldia. They are broadly classified as Zone 1: Arakan-Yoma Zone (AYZ), Zone 2: Himalayan Zone (HZ), Zone 3: Shillong Plateau Zone (SPZ), Zone 4: Bay of Bengal Zone (BBZ) and Zone 5: Shield Zone (SZ). The m _max for Zones 1, 2, 3, 4 and 5 are 8.30 ± 0.51, 9.09 ± 0.58, 9.20 ± 0.51, 6.62 ± 0.43 and 6.61 ± 0.43, respectively. The PGA value is computed for Haldia following the attenuation relationship taking the m _max of each source zone. The expected PGA at Haldia varies from 0.09–0.19 g. The predominant frequency of Haldia is also calculated using the H/V ratio with a frequency ranging from 0.1–3.0 Hz. The elevation map of Haldia is also generated using the Shuttle Radar Topography Mission (STRM) data. A first-order seismic microzonation map of Haldia is prepared in which four zones of hazard have been broadly classified for Haldia as very high seismic hazard zone, high seismic hazard zone, moderate seismic hazard zone and less seismic hazard zone. The very high seismic hazard zone is observed along the southern part of Haldia where there are major industrial and port facilities. The PGA for the four hazard zones are: 0.09–0.13 g for low hazard zone, > 0.13–0.15 g for moderate hazard zone, > 0.15–0.16 g for high hazard zone and > 0.16–0.19 g for very high hazard zone.     

Succession and global correlation of Late Tremadoc graptolite zones from South China

The Tremadocian is the first stage of the Ordovician System and is subdivided into two parts in general. The Upper Tremadocian, spanning a temporal interval of ca. 8 Ma, yields graptolite faunas crucial for biostratigraphic division and correlation in high resolution. Relatively complete successions of Upper Tremadoc graptolite zones have been proposed in Scandinavia, and North and South America. In South China, the coeval graptolite strata are widespread in deep water facies, but the successions of graptolite zones recognized so far are quite incomplete and thus very difficult to be correlated with those in other countries. In recent years, we have sampled bed by bed the Nanba section in the Yiyang area, Hunan Province and, below the Tetragraptus approximatus Zone, identified four Upper Tremadoc graptolite zones in descending order: the Hunnegraptus copiosus Zone, the Araneograptus murrayi Zone, the Aorograptus victoriae Zone and the Adelograptus tenellus Zone. To date, the Nanba section is the only section in China that presents a relatively complete and globally comparable succession of Upper Tremadoc graptolite zones. Therefore, this study not only confirms the existence of some Upper Tremadoc graptolite zones that were never found before in China, but also facilitates a highly resolved division and correlation for the Upper Tremadoc graptolite strata in China. Supported by National Natural Science Foundation of China (Grant No. 40472014)     

Late Paleozoic radiolarians from the Bentong-Raub suture zone, Peninsular Malaysia

Abstract Radiolarians extracted from marine siliceous sediments from the Bentong-Raub suture zone, Peninsular Malaysia have indicated a range of ages for olistostromal blocks of bedded chert, siliceous argillite and tuffaceous argillite, and chert clasts and lenses within the mélange from the suture zone. Late Devonian (Faniennian), Early Carboniferous (Tournaisian and Viséan) and Early Permian (Wolfcampian and Leonardian) ages are represented by seven radiolarian zones from ten localities along the suture zone. In stratigraphic order these include Holoeciscus 2–3 Assemblage Zones, Albaillella paradoxa Zone, Albaillella dejendrei Zone, Albaillella cartalla Zone, Pseudoalbaillella lomentaria Zone, Albaillella sinuata Zone and Pseudoalbaillella longtanensis Zone. Fifteen genera are represented by 35 species. The range of ages from Late Devonian to Early Permian suggests that an ocean existed between the Sibumasu and East Malaya terranes from at least Late Devonian to late Early Permian time and that closure of the ocean between the two terranes could not have occurred until after late Early Permian time. The range of ages and rock types from different depositional environments, indicate that the Bentong-Raub suture zone includes a disrupted accretionary complex.     

Toxicity bioassay of bottom sediments in large water bodies in Northwestern Russia with the use of crustaceans

The results of bioassay and physicochemical analysis of bottom sediments from large water bodies in Northwestern Russia are presented. The water bodies under consideration include Lake Onega, Vygozerskoe Reservoir, and freshwater part of the Neva Estuary (the Eastern Gulf of Finland), which are locally subject to eutrophication and toxic pollution. The potential toxicity of bottom sediments, evaluated by the survival rate of two crustacean species (Gmelinoides fasciatus and Ceriodaphnia affinis) in 7-day tests, varied from high to low values, characterizing 5 quality classes: high, good, moderate, poor, and heavy, with appropriate degrees of toxic pollution from no to very high pollution. Bad zones were identified in the Kondopoga and Petrozavodsk bays of Onega Lake, the northern and southern parts of the Vygozerskoe Reservoir, and the southern part of the Neva Bay near the dam. Bottom sediments were found to have high quality in the open central areas of Lake Onega and the Vygozerskoe Reservoir and in the western part of Neva Estuary.     

Early hydrocarbon generation of biological lipids in non-marine lacustrine basins—a genetic mechanism of immature oil

Taking both eastern Linqing Depression and North Jiangsu Basin as examples, based on geochemical features of immature oils as well as source inputs of hydrocarbons and macerals, it is revealed that a mixed source input of alga bio-lipids and higher plant waxes is a basic characteristic of source material for immature oils in non-marine brackish-saline lacustrine basins. Project supported by the “85–102” Chinese National Key Science and Technology Project and the National Gas Geochemistry Key Laboratory, Lanzhou Institute of Geology, Chinese Academy of Sciences.     

Resistivity measurements on the sea bottom to map fracture zones in the bedrock underneath sediments1

Refraction seismics with the shotpoints and the hydrophone cable on the sea-bottom, have become the standard geophysical method for investigating rock quality before constructing offshore tunnels in Norway. In connection with the construction of a sub-sea tunnel by the Norwegian Public Roads Administration, research work was carried out to compare two low-velocity zones, indicated by refraction seismics with other methods. A special resistivity cable for pole-dipole measurements on the sea-floor, with 10 m between the electrodes, was constructed. A 200 m long profile, crossing the two low-velocity zones, was measured with all combinations of electrode distances. The two zones were detected as low-resistivity zones. A special data processing technique to enhance the anomalies is described. Resistivity soundings in a seawater environment to detect fracture zones in the bedrock underneath the bottom sediments, are discussed. It is concluded that severely fractured zones, which may cause difficulties for the tunnel construction, can be detected both with sea-surface and sea-floor arrays using long electrode spacings.